JP2005232588A - Method for manufacturing thermally sprayed metal plated steel tube - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for manufacturing a thermally sprayed metal plated steel tube provided with a metallic layer nearly uniform and good over the entire surface. <P>SOLUTION: The method for manufacturing the metallic tube which forms the metallic tube by continuously forming a metallic sheet consisting of a first composition component to a tubular form and continuously welding butted ends comprises forming a metallic layer consisting of a second composition component having no discontinuity in a circumference direction and a longitudinal direction directly on the surface of the metallic tube after continuous welding. More particularly, the method includes a working step for making the thickness distribution of the metallic layer uniform as far as possible after the formation of the thermally sprayed metallic layer on the outside surface. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  The present invention relates to a method for manufacturing a metal-plated steel pipe having a thermal spraying process on the inner surface or outer surface of the steel pipe.

  As a method for producing a metal-plated steel pipe, a double-sided plated steel sheet in which different types of metals (typically zinc) are plated on both the front and back surfaces of the steel sheet is continuously formed into a tubular shape using roll forming, and the tubular structure is formed into a tubular shape. A process of forming a pipe by continuously welding the plated steel plate end surfaces, a process of continuously cutting the weld bead formed on the outer surface of the steel pipe at this time, and a part of the plating layer accompanying this cutting It has been known for a long time that a thermal spraying process is applied to a portion which has been cut and unplated, and the unplated portion is coated with the same or different metal as the metal applied to the plating ( Patent Document 1).

In such a process, instead of applying a thermal spraying process to the final unplated part, it is also considered to replace it by continuous hot-dipping (Japanese Patent Application No. 2002-225668 (not disclosed) by the applicant). )).
JP-A-5-148607

  In such technology, thermal spraying is used exclusively for repair applications. That is, there is an idea that the metal is partially sprayed on the metal tube for the non-plated portion in order to shield the non-plated portion from the external atmosphere. There is no idea of using thermal spraying to modify the entire plating layer and forming a metal layer not only on a specific site but also on the entire tube.

  On the other hand, for the purpose of modifying the entire plating layer rather than repairing, there is known a process in which the steel pipe manufactured by the above manufacturing process is again subjected to hot dip plating with the same or different metal. For example, it is known that by adding aluminum to zinc plating, it is possible to realize corrosion resistance that cannot be obtained with zinc alone. The environment in which products are used is becoming severer year by year, and new alloy plating is required because of high corrosion resistance and long service life. Such required properties include not only corrosion resistance but also wear resistance, heat resistance, electrical insulation, electromagnetic shielding, and electrical conductivity, but all of them are coated with other metals and non-metallic materials in a composite manner. This is feasible.

  Conventionally, as a process of coating a plurality of different metals, a zinc double-sided plated steel sheet is formed by roll forming, etc., and after continuous welding, bead portion removal, etc., zinc or a metal different from this (for example, aluminum) is hot-plated. Things have been done. However, newly installing a hot dipping bath in an existing line is difficult in terms of process design and arrangement, and the amount of capital investment is not small.

  In the case of a metal-plated steel pipe obtained by a manufacturing method by continuous spraying, there are the following problems. In other words, since the bonding strength of the sprayed metal layer at the steel pipe interface is weaker than that of the hot-dip plated layer, when the bending process is performed, the sprayed metal layer may peel off or crack, which may cause corrosion resistance problems of the steel pipe. is there. Further, it is difficult to control the fine thickness of the sprayed metal layer, and it is difficult to form a uniform sprayed metal layer.

  The present invention has been proposed in view of the above problems, and an object of the present invention is to provide a method for producing a spray-coated metal-plated steel pipe having a substantially uniform and good metal layer over the entire surface with high productivity. An object of this invention is to form the metal layer which has sufficient bond strength with the metal layer of a plating layer by a thermal spraying process.

  In order to achieve the above object, the thermal spray metal plating manufacturing method of the present invention includes a step of continuously spraying a steel plate, a step of continuously forming a steel pipe, and a longitudinal end face of the steel plate formed into a tubular shape. The method includes a step of continuously welding the joint portion to form a steel pipe, a step of continuously hot-plating the outer surface of the steel pipe, and a step of thermally spraying the outer surface of the steel pipe.

