JP2005189117A - Water wettability determination sheet and battery pack - Google Patents

Water wettability determination sheet and battery pack Download PDF

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JP2005189117A
JP2005189117A JP2003431495A JP2003431495A JP2005189117A JP 2005189117 A JP2005189117 A JP 2005189117A JP 2003431495 A JP2003431495 A JP 2003431495A JP 2003431495 A JP2003431495 A JP 2003431495A JP 2005189117 A JP2005189117 A JP 2005189117A
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sheet
water
wetness determination
battery pack
soluble ink
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JP4086776B2 (en
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Kazuyuki Kaneda
和之 金田
Minoru Aoyama
稔 青山
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Sanyo Electric Co Ltd
Sanyo GS Soft Energy Co Ltd
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Sanyo Electric Co Ltd
Sanyo GS Soft Energy Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/50Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature
    • H01M6/5044Cells or batteries structurally combined with cell condition indicating means
    • H01M6/505Cells combined with indicating means for external visualization of the condition, e.g. by change of colour or of light intensity
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/50Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature
    • H01M6/5044Cells or batteries structurally combined with cell condition indicating means

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a water wettability determination sheet easily controllable when applying a water-soluble ink, dispensing with a printing plate for applying the water-soluble ink so as to form a pattern, capable of suppressing increase of components for displaying information, and suppressing generation of oozing of the water-soluble ink caused by moisture in an adhesive, and a battery pack equipped with the water wettability determination sheet. <P>SOLUTION: In this water wettability determination sheet 4, oozing of the water-soluble ink 6 appears on the other surface 40b of the sheet 40, when the sheet 40 is wetted by water. The water-soluble ink 6 is applied on the whole surface of one surface 40a of the sheet 40. A character or a pattern is entered on the other surface 40b by a waterproof ink. An adhesive 41 is applied to the other surface 40b. In this battery pack, the water wettability determination sheet 4 is arranged so that the other surface 40b is faced to a window inside a case, and that one surface 40a is faced to the window outside the case. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、水没したか否かを判定する水濡れ判定シート、及びこの水濡れ判定シートを備えるパック電池に関する。   The present invention relates to a water wetness determination sheet for determining whether or not the water has been submerged, and a battery pack including the water wetness determination sheet.

携帯電話、携帯情報端末(以下、PDAという)等の携帯機器は、使用者の不注意により水没させる場合があり、この水没により、携帯機器の電源として用いられているパック電池の内部に水が浸入することがある。パック電池は、二次電池と、携帯機器の接点に接続するための端子と、端子を露出させつつ二次電池を覆うケースとを備えており、ケースの内部に水が浸入した状態で使用された場合には、内部に浸入した水により短絡を起こして故障又は性能劣化を招来することがある。   Mobile devices such as mobile phones and personal digital assistants (hereinafter referred to as PDAs) may be submerged inadvertently by the user, and this submersion causes water to enter inside the battery pack used as the power source of the mobile device. May penetrate. The battery pack includes a secondary battery, a terminal for connecting to a contact of a portable device, and a case that covers the secondary battery while exposing the terminal, and is used in a state where water has entered the case. In such a case, a short circuit may occur due to water that has entered the inside, leading to failure or performance degradation.

このように水没が原因で故障又は性能劣化を招来したパック電池は、完全に乾燥させた場合には、水没した痕跡が残り難いことから、例えば、修理に持ち込まれても故障又は性能劣化の原因の究明が非常に困難であることが多い。このため、携帯機器を水没させてパック電池の内部に水が浸入したことの特定を容易にするために、水濡れ判定シートを備えるパック電池がある(例えば、特許文献1参照。)。   In this way, the battery pack that has caused breakdown or performance degradation due to submergence is unlikely to leave traces of submersion when it is completely dried. Is often very difficult to investigate. For this reason, in order to make it easy to specify that water has entered the inside of the battery pack by submerging the portable device, there is a battery pack provided with a water wetness determination sheet (see, for example, Patent Document 1).

水濡れ判定シートは、例えば、水の浸透が可能なシートの一面に水玉模様をなすように水溶性インクを塗布したものであり、パック電池のケースの内側にてケースに設けられた窓にシートの一面が対向するように配される。また、水濡れ判定シートには、シートの一面にポリエステル製の略透明な防水シートを貼着したものもある。   For example, the water wetness determination sheet is obtained by applying water-soluble ink so as to form a polka dot pattern on one side of a sheet that can permeate water, and the sheet is provided on a window provided in the case inside the case of the battery pack. Are arranged so that one side faces each other. Some water wetness determination sheets have a substantially transparent waterproof sheet made of polyester attached to one side of the sheet.

