JP2005221231A - Refrigerating device and deterioration determination method of refrigerating machine oil - Google Patents

Refrigerating device and deterioration determination method of refrigerating machine oil Download PDF

Info

Publication number
JP2005221231A
JP2005221231A JP2005128210A JP2005128210A JP2005221231A JP 2005221231 A JP2005221231 A JP 2005221231A JP 2005128210 A JP2005128210 A JP 2005128210A JP 2005128210 A JP2005128210 A JP 2005128210A JP 2005221231 A JP2005221231 A JP 2005221231A
Authority
JP
Japan
Prior art keywords
oil
deterioration
refrigerating machine
degree
refrigerant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2005128210A
Other languages
Japanese (ja)
Inventor
Shigeji Taira
繁治 平良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daikin Industries Ltd
Original Assignee
Daikin Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daikin Industries Ltd filed Critical Daikin Industries Ltd
Priority to JP2005128210A priority Critical patent/JP2005221231A/en
Publication of JP2005221231A publication Critical patent/JP2005221231A/en
Pending legal-status Critical Current

Links

Images

Landscapes

  • Lubricants (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a refrigerating device capable of determining the deterioration degree of a refrigerating machine oil with a simple constitution, and keeping long-period reliability. <P>SOLUTION: This device is equipped with an oil deterioration determination device 31 disposed between a four-way selector valve 2 and a gas shut-off valve 24. Since a gas coolant including much refrigerating machine oil is discharged from a compressor 1 at the heating operation time, the deterioration degree of the oil can be determined easily. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

この発明は、冷凍装置および冷凍機油の劣化判断方法に関する。   The present invention relates to a refrigeration apparatus and a method for determining deterioration of refrigeration oil.

冷媒を用いたヒートポンプ方式の冷凍装置において、オゾン層破壊係数が大きいHCFC系冷媒がフロン規制の対象となったことから、その代替冷媒として、オゾン層破壊係数ゼロのHFC系冷媒が用いられている。このHFC冷媒を用いた冷凍装置では、冷凍機油とHFC冷媒との相互溶解性が重要な特性の一つとなるため、エーテル油やエステル油等の合成油が冷凍機油として用いられる(例えば、特許文献1参照)。   In a heat pump type refrigeration system using a refrigerant, an HCFC refrigerant having a large ozone depletion coefficient has been subject to Freon regulation, and therefore, an HFC refrigerant having an ozone depletion coefficient of zero is used as an alternative refrigerant. . In this refrigeration system using an HFC refrigerant, mutual solubility between the refrigeration oil and the HFC refrigerant is one of the important characteristics, and therefore synthetic oils such as ether oil and ester oil are used as the refrigeration oil (for example, Patent Documents). 1).

しかしながら、上記合成油は極性が強く、そのため冷凍機油および冷媒以外の残留不純物を溶かしやすいため、電動膨張弁で構成された減圧機構において、冷媒が蒸発した後のスラッジ等による詰まりや初期不良が生じて、冷凍サイクルに異常が発生して信頼性が低下するという問題がある。
特開平8−110101号公報
However, since the synthetic oil has a strong polarity and thus easily dissolves residual impurities other than refrigeration oil and refrigerant, clogging or initial failure due to sludge after the refrigerant evaporates occurs in the decompression mechanism constituted by the electric expansion valve. Thus, there is a problem that the refrigeration cycle is abnormal and reliability is lowered.
JP-A-8-110101

そこで、この発明の目的は、簡単な構成で冷凍機油の劣化の程度を判断でき、減圧機構の詰まりを防止して、長期信頼性を保つことができる冷凍装置および冷凍機油の劣化判断方法を提供することにある。   Accordingly, an object of the present invention is to provide a refrigerating apparatus and a method for determining deterioration of refrigerating machine oil that can determine the degree of deterioration of refrigerating machine oil with a simple configuration, prevent clogging of the decompression mechanism, and maintain long-term reliability. There is to do.

上記目的を達成するため、この発明の冷凍装置は、圧縮機の吐出側とガス閉鎖弁との間または四路切換弁とガス閉鎖弁との間に配設され、冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて冷凍機油の劣化の程度を判断するための油劣化判断装置を備えたことを特徴としている。   In order to achieve the above object, the refrigeration apparatus of the present invention is disposed between the discharge side of the compressor and the gas shut-off valve or between the four-way switching valve and the gas shut-off valve to reduce the degree of deterioration of the refrigeration oil. An oil deterioration judging device is provided for judging the degree of deterioration of the refrigerating machine oil based on at least one of oil color, moisture content, degree of oxidation or air content.

上記構成の冷凍装置によれば、圧縮機の吐出側とガス閉鎖弁との間または四路切換弁とガス閉鎖弁との間(暖房運転時のガス側配管)に油劣化判断装置を取り付けることによって、ガス側配管には冷凍機油を多く含むガス冷媒が圧縮機から吐出するので、油劣化の程度を容易に判断することが可能となる。したがって、簡単な構成で冷凍機油の劣化の程度を判断でき、その判断結果に基づいて必要に応じて作動媒体(冷凍機油を含む冷媒)を交換することによって、減圧機構の詰まり等を防止して、長期信頼性を保つことができる。   According to the refrigeration apparatus having the above configuration, the oil deterioration determination device is attached between the discharge side of the compressor and the gas shut-off valve or between the four-way switching valve and the gas shut-off valve (gas side pipe during heating operation). Thus, since the gas refrigerant containing a large amount of refrigeration oil is discharged from the compressor to the gas side pipe, the degree of oil deterioration can be easily determined. Therefore, the degree of deterioration of the refrigerating machine oil can be determined with a simple configuration, and the clogging of the decompression mechanism is prevented by replacing the working medium (refrigerant including refrigerating machine oil) as necessary based on the determination result. Can keep long-term reliability.

また、この発明の冷凍装置は、ガス側連絡配管に配設され、冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて冷凍機油の劣化の程度を判断するための油劣化判断装置を備えたことを特徴としている。   The refrigerating apparatus according to the present invention is disposed in the gas side connecting pipe, and the degree of deterioration of the refrigerating machine oil is determined based on at least one of the color, moisture content, degree of oxidation, or air content of the refrigerating machine oil. An oil deterioration determination device for determining the degree of deterioration is provided.

