JP2005263516A - Molten steel vessel, method for manufacturing steel using the same, and lining refractory - Google Patents

Molten steel vessel, method for manufacturing steel using the same, and lining refractory Download PDF

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JP2005263516A
JP2005263516A JP2004074838A JP2004074838A JP2005263516A JP 2005263516 A JP2005263516 A JP 2005263516A JP 2004074838 A JP2004074838 A JP 2004074838A JP 2004074838 A JP2004074838 A JP 2004074838A JP 2005263516 A JP2005263516 A JP 2005263516A
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molten steel
refractory
steel container
ladle
lined
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Tsukasa Niide
司 新出
Michihiro Kuwayama
道弘 桑山
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JFE Steel Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To prevent build-up of slag adhering to the inside surface of a molten steel vessel, such as a ladle. <P>SOLUTION: A molten steel lining section 6 on the inside surface of the ladle 1 is lined with the dolomitic refractories. The refractories are composed of CaO, MgO, C, and inevitable impurities. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

この発明は、溶鋼中に発生するスラグ対策として有効な溶鋼容器、それを用いた鋼の製造方法、および、溶鋼容器の内張り耐火物に関するものである。   The present invention relates to a molten steel container effective as a countermeasure against slag generated in molten steel, a method for producing steel using the same, and a refractory lining the molten steel container.

鉄鋼製造プロセスでは、溶鋼を貯留したり、製錬したり、スラブの鋳型に鋳込むために耐火物が内張りされた容器が使用されている。例えば、連続鋳造工程で使用する取鍋の内張り耐火物には、Al23(酸化アルミニウム)質の耐火物が多用されている。 In the steel manufacturing process, a vessel with a refractory lined is used to store molten steel, smelt it, or cast it into a slab mold. For example, Al 2 O 3 (aluminum oxide) refractories are frequently used as lining refractories for ladles used in continuous casting processes.

ところがAl23質の内張り耐火物では、取鍋の内面にスラグが付着する、いわゆるビルドアップの問題がある。そのため、ビルドアップされたスラグによって取鍋の有効体積が減少し、1チャージ当たりの処理量が減少してしまったり、取鍋内面の耐火物に付着したスラグが鋳造中に剥がれ、溶鋼の温度が下がって鋳造ができなくなったり、取鍋のノズルがスラグによって閉塞し、溶鋼流れに支障をきたす等の問題があった。 However, Al 2 O 3 lining refractories have a so-called build-up problem in which slag adheres to the inner surface of the ladle. Therefore, the effective volume of the ladle is reduced by the built-up slag, the processing amount per charge is reduced, or the slag adhering to the refractory on the inner surface of the ladle is peeled off during casting, and the temperature of the molten steel is reduced. There was a problem that the casting could not be performed due to lowering or the nozzle of the ladle was blocked by the slag, which hindered the flow of molten steel.

従来から、これらの容器内面の耐火物の付着に対応して、下記(1)、(2)に示す種々の対策が取られている。   Conventionally, various countermeasures shown in the following (1) and (2) have been taken in response to the adhesion of refractories on the inner surface of these containers.

(1)連続鋳造後、取鍋内面に付着したスラグを除去する方法として、削岩用解体機によって付着物を除去する方法や、高酸素負荷バーナーによって付着物を溶解除去する方法が用いられている(以下、「先行技術」という)。   (1) As a method of removing slag adhering to the ladle inner surface after continuous casting, a method of removing deposits with a rock drilling demolition machine or a method of dissolving and removing deposits with a high oxygen load burner is used. (Hereinafter referred to as “prior art”).

(2)また、溶鋼容器の内面にスラグが付着すること自体を防止する方法として、スラグの存在下で低融点化合物を生成する添加物を溶鋼容器のスラグ上に投入する方法が開示されている。例えば、特許文献1には、ホタル石10〜80wt.%および石灰石90〜20wt.%を主材としてなる溶鋼容器用スラグビルドアップ防止剤を溶鋼容器内のスラグに投下する技術が開示されている。   (2) Further, as a method for preventing the slag from adhering to the inner surface of the molten steel container, a method is disclosed in which an additive that generates a low melting point compound in the presence of slag is introduced onto the slag of the molten steel container. . For example, Patent Document 1 discloses a technique for dropping a slag buildup inhibitor for a molten steel container mainly composed of fluorite 10 to 80 wt.% And limestone 90 to 20 wt.% Onto the slag in the molten steel container. .

