JP2005172937A - Developing device and image forming apparatus - Google Patents

Developing device and image forming apparatus Download PDF

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JP2005172937A
JP2005172937A JP2003409306A JP2003409306A JP2005172937A JP 2005172937 A JP2005172937 A JP 2005172937A JP 2003409306 A JP2003409306 A JP 2003409306A JP 2003409306 A JP2003409306 A JP 2003409306A JP 2005172937 A JP2005172937 A JP 2005172937A
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developer
toner
charging
development
film
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Utako Takahashi
歌子 高橋
Naoki Yoshie
直樹 吉江
Yukiko Mizuguchi
由紀子 水口
Kazuko Fukumoto
和子 福本
Eiji Tabata
英二 田畑
Shigeo Uetake
重夫 植竹
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Konica Minolta Business Technologies Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a developing device in which uniform, steady electrification of developer supplied for the development of an electrostatic latent image can be ensured for a long time and whose structure is simple and inexpensive, and to provide an image forming apparatus for forming a steady and excellent image over a long time by providing the developing device. <P>SOLUTION: The developing device 3 includes: a developing roller 32 for developing an electrostatic latent image on a photoreceptor 1; a toner regulating member 34 which abuts on the developing roller 32 so as to form a thin layer of toner onto the developing roller and generate trivoelectricity in the toner; and a toner electrification film 36 which further electrifies the toner passed through the toner regulating member 34 before supplied to a developing area, film 36 being set smaller in the area of the contact of it with the developing roller 32 for a non-development period than a development period. The image forming apparatus is provided with the developing device. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は複写機やプリンター等の電子写真方式の画像形成装置に用いられる現像装置及び画像形成装置に関する。   The present invention relates to a developing device and an image forming apparatus used in an electrophotographic image forming apparatus such as a copying machine or a printer.

従来、電子写真方式の画像形成装置で用いられる現像装置としては、感光体等の像担持体に回転可能な現像剤担持体を対向させ、この現像剤担持体に供給される現像剤を現像剤規制部材にて規制して現像剤担持体上に現像剤薄層を形成し、該現像剤薄層を現像領域へ供給して像担持体上の静電潜像を現像するものが知られている。   Conventionally, as a developing device used in an electrophotographic image forming apparatus, a rotatable developer carrier is opposed to an image carrier such as a photosensitive member, and the developer supplied to the developer carrier is used as a developer. It is known that a developer thin layer is formed on a developer carrying member regulated by a regulating member, and the developer thin layer is supplied to a developing region to develop an electrostatic latent image on the image carrier. Yes.

現像剤として一成分非磁性現像剤を用いる一成分非磁性現像方式の現像装置の場合には、現像剤を規制部材による規制と同時に摩擦帯電するものが一般的に知られている。
しかし、現像剤規制部材による摩擦帯電では十分に現像剤が帯電されず、画像を繰り返すことにより現像剤の劣化が進み、正規の現像剤帯電極性とは逆極性に帯電した現像剤が増加し、これが像担持体上の非画像部へ転移してしまう(反転かぶり)という現象が生じる。
In the case of a one-component non-magnetic developing type developing device that uses a one-component non-magnetic developer as a developer, it is generally known that the developer is frictionally charged simultaneously with the restriction by the restriction member.
However, the friction charging by the developer regulating member does not sufficiently charge the developer, and the developer deteriorates by repeating the image, and the developer charged to a polarity opposite to the normal developer charging polarity increases. A phenomenon occurs in which this is transferred to a non-image portion on the image carrier (reversal fogging).

そこで、例えば、特開2000−315014号公報や特開2001−34046号公報に開示されているように、現像剤担持体の回転方向において現像領域より上流側で、且つ、現像剤規制部材よりも下流側に設けられた現像剤帯電部材(帯電ローラ)にて、現像剤規制部材により現像剤薄層とされるとともに摩擦帯電された後の現像剤をさらに帯電することにより確実に現像剤を帯電させる方式が提案されている。図6は、この特開2000−315014号公報に開示された現像装置を示している。   Therefore, for example, as disclosed in Japanese Patent Application Laid-Open No. 2000-315014 and Japanese Patent Application Laid-Open No. 2001-34046, in the rotation direction of the developer carrier, upstream of the development region and more than the developer regulating member. The developer charging member (charging roller) provided on the downstream side makes the developer thin layer by the developer regulating member and also charges the developer by further charging the developer after being frictionally charged. A method of making it happen has been proposed. FIG. 6 shows a developing device disclosed in Japanese Patent Application Laid-Open No. 2000-315014.

図6において、PCは感光体、Dは現像装置であり、現像装置Dは像担持体である感光体PCに接触して回転する現像剤担持体(図示例では現像ローラ)drとこれに現像剤tを供給する供給ローラsrを含み、現像剤担持体drにはその回転方向において感光体PCに接触する現像領域より上流側で現像剤帯電部材(帯電ローラCR)が、さらに上流側で現像剤規制部材Bが接触配置されている。現像剤担持体drには電源PWaから現像バイアスが、現像剤帯電部材CRには電源PWbから現像剤帯電用電圧が印加されるようになっている。   In FIG. 6, PC is a photosensitive member, D is a developing device, and the developing device D is a developer carrying member (developing roller in the illustrated example) dr that rotates in contact with the photosensitive member PC which is an image carrier, and a developing device therefor. The developer carrying member dr includes a supply roller sr for supplying the developer t, and a developer charging member (charging roller CR) is developed upstream of the developing region in contact with the photoreceptor PC in the rotation direction, and further developed on the upstream side. The agent regulating member B is disposed in contact. A developing bias is applied from the power source PWa to the developer carrying member dr, and a developer charging voltage is applied from the power source PWb to the developer charging member CR.

この現像装置によると、現像剤帯電部材CRを現像剤担持体drに圧接した状態で、該現像剤帯電部材CRに放電開始電圧以上の電圧を印加して現像剤担持体dr上の現像剤tを放電帯電する。   According to this developing apparatus, in a state where the developer charging member CR is in pressure contact with the developer carrier dr, a voltage equal to or higher than the discharge start voltage is applied to the developer charging member CR to thereby develop the developer t on the developer carrier dr. Is discharged and charged.

また、特開2001−34046号公報に開示された現像装置は、図6に示した現像剤帯電部材(帯電ローラ)CRを現像剤担持体drより離間した状態で(図省略)、その現像剤帯電部材drに放電開始電圧以上の電圧を印加して現像剤担持体dr上の現像剤を放電帯電するように構成されている。   Further, the developing device disclosed in Japanese Patent Application Laid-Open No. 2001-34046 has the developer charging member (charging roller) CR shown in FIG. 6 separated from the developer carrier dr (not shown), and the developer. The charging member dr is configured to discharge and charge the developer on the developer carrier dr by applying a voltage equal to or higher than the discharge start voltage to the charging member dr.

特開2000−315014号公報JP 2000-315014 A 特開2001−34046号公報JP 2001-34046 A

ところが、前記特開2000−315014号公報に開示されている現像装置の場合には、現像剤帯電部材(帯電ローラ)CRを現像剤担持体drに圧接した状態で現像剤を帯電させるため、現像剤規制部材による規制領域を通過してきた現像剤薄層に負荷がかかり、現像剤薄層が乱れやすい。さらに、画像形成を繰り返すことにより現像剤が現像剤帯電部材CRに付着し、該部材の帯電能が低下してくる。これらにより現像剤を均一に、長期にわたり安定して帯電させることが困難である。   However, in the case of the developing device disclosed in Japanese Patent Laid-Open No. 2000-315014, the developer is charged while the developer charging member (charging roller) CR is in pressure contact with the developer carrier dr. A load is applied to the developer thin layer that has passed through the restriction region by the agent restricting member, and the developer thin layer tends to be disturbed. Further, by repeating the image formation, the developer adheres to the developer charging member CR, and the charging ability of the member decreases. Accordingly, it is difficult to charge the developer uniformly and stably over a long period of time.

また、特開2001−34046号公報に開示された現像装置の場合には、現像剤帯電部材(帯電ローラ)CRを離間した状態で現像剤を帯電するので現像剤帯電部材CRに現像剤が付着することは防止されるが、放電開始電圧が高くなるため、高価な高圧電源が必要になり、高圧電源を使用するためランニングコストも高くつく。   Further, in the case of the developing device disclosed in Japanese Patent Application Laid-Open No. 2001-34046, the developer is charged with the developer charging member (charging roller) CR separated, so that the developer adheres to the developer charging member CR. However, since the discharge start voltage becomes high, an expensive high-voltage power supply is required, and the use of the high-voltage power supply increases the running cost.

そこで、本発明は、電子写真方式の画像形成装置に用いる現像装置であって、静電潜像の現像に供給する現像剤を、均一に長期にわたり安定して帯電させることができ、それだけ長期にわたり良好な現像画像を得ることができる現像装置を提供することを課題とする。   Accordingly, the present invention is a developing device used in an electrophotographic image forming apparatus, and the developer supplied to the development of the electrostatic latent image can be uniformly and stably charged over a long period of time. It is an object of the present invention to provide a developing device capable of obtaining a good developed image.

また本発明は、かかる現像装置であって、構造簡単にして、製作費及びランニングコストの点で安価に済む現像装置を提供することを課題とする。   Another object of the present invention is to provide such a developing device that has a simple structure and is inexpensive in terms of production cost and running cost.

