JP2005255823A - Detergent composition for food and washing method for foods - Google Patents

Detergent composition for food and washing method for foods Download PDF

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JP2005255823A
JP2005255823A JP2004068660A JP2004068660A JP2005255823A JP 2005255823 A JP2005255823 A JP 2005255823A JP 2004068660 A JP2004068660 A JP 2004068660A JP 2004068660 A JP2004068660 A JP 2004068660A JP 2005255823 A JP2005255823 A JP 2005255823A
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Taizo Ayukawa
泰三 鮎川
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Abstract

<P>PROBLEM TO BE SOLVED: To obtain a detergent composition for food which shows a high washing performance and can provide food without rinsing when used for washing various foods such as fruits, vegetables, and seafood; and to provide a washing method for foods. <P>SOLUTION: The detergent composition comprises 9-10 wt.% sucrose fatty acid ester, 0.2-0.5 wt.% sodium malate, 3-5 wt.% starch syrup, 3-5 wt.% sodium bicarbonate, and water. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、果物や野菜、或いは魚介類等の各種食品類の洗浄に際し、洗浄性能が高く、且つ濯ぎをしなくても食用に供することができる食品用洗浄剤組成物及び食品類の洗浄方法に関する。   The present invention relates to a cleaning composition for foods and a cleaning method for foods, which have high cleaning performance and can be used for food without rinsing when cleaning various foods such as fruits, vegetables, and seafood. About.

ドイツ、日本、カナダ等世界中にビール工場は存在するが、その原材料である大麦の入荷に際し、十分且つ簡易な洗浄が求められている。
そもそも果物や野菜、或いは魚介類等の各種食品類の表面には、土、砂、木片等の固形物、ワックス等の油や農薬等が付着していたり、虫や微生物等に汚染されていることが多く、これらを洗浄して除去するために、例えばドデシルベンゼンスルホン酸ナトリウム(DSS)等のアニオン性界面活性剤を添加した洗浄液(水槽)中に浸漬して洗浄する方法が採用されてきた。
尤も、前記DDS等は洗浄性能が優れているものの、濯ぎが不十分だと、表面に付着している汚損分(物)を除去するどころか、DDS等が食品類の表面に付着してむしろ衛生面で問題となる可能性が強くなるため、十分な濯ぎを必要とするものであった。
There are beer factories all over the world such as Germany, Japan, Canada, etc., but sufficient and simple cleaning is required when the barley, the raw material, is received.
In the first place, the surface of various foods such as fruits, vegetables, and seafood is soiled with solids such as soil, sand, and wood, oil such as wax, and agricultural chemicals, and is contaminated with insects and microorganisms. In many cases, in order to remove these by washing, a method of washing by immersing in a washing liquid (water tank) to which an anionic surfactant such as sodium dodecylbenzenesulfonate (DSS) is added has been adopted. .
However, although the DDS etc. have excellent cleaning performance, if the rinsing is insufficient, the DDS etc. will adhere to the surface of foods rather than removing the dirt (things) adhering to the surface. Since the possibility of becoming a problem in terms of the surface becomes strong, sufficient rinsing is required.

これに対し、例えば高HLB値のショ糖脂肪酸エステル等は、食品添加物、食品用乳化剤として認可されているので、仮に濯ぎが十分でなくて食品類の表面に残存することになっても衛生面で問題となる可能性も低く、安全性が高い。そのため、ショ糖脂肪酸エステル等を主成分とする洗浄剤組成物が提案されている(例えば特許文献1等)。
特開昭50−39707号公報
On the other hand, for example, sucrose fatty acid esters having high HLB values are approved as food additives and food emulsifiers, so even if they are not sufficiently rinsed and remain on the surface of foods, hygiene It is less likely to cause problems and is highly safe. Therefore, a detergent composition mainly composed of sucrose fatty acid ester or the like has been proposed (for example, Patent Document 1).
JP 50-39707 A

しかしながら、前記特許文献1等の洗浄剤では、洗浄性能が十分でないため、洗浄液中に食品類を長時間浸漬しても、本来の目的である洗浄が満足に果たされないという致命的な問題があった。
そのため、本発明は、洗浄性能が十分に高く、濯ぎが十分でなくても、或いは濯ぎを行わなくても食用に供することができる食品用洗浄剤組成物を提案することを目的とする。
However, since the cleaning agent of Patent Document 1 and the like does not have sufficient cleaning performance, there is a fatal problem that even if foods are immersed in the cleaning liquid for a long time, the original cleaning cannot be performed satisfactorily. there were.
Therefore, an object of the present invention is to propose a food cleaning composition that has a sufficiently high cleaning performance and can be used for foods even if rinsing is not sufficient or rinsing is not performed.

