JP2005183375A - Fuel cell - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a compact fuel cell facilitated in heat self support by reducing a distance between cell stacks to intensively arrange cells. <P>SOLUTION: Cell stack bulk materials formed by arranging a plurality of rows of cell stacks 60a, 60b, 60c and 60d, which are respectively formed by arranging a plurality of solid electrolyte type fuel cells in a line with the predetermined interval, a gas manifold 58 provided with the cell stack bulk materials, a reformer 78 provided over the cell stacks 60a, 60b, 60c and 60d, and a reformed gas supplying tube for connecting the reformer 78 to the gas manifold 58 are provided inside a housing 2. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  The present invention relates to a fuel cell, and in particular, a fuel cell including a gas manifold in which a plurality of solid oxide fuel cells are provided in a housing, and a reformer that supplies reformed gas to the fuel cells. It is about.

  In recent years, various fuel cells in which a plurality of solid electrolyte fuel cells are accommodated in a housing have been proposed as next-generation energy. A solid electrolyte fuel cell is configured, for example, by sequentially forming a solid electrolyte and a fuel side electrode on the surface of an oxygen side electrode, and fuel (hydrogen) is flowed to the fuel side electrode side, and air is supplied to the oxygen side electrode side. Electricity is generated by flowing (oxygen).

Conventionally, one end of a solid oxide fuel cell is erected on a top plate of a gas manifold, a cell stack composed of a plurality of fuel cells is provided on the gas manifold, and a reformer is provided above the cell stack. A fuel cell is known (see Patent Document 1). Further, the applicant has filed an application for a fuel cell in which a plurality of cell stacks are provided in a gas manifold, and a reformer is provided above the plurality of cell stacks. In such a fuel cell, a reformed gas is supplied to a plurality of reformers through a reformed gas supply pipe, and a reformed gas is supplied from the reformer to a gas manifold through a reformed gas supply pipe. A reformed gas is supplied to the cell.
JP 2004-319420 A

  In a conventional fuel cell, a plurality of cell stacks are provided in the gas manifold, so the gas manifold becomes an obstacle, the distance between the cell stacks cannot be reduced, the distance between the cells is widened, and heat is easily dissipated. Therefore, there is a problem that it is difficult to maintain the temperature at which electric power can be generated. There is also a problem that miniaturization cannot be achieved. In addition, it is necessary to supply gas to each gas manifold, the piping is complicated, and the gas supply amount to each gas manifold becomes uneven, which may adversely affect the performance and durability of the fuel cell. It was.

  In addition, it is necessary to provide reformers above each of the plurality of cell stacks, and to supply the reformed gas to each of these reformers using pipes. Further, the reformed gas is supplied from each reformer. There is a problem in that it is necessary to supply each gas manifold using pipes, and the number of pipes is large, miniaturization cannot be achieved, and it is complicated. Further, since the reformed gas supply pipe and the reformed gas supply pipe are provided, the amount of gas supplied from the respective reformed gas supply pipes to the respective reformers, and the respective reformers from the respective reformers. There is a possibility that the amount of gas supplied to the gas manifold may be non-uniform, which may adversely affect the performance and durability of the fuel cell.

  An object of the present invention is to provide a fuel cell that can be easily maintained at a power generation temperature by reducing the distance between cell stacks, and that can achieve miniaturization with a simple structure and good durability. .

  Another object of the present invention is to provide a fuel cell with reduced power generation performance and durability that can reduce the number of pipes connected to the reformer and achieve a reduction in size with a simple structure.

  A fuel cell according to the present invention includes a cell stack assembly in which a plurality of solid oxide fuel cell cells are arranged in a row at a predetermined interval in a housing, and a plurality of rows of cell stack assemblies are provided. A gas manifold provided with a cell stack assembly, a reformer provided above the cell stack, and a reformed gas supply pipe connecting the plurality of reformers and the gas manifold. Features.

  In such a fuel cell, since the cell stack assembly is provided in one gas manifold, when the cell stack assembly including a plurality of cell stacks is provided in the gas manifold, the interval between the cell stacks is reduced, and the cells are arranged. The density can be increased, the power generation temperature can be easily maintained, and the size can be reduced. Further, in such a fuel cell, the reformed gas that has been reformed by supplying the gas to be reformed to each of the plurality of reformers is collectively supplied to the gas manifold and supplied into the fuel cell. Since there is no need to divide the fuel gas into multiple gas manifolds, the amount of fuel gas supplied to the gas manifold will not be uneven, which will adversely affect the performance and durability of the fuel cell. Can be reduced.

