JP2005112437A - Bundle of stacked soft packages - Google Patents

Bundle of stacked soft packages Download PDF

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JP2005112437A
JP2005112437A JP2003351365A JP2003351365A JP2005112437A JP 2005112437 A JP2005112437 A JP 2005112437A JP 2003351365 A JP2003351365 A JP 2003351365A JP 2003351365 A JP2003351365 A JP 2003351365A JP 2005112437 A JP2005112437 A JP 2005112437A
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soft
packaging
film
flexible
product
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JP4171390B2 (en
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Katsuyuki Okubo
勝之 大久保
Chieko Kawashima
智恵子 川嶋
Toshinobu Tsuda
敏亘 津田
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Nitto Denko Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a bundle of stacked soft packages from which a desired number of the soft packages is easily taken out and the number of the packages is checked easily. <P>SOLUTION: The bundle 1 of the stacked soft packages has a stacked structure formed by stacking a plurality of the soft packages 2 each constituted by sealing a sheet-like matter with a packaging film and bundling them with a strip 3, wherein (a) the soft package 2 having a torsion angle of 1°-20° in absolute value and the soft package 2 having a torsion angle of 0° are stacked alternately, or (b) the soft package 2 having a torsion angle of 20° or less in absolute value in the positive direction and the packages 2 having a torsion angle of 20° or less in absolute value in the negative direction are stacked alternately. The neighboring soft packages 2 have a difference of 1° or more in torsion angle. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、シート状物を包装用フィルムにてシールしてなるシート状の軟包装品を複数枚積層して束ねた軟包装品積層束に関する。   The present invention relates to a flexible packaged laminate bundle in which a plurality of sheet-like soft packages obtained by sealing sheet-like materials with a packaging film are stacked and bundled.

例えば、テープ材(医療用テープ(小片シート)状製品等)、美肌パックシート、ウエットティッシュ等のシート状の衛材製品、メンブレンフィルター等の比較的小片のシート状物は、安定性の担保、汚染の防止、使い勝手の向上などの目的で、包装用フィルムにて平袋状にヒートシール包装した軟包装品の製品形態とされることが多くなっている。そして、このような軟包装品は、配送と数量確認を容易にする目的で、通常、複数枚(たとえば、10枚)積層され、帯状フィルムなどからなる帯状物で結束した軟包装品積層束として流通され、使用時に帯状物を外し、所望枚数の軟包装品を取り出して使用される。しかし、軟包装品の1枚1枚は包装用フィルムでヒートシール包装したシート状物であるため、軟包装品積層束より帯状物を外しても、軟包装品同士が密着し、所望枚数だけの軟包装品を取り出すのは容易ではない。このため、しばしば間違えた枚数を抜き取ってしまうこともあり、このような軟包装品の取り出しにくさ、数えにくさは、必要枚数を取り出す際や在庫確認をする際の障害となっていた。特に、シート状物がテープ材の場合には、軟包装品は医療現場で使用されることが多く、特に迅速且つ確実な操作が要求されるので、軟包装品積層束からの軟包装品の取り出しにくさ、数えにくさについての改善が望まれていた。   For example, tape materials (medical tape (small piece sheet) products, etc.), beautified skin pack sheets, sheet-like hygiene products such as wet tissue, relatively small pieces of sheet materials such as membrane filters, For the purpose of preventing contamination and improving usability, the product form of a soft package product which is heat-sealed in a flat bag shape with a packaging film is increasing. Such a soft packaged product is usually formed as a soft packaged product bundle in which a plurality of sheets (for example, 10 sheets) are laminated and bundled with a belt-like material made of a belt-like film for the purpose of facilitating delivery and quantity confirmation. It is distributed, the strip is removed at the time of use, and a desired number of flexible packages are taken out and used. However, since each soft package is a sheet-like product heat-sealed with a packaging film, even if the strip-like product is removed from the laminated bundle of soft packages, the soft packages are in close contact with each other, and only the desired number It is not easy to take out the soft package. For this reason, the wrong number of sheets is often taken out, and such a difficulty in taking out and counting the flexible package has been an obstacle to taking out the necessary number and checking the stock. In particular, in the case where the sheet-like material is a tape material, the soft package is often used in the medical field, and particularly quick and reliable operation is required. Improvements in the difficulty of taking out and counting were desired.