また本発明は、電子写真方式の画像形成装置であって、像担持体上に形成される静電潜像を長期にわたり、安定して良好に現像でき、それにより長期にわたり安定して良好な画像を形成できる画像形成装置を提供することを課題とする。   The present invention also relates to an electrophotographic image forming apparatus, which can stably and satisfactorily develop an electrostatic latent image formed on an image carrier over a long period of time, thereby stably providing a good image over a long period of time. It is an object of the present invention to provide an image forming apparatus capable of forming the image.

本発明は前記課題を解決するこめ、次の現像装置及び画像形成装置を提供する。
(1)現像装置
静電潜像の形成された像担持体に現像剤を接触させて該静電潜像を現像する現像剤担持体と、前記現像剤担持体に現像剤を介して圧接する現像剤規制部材と、前記像担持体とこれに臨む現像剤担持体とで形成される現像領域よりも該現像剤担持体の回転方向において上流側に、且つ、該現像剤担持体に対する前記現像剤規制部材の圧接部よりも該現像剤担持体の回転方向において下流側に該現像剤担持体上の現像剤に近接又は接触するように設けられたフイルム状の現像剤帯電部材とを備え、前記静電潜像の現像時には前記現像剤帯電部材に前記現像剤担持体上の現像剤を帯電させる電圧が印加されて該現像剤帯電部材が現像剤担持体へ静電吸着されるとともに該現像剤を帯電させ、非現像時には、該現像剤帯電部材と現像剤担持体との接触面積が現像時よりも小さく設定される現像装置。
The present invention solves the above problems and provides the following developing device and image forming apparatus.
(1) Developing device A developer is brought into contact with an image carrier on which an electrostatic latent image is formed to develop the electrostatic latent image, and the developer carrier is pressed against the developer carrier via the developer. The development with respect to the developer carrying member, upstream of the development region formed by the developer regulating member, the image carrier and the developer carrying member facing the developer carrying member, in the rotational direction of the developer carrying member. A film-like developer charging member provided so as to be close to or in contact with the developer on the developer carrier on the downstream side in the rotation direction of the developer carrier from the pressure contact portion of the agent regulating member, During the development of the electrostatic latent image, a voltage for charging the developer on the developer carrying member is applied to the developer charging member so that the developer charging member is electrostatically adsorbed to the developer carrying member and the development is performed. When the developer is charged and not developed, the developer charging member and the developer A developing device in which a contact area with the carrier is set smaller than that during development.

ここで、「非現像時には、該現像剤帯電部材と現像剤担持体との接触面積が現像時よりも小さく設定される」には、非現像時にも現像剤帯電部材が現像剤担持体に接触しているがその接触面積が現像時よりも小さく設定される場合だけでなく、現像剤帯電部材が現像剤担持体と非接触とされる場合も含まれる。   Here, “when non-development, the contact area between the developer charging member and the developer carrying member is set smaller than during development”, the developer charging member contacts the developer carrying member even during non-development. However, this includes not only the case where the contact area is set smaller than that during development, but also the case where the developer charging member is not in contact with the developer carrier.

(2)画像形成装置
像担持体と、該像担持体上に静電潜像を形成する潜像形成手段と、該像担持体上に形成される静電潜像を現像するための上記(1)記載の現像装置とを備えた画像形成装置。
(2) Image forming apparatus Image carrier, latent image forming means for forming an electrostatic latent image on the image carrier, and the above (for developing the electrostatic latent image formed on the image carrier ( An image forming apparatus comprising the developing device according to 1).

本発明に係る現像装置によると、像担持体上に形成された静電潜像の現像時、現像剤は現像剤規制部材の現像剤担持体への圧接部を通過することで所定の現像剤薄層とされるとともに摩擦帯電され、さらに、現像剤帯電用電圧が印加された現像剤帯電部材により放電帯電にて一層確実に帯電されて潜像現像に供され、良好な現像画像を形成することができる。   According to the developing device of the present invention, when the electrostatic latent image formed on the image carrier is developed, the developer passes through the pressure contact portion of the developer regulating member to the developer carrier, so that the predetermined developer is obtained. A thin layer is triboelectrically charged, and the developer charging member to which a developer charging voltage is applied is more reliably charged by discharge charging and used for latent image development to form a good developed image. be able to.

また、現像剤帯電部材はフィルム状のものであるから、現像剤担持体上の現像剤に広い面積で接触圧低く接触して該現像剤を帯電させることができるので、現像剤担持体上の現像剤層の乱れが抑制される状態で現像剤を帯電こせることができ、この点でも確実に、均一に安定して現像剤を帯電させることができる。   In addition, since the developer charging member is in the form of a film, the developer can be charged by contacting the developer on the developer carrying member with a wide area and low contact pressure. The developer can be charged in a state in which the disturbance of the developer layer is suppressed. Also in this respect, the developer can be reliably and uniformly charged.

また、現像剤帯電部材はフィルム状のものであり、現像剤担持体上の現像剤に広い面積で接触圧低く接触して該現像剤を帯電させることができるので、さらに、非現像時には、現像剤帯電部材と現像剤担持体との接触面積が現像時より小さく設定されるので、両者の間に現像剤が滞留し難く、また、現像剤が現像剤帯電部材を著しく汚したり、該部材に固着したりして、その帯電能を低下させてしまうことが抑制されるので、この点でも、現像剤を確実に、均一に安定して帯電させることができる。   Further, the developer charging member is in the form of a film, and can be charged by contacting the developer on the developer carrying member over a wide area with a low contact pressure. Since the contact area between the developer charging member and the developer carrying member is set smaller than that during development, the developer is less likely to stay between them, and the developer significantly soils the developer charging member, Since it is possible to prevent the charging ability from being reduced due to fixing, the developer can be charged uniformly and stably in this respect as well.

さらに、現像剤帯電部材はフィルム状のものであるから、該部材に印加する電圧を制御するだけで、該現像剤帯電部材の現像剤担持体への接触面積を制御することができ、且つ、該接触面積の制御は低電圧で容易に行える。従って、それだけ電源コスト及びランニングコストを安価に抑えることができる。また、現像剤帯電部材はフィルム状のものであるから、その製作費も安価に済む。   Further, since the developer charging member is in the form of a film, the contact area of the developer charging member to the developer carrying member can be controlled only by controlling the voltage applied to the member, and The contact area can be easily controlled at a low voltage. Therefore, the power supply cost and the running cost can be reduced to that extent. Further, since the developer charging member is in the form of a film, the production cost can be reduced.

これらにより、本発明に係る現像装置は、静電潜像の現像に供給する現像剤を、均一に長期にわたり安定して帯電させることができ、それだけ長期にわたり良好な現像画像を得ることができる。また、構造が簡単に済み、製作費及びランニングコストの点で安価に済む。   As a result, the developing device according to the present invention can uniformly and stably charge the developer supplied to the development of the electrostatic latent image over a long period of time, so that a good developed image can be obtained over a long period of time. Further, the structure is simple and the manufacturing cost and running cost are low.

本発明の画像形成装置はかかる現像装置を採用するので、それだけ、像担持体上に形成される静電潜像を長期にわたり、安定して良好に現像でき、それにより長期にわたり安定して良好な画像を形成できる。   Since the image forming apparatus of the present invention employs such a developing device, the electrostatic latent image formed on the image bearing member can be stably and satisfactorily developed over a long period of time. An image can be formed.

本発明に係る現像装置、本発明に係る画像形成装置で採用する現像装置において、非現像時に現像剤帯電部材と現像剤担持体との接触面積を現像時よりも小さく設定する例として、次の場合を挙げることができる。   In the developing apparatus according to the present invention and the developing apparatus employed in the image forming apparatus according to the present invention, as an example in which the contact area between the developer charging member and the developer carrying member is set smaller than that during development in the non-development, Cases can be mentioned.

(1) 非現像時に現像剤帯電部材への電圧印加を停止する等して該現像剤帯電部材を前記現像剤担持体と非接触に設定する( この場合、例えばフィルム状現像剤帯電部材の弾性復元力を利用して非接触にできる。) 、
(2) 非現像時に現像剤担持体と現像剤帯電部材との電位差を制御することで現像剤帯電部材と現像剤担持体との接触面積を現像時より小さくする、
(3) 非現像時に現像剤帯電部材と現像剤担持体との間に印加する電圧を、現像時に該現像剤帯電部材と現像剤担持体との間に印加する電圧よりも低くすることで現像剤帯電部材と現像剤担持体との接触面積を現像時より小さくする、
(4) 前記像担持体の帯電電位がVa、現像剤担持体への印加電圧がVb、現像剤帯電部材への印加電圧がVcであるとき、非現像時における|Va−Vc|及び|Vb−Vc|が|Va−Vc|≧|Vb−Vc|の条件を満たすようにし、それにより、非現像時に例えば、現像剤帯電部材が現像剤担持体から離れて像担持体との間に位置したり、像担持体に接触するようにする。
(1) The developer charging member is set in non-contact with the developer carrying member by stopping the voltage application to the developer charging member during non-development (in this case, for example, the elasticity of the film-like developer charging member) It can be made non-contact using the restoring force.)
(2) By controlling the potential difference between the developer carrying member and the developer charging member during non-development, the contact area between the developer charging member and the developer carrying member is made smaller than during development.
(3) Development is performed by setting the voltage applied between the developer charging member and the developer carrying member during non-development to be lower than the voltage applied between the developer charging member and the developer carrying member during development. The contact area between the developer charging member and the developer carrier is smaller than during development,
(4) When the charging potential of the image carrier is Va, the voltage applied to the developer carrier is Vb, and the voltage applied to the developer charging member is Vc, | Va−Vc | and | Vb during non-development −Vc | satisfies the condition of | Va−Vc | ≧ | Vb−Vc |, so that, for example, the developer charging member is separated from the developer carrier and positioned between the image carrier and the non-developing member. Or contact the image carrier.