  Further, the fuel cell of the present invention includes a plurality of cell stacks in which a plurality of solid electrolyte fuel cell cells are arranged in a row at a predetermined interval in a housing, and a gas manifold provided with each of the plurality of cell stacks. A reformer provided above the plurality of cell stacks for supplying reformed gas to the plurality of cell stacks, and a reformed gas supply pipe connecting the reformer and the plurality of gas manifolds. It is characterized by doing.

  In such a fuel cell, there is one reformer provided above the plurality of cell stacks, and the reformed gas that is reformed by supplying the reformed gas to the reformer is supplied to the plurality of gas manifolds. It can be branched and supplied and supplied into the fuel cell. In addition, since it is not necessary to divide and supply the gas to be reformed to the reformer, it is possible to simplify the means for supplying the gas to be reformed, for example, piping, and to reduce the supply amount nonuniformity caused by branching the piping. It can be eliminated, and adverse effects on the performance and durability of the fuel cell can be reduced.

  Furthermore, the fuel cell of the present invention includes a cell stack assembly in which a plurality of solid oxide fuel cell cells are arranged in a row at predetermined intervals in a housing, and a cell stack assembly in which a plurality of rows are arranged. A gas manifold provided with the cell stack assembly, a reformer provided above the cell stack assembly for supplying a reformed gas to the gas manifold, and connecting the reformer and the gas manifold. And a reformed gas supply pipe.

  In such a fuel cell, there is one reformer provided above the cell stack assembly, and it is not necessary to divide and supply the reformed gas to the reformer. For example, the piping can be simplified, and the nonuniformity of the supply amount caused by branching the piping can be eliminated. In addition, since the cell stack assembly is provided in one gas manifold, when the cell stack assembly including a plurality of cell stacks is provided in the gas manifold, the interval between the cell stacks can be narrowed to increase the cell arrangement density. In addition, the power generation temperature can be easily maintained and the size can be reduced. In such a fuel cell, the reformed gas is supplied to the reformer by supplying the reformed gas to the reformer, and then supplied to the fuel cell.

  Furthermore, the fuel cell of the present invention is characterized in that the widths of the gas manifold, the reformer, the reformed gas supply pipe, and the reformed gas supply pipe are substantially equal. In such a fuel cell, the gas to be reformed flows in the reformed gas supply pipe having a hollow flat plate shape, flows into the reformer having substantially the same width, flows almost uniformly between the catalysts in the reformer, and is hollow. The plate-like reformed gas supply pipes flow in a substantially equal distribution and flow into the gas manifold with a substantially equal distribution and flow rate, so that the amount of reformed gas supplied to the fuel cells can be substantially equal.

  The fuel cell of the present invention includes a plurality of cell stack assemblies each having two cell stack columns arranged in rows, a reformer provided above the plurality of cell stack assemblies, and the plurality of sets. A reformed gas is supplied to the cell stack assembly from a reformer thereabove. In such a fuel cell, air introduction means can be disposed between the plurality of cell stack assemblies, and air can be sufficiently supplied from both sides to the fuel cells of the two rows of cell stacks.

  Furthermore, the fuel cell of the present invention is characterized in that the reformed gas supply pipe has a hollow flat plate shape. In such a fuel cell, the reformed gas can be supplied almost uniformly to the gas manifold, and there is no unevenness in the supply of the reformed gas to the fuel cell.

  The fuel cell of the present invention is characterized in that the reformed gas supply pipe has a hollow flat plate shape. In such a fuel cell, the gas to be reformed can be supplied almost uniformly to the reformer, and there is no unevenness in the supply of the gas to be reformed to the reformer.

  Furthermore, the fuel cell of the present invention is characterized in that the reformer has a box shape with a low profile in the upward direction of the fuel cell. Such a fuel cell can be sufficiently heated by the combustion gas that burns above the fuel cell.