  The present invention can be expressed more functionally as follows. That is, the present invention relates to a method of manufacturing a metal tube in which a metal plate comprising a first composition component is continuously formed into a tubular shape, and a welded end is continuously welded to form a metal tube. The present invention relates to a method for manufacturing a metal tube, wherein a metal layer made of a second composition component different from the first composition component having no discontinuity in the circumferential direction and the longitudinal direction is formed on at least one surface of the plate by thermal spraying.

  Further, the present invention provides a similar method for producing a metal tube, wherein the second composition is different from the first composition component in which there is no discontinuity in the circumferential direction and the longitudinal direction directly on the surface of the metal tube after continuous welding. The present invention relates to a method for manufacturing a metal tube, in which a metal layer composed of components is formed by thermal spraying.

  Further, the present invention provides a similar method for manufacturing a metal tube, in a circumferential direction and a longitudinal direction on the surface of the metal tube after continuous welding via a metal layer made of a composition component different from the first composition component. The present invention relates to a method for manufacturing a metal tube, in which a metal layer having no discontinuity is formed by thermal spraying.

  In the present invention, the metal layer is formed by thermal spraying preferably on the inner surface before continuous welding and on the tube surface after continuous welding, but these may be used in combination.

According to the manufacturing method of the present invention, a first metal tube portion comprising the first composition component, wherein at least a part of a cross section of the first metal tube portion is a melt-bonded portion continuous in the longitudinal direction. A first metal tube portion having a first metal tube portion and a second metal layer formed on a surface of either of the first metal tube portions directly or via a metal layer made of a composition component different from the first composition component It is possible to manufacture a metal tube including the second metal layer, the second metal layer being continuously formed in the cross-sectional direction by a thermal spraying process.
Furthermore, the present invention provides a sufficient bonding force with the metal layer constituting the plating layer by performing thermal spraying in a state where the surface of the plating layer is not completely cooled, preferably in a semi-molten state. It may be a feature. The semi-molten state refers to a state in the course of solidification at a temperature from the melting point to about 80% of the melting point. For example, when the plating layer is zinc, the temperature range is from the melting point to 400 ° C.
The plating layer applied to the metal tube obtained by the present invention is such that the metal having the second component is scattered in an island shape in the metal having the first component, and the second in the metal having the first component. The metal having the above components is distributed in layers.

  The metal used for thermal spraying and molten metal plating is preferably zinc, but may be other metals such as an alloy containing aluminum and other metals in zinc, tin, or the like.

  In this specification, spraying is based on a general definition based on well-known metalworking. As one such definition, for example, thermal spraying refers to a process in which a thermal spray material is heated using combustion or electrical energy, and particles that have been melted or brought close to it are sprayed onto the substrate to form a coating (JIS Handbook). (See Metal Surface Treatment H8200).

  According to the present invention, since the metal layer is formed on the inner surface or the outer surface of the metal tube by thermal spraying instead of the conventional plating process such as hot dipping, it is not necessary to install and manage the plating layer which requires a large amount of money and is inexpensive. Various metal layers can be formed by capital investment, and the degree of freedom in designing the metal tube can be increased.

  According to the present invention, the metal layer continuous in the cross-sectional direction or the circumferential direction, such as the entire surface of the metal tube, is formed by thermal spraying instead of the local repair of the metal tube by conventional thermal spraying. The use of thermal spraying, which is not local repair, is not common to those skilled in the art.

According to the present invention, by using a thermal spraying apparatus and forming an alloy metal containing aluminum in the aluminum layer and galvanizing, it is possible to obtain a thermally sprayed metal plated steel pipe having excellent corrosion resistance and a high rust prevention effect.
According to the present invention, when the plating layer is composed of a plurality of metals or alloys having a composition, the positional relationship (distribution relationship) between the base metal and the sprayed metal can be controlled.

  The effects of the invention described in this specification and other features of the invention of the present application should not be construed as narrowing the scope of rights of the invention of the present application. Needless to say, those having some of these effects and features, but not all, are also included in the scope of rights of the present invention based on the interpretation of rights established by Japanese laws and practices.