本発明は上記に鑑み提案されたもので、ショ糖脂肪酸エステル8〜10重量%と、リンゴ酸ナトリウム0.2〜0.5重量%と、水飴3〜5重量%と、重曹3〜5重量%と、水とからなることを特徴とする食品用洗浄剤組成物に関するものである。   The present invention has been proposed in view of the above, sucrose fatty acid ester 8 to 10% by weight, sodium malate 0.2 to 0.5% by weight, starch syrup 3 to 5% by weight, and baking soda 3 to 5% by weight. % And water, it is related with the cleaning composition for foodstuffs characterized by the above-mentioned.

上記食品用洗浄剤組成物において、香料0〜2重量%と、エタノール5〜10重量%とを添加することが望ましい。   In the food cleaning composition, it is desirable to add 0 to 2% by weight of a fragrance and 5 to 10% by weight of ethanol.

また、本発明は、食品類の表面を、前記食品洗浄用組成物に接触させてそのまま食用に供することを特徴とする食品類の洗浄方法をも提案するものである。   The present invention also proposes a method for cleaning foods characterized in that the surface of the foods is brought into contact with the food cleaning composition and used as it is for food.

本発明の食品用洗浄剤組成物は、果物や野菜、或いは魚介類等の各種食品類の洗浄に際し、洗浄性能が高く、且つ濯ぎをしなくても食用に供することができる。
そのため、例えばビール工場において原材料として入荷した大麦の洗浄に用いることができ、大型の水槽中に本発明の食品用洗浄剤組成物を収容し、大容量の大麦をその中に投入して浸漬することにより、十分且つ簡易に洗浄することができる。そして、濯ぎ等を行うことなくその後の工程に供することができる。
さらに、大麦や大豆等の小径の食品類の洗浄に際し、その後の濯ぎを必要としないと言うことは、濯ぎに用いられる膨大な水の使用を必要としないことを意味しており、設備費用の削減も含めて大きな利点となる。
また、各種食品類の出荷直前の洗浄に用いることにより、食品類の鮮度の低下を抑制することができ、食品等が発する特有の臭いを抑制し、或いは搬送中の傷み等も抑制することができる。
The cleaning composition for food of the present invention has high cleaning performance when washing various foods such as fruits, vegetables, and seafood, and can be used for food without rinsing.
Therefore, for example, it can be used for washing barley stocked as a raw material in a beer factory, and the food detergent composition of the present invention is accommodated in a large aquarium, and a large volume of barley is placed therein and immersed therein. Therefore, it can be cleaned sufficiently and easily. And it can use for a subsequent process, without performing rinse etc.
Furthermore, when washing small-sized foods such as barley and soybeans, the fact that no subsequent rinsing is required means that the use of enormous amounts of water used for rinsing is not necessary. This is a big advantage including reduction.
In addition, it can be used for cleaning just before shipment of various foods, so that the freshness of the foods can be prevented from being reduced, the unique odor emitted by the foods can be suppressed, or the damage during transportation can be suppressed. it can.

また、香料やエタノールを添加することにより、前記効果に加え、臭い消しの効果及び保存性の向上を図ることができる。   Moreover, by adding a fragrance | flavor and ethanol, in addition to the said effect, the effect of odor extinction and the improvement of a preservability can be aimed at.