上記実施形態の冷凍装置によれば、室外ユニット,室内ユニットを有するスプリットタイプでは、室外ユニット,室内ユニットを接続する連絡配管のうちの暖房運転時のガス側連絡配管に油劣化判断装置を取り付けることによって、ガス側連絡配管には冷凍機油を多く含むガス冷媒が圧縮機から吐出するので、油劣化の程度を容易に判断することが可能となる。したがって、簡単な構成で冷凍機油の劣化の程度を判断でき、その判断結果に基づいて必要に応じて作動媒体(冷凍機油を含む冷媒)を交換することによって、長期信頼性を保つことができる。また、室外,室内ユニットの設計変更をすることなく、簡単な構成でこの発明を適用できると共に、既設の空気調和機においても連絡配管を油劣化判断装置付きの連絡配管に交換することによって、この発明を容易に適用することができる。   According to the refrigeration apparatus of the above embodiment, in the split type having the outdoor unit and the indoor unit, the oil deterioration determination device is attached to the gas side communication pipe during heating operation among the connection pipes connecting the outdoor unit and the indoor unit. Thus, since the gas refrigerant containing a large amount of refrigeration oil is discharged from the compressor to the gas side communication pipe, the degree of oil deterioration can be easily determined. Therefore, the degree of deterioration of the refrigerating machine oil can be determined with a simple configuration, and long-term reliability can be maintained by replacing the working medium (refrigerant including refrigerating machine oil) as necessary based on the determination result. In addition, the present invention can be applied with a simple configuration without changing the design of the outdoor and indoor units, and in existing air conditioners, the communication pipe can be replaced with a communication pipe with an oil deterioration determination device. The invention can be easily applied.

また、一実施形態の冷凍装置は、HFC系冷媒を用いたことを特徴としている。   Moreover, the refrigeration apparatus of one embodiment is characterized by using an HFC-based refrigerant.

上記実施形態の冷凍装置によれば、HFC冷媒との相互溶解性を有する冷凍機油として用いられるエーテル油やエステル油等の合成油は極性が強いために冷凍機油および冷媒以外の残留不純物を溶かしやすく、電動膨張弁で構成された減圧機構がスラッジ等による詰まりや初期不良が生じやすいが、上記油劣化判断装置を用いて冷凍機油の劣化の程度を早期に発見して、不具合が発生する前に冷凍機油を含む冷媒の交換等の処置を行うことができる。   According to the refrigerating apparatus of the above embodiment, synthetic oils such as ether oils and ester oils used as refrigerating machine oils having mutual solubility with HFC refrigerants are strong in polarity, so that it is easy to dissolve residual impurities other than refrigerating machine oils and refrigerants. The pressure reducing mechanism composed of an electric expansion valve is prone to clogging or initial failure due to sludge, etc., but the degree of deterioration of the refrigerating machine oil is discovered early using the above oil deterioration judgment device, before a malfunction occurs Measures such as replacement of refrigerant containing refrigeration oil can be performed.

また、一実施形態の冷凍装置は、R32冷媒またはR32を少なくとも70重量%以上含む混合冷媒を用いたことを特徴としている。   Further, the refrigeration apparatus of one embodiment is characterized in that R32 refrigerant or a mixed refrigerant containing at least 70% by weight of R32 is used.

上記実施形態の冷凍装置によれば、R32冷媒またはR32を少なくとも70重量%以上含む混合冷媒との相互溶解性を有する冷凍機油として用いられるエーテル油やエステル油等の合成油は、極性が強いために冷凍機油および冷媒以外の残留不純物を溶かしやすく、電動膨張弁で構成された減圧機構がスラッジ等による詰まりや初期不良が生じやすいが、上記油劣化判断装置を用いて冷凍機油の劣化の程度を早期に発見して、不具合が発生する前に冷凍機油を含む冷媒の交換等の処置を行うことができる。   According to the refrigeration apparatus of the above embodiment, synthetic oils such as ether oils and ester oils used as refrigerating machine oils having mutual solubility with R32 refrigerant or a mixed refrigerant containing at least 70% by weight of R32 are strong in polarity. It is easy to dissolve residual impurities other than refrigerating machine oil and refrigerant, and the decompression mechanism composed of an electric expansion valve is likely to be clogged with sludge etc. and initial failure. It can be discovered early and measures such as replacement of refrigerant including refrigeration oil can be performed before a failure occurs.

また、一実施形態の冷凍装置は、上記のいずれか1つの冷凍装置において、上記油劣化判断装置に簡易判断部を設けたことを特徴としている。   Moreover, the refrigeration apparatus of one embodiment is characterized in that, in any one of the above refrigeration apparatuses, a simple determination unit is provided in the oil deterioration determination apparatus.

上記実施形態の冷凍装置によれば、例えば、上記油劣化判断装置に水分に反応して色が変化する化学物質が塗布して、その化学物質の色を比較して水分を含む程度を判断する簡易判断部を設けることによって、油の劣化の程度を容易に判断することができる。   According to the refrigeration apparatus of the above embodiment, for example, a chemical substance that changes color in response to moisture is applied to the oil degradation determination apparatus, and the color of the chemical substance is compared to determine the degree of moisture content. By providing the simple determination unit, it is possible to easily determine the degree of oil degradation.

また、この発明の冷凍機油の劣化判断方法は、圧縮機の吐出側とガス閉鎖弁との間または四路切換弁とガス閉鎖弁との間に、冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて判断するための油劣化判断装置を設けて、冷凍機油の劣化を判断することを特徴としている。   Further, the deterioration judgment method for refrigerating machine oil according to the present invention is a method for determining the degree of deterioration of refrigerating machine oil between the discharge side of the compressor and the gas shut-off valve or between the four-way switching valve and the gas shut-off valve, An oil deterioration determination device for determining based on at least one of the moisture content, the degree of oxidation, or the air content is provided, and deterioration of the refrigerating machine oil is determined.

上記構成の冷凍機油の劣化判断方法によれば、圧縮機の吐出側とガス閉鎖弁との間または四路切換弁とガス閉鎖弁との間(暖房運転時のガス側配管)に油劣化判断装置を取り付けることによって、ガス側配管には冷凍機油を多く含むガス冷媒が圧縮機から吐出するので、油劣化の程度を容易に判断することが可能となる。したがって、簡単な構成で冷凍機油の劣化の程度を判断でき、その判断結果に基づいて必要に応じて作動媒体(冷凍機油を含む冷媒)を交換することによって、減圧機構の詰まり等を防止して、長期信頼性を保つことができる。   According to the method for judging deterioration of refrigeration oil having the above configuration, oil deterioration is judged between the discharge side of the compressor and the gas shut-off valve or between the four-way switching valve and the gas shut-off valve (gas side pipe during heating operation). By attaching the apparatus, gas refrigerant containing a large amount of refrigeration oil is discharged from the compressor into the gas side pipe, so that the degree of oil deterioration can be easily determined. Therefore, the degree of deterioration of the refrigerating machine oil can be determined with a simple configuration, and the clogging of the decompression mechanism is prevented by replacing the working medium (refrigerant including refrigerating machine oil) as necessary based on the determination result. Can keep long-term reliability.

また、この発明の冷凍機油の劣化判断方法は、冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて判断するための油劣化判断装置をガス側連絡配管に設けて、冷凍機油の劣化を判断することを特徴としている。   The deterioration determination method for refrigerating machine oil according to the present invention is an oil deterioration determination device for determining the degree of deterioration of refrigerating machine oil based on at least one of the color, moisture content, degree of oxidation or air content of the oil. Is provided in the gas side communication pipe to determine the deterioration of the refrigerating machine oil.