  The fuel cell of the present invention is characterized in that the gas manifold is in the shape of a box with a low profile in the standing direction of the fuel cell. In such a fuel cell, since the volume of the manifold is reduced, the volume of the entire power generation chamber is also reduced, which can be advantageous in terms of heat self-support.

  Furthermore, the fuel cell of the present invention is characterized in that an air introduction pipe is disposed between the cell stack assemblies. In such a fuel cell, the air in the air introduction pipe is heated in the combustion section at the top of the cell, so that the air can be efficiently preheated.

  The fuel cell of the present invention will be described in further detail below with reference to the accompanying drawings. Referring to FIGS. 1 and 2, the illustrated fuel cell includes a substantially rectangular parallelepiped housing 2. The six wall surfaces of the housing 2 are heat insulating walls formed of an appropriate heat insulating material, that is, an upper heat insulating wall 4, a lower heat insulating wall 6, a right heat insulating wall 8, a left heat insulating wall 10, and a front heat insulating wall (not shown). ) And a rear heat insulating wall (not shown). A power generation / combustion chamber 12 is defined in the housing 2.

  The front heat insulation wall and / or the rear heat insulation wall are detachably or detachably mounted, and the power generation / combustion chamber 12 can be accessed by detaching or opening the front heat insulation wall and / or the rear heat insulation wall. If desired, an outer wall, which may be made of a metal plate, can be disposed on the outer surface of each heat insulating wall.

  A lower gas chamber 14 is disposed at the lower end in the housing 2, and an upper gas chamber 16 is disposed at the upper end. The lower gas chamber 14 is defined in a rectangular parallelepiped case 15 having a relatively small vertical dimension, and the upper gas chamber 16 is similarly defined in a rectangular parallelepiped case 17 having a relatively small vertical dimension. A communication gas chamber 18 extending in the vertical direction is disposed on both the left and right sides in the housing 2. The communication gas chamber 18 is defined in a rectangular parallelepiped case 19 having a relatively small size in the lateral direction (left-right direction in FIG. 1).

  Three communication cylinders 20 are attached to the upper surface of each communication gas chamber 18 at intervals in the front-rear direction, and each of the communication gas chambers 18 is provided on both sides of the lower surface of the upper gas chamber 16 via the communication cylinder 20. It communicates with the department. The inner sides of the lower ends of the communication gas chambers 18 are directly connected to both side surfaces of the lower gas chamber 14.

  Accordingly, both side portions of the upper gas chamber 16 are communicated with both side portions of the lower gas chamber 14 via the communication gas chamber 18. On the upper surface of the lower gas chamber 14, there is disposed a hollow gas ejection plate 22 that protrudes upward at intervals in the lateral direction (left-right direction in FIG. 1). The lower end of the gas ejection plate 22 communicates with the lower gas chamber 14, and a gas ejection hole (not shown) is formed in the upper part.

  A heat exchanger 24 having a flat plate shape as a whole is disposed on both sides of the housing 2, more specifically, inside the right heat insulating wall 8 and inside the left heat insulating wall 10. Each of the heat exchangers 24 is constituted by a case 26 having a hollow flat plate shape extending substantially vertically.

  A partition plate 28 located in the middle in the lateral direction is disposed in the case 26, and the inside of the case 26 is partitioned into a discharge path 30 positioned on the inner side and an inflow path 32 positioned on the outer side. Five partition walls 34 and 36 are arranged in the discharge path 30 at intervals in the vertical direction. More specifically, in the discharge passage 30, the front edge is located rearwardly away from the front wall (not shown) of the case 26, but the rear edge is the rear wall (not shown) of the case 26. And a partition wall 36 whose front edge is connected to the front wall of the case 26 but whose rear edge is spaced forward from the rear wall of the case 26. Are alternately arranged, and thus the combustion gas discharge passage 30 is zigzag-shaped. The combustion gas discharge passage 30 may have a form other than the zigzag flow passage if desired.

  Similarly, the five partition walls 38 and 40, that is, the front edges thereof are also spaced apart from the front wall (not shown) of the case 26 in the inflow path 32 with a space in the vertical direction. The rear wall is connected to the rear wall (not shown) of the case 26, and the front edge of the partition wall 38 is connected to the front wall of the case 26. The partition walls 40 spaced apart from the front are alternately arranged, and thus the inflow passage 32 is also zigzag-shaped. Note that the inflow channel 32 may have a form other than the zigzag type if desired.

