JP2005120331A - Gateway frame of carbonizing oven having extremely less deformation and crack - Google Patents

Gateway frame of carbonizing oven having extremely less deformation and crack Download PDF

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JP2005120331A
JP2005120331A JP2003391431A JP2003391431A JP2005120331A JP 2005120331 A JP2005120331 A JP 2005120331A JP 2003391431 A JP2003391431 A JP 2003391431A JP 2003391431 A JP2003391431 A JP 2003391431A JP 2005120331 A JP2005120331 A JP 2005120331A
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furnace
carbonization furnace
frame
oven
heat
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Kesao Yamazaki
今朝夫 山▲崎▼
Sadao Furukawa
貞男 古川
Takuro Iwama
卓郎 岩間
Yasuo Nagashima
康夫 長島
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JFE Steel Corp
Yamazaki Corp
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JFE Steel Corp
Yamazaki Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a gateway frame of a carbonizing oven, preventing its partial loss by fusion caused by a high dry distillation temperature of coal particles and also reducing the occurring of deformation and crack such as C-shaped warpage, curved deformation, etc., caused by an effect from unavoidable expansion. <P>SOLUTION: The gateway frame of the carbonizing oven is characterized in that a heat-resistant alloy member 13 is fitted with play in an engaging joint form to the inner circumferential face of the carbonizing oven side of an upper beam member 11 of the gateway frame 4 of the carbonizing oven to which a knife-edge sectional shape sealing flange member, provided at the carbonizing oven side of the oven lid for opening and closing the gateway of the carbonizing oven of a coke oven, is abutted. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

発明の詳細な説明Detailed Description of the Invention

本発明は、コークス炉の炭化室(炉)出入口を開閉する炉蓋のシール用フランジ部材を当接する、炭化炉の炉口枠に関するものである。  The present invention relates to a furnace port frame of a carbonization furnace that abuts a sealing flange member of a furnace lid that opens and closes a carbonization chamber (furnace) entrance and exit of a coke oven.

コークス炉の炭化炉出入口を開閉する炉蓋は、炭化炉に装入された石炭粒子の高い乾留温度に耐えられる頑丈な鋼鉄製フレームの構造体で、石炭粒子の乾留中に発生するCOやCHなどの地球環境汚染ガスリークを防止するため、ガスシール性の高い構造に製作されている。この事から高いシール性を目的とする炭化炉蓋に関しては、多くの特許公報がある。例えば実開平7−38156号公報には「炭化炉締結構造に設けた金属製の炉蓋本体に、該炉蓋本体内の空気を閉じ込めて該空気の対流により炉蓋本体の反りや曲がりを防止しかつ該炉蓋本体内の加熱により炉口を保温する密閉構造のボックスを介して、炭化炉口枠に当接するナイフエッジ断面形状のシール用フランジ部材を周設した押圧構造のシールプレートを設け、さらに炭化炉の炉口付近に突入する耐火煉瓦を設けた炉蓋」で、密閉ボックスで閉じ込めた炉蓋本体内に空気の対流を利用して炉蓋本体内外側の温度差を少なくして本体歪み(反りや曲がり)を極力小さくしてシール用フランジ部材のガスシール追従性を向上させた炉蓋がある。また特開2001−288472号公報には「炭化炉口を開閉する炉蓋フレームの炭化炉側に、ナイフエッジ断面形状のフランジ部材を周設したシールプレートを介して炉内プレート、耐熱パッキングシート、炭化炉内に突入する耐火煉瓦などからなる重合部材をスライドプレートを設けると共に、さらにシールプレートのフランジ部材を炭化炉側へ押圧する伸縮自在機構具を付設した、炭化炉内の気密性に優れた炉蓋」などが開発されている。The furnace lid that opens and closes the carbonization furnace inlet / outlet of the coke oven is a sturdy steel frame structure that can withstand the high carbonization temperature of coal particles charged in the carbonization furnace. CO and CH generated during the carbonization of coal particles In order to prevent global environment pollutant gas leaks such as 4, etc., it is manufactured in a structure with a high gas sealing property. For this reason, there are many patent publications relating to carbonization furnace lids intended for high sealing performance. For example, in Japanese Utility Model Publication No. 7-38156, “the furnace lid main body is confined in a metal furnace lid main body provided in the carbonization furnace fastening structure to prevent warping and bending of the furnace lid main body by convection of the air. In addition, a seal plate having a pressing structure is provided in which a sealing flange member having a knife edge cross-sectional shape that abuts against the carbonization furnace port frame is provided through a sealed box that keeps the furnace port warmed by heating in the furnace lid body. In addition, the `` furnace lid provided with refractory bricks that enter the vicinity of the furnace port of the carbonization furnace '' reduces the temperature difference between the inside and outside of the furnace lid using convection of air inside the furnace lid body confined in a sealed box. There is a furnace lid in which main body distortion (warping and bending) is minimized to improve the gas seal followability of the sealing flange member. Further, JP 2001-288472 A discloses a “in-furnace plate, heat-resistant packing sheet, through a seal plate in which a flange member having a knife-edge cross-sectional shape is provided around the carbonization furnace side of the furnace lid frame that opens and closes the carbonization furnace port, Excellent heat-tightness in the carbonization furnace with a slide plate for superposed members made of refractory bricks that enter the carbonization furnace and a retractable mechanism that presses the flange member of the seal plate toward the carbonization furnace. A “furnace lid” has been developed.