画像形成装置の場合、非現像時に現像剤帯電部材を像担持体に接触させるようにしてもよい。   In the case of the image forming apparatus, the developer charging member may be brought into contact with the image carrier at the time of non-development.

以上説明したように本発明によると、電子写真方式の画像形成装置に用いる現像装置であって、静電潜像の現像に供給する現像剤を、均一に長期にわたり安定して帯電させることができ、それだけ長期にわたり良好な現像画像を得ることができる現像装置を提供することができる。   As described above, according to the present invention, the developing device used in the electrophotographic image forming apparatus can uniformly and stably charge the developer supplied to the development of the electrostatic latent image over a long period of time. Thus, it is possible to provide a developing device that can obtain a good developed image for a long period of time.

また本発明によると、かかる現像装置であって、構造簡単にして、製作費及びランニングコストの点で安価に済む現像装置を提供することができる。   In addition, according to the present invention, it is possible to provide such a developing device that has a simple structure and is inexpensive in terms of production cost and running cost.

また本発明によると、電子写真方式の画像形成装置であって、像担持体上に形成される静電潜像を長期にわたり、安定して良好に現像でき、それにより長期にわたり安定して良好な画像を形成できる画像形成装置を提供することができる。   According to the present invention, there is also provided an electrophotographic image forming apparatus that can stably and satisfactorily develop an electrostatic latent image formed on an image carrier over a long period of time, thereby stably and satisfactorily over a long period of time. An image forming apparatus capable of forming an image can be provided.

以下、本発明の実施形態を図面を参照して説明する。
図1は本発明に係る画像形成装置の1例を示している。
<画像形成装置>
図1の画像形成装置は、像担持体の1例であるドラム型の感光体1を備えている。感光体1の周囲には帯電器2、現像装置3、転写装置4及びクリーニング装置5がこの順序で配置されている。また、現像装置3の上方には画像露光装置6が設けられており、該装置6で帯電器2と現像装置3の間から感光体1上に画像露光できるようになっている。また、感光体1の下方に記録材供給カセット7が配置されている。さらに、記録材搬送路の後部に定着器8が設置されている。
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
FIG. 1 shows an example of an image forming apparatus according to the present invention.
<Image forming apparatus>
The image forming apparatus of FIG. 1 includes a drum-type photoreceptor 1 that is an example of an image carrier. Around the photoreceptor 1, a charger 2, a developing device 3, a transfer device 4, and a cleaning device 5 are arranged in this order. Further, an image exposure device 6 is provided above the developing device 3 so that the image exposure can be performed on the photosensitive member 1 from between the charger 2 and the developing device 3. A recording material supply cassette 7 is disposed below the photosensitive member 1. Further, a fixing device 8 is installed at the rear of the recording material conveyance path.

本例では、帯電器2は電源PW1から感光体帯電用電圧が印加される帯電ローラであり、転写装置4は電源PW4から転写電圧を印加される転写ローラであり、クリーニング装置5は感光体1に接触するクリーニングブレード51及びこれにより感光体から除去されるトナー等を収容する容器52とを含むものである。現像装置3については後ほど詳述する。画像形成時、各ローラは図示省略の駆動手段で所定方向に回転駆動される。   In this example, the charger 2 is a charging roller to which a photoreceptor charging voltage is applied from a power source PW1, the transfer device 4 is a transfer roller to which a transfer voltage is applied from a power source PW4, and the cleaning device 5 is a photoreceptor 1. A cleaning blade 51 in contact with the toner, and a container 52 for storing toner and the like removed from the photosensitive member. The developing device 3 will be described in detail later. During image formation, each roller is driven to rotate in a predetermined direction by a driving unit (not shown).

この画像形成装置によると、感光体1が図中時計方向CWに回転駆動され、該感光体表面が帯電ローラ2にて所定電位に帯電され、その帯電域に画像露光装置6から画像データに応じて画像露光が施され、静電潜像が形成される。該静電潜像は現像装置3により現像されて可視トナー像とされる。   According to this image forming apparatus, the photosensitive member 1 is rotationally driven in the clockwise direction CW in the figure, the surface of the photosensitive member is charged to a predetermined potential by the charging roller 2, and the charged area is in accordance with image data from the image exposure device 6. The image is exposed to form an electrostatic latent image. The electrostatic latent image is developed by the developing device 3 to be a visible toner image.

一方、記録材供給カセット7から、ここでの記録材である転写用紙Sが給紙ローラ71にて引き出され、感光体1上の潜像と同期をとって転写領域へ供給され、ここで転写ローラ4にて感光体上のトナー像が用紙Sに転写される。トナー像が転写された用紙Sは定着器8に搬送され、トナー像が加熱加圧下に定着されて排紙トレー9に排出される。トナー像転写後感光体1上に残留するトナーはクリーニング装置5のブレード51にて除去され、次の画像形成に備えられる。除去されたトナーは廃トナー容器52に収容される。   On the other hand, the transfer sheet S, which is the recording material here, is pulled out from the recording material supply cassette 7 by the paper feed roller 71 and supplied to the transfer area in synchronization with the latent image on the photosensitive member 1, where transfer is performed. The toner image on the photosensitive member is transferred onto the paper S by the roller 4. The sheet S on which the toner image is transferred is conveyed to the fixing device 8, where the toner image is fixed under heat and pressure, and is discharged to the paper discharge tray 9. The toner remaining on the photoreceptor 1 after the toner image transfer is removed by the blade 51 of the cleaning device 5 and is prepared for the next image formation. The removed toner is stored in a waste toner container 52.

<現像装置>
前記現像装置3は、本発明に係る現像装置の1例であり全体として、画像形成装置本体に対し着脱可能のカートリッジ型に形成されている。さらに説明すると、1成分系のトナーTを収容する装置ケース30は内部が仕切り壁301により前後2室に分けられている。トナーTを収容する後ろ側の室にはトナーTを攪拌しつつ仕切り壁301の開口を通して前側の室へ供給する回転型アジテータ31が設けられている。前側の室には感光体1に対向し得る位置に現像ローラの形態のトナー担持体(現像剤担持体の1例)32が回転可能に配置されている。また、アジテータ31にて供給されてきたトナーTを現像ローラ32へ供給するトナー供給ローラ33が現像ローラ32に回転可能に接触配置されている。
<Developing device>
The developing device 3 is an example of a developing device according to the present invention, and as a whole, is formed in a cartridge type that is detachable from the main body of the image forming apparatus. More specifically, the inside of the device case 30 that accommodates the one-component toner T is divided into two front and rear chambers by a partition wall 301. A rotary agitator 31 for supplying the toner T to the front chamber through the opening of the partition wall 301 while stirring the toner T is provided in the rear chamber containing the toner T. In the front chamber, a toner carrier (an example of a developer carrier) 32 in the form of a developing roller is rotatably disposed at a position that can face the photoreceptor 1. A toner supply roller 33 for supplying the toner T supplied from the agitator 31 to the developing roller 32 is disposed in contact with the developing roller 32 so as to be rotatable.

さらに、現像ローラ32にはトナー供給ローラ33から供給されるトナーTの層厚を規制するトナー規制部材(現像剤規制部材の1例)34が接触配置されている。トナー規制部材34は、現像領域へ移動する現像ローラ32上のトナーTの層厚を所定の厚さに規制するとともに該トナーを摩擦帯電させる。また、トナー規制部材34の上側に電極34が配置されており、これにトナー帯電用フィルム36が片持ち支持されている。フィルム36は現像剤帯電部材の1例であり、可撓性を有している。   Further, a toner regulating member (an example of a developer regulating member) 34 that regulates the layer thickness of the toner T supplied from the toner supply roller 33 is disposed in contact with the developing roller 32. The toner regulating member 34 regulates the layer thickness of the toner T on the developing roller 32 moving to the developing region to a predetermined thickness and frictionally charges the toner. Further, an electrode 34 is disposed on the upper side of the toner regulating member 34, and a toner charging film 36 is cantilevered on the electrode 34. The film 36 is an example of a developer charging member, and has flexibility.

現像ローラ32には電源PW2から現像バイアス電圧を印加できるようになっている。現像装置カートリッジを画像形成装置本体に装着して現像ローラ32を感光体1に近接又は接触する位置に配置した状態で、該現像バイアス電圧を印加することで現像ローラ32上のトナーで感光体1上に形成された静電潜像を顕像化できる。   A developing bias voltage can be applied to the developing roller 32 from the power source PW2. In a state where the developing device cartridge is mounted on the image forming apparatus main body and the developing roller 32 is disposed at a position close to or in contact with the photosensitive member 1, the toner on the developing roller 32 is applied with the toner on the developing roller 32 by applying the developing bias voltage. The electrostatic latent image formed thereon can be visualized.

