JP2005279327A - Water modifying method employing porous glass film and water modifying apparatus - Google Patents

Water modifying method employing porous glass film and water modifying apparatus Download PDF

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JP2005279327A
JP2005279327A JP2004093237A JP2004093237A JP2005279327A JP 2005279327 A JP2005279327 A JP 2005279327A JP 2004093237 A JP2004093237 A JP 2004093237A JP 2004093237 A JP2004093237 A JP 2004093237A JP 2005279327 A JP2005279327 A JP 2005279327A
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water
spg
porous glass
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Noboru Nakajima
昇 中島
Mitsuteru Fujiwara
光輝 藤原
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SPG TECHNO KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a water modifying method which enables a reduction of a particle size of water molecule clusters certainly and easily, and a water modifying apparatus. <P>SOLUTION: A cylindrical SPG (Shirazu porous glass) film 1 is used as a water-permeable membrane. The pore size of the SPG film 1 is uniform and can be selected within a range of 0.05-20 μm. Thirty SPG films 1 with a pore size of 0.18 μm are attached to an upper lid 3 and a bottom lid 4 to constitute a cylindrical water-permeable module 2 having a water supply port 5 provided to the upper part. Tap water 7 is introduced into the cylindrical water-permeable module 2 to form water 8 containing small clusters. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、シラス多孔質ガラス膜を使用した水の改質方法とその装置に関するものである。   The present invention relates to a water reforming method and apparatus using a shirasu porous glass membrane.

人間をはじめ、動植物の生体の65%以上は水分で構成されている。今日まで私たちは、天然水は無害であるもとの信じてきた。しかし現代においては、自然界では様々な環境汚染が進行し、今後は、安全な水、健康のために良いという水を選択せざるを得ないという時代が到来している。   More than 65% of animals and plants, including humans, are composed of water. To date we have believed that natural water is harmless. However, in the modern world, various environmental pollutions have progressed in the natural world, and in the future, it is time to choose safe water and water that is good for health.

水は、ぶどうの房のようにHO分子が数十個集まった構造になっており、分子の集合体(クラスター)として存在しているが、このクラスターの大きさは様々である。そして、クラスターの小さい水ほど浸透性が高く、生体細胞の隅々まで浸透し、栄養素を運び入れ、老廃物を効率よく運び出し、個々の細胞を活性化する作用があると言われている。 Water has a structure in which dozens of H 2 O molecules are gathered like a bunch of grapes and exists as an aggregate (cluster) of molecules, but the size of this cluster varies. And it is said that the smaller the cluster water, the higher the permeability, and it penetrates to every corner of living cells, carries nutrients, efficiently transports waste products, and activates individual cells.

従来、水分子の水素結合による水分子集合体(以下、クラスターという)を小さくする方法として、活性炭やセラミックスを用いる方法がある。これは水の流通経路にこれらの固形体を多数個収納し、水に浸漬あるいは接触させることでクラスターを小さくしようとするものである(例えば、特許文献1及び特許文献2参照。)。   Conventionally, there is a method using activated carbon or ceramics as a method for reducing a water molecule aggregate (hereinafter referred to as a cluster) due to hydrogen bonding of water molecules. In this method, a large number of these solid bodies are accommodated in a water flow path, and the clusters are made smaller by being immersed or brought into contact with water (see, for example, Patent Document 1 and Patent Document 2).

特開平6−320175号公報JP-A-6-320175 特開平8−252574号公報JP-A-8-252574

また、クラスターの小さい水の効果に関する報告が数々なされている。磁気発生装置などで生成したクラスターの小さい水などもあるが、これは、長時間、強制的に振動を与えられると水分子の大きな集合体は小さな集合体に分裂されていくという原理である。   There have also been many reports on the effects of water with small clusters. There is water with small clusters generated by a magnetic generator, etc., but this is the principle that a large aggregate of water molecules is split into small aggregates when forced to vibrate for a long time.