シート状物の積層物からシート状物を1枚ずつ取り出しやすくするための技術としては、シート状物がティッシュペーパーである場合には、ティッシュペーパーを1枚1枚の折り目を重ねて積層する方法が実用化されている。その他の技術としては、箱状容器のホルダー本体の一側面に単位粘着テープ抜き取り用の抜取口が開口形成され、該開口部に最上層の単位粘着テープが位置するようにホルダー本体内に、一端部が粘着剤未塗布面となるように粘着剤を塗布して形成した単位粘着テープを該粘着剤未塗布面を交互に互いに反対側に位置するようにして積層してなる粘着テープ束が収納され、該粘着テープ束の底側を開口方向に押圧するばねを有する押圧具がホルダー内に装着されてなる構成を有するホルダー付粘着テープが開示されている(たとえば、特許文献1を参照。)。かかる特許文献1に開示されたホルダー付粘着テープは、上記押圧具によって粘着テープ束全体を開口方向に押圧することで、粘着テープ束の最上部の1枚だけを取り出しやすくしたものである。しかし、上述したようなシート状物を包装用フィルムでシールしてなるような軟包装品においては、積層して束ねた軟包装品積層束の状態から、軟包装品を1枚ずつ取り出し易くする技術についての検討は殆どなされていない。
実開平5−65960号公報
As a technique for making it easy to take out sheet-like materials one by one from a laminate of sheet-like materials, when the sheet-like material is tissue paper, a method of laminating tissue papers by stacking folds one by one Has been put to practical use. As another technique, an opening for removing the unit adhesive tape is formed on one side surface of the holder body of the box-shaped container, and one end of the unit adhesive tape is placed in the holder body so that the uppermost unit adhesive tape is located in the opening. Contains a unitary adhesive tape formed by applying adhesive so that the part becomes the adhesive-unapplied surface, and an adhesive tape bundle formed by laminating the adhesive-unapplied surfaces alternately on opposite sides An adhesive tape with a holder having a configuration in which a pressing tool having a spring that presses the bottom side of the adhesive tape bundle in the opening direction is mounted in the holder is disclosed (see, for example, Patent Document 1). . Such a pressure-sensitive adhesive tape with a holder disclosed in Patent Document 1 makes it easy to take out only the uppermost one of the pressure-sensitive adhesive tape bundle by pressing the whole pressure-sensitive adhesive tape bundle in the opening direction with the pressing tool. However, in a soft package product in which a sheet-like material as described above is sealed with a packaging film, the soft package product can be easily taken out one by one from the state of the soft package product stack bundled and stacked. There has been little research on technology.
Japanese Utility Model Publication No. 5-65960

本発明は、上記事情に鑑みなされたものであり、その解決しようとする課題は、所望の枚数の軟包装品を取り出しやすく、軟包装品の枚数確認も容易な軟包装品積層束を提供することにある。   The present invention has been made in view of the above circumstances, and a problem to be solved is to provide a flexible packaged bundle that allows easy extraction of a desired number of flexible packages and easy confirmation of the number of flexible packages. There is.

本発明者らは、上記課題を解決するため鋭意研究を行った結果、僅かにねじれた形状の軟包装品と、実質的にねじれのない軟包装品、または、互いに逆向きに僅かにねじれた軟包装品を作製し、それらを特定の組み合わせで積層して束ねた軟包装品積層束とすることによって、軟包装品積層束の帯を外したときに軟包装品の積層構造が板ばね的に作用して、隣接する軟包装品との間の隙間を押し広げ、その結果、所望枚数の軟包装品の取り出しと、軟包装品の枚数確認が容易になることを見出し、本発明を完成するに至った。   As a result of diligent research to solve the above-mentioned problems, the present inventors have found that a soft package with a slightly twisted shape and a soft package with substantially no twist, or slightly twisted in opposite directions. By creating flexible packaged products and stacking them in a specific combination to form a bundle of flexible packaged products, the laminated structure of the flexible packaged product is like a leaf spring when the strip of the flexible packaged product bundle is removed. The present invention has been completed by finding that it is easy to take out a desired number of flexible packages and confirm the number of flexible packages as a result of expanding the gap between adjacent soft packages. It came to do.