また、トナー帯電用フィルム36には電源PW3から電極34を介してトナー帯電用電圧を印加できるようになっている。
フィルム36は、非現像時には電源PW3から電圧は印加されない。電源PW3から電圧が印加されない非現像時には、図2(A)に示すように、フィルム36はその弾性復元力で、現像ローラ32には接触せず、それに近接する位置に置かれる。感光体1上の静電潜像の現像時には電源PW3から電圧が印加される。現像時、フィルム36に印加する電圧は、現像ローラ32上のトナーに対して放電開始電圧以上で、且つ、トナーの帯電極性と同極性の所定のDC電圧である。
Further, a toner charging voltage can be applied to the toner charging film 36 from the power source PW3 via the electrode 34.
When the film 36 is not developed, no voltage is applied from the power source PW3. At the time of non-development where no voltage is applied from the power source PW3, as shown in FIG. 2A, the film 36 is placed in a position adjacent to the developing roller 32 without contacting with the developing roller 32 by its elastic restoring force. A voltage is applied from the power source PW3 when developing the electrostatic latent image on the photoconductor 1. During development, the voltage applied to the film 36 is a predetermined DC voltage that is equal to or higher than the discharge start voltage for the toner on the developing roller 32 and has the same polarity as the charging polarity of the toner.

現像時、フィルム36に電源PW3から電圧が印加されると、フィルム36は、現像ローラ32との電位差により現像ローラ32側へ静電吸着されて図2(B)に示すように現像ローラ32上のトナー層に接触し、且つ、該トナーを放電により帯電させる。   When a voltage is applied to the film 36 from the power source PW3 during development, the film 36 is electrostatically attracted to the developing roller 32 side due to a potential difference with the developing roller 32, and the film 36 is placed on the developing roller 32 as shown in FIG. The toner layer and the toner is charged by discharging.

現像に供される、フィルム36による帯電後のトナーの帯電量の絶対値は20μC/g〜60μC/g程度が好ましい。
また、トナー規制部材34により規制される現像ローラのトナー搬送量は2g/m2 〜20g/m2 程度が好ましい。これより少なすぎると現像不良を招き、多すぎても、フィルム36による帯電が不十分となり、現像不良を招く。
The absolute value of the charge amount of the toner charged by the film 36 used for development is preferably about 20 μC / g to 60 μC / g.
Further, the toner conveyance amount of the developing roller is regulated by a toner regulating member 34 is preferably 2 to 20 g / m 2 about 2 g / m. If it is less than this, development failure will be caused, and if it is too much, charging by the film 36 will be insufficient and development failure will be caused.

以上説明したように、現像時には、フィルム36に電源PW3から所定の電圧を印加し、それにより、現像ローラ32上の、トナー規制部材にて摩擦帯電したトナーを一層確実に放電帯電させることができる。   As described above, at the time of development, a predetermined voltage is applied to the film 36 from the power source PW3, so that the toner frictionally charged by the toner regulating member on the developing roller 32 can be discharged and charged more reliably. .

また、現像時、トナー帯電用フィルム36は現像ローラ32上のトナーに広い面積で接触圧低く接触して該トナーを帯電させることができるので、現像ローラ32上のトナー薄層の乱れが抑制される状態でトナーを帯電させることができ、この点でも確実に、均一に安定してトナーを帯電させることができる。   Further, at the time of development, the toner charging film 36 can contact the toner on the developing roller 32 with a low contact pressure over a wide area to charge the toner, so that the disturbance of the toner thin layer on the developing roller 32 is suppressed. In this state, the toner can be charged. Also in this respect, the toner can be reliably and uniformly charged.

また、トナー帯電用フィルム36は現像ローラ32上のトナーに広い面積で接触圧低く接触して該トナーを帯電させることができるので、さらに、非現像時には、電源PW3をオフすることでフィルム36と現像ローラ32間の静電吸着力を解除してフィルム36を現像ローラ32から離間させることができるので、フィルム36と現像ローラ32との間にトナーが滞留し難く、また、トナーがフィルム36を著しく汚したり、フィルム36に固着したりして、その帯電能を低下させてしまうことが抑制されるので、この点でも、トナーを確実に、均一に安定して帯電させることができる。   Further, the toner charging film 36 can be charged by contacting the toner on the developing roller 32 in a wide area with a low contact pressure. Further, when the toner is not developed, the power supply PW3 is turned off. Since the electrostatic attraction force between the developing rollers 32 can be released and the film 36 can be separated from the developing roller 32, the toner hardly stays between the film 36 and the developing roller 32. Since it is suppressed that the charging ability is deteriorated due to remarkably fouling or adhering to the film 36, the toner can be reliably and uniformly charged in this respect as well.

さらに、トナー帯電用フィルム36に印加する電圧を制御するだけで、フィルム36の現像ローラ32に対する接触、離反を制御することができ、且つ、その制御は低電圧で容易に行える。従って、それだけ電源コスト及びランニングコストを安価に抑えることができる。また、フィルム36は製作費が安価に済む。   Further, the contact and separation of the film 36 with respect to the developing roller 32 can be controlled only by controlling the voltage applied to the toner charging film 36, and the control can be easily performed at a low voltage. Therefore, the power supply cost and the running cost can be reduced to that extent. In addition, the film 36 is inexpensive to manufacture.

これらにより、現像装置3は静電潜像の現像に供給するトナーを、均一に長期にわたり安定して帯電させることができ、それだけ長期にわたり良好な画像を得ることができる。また、構造が簡単に済み、製作費及びランニングコストの点で安価に済む。   As a result, the developing device 3 can uniformly and stably charge the toner supplied to the development of the electrostatic latent image over a long period of time, so that a good image can be obtained over a long period of time. Further, the structure is simple and the manufacturing cost and running cost are low.

<現像装置、特にトナー帯電用フィルムの変形例>
次に現像剤帯電部材(ここではトナー帯電用フィルム36)の変形例について図3及び図4を参照して説明する。
図3に示す例では、図1及び図2に示す構成において、トナー帯電用フィルム36が現像ローラ32に接触して設けられている。現像時には、図3(B)に示すように、現像ローラ32とフィルム36との電位差により、フィルム36が現像ローラ32に静電吸着力によりさらに密着すると同時に現像ローラ32上のトナーを放電帯電する。
<Modification of developing device, particularly toner charging film>
Next, a modified example of the developer charging member (here, the toner charging film 36) will be described with reference to FIGS.
In the example shown in FIG. 3, in the configuration shown in FIGS. 1 and 2, the toner charging film 36 is provided in contact with the developing roller 32. At the time of development, as shown in FIG. 3B, due to the potential difference between the developing roller 32 and the film 36, the film 36 is further brought into close contact with the developing roller 32 by electrostatic adsorption force, and at the same time, the toner on the developing roller 32 is discharged and charged. .

非現像時には、図3(A)に示すように、トナー帯電用フィルム36への印加電圧を現像時よりも低い電圧にすることにより、現像ローラ32とフィルム36との間に生じる電位差を小さくして静電吸着力を小さくし、これによりフィルム36と現像ローラ32との接触面積(接触圧)を小さくする。   At the time of non-development, as shown in FIG. 3A, the potential difference generated between the developing roller 32 and the film 36 is reduced by setting the voltage applied to the toner charging film 36 to a voltage lower than that at the time of development. Thus, the electrostatic attraction force is reduced, thereby reducing the contact area (contact pressure) between the film 36 and the developing roller 32.

これにより、現像時にフィルム36と現像ローラ32との接触部に滞留したトナーはすり抜けやすくなるため、フィルム36と現像ローラ32との接触部においてトナーが固着したり、トナー溜まりにより画像が乱れることが抑制される。また、非現像時には現像ローラ32との接触面積(接触圧)が小さくなるのでフィルム36にトナーが付着しにくく、フィルム36の汚れが少なく済む。
なお、この例では現像ローラ32からフィルム36を離さないので制御が容易である。
As a result, the toner staying at the contact portion between the film 36 and the developing roller 32 during development is likely to slip through, and thus the toner is fixed at the contact portion between the film 36 and the developing roller 32, or the image is disturbed due to the toner accumulation. It is suppressed. Further, since the contact area (contact pressure) with the developing roller 32 becomes small during non-development, the toner hardly adheres to the film 36 and the film 36 is less contaminated.
In this example, since the film 36 is not separated from the developing roller 32, the control is easy.

図4に示す例では、トナー帯電用フィルム36は当初現像ローラ32に軽く接触して設けられるか又は現像ローラに近接配置されるが、現像時には、図4(B)に示すように、現像ローラ32とフィルム36との電位差により、フィルム36は静電吸着力により現像ローラ32にさらに密着すると同時に現像ローラ32上のトナーを放電帯電する。   In the example shown in FIG. 4, the toner charging film 36 is initially provided in light contact with the developing roller 32 or is disposed close to the developing roller. At the time of development, as shown in FIG. Due to the potential difference between the film 32 and the film 36, the film 36 is further brought into close contact with the developing roller 32 by electrostatic attraction, and at the same time, the toner on the developing roller 32 is discharged and charged.

非現像時には、フィルム36と感光体1の表面電位との電位差が現像ローラ32とフィルム36との電位差よりも大きくなるようにする。かくして非現像時には、図4(A)に示すように、フィルム36は感光体1側に静電吸着され、現像ローラ32とフィルム36は非接触となる。   At the time of non-development, the potential difference between the film 36 and the surface potential of the photoreceptor 1 is made larger than the potential difference between the developing roller 32 and the film 36. Thus, at the time of non-development, as shown in FIG. 4A, the film 36 is electrostatically attracted to the photosensitive member 1 side, and the developing roller 32 and the film 36 are not in contact with each other.