Hereinafter, embodiments of the present invention will be described in detail.
The manufacturing method of the thermal spray metal steel pipe of this embodiment is comprised by the manufacturing line shown in FIG. This production line consists of an uncoiler 2 that continuously supplies a long steel sheet wound around a coil 1, a forming device 5 that continuously forms the steel sheet supplied from the uncoiler 2 into a tubular shape, and a continuous steel sheet. An inner surface spraying device 4 that sprays a desired metal on a steel plate immediately before being formed into a tubular shape, and a welding device 7 that continuously welds the longitudinal end surface joint portion of the plated steel plate formed into a tubular shape to form a tubular body, A cutting device 8 that continuously cuts the weld bead formed on the outer surface of the tubular body, and a hot dip galvanizing device 11 that continuously hot dip galvanizes the outer surface of the tubular body to form a hot dip galvanized steel pipe. Including at least.

In addition, from the above configuration, except for the inner surface spraying device 4 installed immediately before the tubular forming of the steel sheet continuously, instead of the hot dip galvanizing device 11, an outer surface spraying device 12 for spraying after the hot dip galvanizing device is required. Can be provided accordingly.
Further, both the inner surface spraying device 4 and the outer surface spraying device 12 can be provided during the manufacturing process. These depend on the specifications of the steel pipe to be manufactured.

  If necessary, a flux application device 9 for continuously applying a flux liquid for cleaning and preventing the outer surface of the tubular body and a preheating device 10 for drying the outer surface of the tubular body and preheating the tubular body are provided. May be. Further, a sizing device 13 for forming the hot-dip galvanized steel pipe manufactured as described above into a standard size and a cutting device 14 for cutting the hot-dip galvanized steel pipe into a predetermined length may be provided.

  Next, the manufacturing method of the present invention using the above manufacturing line will be described.

First, a steel sheet wound in a coil shape is continuously supplied from the uncoiler 2 toward the downstream of the line.
The supplied steel sheet is drawn into the forming device 5 and sprayed by the spraying device 4 to be cold-formed into a tubular shape. The thermal spraying is preferably performed on one surface of the steel plate, and the sprayed surface is preferably the inner surface of the formed tube. The thermal spraying may be performed before the start of forming or after the start of forming. Subsequently, the welding device 7 continuously welds the longitudinal end surface joining portions of the steel plates to form one continuous tubular body 6.

  Next, the tubular body 6 is sent to a cutting device 8 to which a cutter having a shape along the outer surface of the tubular body 6 is attached. Then, the weld bead portion formed on the outer surface of the tubular body 6 is scraped off by the cutting tool of the cutting device 8, and the outer surface of the tubular body 6 is smoothly formed.

Thereafter, the tubular body is sent to the flux applying device 9, and a flux liquid for cleaning and antioxidant is applied to the outer surface of the tubular body.
The tubular body 6 is sent to the preheating device 10 to be preheated, and the outer surface thereof is dried.

  Thereafter, the tubular body is sent to the hot dip galvanizing apparatus 11. In the hot dip galvanizing apparatus 11, the tubular body 6 is immersed in the upper plating tank filled with the pumped up hot dip, and the entire outer surface is hot dip galvanized. The tubular body 6 soaked in the upper plating tank is formed with a hot dip galvanized layer having a healthy alloy layer to form a hot dip galvanized steel pipe. Then, after the excess hot dip galvanizing is removed by a wiping device (not shown), the outer surface spraying device 12 becomes a sprayed metal plated steel pipe 40. Then it is cooled.

  At this time, the thermal spraying by the outer surface spraying device 12 needs to be performed when the surface temperature of the hot-dip galvanized layer is not cooled to the ambient temperature. Generally, a sprayed metal layer formed on a cooled metal surface is formed all over the unevenness of the metal surface, thereby ensuring a binding force only by an anchor effect due to the unevenness. However, when the thermal spraying is performed under the condition that the surface temperature of the hot dip galvanized layer does not decrease to the ambient temperature as in the present invention, a part of the sprayed metal enters the hot dip galvanized layer or the hot dip galvanized layer and the sprayed layer. It is possible to form an alloy layer between them and an element diffusion layer to improve the bonding force due to factors other than the anchor effect.