即ち、本発明は以下のとおりである。
(1)シート状物を包装用フィルムにてシールしてなる軟包装品を複数枚積層し、帯状物で束ねた軟包装品積層束であって、以下の(a)または(b)の積層構造を有する軟包装品積層束。
(a)ねじれ角度の絶対値が1°〜20°の軟包装品とねじれ角度が0°の軟包装品とを交互に積層した積層構造、
(b)ねじれ角度の絶対値が20°以下のねじれの向きが正方向の軟包装品とねじれ角度の絶対値が20°以下のねじれの向きが負方向の軟包装品とを交互に積層した積層構造であって、各隣接する軟包装品間のねじれ角度の差が1°以上である積層構造。
(2)各軟包装品の包装用フィルムは、1回目曲げ応力最大値が0.01N/15mm幅/2枚〜2.0N/15mm幅/2枚であって、かつ2回目曲げ応力最大値が1回目曲げ応力最大値の80%以上である上記(1)記載の軟包装品積層束。
(3)軟包装品の外周形状(輪郭)が方形状である、上記(1)または(2)に記載の軟包装品積層束。
(4)シート状物がテープ材である、上記(1)〜(3)のいずれかに記載の軟包装品積層束。
That is, the present invention is as follows.
(1) A soft package laminate bundle obtained by laminating a plurality of soft package products obtained by sealing a sheet-like material with a packaging film and bundling with a belt-like product, and the laminate of the following (a) or (b) Flexible packaged laminated bundle having a structure.
(A) a laminated structure in which soft packaging products having an absolute value of twist angle of 1 ° to 20 ° and soft packaging products having a twist angle of 0 ° are alternately laminated;
(B) A soft package with a positive twist direction with an absolute value of 20 degrees or less and a soft package with a negative twist direction with an absolute value of 20 degrees or less alternately stacked. A laminated structure, wherein the difference in twist angle between each adjacent flexible package is 1 ° or more.
(2) The packaging film of each soft packaged product has a first bending stress maximum value of 0.01 N / 15 mm width / 2 sheets to 2.0 N / 15 mm width / 2 sheets, and a second bending stress maximum value. The soft-packaging laminate bundle according to (1), wherein is 80% or more of the maximum value of the first bending stress.
(3) The flexible packaged product bundle according to (1) or (2), wherein the outer peripheral shape (contour) of the soft package product is a square shape.
(4) The flexible packaged laminated bundle according to any one of (1) to (3), wherein the sheet-like material is a tape material.

本発明の軟包装品積層束は、軟包装品積層束の帯状物を外した際に、互いに隣接する軟包装品同士の反発力により隣接する軟包装品同士の間に隙間ができることから、軟包装品の枚数を確認することが容易になり、また、必要枚数の軟包装品を抜き取る操作も容易となる。従って、本発明によれば、迅速、かつ、確実な操作が要求される現場の要求を満たし得る、極めて有用な軟包装品積層束を提供することができる。   When the strip of the soft package laminate bundle is removed, the soft package laminate bundle of the present invention has a gap between the adjacent soft package products due to the repulsive force between the adjacent soft package products. It becomes easy to check the number of packaged products, and the operation of extracting the required number of soft packaged products becomes easy. Therefore, according to the present invention, it is possible to provide a very useful flexible packaged laminated bundle that can satisfy the requirements of the field where a quick and reliable operation is required.