しかしながら、上記のように活性炭やセラミックスなどの固形体に水を接触させて水分子クラスターを小さくする方法は、固形体に接触するだけで水分子クラスターが小さくなるといっても、固形体を収納している容器内で隣接する固形体間に様々な大きさの空隙が生じ、この空隙を通過する水に関しては水分子クラスターを小さくするには不十分と思料される。
本発明は、上記課題に鑑みなされたもので、孔径の均一に揃ったシラス多孔質ガラス膜に水を強制的に透過させることにより確実且つ手軽に水分子クラスターを小さくすることのできる方法とその装置を提供することにある。
However, as described above, the method of reducing the water molecule cluster by bringing water into contact with a solid body such as activated carbon or ceramics accommodates the solid body even if the water molecule cluster is reduced simply by contacting the solid body. Voids of various sizes are generated between adjacent solid bodies in a container, and it seems that water passing through the voids is insufficient to make the water molecule cluster small.
The present invention has been made in view of the above problems, and a method capable of reliably and easily reducing a water molecule cluster by forcibly allowing water to permeate through a shirasu porous glass film having a uniform pore size and its To provide an apparatus.

このため本発明では、成形した多孔質ガラス膜の三次元的な網目状の連続した細孔に水を透過させることにより、水分子クラスターを小さくし、水を改質することができる。本発明に最も適しているシラス多孔質ガラス膜(以下、SPGという)は、膜を貫通する多数の細孔を有し、気孔率の高い細孔の均一性について優れている公知の多孔質ガラス膜である。成形するSPGの形状自体は特に限定されないが、平板形、円柱形など使用目的に応じた形状に成形できる。また、SPGの表面を鍍金や二酸化チタンなどの有効触媒でコートすることによりSPGの汚染を少なくしたり、水の改質を向上させたりすることも可能である。また、SPG膜表面層に通電可能な鍍金を施すことにより片面にプラス極、もう片面にマイナス極の電極を取り付け、水を透過させながら水を電気的に改質することも可能である。   For this reason, in this invention, a water molecule cluster can be made small and water can be modified | denatured by making water permeate | transmit the three-dimensional network-like continuous pore of the shape | molded porous glass film | membrane. The Shirasu porous glass membrane (hereinafter referred to as SPG) most suitable for the present invention has many pores penetrating the membrane, and is a known porous glass excellent in uniformity of pores with high porosity. It is a membrane. The shape of the SPG to be formed is not particularly limited, but can be formed into a shape according to the purpose of use, such as a flat plate shape or a cylindrical shape. In addition, it is possible to reduce SPG contamination or improve water reforming by coating the surface of SPG with an effective catalyst such as plating or titanium dioxide. It is also possible to electrically modify water while allowing water to permeate by attaching a positive electrode on one side and a negative electrode on the other side by applying an energizable plating to the surface layer of the SPG film.

本発明によれば、確実且つ手軽にクラスターの小さい水を得ることができる。   According to the present invention, water with small clusters can be obtained reliably and easily.

以下に、本発明の実施の形態を図面に示す実施例に基づいて説明する。
図1は、本発明の一実施例を示す水透過モジュール全体概略図を示すものであり、図5は水クラスターの質量分析スペクトラムを示すグラフである。
Hereinafter, embodiments of the present invention will be described based on examples shown in the drawings.
FIG. 1 is an overall schematic view of a water permeation module showing an embodiment of the present invention, and FIG. 5 is a graph showing a mass analysis spectrum of a water cluster.

図1に示すように、本実施例では水の透過膜として、円筒状のSPG膜1を用いた。このSPG膜1は、細孔径が均一で、0.05μm乃至20μmの範囲で細孔径を選定できるが、本実施例では孔径3μmのSPG膜を使用した。図5のグラフは透過した水(以下、SPG処理水という)の質量分析スペクトラムの水分子を換算してその個数として示したものである。   As shown in FIG. 1, a cylindrical SPG membrane 1 was used as a water permeable membrane in this example. The SPG membrane 1 has a uniform pore diameter, and the pore diameter can be selected in the range of 0.05 μm to 20 μm. In this example, an SPG membrane having a pore diameter of 3 μm was used. The graph of FIG. 5 shows the number of water molecules in the mass spectrometry spectrum of the permeated water (hereinafter referred to as SPG treated water) in terms of the number.