上記実施形態の冷凍機油の劣化判断方法よれば、室外ユニット,室内ユニットを有するスプリットタイプでは、室外ユニット,室内ユニットを接続する連絡配管のうちの暖房運転時のガス側連絡配管に油劣化判断装置を取り付けることによって、ガス側連絡配管には冷凍機油を多く含むガス冷媒が圧縮機から吐出するので、油劣化の程度を容易に判断することが可能となる。したがって、簡単な構成で冷凍機油の劣化の程度を判断でき、その判断結果に基づいて必要に応じて作動媒体(冷凍機油を含む冷媒)を交換することによって、長期信頼性を保つことができる。また、室外,室内ユニットの設計変更をすることなく、簡単な構成でこの発明を適用できると共に、既設の空気調和機においても連絡配管を油劣化判断装置付きの連絡配管に交換することによって、この発明を容易に適用することができる。   According to the method for determining deterioration of refrigerating machine oil according to the above embodiment, in the split type having an outdoor unit and an indoor unit, an oil deterioration determination device is provided for the gas side connection pipe during heating operation among the connection pipes connecting the outdoor unit and the indoor unit. Since a gas refrigerant containing a large amount of refrigerating machine oil is discharged from the compressor to the gas side connecting pipe, it becomes possible to easily determine the degree of oil deterioration. Therefore, the degree of deterioration of the refrigerating machine oil can be determined with a simple configuration, and long-term reliability can be maintained by replacing the working medium (refrigerant including refrigerating machine oil) as necessary based on the determination result. In addition, the present invention can be applied with a simple configuration without changing the design of the outdoor and indoor units, and in existing air conditioners, the communication pipe can be replaced with a communication pipe with an oil deterioration determination device. The invention can be easily applied.

また、一実施形態の冷凍機油の劣化判断方法は、HFC系冷媒を用いたことを特徴としている。   In addition, the method for determining deterioration of refrigerating machine oil according to one embodiment is characterized in that an HFC-based refrigerant is used.

上記実施形態の冷凍機油の劣化判断方法によれば、HFC冷媒との相互溶解性を有する冷凍機油として用いられるエーテル油やエステル油等の合成油は極性が強いために冷凍機油および冷媒以外の残留不純物を溶かしやすく、電動膨張弁で構成された減圧機構がスラッジ等による詰まりや初期不良が生じやすいが、上記油劣化判断装置を用いて冷凍機油の劣化の程度を早期に発見して、不具合が発生する前に冷凍機油を含む冷媒の交換等の処置を行うことができる。   According to the method for judging deterioration of refrigerating machine oil according to the above embodiment, since synthetic oils such as ether oil and ester oil used as refrigerating machine oil having mutual solubility with HFC refrigerant are strong in polarity, residual oil other than refrigerating machine oil and refrigerant remains. It is easy to dissolve impurities, and the pressure reducing mechanism composed of an electric expansion valve is likely to be clogged with sludge, etc., or to cause initial failure. Before the occurrence, it is possible to take measures such as replacing the refrigerant containing the refrigeration oil.

また、一実施形態の冷凍機油の劣化判断方法は、R32冷媒またはR32を少なくとも70重量%以上含む混合冷媒を用いたことを特徴としている。   In addition, the method for determining deterioration of refrigerating machine oil according to an embodiment is characterized in that R32 refrigerant or a mixed refrigerant containing at least 70% by weight of R32 is used.

上記実施形態の冷凍機油の劣化判断方法によれば、R32冷媒またはR32を少なくとも70重量%以上含む混合冷媒との相互溶解性を有する冷凍機油として用いられるエーテル油やエステル油等の合成油は、極性が強いために冷凍機油および冷媒以外の残留不純物を溶かしやすく、電動膨張弁で構成された減圧機構がスラッジ等による詰まりや初期不良が生じやすいが、上記油劣化判断装置を用いて冷凍機油の劣化の程度を早期に発見して、不具合が発生する前に冷凍機油を含む冷媒の交換等の処置を行うことができる。   According to the method for judging deterioration of refrigerating machine oil of the above embodiment, synthetic oil such as ether oil and ester oil used as refrigerating machine oil having mutual solubility with R32 refrigerant or a mixed refrigerant containing at least 70% by weight of R32, Due to its strong polarity, it is easy to dissolve residual impurities other than refrigeration oil and refrigerant. It is possible to detect the degree of deterioration at an early stage, and to take measures such as replacement of a refrigerant containing refrigeration oil before a failure occurs.

以上より明らかなように、この発明の冷凍装置は、圧縮機の吐出側とガス閉鎖弁との間または四路切換弁とガス閉鎖弁との間に配設され、冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて冷凍機油の劣化の程度を判断するための油劣化判断装置を備えたものである。   As is clear from the above, the refrigeration apparatus of the present invention is disposed between the discharge side of the compressor and the gas shut-off valve or between the four-way switching valve and the gas shut-off valve to reduce the degree of deterioration of the refrigeration oil. An oil deterioration judging device is provided for judging the degree of deterioration of the refrigerating machine oil based on at least one of oil color, moisture content, degree of oxidation or air content.

したがって、上記構成の冷凍装置によれば、上記油劣化判断装置を配設した圧縮機の吐出側とガス閉鎖弁との間(または四路切換弁とガス閉鎖弁との間)では、冷凍機油を多く含むガス冷媒が圧縮機から吐出するので、簡単な構成で冷凍機油の劣化の程度を判断でき、その判断結果に基づいて必要に応じて作動媒体(冷凍機油を含む冷媒)を交換することによって、長期信頼性を保つことができる。   Therefore, according to the refrigeration apparatus having the above configuration, between the discharge side of the compressor provided with the oil deterioration determination device and the gas shut-off valve (or between the four-way switching valve and the gas shut-off valve), the refrigeration oil Since the gas refrigerant containing a large amount of gas is discharged from the compressor, the degree of deterioration of the refrigeration oil can be determined with a simple configuration, and the working medium (refrigerant including refrigeration oil) can be replaced as necessary based on the determination result. Therefore, long-term reliability can be maintained.

また、この発明の冷凍装置は、ガス側連絡配管に配設され、冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて冷凍機油の劣化の程度を判断するための油劣化判断装置を備えたものである。   The refrigerating apparatus according to the present invention is disposed in the gas side connecting pipe, and the degree of deterioration of the refrigerating machine oil is determined based on at least one of the color, moisture content, degree of oxidation, or air content of the refrigerating machine oil. An oil deterioration determination device for determining the degree of deterioration is provided.