  In the present invention, preferably, the thermal spraying is performed in a state where the surface temperature of the hot-dip galvanized layer is higher than the ambient temperature. More preferably, the surface of the hot dip galvanized layer is preferably in a semi-molten state. The semi-molten state refers to the solid-liquid coexistence region temperature or a temperature lowered by several tens of degrees Celsius, or at most about 100 ° C, when the metal layer applied to the plating layer is a metal having a solid-liquid coexistence region. Say. In the case where the pure metal is a plating layer, there is no solid-liquid coexistence region temperature, but in this case, the same may be considered. The temperature required for the semi-molten state suitable for the present invention varies depending on the combination of the plating layer and the sprayed metal layer. In general, it is applicable to the object of the present invention as long as the bonding force can be obtained by a mechanism different from the element diffusion, alloying, and other anchor effects between the plating layer and the sprayed layer. .

  In this embodiment, the metal layer by thermal spraying needs to be formed on the entire surface in the circumferential direction of the tube. Therefore, in the present embodiment, the outer surface spraying apparatus is provided with spray nozzles from three directions separated by 120 ° to perform metal spraying. Although it is possible to form a sprayed metal layer by spraying from two directions separated by 180 °, it is desirable to provide a spray nozzle on three or more sides to form the sprayed metal layer.

  The sprayed metal-plated steel pipe 40 is cold-rolled by the sizing device 13 in order to set the outer shape to the standard dimension. In this embodiment, the cold roll process is a process necessary to make the sprayed layer have a relatively uniform thickness in the circumferential direction. In other words, even if the sprayed metal layer immediately after being formed by the outer surface spraying apparatus has a non-uniform thickness in the circumferential direction, the sprayed metal layer is comparatively formed through a subsequent process such as cold roll processing. A uniform thickness can be achieved. Thus, in a preferred embodiment of the present invention, after forming the sprayed metal layer by the outer surface spraying apparatus, for example, sizing processing such as cold roll processing is performed, and the sprayed metal layer formed by spraying is relatively It is desirable to adopt a step of making the thickness uniform (a step of making the thickness distribution more uniform than immediately after forming the sprayed metal layer).

  The thermally sprayed metal-plated steel pipe is cut into a predetermined length by a cutting device 14 to become a steel pipe product 15.

  According to the method of manufacturing a sprayed metal plated steel pipe having the above configuration, as shown in FIG. 2, the sprayed metal layer M is applied to the inner surface of the tubular body 6 on which the hot dip galvanized layer is formed, and the sprayed metal layer O is applied to the tubular body 6. By forming it on the outer surface, a thermally sprayed metal steel pipe having excellent corrosion resistance and a high rust prevention effect can be obtained continuously. In FIG. 2, a sprayed metal layer O is formed on the outer periphery of the galvanized layer N.

  In addition, this invention is not limited to said embodiment. For example, in the present embodiment, the sprayed metal layer is formed on both the inner and outer surfaces by the thermal spraying device, but the sprayed metal layer by the thermal spraying device may be provided only on the inner surface or the outer surface. In addition, when a sprayed metal layer is provided only on the outer surface, if a double-sided plated steel plate is used, a steel pipe having a plated layer on the inner surface and a double metal layer (plating layer + sprayed metal layer) on the outer surface can be manufactured. Is possible. In addition, when using a metal steel plate with a plating layer on one side, the sprayed metal layer is formed only on the surface on which the plating layer is not provided, and the metal layer is provided on both the inner and outer surfaces of the pipe to prevent corrosion. It is also possible to increase the effect.

  Alternatively, the upper surface of the sprayed metal layer may be covered with a protective film made of synthetic resin or the like. If it does in this way, the rust prevention effect of a thermal spray metal steel pipe can be improved more.

  Furthermore, in this embodiment, although molten zinc was applied as plating applied to a steel pipe, you may apply another metal as needed. Moreover, although this embodiment demonstrated on the assumption that a steel plate was used, you may presuppose that this invention uses another metal plate. Examples of such a metal plate include, but are not limited to, copper tape and aluminum tape.