さらに、本発明の食品類の洗浄方法は、特に小径の食品類の洗浄に好適であり、例えば水槽中に本発明の食品用洗浄剤組成物の水溶液を収容し、その中に各種食品類を投入するようにしてもよいし、或いは洗浄水をコンベア上を搬送される食品類にシャワーのように降り注がせ、洗浄水は繰り返し循環利用するようにしてもよいし、何れの方式でもその後の濯ぎ等の処理を必要としないため、特に大豆や大麦等の小径の食品類の洗浄に好適に用いることができる。   Furthermore, the method for cleaning foods of the present invention is particularly suitable for cleaning small diameter foods. For example, an aqueous solution of the food cleaning composition of the present invention is contained in a water tank, and various foods are contained therein. The washing water may be poured into the foods conveyed on the conveyor like a shower, and the washing water may be repeatedly circulated. Therefore, it can be suitably used for washing small-diameter foods such as soybeans and barley.

ショ糖脂肪酸エステル8〜10重量%と、リンゴ酸ナトリウム0.2〜0.5重量%と、水飴3〜5重量%と、重曹3〜5重量%と、香料0〜2重量%と、エタノール5〜10重量%と、水とからなる組成の洗浄剤組成物によって食品類を洗浄する。   Sucrose fatty acid ester 8-10 wt%, sodium malate 0.2-0.5 wt%, starch syrup 3-5 wt%, baking soda 3-5 wt%, flavor 0-2 wt%, ethanol Foods are washed with a detergent composition having a composition of 5 to 10% by weight and water.

本発明における食品とは、そのまま食用に供される例えば果物や野菜類等は勿論、煮る、蒸す、焼く等の加工を施した後に食用に供される例えば穀類、魚介類等も含み、更には殻や皮の表皮等を付けた状態の例えば貝類やトウモロコシ等も含むものである。例えばトウモロコシでは、皮を付けた状態で畑から収穫されるが、そのまま出荷されて市場に供される場合もある。皮を剥いだ状態で出荷され、その状態で市場に供する場合もあるし、焼く、蒸す等の加工を加えて市場に供する場合もある。蒸してさらに実を分離させ、その状態で市場に供する場合もあるし、冷凍加工されて冷凍食品用として市場に供する場合もある。本発明における食品とは、これらの全ての状態を含むものである。   The food in the present invention includes, for example, fruits and vegetables as they are used for food as they are, but also includes foods such as cereals and seafood that are used for food after processing such as boiling, steaming, baking, etc. For example, shellfish, corn and the like with shells and skins are also included. For example, corn is harvested from the field in a peeled state, but it may be shipped as it is to the market. Shipped in a peeled state, the product may be supplied to the market in that state, or may be supplied to the market after processing such as baking and steaming. In some cases, the fruit is further separated by steaming, and the fruit is then provided to the market, or it may be frozen and used for frozen food. The food in the present invention includes all these states.

本発明の食品用洗浄剤組成物に含まれるショ糖脂肪酸エステルは、HLBが7以上の親水性の高い起泡力にすぐれた食品添加剤、食品用乳化剤である。より具体的には、脂肪酸は飽和脂肪酸でもよいし、不飽和脂肪酸でもよく、脂肪酸のエステル化度はモノエステルを主として、ジエステル、トリエステルが混在するものが望ましい。例えばショ糖モノオレイン酸エステル、ショ糖モノラウリン酸エステル、ショ糖モノステアリン酸エステル、ショ糖モノミリスチン酸エステル、ショ糖モノパルミチン酸エステル、ショ糖モノリノール酸エステルなどを使用することができる。
このショ糖脂肪酸エステルの含有量は、8〜10重量%であるが、8重量%に満たないと十分な洗浄性能が得られず、10重量%を超えると他の成分の割合が少なくなるため、所定の効果が得られない。
The sucrose fatty acid ester contained in the food detergent composition of the present invention is a food additive and a food emulsifier having an HLB of 7 or more and excellent in hydrophilic foaming power. More specifically, the fatty acid may be a saturated fatty acid or an unsaturated fatty acid, and the esterification degree of the fatty acid is preferably a monoester mainly containing a diester and a triester. For example, sucrose monooleate, sucrose monolaurate, sucrose monostearate, sucrose monomyristate, sucrose monopalmitate, sucrose monolinoleate, etc. can be used.
The content of the sucrose fatty acid ester is 8 to 10% by weight, but sufficient cleaning performance cannot be obtained unless the content is less than 8% by weight, and the proportion of other components decreases if it exceeds 10% by weight. The predetermined effect cannot be obtained.