特開平4−116117号公報JP-A-4-116117

しかしながら、上述した(1)、(2)には下記に示す問題がある。   However, (1) and (2) described above have the following problems.

(1)先行技術のように、削岩用解体機で取鍋に付着したスラグを除去すると、取鍋内面の破損は避けられず、取鍋の寿命を低下させる。また、除去作業は取鍋が冷えてからの作業になるため、連続的に取鍋を使用することができないばかりか、取鍋の使用に際して、必要な温度まで上げなければならないので、熱エネルギーロスや転炉耐火物の寿命低下にもつながるという弊害も発生する。   (1) When the slag adhering to the ladle is removed by a rock drilling dismantling machine as in the prior art, the inner surface of the ladle is inevitably damaged, and the life of the ladle is reduced. In addition, since the ladle operation is performed after the ladle has cooled down, not only can the ladle be used continuously, but also when the ladle is used, the temperature must be raised to the required temperature. There is also a negative effect that the life of the converter refractory is shortened.

(2)特許文献1に示した溶鋼容器内のスラグにビルドアップ防止剤を添加する技術においては、ビルドアップ防止剤を添加する工程が追加されるため、製造コストの上昇につながる問題がある。   (2) In the technique of adding a buildup inhibitor to the slag in the molten steel container shown in Patent Document 1, a process of adding the buildup inhibitor is added, which causes a problem that leads to an increase in manufacturing cost.

以上より、工程の中断がなく、エネルギーコストおよび製造効果の両面で有利な製造技術の開発が望まれている。   From the above, there is a demand for the development of a manufacturing technique that is advantageous in terms of both energy cost and manufacturing effect without interruption of the process.

従って、この発明の目的は、上述の課題を解決し、溶鋼中に発生するスラグの影響を極力防止することができる溶鋼容器、それを用いた鋼の製造方法および内張り耐火物を提供することにある。   Accordingly, an object of the present invention is to solve the above-mentioned problems and provide a molten steel container capable of preventing the influence of slag generated in molten steel as much as possible, a method for manufacturing steel using the same, and a lining refractory. is there.

