JP2005193726A - Foaming duct - Google Patents
Foaming duct Download PDFInfo
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- JP2005193726A JP2005193726A JP2003435955A JP2003435955A JP2005193726A JP 2005193726 A JP2005193726 A JP 2005193726A JP 2003435955 A JP2003435955 A JP 2003435955A JP 2003435955 A JP2003435955 A JP 2003435955A JP 2005193726 A JP2005193726 A JP 2005193726A
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- Prior art keywords
- duct
- foaming
- foamed
- resin
- foam
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- 238000005187 foaming Methods 0.000 title claims abstract description 29
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 25
- 238000000071 blow moulding Methods 0.000 claims abstract description 18
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 9
- 239000011162 core material Substances 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 6
- 230000001737 promoting effect Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 239000002356 single layer Substances 0.000 claims description 2
- 239000006260 foam Substances 0.000 abstract description 24
- 238000000465 moulding Methods 0.000 abstract description 4
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 238000004378 air conditioning Methods 0.000 description 8
- 210000004027 cell Anatomy 0.000 description 7
- 239000004088 foaming agent Substances 0.000 description 7
- 239000010410 layer Substances 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 229910001873 dinitrogen Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 210000000497 foam cell Anatomy 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
Images
Landscapes
- Air-Conditioning For Vehicles (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
Abstract
Description
本発明は、主として自動車の空調用ダクトとして用いられる発泡ダクトであって、ブロー成形により樹脂を発泡させるとともに所要の形状に成形した発泡ダクトに関するものである。 The present invention relates to a foam duct mainly used as an air conditioning duct of an automobile, and relates to a foam duct formed by foaming a resin by blow molding and molding the resin into a required shape.
自動車の空調用ダクトは断熱性の高いことと、ダクトの表面に結露が生じないものであることが求められる。従来この要件を満たすために特開平11−99579号公報はダクトの外表面を断熱材で巻いたものを提案しており、また、特開平10−181334号公報はブロー成形樹脂に有機分解性の化学発泡剤を配合してブロー成形した発泡ダクトを提案しており、さらに特開昭63−236620号公報および特開平2003−39536公報は、発泡層に表皮層を設けた多層状のパリソンをブロー成形してなる発泡ダクトを提案している。
前掲の特開平11−99579号公報に記載されたダクトは、断熱効果有するものであるが、断熱材をダクトと一体化するために製造工程が増加することと、曲面状のダクト表面に断熱材を貼着するのが困難であるという問題点があった。また、前掲の特開平10−181334号公報に記載されているように、樹脂に化学発泡剤を配合してブロー成形すればダクトの管路自体が発泡して断熱性を有するダクトが得られる。しかしながら、従来の分解性の化学発泡剤を配合してブロー成形した発泡ダクトは、実際上多くの製造上の問題点があり、自動車用空調ダクトとして多用されるまでには至っていない。その理由を次に説明する。 The duct described in the above-mentioned Japanese Patent Application Laid-Open No. 11-99579 has a heat insulating effect. However, the manufacturing process is increased in order to integrate the heat insulating material with the duct, and the heat insulating material is formed on the curved duct surface. There was a problem that it was difficult to stick. Further, as described in the above-mentioned JP-A-10-181334, if a chemical foaming agent is blended into a resin and blow-molded, the duct line itself foams to obtain a duct having heat insulation properties. However, conventional foam ducts that are blow-molded with a degradable chemical foaming agent have many manufacturing problems in practice and have not yet been widely used as automotive air-conditioning ducts. The reason will be described next.
ポリプロピレン、ポリエチレン等のポリオレフィン系樹脂に重炭酸アンモニウム、重炭酸ソーダ等の無機剤やジニトソペンタメチレンテトラアミン、アソジカルボンアミド等の有機分解性化学発泡剤を添加した場合、温度の上昇にともない発泡したセルが膨張し、セルの膨張に従ってパリソンの伸びが低下し、ブロー成形性が低下するという問題があった。また、セルの膨張は金型のキャビティに接しないパリソンの内表面においてセルの破れ現象をきたし、所要の発泡倍率のものが得られないという問題を有していた。特に、管路の両端に接続口部を有し、エアの通過する管路が複雑な三次元形状に曲折したダクトにあっては、ブロー成形性の低下は重大な問題となる。そして、これらの理由により発泡ブロー成形されたダクトは実施上の商品化に多くの問題を抱えていた。 When an inorganic agent such as ammonium bicarbonate or sodium bicarbonate, or an organic degradable chemical foaming agent such as dinitosopentamethylenetetraamine or asodicarbonamide is added to a polyolefin resin such as polypropylene or polyethylene, the cell expands as the temperature rises. There is a problem that the expansion of the parison decreases as the cell expands, and the blow moldability decreases. Further, the expansion of the cell has a problem that the cell tears on the inner surface of the parison that does not contact the cavity of the mold, and the required expansion ratio cannot be obtained. In particular, in a duct having connection ports at both ends of a pipe and the pipe through which air passes is bent in a complicated three-dimensional shape, the deterioration of blow moldability becomes a serious problem. For these reasons, foam blow molded ducts have many problems in commercialization.
