JP2005234135A5 - - Google Patents

Download PDF

Info

Publication number
JP2005234135A5
JP2005234135A5 JP2004041930A JP2004041930A JP2005234135A5 JP 2005234135 A5 JP2005234135 A5 JP 2005234135A5 JP 2004041930 A JP2004041930 A JP 2004041930A JP 2004041930 A JP2004041930 A JP 2004041930A JP 2005234135 A5 JP2005234135 A5 JP 2005234135A5
Authority
JP
Japan
Prior art keywords
optical fiber
plastic optical
clad
unit
meth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2004041930A
Other languages
Japanese (ja)
Other versions
JP2005234135A (en
Filing date
Publication date
Application filed filed Critical
Priority to JP2004041930A priority Critical patent/JP2005234135A/en
Priority claimed from JP2004041930A external-priority patent/JP2005234135A/en
Publication of JP2005234135A publication Critical patent/JP2005234135A/en
Publication of JP2005234135A5 publication Critical patent/JP2005234135A5/ja
Pending legal-status Critical Current

Links

Claims (4)

コアと、該コアの外周に第1クラッド、第2クラッドの順に積層された2層構造のクラッドを有し、
前記コアが、ポリメタクリル酸メチル、又は1種類以上のビニル系単量体単位とメタクリル酸メチル単位との共重合体からなり、
前記第1クラッドが、下記一般式(I)

<化1>
CH2=CX−COO(CH2m−R (I)
(式中、Xは水素原子、フッ素原子、またはメチル基、R は炭素数1〜12の(フルオロ)アルキル基、mは1又は2の整数を示す。)

で表されるフルオロアルキル(メタ)クリレートの単位(A)15〜90質量%と、他の共重合可能な単量体単位(B)10〜85質量%からなり、示差走査熱量測定(DSC)におけるガラス転移温度が90℃以上であって、アッベ屈折率計で測定した25℃での屈折率が1.39〜1.475の範囲にある共重合体からなり、
前記第2クラッドが、少なくともテトラフルオロエチレン単位を含み、示差走査熱量測定(DSC)における結晶融解熱が40mJ/mg以下である含フッ素オレフィン系樹脂からなることを特徴としたプラスチック光ファイバ素線。
A core and a clad having a two-layer structure in which the first clad and the second clad are laminated in this order on the outer periphery of the core;
The core is made of polymethyl methacrylate or a copolymer of one or more vinyl monomer units and methyl methacrylate units,
The first cladding has the following general formula (I)

<Chemical formula 1>
CH 2 = CX-COO (CH 2) m -R 1 f (I)
(In the formula, X represents a hydrogen atom, a fluorine atom, or a methyl group, R 1 f represents a (fluoro) alkyl group having 1 to 12 carbon atoms, and m represents an integer of 1 or 2.)

In the unit (A) 15 to 90 wt% of the fluoroalkyl (meth) acrylate represented, made from the other copolymerizable monomer unit (B) 10 to 85 wt%, differential scanning calorimetry (DSC ) And a glass transition temperature of 90 ° C. or higher, and having a refractive index at 25 ° C. measured by an Abbe refractometer in the range of 1.39 to 1.475,
The plastic optical fiber, wherein the second clad is made of a fluorine-containing olefin resin containing at least a tetrafluoroethylene unit and having a crystal melting heat of 40 mJ / mg or less in differential scanning calorimetry (DSC).
前記フルオロアルキル(メタ)アクリレートの単位(A)が、(メタ)アクリル酸ヘキサフルオロネオペンチルであることを特徴とした請求項1記載のプラスチック光ファイバ素線。The plastic optical fiber strand according to claim 1, wherein the unit (A) of the fluoroalkyl (meth) acrylate is hexafluoroneopentyl (meth) acrylate. 請求項1または2に記載のプラスチック光ファイバ素線の外周に、ポリアミド系樹脂組成物からなる被覆層を被覆してなるプラスチック光ファイバケーブル。 A plastic optical fiber cable obtained by coating the outer periphery of the plastic optical fiber according to claim 1 or 2 with a coating layer made of a polyamide-based resin composition. 請求項記載のプラスチック光ファイバケーブルの末端にコネクター端子を設けたコネクター端子付プラスチック光ファイバケーブル。 The plastic optical fiber cable with a connector terminal which provided the connector terminal at the terminal of the plastic optical fiber cable of Claim 3 .
JP2004041930A 2004-02-18 2004-02-18 Plastic optical fiber and plastic optical fiber cable Pending JP2005234135A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2004041930A JP2005234135A (en) 2004-02-18 2004-02-18 Plastic optical fiber and plastic optical fiber cable

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004041930A JP2005234135A (en) 2004-02-18 2004-02-18 Plastic optical fiber and plastic optical fiber cable

Publications (2)

Publication Number Publication Date
JP2005234135A JP2005234135A (en) 2005-09-02
JP2005234135A5 true JP2005234135A5 (en) 2007-04-05

Family

ID=35017170

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004041930A Pending JP2005234135A (en) 2004-02-18 2004-02-18 Plastic optical fiber and plastic optical fiber cable

Country Status (1)

Country Link
JP (1) JP2005234135A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007101924A (en) * 2005-10-05 2007-04-19 Fujikura Ltd Plastic optical fiber ribbon, plastic optical fiber, and cord, cable and sheet using same
US8023789B2 (en) 2006-09-28 2011-09-20 Mitsubishi Rayon Co., Ltd. Plastic optical fiber cable and method of signal transmission using the same
JP6446822B2 (en) * 2014-04-24 2019-01-09 三菱ケミカル株式会社 Optical fiber manufacturing method, optical fiber, communication device, and illumination

Similar Documents

Publication Publication Date Title
JPS59227908A (en) Fluorine-containing polymer and its use
JPWO2006121048A1 (en) Plastic optical fiber cable
JP2821935B2 (en) Plastic optical fiber
JP2010237414A (en) Plastic optical fiber
JP2005234135A5 (en)
JP3991730B2 (en) Polymerizable compound and polymer thereof
JP2004163927A5 (en)
JPH0223843B2 (en)
JP5304704B2 (en) Plastic optical fiber cord
JP2003139972A5 (en)
JPH10274716A (en) Plastic optical fiber high in numerical aperture
JP4245513B2 (en) Plastic optical fiber cable and plastic optical fiber cable with plug
JP2003139973A5 (en)
JP2005164714A5 (en)
JP2011008240A5 (en)
JP2002148451A (en) Plastic optical fiber
JP4052309B2 (en) Fluorine-containing optical material and fluorine-containing copolymer
JP2696521B2 (en) Polymer for optical fiber sheath material
JP2005070213A5 (en)
JPH0451206A (en) Plastic optical fiber
JP2005266742A (en) Plastic optical fiber cable and its manufacturing method
JPH06256433A (en) Transparent resin composition
JP2004151702A5 (en)
JP4245521B2 (en) Sheath material for plastic optical fiber
JP2009175683A (en) Plastic optical fiber and plastic optical fiber cord