本発明の食品用洗浄剤組成物に含まれるリンゴ酸ナトリウムは、ヒドロキシカルボン酸塩に属するものであって、前記ショ糖脂肪酸エステルと同様に食品添加剤であって、本発明の食品用洗浄剤組成物においては洗浄性能を向上するビルダー(助剤)としての効果を果たす他、食品類の味覚向上にも寄与する。
このリンゴ酸ナトリウムの含有量は、0.2〜0.5重量%であるが、0.2重量%に満たないと十分な洗浄性能の向上が図れず、味覚向上効果も得られない。0.5重量%を超えると結晶が析出してしまう。
Sodium malate contained in the food detergent composition of the present invention belongs to the hydroxycarboxylate, and is a food additive similar to the sucrose fatty acid ester, and the food detergent of the present invention. In addition to serving as a builder (auxiliary) that improves cleaning performance, the composition also contributes to improving the taste of foods.
The content of this sodium malate is 0.2 to 0.5% by weight. However, if the content is less than 0.2% by weight, sufficient cleaning performance cannot be improved and the taste enhancing effect cannot be obtained. If it exceeds 0.5% by weight, crystals will precipitate.

本発明の食品用洗浄剤組成物に含まれる水飴は、糖類に属するものであって、酸糖化水飴、酵素糖化水飴があるが、食品であって、本発明の食品用洗浄剤組成物においては高粘度であるため他の成分を食品類に貼着する効果を果たし、保湿性を付与する効果もある。
この水飴の含有量は、3〜5重量%であるが、3重量%に満たないと上述の効果を得られず、5重量%を超えると他の成分の割合が少なくなるため、所定の効果が得られない。
The varicella contained in the food cleaning composition of the present invention belongs to saccharides, and there are acid saccharified varieties and enzyme saccharified varicella, but it is a food and in the food cleaning composition of the present invention. Because of its high viscosity, it has the effect of sticking other ingredients to foods and has the effect of imparting moisture retention.
The content of this starch syrup is 3 to 5% by weight. However, if the content is less than 3% by weight, the above-mentioned effect cannot be obtained. Cannot be obtained.

本発明の食品用洗浄剤組成物に含まれる重曹は、炭酸水素ナトリウム、或いは炭酸水素ナトリウムを主成分とする製品であって、前記各成分と同様に食品添加剤(ベーキングパウダー等)であって、本発明の食品用洗浄剤組成物においては鮮度保持効果を果たし、洗浄剤組成物(水溶液)をpH8〜9程度の弱アルカリに保持する作用もある。さらに、洗浄向上、臭い除去にも寄与する。
この重曹の含有量は、3〜5重量%であるが、3重量%に満たないと上述の効果を得られず、5重量%を超えると他の成分の割合が少なくなるため、所定の効果が得られない。
The baking soda contained in the food cleaning composition of the present invention is a product containing sodium bicarbonate or sodium bicarbonate as a main component, and is a food additive (baking powder or the like) in the same manner as the above components. In addition, the food detergent composition of the present invention has a freshness-keeping effect and also has an action of keeping the detergent composition (aqueous solution) in a weak alkali having a pH of about 8-9. It also contributes to improved cleaning and odor removal.
The content of this baking soda is 3 to 5% by weight, but the above effect cannot be obtained unless the content is less than 3% by weight. Cannot be obtained.

また、本発明の食品用洗浄剤組成物中には、香料0〜2重量%を添加してもよい。
香料は、前記各成分と同様に食品添加用として認可されているものを用い、特にその種類を限定するものではなく、本発明の食品用洗浄剤組成物においては食品類の臭い消しの効果を果たす。
この香料は、2重量%を超えると香料自体が有する芳香が食品に付与されてしまう。
Moreover, you may add 0-2 weight% of fragrance | flavor in the cleaning composition for foodstuffs of this invention.
The fragrance is used for food addition as in the case of the above-mentioned components, and is not particularly limited in its kind. In the food cleaning composition of the present invention, the effect of deodorizing foods is obtained. Fulfill.
If this fragrance exceeds 2% by weight, the fragrance of the fragrance itself is imparted to the food.