実開平7−38156号公報(第4頁 図1)            Japanese Utility Model Publication No. 7-38156 (page 4 Fig. 1) 特開2001−288472号公報(第1頁 図3)            Japanese Patent Laying-Open No. 2001-288472 (first page, FIG. 3)

発明が解決しようとする課題Problems to be solved by the invention

上記の様にいずれの炉蓋も、耐熱構造でかつ気密構造に設計されている。しかしながら、シールプレートの周端部に設けたフエッジ断面形状のフランジ部材を当接する厚肉(160mm程度の鋳鉄製)の炭化炉口枠は、石炭粒子の高い乾留温度に曝されるため、枠内(開口)内周面の炭化炉側で、部分溶損する問題があった。また炉蓋を開閉する毎に急熱と急冷の熱サイクルが繰り返される使用条件の中で、炭化炉口枠が徐々にC形反りや湾曲変形を起こし、炉蓋との当接間に隙間を形成し、炉内発生ガスを放出する問題があった。さらに炭化炉口枠の上方桁部材においては、炉口内周面の炭化炉側あるいはその内周両隅角部から亀裂が発生し、上方向に大きく伝播する問題もあった。従って、気密性の優れた炉蓋を炭化炉口枠に当接しても、炭化炉口枠にC形反りや湾曲変形や亀裂が発生し、炭化炉内の気密性が長期間にわたって保持されない問題があった。  As described above, each furnace lid is designed to have a heat-resistant structure and an airtight structure. However, the thick-walled (160 mm cast iron) carbonization furnace mouth frame that abuts the flange cross-sectional flange member provided at the peripheral edge of the seal plate is exposed to the high dry distillation temperature of coal particles. (Opening) There was a problem of partial melting on the carbonization furnace side of the inner peripheral surface. Also, the carbonization furnace frame gradually undergoes C-shaped warping and bending deformation under the usage conditions in which rapid heating and rapid cooling heat cycles are repeated each time the furnace lid is opened and closed, and a gap is formed between the contact with the furnace lid. There was a problem of forming and releasing the gas generated in the furnace. Further, in the upper girder member of the carbonization furnace port frame, there is a problem that cracks are generated from the carbonization furnace side of the inner peripheral surface of the furnace port or both corners of the inner periphery and propagate greatly upward. Therefore, even when a furnace lid with excellent airtightness is brought into contact with the carbonization furnace frame, C-shaped warpage, curved deformation or cracking occurs in the carbonization furnace frame, and the airtightness in the carbonization furnace is not maintained for a long time. was there.