したがって、上記構成の冷凍装置によれば、室外ユニット,室内ユニットを接続する連絡配管のうちの暖房運転時のガス側連絡配管であって、上記油劣化判断装置を配設したガス側連絡配管では、冷凍機油を多く含むガス冷媒が圧縮機から吐出するので、簡単な構成で冷凍機油の劣化の程度を判断でき、その判断結果に基づいて必要に応じて作動媒体(冷凍機油を含む冷媒)を交換することによって、長期信頼性を保つことができる。また、室外,室内ユニットの設計変更をすることなく、簡単な構成でこの発明を適用できると共に、既設の空気調和機においても連絡配管を油劣化判断装置付きの連絡配管に交換することによって、この発明を容易に適用することができる。   Therefore, according to the refrigeration apparatus configured as described above, the gas side connection pipe during heating operation among the connection pipes connecting the outdoor unit and the indoor unit, and the gas side connection pipe provided with the oil deterioration determination device is Since the gas refrigerant containing a large amount of refrigerating machine oil is discharged from the compressor, the degree of deterioration of the refrigerating machine oil can be determined with a simple configuration, and the working medium (refrigerant including refrigerating machine oil) can be selected as necessary based on the determination result. Long-term reliability can be maintained by replacement. In addition, the present invention can be applied with a simple configuration without changing the design of the outdoor and indoor units, and in existing air conditioners, the communication pipe can be replaced with a communication pipe with an oil deterioration determination device. The invention can be easily applied.

また、一実施形態の冷凍装置によれば、減圧機構がスラッジ等により詰まりやすいHFC系冷媒を用いても、上記油劣化判断装置を用いて冷凍機油の劣化の程度を早期に発見して、不具合が発生する前に冷凍機油を含む冷媒の交換等の処置を行うことができる。   Also, according to the refrigeration apparatus of one embodiment, even if the decompression mechanism uses an HFC-based refrigerant that is likely to be clogged with sludge, etc., the degree of deterioration of the refrigeration oil can be detected early using the above oil deterioration determination device, causing a problem. Before the occurrence of this, it is possible to take measures such as replacing the refrigerant containing the refrigerator oil.

また、一実施形態の冷凍装置は、減圧機構がスラッジ等により詰まりやすいR32冷媒またはR32を少なくとも70重量%以上含む混合冷媒を用いても、上記油劣化判断装置を用いて冷凍機油の劣化の程度を早期に発見して、不具合が発生する前に冷凍機油を含む冷媒の交換等の処置を行うことができる。   In addition, the refrigeration apparatus of one embodiment uses the oil deterioration determination device to determine the degree of deterioration of refrigeration oil even when an R32 refrigerant or a mixed refrigerant containing at least 70 wt% or more of R32 is used in which the decompression mechanism is easily clogged with sludge or the like. Can be detected at an early stage, and measures such as replacement of the refrigerant containing the refrigerating machine oil can be performed before the trouble occurs.

また、一実施形態の冷凍装置は、上記のいずれか1つの冷凍装置において、上記油劣化判断装置に簡易判断部を設けたので、油の劣化の程度を容易に判断することができる。   Moreover, the refrigeration apparatus of one embodiment can easily determine the degree of oil deterioration because any one of the refrigeration apparatuses includes a simple determination unit in the oil deterioration determination apparatus.

また、この発明の冷凍機油の劣化判断方法は、圧縮機の吐出側とガス閉鎖弁との間または四路切換弁とガス閉鎖弁との間に、冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて判断するための油劣化判断装置を設けて、冷凍機油の劣化を判断するものである。   Further, the deterioration judgment method for refrigerating machine oil according to the present invention is a method for determining the degree of deterioration of refrigerating machine oil between the discharge side of the compressor and the gas shut-off valve or between the four-way switching valve and the gas shut-off valve, An oil deterioration determination device for determining based on at least one of the moisture content, the degree of oxidation, or the air content is provided to determine the deterioration of the refrigerating machine oil.

したがって、上記構成の冷凍機油の劣化判断方法によれば、上記油劣化判断装置を配設した圧縮機の吐出側とガス閉鎖弁との間(または四路切換弁とガス閉鎖弁との間)では、冷凍機油を多く含むガス冷媒が圧縮機から吐出するので、簡単な構成で冷凍機油の劣化の程度を判断でき、その判断結果に基づいて必要に応じて作動媒体(冷凍機油を含む冷媒)を交換することによって、長期信頼性を保つことができる。   Therefore, according to the refrigeration oil deterioration determination method having the above-described configuration, between the discharge side of the compressor provided with the oil deterioration determination device and the gas shutoff valve (or between the four-way switching valve and the gas shutoff valve). Then, since the gas refrigerant containing a large amount of refrigerating machine oil is discharged from the compressor, the degree of deterioration of the refrigerating machine oil can be determined with a simple configuration, and the working medium (refrigerant including refrigerating machine oil) can be determined as necessary based on the determination result. Replacing can maintain long-term reliability.

また、この発明の冷凍機油の劣化判断方法は、冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて判断するための油劣化判断装置をガス側連絡配管に設けて、冷凍機油の劣化を判断するものである。   The deterioration determination method for refrigerating machine oil according to the present invention is an oil deterioration determination device for determining the degree of deterioration of refrigerating machine oil based on at least one of the color, moisture content, degree of oxidation or air content of the oil. Is provided in the gas side communication pipe to judge the deterioration of the refrigerating machine oil.

したがって、上記構成の冷凍機油の劣化判断方法によれば、室外ユニット,室内ユニットを接続する連絡配管のうちの暖房運転時のガス側連絡配管であって、上記油劣化判断装置を配設したガス側連絡配管では、冷凍機油を多く含むガス冷媒が圧縮機から吐出するので、簡単な構成で冷凍機油の劣化の程度を判断でき、その判断結果に基づいて必要に応じて作動媒体(冷凍機油を含む冷媒)を交換することによって、長期信頼性を保つことができる。また、室外,室内ユニットの設計変更をすることなく、簡単な構成でこの発明を適用できると共に、既設の空気調和機においても連絡配管を油劣化判断装置付きの連絡配管に交換することによって、この発明を容易に適用することができる。   Therefore, according to the refrigeration oil deterioration determination method having the above-described configuration, the gas-side connection pipe during heating operation of the outdoor unit and the connection pipe connecting the indoor units, the gas having the oil deterioration determination device disposed therein. In the side connection pipe, gas refrigerant containing a large amount of refrigeration oil is discharged from the compressor, so the degree of deterioration of the refrigeration oil can be judged with a simple configuration, and the working medium (refrigeration oil can be removed as needed) based on the judgment result. Long-term reliability can be maintained by exchanging the refrigerant. In addition, the present invention can be applied with a simple configuration without changing the design of the outdoor and indoor units, and in existing air conditioners, the communication pipe can be replaced with a communication pipe with an oil deterioration determination device. The invention can be easily applied.