また、本発明の食品用洗浄剤組成物中には、エタノール5〜10重量%を添加してもよい。
エタノールは、酒類の主成分であるから食品であって、本発明の食品用洗浄剤組成物においては保存剤の効果を果たし、さらには前記各成分の溶解性を向上する(ハイドロトロープ剤としての)効果、殺菌効果も果たすものである。
このエタノールは、5重量%に満たないと上述の効果を得られず、10重量%を超えると抽出性を有するため、食品類から一部の成分が溶け出す虞がある。
Moreover, you may add 5-10 weight% of ethanol in the cleaning composition for foodstuffs of this invention.
Ethanol is a food because it is the main component of alcoholic beverages, and serves as a preservative in the food detergent composition of the present invention, and further improves the solubility of each component (as a hydrotrope agent). ) The effect and the bactericidal effect are also achieved.
If this ethanol is less than 5% by weight, the above-mentioned effects cannot be obtained, and if it exceeds 10% by weight, it has extractability, so that some components may be dissolved from foods.

上記の各成分から構成される本発明の食品用洗浄剤組成物は、各成分の固有の効果、並びに相乗効果によって、各種食品類の洗浄に際し、極めて高い洗浄性能を示す。また、構成成分は何れも食品添加物又は食品であるから、食品類に残存しても毒性を考慮する虞もない。そのため、例えば水槽中に本発明の食品用洗浄剤組成物(水溶液)を収容し、その中に各種食品類を投入してすぐに取り出すようにしてもよいし、或いは洗浄水をコンベア上を搬送される食品類にシャワーのように降り注いて洗浄してもよい。そして、食品類がどのような形態であっても濯ぎをしなくても食用に供することができる。尚、条規千条方式に使用する洗浄剤組成物は、適宜に濃度管理を行って、構成成分の割合が前記の所定範囲となるように適宜に成分調整しながら継続的に、或いは繰り返し循環させて利用するようにしてもよい。   The cleaning composition for foods of the present invention composed of each of the above components exhibits extremely high cleaning performance when cleaning various foods due to the unique effect and synergistic effect of each component. In addition, since all of the constituent components are food additives or foods, there is no possibility of considering toxicity even if they remain in foods. Therefore, for example, the food detergent composition (aqueous solution) of the present invention may be accommodated in a water tank, and various foods may be put in and taken out immediately, or the cleaning water is conveyed on a conveyor. It may be washed by pouring onto the foods to be washed. And even if it is what kind of foodstuffs is not rinsed, it can use for food. In addition, the detergent composition used in the Thousand-Thousand-Six Method is circulated continuously or repeatedly while appropriately controlling the concentration and adjusting the components appropriately so that the proportion of the constituent components is within the predetermined range. May be used.

〔配合例1,2及び比較例1,2〕
表1に示す組成の洗浄剤組成物を調製した。
また、比較のために、重曹を配合しないものを比較例とし、配合例1中の重曹を配合していない例を比較例1とし、配合例2中の重曹を配合していない例を比較例2とした。

Figure 2005255823
[Formulation Examples 1 and 2 and Comparative Examples 1 and 2]
A cleaning composition having the composition shown in Table 1 was prepared.
In addition, for comparison, an example in which sodium bicarbonate is not blended is used as a comparative example, an example in which sodium bicarbonate in Formulation Example 1 is not blended is used as Comparative Example 1, and an example in which sodium bicarbonate in Formulation Example 2 is not blended. 2.
Figure 2005255823

〔洗浄試験(その1)〕
収穫したままの状態の大麦及び大豆を試験食品類とし、それぞれ1kg中の菌数を測定した。その後、前記配合例1,2及び比較例1,2の各1tの洗浄剤組成物を水槽中に収容した中に投入し、30秒程度浸漬し、引き上げ、濯ぎを行わなかった。但し、菌数を測定するため風乾した。{(未洗浄の際の菌数)−(洗浄処理後の菌数)}/(未洗浄の際の菌数)を洗浄性能として算出した。結果は表2に示した。

