JP2005112897A - Liquid epoxy resin, epoxy resin composition and cured product thereof - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a scarcely crystallizable liquid epoxy resin affording a cured product thereof having excellent heat resistance and mechanical strength. <P>SOLUTION: The liquid epoxy resin is represented by formula (1). An epoxy resin composition comprises the liquid epoxy resin and a curing agent. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  The present invention relates to a liquid epoxy resin and an epoxy resin composition that give a cured product having high heat resistance, have excellent mechanical strength, and hardly cause crystallization.

Epoxy resins are generally cured with various curing agents, resulting in cured products with excellent mechanical properties, water resistance, chemical resistance, heat resistance, electrical properties, etc., adhesives, paints, laminates, moldings It is used in a wide range of fields such as materials and casting materials. Conventionally, as a liquid epoxy resin most used industrially, a compound obtained by reacting bisphenol A with epichlorohydrin is known. Resins obtained by reacting bisphenol S with epichlorohydrin are known to have excellent heat resistance and mechanical strength of the cured product.
However, it has been pointed out that the bisphenol S-type epoxy resin as described above is semi-solid at room temperature and crystallizes easily when left as it is, so that it is difficult to handle. Patent Document 1 describes a photocurable resin obtained by condensation reaction of (meth) acrylic acid with a compound obtained by adding ethylene oxide to bisphenol. The photocurable resin is excellent in workability, but is extremely inferior to the thermosetting resin such as an epoxy resin in terms of the reliability of the cured product.

JP-A-6-16594 (Claims and paragraph number 0036)

  An object of this invention is to provide the liquid epoxy resin which gives the hardened | cured material excellent in heat resistance and mechanical strength, and also is hard to produce crystallization.

  As a result of intensive studies to solve the above problems, the present inventors have found that an epoxy resin having a specific molecular structure satisfies these characteristics, and has completed the present invention.

That is, the present invention provides the following formula (1)

で表される液状エポキシ樹脂、
（２）上記（１）記載の液状エポキシ樹脂、硬化剤を含有するエポキシ樹脂組成物、
（３）硬化促進剤を含有する上記（２）記載のエポキシ樹脂組成物、
（４）無機充填材を含有する上記（２）または（３）記載のエポキシ樹脂組成物、
（５）上記（２）、（３）または（４）のいずれか１項に記載のエポキシ樹脂組成物を硬化してなる硬化物、
を提供するものである。

Liquid epoxy resin represented by
(2) The liquid epoxy resin according to (1) above, an epoxy resin composition containing a curing agent,
(3) The epoxy resin composition according to the above (2), which contains a curing accelerator,
(4) The epoxy resin composition according to the above (2) or (3), which contains an inorganic filler,
(5) Hardened | cured material formed by hardening | curing the epoxy resin composition of any one of said (2), (3) or (4),
Is to provide.

The epoxy resin of the present invention is a liquid that is difficult to crystallize, and its cured product has high heat resistance and excellent mechanical strength.
Therefore, the epoxy resin composition of the present invention is extremely useful for a wide range of applications such as electric / electronic materials, molding materials, casting materials, laminated materials, paints, adhesives, resists, optical materials and the like.

  The epoxy resin represented by the formula (1) is, for example, the following formula (2)

It can obtain by performing reaction of the compound represented by and epihalohydrin in presence of an alkali metal hydroxide. The compound represented by the formula (2) can be synthesized from 2,4′-di (hydroxyphenyl) sulfone and ethylene oxide by a known method.

  In the reaction for obtaining the epoxy resin of the present invention, epichlorohydrin, epibromohydrin, or the like can be used as the epihalohydrin. The usage-amount of epihalohydrin is 2-15 mol normally with respect to 1 mol of hydroxyl groups of the compound represented by Formula (2), Preferably it is 2.5-10 mol.

  Examples of the alkali metal hydroxide that can be used include sodium hydroxide and potassium hydroxide, and an aqueous solution thereof may be used. In that case, the aqueous solution of the alkali metal hydroxide is continuously added to the reaction system. In addition to the addition, water and epihalohydrin are allowed to flow out continuously under reduced pressure or at normal pressure, and the solution is separated, water is removed, and epihalohydrin is continuously returned to the reaction system. The usage-amount of an alkali metal hydroxide is 1.0-2.5 mol normally with respect to 1 mol of hydroxyl groups of the compound represented by Formula (2), Preferably it is 1.05-2.0 mol.