以下、本発明を詳細に説明する。
図1は、本発明の好ましい一例の軟包装品積層束1を簡略化して示す図である。本発明の軟包装品積層束1は、シート状物を包装用フィルムにてシールしてなる軟包装品2を複数枚積層して、帯状物3にて束ねてなる基本構造を有する。ここで、「シート状物を包装用フィルムにてシールする」とは、シート状物の表裏両面を包装用フィルムで覆った状態で包装用フィルムをシールして密閉することであり、「積層」とは、略同一の形状および大きさを有する複数枚の軟包装品を、当該軟包装品の厚み方向と積層方向とが略一致するように積み重ねてなる状態を指すものとする。該軟包装品の積層は、積層された状態で各軟包装品が各々端部を揃えてなるのが好ましい。本発明の軟包装品積層束1は、上記基本構造に加え、(a)ねじれ角度の絶対値が1°〜20°の軟包装品とねじれ角度が0°の軟包装品を交互に積層するか、あるいは、(b)ねじれ角度の絶対値が20°以下のねじれの向きが正方向の軟包装品とねじれ角度の絶対値が20°以下のねじれの向きが負方向の軟包装品とを交互に積層し、その際各隣接する軟包装品間のねじれ角度の差が1°以上となるようにした、積層構造を有することを特徴とする。このような本発明の軟包装品積層束1によれば、帯状物3を外した際に、各軟包装品2が板ばね的に作用し、隣接する軟包装品2間の隙間を押し広げ、結果、所望枚数の軟包装品の取り出し、ならびに軟包装品の枚数確認を容易に行うことができる。
Hereinafter, the present invention will be described in detail.
FIG. 1 is a diagram showing a simplified example of a flexible packaged laminated bundle 1 of the present invention. The soft-packaging product stack 1 of the present invention has a basic structure in which a plurality of soft-packaging products 2 formed by sealing sheet-like materials with a packaging film are laminated and bundled with a belt-like material 3. Here, “sealing a sheet-like material with a packaging film” means sealing and sealing the packaging film in a state where both front and back surfaces of the sheet-like material are covered with a packaging film. The term “a” refers to a state in which a plurality of flexible packages having substantially the same shape and size are stacked such that the thickness direction and the stacking direction of the flexible packages are substantially coincident. In the lamination of the soft packaged product, it is preferable that each soft packaged product has its ends aligned in the laminated state. In addition to the above basic structure, the soft-packaging laminate bundle 1 of the present invention (a) alternately stacks soft-packaging products with an absolute value of twist angle of 1 ° to 20 ° and soft-packaging products with a twist angle of 0 °. Or (b) a soft package with a positive twist direction with an absolute value of 20 ° or less and a soft package with a negative twist direction with an absolute value of 20 ° or less. It is characterized by having a laminated structure in which the layers are alternately laminated, and the difference in twist angle between adjacent soft packages is 1 ° or more. According to such a soft-packaging laminated bundle 1 of the present invention, when the strip 3 is removed, each soft-packaging product 2 acts like a leaf spring and pushes the gap between adjacent soft-packaging products 2. As a result, it is possible to easily take out a desired number of flexible packages and confirm the number of flexible packages.