Figure 2005255823
[Cleaning test (1)]
Harvested barley and soybeans were used as test foods, and the number of bacteria in 1 kg was measured. Thereafter, the cleaning compositions of 1 t of each of Formulation Examples 1 and 2 and Comparative Examples 1 and 2 were placed in a water tank, immersed for about 30 seconds, pulled up, and not rinsed. However, it was air-dried to measure the number of bacteria. {(The number of bacteria when not washed) − (the number of bacteria after washing)} / (the number of bacteria when not washed) was calculated as the washing performance. The results are shown in Table 2.
Figure 2005255823

〔洗浄試験(その2)〕
カゼインカルシウム0.3gとヒ酸鉛0.8gとを水1L中に溶解して汚損水溶液とし、該汚損水溶液中にキャベツ、リンゴを浸漬し、取り出し、乾燥する工程を繰り返し、2日放置し、キャベツ表面、リンゴ表面に汚損成分を付着させたものを試験食品類とした。その後、前記配合例1,2及び比較例1,2の各1tの洗浄剤組成物を水槽中に収容した中に投入し、30秒程度浸漬し、引き上げ、濯ぎを行わなかった。但し、農薬(ヒ素)付着量を原子吸光分光分析法にて測定するため風乾した。{(未洗浄の際の農薬付着量)−(洗浄処理後の付着量)}/(未洗浄の際の農薬付着量)を洗浄性能として算出した。結果は表3に示した。

Figure 2005255823
[Cleaning test (2)]
Dissolve 0.3 g of calcium caseinate and 0.8 g of lead arsenate in 1 liter of water to give a fouling aqueous solution, soak cabbage and apples in the fouling aqueous solution, take them out, and repeat the drying process. Test foods were prepared by attaching fouling components to the cabbage surface and apple surface. Thereafter, the cleaning compositions of 1 ton of each of Formulation Examples 1 and 2 and Comparative Examples 1 and 2 were put in a water tank, immersed for about 30 seconds, pulled up, and not rinsed. However, it was air-dried in order to measure the amount of attached pesticide (arsenic) by atomic absorption spectrometry. {(Agrochemical adhesion amount when not washed) − (Amount of adhesion after washing treatment)} / (Agricultural chemical adhesion amount when unwashed) was calculated as the cleaning performance. The results are shown in Table 3.
Figure 2005255823

果物や野菜、或いは魚介類等の各種食品類の洗浄に利用できる。   It can be used for washing various foods such as fruits, vegetables, and seafood.

Claims (3)

ショ糖脂肪酸エステル8〜10重量%と、リンゴ酸ナトリウム0.2〜0.5重量%と、水飴3〜5重量%と、重曹3〜5重量%と、水とからなることを特徴とする食品用洗浄剤組成物。   It consists of sucrose fatty acid ester 8 to 10% by weight, sodium malate 0.2 to 0.5% by weight, starch syrup 3 to 5% by weight, sodium bicarbonate 3 to 5% by weight and water. A cleaning composition for food. 香料0〜2重量%と、エタノール5〜10重量%とを添加してなることを特徴とする請求項1に記載の食品洗浄用組成物。   The composition for food cleaning according to claim 1, wherein 0 to 2% by weight of a fragrance and 5 to 10% by weight of ethanol are added. 食品類の表面を、請求項1又は2に記載の食品洗浄用組成物に接触させてそのまま食用に供することを特徴とする食品類の洗浄方法。   A method for cleaning foods, wherein the surface of the foods is brought into contact with the food cleaning composition according to claim 1 or 2 and used as it is for food.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106047531A (en) * 2016-06-03 2016-10-26 芜湖县富园食品有限公司 Material composition of vegetable and fruit cleaning agent, vegetable and fruit cleaning agent as well as preparation method and application of vegetable and fruit cleaning agent
CN115058295A (en) * 2022-07-21 2022-09-16 殷桂钊 Edible cleaning agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106047531A (en) * 2016-06-03 2016-10-26 芜湖县富园食品有限公司 Material composition of vegetable and fruit cleaning agent, vegetable and fruit cleaning agent as well as preparation method and application of vegetable and fruit cleaning agent
CN115058295A (en) * 2022-07-21 2022-09-16 殷桂钊 Edible cleaning agent

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