また、一実施形態の冷凍機油の劣化判断方法によれば、減圧機構がスラッジ等により詰まりやすいHFC系冷媒を用いても、上記油劣化判断装置を用いて冷凍機油の劣化の程度を早期に発見して、不具合が発生する前に冷凍機油を含む冷媒の交換等の処置を行うことができる。   In addition, according to the method for determining deterioration of refrigerating machine oil according to an embodiment, even when an HFC refrigerant whose decompression mechanism is easily clogged with sludge or the like is used, the degree of deterioration of refrigerating machine oil can be detected early using the oil deterioration determining apparatus. Thus, measures such as replacement of the refrigerant containing the refrigerating machine oil can be performed before the trouble occurs.

また、一実施形態の冷凍機油の劣化判断方法は、減圧機構がスラッジ等により詰まりやすいR32冷媒またはR32を少なくとも70重量%以上含む混合冷媒を用いても、上記油劣化判断装置を用いて冷凍機油の劣化の程度を早期に発見して、不具合が発生する前に冷凍機油を含む冷媒の交換等の処置を行うことができる。   In addition, the method for determining deterioration of refrigerating machine oil according to one embodiment uses refrigerating machine oil using the above oil deterioration determining apparatus, even if the decompression mechanism uses R32 refrigerant that is easily clogged with sludge or the like, or a mixed refrigerant that contains at least 70% by weight of R32. It is possible to detect the degree of deterioration at an early stage and take measures such as replacing the refrigerant containing the refrigeration oil before the trouble occurs.

以下、この発明の冷凍装置および冷凍機油の劣化判断方法を図示の実施の形態により詳細に説明する。   Hereinafter, the refrigeration apparatus and the method for determining deterioration of refrigeration oil according to the present invention will be described in detail with reference to the illustrated embodiments.

(第1実施形態)
図1はこの発明の第1実施形態の冷凍装置としてのヒートポンプ式の空気調和機の概略構成を示す回路図であり、1は圧縮機、2は上記圧縮機1の吐出側に一端が接続された四路切換弁、3は上記四路切換弁2の他端に一端が接続された室外熱交換器、4は上記室外熱交換器3の他端に一端が接続された電動膨張弁、5は上記電動膨張弁4の他端に一端が接続された室内熱交換器、6は上記室内熱交換器5の他端に四路切換弁2を介して一端が接続され、他端が圧縮機1の吸入側に接続されたアキュームレータである。
(First embodiment)
FIG. 1 is a circuit diagram showing a schematic configuration of a heat pump type air conditioner as a refrigeration apparatus according to a first embodiment of the present invention. 1 is a compressor, 2 is one end connected to the discharge side of the compressor 1. The four-way switching valve 3 is an outdoor heat exchanger having one end connected to the other end of the four-way switching valve 2, and 4 is an electric expansion valve having one end connected to the other end of the outdoor heat exchanger 3. Is an indoor heat exchanger having one end connected to the other end of the electric expansion valve 4, and 6 is connected to the other end of the indoor heat exchanger 5 via a four-way switching valve 2, and the other end is a compressor. 1 is an accumulator connected to the suction side of 1.

また、上記空気調和機は、圧縮機1の吐出管温度を検出する温度センサ11と、室外熱交換器3の冷媒温度を検出する温度センサ12と、外気温度を検出する温度センサ13と、室内熱交換器5の冷媒温度を検出する温度センサ14と、室内温度を検出する温度センサ15と、上記圧縮機1の吸込側の冷媒温度を検出する温度センサ16と、上記温度センサ11〜16からの信号を受けて、圧縮機1,電動膨張弁4等を制御する制御装置7とを備えている。また、上記電動膨張弁4と室内熱交換器5との間に閉鎖弁21を配設すると共に、室内熱交換器5と四路切換弁2との間に閉鎖弁24を配設している。上記四路切換弁2と暖房運転時にガス側となる閉鎖弁24との間に油劣化判断装置31を配設している。   The air conditioner includes a temperature sensor 11 that detects a discharge pipe temperature of the compressor 1, a temperature sensor 12 that detects a refrigerant temperature of the outdoor heat exchanger 3, a temperature sensor 13 that detects an outdoor air temperature, From the temperature sensor 14 that detects the refrigerant temperature of the heat exchanger 5, the temperature sensor 15 that detects the indoor temperature, the temperature sensor 16 that detects the refrigerant temperature on the suction side of the compressor 1, and the temperature sensors 11 to 16. And a control device 7 for controlling the compressor 1, the electric expansion valve 4 and the like. In addition, a closing valve 21 is disposed between the electric expansion valve 4 and the indoor heat exchanger 5, and a closing valve 24 is disposed between the indoor heat exchanger 5 and the four-way switching valve 2. . An oil deterioration determining device 31 is disposed between the four-way switching valve 2 and the closing valve 24 that is on the gas side during heating operation.

上記圧縮機1,四路切換弁2,室外熱交換器3,電動膨張弁4,アキュームレータ6,制御装置7,閉鎖弁21,閉鎖弁24,温度センサ11〜13,温度センサ16および室外ファン(図示せず)で室外ユニット10を構成すると共に、室内熱交換器5,温度センサ14,温度センサ15および室内ファン(図示せず)で室内ユニット20を構成している。   The compressor 1, the four-way switching valve 2, the outdoor heat exchanger 3, the electric expansion valve 4, the accumulator 6, the control device 7, the closing valve 21, the closing valve 24, the temperature sensors 11 to 13, the temperature sensor 16 and the outdoor fan ( The outdoor unit 10 is configured by an unillustrated), and the indoor unit 20 is configured by an indoor heat exchanger 5, a temperature sensor 14, a temperature sensor 15, and an indoor fan (not illustrated).

図1に示すように、上記油劣化判断装置31は、両端に配管が接続された容器本体31aに窓ガラス31bを設けたサイトガラスであり、油の劣化の程度は窓ガラス31bから容器本体31a内を目視で判断し、窓ガラス31bの内側に付着したスラッジ等の黒色化した樹脂状の合成物または重合物を目視で判断する。   As shown in FIG. 1, the oil deterioration judging device 31 is a sight glass in which a window glass 31b is provided on a container main body 31a having pipes connected to both ends, and the degree of oil deterioration is determined from the window glass 31b to the container main body 31a. The inside is judged visually, and a blackened resinous composition or polymer such as sludge adhering to the inside of the window glass 31b is judged visually.

図4(A)〜(D)は油劣化判断装置31に設ける判断表を示している。   4A to 4D show determination tables provided in the oil deterioration determination device 31. FIG.

図4(A)は、窓ガラス31bの内側に付着した油の色と判断表51の色とを比較して油劣化の程度を判断する。例えば、窓ガラス31bの内側に付着した油の色が茶色から黒色になるほど、油が悪くなっていることを示している。   In FIG. 4A, the degree of oil deterioration is determined by comparing the color of the oil adhering to the inside of the window glass 31b with the color of the determination table 51. For example, it is shown that the oil becomes worse as the color of the oil attached to the inside of the window glass 31b changes from brown to black.