図2は、上記(a)の態様の軟包装品2を用いた軟包装品積層束1の帯状物を外した状態を簡略化して示す図である。かかる態様の軟包装品積層束1においては、ねじれ角度の絶対値が1°〜20°(好ましくは3°〜18°)の軟包装品(以下、説明の便宜上「軟包装品2A」と呼ぶことがある)と、ねじれ角度が0°の軟包装品(以下、説明の便宜上「軟包装品2B」と呼ぶことがある)とを、交互に積層させてなるものである。なお、ねじれ角度の絶対値が1°〜20°の軟包装品は、ねじれ角度が+1°〜+20°の軟包装品(正方向にねじれた軟包装品)、ならびにねじれ角度が−20°〜−1°の軟包装品(逆方向にねじれた軟包装品)を包含する。かかる態様における軟包装品2Aは、いずれも同方向にねじれた軟包装品を用いるようにしてもよいし、正方向にねじれた軟包装品と逆方向にねじれた軟包装品が混在していてもよい。また、軟包装品2Aは、ねじれ角度の絶対値が1°〜20°であるならば、軟包装品2Bと交互に積層される各軟包装品について、いずれも同じねじれ角度の軟包装品であってもよいし、二種以上のねじれ角度の軟包装品が混在していてもよい。かかる(a)の態様において組み合わせる軟包装品について、軟包装品2Aのねじれ角度の絶対値が1°未満であると、ねじれ角度が0°の軟包装品2Bと交互に積層しても、各軟包装品が板ばね的に作用せず、本発明の目的を達成することができない。また、軟包装品2Aのねじれ角度の絶対値が20°を越えると、軟包装品1枚の外観として、ねじれていることが目立ってしまうことから、外観不良の印象を与えてしまうし、自動包装機でシールする工程において、シール後、束ねるまでの自動包装機ライン中で配送の安定性や束ねる際の集積性も悪化してしまうという不具合がある。   FIG. 2 is a diagram schematically showing a state in which a strip-like product of the flexible packaged product stack 1 using the soft package product 2 of the aspect (a) is removed. In the soft-packaging laminated bundle 1 having such an aspect, a soft-packaging product (hereinafter referred to as “soft-packaging product 2A” for convenience of explanation) having an absolute value of a twist angle of 1 ° to 20 ° (preferably 3 ° to 18 °). And a flexible packaged product having a twist angle of 0 ° (hereinafter, sometimes referred to as “soft-packaged product 2B” for convenience of explanation) are alternately laminated. In addition, a soft package product having an absolute value of the twist angle of 1 ° to 20 ° is a soft package product having a twist angle of + 1 ° to + 20 ° (a soft package product twisted in the positive direction), and a twist angle of −20 ° to Includes -1 ° soft packaging (soft packaging twisted in the opposite direction). The soft package 2A in such an embodiment may be a soft package that is twisted in the same direction, or a soft package that is twisted in the forward direction and a soft package that is twisted in the reverse direction are mixed. Also good. Moreover, if the absolute value of the twist angle is 1 ° to 20 °, the soft package 2A is a soft package with the same twist angle for each of the soft packages stacked alternately with the soft package 2B. It may be present, or two or more types of flexible packages having twist angles may be mixed. With regard to the flexible packaging product combined in the aspect of (a), if the absolute value of the twist angle of the flexible packaging product 2A is less than 1 °, each of the flexible packaging products 2B is alternately laminated with the flexible packaging product 2B having a twist angle of 0 °. The soft package does not act like a leaf spring, and the object of the present invention cannot be achieved. Also, if the absolute value of the twist angle of the soft package 2A exceeds 20 °, the appearance of one soft package will be noticeable as being twisted. In the process of sealing with a packaging machine, there is a problem that the stability of delivery and the accumulation property at the time of bundling are also deteriorated in the automatic packaging machine line after sealing and bundling.

図3は、上記(b)の態様の軟包装品を用いた軟包装品積層束1’の帯状物を外した状態を簡略化して示す図である。なお、(b)の態様の軟包装品積層束1’においても、帯状物で束ねた状態は、図1に示したのと同様である。かかる態様の軟包装品積層束においては、ねじれ角度の絶対値が20°以下のねじれの向きが正方向の軟包装品(以下、説明の便宜上「軟包装品2C」と呼ぶことがある。)と、ねじれ角度の絶対値が20°以下のねじれの向きが負方向の軟包装品(以下、説明の便宜上「軟包装品2D」と呼ぶことがある)とを交互に積層したものであり、各隣接する軟包装品間のねじれ角度の差が1°以上となるように積層することが重要である。ここでの「ねじれ角度の差」とは、ねじれの向きが正方向(すなわち、ねじれ角度が正の値)の軟包装品のねじれ角度と、ねじれの向きが負方向(すなわち、ねじれ角度が負の値)の軟包装品のねじれ角度の差([ねじれの向きが正方向の軟包装品のねじれ角度]−[ねじれの向きが負方向の軟包装品のねじれ角度])のことである。   FIG. 3 is a diagram schematically showing a state in which a strip-like material is removed from a soft-packaging laminated bundle 1 ′ using the soft-packaging product of the aspect (b). In the soft package laminated bundle 1 ′ in the mode (b), the state of being bundled with a strip is the same as that shown in FIG. 1. In the soft-packaging laminated bundle of this aspect, the soft-wrapping product in which the twist direction has an absolute value of 20 ° or less and the twist direction is the positive direction (hereinafter sometimes referred to as “soft-packaging product 2C” for convenience of explanation). And a flexible packaged product in which the twist direction has an absolute value of 20 ° or less and the twist direction is negative (hereinafter sometimes referred to as “soft packaged product 2D” for convenience of explanation), It is important to laminate so that the difference in twist angle between each adjacent flexible package is 1 ° or more. Here, the “difference in twist angle” means the twist angle of a soft package product in which the twist direction is positive (that is, the twist angle is positive) and the twist direction in the negative direction (that is, the twist angle is negative). )) Of the flexible package product ([twist angle of the flexible package product in which the twist direction is positive] − [twist angle of the soft package product in which the twist direction is negative]).