本発明者らは先ず、実用コークス炉でこの問題を発生した炭化炉口枠を供試材にして外観観察や金属組織観察や各種の材質試験からその原因について調査した結果、炭化炉口枠の部分溶損は、鋳鉄材料が石炭粒子の高い燃焼温度に耐えられず、終極的に起こした現象であると考察した。また炭化炉口枠のC形反りや湾曲変形は、炉蓋の開閉毎に繰り返される加熱冷却の熱サイクルで起こる化合炭素の黒鉛化による膨張とA変態を通過する際に生じる膨張、大きく成長した片状黒鉛の間隙を通って内部に侵入した炭化炉内ガスや空気が鋳鉄中の鉄や珪素を酸化し体積が大きい酸化物を生成して次第に増加する膨張などによって生じるものと考察した。さらに亀裂は、外観観察から炭化炉口枠の上方桁部材が特に高く加熱された形跡があり、該温度から冷却される外部の収縮と内部から大きな引張応力を受ける熱応力の影響を受けて発生し、強度の低い低片状黒鉛に沿って徐々に大きく進展するものと考察した。First, as a result of investigating the cause of the carbonization furnace frame that caused this problem in a practical coke oven from the appearance observation, the metallographic structure observation, and various material tests, the carbonization furnace frame was generated. It was considered that the partial erosion was a phenomenon that the cast iron material could not withstand the high combustion temperature of coal particles and eventually occurred. The C-shaped warping and bending deformation of the carbonization furnace mouth frame, expansion occurs while passing through the expansion and the A 1 transformation by graphitization of compounds the carbon that occurs in thermal cycle of heating and cooling which are repeated for each opening and closing of the furnace lid, large growth It was considered that the carbonization furnace gas and air that entered the inside of the flake graphite through the gap oxidized the iron and silicon in the cast iron to produce oxides with a large volume, which gradually increased. In addition, cracks appear to have been observed from the observation of the appearance that the upper girder member of the carbonization furnace frame has been heated to a particularly high temperature, affected by external shrinkage that is cooled from the temperature and thermal stress that is subject to large tensile stress from the inside. However, it was considered that it gradually advanced greatly along the low flake graphite with low strength.

課題を解決するための手段Means for solving the problem

さらに本発明者らは、上記した現象の知見や考察を基に、石炭粒子の高い燃焼温度による炭化炉口枠の部分溶損を防止し、不可避的な膨張の影響で生じるC形反りや湾曲変形と亀裂の発生を少なめた炭化炉口枠を提供する事を目的に種々検討した結果、溶損と変形や亀裂を起こし易い箇所すなわち炭化炉口枠の上方桁部材に耐熱金属部材を遊嵌する事で、目的が達成される事を知見した。
本発明はこの知見に基づいて構成したもので、その要旨は、コークス炉の炭化炉出入口を開閉する炉蓋の炭化炉側に設けたナイフエッジ断面形状のシール用フランジ部材を当接する炭化炉口枠の上方桁部材でかつ開口側内周面の炭化炉側に、耐熱合金部材を掛合継手形状で遊嵌した変形と亀裂が極めて少ない炭化炉口枠である。
Furthermore, the present inventors prevent partial melting of the carbonization furnace frame due to the high combustion temperature of the coal particles based on the knowledge and consideration of the phenomenon described above, and C-shaped warping and bending caused by the influence of inevitable expansion. As a result of various investigations aimed at providing a carbonization furnace frame with less deformation and cracking, a heat-resistant metal member is loosely fitted to a place where erosion, deformation and cracks are likely to occur, that is, an upper girder member of the carbonization furnace frame. I found out that the purpose was achieved.
The present invention is configured on the basis of this knowledge, and the gist thereof is a carbonization furnace port for contacting a sealing flange member having a knife edge cross-sectional shape provided on the carbonization furnace side of the furnace lid for opening and closing the carbonization furnace entrance and exit of the coke oven This is a carbonization furnace opening frame in which the heat resistant alloy member is loosely fitted in the shape of a latching joint on the carbonization furnace side of the opening side inner peripheral surface as the upper girder member of the frame, and the deformation and cracks are extremely small.