  A discharge opening 42 is formed at the upper end of the inner wall of the case 26, and the discharge path 30 is communicated with the power generation / combustion chamber 12 through the discharge opening 42. In the illustrated embodiment, heat insulating members 44 and 46 are disposed between each of the heat exchangers 24 and the communication gas chamber 18 and on the inner surface of the communication gas chamber 18. The upper end of the exhaust gas is positioned substantially at the same level as or slightly below the lower edge of the discharge opening 42, and the discharge opening 42 is left above the heat insulating members 44 and 46 and the communication gas chamber 18. Is connected to the power generation / combustion chamber 12 through a space between the three communication cylinders 20 disposed at the upper end.

  An inflow opening 48 is formed on the outer side of the upper wall of the case 26, and the inflow path 32 is communicated with the upper gas chamber 16 through the inflow opening 48. A double cylinder 50 (only the upper end portion thereof is shown in FIG. 1) extending in the vertical direction is disposed behind each of the heat exchangers 24. The double cylinder 50 is an outer cylinder. The member 52 and the inner cylinder member 54 are configured. The lower end of the discharge path 30 is connected to the lower end of the discharge path defined between the outer cylinder member 52 and the inner cylinder member 54, and the lower end of the inflow path 32 is defined in the inner cylinder member 54. Connected to the inflow channel.

  Thus, the configuration of the fuel cell assembly shown in the drawing is substantially the same as the fuel cell assembly disclosed in the specification and drawings of Japanese Patent Application No. 2003-295790 filed by the present applicant. Therefore, the details of the configuration described above are left to the specification and drawings of Japanese Patent Application No. 2003-295790, and the description thereof is omitted in this specification.

  Four cell stacks 60a, 60b, 60c and 60d are arranged on the upper surface of the lower gas chamber 14 described above. These cell stacks 60a, 60b, 60c, and 60d are arranged in parallel in four rows at a predetermined interval to form a cell stack aggregate. 5 together with FIGS. 1 and 2, the cell stack 60a is erected on one fuel gas manifold 58 having a rectangular parallelepiped shape extending in the front-rear direction (direction perpendicular to the paper surface in FIG. 1). Is provided.

  Cell stacks 60a, 60b, 60c, and 60d are mounted on the upper surface of the fuel gas manifold 58 that defines the fuel gas chamber 59. As shown in FIG. 1, the cell stacks 60 a, 60 b, 60 c, and 60 d have a plurality of plate-like and column-like upright cells 62 that are elongated in the vertical direction, arranged in tandem in the longitudinal direction of the fuel gas manifold 58 (that is, the front-rear direction) These cell stacks 60a, 60b, 60c and 60d are arranged in a matrix at a predetermined interval. The arrangement direction of the fuel cells 62 and the arrangement direction of the cell stacks 60a, 60b, 60c, and 60d are orthogonal to each other.

  In other words, in one fuel gas manifold 58, cell stacks 60a, 60b, 60c and 60d in which cells 62 are arranged in a line at a predetermined interval are arranged so as to form a matrix at a predetermined interval of four columns. ing.

  Each cell 62 includes an electrode support substrate 64, a fuel electrode layer 66 as an inner electrode layer, a solid electrolyte layer 68, an oxygen electrode layer 70 as an outer electrode layer, and an interconnector 72, as clearly shown in FIG. It is configured.

  The electrode support substrate 64 is a plate-like piece that is elongated in the vertical direction, and has both flat surfaces and both sides of a semicircular shape. The electrode support substrate 64 is formed with a plurality (six in the illustrated example) of fuel gas passages 74 penetrating the electrode support substrate 64 in the vertical direction. The lower end of the cell 62 is joined to the fuel gas manifold 58 by, for example, a sealing material having excellent heat resistance, as will be described later.

  A plurality of slits (not shown) extending in the left-right direction at intervals in the direction perpendicular to the paper surface in FIG. 1 are formed in the upper wall of the fuel gas manifold 58. A fuel gas passage 74 formed in each of the slits is communicated with each of the slits, and thus with the fuel gas chamber 59.