これにより、現像時にフィルム36と現像ローラ32との接触部に滞留したトナーが除去されるため、フィルム36と現像ローラ32との接触部においてトナーが固着したり、トナー溜まりにより画像が乱れることがない。また、非現像時には現像ローラ32と非接触に保持されるのでフィルム36にトナーが付着せず、現像時のみフィルム36にトナーが付着するだけなのでフィルム36の汚れが少なく済む。
この例によると、確実にトナー帯電用フィルム36を非接触状態にすることができる。
As a result, the toner staying in the contact portion between the film 36 and the developing roller 32 at the time of development is removed, so that the toner adheres to the contact portion between the film 36 and the developing roller 32 or the image is disturbed due to toner accumulation. Absent. Further, since the toner is not attached to the developing roller 32 during non-development, the toner does not adhere to the film 36, and only the toner adheres to the film 36 at the time of development.
According to this example, the toner charging film 36 can be reliably brought into a non-contact state.

<トナー帯電用フィルムの材質等>
次にトナー帯電用フィルム、現像ローラ、トナーについてさらに説明する。
(トナー帯電用フィルム)
トナー帯電用フィルムは導電性を調整された高分子フィルムである。フィルムを構成する高分子は、特に制限はない。
例えば、ポリエステル樹脂、ポリカーボネート樹脂、アクリル樹脂、ポリエチレン樹脂、ポリプロピレン樹脂、ウレタン樹脂、ポリアミド樹脂、ポリイミド樹脂、ポリスルホン樹脂、ポリエーテルケトン樹脂、塩化ビニル樹脂、酢酸ビニル樹脂、シリコーン樹脂、フッ素樹脂等の樹脂からなるフィルムやシリコーンゴム、ウレタンゴム、ニトリルゴム、天然ゴム、イソプレンゴム等のゴムからなるフィルムが挙げられるが、これに制約されない。
<Material of toner charging film>
Next, the toner charging film, the developing roller, and the toner will be further described.
(Toner charging film)
The toner charging film is a polymer film with adjusted conductivity. There is no restriction | limiting in particular for the polymer which comprises a film.
For example, polyester resin, polycarbonate resin, acrylic resin, polyethylene resin, polypropylene resin, urethane resin, polyamide resin, polyimide resin, polysulfone resin, polyether ketone resin, vinyl chloride resin, vinyl acetate resin, silicone resin, fluorine resin, etc. And films made of rubber such as silicone rubber, urethane rubber, nitrile rubber, natural rubber, and isoprene rubber are not limited thereto.

フィルムの厚さは10μm以上1mm以下、より好ましくは10μm以上200μm以下である。薄いと強度不足となり、厚すぎるとトナー層に筋ムラが発生したり、現像剤担持体(ここでは現像ローラ)に均一に接触しにくくなったり、ニップがかせぎにくくなる。フィルムは単層構造であっても、必要に応じて2層以上の構造であってもよい。   The thickness of the film is from 10 μm to 1 mm, more preferably from 10 μm to 200 μm. If it is too thin, the strength will be insufficient, and if it is too thick, streaky unevenness will occur in the toner layer, it will be difficult to uniformly contact the developer carrying member (here, the developing roller), or the nip will be difficult to make. The film may have a single layer structure or may have a structure of two or more layers as required.

フィルムは適度な電気抵抗を得るために、フィルムのバルク若しくは表面に導電剤を必要に応じて添加してもよい。
導電剤としては電子導電剤若しくはイオン導電剤が挙げられる。電子導電剤として、ケッチンブラック、アセチレンブラック、ファーネスブラック等のカーボンブラックや、金属粉、金属酸化物の微粒子等が挙げられるが、これに制約されない。
In order to obtain an appropriate electric resistance, a conductive agent may be added to the bulk or surface of the film as necessary.
Examples of the conductive agent include an electronic conductive agent or an ionic conductive agent. Examples of the electronic conductive agent include carbon black such as kettin black, acetylene black, and furnace black, metal powder, and metal oxide fine particles, but are not limited thereto.

イオン導電剤としては、四級アンモニゥム塩等のカチオン性化合物や、アニオン性化合物、側鎖にアルキレンオキサイド基を持ったノニオン性化合物、その他イオン性高分子材料が挙げられるが、これにこだわらない。   Examples of the ionic conductive agent include cationic compounds such as quaternary ammonium salts, anionic compounds, nonionic compounds having an alkylene oxide group in the side chain, and other ionic polymer materials.

以上の導電剤を添加することにより、フィルムの表面抵抗率は105 Ω/□〜1012Ω/□に、より好ましくは106 Ω/□〜1010Ω/□に、さらに好ましくは107 Ω/□〜109 Ω/□に調整される。ここに記載の下限を下回ってくると放電開始電圧に達する前に過剰な電流が流れ、放電開始電圧に達しない恐れがあり、上限を上回ると、放電開始電圧が上がりすぎ、好ましくない。フィルムの場合、表面伝導が主なため、表面抵抗率の制御が重要となる。 By adding the above conductive agent, the surface resistivity of the film is 10 5 Ω / □ to 10 12 Ω / □, more preferably 10 6 Ω / □ to 10 10 Ω / □, and even more preferably 10 7. It is adjusted to Ω / □ to 10 9 Ω / □. If the value falls below the lower limit described here, an excessive current may flow before reaching the discharge start voltage, and the discharge start voltage may not be reached. If the value exceeds the upper limit, the discharge start voltage increases excessively, which is not preferable. In the case of a film, since surface conduction is the main, control of surface resistivity is important.

フィルム電極(ここではフィルム36を取り付けた電極35)とフィルム・トナー担持体(ここでは現像ローラ)間ニップ部との距離は、2mm以上が好ましい。しかし、この距離が大きすぎるとフィルムが薄い場合変形しやすくなり、好ましくない。該距離は3cm程度以下が好ましい。短すぎると、導電剤が局所的にある場合、局所的に導通のパスができ、リークが発生しやすくなる。ある程度該距離を大きくすることにより、フィルムの表面に流れる電流をより均一にできる。これは帯電ローラなどのバルクを通して導電する材料に比べて、大きなメリットとなる(帯電ローラの抵抗層の厚さは最大数mm程度のため)。この結果、フィルム電極とニップ部の間の抵抗は105 Ω〜109 Ωとなる。 The distance between the film electrode (here, the electrode 35 to which the film 36 is attached) and the nip portion between the film / toner carrier (here, the developing roller) is preferably 2 mm or more. However, if this distance is too large, the film is easily deformed when it is thin, which is not preferable. The distance is preferably about 3 cm or less. If it is too short, when the conductive agent is locally present, a conductive path is locally formed, and leakage is likely to occur. By increasing the distance to some extent, the current flowing on the surface of the film can be made more uniform. This is a great advantage compared to a material that conducts through a bulk such as a charging roller (since the thickness of the resistance layer of the charging roller is about several millimeters at the maximum). As a result, the resistance between the film electrode and the nip is 10 5 Ω to 10 9 Ω.

(現像剤担持体(こここではトナー担持体)
一般的に言えば、トナー担持体としてはロール型のものでも、ベルト型のものでも採用できる。図1に示す現像装置におけるトナー担持体はロール型の現像ローラの形態のものである。
このトナー担持体(現像ローラ)32は、図5(A)に示すように、アルミニウムなどで構成された芯金321の上にべース層322を設け、さらにべース層322の上に表層323を設けて構成されている。
(Developer carrier (here, toner carrier)
Generally speaking, the toner carrier can be either a roll type or a belt type. The toner carrier in the developing device shown in FIG. 1 is in the form of a roll type developing roller.
As shown in FIG. 5A, the toner carrier (developing roller) 32 is provided with a base layer 322 on a cored bar 321 made of aluminum or the like, and further on the base layer 322. A surface layer 323 is provided.

ベース層322は硬度50度以下の導電性ゴム層からなり、厚みは0.5mm〜6mm程度が好ましい。導電性ゴム層の体積抵抗率は1×103 Ω・cm〜1×108 Ω・cm程度が好ましい。導電性ゴム層の材料としては、シリコーンゴム、ウレタンゴム、EPDMゴム、ニトリルゴム、フッ素ゴムなどを例示できるが、これらに限定されるものではない。そして、導電性を与えるために導電剤を混合し、電気抵抗値を調整する。導電剤としては、前記フィルムに添加する導電剤と同様のものを採用できる。 The base layer 322 is made of a conductive rubber layer having a hardness of 50 degrees or less, and the thickness is preferably about 0.5 mm to 6 mm. The volume resistivity of the conductive rubber layer is preferably about 1 × 10 3 Ω · cm to 1 × 10 8 Ω · cm. Examples of the material for the conductive rubber layer include, but are not limited to, silicone rubber, urethane rubber, EPDM rubber, nitrile rubber, and fluorine rubber. And in order to provide electroconductivity, a conductive agent is mixed and an electrical resistance value is adjusted. As the conductive agent, the same conductive agent added to the film can be employed.

表層323としては、ウレタン樹脂、ポリアミド樹脂、ニトリル樹脂などの含窒素樹脂のフィルムが荷電性の点から好ましい。厚さは1μm〜10μm、より好ましくは5μm〜30μm程度である。表層の表面抵抗率は、1×107 Ω/□以上1×1012Ω/□以下、より好ましくは1×108 Ω/□以上1×1012Ω/□以下である。表層を設けた状態でのトナー担持体の全抵抗は1×104 Ω以上1×108 Ω以下程度が好ましい。 As the surface layer 323, a film of a nitrogen-containing resin such as a urethane resin, a polyamide resin, or a nitrile resin is preferable from the viewpoint of chargeability. The thickness is about 1 μm to 10 μm, more preferably about 5 μm to 30 μm. The surface resistivity of the surface layer is 1 × 10 7 Ω / □ or more and 1 × 10 12 Ω / □ or less, more preferably 1 × 10 8 Ω / □ or more and 1 × 10 12 Ω / □ or less. The total resistance of the toner carrier with the surface layer provided is preferably about 1 × 10 4 Ω to 1 × 10 8 Ω.