また、図4(B)は、水分含有率に応じて色が変化する化学物質(コバルト等)を容器本体31a内の窓ガラス31bを介して見える位置に塗布し、その塗布された化学物質の色と判断表52の色とを比較して含水の程度を判断する。例えば、化学物質の色が黄色からグリーンになるほど水分含水率が多くなり、油が悪くなっていることを示している。   FIG. 4B shows that a chemical substance (cobalt or the like) whose color changes according to the moisture content is applied to a position that can be seen through the window glass 31b in the container body 31a. The degree of water content is determined by comparing the color with the color in the determination table 52. For example, the moisture content increases as the color of the chemical substance changes from yellow to green, indicating that the oil is getting worse.

また、図4(C)は、油の酸化の度合いによって色が変わるpH指示薬等の色素を容器本体31a内の窓ガラス31bを介して見える位置に塗布し、その塗布された色素の色と判断表53の色とを比較して油劣化の程度を判断する。例えば、色素の色が青から赤になるほど酸化の度合いが高くなって、油が悪くなっていることを示している。   In FIG. 4C, a pigment such as a pH indicator whose color changes depending on the degree of oil oxidation is applied to a position visible through the window glass 31b in the container main body 31a, and is determined as the color of the applied pigment. The degree of oil deterioration is determined by comparing the colors in Table 53. For example, the degree of oxidation increases as the color of the pigment changes from blue to red, indicating that the oil is getting worse.

また、図4(D)は、空気を含む程度を空気含有率に応じて色が変化する化学物質を容器本体31a内の窓ガラス31bを介して見える位置に塗布し、その塗布された化学物質と判断表54の色とを比較して空気を含む程度を判断する。例えば、化学物質の色の変化にともって、空気含有率が多くなっていることを示している。   Further, FIG. 4D shows that a chemical substance whose color changes depending on the air content is applied to a position that can be seen through the window glass 31b in the container body 31a, and the applied chemical substance. And the color of the determination table 54 are compared to determine the degree of air inclusion. For example, it shows that the air content increases as the color of the chemical substance changes.

図4(A)〜(D)に示す各判断表51〜54は、図5に示すように、容器本体40の両端近傍に貼り付ける。なお、図5では、窓ガラス45とその窓ガラス45を介して見える簡易判断部46(塗布された化学物質,固定された磁石等)を示している。   The determination tables 51 to 54 shown in FIGS. 4A to 4D are pasted in the vicinity of both ends of the container main body 40 as shown in FIG. FIG. 5 shows a window glass 45 and a simple determination unit 46 (applied chemical substance, fixed magnet, etc.) that can be seen through the window glass 45.

上記構成の空気調和機では、暖房運転時のガス側配管に油劣化判断装置31を取り付けることによって、ガス側配管に冷凍機油を多く含むガス冷媒が吐出するので、油劣化の程度を容易に判断することが可能となる。   In the air conditioner having the above configuration, by attaching the oil deterioration determination device 31 to the gas side pipe during heating operation, gas refrigerant containing a large amount of refrigeration oil is discharged to the gas side pipe, so the degree of oil deterioration can be easily determined. It becomes possible to do.

このようにして、簡単な構成で冷凍機油の劣化の程度を判断でき、その判断結果に基づいて必要に応じて作動媒体(冷凍機油を含む冷媒)を交換することによって、長期信頼性を保つことができる。   In this way, the degree of deterioration of refrigeration oil can be determined with a simple configuration, and long-term reliability can be maintained by replacing the working medium (refrigerant including refrigeration oil) as necessary based on the determination result. Can do.

また、上記容器本体31a近傍に判断表51〜54を設けることによって、油の劣化の程度をその場で容易に判断することができる。   Further, by providing the determination tables 51 to 54 in the vicinity of the container main body 31a, the degree of deterioration of the oil can be easily determined on the spot.

(第2実施形態)
図2はこの発明の第2実施形態の冷凍装置としてのヒートポンプ式の空気調和機の概略構成を示す回路図であり、油劣化判断装置を除き第1実施形態の空気調和機と同一の構成をしており、同一構成部は同一参照番号を付して説明を省略する。この空気調和機は、図2に示すように、暖房運転時にガス側となる連絡配管23に油劣化判断装置32を配設している。
(Second Embodiment)
FIG. 2 is a circuit diagram showing a schematic configuration of a heat pump type air conditioner as a refrigeration apparatus according to a second embodiment of the present invention, and has the same configuration as the air conditioner of the first embodiment except for an oil deterioration judging device. The same components are denoted by the same reference numerals and description thereof is omitted. In this air conditioner, as shown in FIG. 2, an oil deterioration determination device 32 is disposed in a communication pipe 23 that is on the gas side during heating operation.

また、図3は上記油劣化判断装置が配設された連絡配管を示しており、油劣化判断装置40の一端に一端が接続された配管41の他端をフレア継手により室外ユニットおよび室内ユニットに接続してもよいし、油劣化判断装置40の他端に一端が接続された配管43の他端を高圧継手(スエッジロックや2重ロック等)により室外ユニットおよび室内ユニットに接続してもよい。   FIG. 3 shows a connecting pipe provided with the oil deterioration judging device. The other end of the pipe 41 connected to one end of the oil deterioration judging device 40 is connected to the outdoor unit and the indoor unit by a flare joint. The other end of the pipe 43 whose one end is connected to the other end of the oil deterioration determination device 40 may be connected to the outdoor unit and the indoor unit by a high-pressure joint (sedge lock, double lock, etc.). Good.

この第2実施形態の場合も第1実施形態と同様に、簡単な構成で冷凍機油の劣化の程度を判断でき、その判断結果に基づいて必要に応じて作動媒体(冷凍機油を含む冷媒)を交換することによって、長期信頼性を保つことができる。また、室外ユニット,室内ユニットの設計変更することなく、簡単な構成でこの発明を適用できると共に、既設の空気調和機においても連絡配管を油劣化判断装置付きの連絡配管に交換することによって、この発明を容易に適用することができる。   In the case of the second embodiment, similarly to the first embodiment, the degree of deterioration of the refrigerating machine oil can be determined with a simple configuration, and the working medium (refrigerant including the refrigerating machine oil) can be added as necessary based on the determination result. Long-term reliability can be maintained by replacement. In addition, the present invention can be applied with a simple configuration without changing the design of the outdoor unit and the indoor unit, and in the existing air conditioner, the communication pipe is replaced with a communication pipe with an oil deterioration determination device. The invention can be easily applied.