  The interconnector 72 is disposed on one side of the electrode support substrate 64 (upper surface in the cell stack 60a in FIG. 5). The fuel electrode layer 66 is disposed on the other surface (the lower surface in the cell stack 60a of FIG. 5) and both side surfaces of the electrode support substrate 64, and both ends thereof are joined to both ends of the interconnector 72. The solid electrolyte layer 68 is disposed so as to cover the entire fuel electrode layer 66, and both ends thereof are joined to both ends of the interconnector 72. The oxygen electrode layer 70 is disposed on the main part of the solid electrolyte layer 68, that is, on the portion covering the other surface of the electrode support substrate 64, and is positioned to face the interconnector 72 with the electrode support substrate plate 64 interposed therebetween. Yes.

  A current collecting member 76 is disposed between adjacent cells 62 in the cell stack 60a, and connects the interconnector 72 of one cell 62 and the oxygen electrode layer 70 of the other cell 62. Current collecting members 76 are disposed on both ends of the cell stack 60a, that is, on one side and the other side of the cell 62 positioned at the upper end and the lower end in FIG. Electric power extraction means (not shown) is connected to the current collecting members 76 located at both ends of the cell stack 60a, and the electric power extraction means is the front wall (not shown) and / or the rear wall of the housing 2. It extends outside the housing 2 (not shown). If desired, the cell stacks 60a, 60b, 60c and 60d are connected in series with each other by appropriate connection means instead of disposing the power extraction means in each of the cell stacks 60a, 60b, 60c and 60d. Common power extraction means may be provided for the cell stacks 60a, 60b, 60c and 60d.

  More specifically about the cell 62, the electrode support substrate 64 is gas permeable to allow fuel gas to permeate to the anode layer 66, and is also conductive to collect current through the interconnector 72. Can be formed from a porous conductive ceramic (or cermet) that satisfies such requirements.

  In order to manufacture the electrode support substrate 64 by co-firing with the fuel electrode layer 66 and / or the solid electrolyte layer 68, it is preferable to form the electrode support substrate 64 from an iron group metal component and a specific rare earth oxide. In order to provide the required gas permeability, it is preferred that the open porosity is in the range of 30% or more, in particular 35 to 50%, and the conductivity is also 300 S / cm or more, in particular 440 S / cm or more. Is preferred.

The fuel electrode layer 66 can be formed of a porous conductive ceramic, for example, ZrO ₂ (referred to as stabilized zirconia) in which a rare earth element is dissolved, and Ni and / or NiO.

The solid electrolyte layer 68 has a function as an electrolyte that bridges electrons between the electrodes, and at the same time has a gas barrier property to prevent leakage between the fuel gas and the oxygen-containing gas. It is necessary and is usually formed from ZrO ₂ in which ₃ to 15 mol% of a rare earth element is dissolved.

The oxygen electrode layer 70 can be formed of a conductive ceramic made of a so-called ABO ₃ type perovskite oxide. The oxygen electrode layer 70 is required to have gas permeability, and the open porosity is preferably 20% or more, particularly preferably in the range of 30 to 50%.

Although the interconnector 72 can be formed from a conductive ceramic, it needs to have reduction resistance and oxidation resistance because of contact with a fuel gas that may be hydrogen gas and an oxygen-containing gas that may be air. In addition, a lanthanum chromite perovskite oxide (LaCrO ₃ oxide) is preferably used. The interconnector 72 must be dense to prevent leakage of fuel gas passing through the fuel gas passage 74 formed in the electrode support substrate 64 and oxygen-containing gas flowing outside the electrode support substrate 64, and 93% As described above, it is particularly desirable to have a relative density of 95% or more.

  The current collecting member 76 can be composed of a member having an appropriate shape formed of a metal or alloy having elasticity, or a member obtained by adding a required surface treatment to a felt made of metal fiber or alloy fiber.

  1 to 3 and 5, the fuel cell of the present invention is a reforming case having a rectangular shape extending in the front-rear direction above the cell stacks 60a, 60b, 60c and 60d. 78 is also provided. One end, that is, the upper end of a reformed fuel gas hollow plate-like fuel gas supply pipe 80 is connected to the side surface of the front end portion of the reforming case 78.