ねじれの向きが正方向(すなわち、ねじれ角度が正の値)の軟包装品2Cは、軟包装品2Dと交互に積層される各軟包装品について、いずれも同じねじれ角度の軟包装品であってもよいし、二種以上のねじれ角度の軟包装品が混在していてもよく、また、ねじれの向きが負方向(すなわち、ねじれ角度が負の値)の軟包装品2Dは、軟包装品2Cと交互に積層される各軟包装品について、いずれも同じねじれ角度の軟包装品であってもよいし、二種以上のねじれ角度の軟包装品が混在していてもよい。ただし、上記のように、当該態様では、隣接する軟包装品間のねじれ角度の差を1°以上にすることが必要であることから、軟包装品2C及び2Dのいずれか一方または両方にねじれ角度の絶対値が1°未満のものを使用する場合、隣接する軟包装品2Cと軟包装品2Dとの間でのねじれ角度の差が1°以上となるようなねじれ角度のものを使用する点に注意が必要である。   The flexible package 2C having a positive twist direction (that is, a positive twist angle) is a flexible package having the same twist angle for each of the flexible packages stacked alternately with the flexible package 2D. Alternatively, two or more kinds of soft packaging products having a twist angle may be mixed, and the soft packaging product 2D having a negative twist direction (that is, a negative twist angle) is a soft packaging product. About each soft packaging product laminated | stacked with the product 2C alternately, all may be a soft packaging product of the same twist angle, and the soft packaging product of 2 or more types of twist angles may be mixed. However, as described above, in this aspect, since it is necessary to set the difference in the twist angle between adjacent soft packages to 1 ° or more, it is possible to twist one or both of the soft packages 2C and 2D. When using the one whose absolute value is less than 1 °, use one having a twist angle such that the difference in twist angle between the adjacent soft package 2C and the soft package 2D is 1 ° or more. It is necessary to pay attention to this point.

かかる(b)の態様において、隣接する軟包装品2Cと軟包装品2Dとの間でのねじれ角度の差が1°未満の場合(例えば、ねじれ角度が+0.5°の軟包装品2Cとねじれ角度が−0.3°の軟包装品2Dを使用する場合、ねじれ角度の差は0.8°である。)、隣接する軟包装品間での反発(板ばね的作用)が乏しく、本発明の目的を達成することができない。また、軟包装品2C及び2Dのねじれ角度の絶対値が20°を越えると、軟包装品1枚の外観としてねじれていることが目立ってしまうことから、外観不良の印象を与えてしまい、また、自動包装機でシールする工程で、シール後、束ねるまでの自動包装機ライン中での配送の安定性や束ねる際の集積性も悪くなるという不具合がある。当該態様において、軟包装品2Cのねじれ角度は好ましくは+1°〜+20°、より好ましくは+3°〜+18°であり、軟包装品2Dのねじれ角度は好ましくは−20°〜−1°、より好ましくは−18°〜−3°である。   In the embodiment (b), when the difference in the twist angle between the adjacent soft package 2C and the soft package 2D is less than 1 ° (for example, the soft package 2C having a twist angle of + 0.5 ° When using a flexible package 2D having a twist angle of −0.3 °, the difference in twist angle is 0.8 °.), And there is little repulsion (plate spring action) between adjacent soft packages, The object of the present invention cannot be achieved. In addition, if the absolute value of the twist angle of the soft packaging products 2C and 2D exceeds 20 °, the appearance of one soft packaging product becomes conspicuous, giving an impression of poor appearance, In the process of sealing with an automatic packaging machine, there is a problem that the stability of delivery in the automatic packaging machine line after the sealing and the bundling of the automatic packaging machine and the accumulation property at the time of bundling also deteriorate. In this embodiment, the twist angle of the soft package 2C is preferably + 1 ° to + 20 °, more preferably + 3 ° to + 18 °, and the twist angle of the soft package 2D is preferably −20 ° to −1 °. Preferably, it is −18 ° to −3 °.