以下、本発明について、図面を参照しながら詳細に説明する。
図1は本発明の一実施例で、炭化炉出口(または入口)近傍部の炭化炉高方向の断面図を示す。図1において、1は押圧式の炉蓋で、炭化炉2のコークス押出機側またはコークス排出側の出入口3の周縁部に装着された炭化炉口枠4を押しながら該炭化炉2を密閉するもので、開閉自在な鋼鉄製枠体フレーム5の炭化炉側には、炭化炉口枠4を押圧するナイフエッジ断面形状のフランジ部材6を周縁部に設けた可撓性耐熱金属材のシールプレート7と必要によってはさらに耐熱性パッキングシートを介して、炭化炉内に突出する耐火煉瓦8または該耐火煉瓦8に不定形耐火物材料を施した二層構造の耐火物部材あるいは耐熱金属短冊板を縦横に配列して構成した炉内ガス発生回遊離隔室と断熱ボックスからなる耐熱構造物など、各種の耐熱部材を重合する耐熱構造物が設けられている。さらに鋼鉄製枠体フレーム5の炉外側には、炭化炉1の出入口3を強く押圧し締結するための圧縮バネやボルトなどの締結用部材を組み合わせて構成された閂9、また前記したシールプレート7の周縁部には、フランジ部材6を炭化炉口枠4に押圧するシリンダーやバネなどを使用した進退自在な押圧治具10が設けられている。すなわち、炉蓋1は、炭化炉2の出入口3を閉塞し該炭化炉内を密閉する耐熱構造体に設けられたもので、本発明においてはその構造について特に限定するものではなく、上記以外に通常使用される炉蓋構造であってもよい。
Hereinafter, the present invention will be described in detail with reference to the drawings.
FIG. 1 shows an embodiment of the present invention, and shows a sectional view in the high direction of the carbonization furnace in the vicinity of the carbonization furnace outlet (or inlet). In FIG. 1, reference numeral 1 denotes a press-type furnace lid, which seals the carbonization furnace 2 while pushing the carbonization furnace frame 4 mounted on the peripheral edge of the inlet / outlet 3 on the coke extruder side or the coke discharge side of the carbonization furnace 2. On the carbonization furnace side of the steel frame body 5 that can be freely opened and closed, a flexible heat-resistant metal seal plate provided with a flange member 6 having a knife-edge cross-sectional shape that presses the carbonization furnace mouth frame 4 at the peripheral edge. 7 and, if necessary, a refractory brick 8 protruding into the carbonization furnace or a two-layer refractory member or a refractory metal strip with an irregular refractory material applied to the refractory brick 8 through a heat-resistant packing sheet. A heat-resistant structure for polymerizing various heat-resistant members is provided, such as a heat-resistant structure composed of in-furnace gas generation regenerator compartments and heat insulation boxes arranged vertically and horizontally. Further, on the outside of the furnace of the steel frame 5, a flange 9 formed by combining a fastening member such as a compression spring or a bolt for strongly pressing and fastening the entrance / exit 3 of the carbonization furnace 1, and the above-described seal plate 7 is provided with a pressing jig 10 that can be moved forward and backward using a cylinder, a spring, or the like that presses the flange member 6 against the carbonization furnace mouth frame 4. That is, the furnace lid 1 is provided in a heat-resistant structure that closes the inlet / outlet 3 of the carbonization furnace 2 and seals the inside of the carbonization furnace. In the present invention, the structure is not particularly limited. A normally used furnace lid structure may be used.