表面抵抗率が107 Ω/□を下回ると、トナー担持体への局所的な導通があり、ひどい場合には焼け付く恐れがある。1012Ω/□を上回ると、チャージアップやゴーストの発生の恐れがでてくる。 When the surface resistivity is less than 10 7 Ω / □, there is local conduction to the toner carrier, and in the worst case, there is a risk of burning. If it exceeds 10 12 Ω / □, there is a risk of charge-up and ghosting.

表層の算術平均表面粗さRaは0.3μm以上5μm以下が好ましく、より好ましくは0.7μm以上3μm以である。表層の表面粗さRaを調整するための方法は特に限定されないが、表層を形成する材料に粗さ調整剤を添加するのが一般的である。粗さ調整剤としては、アクリル樹脂等の有機材料の微粒子、シリカ、アルミナ等の無機材料の微粒子が好ましい。また、必要に応じて表層を形成する材料にイソシアネート化合物、メチロール化合物、エポキシ化合物等の架橋剤を添加してもよい。さらに、表層323とベース層322との間にシランカップリング剤や重合体などの接着層を設けてもよい。   The arithmetic average surface roughness Ra of the surface layer is preferably 0.3 μm or more and 5 μm or less, and more preferably 0.7 μm or more and 3 μm or less. The method for adjusting the surface roughness Ra of the surface layer is not particularly limited, but it is common to add a roughness adjusting agent to the material forming the surface layer. As the roughness adjusting agent, fine particles of organic material such as acrylic resin and fine particles of inorganic material such as silica and alumina are preferable. Moreover, you may add crosslinking agents, such as an isocyanate compound, a methylol compound, an epoxy compound, to the material which forms a surface layer as needed. Furthermore, an adhesive layer such as a silane coupling agent or a polymer may be provided between the surface layer 323 and the base layer 322.

ベルト型のトナー担持体について、その1例を図5(B)に示す。図5(B)のトナー担持体32’は、内部に図示省略の導電性のスポンジローラなどを担持させて駆動する無端ベルト型のものであって、前記した現像ローラ32に置き換えて使用することができる。   An example of a belt-type toner carrier is shown in FIG. The toner carrier 32 ′ shown in FIG. 5B is of an endless belt type that is driven by carrying a conductive sponge roller (not shown) inside, and is used in place of the developing roller 32 described above. Can do.

図5(B)に示すトナー担持体32’は、ベース層321’の上に表層322’を設けて構成されている。ベース層321’は厚み10μm〜1mm、より好ましくは100μm〜300μmの合成樹脂又は金属からなる薄板であり、金属の場合はニッケル等が使用される。合成樹脂を使用する場合は、ポリエステル、ポリアミド、ポリエチレン、ポリイミド、ポリカーボネート等が使用される。そして導電性を与えるために、トナー担持体32の場合と同じく導電剤が添加される。表層322’はトナー担持体32の表層323と同様でよい。   The toner carrier 32 ′ shown in FIG. 5B is configured by providing a surface layer 322 ′ on a base layer 321 ′. The base layer 321 ′ is a thin plate made of a synthetic resin or metal having a thickness of 10 μm to 1 mm, more preferably 100 μm to 300 μm. In the case of a metal, nickel or the like is used. When a synthetic resin is used, polyester, polyamide, polyethylene, polyimide, polycarbonate, or the like is used. In order to provide conductivity, a conductive agent is added as in the case of the toner carrier 32. The surface layer 322 ′ may be the same as the surface layer 323 of the toner carrier 32.

(トナー)
ここで使用するトナーTは、特に限定されず、従来より一般に使用されている公知のトナーを使用することができ、一般に、バインダー樹脂中に着色剤や荷電制御剤や離型剤等を含有させたものが用いられ、また必要に応じて流動化剤等を添加してもよい。
そして、このようなトナーを製造するにあたっても、従来より一般に採用されている公知の方法で製造することができ、例えば、粉砕法、乳化重合法、懸濁重合法等により製造することができる。
(toner)
The toner T used here is not particularly limited, and a publicly known toner that has been generally used can be used. Generally, a binder resin contains a colorant, a charge control agent, a release agent, and the like. In addition, a fluidizing agent or the like may be added if necessary.
Such a toner can also be produced by a known method that has been generally employed conventionally. For example, it can be produced by a pulverization method, an emulsion polymerization method, a suspension polymerization method, or the like.

トナーに使用するバインダー樹脂としては、ゲルパーミッションクロマトグラフ(GPC)によって測定された数平均分子量(Mn)が1000〜15000の範囲のものを、また軟化温度が80℃〜160℃の範囲のものを、またガラス転移点が50℃〜75℃の範囲のものを用いることが好ましい。   The binder resin used for the toner has a number average molecular weight (Mn) measured by gel permeation chromatography (GPC) in the range of 1000 to 15000, and a softening temperature in the range of 80 to 160 ° C. Moreover, it is preferable to use a glass transition point in the range of 50 ° C to 75 ° C.

上記着色剤としては、従来より一般に使用されている公知のものを用いることができ、例えば、カーボンブラック、アニリンブラック、活性炭、マグネタイト、ベンジジンイエロー、パーマネントイエロー、ナフトールイエロー、フタロシアニンブルー、ファーストスカイブルー、ウルトラマリンブルー、ローズベンガル、レーキーレッド等を用いることができ、一般に上記のバインダー樹脂100重量部に対して2〜20重量部の割合で用いることが好ましい。   As the colorant, known materials that have been conventionally used can be used, such as carbon black, aniline black, activated carbon, magnetite, benzidine yellow, permanent yellow, naphthol yellow, phthalocyanine blue, first sky blue, Ultramarine blue, rose bengal, lake red, or the like can be used, and generally it is preferably used in a ratio of 2 to 20 parts by weight with respect to 100 parts by weight of the binder resin.

上記荷電制御剤としては、従来より一般に使用されている公知のものを用いることができ、例えば、モノアゾ金属錯体、芳香族ヒドロキシカルボン酸系の金属錯体、芳香族ジカルボン酸系の金属錯体等の有機金属錯体やキレート化合物等を用いることができ、一般に上記のバインダー樹脂100重量部に対して1〜10重量部の割合で用いることが好ましい。   As the charge control agent, known ones that have been conventionally used can be used, and examples thereof include organic compounds such as monoazo metal complexes, aromatic hydroxycarboxylic acid metal complexes, and aromatic dicarboxylic acid metal complexes. A metal complex, a chelate compound, etc. can be used, and it is preferable to use generally in the ratio of 1-10 weight part with respect to 100 weight part of said binder resin.

上記離型剤としては、従来より一般に使用されている公知のものを用いることができ、例えば、ポリエチレン、ポリプロピレン、カルナバワックス、サゾールワックス等を単独或いは2種類以上組み合わせて使用することができ、一般に上記のバインダー樹脂100重量部に対して1〜8重量部の割合で用いることが好ましい。   As the mold release agent, known ones that have been generally used can be used, for example, polyethylene, polypropylene, carnauba wax, sazol wax, etc. can be used alone or in combination of two or more, In general, it is preferably used at a ratio of 1 to 8 parts by weight with respect to 100 parts by weight of the binder resin.

上記流動化剤としては、従来より一般に使用されている公知のものを用いることができ、例えば、シリカ、酸化チタン、酸化アルミニウム等の無機微粒子や、アクリル樹脂、スチレン樹脂、シリコン樹脂、フッ素樹脂等の樹脂微粒子を使用することができ、特にシランカプリング剤やチタンカップリング剤やシリコンオイル等で疎水化したものを用いるのが好ましい。そして、このような流動化剤を上記のトナー100重量部に対して0.1〜3重量部の割合で添加して用いるようにする。   As the fluidizing agent, known ones that have been conventionally used can be used. For example, inorganic fine particles such as silica, titanium oxide, aluminum oxide, acrylic resin, styrene resin, silicon resin, fluorine resin, etc. In particular, it is preferable to use a resin particle hydrophobized with a silane coupling agent, a titanium coupling agent, silicon oil or the like. Such a fluidizing agent is added at a ratio of 0.1 to 3 parts by weight with respect to 100 parts by weight of the toner.

<実験例>
次に実験例、比較実験例について説明する。
以下に説明する実験例、比較実験例で採用したトナー担持体(現像ローラ)は次のものである。すなわち、
易接着処理した直径8mmの芯金を型に嵌め、該型内、且つ、該芯金のまわりにカーボンブラックで導電性を調整した液状シリコーンゴムを流し込み加硫後130℃で2時間加硫して成型した。このときゴム硬度は30度、ゴムの厚さは4mmであった。
<Experimental example>
Next, experimental examples and comparative experimental examples will be described.
The toner carrier (developing roller) employed in the experimental examples and comparative experimental examples described below is as follows. That is,
An easy-adhesion-treated core metal with a diameter of 8 mm is fitted into a mold, and liquid silicone rubber whose conductivity is adjusted with carbon black is poured into the mold and around the core metal, followed by vulcanization at 130 ° C. for 2 hours. And molded. At this time, the rubber hardness was 30 degrees and the rubber thickness was 4 mm.