本発明における軟包装品の上記ねじれ角度は、次のようにして測定される。
図4は、本発明における軟包装品のねじれ角度を測定する方法を模式的に示す図である。まず、中心Pから放射状に線が引いてある円盤11(線の間隔は1°刻みであり、基準線11aの目盛りを0°とする)の中心Pに鉛直柱12を立てる。鉛直柱12は四角柱であり、その一つの角が円盤11の中心Pに合わせてあり、その角と隣接する一方の面が基準線11aと同一面上で、円盤中心から目盛り180°の方向に設置されている。さらにこの鉛直柱12に水平柱13を取り付ける。水平柱13も鉛直柱12も同じ断面積を有する四角柱であり、その一つの面が円盤11の基準線11aと同一面上にあるよう設置される。水平柱13の高さは、測定する軟包装品の大きさに合わせて調節可能な構造になっている。水平柱13と円盤11上の基準線11aとが平行となるよう調整され、設置される。
The twist angle of the flexible package according to the present invention is measured as follows.
FIG. 4 is a diagram schematically showing a method for measuring the twist angle of the soft packaged product in the present invention. First, the vertical column 12 is erected at the center P of the disk 11 in which lines are radially drawn from the center P (the interval between the lines is 1 ° and the scale of the reference line 11a is 0 °). The vertical column 12 is a quadrangular column, and one corner thereof is aligned with the center P of the disk 11, and one surface adjacent to the corner is on the same plane as the reference line 11a, and the direction is 180 ° from the center of the disk. Is installed. Further, a horizontal column 13 is attached to the vertical column 12. The horizontal column 13 and the vertical column 12 are quadrangular columns having the same cross-sectional area, and are installed so that one surface thereof is on the same plane as the reference line 11 a of the disk 11. The height of the horizontal column 13 has a structure that can be adjusted in accordance with the size of the flexible package to be measured. The horizontal column 13 and the reference line 11a on the disk 11 are adjusted and installed so as to be parallel.

軟包装品は、その外周形状(輪郭)が方形状の場合はそれをそのまま用いて測定し、方形状以外の場合には軟包装品より方形状に切り出した断片を用いる。なお、方形状とは角が直角の四角形であり長方形及び正方形を含むが、正方形の場合、便宜的に一方の一対の対向する辺を長辺とし、他方の一対の対向する辺を短辺と決めて取り扱う。なお、角部がとれて丸くなっているものも本発明でいう「方形状」に含まれるものとする。   When the outer peripheral shape (contour) is a square shape, the flexible package product is measured by using it as it is, and when the outer shape is not a square shape, a piece cut into a square shape from the soft package product is used. Note that a square is a quadrangle with a right angle and includes a rectangle and a square, but in the case of a square, for convenience, one pair of opposite sides is a long side, and the other pair of opposite sides is a short side. Decide and handle. It should be noted that the rounded corners are also included in the “square shape” in the present invention.