ところで、前掲の特開昭63−236620号公報または特開平2003−39536号公報に記載されているように、発泡層に表皮層を設けることにより、ブロー成形時に発泡した気泡の破壊を防止することができるとしても、表皮層を有するところから発泡層の発泡率が抑制されてしまい、高発泡率の発泡ダクトを得ることができないという問題があった。また、発泡剤として揮発性を利用した記載がある。本発明においては揮発性でない。常温で気体のガス(炭酸ガス、窒素ガス)を昇圧して超臨界状態で溶融樹脂に入れこみ、常圧にして発泡させるもので揮発性を利用したものとは異なる。揮発性発泡剤は燃え易い欠点がある。 By the way, as described in the above-mentioned JP-A-63-236620 or JP-A-2003-39536, by providing a skin layer on the foam layer, it is possible to prevent destruction of foamed bubbles during blow molding. Even if it is possible, the foaming rate of the foamed layer is suppressed from having the skin layer, and there is a problem that a foaming duct having a high foaming rate cannot be obtained. There is also a description using volatility as a foaming agent. In the present invention, it is not volatile. This is different from the one using volatility, in which gaseous gas (carbon dioxide gas, nitrogen gas) is pressurized at normal temperature, put into the molten resin in a supercritical state, and foamed at normal pressure. Volatile blowing agents have the disadvantage of being flammable.
一方、樹脂に発泡剤を配合せずに発泡樹脂製品を得る技術として、樹脂に窒素ガスなどのガスを吹き込んでブロー成形する方法が提案されている(特表2001−527106公報参照)。しかしながら、上記技術は60μm未満の微孔質の発泡セルを有するミルクボトル等の食品容器を製造する技術に関するものであって、本発明のごとき自動車用空調ダクトに応用する例は開示されていない。 On the other hand, as a technique for obtaining a foamed resin product without adding a foaming agent to the resin, a method of blow molding by blowing a gas such as nitrogen gas into the resin has been proposed (see Japanese Patent Application Publication No. 2001-527106). However, the above technique relates to a technique for producing a food container such as a milk bottle having a microporous foam cell of less than 60 μm, and an example of application to an air conditioning duct for automobiles as in the present invention is not disclosed.
そこで本発明は、このような従来の技術の状況に対応すべく、ブロー成形により樹脂を発泡させるとともに所要の形状に成形することができる発泡ダクトを提供することを目的とするものである。 Accordingly, an object of the present invention is to provide a foam duct that can foam a resin by blow molding and can be molded into a required shape in order to cope with such a state of the art.
上記目的を達成するための本発明の請求項1に係る発泡ダクトは、自動車用の空調装置においおて、両端に他の部材を嵌合する接続口部を備え、上記接続口部の間にはエアーの通過する管路が三次元形状に曲折したダクト本体を有し、上記接続口部およびダクト本体は物理発泡法により発泡させた単層のパリソンをブロー成形することにより発泡平均粒子径が100〜300μmの発泡セルで構成されていることを特徴とするものである。
In order to achieve the above object, a foam duct according to
また、本発明の請求項2に係る発泡ダクトは、請求項1の構成において、発泡樹脂はポリオレフィン系樹脂であり、その発泡倍率は2〜5倍で、230℃でのMTが5〜10gfMFR1〜5であることを特徴とするものである。
The foam duct according to
さらに、本発明の請求項3に係る発泡ダクトは、請求項2の構成において、ポリオレフィン系樹脂に発泡を促すための核材を2.5〜7%配合して、発泡した気泡の平均粒子径が100〜300μmとなるように発泡させ、かつ外周全てにバリを付けたことを特徴とするものである。
Furthermore, the foam duct according to claim 3 of the present invention is the composition of
本発明によれば、ブロー成形により樹脂を発泡させるとともに所要の形状に成形する発泡ダクトであっても、高発泡倍率の発泡樹脂で構成することができる。 According to this invention, even if it is a foaming duct which foams resin by blow molding and shape | molds in a required shape, it can be comprised with the foaming resin of a high expansion ratio.