Since the compound represented by the formula (2) is difficult to dissolve in epihalohydrin, it is preferable to increase the solubility by adding another solvent. Solvents that can be used include alcohols such as methanol and ethanol, and aprotic polar solvents such as dimethyl sulfone and dimethyl sulfoxide.
The amount of solvents used as necessary is usually 5 to 200% by weight, preferably 10 to 150% by weight, based on the amount of epihalohydrin.

  Further, in order to accelerate the reaction, it is preferable to add a quaternary ammonium salt such as tetramethylammonium chloride, tetramethylammonium bromide, trimethylbenzylammonium chloride as a catalyst. The amount of the quaternary ammonium salt used is preferably 0.05 to 20 parts by weight, particularly preferably 0.1 to 10 parts by weight, based on 1 equivalent of the hydroxyl group of the compound represented by the formula (2).

  The reaction temperature is usually 20-100 ° C, preferably 30-90 ° C. The reaction time is usually 0.5 to 15 hours, preferably 1 to 10 hours.

  After the reaction product of these epoxidation reactions is washed with water, the epihalohydrin, the solvent and the like are removed under heating and reduced pressure. In order to make the epoxy resin less hydrolyzable halogen, the recovered epoxy resin is dissolved in a solvent such as toluene or methyl isobutyl ketone, and an aqueous solution of an alkali metal hydroxide such as sodium hydroxide or potassium hydroxide is added. The reaction can be carried out to ensure the ring closure. In this case, the amount of alkali metal hydroxide used is usually 0.01 to 0.3 mol, preferably 0.05 to 0.2 mol, based on 1 mol of the hydroxyl group of the compound of formula (2) used for epoxidation. is there. The reaction temperature is usually 50 to 120 ° C., and the reaction time is usually 0.5 to 2 hours.

  After completion of the reaction, the produced salt is removed by filtration, washing with water, etc., and the solvent is distilled off under heating and reduced pressure to obtain the epoxy resin of the present invention.

  The epoxy resin composition of the present invention contains the epoxy resin of the present invention and a curing agent as essential components. In the epoxy resin composition of the present invention, the epoxy resin of the present invention can be used alone or in combination with other epoxy resins. When used in combination, the proportion of the epoxy resin of the present invention in the total epoxy resin is preferably 30% by weight or more, particularly preferably 40% by weight or more.

  Specific examples of other epoxy resins that can be used in combination with the epoxy resin of the present invention include novolac type epoxy resins, bisphenol A type epoxy resins, bisphenol F type epoxy resins, biphenyl type epoxy resins, and dicyclopentadienephenol cocondensation type epoxy resins. , Triphenylmethane type epoxy resin, biphenyl novolac type epoxy resin and the like may be mentioned, but these may be used alone or in combination of two or more.

Examples of the curing agent contained in the epoxy resin composition of the present invention include amine compounds, acid anhydride compounds, amide compounds, and phenol compounds. Specific examples of curing agents that can be used include diaminodiphenylmethane, diethylenetriamine, triethylenetetramine, diaminodiphenylsulfone, isophoronediamine, dicyandiamide, polyamide resin synthesized from linolenic acid and ethylenediamine, phthalic anhydride, triethylene anhydride. Mellitic acid, pyromellitic anhydride, maleic anhydride, tetrahydrophthalic anhydride, methyltetrahydrophthalic anhydride, methylnadic acid anhydride, hexahydrophthalic anhydride, methylhexahydrophthalic anhydride, phenol novolac, and modified products thereof, imidazole BF ₃ -amine complex, guanidine derivative and the like, but are not limited thereto. These may be used alone or in combination of two or more.

  In the epoxy resin composition of the present invention, the amount of the curing agent used is preferably 0.7 to 1.2 equivalents relative to 1 equivalent of the epoxy group of the epoxy resin. When less than 0.7 equivalent or more than 1.2 equivalent with respect to 1 equivalent of epoxy group, curing may be incomplete and good cured properties may not be obtained.

  In the epoxy resin composition of the present invention, a curing accelerator may be used. Specific examples of the curing accelerator that can be used include imidazoles such as 2-methylimidazole, 2-ethylimidazole, 2-ethyl-4-methylimidazole, 2- (dimethylaminomethyl) phenol, 1,8-diaza-bicyclo ( And tertiary amines such as 5,4,0) undecene-7, phosphines such as triphenylphosphine, and metal compounds such as tin octylate. The curing accelerator is used as necessary in an amount of 0.1 to 5.0 parts by weight based on 100 parts by weight of the epoxy resin.