本発明者らは、連続使用に耐え得る溶鋼容器の構造並びに鋼の製造方法等について鋭意研究を重ねた結果、ビルドアップを防止させる成分を含む耐火物を見出し、前記耐火物を溶鋼容器の内面に内張りすることにより、連続的に使用できる溶鋼容器並びに鋼の製造方法を得られることを知見した。この発明は、上記知見によってなされたものであり、次のような構成を有している。
[1]内面が耐火物によって内張りされた溶鋼容器であって、少なくとも前記溶鋼容器内に装入された溶鋼が滞留する溶鋼ライン部に内張りされた前記耐火物がドロマイトからなることを特徴とする溶鋼容器。
[2]前記耐火物が、更に、質量%で、2〜5%のCを含有することを特徴とする前項[1]に記載の溶鋼容器。
[3]内面が耐火物によって内張りされ、前記耐火物は、質量%で、CaO:50〜90%、MgO:10〜40%および不可避不純物を含有し、且つ、含有物の合計が100%であることを特徴とする溶鋼容器。
[4]内面が耐火物によって内張りされ、前記耐火物は、質量%で、CaO:50〜90%、MgO:10〜40%、C:2〜5%および不可避不純物を含有し、且つ、含有物の合計が100%であることを特徴とする溶鋼容器。
[5]内面が耐火物によって内張りされた溶鋼容器であって、少なくとも前記溶鋼容器内に装入された溶鋼が滞留する溶鋼ライン部が、前項[3]または[4]に記載の耐火物からなることを特徴とする溶鋼容器。
[6]転炉において製錬した溶鋼を取鍋に移し、次いで、前記溶鋼を連続鋳造する鋼の製造方法において、前記取鍋として前項[1]から[5]のうちの何れか1に記載の溶鋼容器を用いることを特徴とする鋼の製造方法。
[7]内面が耐火物によって内張りされた溶鋼容器の前記耐火物であって、質量%で、CaO:50〜90%、MgO:10〜40%および不可避不純物を含有し、且つ、含有物の合計が100%であることを特徴とする溶鋼容器の内張り耐火物。
[8]内面が耐火物によって内張りされた溶鋼容器の前記内張り耐火物であって、質量%で、CaO:50〜90%、MgO:10〜40%、C:2〜5%および不可避不純物を含有し、且つ、含有物の合計が100%であることを特徴とする溶鋼容器の内張り耐火物。
As a result of earnest research on the structure of the molten steel container that can withstand continuous use and the steel manufacturing method, the present inventors have found a refractory containing a component that prevents build-up, and the refractory is used as an inner surface of the molten steel container. It has been found that a molten steel container that can be used continuously and a method for producing steel can be obtained by lining the steel. The present invention has been made based on the above findings, and has the following configuration.
[1] A molten steel container lined with a refractory material, wherein the refractory material lined at least in a molten steel line portion where the molten steel charged in the molten steel container is made of dolomite Molten steel container.
[2] The molten steel container as described in the above item [1], wherein the refractory further contains 2 to 5% by mass of C.
[3] The inner surface is lined with a refractory, and the refractory contains, by mass%, CaO: 50 to 90%, MgO: 10 to 40% and unavoidable impurities, and the total content is 100%. A molten steel container characterized by being.
[4] The inner surface is lined with a refractory, and the refractory contains, by mass%, CaO: 50 to 90%, MgO: 10 to 40%, C: 2 to 5%, and inevitable impurities. A molten steel container characterized in that the total of the objects is 100%.
[5] A molten steel container whose inner surface is lined with a refractory, and at least a molten steel line portion in which the molten steel charged in the molten steel container is retained is the refractory according to [3] or [4] above. A molten steel container characterized by comprising:
[6] In the method for producing steel in which molten steel smelted in a converter is transferred to a ladle and then continuously casted, the ladle according to any one of [1] to [5] above as the ladle. A method for producing steel, characterized by using a molten steel container.
[7] The refractory of the molten steel container whose inner surface is lined with a refractory, and containing, by mass%, CaO: 50 to 90%, MgO: 10 to 40% and inevitable impurities, and A lining refractory for a molten steel container, characterized in that the total is 100%.
[8] The lining refractory of a molten steel container whose inner surface is lined with a refractory, wherein CaO: 50 to 90%, MgO: 10 to 40%, C: 2 to 5% and inevitable impurities are contained in mass%. A refractory for lining a molten steel container, characterized in that the total content is 100%.

取鍋等の溶鋼容器に内張りされた耐火物中に含有されているCaOがスラグと反応し、スラグが溶鋼容器の内面に付着するビルドアップが防止され、溶鋼装入量の減少を防ぐことができ、歩留まりを大幅に向上できる。   CaO contained in a refractory lined in a molten steel container such as a ladle reacts with slag, preventing build-up where the slag adheres to the inner surface of the molten steel container and preventing a decrease in the amount of molten steel charged And the yield can be greatly improved.

MgOや更にCが含有されているため、従来の溶鋼容器と同等の耐用度が得られる。   Since MgO and C are contained, the durability equivalent to that of a conventional molten steel container can be obtained.

ビルドアップ防止剤を添加する工程を必要としないので作業効率が良好である。   Since a process for adding a buildup inhibitor is not required, the working efficiency is good.

溶鋼容器の内面に付着したスラグを取り除く作業が不要となり、この除去作業のための中断がなくなり、転炉耐火物や溶鋼容器の冷却による熱エネルギーロスや寿命低下が防止される。   There is no need to remove the slag adhering to the inner surface of the molten steel container, there is no interruption for this removal work, and heat energy loss and life reduction due to cooling of the converter refractory and the molten steel container are prevented.

次に、この発明の実施の形態を図面を参照しながら説明する。   Next, embodiments of the present invention will be described with reference to the drawings.

本発明の溶鋼容器、例えば、取鍋においては、容器内面に、CaO(酸化カルシウム)およびMgO(酸化マグネシウム)からなるドロマイトおよび不可避不純物からなる耐火物が内張りされている。耐火物には、必要に応じて、更に、C(炭素)を含有することもできる。Cを含むカーボンドロマイトを用いることもできる。このように、取鍋の内面の内張りを、ドロマイト質の耐火物によって構成することにより、所望のビルドアップ防止効果が得られる。   In the molten steel container of the present invention, for example, a ladle, dolomite composed of CaO (calcium oxide) and MgO (magnesium oxide) and a refractory composed of inevitable impurities are lined on the inner surface of the container. The refractory can further contain C (carbon) as necessary. Carbon dolomite containing C can also be used. Thus, a desired buildup prevention effect is acquired by comprising the lining of the inner surface of a ladle with a dolomite refractory.