このグラフから、原水(通常の水道水)の水分子のクラスター分布に比べて、SPG処理水は、大きい方のクラスター分布が減少し、小さい方のクラスター分布が増加していることが判かる。   From this graph, it can be seen that the larger cluster distribution of the SPG treated water is decreased and the smaller cluster distribution is increased compared to the cluster distribution of water molecules of the raw water (normal tap water).

また、図6、図7に手軽にクラスターの小さい水を生成できる携行可能な器具を示す。図6に示す噴霧器は、ハンドスプレータイプで、ポンプ部11を人手で押圧すると、水汲み上げ導管10よりSPG膜1を介してクラスターが小さくなった水がノズル12から噴霧される構成にされている。また、図7に示す噴霧器は、容器内の気圧をポンプ部11で高めておいて、水を噴霧させたいときにボタン13を押圧することにより水汲み上げ導管10よりSPG膜を介してクラスターが小さくなった水がノズル12から噴霧されるという構成にされている。これら噴霧器に水道水や、ミネラルウォーターを入れて噴霧操作するだけでいつでもどこでも必要に応じてその場でクラスターの小さい水分を肌や、植物などに補給することができる。   6 and 7 show portable devices that can easily generate water with small clusters. The sprayer shown in FIG. 6 is a hand spray type, and when the pump unit 11 is manually pressed, water having a smaller cluster is sprayed from the nozzle 12 through the SPG film 1 from the water pumping conduit 10. . Further, the sprayer shown in FIG. 7 has a cluster smaller than the water pumping conduit 10 through the SPG membrane by pressing the button 13 when the pressure inside the container is increased by the pump unit 11 and it is desired to spray water. The water thus formed is sprayed from the nozzle 12. By simply putting tap water or mineral water into these sprayers and spraying them, you can replenish your skin, plants, etc. with small clusters of water anytime and anywhere.

孔径0.18μmのSPG膜に透過させた水による切花の持続経過観測を実施した。SPG膜の形状は、外径10mm、内径8.5mm、肉厚0.75mm、長さ250mmの円筒状で、図1に示すような30本のSPG膜1を上蓋3及び底蓋4で密閉状に取付け、上部に給水口5を有する円筒形の水透過モジュール2で水を生成した。切花に使用した水は、水道6から直接導入される通常の水道水7とSPG膜1で透過した後の水道水を用いた。花の品種は、バラと、ユリを用いた。表1に示すように、通常の水道水よりも、SPG膜処理後のクラスターの小さい水の方が花の持ちが良かった。

Figure 2005279327
A continuous progress observation of cut flowers with water permeated through an SPG membrane having a pore size of 0.18 μm was performed. The SPG film has a cylindrical shape with an outer diameter of 10 mm, an inner diameter of 8.5 mm, a wall thickness of 0.75 mm, and a length of 250 mm, and 30 SPG films 1 as shown in FIG. Water was generated by a cylindrical water transmission module 2 having a water supply port 5 at the top. The water used for the cut flowers was normal tap water 7 introduced directly from the tap 6 and tap water after passing through the SPG membrane 1. The flower varieties were roses and lilies. As shown in Table 1, the water with smaller clusters after the SPG membrane treatment had better flowers than ordinary tap water.
Figure 2005279327