上記第1,第2実施形態では、HFC系冷媒としてR32冷媒またはR32を少なくとも70重量%以上含む混合冷媒を用いている。なお、R32冷媒とCO2との混合冷媒であって、CO2に対してR32冷媒が70重量%以上かつ90重量%以下の混合冷媒でもよいし、R32冷媒とR22冷媒との混合冷媒であって、R22冷媒に対してR32冷媒が70重量%以上かつ90重量%以下の混合冷媒でもよい。 In the first and second embodiments, R32 refrigerant or a mixed refrigerant containing at least 70% by weight of R32 is used as the HFC refrigerant. Note that a mixed refrigerant of R32 refrigerant and CO 2, R32 refrigerant may be a 70% by weight or more and 90% by weight of the mixed refrigerant with respect to CO 2, a by mixed refrigerant of R32 refrigerant and R22 refrigerant Thus, the R32 refrigerant may be a mixed refrigerant in which the R32 refrigerant is 70% by weight or more and 90% by weight or less.

また、上記第1,第2実施形態では、油劣化判断装置31を備えた冷凍装置としての空気調和機について説明したが、油劣化判断装置とは別に磨耗粉判断装置を備えてもよい。この磨耗粉判断装置は、容器本体31a(図1に示す)内の窓ガラス31bを介して見える位置に磁石を埋め込み、その磁石に付着した磨耗粉の付着物の色と判断表55(図4(E)に示す)の色とを比較して磨耗粉を含む程度を判断する。例えば、磨耗粉の付着量が多いほど色が濃くなって、磨耗粉が多くなっていることを示している。この場合、上記磁石に付着する磨耗粉の量によって冷媒中に含まれる磨耗粉の量の程度を判断することが可能となり、簡単な構成で冷媒回路内の磨耗粉の程度を判断でき、その判断結果に基づいて必要に応じて作動媒体(冷凍機油を含む冷媒)を交換することによって、減圧機構の詰まり等を防止して、長期信頼性を維持することができる。また、上記容器本体31a近傍に判断表55を設けることによって、冷媒の劣化の程度をその場で容易に判断することができる。   In the first and second embodiments, the air conditioner as a refrigeration apparatus including the oil deterioration determination device 31 has been described. However, a wear powder determination device may be provided separately from the oil deterioration determination device. This wear powder judgment device embeds a magnet in a position visible through the window glass 31b in the container body 31a (shown in FIG. 1), and the color of the wear powder adhering to the magnet and the judgment table 55 (FIG. 4). Compare the color of (shown in (E)) to determine the degree of inclusion of wear powder. For example, the greater the amount of wear powder adhering, the darker the color and the greater the amount of wear powder. In this case, it is possible to determine the degree of the amount of wear powder contained in the refrigerant by the amount of the wear powder adhering to the magnet, and the degree of the wear powder in the refrigerant circuit can be determined with a simple configuration. By replacing the working medium (refrigerant containing refrigeration oil) as necessary based on the result, it is possible to prevent clogging of the decompression mechanism and maintain long-term reliability. Further, by providing the determination table 55 in the vicinity of the container body 31a, the degree of deterioration of the refrigerant can be easily determined on the spot.

また、上記油劣化判断装置,磨耗粉判断装置とは別に冷媒酸化判断装置を備えてもよい。この冷媒酸化判断装置は、冷媒の酸化の度合いによって色が変わるpH指示薬等の色素を容器本体31a(図1に示す)内の窓ガラス31bを介して見える位置に塗布し、その塗布された色素の色と判断表(図4(C)と同様)の色とを比較して冷媒の酸化の程度を判断する。この場合、HFC冷媒の分解生成物であるフッ酸やHCFC冷媒の分解生成物であるホスゲン等の有害物質の量を判断でき、その判断結果に基づいて必要に応じて作動媒体を交換することによって、有害物質による各部の劣化を防止でき、長期信頼性を維持することができる。また、上記容器本体31a近傍に判断表を設けることによって、冷媒の劣化の程度をその場で容易に判断することができる。   Further, a refrigerant oxidation determination device may be provided separately from the oil deterioration determination device and the wear powder determination device. This refrigerant oxidation determination device applies a dye such as a pH indicator whose color changes depending on the degree of oxidation of the refrigerant to a position that can be seen through the window glass 31b in the container main body 31a (shown in FIG. 1). And the color of the judgment table (similar to FIG. 4C) are compared to judge the degree of oxidation of the refrigerant. In this case, the amount of harmful substances such as hydrofluoric acid, which is a decomposition product of HFC refrigerant, and phosgene, which is the decomposition product of HCFC refrigerant, can be determined, and the working medium is replaced as necessary based on the determination result. , It can prevent deterioration of each part due to harmful substances and maintain long-term reliability. Further, by providing a judgment table in the vicinity of the container body 31a, the degree of deterioration of the refrigerant can be easily judged on the spot.

図1はこの発明の第1実施形態の冷凍装置の回路図である。FIG. 1 is a circuit diagram of a refrigerating apparatus according to a first embodiment of the present invention. 図2はこの発明の第2実施形態の冷凍装置の回路図である。FIG. 2 is a circuit diagram of a refrigeration apparatus according to a second embodiment of the present invention. 図3は上記冷凍装置の連絡配管に配設された油劣化判断装置の概略図である。FIG. 3 is a schematic view of an oil deterioration determination device arranged in the communication pipe of the refrigeration apparatus. 図4は簡易判断部用の判断表を示す図である。FIG. 4 is a diagram showing a judgment table for the simple judgment unit. 図5は上記判断表の貼り付け位置を示す図である。FIG. 5 is a diagram showing the pasting position of the judgment table.

符号の説明Explanation of symbols

1…圧縮機、2…四路切換弁、
3…室外熱交換器、4…電動膨張弁、
5…室外熱交換器、6…アキュームレータ、
7…制御装置、10…室外ユニット、
20…室内ユニット、21,24…閉鎖弁、
22,23…連絡配管、31,32…油劣化判断装置。
1 ... compressor, 2 ... four-way switching valve,
3 ... outdoor heat exchanger, 4 ... electric expansion valve,
5 ... Outdoor heat exchanger, 6 ... Accumulator,
7 ... Control device, 10 ... Outdoor unit,
20 ... indoor unit, 21, 24 ... shut-off valve,
22, 23 ... communication piping, 31, 32 ... oil deterioration judging device.