  The surface treatment method according to the present invention can be applied not only to a metal tube but also to any metal member. Such a metal member has, for example, a first metal layer formed by applying molten metal plating on a metal having a first component to the metal surface, and has a second component on the surface of the first metal layer. A metal is thermally sprayed to form a surface layer, and the surface layer has a metal surface characterized in that the metal having the first and second components is naturally integrated.

Hereinafter, the Example which manufactures the thermal spray metal steel pipe of this invention is shown.
(Example 1)
Aluminum is used as the spray metal. A long rolled steel sheet with a thickness of 1.2mm and a width of 59.5mm is set on the production line shown in Fig. 1. After shot blasting and machining the inner surface with a shot blasting device, the inner surface is sprayed with a thermal spraying device. A layer was formed. Further, after the hot dip galvanizing apparatus, aluminum was sprayed by an outer surface spraying apparatus.
In the present invention, conditions such as the zinc surface temperature during spraying (room temperature to 450 ° C.), the line speed (0 to 400 m / min), and the spray angle (0 to 90 °) can be appropriately combined. At the same time, the bond concentration and distribution of aluminum can be adjusted by adjusting the amount of sprayed aluminum.

  FIG. 5 shows a comparison in appearance between the steel pipe manufactured according to Example 1 and the steel pipe manufactured by the conventional hot dipping method. According to the conventional hot-dip plating method, the surface shows a pattern (spangle) reflecting a unique grain boundary (FIG. 5 (a)), whereas the steel pipe manufactured by the thermal spraying of Example 1 is used. The surface is rough and granular (FIG. 5 (b)). A plated steel pipe having a rough granular surface is not known at the time of this application, and it is presumed that a plated steel pipe having such a surface was produced by the method of the present invention. Moreover, the external appearance of what grind | polished the steel pipe manufactured by Example 1 with the sandpaper is shown (FIG.5 (c)). The material polished with sandpaper has a metallic luster, but has dot-like depressions or holes peculiar to thermal spraying, and such an appearance is presumed to have been produced by the method of the present invention.

  In FIG. 3, the schematic diagram of the Al element distribution result concerning the product manufactured in Example 1 is shown. (As a result of elemental analysis of the outer surface sprayed metal layer, it is confirmed that the sprayed metal (aluminum) is scattered in an island shape in the zinc layer. In addition, FIG. 3 shows the results of Al elemental analysis, unlike in Fig. 3. Al segregates in the vicinity of the steel wire (St) and forms a layer in the vicinity of the steel wire that is different from Zn and far from the spraying direction. Thus, in the plating layer manufactured by the method according to the present invention, one feature is that the sprayed metal is scattered in the base metal in an island shape or distributed in a layer shape. In Example 1, it is clear that the plating layer and the sprayed layer are not bonded only by the anchor effect.

  This island-shaped distribution and layered distribution are one of the characteristics when the manufacturing method according to the present invention is used. However, after applying the manufacturing method according to the present invention, this characteristic disappears by heat treatment or the like. It is possible to do. It can be estimated that the plating layer having such characteristics is manufactured according to the present invention.

  Assuming the details of the principle of such distribution, compared to the conventional multiple times of hot dipping, according to the manufacturing method according to the present invention, a method called thermal spraying that irradiates a metal different from the plating base metal with physical force is adopted. Therefore, at least the temperature of the plating base metal during spraying (which affects the hardness of the surface, etc.), the temperature of the spraying metal during spraying (which affects the hardness of the sprayed metal), and the speed at which the sprayed metal reaches the plating base metal This is because (the kinetic energy) affects the distribution state of the plating base metal and the sprayed metal. Due to these factors, the distribution as shown in FIG. 3 is formed under the condition that the sprayed metal convects relatively near the surface. On the other hand, when the conditions are such that the sprayed metal reaches the vicinity of the surface of the steel wire (St), a distribution as shown in FIG. 4 can be formed.

(Example 2)
Aluminum steel is used as the thermal spray metal, a long rolled steel plate with a thickness of 1.2mm and a width of 59.5mm is set on the production line shown in Fig. 1, and shot blasting is performed on the inner surface with shot blasting and equipment. A sprayed metal layer was formed by a spraying device. Moreover, after the hot dip galvanization, thermal spraying of aluminum was performed by an outer surface spraying device.