以上のように、本発明では、大掛かりな電気的な装置を必要とせず安価な装置で水のクラスターを小さくすることができる。セラミックスなどを積層させたフィルターのような隣同士のセラミックス間の空隙を通過するような状態は全く起こらず、SPG膜を用いた水透過装置は、均一に揃った図4に示すような孔を確実に透過させることのできる水改質装置である。SPG膜はガラスフィルターであり、管状のものでは外圧に対して約30kgf/cm耐えることができるなど、孔径の不均一な有機膜のように外圧を加えたときその孔径より大きいものであれば、有機膜の孔径が拡がりながら大きいものが透過してしまい、不均一な孔径ゆえに大きい孔径から透過してしまいやすいという問題は全くない。よってSPG膜のような無機質膜で孔径が均一に揃っていることにより、圧力を加えれば水を強制的にSPG膜孔に均一に透過させることができ、手軽に水のクラスターの大きさを小さくすることが可能である。磁気や電気などを使うクラスター改質装置と違い、電力エネルギーも必要なく危険性もまったくない。 As described above, in the present invention, a water cluster can be reduced with an inexpensive device without requiring a large-scale electrical device. The state of passing through the gap between adjacent ceramics such as a filter in which ceramics are laminated does not occur at all, and the water permeation device using the SPG film has uniform holes as shown in FIG. It is a water reforming device that can permeate reliably. The SPG membrane is a glass filter, and it can withstand about 30 kgf / cm 2 with respect to the external pressure in the case of a tubular one, so long as it is larger than the pore size when an external pressure is applied like an organic membrane with a nonuniform pore size. However, there is no problem that a large organic substance permeates while the pore diameter of the organic film is widened, and it is easy to permeate from a large pore diameter because of the nonuniform pore diameter. Therefore, since the pore size is uniform in an inorganic membrane such as an SPG membrane, water can be forced to permeate the SPG membrane pores uniformly when pressure is applied, and the size of the water cluster can be easily reduced. Is possible. Unlike cluster reformers that use magnetism or electricity, there is no need for energy and no danger.

このようにSPG膜を搭載した水クラスターの改質装置は、図9に示すような片側を封管したSPG膜を搭載した図8のような構造の水クラスター改質装置も考えられる。この図8の装置はSPG膜の周辺に活性炭14を敷き詰めて、活性炭層15で水中の大きな不純物などを一次ろ過として行い、二次フィルターとしてSPG膜に通水させることにより汚れた水道水を効率よく浄化させながら水のクラスターを小さくすることのできる水の改質装置が考えられる。SPG膜そのものは、水のクラスターを変えるだけでなく均一な孔径を有しているので、大きな抜け穴がなく、ろ過不足などの心配が全くない除菌効果なども期待できる。   As the water cluster reformer equipped with the SPG membrane in this way, a water cluster reformer having a structure as shown in FIG. 8 equipped with an SPG membrane sealed on one side as shown in FIG. 9 is also conceivable. The apparatus of FIG. 8 spreads activated carbon 14 around the SPG membrane, performs large-scale impurities in the water as primary filtration with the activated carbon layer 15, and passes the water through the SPG membrane as a secondary filter to efficiently remove dirty tap water. A water reformer that can reduce water clusters while purifying well is considered. Since the SPG membrane itself has a uniform pore size as well as changing the water cluster, it can be expected to have a sterilization effect without any large loopholes and no fear of insufficient filtration.

クラスターの小さい水は、浸透性が良いといわれているので、乾燥した肌などに噴霧し保水力を高めたり、またクラスターの小さい水は、油脂を溶かす能力があるとも言われており、頭皮にスプレーすることにより頭髪の毛根に埋まった皮脂などを洗い流すのに効果があることも考えられる。さらに、人体は自分自身でクラスターの小さい水を体内で製造する能力があるといわれているが、赤ちゃんや幼児の身体では効率良く製造するためのエネルギーが豊富にあるのに対し、加齢により、生体自身がクラスターの小さい水を製造しようとするエネルギーが減少していき、体内のクラスターの小さい水が減少していくということが言われている。また、一番多くクラスターの小さい水を製造できる臓器が女性の子宮だとも言われている。本発明の水のクラスターを小さくするSPG膜搭載水の改質装置で生成した水を飲料水として利用し、クラスターの小さい水を供給することにより身体の体質改善にも効果があると期待できる。   Water with small clusters is said to have good permeability, so it can be sprayed on dry skin to increase water retention, and water with small clusters is said to have the ability to dissolve oils and fats. It may be effective to wash away sebum buried in the hair root by spraying. In addition, the human body is said to have the ability to produce small clusters of water by itself, but the body of babies and infants has abundant energy to produce efficiently, It is said that the energy that the living body itself tries to produce water with small clusters decreases, and the water with small clusters in the body decreases. It is also said that the organ that can produce the most water with small clusters is the female uterus. It can be expected that the water produced by the SPG membrane-equipped water reforming apparatus for reducing the water cluster of the present invention is used as drinking water, and by supplying water with a small cluster, it is also effective for improving the constitution of the body.