このような水濡れ判定シートを備えることにより、ケースの内部に水が浸入した場合には、浸入した水がシートに付着して水溶性インクを滲ませるから、シートの一面に施された水玉模様が滲んで不鮮明になる。ケースの内部に水が浸入したパック電池を完全に乾燥させた場合には、シートは、水玉模様が滲んで不鮮明になった状態を保持して乾燥するから、水濡れ判定シートをケースの窓から視認することによりパック電池の内部に水が浸入したか否かが判定できる。
特開平11−144695号公報
By providing such a water wetness determination sheet, when water intrudes into the case, the infiltrated water adheres to the sheet and soaks water-soluble ink, so a polka dot pattern applied to one side of the sheet Becomes blurred and blurry. If the battery pack with water in the case is completely dried, the sheet will dry with the polka dot pattern smeared and blurred. By visually recognizing, it can be determined whether water has entered the inside of the battery pack.
Japanese Patent Laid-Open No. 11-144695

しかしながら、前述した水濡れ判定シートは、シートの一面に施された水玉模様に滲みがあるか否かにより、水に濡れたか否かの判定をするから、水に濡れる前の状態では、水玉模様に滲みがなく鮮明でなければならない。このため、シートの一面に水溶性インクを塗布するときに滲みが発生しないようにするための管理が複雑になる、又は保管時の水分を十分に抑える必要があるという問題があった。   However, since the water wetness determination sheet described above determines whether or not the water is wet depending on whether or not the polka dot pattern applied on one side of the sheet has bleeding, in the state before the water wets, There must be no blur and clear. For this reason, there has been a problem that management for preventing bleeding from occurring when applying water-soluble ink to one surface of the sheet is complicated, or that moisture during storage needs to be sufficiently suppressed.

また、水玉模様となるように水溶性インクをシートの一面に塗布するために、水玉模様を彫り込んだ印刷版が必要であり、水濡れ判定シートのコストを押し上げるという問題があった。   In addition, in order to apply water-soluble ink to one side of the sheet so as to form a polka dot pattern, a printing plate engraved with a polka dot pattern is necessary, which raises the problem of increasing the cost of the water wetness determination sheet.

また、パック電池の外側に文字、模様等の情報を表す場合に、シートの一面に文字、模様等の情報を記入し、ケースの窓から視認できるようにしても、シートの一面には、水溶性インクによる水玉模様が施されているから、文字、模様等の情報が確認し難い。このため、パック電池の外側に文字、模様等の情報を表す場合には、文字、模様等を記入したラベルをケースの外側に貼着しなければならず、部品点数が増加するという問題があった。   In addition, when displaying information such as characters and patterns on the outside of the battery pack, even if information such as characters and patterns is entered on one side of the sheet so that it can be viewed from the window of the case, the surface of the sheet is water-soluble. Since the polka dot pattern is made of the characteristic ink, it is difficult to confirm information such as characters and patterns. For this reason, when displaying information such as characters and patterns on the outside of the battery pack, a label on which the characters and patterns are written must be attached to the outside of the case, which increases the number of parts. It was.

さらに、防水シートをシートに貼着するため、又は水濡れ判定シートをパック電池のケースの窓に貼着するための接着剤をシートの一面に塗布するから、接着剤が吸収した空気中の水分により水溶性インクの水玉模様が徐々に滲み、シートが水に濡れていないにも拘わらず、水濡れしたと判定される場合があるという問題があった。従来は、この問題を避けるため、パック電池の外側から見える範囲に接着剤43を塗布しないようにしているため(図6参照)、部分的接着剤43にするための工程を必要とし、コストを押し上げる問題となっている。   Furthermore, since the adhesive for adhering the waterproof sheet to the sheet or for adhering the water wetness determination sheet to the window of the battery pack case is applied to one surface of the sheet, the moisture in the air absorbed by the adhesive As a result, the polka dot pattern of the water-soluble ink gradually bleeds, and there is a problem that it may be determined that the sheet is wet even though the sheet is not wet. Conventionally, in order to avoid this problem, the adhesive 43 is not applied in a range that can be seen from the outside of the battery pack (see FIG. 6). It is a problem to push up.

本発明は斯かる事情に鑑みてなされたものであり、水の浸透が可能であると共に、一面に水溶性インクが塗布されたシートを備え、該シートの他面を水濡れの判定面にできるように構成することにより、水溶性インクを塗布するときの管理が簡易な水濡れ判定シートを提供することを目的とする。   The present invention has been made in view of such circumstances, and is capable of permeating water, and includes a sheet coated with water-soluble ink on one side, and the other side of the sheet can be used as a water wetting determination surface. With this configuration, an object is to provide a water wetness determination sheet that can be easily managed when water-soluble ink is applied.

また、本発明は、印刷版が必要ないように水溶性インクを塗布することにより、コストを抑えることができる水濡れ判定シートを提供することを目的とする。   It is another object of the present invention to provide a water wetness determination sheet that can reduce costs by applying water-soluble ink so that a printing plate is not required.

また、本発明は、シートの他面に文字、模様等の情報を明確に表示できるようにすることにより、部品点数の増加を抑制することができる水濡れ判定シートを提供することを目的とする。   Another object of the present invention is to provide a water wetness determination sheet that can suppress an increase in the number of parts by making it possible to clearly display information such as characters and patterns on the other side of the sheet. .

また、本発明は、接着剤を塗布するシート面を、水溶性インクを施すシート面と異ならせることにより、接着剤が吸収した空気中の水分による水溶性インクの滲みの発生を抑制し、水濡れの判定が正確にできる水濡れ判定シートを提供することを目的とする。また、本発明は、水溶性インクを施すシート面と、接着剤を塗布するシート面とが同一ではないから、接着剤を部分的にする必要がなく、シート面の全面に接着剤を塗布することで、製作工程を簡易にしてコストを抑えた水濡れ判定シートを提供することを目的とする。   Further, the present invention suppresses occurrence of bleeding of water-soluble ink due to moisture in the air absorbed by the adhesive by making the sheet surface to which the adhesive is applied different from the sheet surface to which the water-soluble ink is applied. An object of the present invention is to provide a water wetness determination sheet capable of accurately determining wetness. In the present invention, since the sheet surface to which the water-soluble ink is applied and the sheet surface to which the adhesive is applied are not the same, it is not necessary to partially apply the adhesive, and the adhesive is applied to the entire surface of the sheet. Thus, an object of the present invention is to provide a water wetness determination sheet that simplifies the manufacturing process and reduces the cost.