  FIG. 6A shows an appearance photograph of the obtained cross section, and FIG. 6B shows a chart obtained by measuring the element distribution of the cross section with EPMA. As shown in FIG. 6 (a), the feature of this example was that the spray metal was finely scattered in the form of islands in the base metal. It can be seen that fine and dark aluminum is scattered on the whitish zinc base. In addition, as shown in FIG. 6B, in the steel pipe manufactured according to this example, zinc and aluminum were distributed at a relatively uniform concentration.

Example 3
Aluminum steel is used as the thermal spray metal, a long rolled steel plate with a thickness of 1.2mm and a width of 59.5mm is set on the production line shown in Fig. 1, and shot blasting is performed on the inner surface with shot blasting and equipment. A sprayed metal layer was formed by a spraying device. In addition, after the hot dip galvanizing apparatus, aluminum was sprayed by an outer surface spraying apparatus. In this example, the surface temperature of the galvanized plate was about 400 ° C., and aluminum was sprayed at 15 g / min at a spray angle of 90 ° during low-speed production of about 20 m / min. The contact portion between the zinc and the sprayed aluminum melts and promotes bonding with the aluminum, and a distribution of the aluminum layer on the surface, the zinc-aluminum layer in the middle, and the zinc layer on the inner layer can be obtained. This structure can also be realized in medium to high speed production by a series of correlations such as line speed, galvanized surface temperature, and aluminum spray amount.

  FIG. 7A shows the obtained cross section, and FIG. 7B shows a chart obtained by measuring the element distribution of the cross section with EPMA. As shown in FIG. 7 (a), in this example, aluminum (blackish portion) was unevenly distributed on the surface, and zinc (whitish portion) was present at the interface with the steel core. When the elemental distribution was analyzed in more detail, as shown in FIG. 7, the surface almost formed a pure aluminum layer and showed a distribution in which the concentrations of aluminum and zinc were gradually reversed. The reason for this element distribution is not clear, but it is a metal to be sprayed depending on the melting temperature of aluminum during spraying, the temperature of zinc as the sprayed metal layer, the initial velocity (kinetic energy) of the sprayed metal particles, etc. This is thought to be due to the change in the depth of aluminum in the zinc. This suggests the possibility that the element distribution in the metal layer can be arbitrarily controlled by adjusting these parameters.

  In this embodiment, an aluminum layer having a purity of almost 100% is formed from the surface to a depth of about 50 μm, and the deeper portion is an aluminum / zinc alloy layer. In general, pure aluminum has higher corrosion resistance, and those with such an element distribution have higher corrosion resistance as a plated steel pipe. The cause of the increased corrosion resistance is that even when fine defects (pinholes) are present in the aluminum layer, the zinc layer exhibits a sacrificial anticorrosive action, and the corrosion resistance function is shared by a function different from that of aluminum. . According to the present invention, it is possible to obtain one having a pure aluminum layer on the surface and an aluminum / zinc alloy layer or zinc layer inside. In that case, the pure aluminum layer preferably has a thickness of 30% or more, preferably 50% or more of the total plating layer thickness. Further, the aluminum layer on the surface is not necessarily an aluminum layer having a purity of 100%, and may have corrosion resistance substantially equivalent to 100% aluminum. From this point of view, mixing of other elements such as zinc of about 1 to 5% is acceptable.

  This indicates that not only the composition of the plating layer but also the metal distribution can be controlled by employing the manufacturing process according to the present invention.

  In this specification, although zinc was demonstrated to the example as a metal used for molten metal plating, it is not limited to this. For example, other metals such as an alloy containing aluminum or other metals in zinc, tin, or the like may be used. Moreover, although aluminum was demonstrated to the example as a metal to spray, it is not limited to this. For example, zinc, magnesium, and other metals may be used. The invention of the present application includes an invention relating to a manufacturing method, and at least the invention of the manufacturing method does not ask for the type of metal / alloy.