図2は、炭化炉口枠4の一実施例を下方側切欠図面で示したもので、上方桁部材の炉高方向断面図aとその炭化炉側外観図bを示す。炭化炉口枠4は、上方桁部材11と下方桁部材(切欠図面のため、図示せず)と柱部材12の2本を枠体形状に繋ぎ合わせたものあるいは一体形状に鋳造または加工を施して製造された厚肉鋳鉄製のもので、過酷な使用条件で大きな膨脹と亀裂を起こし易いとされる上方桁部材11の一部または全部さらには隣接する柱部材12との隅角近傍部でかつ枠内(開口側)内周面の炭化炉側に、耐熱合金部材13を掛合継手形状で遊嵌したものである。つまり、本発明は、鋳鉄材料の黒鉛化と酸化物がもたらす膨脹による炭化炉口枠4の形状変化さらには片状黒鉛に沿って起こる亀裂の問題を起こし易い該炭化炉口枠4の箇所に、黒鉛化や多くの酸化物を生成する事のない耐熱金属部材を遊嵌する事で、上記した問題を解決しようとするものである。耐熱合金部材とは、結晶組織上からフェライト系やオーステナイト系に属する金属で、高温度において形状不変で強度を保持し、しかも高温ガスの侵食にも耐えられる特性を有する金属で、鋼にクロム、モリブデン、珪素やタングステンなどの特殊元素を含有した耐熱鋼で例えば耐熱クロム鋼、ニッケルクロム耐熱鋼、モリブデン耐熱鋼、シルクロム耐熱鋼などの他に、インコネル金属の様なニッケル基合金など特殊金属を使用してもよい。さらに本発明においては、上方桁部材11と該上方桁部材11に遊嵌する耐熱合金部材13の両部材が、屈折した継手形状でかつお互いに掛け合ういわゆる掛合継手形状で、炭化炉側から両部材の継手面を擦りながら進退自在に挿嵌し遊嵌された継手構造に組立てられているため、炉蓋1の開閉動作中に耐熱合金部材13を脱落する事がなく、炭化炉から飛来する石炭微粒子の侵入を防いで継手間のタール化を防止する共に、遊嵌する事で出来る隙間が各部材の膨脹を吸収するため、炭化炉口枠のC形反りや湾曲変形さらには亀裂の発生を抑制し、例え発生しても耐熱合金部材13への伝播を防止する効果を奏する。
14は螺子込みボルトである。螺子込みボルト14は、上方桁部材11に挿嵌された耐熱合金部材13が、炭化炉口枠4の運搬中やコークス操業中あるいは炉蓋の開閉作業中に何らかの衝撃を受けて脱落しまた所定の遊嵌位置から移動して該炭化炉口枠4の機能低下を防止するものであって、必要に応じて設けられる耐熱金属部材13の締結具である。
FIG. 2 shows an embodiment of the carbonization furnace mouth frame 4 in a lower cutaway drawing, and shows a cross sectional view a of the upper girder member in the furnace height direction and a carbon furnace side external view b thereof. The carbonization furnace opening frame 4 is cast or processed into one in which the upper girder member 11, the lower girder member (not shown for notch drawing) and the column member 12 are joined together in a frame shape or in an integral shape. In the vicinity of the corner of the upper girder member 11 which is made of thick cast iron manufactured in this way and is likely to cause large expansion and cracking under severe use conditions, and also to the adjacent column member 12. In addition, the heat-resistant alloy member 13 is loosely fitted in the shape of a hook joint on the carbonization furnace side of the inner peripheral surface of the frame (opening side). In other words, the present invention provides the carbonization furnace frame 4 where the shape change of the carbonization furnace frame 4 due to graphitization of the cast iron material and the expansion caused by the oxide, and the problem of cracks that occur along the flake graphite are likely to occur. The above-described problems are to be solved by loosely fitting a heat-resistant metal member that does not graphitize or generate many oxides. A heat-resistant alloy member is a metal that belongs to ferrite and austenite from the crystal structure, has a shape that does not change shape at high temperatures, and has strength that can withstand erosion of high-temperature gas. Heat-resistant steel containing special elements such as molybdenum, silicon, tungsten, etc. In addition to heat-resistant chromium steel, nickel-chrome heat-resistant steel, molybdenum heat-resistant steel, sill chromium heat-resistant steel, etc., special metals such as nickel-based alloys such as Inconel metal are used. May be. Further, in the present invention, both the upper girder member 11 and the heat-resistant alloy member 13 loosely fitted to the upper girder member 11 have a refracted joint shape and a so-called hooked joint shape, and both members from the carbonization furnace side. Since the joint surface is assembled so that it can be freely moved back and forth while rubbing the joint surface of the steel, the heat-resistant alloy member 13 is not dropped during the opening / closing operation of the furnace lid 1, and the coal flying from the carbonization furnace In addition to preventing the entry of fine particles and preventing tar formation between joints, the gap formed by loose fitting absorbs the expansion of each member. Even if it occurs, even if it occurs, there is an effect of preventing propagation to the heat-resistant alloy member 13.
Reference numeral 14 denotes a screw bolt. The screw bolt 14 is dropped when the heat-resistant alloy member 13 inserted into the upper girder member 11 is subjected to some impact during transportation of the carbonization furnace mouth frame 4, during coke operation, or during opening and closing operation of the furnace lid, This is a fastener for the heat-resistant metal member 13 that is moved from the loose-fitting position to prevent the function of the carbonization furnace mouth frame 4 from being lowered.

上記の様に構造に組立てられた本発明の炭化炉口枠4は、従来から使用される鋳鉄製の炭化炉口枠と同様に、炭化炉2の出入口3の周縁部に装着し、炉蓋1にシールプレート7を介して設けられたナイフエッジ断面形状のフランジ部材6に押圧さながら該炭化炉内を密封する。  The carbonization furnace frame 4 of the present invention assembled in the structure as described above is attached to the peripheral edge of the entrance / exit 3 of the carbonization furnace 2 in the same manner as the conventional cast iron carbonization furnace frame. The inside of the carbonizing furnace is sealed while being pressed by a flange member 6 having a knife edge cross-sectional shape provided in 1 through a seal plate 7.