さらに、本発明は、前述した水濡れ判定シートを備えることにより、ケースの内部に水が浸入したことを判定できると共に、生産性の向上等によりコストを抑えたパック電池を提供することを目的とする。   Furthermore, the present invention has an object of providing a battery pack that can determine that water has entered the case by providing the water wetness determination sheet described above, and can reduce costs by improving productivity. To do.

第1発明に係る水濡れ判定シートは、水の浸透が可能なシートの一面に水溶性インクが塗布された水濡れ判定シートにおいて、前記シートが水に濡れた場合に前記水溶性インクの滲みが前記シートの他面に現れるようになしてあることを特徴とする。   The water-wetting determination sheet according to the first aspect of the present invention is a water-wetting determination sheet in which water-soluble ink is applied to one surface of a water-permeable sheet, and the water-soluble ink bleeds when the sheet is wet. It is made to appear on the other surface of the sheet.

第1発明においては、シートに水が付着した場合、水は、一面に塗布された水溶性インクを滲ませつつシートに浸透し、シートの他面に水溶性インクの滲みを形成する。シートの他面には、水に濡れることにより水溶性インクの滲みが現れるから、水濡れの判定をする判定面とすることができる。   In the first aspect of the invention, when water adheres to the sheet, the water penetrates the sheet while bleeding the water-soluble ink applied on one surface, and forms water-soluble ink bleeding on the other surface of the sheet. On the other side of the sheet, since water-soluble ink appears when wet, it can be used as a determination surface for determining whether the water is wet.

第2発明に係る水濡れ判定シートは、第1発明において、前記シートの前記他面に文字又は模様を耐水性インクにより記入してあることを特徴とする。   The water wetness determination sheet according to the second invention is characterized in that, in the first invention, characters or patterns are written on the other surface of the sheet with water-resistant ink.

第2発明においては、シートの他面に文字又は模様を耐水性インクにて記入する。シートに水が浸透した場合でも、耐水性インクは滲まず、シートの他面に記入した文字又は模様を維持できる。   In the second invention, characters or patterns are written on the other side of the sheet with water-resistant ink. Even when water permeates the sheet, the water-resistant ink does not bleed and the characters or patterns written on the other side of the sheet can be maintained.

第3発明に係る水濡れ判定シートは、第1発明又は第2発明において、前記シートの前記他面に接着剤を塗布してあることを特徴とする。   The water wetness determination sheet according to the third invention is characterized in that, in the first invention or the second invention, an adhesive is applied to the other surface of the sheet.

第3発明においては、例えば、パック電池のケースに水濡れ判定シート自身を貼着するため、又はシートに防水シートを貼着するために、シートの他面に接着剤を塗布する。   In the third invention, for example, an adhesive is applied to the other surface of the sheet in order to stick the wetness determination sheet itself to the case of the battery pack, or in order to stick a waterproof sheet to the sheet.

第4発明に係るパック電池は、二次電池の外側を覆うケースに窓が設けられ、前記ケースの内側にて前記窓に対向するように水濡れ判定シートを設けてあるパック電池において、前記水濡れ判定シートは、第1発明乃至第3発明の何れかに記載された水濡れ判定シートであり、前記シートの前記他面を前記窓に対向させてあることを特徴とする。   A battery pack according to a fourth aspect of the present invention is directed to a battery pack in which a window is provided in a case that covers the outside of a secondary battery, and a water wetness determination sheet is provided inside the case so as to face the window. The wetness determination sheet is a water wetness determination sheet described in any one of the first to third inventions, wherein the other surface of the sheet is opposed to the window.

第4発明においては、第1発明乃至第3発明の何れかに記載された水濡れ判定シートを、シートの他面がケースに設けられた窓に対向するように配する。ケースの内部に浸入した水は、シートに浸透して水溶性インクを滲ませ、シートの他面に水溶性インクの滲みが現れる。   In the fourth invention, the water wetness determination sheet described in any one of the first invention to the third invention is arranged so that the other surface of the sheet faces a window provided in the case. The water that has entered the case penetrates the sheet and soaks the water-soluble ink, and the water-soluble ink appears on the other surface of the sheet.

第5発明に係るパック電池は、二次電池の外側を覆うケースに窓が設けられ、該窓に対向するように水濡れ判定シートを設けてあるパック電池において、前記水濡れ判定シートは、第1発明乃至第3発明の何れかに記載された水濡れ判定シートであり、前記ケースの外側にて前記シートの前記一面を前記窓に対向させてあり、前記シートの前記他面に略透明な防水シートを貼着してあることを特徴とする。   A battery pack according to a fifth aspect of the invention is a battery pack in which a window is provided in a case that covers the outside of the secondary battery, and a water wetness determination sheet is provided so as to face the window. The water wetness determination sheet according to any one of the first to third aspects, wherein the one surface of the sheet is opposed to the window outside the case, and is substantially transparent to the other surface of the sheet. A waterproof sheet is pasted.