CaOは、取鍋内に装入された溶鋼により溶けてスラグと反応し、スラグの融点を下げ低融点にして取鍋内面への付着を防止しビルドアップを防ぐ作用を有する。耐火物中のCaOの好ましい含有量の範囲は、質量%(以下、「mass%」)で50〜90mass%である。CaO含有量が50mass%未満では、前記作用があまり顕著とならない。一方、CaO含有量が90mass%超えでは、複合して用いられるMgOの含有量が少なくなり、内張り耐火物としての耐用度が減少する。   CaO is melted by the molten steel charged in the ladle and reacts with the slag, lowers the melting point of the slag, lowers the melting point, prevents adhesion to the inner surface of the ladle, and has an effect of preventing build-up. The range of the preferable content of CaO in the refractory is 50 to 90 mass% in mass% (hereinafter, “mass%”). When the CaO content is less than 50 mass%, the above action is not so remarkable. On the other hand, when the CaO content exceeds 90 mass%, the content of MgO used in combination decreases, and the durability as a lining refractory decreases.

MgOは、耐火物の耐用度を確保する作用を有する。MgOの好ましい含有量の範囲は、10〜40mass%である。MgO含有量が10mass%未満では、内張り耐火物としての耐用度が減少する。一方、MgO含有量が40mass%超えでは、CaOの含有量が減少しビルドアップ防止作用に影響する。このように、CaO:50〜90mass%、MgO:10〜40mass%の範囲内で含有し、不可避不純物を含め合計を100mass%としてCaOおよびMgOの複合構造とすることにより、CaOによりビルドアップの成長を防止し且つMgOにより所望の耐用度を得ることができる。   MgO has the effect | action which ensures the durability of a refractory. The range of preferable content of MgO is 10 to 40 mass%. When the MgO content is less than 10 mass%, the usefulness as a lining refractory decreases. On the other hand, if the MgO content exceeds 40 mass%, the CaO content decreases, which affects the buildup prevention effect. In this way, CaO: 50 to 90 mass%, MgO: contained in the range of 10 to 40 mass%, and the total of 100 mass% including unavoidable impurities is used as a composite structure of CaO and MgO, so that build-up growth with CaO And a desired durability can be obtained with MgO.

Cは、耐火物の耐久性を強化するために用いる。取鍋は1日に複数回(複数チャージ)、例えば、4〜8回位使用されるが、本発明耐火物はCaOを所定量含有するドロマイト質であるため、割れ、破損などのスポーリング性が問題となる。例えば、取鍋を1日に複数回使用する場合において、1回の使用の後、次の使用までの時間的間隔の間に取鍋が冷えて耐火物の温度が下がり、加熱時(溶鋼装入)と冷却時(溶鋼なし)との温度差により耐火物が割れる原因となる。特に、間隔が長くなると冷えが顕著となる。従って、耐火物に、更に、Cを2〜5mass%含有して耐久性を強化する。すなわち、Cは、耐火物の耐用度を向上する作用を有する。このように、CaO:50〜90%、MgO:10〜40%C:2〜5mass%の範囲内で含有し、不可避不純物を含め合計を100mass%とすることにより、CaOによりビルドアップの成長を防止し且つMgOにより所望の耐用度を得、そして、Cにより耐用度が強化される。C含有量が2mass%未満では、上記作用に所望の効果が得られない。一方、C含有量が5mass%を超えると、溶鋼中に溶け出したCによって溶鋼中のC量が増加し、製品(溶鋼)の成分調整に影響がでる。   C is used to enhance the durability of the refractory. The ladle is used several times a day (multiple charges), for example, 4 to 8 times. However, since the refractory of the present invention is dolomite containing a predetermined amount of CaO, it is spalling such as cracking and breakage. Is a problem. For example, when a ladle is used several times a day, the ladle cools during the time interval until the next use after one use, and the temperature of the refractory decreases, and when heated (molten steel ON) and cooling (no molten steel) causes the refractory to crack. In particular, when the interval becomes long, the cooling becomes remarkable. Accordingly, the refractory further contains 2 to 5 mass% of C to enhance durability. That is, C has an effect of improving the durability of the refractory. In this way, CaO: 50 to 90%, MgO: 10 to 40% C: 2 to 5 mass%, including the inevitable impurities, the total is 100 mass%, the build-up growth by CaO Prevent and obtain the desired service life with MgO, and C enhances the service life. When the C content is less than 2 mass%, a desired effect cannot be obtained in the above action. On the other hand, when the C content exceeds 5 mass%, the amount of C in the molten steel increases due to the C that has melted into the molten steel, which affects the adjustment of the components of the product (molten steel).