  The fuel gas supply pipe 80 extends downward, then curves and extends rearward, and the other end of the fuel gas supply pipe 80 is connected to the front surface of the fuel gas manifold 58. One end of a to-be-reformed gas supply pipe 82 to be reformed is connected to the rear surface of the reforming case 78. The to-be-reformed gas supply pipe 82 extends downward from the reforming case, and extends under the housing 2 to the outside of the housing 2. The widths of the fuel gas supply pipe 80 and the reformed gas supply pipe 82 are substantially equal to the widths of the gas manifold 58 and the reforming case 78. In particular, it is desirable that the widths of the internal spaces of the fuel gas supply pipe 80 and the reformed gas supply pipe 82 are substantially equal to the widths of the internal spaces of the gas manifold 58 and the reforming case 78.

  The to-be-reformed gas supply pipe 82 is connected to a to-be-reformed gas supply source (not shown) which may be a hydrocarbon gas such as city gas, and is connected to the reforming case 78 through the to-be-reformed gas supply pipe 82. A gas to be reformed is supplied. An appropriate reforming catalyst for reforming the fuel gas into a hydrogen-rich fuel gas is accommodated in the reforming case 78.

  In the illustrated embodiment, the reforming case 78 is connected to the fuel gas manifold 58 via the fuel gas supply pipe 80 and is thereby held in a required position.

  Each of the cell stacks 60a, 60b, 60c and 60d is located on the upper surface of the case 15 which defines the lower gas chamber 14 between the gas injection plates 22, as will be clearly understood by referring to FIGS. It is placed and fixed in place by appropriate fixing means (not shown) such as a bolt.

  In the fuel cell assembly as described above, the gas to be reformed is supplied to the reforming case 78 through the gas to be reformed supply pipe 82 and reformed into a hydrogen-rich fuel gas in the reforming case 78. Thereafter, the fuel gas is supplied to the fuel gas chamber 59 defined in the fuel gas manifold 58 through the fuel gas supply pipe 80, and then supplied to the cell stacks 60a, 60b, 60c and 60d.

  On the other hand, oxygen-containing gas, which may be air, is supplied to the inflow path 32 of the heat exchanger 24 through the inflow path defined in the inner cylinder member 54 of the double cylinder 50, and then the upper gas chamber 16 and the communication gas chamber 18. The gas is supplied to the lower gas chamber 14 through the gas injection plate 22 and is injected toward the cell stacks 60a, 60b, 60c and 60d from the injection holes of the gas injection plate 22.

In each of the cell stacks 60a, 60b, 60c and 60d, at the oxygen electrode,
1 / 2O ₂ + 2e ⁻ → O ²⁻ (solid electrolyte)
The electrode reaction of
O ²⁻ (solid electrolyte) + H ₂ → H ₂ O + 2e ⁻
The electrode reaction is generated and power is generated.

  The fuel gas and oxygen-containing gas that have flowed upward from the cell stacks 60a, 60b, 60c and 60d without being used for power generation are igniting means (not shown) disposed in the power generation / combustion chamber 12 at the time of startup. ) Is ignited and burned. As is well known, the temperature in the power generation / combustion chamber 12 becomes high, for example, about 1000 ° C. due to power generation in the cell stacks 60a, 60b, 60c and 60d, and also due to combustion of fuel gas and oxygen-containing gas. . The reforming case 78 is disposed in the power generation / combustion chamber 12 and is positioned immediately above the cell stack 60, and is directly heated by the combustion flame, and thus is generated in the power generation / combustion chamber 12. The high temperature is effectively used for reforming the gas to be reformed.

  The combustion gas generated in the power generation / combustion chamber 12 flows into the discharge passage 30 from the discharge opening 42 formed in the heat exchanger 24, and flows through the discharge passage 30 extending in a zigzag shape. 50 is discharged through a discharge passage defined between the outer cylinder member 52 and the inner cylinder member 54. When the combustion gas flows through the discharge path in the double cylinder 50, the oxygen-containing gas flows through the inflow path in the double cylinder 50, and heat exchange is performed between the combustion gas and the oxygen-containing gas.