第5発明においては、ケースの内部に浸入した水は、窓を経由してシートの一面に付着し、シートに浸透して水溶性インクを滲ませ、シートの他面に水溶性インクの滲みが現れる。なお、シートの他面側からの水濡れは、防水シートにより防止される。   In the fifth invention, the water that has entered the inside of the case adheres to one surface of the sheet through the window, permeates the sheet and soaks the water-soluble ink, and the water-soluble ink is smeared on the other surface of the sheet. appear. In addition, water wetting from the other surface side of the sheet is prevented by the waterproof sheet.

第1発明に係る水濡れ判定シートにおいては、水の浸透が可能なシートの一面に水溶性インクを塗布すると共に、シートが水に濡れた場合に水溶性インクの滲みがシートの他面に現れるようになすことで、シートの他面を水濡れの判定面にした。従って、水溶性インクを塗布したシートの一面は、判定面ではないから、シートの一面における水溶性インクの水濡れ前の滲みの有無は問題にならず、水溶性インクを塗布するときの管理を簡易にすることができる。   In the water wetting determination sheet according to the first aspect of the invention, water-soluble ink is applied to one surface of a sheet that can penetrate water, and bleeding of the water-soluble ink appears on the other surface of the sheet when the sheet gets wet with water. By doing so, the other surface of the sheet was used as a water wetting determination surface. Therefore, since the surface of the sheet coated with water-soluble ink is not a judgment surface, the presence or absence of bleeding of the water-soluble ink before wetting on the surface of the sheet does not matter, and management is performed when water-soluble ink is applied. It can be simplified.

また、第2発明に係る水濡れ判定シートにおいては、シートの他面に文字又は模様を耐水性インクにて記入するから、文字又は模様は、シートが水に濡れた場合でも滲まず維持することができる。従って、例えば、パック電池の外側に文字、模様等を記入する必要がある場合には、シートの他面に耐水性インクにて記入することにより、文字、模様等が記入されたラベルが不要になり部品点数の増加を抑制することができる。   Further, in the water wetness determination sheet according to the second invention, since the character or pattern is written with water-resistant ink on the other surface of the sheet, the character or pattern should be maintained without bleeding even when the sheet gets wet. Can do. Therefore, for example, when it is necessary to write characters, patterns, etc. on the outside of the battery pack, a label with characters, patterns, etc. made unnecessary by filling in the other side of the sheet with water-resistant ink. Therefore, the increase in the number of parts can be suppressed.

また、第3発明に係る水濡れ判定シートにおいては、シートの他面に接着剤を塗布するから、接着剤が吸収した空気中の水分により水溶性インクが徐々に滲むことがなくなり、水濡れの判定が正確にできる。   Further, in the water wetness determination sheet according to the third invention, since the adhesive is applied to the other surface of the sheet, the water-soluble ink does not gradually bleed due to moisture in the air absorbed by the adhesive. Judgment can be made accurately.

さらに、第4発明又は第5発明に係るパック電池においては、第1発明乃至第3発明の何れかに係る水濡れ判定シートを備えるから、ケースの内部に水が浸入したことを判定することができると共に、コストを抑えることができる。   Furthermore, in the battery pack according to the fourth or fifth invention, since the water wetness determination sheet according to any one of the first to third inventions is provided, it can be determined that water has entered the case. While being able to reduce costs.

以下、本発明をその実施の形態を示す図面に基づいて詳述する。図1は、本発明に係る水濡れ判定シートを備える本発明に係るパック電池の分解斜視図である。   Hereinafter, the present invention will be described in detail with reference to the drawings illustrating embodiments thereof. FIG. 1 is an exploded perspective view of a battery pack according to the present invention including a water wetness determination sheet according to the present invention.

図において1は、矩形の板状をなす二次電池であり、二次電池1の長手方向の一端部側には端子2,2,2が設けられ、二次電池1及び端子2,2,2は、直方体状をなす合成樹脂製のケース3に覆われている。ケース3は、皿状をなす2つのケース半体30,31により構成され、ケース半体30,31の周縁面34,34を互いに突き合わせるようにして溶着されている。ケース半体30は、端子2,2,2をケース3の外部に露出するために長手方向の一端部側にて端子2,2,2の位置に対応して形成された孔部32,32,32と、孔部32,32,32の近傍に形成された窓33とを備える。また、ケース半体30の内面には、窓33を閉鎖するように、防水シート5が貼着された水濡れ判定シート4が接着されている。   In the figure, reference numeral 1 denotes a secondary battery having a rectangular plate shape. Terminals 2, 2, and 2 are provided on one end side in the longitudinal direction of the secondary battery 1, and the secondary battery 1 and the terminals 2, 2, and 2 are provided. 2 is covered with a synthetic resin case 3 having a rectangular parallelepiped shape. The case 3 is composed of two case halves 30 and 31 having a dish shape, and is welded so that the peripheral surfaces 34 and 34 of the case halves 30 and 31 face each other. The case half 30 has holes 32, 32 formed corresponding to the positions of the terminals 2, 2, 2 on one end side in the longitudinal direction in order to expose the terminals 2, 2, 2 to the outside of the case 3. , 32 and a window 33 formed in the vicinity of the holes 32, 32, 32. In addition, a water wetness determination sheet 4 to which a waterproof sheet 5 is attached is adhered to the inner surface of the case half 30 so as to close the window 33.