Claims (9)

圧縮機(1)の吐出側とガス閉鎖弁(24)との間または四路切換弁(2)とガス閉鎖弁(24)との間に配設され、冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて判断するための油劣化判断装置(31)を備えたことを特徴とする冷凍装置。   Between the discharge side of the compressor (1) and the gas shut-off valve (24) or between the four-way switching valve (2) and the gas shut-off valve (24), the degree of deterioration of the refrigerating machine oil is determined. A refrigeration apparatus comprising an oil deterioration determination device (31) for determining based on at least one of color, moisture content, degree of oxidation, or air content. ガス側連絡配管(23)に配設され、冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて判断するための油劣化判断装置(31)を備えたことを特徴とする冷凍装置。   An oil deterioration judgment device (23) disposed in the gas side communication pipe (23) for judging the degree of deterioration of the refrigeration oil based on at least one of oil color, moisture content, degree of oxidation or air content. 31) A refrigeration apparatus comprising the above. 請求項1または2に記載の冷凍装置において、
HFC系冷媒を用いたことを特徴とする冷凍装置。
The refrigeration apparatus according to claim 1 or 2,
A refrigeration apparatus using an HFC refrigerant.
請求項1または2に記載の冷凍装置において、
R32冷媒またはR32を少なくとも70重量%以上含む混合冷媒を用いたことを特徴とする冷凍装置。
The refrigeration apparatus according to claim 1 or 2,
A refrigerating apparatus using an R32 refrigerant or a mixed refrigerant containing at least 70% by weight of R32.
請求項1乃至4のいずれか1つに記載の冷凍装置において、
上記油劣化判断装置(31,32)に簡易判断部を設けたことを特徴とする冷凍装置。
The refrigeration apparatus according to any one of claims 1 to 4,
A refrigeration apparatus comprising a simple determination unit in the oil deterioration determination apparatus (31, 32).
圧縮機(1)の吐出側とガス閉鎖弁(24)との間または四路切換弁(2)とガス閉鎖弁(24)との間に、冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて判断するための油劣化判断装置(31)を設けて、冷凍機油の劣化を判断することを特徴とする冷凍機油の劣化判断方法。   Between the discharge side of the compressor (1) and the gas shut-off valve (24) or between the four-way switching valve (2) and the gas shut-off valve (24), the degree of deterioration of the refrigeration oil is determined by the color of the oil and the moisture. A method for judging deterioration of a refrigerating machine oil, comprising a device for judging oil deterioration (31) for judging based on at least one of a content rate, a degree of oxidation or an air content rate, and judging a deterioration of refrigerating machine oil . 冷凍機油の劣化の程度を油の色,水分含有率,酸化の度合いまたは空気含有率の少なくとも1つに基づいて判断するための油劣化判断装置(31)をガス側連絡配管(23)に設けて、冷凍機油の劣化を判断することを特徴とする冷凍機油の劣化判断方法。   An oil deterioration judgment device (31) for judging the degree of deterioration of refrigeration oil based on at least one of oil color, moisture content, degree of oxidation or air content is provided in the gas side connecting pipe (23). And determining the deterioration of the refrigerating machine oil. 請求項6または7に記載の冷凍機油の劣化判断方法において、
HFC系冷媒を用いたことを特徴とする冷凍機油の劣化判断方法。
In the method for judging deterioration of refrigerating machine oil according to claim 6 or 7,
A method for judging deterioration of refrigerating machine oil, characterized by using an HFC refrigerant.
請求項6または7に記載の冷凍機油の劣化判断方法において、
R32冷媒またはR32を少なくとも70重量%以上含む混合冷媒を用いたことを特徴とする冷凍機油の劣化判断方法。
In the method for judging deterioration of refrigerating machine oil according to claim 6 or 7,
A method for judging deterioration of refrigerating machine oil, wherein R32 refrigerant or a mixed refrigerant containing at least 70% by weight of R32 is used.
JP2005128210A 2005-04-26 2005-04-26 Refrigerating device and deterioration determination method of refrigerating machine oil Pending JP2005221231A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005128210A JP2005221231A (en) 2005-04-26 2005-04-26 Refrigerating device and deterioration determination method of refrigerating machine oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005128210A JP2005221231A (en) 2005-04-26 2005-04-26 Refrigerating device and deterioration determination method of refrigerating machine oil

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP2000034948A Division JP3704269B2 (en) 2000-02-14 2000-02-14 Refrigeration apparatus having oil deterioration judgment device

Publications (1)

Publication Number Publication Date
JP2005221231A true JP2005221231A (en) 2005-08-18

Family

ID=34997000

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005128210A Pending JP2005221231A (en) 2005-04-26 2005-04-26 Refrigerating device and deterioration determination method of refrigerating machine oil

Country Status (1)

Country Link
JP (1) JP2005221231A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017032185A (en) * 2015-07-30 2017-02-09 ダイキン工業株式会社 Refrigerating device
JPWO2015125253A1 (en) * 2014-02-20 2017-03-30 三菱電機株式会社 Scroll compressor and refrigeration cycle apparatus using the same
WO2018043430A1 (en) * 2016-08-29 2018-03-08 旭硝子株式会社 Heat cycle system

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2015125253A1 (en) * 2014-02-20 2017-03-30 三菱電機株式会社 Scroll compressor and refrigeration cycle apparatus using the same
JP2017032185A (en) * 2015-07-30 2017-02-09 ダイキン工業株式会社 Refrigerating device
US11060773B2 (en) 2015-07-30 2021-07-13 Daikin Industries, Ltd. Refrigerating device
WO2018043430A1 (en) * 2016-08-29 2018-03-08 旭硝子株式会社 Heat cycle system
JPWO2018043430A1 (en) * 2016-08-29 2019-06-27 Agc株式会社 Thermal cycle system
US11548267B2 (en) 2016-08-29 2023-01-10 AGC Inc. Heat cycle system

Similar Documents

Publication Publication Date Title
CN102066852B (en) Non-azeotropic refrigerant mixture and refrigeration cycle device
JP3109500B2 (en) Refrigeration equipment
JP5939828B2 (en) Heat pump cycle equipment
JP5780977B2 (en) Heat pump cycle equipment
EP2840335A1 (en) Refrigerating cycle device
JP3704269B2 (en) Refrigeration apparatus having oil deterioration judgment device
JP6079061B2 (en) Refrigeration equipment
AU2016225575B2 (en) Oil return circuit and oil return method for refrigerating cycle
CN110291338A (en) Conditioner
JP2016095130A (en) Heat pump cycle device
JP2010007998A (en) Indoor unit of air conditioner and air conditioner including it
WO2014068819A1 (en) Air conditioner
JP2009250554A (en) Refrigerating device
JP2005221231A (en) Refrigerating device and deterioration determination method of refrigerating machine oil
EP3591311B1 (en) Refrigeration cycle device
JP2008241065A (en) Refrigerating device and oil returning method of refrigerating device
EP3404345B1 (en) Refrigeration cycle device
CN111033154B (en) Air conditioner
JP5487831B2 (en) Leakage diagnosis method and leak diagnosis apparatus
WO2018181065A1 (en) Air conditioning device
JP4468222B2 (en) Refrigeration apparatus and air conditioner equipped with the same
JP2005049057A (en) Refrigerating cycle device
JP2010151388A (en) Air conditioning device
JPH08121888A (en) Refrigerating machine
JPH0933114A (en) Refrigerating device

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20061018

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20061024

A521 Written amendment

Effective date: 20061219

Free format text: JAPANESE INTERMEDIATE CODE: A523

A02 Decision of refusal

Effective date: 20070206

Free format text: JAPANESE INTERMEDIATE CODE: A02