発明の効果The invention's effect

以上述べた様な本発明の炭化炉口枠4によれば、過熱を受ける上方桁部材11でかつ開口側内周面の炭化炉側に、黒鉛組織を生成しない耐熱合金部材13を掛合継手形状でしかも膨脹を考慮した遊嵌構造の鋳鉄製構造物に製作されているため、部分溶損を起こす事もなく、C形反りや湾曲変形を著しく低減する。例え膨脹の大きい鋳鉄部材で亀裂が発生しても掛合継手形状の隙間によって伝播阻止されるため、耐熱合金部材13に何ら影響を及ぼす事なく、本発明の炭化炉口枠4は長期間継続して使用する事ができる。  According to the carbonization furnace mouth frame 4 of the present invention as described above, the heat resistant alloy member 13 that does not generate a graphite structure is formed on the upper girder member 11 that receives overheating and on the carbonization furnace side of the opening side inner peripheral surface. Moreover, since it is manufactured as a cast-iron structure having a loose fitting structure in consideration of expansion, C-shaped warpage and curved deformation are remarkably reduced without causing partial melting damage. For example, even if a crack is generated in a cast iron member having a large expansion, propagation is prevented by the clearance of the hook joint shape, so that the heat-resistant alloy member 13 is not affected and the carbonization furnace frame 4 of the present invention continues for a long time. Can be used.

本発明における炭化炉出口近傍部の一実施例で、炉高方向の断面図を示す。  1 is a cross-sectional view in the furnace height direction in one embodiment of the vicinity of a carbonization furnace outlet in the present invention. 炭化炉口枠の一実施例を下方側切欠図面で示したもので、上方桁部材炉高方向の断面図aとその炭化炉側外観図bを示す。  An embodiment of the carbonization furnace frame is shown in a lower side cutaway drawing, and shows a sectional view a in the upper girder member furnace height direction and an appearance view b on the side of the carbonization furnace.

符号の説明Explanation of symbols

1 炉蓋
2 炭化炉
3 出入口
4 炭化炉口枠
6 シール用フランジ部材
11 上方桁部材
13 耐熱合金部材
DESCRIPTION OF SYMBOLS 1 Furnace 2 Carbonization furnace 3 Entrance / exit 4 Carbonization furnace port frame 6 Flange member for sealing 11 Upper girder member 13 Heat-resistant alloy member

Claims (1)

コークス炉の炭化炉(2)の出入口(3)を開閉する炉蓋(1)の炭化炉側に設けたナイフエッジ断面形状のシール用フランジ部材(6)を当接する炭化炉口枠(4)の上方桁部材(11)でかつ開口側内周面の炭化炉側に、耐熱合金部材(13)を掛合継手形状で遊嵌した事を特徴とする変形と亀裂が極めて少ない炭化炉口枠。  A carbonization furnace frame (4) that abuts a sealing flange member (6) having a knife edge cross-sectional shape provided on the carbonization furnace side of a furnace lid (1) that opens and closes the inlet / outlet (3) of the carbonization furnace (2) of the coke oven. A carbonizer furnace frame having very little deformation and cracking, characterized in that a heat-resistant alloy member (13) is loosely fitted in the shape of a hook joint on the opening side inner peripheral surface of the upper girder member (11).
JP2003391431A 2003-10-17 2003-10-17 Gateway frame of carbonizing oven having extremely less deformation and crack Pending JP2005120331A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2003391431A JP2005120331A (en) 2003-10-17 2003-10-17 Gateway frame of carbonizing oven having extremely less deformation and crack

Publications (1)

Publication Number Publication Date
JP2005120331A true JP2005120331A (en) 2005-05-12

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Family Applications (1)

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Country Link
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101793463B (en) * 2009-09-18 2012-07-18 苏州新长光热能科技有限公司 Crossbeam of hanging door lintel
CN115448721A (en) * 2022-09-07 2022-12-09 重庆镪正科技有限公司 Copper-impregnated carbon sliding plate material and preparation method of copper-impregnated carbon sliding plate

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101793463B (en) * 2009-09-18 2012-07-18 苏州新长光热能科技有限公司 Crossbeam of hanging door lintel
CN115448721A (en) * 2022-09-07 2022-12-09 重庆镪正科技有限公司 Copper-impregnated carbon sliding plate material and preparation method of copper-impregnated carbon sliding plate
CN115448721B (en) * 2022-09-07 2023-11-17 重庆镪正科技有限公司 Preparation method of copper-impregnated carbon sliding plate

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