図2は、防水シート5が貼着された水濡れ判定シート4の分解斜視図である。   FIG. 2 is an exploded perspective view of the water wetness determination sheet 4 to which the waterproof sheet 5 is attached.

水濡れ判定シート4は、水の浸透が可能な矩形のシート40の一面40aに水玉模様をなすように水溶性インク6を塗布し、シート40が水に濡れた場合には、水溶性インク6の滲みがシート40の他面40bに現れるようになしてある。シート40には、例えば、0.05mm〜0.2mmの厚みを有する上質紙が用いられる。   The water-wetting determination sheet 4 is formed by applying the water-soluble ink 6 so as to form a polka dot pattern on one surface 40a of the rectangular sheet 40 that can penetrate water, and when the sheet 40 gets wet with water, the water-soluble ink 6 This appears on the other surface 40b of the sheet 40. For the sheet 40, for example, high-quality paper having a thickness of 0.05 mm to 0.2 mm is used.

水濡れ判定シート4の他面40b側には、防水シート5が設けられている。防水シート5は、水濡れ判定シート4と略同一の大きさ及び形状に形成された合成樹脂製の略透明なシートであり、水濡れ判定シート4が他面40b側から水に濡れるのを防止する。防水シート5と水濡れ判定シート4との間には、水濡れ判定シート4の他面40bの全面に厚さが0.05mm〜0.06mmとなるように塗布された略透明な接着剤41が介され、防水シート5の水濡れ判定シート4側の反対側の面には、防水シート5及び水濡れ判定シート4をケース半体30の内面へ接着するための略透明な接着剤50が塗布されている。   On the other surface 40b side of the water wetness determination sheet 4, a waterproof sheet 5 is provided. The waterproof sheet 5 is a synthetic resin substantially transparent sheet formed in substantially the same size and shape as the water wetness determination sheet 4 and prevents the water wetness determination sheet 4 from getting wet from the other surface 40b side. To do. A substantially transparent adhesive 41 applied between the waterproof sheet 5 and the water wetness determination sheet 4 so as to have a thickness of 0.05 mm to 0.06 mm on the entire other surface 40 b of the water wetness determination sheet 4. The substantially transparent adhesive 50 for bonding the waterproof sheet 5 and the water wetness determination sheet 4 to the inner surface of the case half 30 is provided on the surface of the waterproof sheet 5 opposite to the water wetness determination sheet 4 side. It has been applied.

これらの水濡れ判定シート4及び防水シート5は、水溶性インク6による水玉模様が施された一面40aを下側として配された水濡れ判定シート4の上側にシート状をなすように加工された接着剤41を載せ、接着剤41の上側に防水シート5を載せ、防水シート5の上側に、窓33に対応する部分を切り欠いてシート状に加工された接着剤50を載せ、上側と下側とからプレスすることにより、水濡れ判定シート4、接着剤41、防水シート5及び接着剤50を接着して一体にしてある。   The water wetness determination sheet 4 and the waterproof sheet 5 were processed so as to form a sheet on the upper side of the water wetness determination sheet 4 disposed with the one surface 40a on which the water-soluble ink 6 was applied with a polka dot pattern as the lower side. The adhesive 41 is placed, the waterproof sheet 5 is placed on the upper side of the adhesive 41, and the adhesive 50 processed into a sheet shape by cutting away the portion corresponding to the window 33 is placed on the upper side of the waterproof sheet 5. By pressing from the side, the water wetness determination sheet 4, the adhesive 41, the waterproof sheet 5 and the adhesive 50 are bonded and integrated.

以上の構成により本発明に係るパック電池が水没し、例えば、孔部32,32,32からケース3の内部に水が浸入した場合には、ケース3の内部に浸入した水が水濡れ判定シート4に付着する。水濡れ判定シート4に付着した水は、水溶性インク6を滲ませつつ水濡れ判定シート4に浸透し、水溶性インク6の滲みが水濡れ判定シート4の他面40bに現れる。   With the above configuration, the battery pack according to the present invention is submerged. For example, when water enters the inside of the case 3 from the holes 32, 32, 32, the water that has entered the case 3 is wet. 4 adheres. The water adhering to the water wetness determination sheet 4 penetrates into the water wetness determination sheet 4 while bleeding the water soluble ink 6, and bleeding of the water soluble ink 6 appears on the other surface 40 b of the water wetness determination sheet 4.

本発明に係る水濡れ判定シート4は、水玉模様をなすように水溶性インク6をシート40の一面40aに塗布すると共に、シート40が水に濡れた場合に水溶性インク6の滲みがシート40の他面40bに現れるようになすことで、水濡れ判定シート4の他面40bを水濡れの判定面にした。従って、水濡れ判定シート4の一面40aに施された水溶性インク6による水玉模様について、水に濡れる前における滲みの有無は問題にならないから、水溶性インク6を塗布するときの管理を簡易にすることができる。   In the water wetness determination sheet 4 according to the present invention, the water-soluble ink 6 is applied to one surface 40a of the sheet 40 so as to form a polka dot pattern, and when the sheet 40 gets wet with water, bleeding of the water-soluble ink 6 occurs. By making it appear on the other surface 40b, the other surface 40b of the water wetness determination sheet 4 was made a water wetness determination surface. Accordingly, since the presence or absence of bleeding before wetting with water does not matter with respect to the polka dot pattern with the water-soluble ink 6 applied to the one surface 40a of the water-wetting determination sheet 4, the management when applying the water-soluble ink 6 is simplified. can do.