図1は本発明の一実施の形態に係る発泡ダクトの斜視図、図2はそのブロー成形態様を示す断面図、図3は図2の状態から型締めした状態を示す断面図、図4は図3のA−A断面図である。 FIG. 1 is a perspective view of a foam duct according to an embodiment of the present invention, FIG. 2 is a cross-sectional view showing a blow molding aspect thereof, FIG. 3 is a cross-sectional view showing a state of clamping from the state of FIG. It is AA sectional drawing of FIG.
図1において、1は発泡ダクトであって自動車の空調ダクトを例示している。2はダクト部、3は接続口の吹込口、4は接続口の吹出口、5はバリ部である。この発泡ダクト1は、ブロー成形により樹脂を発泡させるとともに所要の形状に成形してなるものであって、高発泡倍率の発泡樹脂で構成されている。発泡ダクト1を構成する発泡樹脂はポリオレフィン系樹脂であり、その発泡倍率は2〜5倍で、230℃でのMTが5〜10gfMFR1〜5である。ポリオレフィン系樹脂には発泡を促すための核材を2.5〜7%配合して、ブロー成形時に発泡する気泡の平均粒子径が100〜300μmとなるように発泡させたものである。平均粒子径は、成形品をカットし、気泡部分の楕円断面のうち、平均的な大きさの楕円の長径とした。核材はタルク、シリカ、マイカ、炭酸カルシウム、珪酸カルシウム、硫酸バリウム等の微粒子であって、ブロー成形時に溶融樹脂に吹き込んだ窒素ガス等を付着させてその周囲に小気泡を生じさせる作用をする。
In FIG. 1,
図1に示す発泡ダクト1は、図2ないし図4に示す態様でブロー成形される。すなわち、6,6は一対の分割金型、7は押出ヘッド、8はパリソンであって、押出ヘッド7から押し出すパリソン8には核材が配合されており、かつ窒素ガスが吹き込まれている。9はバリであって図1に示すバリ部5となる部分である。
The
図2および図3に示すように、一対の分割金型6,6間にパリソン8を配置し、図3に示すように型締めしてブロー成形するが、ブロー成形時にはパリソン8に配合されている核材に付着した窒素ガスが膨張して小気泡を生じさせるので、成形体は小気泡による高発泡体となる。また図3にブロー用の吹き込みノズルがある。このため、図1に示すように複雑な形状の発泡ダクト1であっても、気泡の破壊を生じさせることなくブロー成形することができる。
2 and 3, the
ダクトについて図5に正面図、図6に側面図、図7に上面図を示す。図5、図6、図7に示すように、ダクト本体は3次元曲げと複雑な曲げになっている。また、このダクトの両端接続口は、嵌合係止部を持つために、従来のダクトより複雑な形状をしている。この形状でもブロー成形が可能となった。嵌合係止部の詳細は図8に示してある。本ダクトの嵌合係止部はメス側となっている。このような嵌合係止部であっても、気泡のつぶれ、また他より薄肉になることなく成形できる。 FIG. 5 is a front view, FIG. 6 is a side view, and FIG. 7 is a top view of the duct. As shown in FIGS. 5, 6, and 7, the duct body is subjected to three-dimensional bending and complicated bending. Moreover, since the both ends connection port of this duct has a fitting latching | locking part, it has a more complicated shape than the conventional duct. This shape also allowed blow molding. The details of the fitting locking portion are shown in FIG. The fitting locking portion of the duct is on the female side. Even such a fitting and locking portion can be molded without causing collapse of bubbles or becoming thinner than others.