1 is a schematic diagram of a production line according to an embodiment of the present invention. The longitudinal cross-sectional view of the thermal spray metal plating manufactured with the manufacturing method of this embodiment. The surface analysis result concerning Al element of the surface treatment layer of the metal pipe manufactured by the present Example. The surface analysis result concerning Al element of the surface treatment layer of the metal pipe manufactured by the present Example. The external appearance of the metal tube manufactured by Example 1 is shown. The line analysis result of the surface treatment layer of the metal pipe manufactured by Example 2. FIG. The line analysis result of the surface treatment layer of the metal pipe manufactured by Example 3. FIG.

Explanation of symbols

1
steel sheet
3 Shot blasting equipment
4 Inner surface spraying device (inner surface spraying process)
Five
Forming device (process to form steel plate into a tube)
6 Tubular body tube
40 Thermal sprayed metal plated steel
7
Welding device (the process of welding the longitudinal direction end face joints of steel plates to make steel pipes)
8
Cutting device (process of cutting the weld bead formed on the outer surface of the steel pipe)
11 Hot dip galvanizing equipment (process for continuous hot dip plating on the outer surface of steel pipes)
12 External spraying device (process to perform external spraying)
13 Sizing device (process to make the outer diameter a standard dimension)
14 Cutting device (process to cut to a predetermined length)
15 Steel pipe product M Inner surface sprayed metal layer N Hot-dip galvanized layer O Outer surface sprayed metal layer

Claims (9)

A first metal tube portion comprising a first composition component, wherein at least a part of a cross section of the first metal tube portion has a melt joint portion continuous in the longitudinal direction;
A second metal layer formed on any surface of the first metal tube portion directly or via a metal layer made of a composition component different from the first composition component, A second metal layer formed by a thermal spraying process continuously in a circumferential direction and a longitudinal direction of the second metal layer;
A metal tube comprising: In the method for manufacturing a metal tube, a metal plate formed of a first composition component is continuously formed into a tubular shape, and a welded end is continuously welded to form a metal tube.
A method of manufacturing a metal tube, wherein a metal layer comprising a second composition component different from the first composition component is formed on at least one surface of the metal plate before the continuous welding over the entire width of the metal plate by thermal spraying. In the method for manufacturing a metal tube, a metal plate formed of a first composition component is continuously formed into a tubular shape, and a welded end is continuously welded to form a metal tube.
A metal tube formed by spraying a metal layer made of a second composition component different from the first composition component without discontinuity in the circumferential direction and the longitudinal direction directly on the surface of the metal tube after the continuous welding. Manufacturing method. In the method for manufacturing a metal tube, a metal plate formed of a first composition component is continuously formed into a tubular shape, and a welded end is continuously welded to form a metal tube.
Forming a metal layer having no discontinuity in the circumferential direction and the longitudinal direction by thermal spraying on the surface of the metal tube after the continuous welding via a metal layer made of a composition component different from the first composition component; A method of manufacturing a tube.   The metal tube manufacturing method according to claim 3, further comprising a processing step for making the thickness distribution of the metal layer close to uniform after forming the metal layer having no discontinuity in the circumferential direction and the longitudinal direction. Method. A first metal layer having a first component formed by molten metal plating directly on the surface of the metal tube or via a metal layer made of a composition component different from the composition component of the metal tube;
A second metal portion having a second component formed by thermal spraying on the surface of the first metal layer,
The metal tube, wherein the second metal portion is scattered in an island shape in the first metal layer. A first metal layer having a first component formed by molten metal plating directly on the surface of the metal tube or via a metal layer made of a composition component different from the composition component of the metal tube;
A second metal portion having a second component formed by thermal spraying on the surface of the first metal layer,
The metal tube, wherein the second metal portion is distributed in a layered manner in the first metal layer. A zinc layer formed by molten metal plating directly on the surface of the metal tube or via a metal layer made of a composition component different from the composition component of the metal tube;
Comprising an aluminum layer formed by thermal spraying on the surface of the zinc layer;
The metal tube, wherein the aluminum layer has a thickness of 30% or more of the total thickness of the zinc layer and the aluminum layer. The metal tube according to claim 7 or 8, wherein the metal tube has a rough granular surface, or has a metallic luster and point-like holes.