また、水溶性インク6により水玉模様を施した面と、防水シート5を貼着するための接着剤41を塗布した面とが異なるから、接着剤41が吸収した空気中の水分により水溶性インク6が徐々に滲むことがなく、水濡れ判定シート4が水に濡れていないにも拘わらず、水濡れしたと判定されることが防止できる。さらに、接着剤41の塗布部位を従来品のように限定する必要がなく、シート40の他面40bの全面に接着剤41を塗布することも可能なため、塗布作業の簡略化により生産性を向上することができる。   Further, since the surface on which the polka dot pattern is applied with the water-soluble ink 6 is different from the surface on which the adhesive 41 for applying the waterproof sheet 5 is applied, the water-soluble ink is absorbed by the moisture in the air absorbed by the adhesive 41. 6 does not gradually bleed, and it can be determined that the water wetness determination sheet 4 is determined to be wet even though the water wetness determination sheet 4 is not wetted with water. Furthermore, since it is not necessary to limit the application part of the adhesive 41 as in the conventional product and the adhesive 41 can be applied to the entire other surface 40b of the sheet 40, productivity can be improved by simplifying the application work. Can be improved.

以上、本発明に係る水濡れ判定シート4又はパック電池について、実施の形態に示した構成に基づいて説明したが、本発明に係る水濡れ判定シート4又はパック電池は、前述した実施の形態に示した構成に限らず、本発明の趣旨に逸脱しない範囲にて一部の構成を削除、変更又は追加した他の実施の形態として構成することも可能である。   As described above, the water wetting determination sheet 4 or the battery pack according to the present invention has been described based on the configuration shown in the embodiment. However, the water wetting determination sheet 4 or the battery pack according to the present invention is the same as the embodiment described above. The present invention is not limited to the illustrated configuration, and may be configured as another embodiment in which a part of the configuration is deleted, changed, or added without departing from the spirit of the present invention.

例えば、前述した実施の形態では、水濡れ判定シート4は、接着剤41、防水シート5及び接着剤50と一体にしたが、水濡れ判定シート4、接着剤41、防水シート5及び接着剤50を一体にする必要はなく、水濡れ判定シート4単体としてもよい。また、水濡れ判定シート4は、接着剤50を除き、防水シート5及び接着剤41と一体になった構成、又は接着剤41及び防水シート5を除き、シート40の他面40bに接着剤50が塗布された構成としてもよく、また、図3に示すように、互いの一面40a,40aが対向するように2つの水濡れ判定シート4,4を接着剤42にて接着し、水濡れ判定シート4,4の両側から水濡れの判定ができるように構成してもよい。   For example, in the embodiment described above, the water wetness determination sheet 4 is integrated with the adhesive 41, the waterproof sheet 5 and the adhesive 50, but the water wetness determination sheet 4, the adhesive 41, the waterproof sheet 5 and the adhesive 50 are integrated. Need not be integrated, and the water wetness determination sheet 4 alone may be used. Further, the water wetness determination sheet 4 is configured to be integrated with the waterproof sheet 5 and the adhesive 41 except for the adhesive 50, or the adhesive 50 on the other surface 40b of the sheet 40 except for the adhesive 41 and the waterproof sheet 5. Further, as shown in FIG. 3, the two water wetness determination sheets 4 and 4 are bonded with an adhesive 42 so that the one surfaces 40a and 40a face each other, and the water wetness determination is performed. You may comprise so that determination of water wetting can be performed from both sides of the sheets 4 and 4.

また、水溶性インク6は、シート40の一面40aに水玉模様をなすように塗布したが、水溶性インク6の塗布は、水玉模様に限らず、他の模様にしてもよい。また、シート40の一面40aの全面に水溶性インク6を塗布してもよく、水溶性インク6をシート40の一面40aの全面に塗布した場合には、模様をなすように水溶性インク6を塗布するための印刷版が不要となり、水濡れ判定シート4のコストを抑えることができる。   Further, the water-soluble ink 6 is applied so as to form a polka dot pattern on the one surface 40a of the sheet 40, but the application of the water-soluble ink 6 is not limited to the polka dot pattern and may be other patterns. Further, the water-soluble ink 6 may be applied to the entire surface 40a of the sheet 40. When the water-soluble ink 6 is applied to the entire surface 40a of the sheet 40, the water-soluble ink 6 is applied so as to form a pattern. A printing plate for application becomes unnecessary, and the cost of the water wetness determination sheet 4 can be suppressed.

また、シート40の厚みを0.05mm〜0.2mmとしたが、シート40の厚みは、0.05mm〜0.2mmに限らない。また、シート40を上質紙としたが、シート40は上質紙に限らず、他の種類の紙でもよく、また紙に限らず布でもよい。つまり、シート40は、水の浸透が可能なものであればよい。   Moreover, although the thickness of the sheet 40 is 0.05 mm to 0.2 mm, the thickness of the sheet 40 is not limited to 0.05 mm to 0.2 mm. Further, although the sheet 40 is a high-quality paper, the sheet 40 is not limited to a high-quality paper, but may be other types of paper, and is not limited to paper but may be a cloth. That is, the sheet 40 may be any sheet that can permeate water.