本発明に係る水透過モジュールの一実施例を示す概略図である。It is the schematic which shows one Example of the water permeation | transmission module which concerns on this invention. 水透過モジュールの上蓋の平面図である。It is a top view of the upper cover of a water permeation module. 水透過モジュールの底蓋の平面図である。It is a top view of the bottom cover of a water permeation module. SPG膜を模式的に示す断面図である。It is sectional drawing which shows a SPG film | membrane typically. 通常の水道水とSPG処理水の質量分析スペクトラムを示すグラフである。It is a graph which shows the mass spectrometry spectrum of normal tap water and SPG processing water. SPG膜を搭載した噴霧器の一実施例を示す斜視図である。It is a perspective view which shows one Example of the sprayer carrying an SPG film | membrane. SPG膜を搭載した噴霧器の他の実施例を示す斜視図である。It is a perspective view which shows the other Example of the sprayer carrying an SPG film | membrane. SPG膜を搭載した浄水装置を示す斜視図である。It is a perspective view which shows the water purifier which mounts an SPG membrane. 浄水装置に搭載されたSPG膜を模式的に示す断面図である。It is sectional drawing which shows typically the SPG membrane mounted in the water purifier.

符号の説明Explanation of symbols

1 シラス多孔質ガラス膜(SPG膜)
2 水透過モジュール
3 上蓋
4 底蓋
5 給水口
6 水道
7 原水(水道水)
8 SPG処理水
9 ポンプ式容器
10 水汲み上げ導管
11 ポンプ部
12 ノズル
13 ボタン
14 活性炭
15 活性炭層
1 Shirasu porous glass membrane (SPG membrane)
2 Water permeation module 3 Top lid 4 Bottom lid 5 Water supply port 6 Water supply 7 Raw water (tap water)
8 SPG treated water 9 Pump type vessel 10 Water pumping conduit 11 Pump part 12 Nozzle 13 Button 14 Activated carbon 15 Activated carbon layer

Claims (4)

シラス多孔質ガラス膜を用いた水の改質方法であって、シラス多孔質ガラス膜の貫通孔に水を透過させることにより水のクラスターを小さくすることを特徴とする水の改質方法。   A water reforming method using a shirasu porous glass membrane, wherein the water cluster is made smaller by allowing water to permeate through the through holes of the shirasu porous glass membrane. 多孔質ガラス膜の三次元的な網目状の連続した細孔に水を透過させることにより、水分子クラスターを小さくすることを特徴とする水の改質方法。   A method for reforming water, wherein water molecules are made smaller by allowing water to permeate through three-dimensional network-like continuous pores of a porous glass membrane. 多孔質ガラス膜の表面を鍍金や二酸化チタンなどの有効触媒で被覆することを特徴とする請求項1記載の水の改質方法。   The method for reforming water according to claim 1, wherein the surface of the porous glass film is coated with an effective catalyst such as plating or titanium dioxide. ノズルを有する押圧ヘッドと内部に液体汲み上げ用の導管が挿通されると共に、水が収納された水収納容器とからなり、前記押圧ヘッドに圧力を加えることによりシラス多孔質ガラス膜を介してノズルよりクラスターの小さい水を生成吐出することを特徴とする水の改質装置。   It consists of a pressure head having a nozzle and a water storage container in which water is drawn up and a water storage container in which water is stored. By applying pressure to the pressure head, the nozzle is inserted through a shirasu porous glass membrane. A water reforming apparatus characterized by generating and discharging water having small clusters.
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