次に、このシリコーンゴムローラをコロナ処理し、シランカップリング剤処理後、粗さ調整剤として粒径5μmのシリカ微粒子及び導電剤としてカーボンブラックを含んだウレタン樹脂塗布液をゴム層の外周にディップ法にて塗布し、表層を形成した。表層の膜厚は15μmであった。抵抗率測定器ハイレスタ(三菱油化社製)にて表面抵抗率を測定したところ、1×109 Ω・cmで、全抵抗を測定したところ2×106 Ωであった。算術平均粗さRaを表面粗さ測定機(サーフコム550 東京精密社製)にて測定したところ1.2μmであった。 Next, this silicone rubber roller is corona-treated, treated with a silane coupling agent, and then a urethane resin coating liquid containing silica fine particles having a particle diameter of 5 μm as a roughness adjusting agent and carbon black as a conductive agent is applied to the outer periphery of the rubber layer. Was applied to form a surface layer. The film thickness of the surface layer was 15 μm. When the surface resistivity was measured with a resistivity meter Hiresta (manufactured by Mitsubishi Yuka Kabushiki Kaisha), it was 1 × 10 9 Ω · cm, and the total resistance was 2 × 10 6 Ω. The arithmetic average roughness Ra was measured with a surface roughness measuring machine (Surfcom 550 manufactured by Tokyo Seimitsu Co., Ltd.) and found to be 1.2 μm.

こうして作製したトナー担持体(現像ローラ)を図1の構成の現像装置にセットし、さらにこの現像装置を図1の構成の画像形成装置に装着した。現像装置におけるトナー帯電用フィルムとして次の実験例1〜3のものを採用した。
感光体帯電用電源PW1から帯電器2に−1.2kVを印加して感光体1の表面を−600Vに一様に接触帯電させ、以下の実験例、比較実験例の条件で網点画像をプリントした。
The toner carrier (developing roller) thus produced was set in the developing device having the configuration shown in FIG. 1, and this developing device was mounted on the image forming apparatus having the configuration shown in FIG. The following experimental examples 1 to 3 were used as toner charging films in the developing device.
A -1.2 kV voltage is applied to the charger 2 from the power supply PW1 for charging the photoconductor to uniformly contact and charge the surface of the photoconductor 1 to -600V, and a halftone image is obtained under the conditions of the following experimental example and comparative experimental example. Printed.

(実験例1)
トナー帯電用フィルムとして、ポリウレタンにカーボンブラックを12wt%添加した溶液をバーコーターによりPET(ポリエチレンテレフタレート)フィルム上に塗布し乾燥させた後、該PETフィルムより剥離したものを用いた。厚みは25μm、表面抵抗率は1×107 Ω/□であった。
(Experimental example 1)
As a toner charging film, a solution obtained by adding 12 wt% of carbon black to polyurethane was applied onto a PET (polyethylene terephthalate) film with a bar coater, dried, and then peeled off from the PET film. The thickness was 25 μm and the surface resistivity was 1 × 10 7 Ω / □.

このトナー帯電用フィルムを図2(A)に示すように現像ローラに近接して設けた。そして現像時、図2(B)に示すように、両者の電位差でトナー帯電用フィルムが現像ローラに吸着するようにした。このとき、現像ローラとトナー帯電用フィルム間の電位差が800Vとなるように、現像ローラに電源PW2より現像バイアスとして−200Vを印加し、トナー帯電用フィルムには電源PW3から−1.0kVを印加した。
現像ローラ上にトナー搬送量が約5g/m2 、トナー帯電量が−25μC/g〜45μC/gのトナー薄層を安定して形成できた。
なお、非現像時には電源PW3をオフした。
This toner charging film was provided in the vicinity of the developing roller as shown in FIG. At the time of development, as shown in FIG. 2B, the toner charging film is attracted to the developing roller by the potential difference between the two. At this time, −200 V is applied as a developing bias from the power source PW2 to the developing roller so that the potential difference between the developing roller and the toner charging film is 800 V, and −1.0 kV is applied to the toner charging film from the power source PW3. did.
A thin toner layer having a toner conveyance amount of about 5 g / m 2 and a toner charge amount of −25 μC / g to 45 μC / g could be stably formed on the developing roller.
Note that the power supply PW3 was turned off during non-development.

(実験例2)
トナー帯電用フィルムは実験例1と同じものを用いた。
このトナー帯電用フィルムを図3(A)に示すように現像ローラに接触させて設けた。そして現像時、図3(B)に示すように、両者の電位差でトナー帯電用フィルムが現像ローラに強く吸着するようにした。このとき、現像ローラとトナー帯電用フィルム間の電位差が800Vとなるように、現像ローラに電源PW2より現像バイアスとして−200Vを印加し、トナー帯電用フィルムには電源PW3から−1.0kVを印加した。
現像ローラ上にトナー搬送量が約5g/m2 、トナー帯電量が−25μC/g〜45μC/gのトナー薄層を安定して形成できた。
なお、非現像時には、トナー帯電用フィルムに−300Vを印加した。
(Experimental example 2)
The same toner charging film as in Experimental Example 1 was used.
This toner charging film was provided in contact with the developing roller as shown in FIG. At the time of development, as shown in FIG. 3B, the toner charging film is strongly adsorbed to the developing roller by the potential difference between the two. At this time, −200 V is applied as a developing bias from the power source PW2 to the developing roller so that the potential difference between the developing roller and the toner charging film is 800 V, and −1.0 kV is applied to the toner charging film from the power source PW3. did.
A thin toner layer having a toner conveyance amount of about 5 g / m 2 and a toner charge amount of −25 μC / g to 45 μC / g could be stably formed on the developing roller.
At the time of non-development, −300 V was applied to the toner charging film.

(実験例3)
トナー帯電用フィルムは実験例1と同じものを用いた。
このトナー帯電用フィルムを現像ローラに近接させて設けた。そして現像時、図4(B)に示すように、両者の電位差でトナー帯電用フィルムが現像ローラに吸着するようにした。このとき、現像ローラとトナー帯電用フィルム間の電位差が800Vとなるように、現像ローラに電源PW2より現像バイアスとして−200Vを印加し、トナー帯電用フィルムには電源PW3から−1.0kVを印加した。
現像ローラ上にトナー搬送量が約5g/m2 、トナー帯電量が−25μC/g〜45μC/gのトナー薄層を安定して形成できた。
なお、非現像時には、トナー帯電用フィルムに−200Vを印加した。その結果、フィルムは図4(A)に示すように感光体1に接触した。
(Experimental example 3)
The same toner charging film as in Experimental Example 1 was used.
The toner charging film was provided close to the developing roller. At the time of development, as shown in FIG. 4B, the toner charging film is attracted to the developing roller by the potential difference between the two. At this time, −200 V is applied as a developing bias from the power source PW2 to the developing roller so that the potential difference between the developing roller and the toner charging film is 800 V, and −1.0 kV is applied to the toner charging film from the power source PW3. did.
A thin toner layer having a toner conveyance amount of about 5 g / m 2 and a toner charge amount of −25 μC / g to 45 μC / g could be stably formed on the developing roller.
At the time of non-development, −200 V was applied to the toner charging film. As a result, the film contacted the photoreceptor 1 as shown in FIG.

(比較例1)
実験例1〜3で用いたトナー帯電用フィルムの代わりに、帯電ローラ(直径3mmのステンレススチール製棒に厚さ1mmの導電性ウレタン層を設けたもの。表面抵抗率は1×1010Ω/□)を用いた。現像ローラには現像バイアスとして−200Vを印加し、トナー帯電用の帯電ローラには−1.7kVを印加した。
(比較例2)
実験例1〜3においてトナー帯電用フィルムに非現像時にも現像時と同じ電圧を印加した。
(Comparative Example 1)
Instead of the toner charging film used in Experimental Examples 1 to 3, a charging roller (3 mm diameter stainless steel rod provided with a 1 mm thick conductive urethane layer. The surface resistivity is 1 × 10 10 Ω / □) was used. A developing bias of −200 V was applied to the developing roller, and −1.7 kV was applied to the charging roller for charging the toner.
(Comparative Example 2)
In Experimental Examples 1 to 3, the same voltage as that during development was applied to the toner charging film even during non-development.

<現像ローラ上トナーの帯電均一性及びトナー帯電用部材汚れ評価>
現像ローラ上トナーの帯電均一性及びトナー帯電用部材汚れ評価を次表に示す。
現像ローラ上トナーの帯電均一性はローラ上の5ケ所の帯電量を測定して評価した。
トナー帯電用部材汚れは、汚れをテープ剥離することで評価した。
<Evaluation of charging uniformity of toner on developing roller and contamination of toner charging member>
The following table shows the charging uniformity of toner on the developing roller and the evaluation of toner charging member contamination.
The charging uniformity of the toner on the developing roller was evaluated by measuring the charging amount at five locations on the roller.
Toner charging member contamination was evaluated by tape-removing the contamination.

次表において帯電均一性及び帯電用部材汚れの評価欄において「○」はトナー帯電用部材にトナーの付着がほとんど見られず、トナーの帯電均一性良好で、良好な画像が形成されたことを示している。「×」はトナーがトナー帯電用部材全体に多量に付着し、そのトナーが固着し、画像に筋ムラが多発したことを示している。「△」はトナー帯電用部材(フィルム)の先端部にトナーが付着し、そのトナーが一部固着し、画像の一部に筋ムラが発生したことを示している。   In the following table, in the evaluation section for charging uniformity and charging member contamination, “◯” indicates that toner adhesion was hardly observed on the toner charging member, and that a good image was formed with good toner charging uniformity. Show. "X" indicates that a large amount of toner adheres to the entire toner charging member, the toner is fixed, and streak unevenness occurs frequently in the image. “Δ” indicates that the toner adheres to the front end portion of the toner charging member (film), the toner is partially fixed, and streak unevenness occurs in a part of the image.