また、接着剤41を、水濡れ判定シート4の他面40bの全面に厚さが0.05mm〜0.06mmとなるように塗布したが、接着剤41を塗布する厚さは、0.05mm〜0.06mmに限らない。また、接着剤41を塗布する範囲は、水濡れ判定シート4の他面40bの全面に限らず、部分的でもよく、部分的に複数箇所としてもよい。なお、水濡れ判定シート4の他面40bの全面に接着剤41を塗布する場合には、一工程にて接着剤41の塗布ができるから、水濡れ判定シート4の他面40bの部分的な複数箇所に接着剤41を塗布する場合よりも工程の簡略化ができ、コストも抑えることができる。   In addition, the adhesive 41 is applied to the entire other surface 40b of the water wetness determination sheet 4 so that the thickness is 0.05 mm to 0.06 mm. The thickness of the adhesive 41 is 0.05 mm. It is not limited to .about.0.06 mm. Moreover, the range which apply | coats the adhesive agent 41 is not restricted to the whole surface of the other surface 40b of the water wetness determination sheet | seat 4, Partial may be sufficient, and it is good also as several partially. Note that when the adhesive 41 is applied to the entire other surface 40b of the water wetness determination sheet 4, the adhesive 41 can be applied in one step. The process can be simplified and the cost can be reduced as compared with the case where the adhesive 41 is applied to a plurality of locations.

さらに、ケース半体30に形成した窓33は、例えば、透明な合成樹脂板を嵌め合わせた構成としてもよい。つまり、窓33は、ケース3の内側に設けた水濡れ判定シート4をケース3の外側から視認できる構成であれば、開放してもよく、閉鎖してもよい。窓33に透明な合成樹脂板を嵌め合わせた場合には、水濡れ判定シート4は、ケース半体30の内面に接着する必要がなく、窓33に対向していれば、例えば、二次電池1の外面に接着してもよい。   Furthermore, the window 33 formed in the case half 30 may have a configuration in which a transparent synthetic resin plate is fitted, for example. That is, the window 33 may be opened or closed as long as the water wetness determination sheet 4 provided inside the case 3 can be viewed from the outside of the case 3. When a transparent synthetic resin plate is fitted to the window 33, the water wetness determination sheet 4 does not need to be adhered to the inner surface of the case half 30. 1 may be adhered to the outer surface.

図4は、本発明に係る水濡れ判定シート4の他の実施の形態を示した分解斜視図である。図に示したように、水濡れ判定シート4の他面40bには、耐水性インク7にて文字又は模様を記入してもよい。例えば、パック電池の製造ロットNOを記入することにより、製造ロットNOを表示するためのラベルを用いる必要がなくなり、部品点数の増加を抑制することができる。製造ロットNOは、耐水性インク7により水濡れ判定シート4の他面40bに記入するから、水濡れ判定シート4が水に濡れた場合でも、滲むことなく表示を維持できる。なお、その他の構成及び作用は、図2で示した実施の形態と同様のため、対応する構成部材に同一の参照符号を付し、その構成及び作用の説明を省略する。   FIG. 4 is an exploded perspective view showing another embodiment of the water wetness determination sheet 4 according to the present invention. As shown in the drawing, characters or patterns may be written with the water-resistant ink 7 on the other surface 40 b of the water wetness determination sheet 4. For example, by entering the manufacturing lot number of the battery pack, it is not necessary to use a label for displaying the manufacturing lot number, and an increase in the number of parts can be suppressed. Since the production lot number is written on the other surface 40b of the water wetness determination sheet 4 with the water-resistant ink 7, the display can be maintained without bleeding even when the water wetness determination sheet 4 gets wet. Since other configurations and operations are the same as those in the embodiment shown in FIG. 2, the same reference numerals are assigned to corresponding components, and descriptions of the configurations and operations are omitted.

図5は、本発明に係るパック電池の他の実施の形態を示した斜視図である。図に示したように、水濡れ判定シート4は、ケース3に設けられた窓33を閉鎖するように、しかも水濡れ判定シート4の一面40aが窓33に対向するようにケース3の外面に接着してもよい。水濡れ判定シート4をケース3の外面に接着することにより、水濡れ判定シート4のケース3の外側から視認できる部分が大きくなり、耐水性インク7にて文字又は模様を記載できる範囲も大きくなる。なお、その他の構成及び作用は、図1で示した実施の形態と同様のため、対応する構成部材に同一の参照符号を付し、その構成及び作用の説明を省略する。   FIG. 5 is a perspective view showing another embodiment of the battery pack according to the present invention. As shown in the figure, the water wetness determination sheet 4 is placed on the outer surface of the case 3 so as to close the window 33 provided in the case 3 and so that one surface 40 a of the water wetness determination sheet 4 faces the window 33. It may be glued. By adhering the water wetness determination sheet 4 to the outer surface of the case 3, the portion of the water wetness determination sheet 4 that can be seen from the outside of the case 3 is increased, and the range in which characters or patterns can be written with the water-resistant ink 7 is also increased. . Since other configurations and operations are the same as those in the embodiment shown in FIG. 1, the same reference numerals are assigned to corresponding components, and descriptions of the configurations and operations are omitted.