なお、本発明において物理発泡とは、気体と液体が共存できる限界の温度および圧力(臨界点)を超えた状態(超臨界状態)で押出されて大気圧となる時点で微細なセルを成長させ発泡させるとともにブロー成形するものである。また、核材の添加は、圧力降下によって熱力学的に不安定となった状態を速やかに気泡核の発生へと移行させる手段として有効となる。本発明においては、従来のような化学発泡剤を使用する必要がない為、ブロー成形時のセルの発泡また潰れによる発泡倍率低下を抑制し、結露防止性に優れた自動車の空調ダクトを提供することができる。 In the present invention, physical foaming means that a fine cell is grown at the time when the pressure and the critical temperature at which gas and liquid can coexist are exceeded (supercritical state) and the pressure reaches the atmospheric pressure. It is foamed and blow molded. In addition, the addition of the core material is effective as a means for quickly shifting the state that becomes thermodynamically unstable due to the pressure drop to the generation of bubble nuclei. In the present invention, since it is not necessary to use a conventional chemical foaming agent, a reduction in foaming ratio due to foaming or crushing of cells during blow molding is suppressed, and an automobile air conditioning duct having excellent dew condensation prevention properties is provided. be able to.
本発明に係る発泡ダクトは、自動車の空調ダクトにとどまらず、各種冷暖房用のダクトとして汎用性にすぐれたものである。 The foam duct according to the present invention is not limited to an air conditioning duct of an automobile, but is excellent in versatility as a duct for various air conditioning.
1 発泡ダクト
2 ダクト部
3 吹込口
4 吹出口
5 バリ部
6,6 一対の分割金型
7 押出ヘッド
8 パリソン
9 バリ
DESCRIPTION OF
Claims (3)
Priority Applications (1)
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JP2003435955A JP4776879B2 (en) | 2003-12-26 | 2003-12-26 | Foam duct molding method |
Applications Claiming Priority (1)
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JP2003435955A JP4776879B2 (en) | 2003-12-26 | 2003-12-26 | Foam duct molding method |
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JP2005193726A true JP2005193726A (en) | 2005-07-21 |
JP4776879B2 JP4776879B2 (en) | 2011-09-21 |
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JP2003435955A Expired - Lifetime JP4776879B2 (en) | 2003-12-26 | 2003-12-26 | Foam duct molding method |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009166520A (en) * | 2008-01-10 | 2009-07-30 | Toyota Auto Body Co Ltd | Air-conditioning duct |
JP2011093517A (en) * | 2009-09-30 | 2011-05-12 | Kyoraku Co Ltd | Method for manufacturing air-conditioning duct, and air-conditioning dust |
JP2013063639A (en) * | 2011-08-31 | 2013-04-11 | Kyoraku Co Ltd | Tubular molded foam with plate-like part |
WO2015083447A1 (en) | 2013-12-03 | 2015-06-11 | 日産自動車株式会社 | Foam molded body, duct for air conditioner, and duct for vehicle air conditioner |
JP2018083477A (en) * | 2016-11-22 | 2018-05-31 | 日野自動車株式会社 | Duct structure of cool storage type cooler |
-
2003
- 2003-12-26 JP JP2003435955A patent/JP4776879B2/en not_active Expired - Lifetime
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009166520A (en) * | 2008-01-10 | 2009-07-30 | Toyota Auto Body Co Ltd | Air-conditioning duct |
JP2011093517A (en) * | 2009-09-30 | 2011-05-12 | Kyoraku Co Ltd | Method for manufacturing air-conditioning duct, and air-conditioning dust |
US8770232B2 (en) | 2009-09-30 | 2014-07-08 | Kyoraku Co., Ltd. | Method for manufacturing climate control duct, and climate control duct |
US9174402B2 (en) | 2009-09-30 | 2015-11-03 | Kyoraku Co., Ltd. | Method for manufacturing climate control duct, and climate control duct |
JP2013063639A (en) * | 2011-08-31 | 2013-04-11 | Kyoraku Co Ltd | Tubular molded foam with plate-like part |
EP2565011A3 (en) * | 2011-08-31 | 2014-03-26 | Kyoraku Co., Ltd. | Tubular molded foam with plate portion and method and apparatus for forming the same |
WO2015083447A1 (en) | 2013-12-03 | 2015-06-11 | 日産自動車株式会社 | Foam molded body, duct for air conditioner, and duct for vehicle air conditioner |
US10315491B2 (en) | 2013-12-03 | 2019-06-11 | Nissan Motor Co., Ltd. | Foam molded body, duct for air conditioner, and duct for vehicle air conditioner |
JP2018083477A (en) * | 2016-11-22 | 2018-05-31 | 日野自動車株式会社 | Duct structure of cool storage type cooler |
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Publication number | Publication date |
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JP4776879B2 (en) | 2011-09-21 |
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