  The epoxy resin composition of the present invention may contain an inorganic filler as necessary. Specific examples of the inorganic filler that can be used include silica, alumina, talc and the like. The inorganic filler is used in an amount of 0 to 90% by weight in the epoxy resin composition of the present invention. Furthermore, various compounding agents such as a silane coupling agent, a release agent such as stearic acid, palmitic acid, zinc stearate, and calcium stearate, and a pigment can be added to the epoxy resin composition of the present invention.

  The epoxy resin composition of the present invention can be obtained by uniformly mixing the above components. For example, an epoxy resin composition is obtained by thoroughly mixing an epoxy resin, a curing agent and, if necessary, a curing accelerator, an inorganic filler, and a compounding agent as necessary using an extruder, kneader, roll or the like until uniform. be able to. For example, the epoxy resin composition of the present invention can be easily made into a cured product by a method similar to a conventionally known method. A cured product can be obtained by melting the epoxy resin composition after melting and molding using a casting mold or a transfer molding machine, and further heating at 80 to 200 ° C. for 2 to 10 hours.

  Also, the epoxy resin composition of the present invention is dissolved in a solvent such as toluene, xylene, acetone, methyl ethyl ketone, methyl isobutyl ketone, and impregnated on a substrate such as glass fiber, carbon fiber, polyester fiber, polyamide fiber, alumina fiber, paper, and the like. A prepreg obtained by heating and semi-drying can be hot press molded to obtain a cured product. The solvent used here is usually 10 to 70% by weight, preferably 15 to 70% by weight in the mixture of the epoxy resin composition of the present invention and the solvent.

  EXAMPLES Next, the present invention will be described more specifically with reference to examples. In the following, parts are parts by weight unless otherwise specified.

Example 1
To 169 parts of the compound represented by the formula (2), 370 parts of epichlorohydrin and 185 parts of dimethyl sulfoxide were added and dissolved under stirring, and the temperature was raised to 50 ° C. Next, 60 parts of flaky sodium hydroxide was added in portions over 100 minutes, and then post-reaction was performed at 50 ° C. for 3 hours. After completion of the reaction, 400 parts of water was added and washed with water. Excess epichlorohydrin and the like were distilled off from the oil layer under reduced pressure at 130 ° C. using a rotary evaporator. To the residue, 450 parts of methyl isobutyl ketone was added and dissolved, and the temperature was raised to 70 ° C. Under stirring, 10 parts of a 30% by weight aqueous sodium hydroxide solution was added and reacted for 1 hour, followed by washing with water three times. The methyl isobutyl ketone was distilled off under reduced pressure at 180 ° C. using a rotary evaporator, 220 parts of the liquid epoxy resin (A) of the present invention represented by the formula (1) was obtained. The epoxy equivalent of the obtained epoxy resin was 228 g / eq, and the viscosity at 25 ° C. was 22000 mPa · s as measured with an E-type viscometer. Furthermore, when 100 parts of the obtained epoxy resin was refrigerated at 5 ° C., it did not crystallize even after standing for 10 days.

Example 2
To 100 parts of the epoxy resin (A) obtained in Example 1, 70 parts of methylnadic acid anhydride and 1 part of 2-ethyl-4-methylimidazole were uniformly mixed to obtain an epoxy resin composition of the present invention. This was poured into a mold and cured at 120 ° C. for 2 hours and at 150 ° C. for 3 hours to obtain a cured specimen. It was 169 degreeC when the glass transition temperature of the test piece of the obtained hardened | cured material was measured using TMA (Thermomechanical measuring device TM-7000 temperature rising rate: 2 degree-C / min.). The bending strength was 135 MPa when measured based on JIS K 6911.

  Thus, the epoxy resin of the present invention is liquid and difficult to crystallize, and the cured product is excellent in heat resistance and mechanical strength.

Claims (5)

Formula (1)

Liquid epoxy resin represented by An epoxy resin composition comprising the liquid epoxy resin according to claim 1 and a curing agent. The epoxy resin composition of Claim 2 containing a hardening accelerator. The epoxy resin composition according to claim 2 or 3, comprising an inorganic filler. Hardened | cured material formed by hardening | curing the epoxy resin composition of any one of Claim 2, 3 or 4