本発明に係る水濡れ判定シートを備える本発明に係るパック電池の分解斜視図である。1 is an exploded perspective view of a battery pack according to the present invention including a water wetness determination sheet according to the present invention. 防水シートが貼着された水濡れ判定シートの分解斜視図である。It is a disassembled perspective view of the water wetness determination sheet | seat with which the waterproof sheet was stuck. 本発明に係る水濡れ判定シートの他の実施の形態を示した分解斜視図である。It is the disassembled perspective view which showed other embodiment of the water wetness determination sheet | seat based on this invention. 本発明に係る水濡れ判定シートの他の実施の形態を示した分解斜視図である。It is the disassembled perspective view which showed other embodiment of the water wetness determination sheet | seat based on this invention. 本発明に係るパック電池の他の実施の形態を示した斜視図である。It is the perspective view which showed other embodiment of the battery pack which concerns on this invention. 従来の水濡れ判定シートを示した分解斜視図である。It is the disassembled perspective view which showed the conventional water wetness determination sheet | seat.

符号の説明Explanation of symbols

1 二次電池
3 ケース
4 水濡れ判定シート
5 防水シート
6 水溶性インク
7 耐水性インク
33 窓
40 シート
40a 一面
40b 他面
41 接着剤
DESCRIPTION OF SYMBOLS 1 Secondary battery 3 Case 4 Water wetness determination sheet 5 Waterproof sheet 6 Water-soluble ink 7 Water-resistant ink 33 Window 40 Sheet 40a One side 40b Other side 41 Adhesive

Claims (5)

水の浸透が可能なシートの一面に水溶性インクが塗布された水濡れ判定シートにおいて、
前記シートが水に濡れた場合に前記水溶性インクの滲みが前記シートの他面に現れるようになしてあることを特徴とする水濡れ判定シート。
In a water wetness determination sheet in which water-soluble ink is applied to one side of a sheet that can penetrate water,
A water wetness determination sheet, wherein the water-soluble ink bleeding appears on the other surface of the sheet when the sheet is wetted with water.
前記シートの前記他面に文字又は模様を耐水性インクにより記入してあることを特徴とする請求項1に記載の水濡れ判定シート。   The water wetness determination sheet according to claim 1, wherein characters or patterns are written on the other surface of the sheet with water-resistant ink. 前記シートの前記他面に接着剤を塗布してあることを特徴とする請求項1又は2に記載の水濡れ判定シート。   The water wetness determination sheet according to claim 1 or 2, wherein an adhesive is applied to the other surface of the sheet. 二次電池の外側を覆うケースに窓が設けられ、前記ケースの内側にて前記窓に対向するように水濡れ判定シートを設けてあるパック電池において、
前記水濡れ判定シートは、請求項1乃至3の何れかに記載された水濡れ判定シートであり、
前記シートの前記他面を前記窓に対向させてあることを特徴とするパック電池。
In the battery pack in which a window is provided in a case that covers the outside of the secondary battery, and a water wetness determination sheet is provided so as to face the window inside the case.
The water wetness determination sheet is the water wetness determination sheet according to any one of claims 1 to 3,
A battery pack, wherein the other surface of the sheet is opposed to the window.
二次電池の外側を覆うケースに窓が設けられ、該窓に対向するように水濡れ判定シートを設けてあるパック電池において、
前記水濡れ判定シートは、請求項1乃至3の何れかに記載された水濡れ判定シートであり、
前記ケースの外側にて前記シートの前記一面を前記窓に対向させてあり、
前記シートの前記他面に略透明な防水シートを貼着してあることを特徴とするパック電池。
In a battery pack in which a window is provided in a case covering the outside of the secondary battery, and a water wetness determination sheet is provided so as to face the window,
The water wetness determination sheet is the water wetness determination sheet according to any one of claims 1 to 3,
The one side of the sheet is opposed to the window on the outside of the case;
A battery pack, wherein a substantially transparent waterproof sheet is adhered to the other surface of the sheet.
JP2003431495A 2003-12-25 2003-12-25 Wetness determination sheet and battery pack Expired - Fee Related JP4086776B2 (en)

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EP2061105A1 (en) 2007-11-13 2009-05-20 Samsung SDI Co., Ltd. Rechargeable battery
JP2009224049A (en) * 2008-03-13 2009-10-01 Sanyo Electric Co Ltd Battery pack
JP2010040465A (en) * 2008-08-08 2010-02-18 Nec Tokin Corp Name plate and battery pack pasted with name plate
JP2013011654A (en) * 2011-06-28 2013-01-17 Toko Kogyo:Kk Water wetting sensing sheet

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2061105A1 (en) 2007-11-13 2009-05-20 Samsung SDI Co., Ltd. Rechargeable battery
US9236618B2 (en) 2007-11-13 2016-01-12 Samsung Sdi Co., Ltd. Rechargeable battery
JP2009224049A (en) * 2008-03-13 2009-10-01 Sanyo Electric Co Ltd Battery pack
JP2010040465A (en) * 2008-08-08 2010-02-18 Nec Tokin Corp Name plate and battery pack pasted with name plate
JP2013011654A (en) * 2011-06-28 2013-01-17 Toko Kogyo:Kk Water wetting sensing sheet

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