図1は、この発明の実施の形態に係る連続鋳造に用いる取鍋の断面構造を示す概念図である。図1に示すように、取鍋1内に装入された溶鋼2は、取鍋1の下方の溶鋼ライン部6に滞留し、一方、スラグ3は溶鋼2の上方のスラグライン部5に位置する。従って、装入された溶鋼2が多くの時間接触するのは、溶鋼が滞留する溶鋼ライン部6である。すなわち、ビルドアップの成長により溶鋼装入量の減少に影響するのは溶鋼ライン部6に付着したスラグである。従って、スラグライン部5を、CaOを含まない耐火物、例えば、MgOあるいはAl23を主体とする耐火物によって構成しても、溶鋼装入量にさほど影響しない。すなわち、溶鋼ライン部6を本発明の耐火物によって構成し、スラグライン部5は、CaOを含まない耐火物、例えば、MgOあるいはAl23を主体とする耐火物によって構成することもできる。 FIG. 1 is a conceptual diagram showing a cross-sectional structure of a ladle used for continuous casting according to an embodiment of the present invention. As shown in FIG. 1, the molten steel 2 charged in the ladle 1 stays in the molten steel line portion 6 below the ladle 1, while the slag 3 is located in the slag line portion 5 above the molten steel 2. To do. Therefore, it is the molten steel line part 6 in which molten steel retains that the molten steel 2 with which it was charged contacts for many hours. That is, it is the slag adhering to the molten steel line part 6 that influences the decrease of the molten steel charging amount by the build-up growth. Therefore, even if the slag line portion 5 is composed of a refractory that does not contain CaO, for example, a refractory mainly composed of MgO or Al 2 O 3 , the amount of molten steel charged is not significantly affected. That constitutes the molten steel line portion 6 by refractory of the present invention, the slag line portion 5, a refractory containing no CaO, for example, it may be constituted by a refractory mainly composed of MgO or Al 2 O 3.

次に、この発明を実施例により更に詳細に説明する。   Next, the present invention will be described in more detail with reference to examples.

本発明の耐火物を取鍋型の溶鋼容器に適用した。図1に示すように、取鍋1の内面を、底面(以下、底面を「敷き」という)4、下側の内側面を構成する溶鋼ライン部6、および、溶鋼ライン部6の上方の上側の内側面を構成するスラグライン部5とに分け、敷き4は、Al23を主体とする耐火物、スラグライン部5は、MgOを主体とする耐火物により内張りし、そして、溶鋼ライン部6は、表1に示す本発明例1〜10に示す本発明耐火物によって内張りし、取鍋の供試体を調製した。比較例として、溶鋼ライン部6に、Al23を主体とする表1に示す耐火物を内張りし、敷き4およびスラグライン部5は、本発明供試体と同様にMgOやAl23を主体とする耐火物によって内張りした取鍋の供試体を調製した。表1の「その他」の項に示す「Bal.」は、不可避不純物を含む。 The refractory of the present invention was applied to a ladle type molten steel container. As shown in FIG. 1, the inner surface of the ladle 1 includes a bottom surface (hereinafter referred to as “laying”) 4, a molten steel line portion 6 constituting the lower inner surface, and an upper side above the molten steel line portion 6. The slag line portion 5 is divided into a slag line portion 5 constituting the inner surface of the slag, the lay 4 is refractory mainly composed of Al 2 O 3 , the slag line portion 5 is lined with a refractory composed mainly of MgO, and the molten steel line Part 6 was lined with the refractory of the present invention shown in Examples 1 to 10 of the present invention shown in Table 1 to prepare a ladle specimen. As a comparative example, the molten steel line portion 6 is lined with a refractory as shown in Table 1 mainly composed of Al 2 O 3 , and the lay 4 and the slag line portion 5 are made of MgO or Al 2 O 3 in the same manner as the specimen of the present invention. A specimen of a ladle lined with a refractory mainly composed of a refractory was prepared. “Bal.” Shown in the “Others” section of Table 1 includes inevitable impurities.