トナー帯電用部材 初期の帯電均一性 5000枚印刷後の帯電均一性
及び帯電用部材汚れ 及び帯電用部材汚れ
実験例1 フィルム ○(良好) ○
実験例2 フィルム ○(良好) ○
実験例3 フィルム ○(良好) ○
比較例1 帯電ローラ ○(良好) ×
比較例2 フィルム ○(良好) △
Table Toner charging material Initial charge uniformity Charge uniformity after printing 5000 sheets
And Charging Member Dirt and Charging Member Dirt Experiment 1 Film ○ (Good) ○
Experimental Example 2 Film ○ (Good) ○
Experimental Example 3 Film ○ (Good) ○
Comparative Example 1 Charging roller ○ (Good) ×
Comparative Example 2 Film ○ (Good) △

比較例1及び2においては、実験例1〜3と同じ条件で評価を行ったところ、比較例1及び2共に印刷初期においては現像ローラとトナー帯電部材との接触部分にトナーの溜まりや固着、トナー汚れなどは殆ど見られなかった。しかし、印刷枚数の増加に伴いトナー溜まり(一部固着)が発生し、その結果現像ローラ上のトナー層が乱れ、筋ムラが発生した。また、トナー帯電用部材にトナーが多量に付着するようになり、帯電性能の低下が見られた。本発明に係る実験例1〜3では5000枚印刷後でも良好な状態が維持された。   In Comparative Examples 1 and 2, the evaluation was performed under the same conditions as in Experimental Examples 1 to 3. As a result, in both Comparative Examples 1 and 2, toner accumulated or adhered to the contact portion between the developing roller and the toner charging member in the initial printing stage. Almost no toner stains were seen. However, toner accumulation (partially fixed) occurred as the number of printed sheets increased, and as a result, the toner layer on the developing roller was disturbed, resulting in streak unevenness. Further, a large amount of toner came to adhere to the toner charging member, and a decrease in charging performance was observed. In Experimental Examples 1 to 3 according to the present invention, a good state was maintained even after printing 5000 sheets.

本発明の現像装置及び画像形成装置は電子写真方式の画像形成において長期に渡り安定した良好な画像を形成することに利用できる。   The developing device and the image forming apparatus of the present invention can be used to form a stable and good image for a long period of time in electrophotographic image formation.

本発明に係る画像形成装置の1例の概略構成を示す図である。1 is a diagram illustrating a schematic configuration of an example of an image forming apparatus according to the present invention. 本発明に係る現像装置におけるトナー帯電用フィルムの1例の動作状態を示す図である。It is a figure which shows the operation state of one example of the film for toner charging in the developing device which concerns on this invention. 本発明に係る現像装置におけるトナー帯電用フィルムの他の例の動作状態を示す図である。It is a figure which shows the operation state of the other example of the film for toner charging in the developing device which concerns on this invention. 本発明に係る現像装置におけるトナー帯電用フィルムのさらに他の例の動作状態を示す図である。It is a figure which shows the operation state of the further another example of the film for toner charging in the image development apparatus concerning this invention. 図5(A)はローラ型のトナー担持体の1例の断面図であり、図5(B)はベルト型のトナー担持体の1例の断面図である。FIG. 5A is a cross-sectional view of an example of a roller-type toner carrier, and FIG. 5B is a cross-sectional view of an example of a belt-type toner carrier. 従来現像装置例を示す図である。It is a figure which shows the example of a conventional image development apparatus.

符号の説明Explanation of symbols

1 感光体
2 帯電器
PW1 感光体帯電用電源
3 現像装置
30 現像装置ケース
31 アジテータ
32 現像ローラ(ローラ型トナー担持体)
321 芯金
322 ベース層
323 表層
32’ ベルト型トナー担持体
321’ベース層
322’表層
PW2 現像バイアス電源
33 トナー供給ローラ
34 トナー規制部材
35 電極
36 トナー帯電用フィルム
PW3 トナー帯電用電源
4 転写装置
PW4 転写用電源
5 クリーニング装置
51 クリーニングブレード
52 廃トナー容器
6 画像露光装置
7 記録剤供給カセット
71 給紙ローラ
S 用紙
8 定着器
9 排紙トレー
DESCRIPTION OF SYMBOLS 1 Photoconductor 2 Charger PW1 Photoconductor charging power supply 3 Developing device 30 Developing device case 31 Agitator 32 Developing roller (roller type toner carrier)
321 Core metal 322 Base layer 323 Surface layer 32 ′ Belt type toner carrier 321 ′ Base layer 322 ′ surface layer PW2 Developing bias power supply 33 Toner supply roller 34 Toner regulating member 35 Electrode 36 Toner charging film PW3 Toner charging power supply 4 Transfer device PW4 Transfer power supply 5 Cleaning device 51 Cleaning blade 52 Waste toner container 6 Image exposure device 7 Recording agent supply cassette 71 Paper feed roller S Paper 8 Fixing device 9 Paper discharge tray

Claims (7)

静電潜像の形成された像担持体に現像剤を接触させて該静電潜像を現像する現像剤担持体と、前記現像剤担持体に現像剤を介して圧接する現像剤規制部材と、前記像担持体とこれに臨む現像剤担持体とで形成される現像領域よりも該現像剤担持体の回転方向において上流側に、且つ、該現像剤担持体に対する前記現像剤規制部材の圧接部よりも該現像剤担持体の回転方向において下流側に該現像剤担持体上の現像剤に近接又は接触するように設けられたフイルム状の現像剤帯電部材とを備え、前記静電潜像の現像時には前記現像剤帯電部材に前記現像剤担持体上の現像剤を帯電させる電圧が印加されて該現像剤帯電部材が現像剤担持体へ静電吸着されるとともに該現像剤を帯電させ、非現像時には、該現像剤帯電部材と現像剤担持体との接触面積が現像時よりも小さく設定されることを特徴とする現像装置。 A developer carrier that develops the electrostatic latent image by bringing a developer into contact with the image carrier on which the electrostatic latent image is formed; and a developer regulating member that is pressed against the developer carrier via the developer. The developer regulating member is in pressure contact with the developer carrying member upstream of the developing region formed by the image carrier and the developer carrying member facing the image carrying member and in the rotational direction of the developer carrying member. A developer charging member in the form of a film provided on the downstream side in the rotation direction of the developer carrying member relative to the portion so as to be close to or in contact with the developer on the developer carrying member. At the time of development, a voltage for charging the developer on the developer carrying member is applied to the developer charging member so that the developer charging member is electrostatically adsorbed to the developer carrying member and the developer is charged. At the time of non-development, contact between the developer charging member and the developer carrier Developing apparatus is characterized in that the product is set smaller than the time of development. 非現像時に前記現像剤帯電部材を前記現像剤担持体と非接触にする請求項1記載の現像装置。 The developing device according to claim 1, wherein the developer charging member is brought into non-contact with the developer carrying member during non-development. 非現像時に前記現像剤担持体と前記現像剤帯電部材との電位差を制御することで前記現像剤帯電部材と現像剤担持体との接触面積を現像時より小さくする請求項1又は2記載の現像装置。 The development according to claim 1 or 2, wherein a contact area between the developer charging member and the developer carrying member is made smaller than that during development by controlling a potential difference between the developer carrying member and the developer charging member during non-development. apparatus. 非現像時に前記現像剤帯電部材と現像剤担持体との間に印加する電圧を、現像時に該現像剤帯電部材と現像剤担持体との間に印加する電圧よりも低くすることで前記現像剤帯電部材と現像剤担持体との接触面積を現像時より小さくする請求項1又は2記載の現像装置。 The developer applied by lowering the voltage applied between the developer charging member and the developer carrying member during non-development than the voltage applied between the developer charging member and the developer carrying member during development. The developing device according to claim 1, wherein a contact area between the charging member and the developer carrying member is smaller than that during development. 前記像担持体の帯電電位がVa、前記現像剤担持体への印加電圧がVb、前記現像剤帯電部材への印加電圧がVcであるとき、非現像時における|Va−Vc|及び|Vb−Vc|が|Va−Vc|≧|Vb−Vc|の条件を満たす請求項1記載の現像装置。 When the charging potential of the image bearing member is Va, the applied voltage to the developer bearing member is Vb, and the applied voltage to the developer charging member is Vc, | Va−Vc | and | Vb− at the time of non-development The developing device according to claim 1, wherein Vc | satisfies a condition of | Va−Vc | ≧ | Vb−Vc |. 像担持体と、該像担持体上に静電潜像を形成する潜像形成手段と、該像担持体上に形成される静電潜像を現像するための請求項1から5のいずれかに記載の現像装置とを備えた画像形成装置。 6. The image carrier, latent image forming means for forming an electrostatic latent image on the image carrier, and developing the electrostatic latent image formed on the image carrier. An image forming apparatus comprising the developing device according to 1. 非現像時に前記現像剤帯電部材を前記像担持体に接触させる請求項6記載の画像形成装置。 The image forming apparatus according to claim 6, wherein the developer charging member is brought into contact with the image carrier during non-development.
JP2003409306A 2003-12-08 2003-12-08 Developing device and image forming apparatus Withdrawn JP2005172937A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007086361A (en) * 2005-09-21 2007-04-05 Fuji Xerox Co Ltd Developing device and image forming apparatus using the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007086361A (en) * 2005-09-21 2007-04-05 Fuji Xerox Co Ltd Developing device and image forming apparatus using the same

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