  In addition, when the combustion gas is caused to flow in the exhaust passage 30 of the heat exchanger 24 in a zigzag manner, the oxygen-containing gas is caused to flow in the inflow passage 32 of the heat exchanger 24 in a zigzag manner. Thus, heat is effectively exchanged between the combustion gas and the oxygen-containing gas, and the oxygen-containing gas is preheated. The oxygen-containing gas is heated by the high temperature in the power generation / combustion chamber 12 even when passing through the upper gas chamber 16, the communication gas chamber 18, and the lower gas chamber 14.

  The preferred embodiments of the present invention have been described in detail above with reference to the accompanying drawings. However, the present invention is not limited to such embodiments, and various modifications and corrections can be made without departing from the scope of the present invention. It goes without saying that this is possible.

  For example, as shown in FIG. 6, two sets of cell stack assemblies arranged like cell stacks 60a and 60b and cell stacks 60c and 60d are arranged in parallel, and reformers 78a are respectively arranged above the two sets of cell stack assemblies. , 78b, and the reformed gas can be supplied to the two cell stack assemblies from the reformers 78a, 78b above them. A gas ejection plate 22 is disposed between the gas manifolds 58a and 58b where the two cell stack assemblies are disposed. In this case, air can be sufficiently supplied from both sides to the two rows of cell stacks 60a and 60b, 60c and 60d. 1 and 6, an air introduction pipe communicating with the upper gas chamber 16 can be used instead of the gas ejection plate 22.

  Further, as shown in FIG. 7, on one gas manifold 58, cell stacks 60a and 60b arranged in two rows and cell stacks 60c and 60d arranged in two rows are provided at predetermined intervals in the front-rear direction. One reformer may be provided on the cell stacks 60a, 60b, 60c, 60d.

Sectional drawing which shows suitable embodiment of the fuel cell of this invention. The perspective view which abbreviate | omits and shows the fuel cell of FIG. The perspective view which shows the state which connected the reformer to the gas manifold using the reformed gas supply pipe. The perspective view which shows the cell stack of FIG. Sectional drawing which shows the cell stack of FIG. Sectional drawing which shows the other form of the fuel cell of this invention. The further another form of the fuel cell of this invention is shown, (a) is a cross-sectional view, (b) is a longitudinal cross-sectional view.

Explanation of symbols

2: Housing 58, 58a, 58b: Fuel gas manifolds 60a, 60b, 60c and 60d: Cell stack 62: Fuel cell 78, 78a, 78b: Reformer 80: Reformed gas supply pipe 82: Reformed gas supply tube

Claims (7)

A cell stack assembly comprising a plurality of rows of cell stacks in which a plurality of solid oxide fuel cells are arranged in a row at predetermined intervals in a housing, and the cell stack assembly are provided. A fuel cell, comprising: a gas manifold; a reformer provided above the cell stack; and a reformed gas supply pipe connecting the plurality of reformers and the gas manifold. A plurality of cell stacks in which a plurality of solid oxide fuel cells are arranged in a row at predetermined intervals in a housing, a gas manifold in which each of the plurality of cell stacks is provided, and above the plurality of cell stacks And a reformer that supplies reformed gas to the plurality of cell stacks, and a reformed gas supply pipe that connects the reformer and the plurality of gas manifolds. battery. A cell stack assembly comprising a plurality of rows of cell stacks in which a plurality of solid oxide fuel cells are arranged in a row at predetermined intervals in a housing, and the cell stack assembly are provided. A gas manifold; a reformer that is provided above the cell stack assembly and supplies reformed gas to the gas manifold; and a reformed gas supply pipe that connects the reformer and the gas manifold. The fuel cell characterized by the above-mentioned. A plurality of cell stack assemblies in which two rows of cell stacks are arranged, a reformer provided above the plurality of cell stack assemblies, and a reformer above the plurality of cell stack assemblies. The fuel cell according to claim 3, wherein the reformed gas is supplied. The fuel cell according to any one of claims 1 to 4, wherein the reformed gas supply pipe has a hollow plate shape. 6. The fuel cell according to claim 1, wherein the reformed gas supply pipe for supplying the reformed gas to the reformer has a hollow plate shape. 7. The fuel cell according to claim 5, wherein the gas manifold, the reformer, the reformed gas supply pipe, and the reformed gas supply pipe have substantially the same width.

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