Figure 2005263516
Figure 2005263516

そして、鋼の製造プロセスにおいて転炉において精錬した溶鋼を連続鋳造する際に、上記の取鍋の供試体の各々を用い、溶鋼の装入、排出を複数回(複数チャージ)繰り返す操業を実施した。そして、実施の終了時に、取鍋の溶鋼装入量がどれだけ減少したかを調べた。実施は、耐火物が溶けて取鍋1が使用不能になるまで行い、耐火物の所定の張替え時期を終了時期とした。   And when continuously casting the molten steel refined in the converter in the steel manufacturing process, each of the above ladle specimens was used to repeat the charging and discharging of the molten steel multiple times (multiple charges). . At the end of the implementation, the amount of molten steel charged in the ladle was examined. Implementation was performed until the refractory melted and the ladle 1 became unusable, and the predetermined re-covering time of the refractory was set as the end time.

図2は、本発明例3および比較例について溶鋼装入量の減少を示すグラフである。図2に示すように、CaOを57mass%含有する本発明例3は、実施開始時の溶鋼装入量を100%とすると、終了時の装入量が開始時の95%であり、減少量は5%とわずかで、ビルドアップの成長が防止され溶鋼ライン部6にスラグがほとんど付着しないことがわかる。なお、評価は、終了時の溶鋼装入量が95%以上のものが◎印、終了時の溶鋼装入量が90%以上のものが○印、終了時の溶鋼装入量が90%未満のものが×印であった。また、図示はしないが、本発明例1、2、4〜10についても調べた結果、表1に示すように、ビルドアップの防止状況は良好であった。一方、比較例は、終了時の溶鋼装入量が80%であり、ビルドアップの成長が大きいことがわかる。   FIG. 2 is a graph showing a decrease in molten steel charging amount for Invention Example 3 and Comparative Example. As shown in FIG. 2, in Example 3 of the present invention containing 57 mass% of CaO, assuming that the molten steel charging amount at the start of the implementation is 100%, the charging amount at the end is 95% at the start, and the reduction amount Is 5%, which indicates that buildup growth is prevented and slag hardly adheres to the molten steel line portion 6. In addition, the evaluation is that the molten steel charge at the end is 95% or more, ◎, the molten steel charge at the end is 90% or more, ○, the molten steel charge at the end is less than 90% Was marked with a cross. Although not shown, as a result of examining Example 1, 2, 4 to 10 of the present invention, as shown in Table 1, the build-up prevention situation was good. On the other hand, in the comparative example, the molten steel charging amount at the end is 80%, and it can be seen that the build-up growth is large.

更に、本発明例および比較例について、耐火物の耐用度を調べた。評価は、実施終了時に耐火物に割れなどの損傷が発生していないものを○印、発生しているものを×印とした。その結果、本発明例1〜10には損傷は発生していなかった。比較例と同等の耐用度を有することがわかる。   Furthermore, the durability of the refractories was examined for the inventive examples and comparative examples. In the evaluation, ◯ marks indicate that no damage such as cracking occurred in the refractory at the end of the implementation, and X marks indicate what occurred. As a result, no damage occurred in Examples 1 to 10 of the present invention. It can be seen that it has the same durability as the comparative example.

以上の結果から、本発明例によれば、比較例よりもビルドアップの成長を大幅に低減でき、溶鋼装入量の減少を防ぐことができ、しかも、比較例と同等の耐用度を備え、歩留まりを大幅に向上できることがわかる。   From the above results, according to the present invention example, it is possible to significantly reduce the build-up growth than the comparative example, prevent a decrease in the molten steel charging amount, and furthermore, have the same durability as the comparative example, It can be seen that the yield can be greatly improved.

この発明の実施の形態に係る連続鋳造に用いる取鍋の断面構造を示す概念図である。It is a conceptual diagram which shows the cross-sectional structure of the ladle used for the continuous casting which concerns on embodiment of this invention. この発明の実施例に係る本発明例および比較例の溶鋼装入量の減少を示すグラフである。It is a graph which shows the reduction | decrease of the molten steel charging amount of the example of this invention based on the Example of this invention, and a comparative example.

符号の説明Explanation of symbols

1 取鍋
2 溶鋼
3 スラグ
4 敷き
5 スラグライン部
6 溶鋼ライン部
1 Ladle 2 Molten Steel 3 Slag 4 Laying 5 Slag Line 6 Molten Steel Line

Claims (8)

内面が耐火物によって内張りされた溶鋼容器であって、少なくとも前記溶鋼容器内に装入された溶鋼が滞留する溶鋼ライン部に内張りされた前記耐火物がドロマイトからなることを特徴とする溶鋼容器。   A molten steel container having an inner surface lined with a refractory, wherein the refractory lined at least in a molten steel line portion in which the molten steel charged in the molten steel container stays is made of dolomite. 前記耐火物が、更に、質量%で、2〜5%のCを含有する請求項1記載の溶鋼容器。   The molten steel container according to claim 1, wherein the refractory further contains 2 to 5% C by mass. 内面が耐火物によって内張りされ、前記耐火物は、質量%で、CaO:50〜90%、MgO:10〜40%および不可避不純物を含有し、且つ、含有物の合計が100%であることを特徴とする溶鋼容器。   The inner surface is lined with a refractory, and the refractory contains, by mass%, CaO: 50 to 90%, MgO: 10 to 40% and inevitable impurities, and the total content is 100%. Features a molten steel container. 内面が耐火物によって内張りされ、前記耐火物は、質量%で、CaO:50〜90%、MgO:10〜40%、C:2〜5%および不可避不純物を含有し、且つ、含有物の合計が100%であることを特徴とする溶鋼容器。   The inner surface is lined with a refractory, and the refractory contains, by mass%, CaO: 50 to 90%, MgO: 10 to 40%, C: 2 to 5% and inevitable impurities, and the total of the contents Is a molten steel container characterized by 100%. 内面が耐火物によって内張りされた溶鋼容器であって、少なくとも前記溶鋼容器内に装入された溶鋼が滞留する溶鋼ライン部が、請求項3または4に記載の耐火物からなることを特徴とする溶鋼容器。   It is a molten steel container whose inner surface is lined with a refractory, and at least a molten steel line portion in which the molten steel charged in the molten steel container is made of the refractory according to claim 3 or 4. Molten steel container. 転炉において製錬した溶鋼を取鍋に移し、次いで、前記溶鋼を連続鋳造する鋼の製造方法において、前記取鍋として請求項1から5のうちの何れか1に記載の溶鋼容器を用いることを特徴とする鋼の製造方法。   In the steel manufacturing method of transferring molten steel smelted in a converter to a ladle and then continuously casting the molten steel, the molten steel container according to any one of claims 1 to 5 is used as the ladle. A method for producing steel characterized by the following. 内面が耐火物によって内張りされた溶鋼容器の前記耐火物であって、質量%で、CaO:50〜90%、MgO:10〜40%および不可避不純物を含有し、且つ、含有物の合計が100%であることを特徴とする溶鋼容器の内張り耐火物。   The refractory of the molten steel container whose inner surface is lined with a refractory, and containing, by mass%, CaO: 50 to 90%, MgO: 10 to 40% and inevitable impurities, and the total of the inclusions is 100 % Lining refractories for molten steel containers. 内面が耐火物によって内張りされた溶鋼容器の前記耐火物であって、質量%で、CaO:50〜90%、MgO:10〜40%、C:2〜5%および不可避不純物を含有し、且つ、前記含有物の合計が100%であることを特徴とする溶鋼容器の内張り耐火物。   The inner surface of the molten steel container lined with a refractory, the refractory of a molten steel container, containing by mass%, CaO: 50-90%, MgO: 10-40%, C: 2-5% and inevitable impurities, and The lining refractory of a molten steel container, wherein the total content is 100%.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20230131247A (en) 2021-04-07 2023-09-12 제이에프이 스틸 가부시키가이샤 castable refractory

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20230131247A (en) 2021-04-07 2023-09-12 제이에프이 스틸 가부시키가이샤 castable refractory

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