方形状の軟包装品14の一方の短辺を円盤11の面にあわせた状態で、軟包装品14の一方の長辺の端5mm幅を鉛直柱12に貼り付ける。さらに、水平柱13の高さを調節して、軟包装品14の他方の短辺の上端5mm幅を水平柱13に貼り付ける。この状態で、円盤11と接している方の軟包装品14の短辺の円盤中心から遠い方の頂点14aの位置を、真上から読み取ることで、ねじれ角度を決定する。そして、頂点14aと中心Pとを結ぶ直線と基準線11aとのなす角度をねじれ角度とし、基準線11aよりも時計周り方向にずれた位置に頂点14aがくる場合は、ねじれの向きは正方向であり、ねじれ角度は正(+)の値として読み取る。逆に基準線11aよりも反時計周り方向にずれた位置に頂点14aがくる場合は、ねじれの向きは負方向であり、ねじれ角度は負(+)の値として読みとる。   In a state where one short side of the rectangular soft package 14 is aligned with the surface of the disk 11, the end 5 mm width of one long side of the soft package 14 is attached to the vertical column 12. Further, the height of the horizontal column 13 is adjusted, and the upper end 5 mm width of the other short side of the soft package 14 is attached to the horizontal column 13. In this state, the twist angle is determined by reading the position of the apex 14a far from the center of the short side of the flexible package 14 in contact with the disk 11 from the top. If the angle formed between the straight line connecting the vertex 14a and the center P and the reference line 11a is a twist angle, and the vertex 14a comes to a position shifted in the clockwise direction from the reference line 11a, the twist direction is positive. The twist angle is read as a positive (+) value. Conversely, when the apex 14a comes to a position shifted counterclockwise from the reference line 11a, the twist direction is negative and the twist angle is read as a negative (+) value.

図5は、本発明に使用される軟包装品について模式的に示す図である。上記方法により、図5(a)のような軟包装品については、ねじれ角度0°と測定され(すなわち、上述した軟包装品2Bに相当する)、図5(b)のような軟包装品については、正方向のねじれ角度で測定され(すなわち、上述した軟包装品2Cに相当する)、図5(c)のような軟包装品については、負方向のねじれ角度で測定される(すなわち、上述した軟包装品2Dに相当する。)。なお、軟包装品2C、2Dのうちねじれ角度の絶対値が1〜20°のものは前記(a)の態様で使用する場合、軟包装品2Aである。
なお、軟包装品の外周形状(輪郭)が正方形状である場合、軟包装品を厚み方向に関する軸線を中心にして90°回転させることでねじれ角度が同じであって、かつねじれ方向が反対(負方向)の軟包装品とすることができる。たとえば、図5(b)に示すねじれ方向が正方向である軟包装品2Cについて、軟包装品2Cの厚み方向Zに関する中心軸線Lzまわりに90°回転(この場合は、時計周りに90°回転)させることで、軟包装品2Cとねじれ角度が同じであって、かつ負方向にねじれた軟包装品2Dとすることができる。かかる方法でねじれ方向が反対の軟包装品を得ると、軟包装品に印刷が施してあった場合、印刷の向きが90°回転した外観となってしまう。このことが軟包装品積層束の外観として許容できない場合には、予め印刷デザインを90°回転させた印刷パターンの包材を作製して用いることで対処することもできる。
FIG. 5 is a diagram schematically showing the soft package used in the present invention. By the above method, the flexible package as shown in FIG. 5A is measured with a twist angle of 0 ° (that is, corresponding to the above-described flexible package 2B), and the flexible package as shown in FIG. 5B. Is measured with a twist angle in the positive direction (that is, corresponding to the above-described soft package 2C), and for a soft package as shown in FIG. 5C, it is measured with a twist angle in the negative direction (that is, , Corresponding to the above-mentioned soft package 2D). In addition, when the absolute value of the twist angle is 1 to 20 ° among the soft packaging products 2C and 2D, the soft packaging product 2A is used when used in the mode (a).
In addition, when the outer peripheral shape (contour) of the soft package is a square shape, the twist angle is the same by rotating the soft package 90 degrees about the axis in the thickness direction, and the twist direction is opposite ( (Negative direction) soft package product. For example, with respect to the flexible package 2C in which the twist direction shown in FIG. 5B is the positive direction, it is rotated 90 ° around the central axis Lz with respect to the thickness direction Z of the flexible package 2C (in this case, rotated 90 ° clockwise). ), The flexible package 2D has the same twist angle as that of the soft package 2C and is twisted in the negative direction. When a soft packaged product having an opposite twist direction is obtained by such a method, when printing is performed on the soft package product, an appearance in which the printing direction is rotated by 90 ° is obtained. If this is unacceptable as the appearance of the flexible packaged laminated bundle, it can be dealt with by preparing and using a packaging material having a printing pattern obtained by rotating the printing design by 90 ° in advance.

本発明の軟包装品積層束において、積層される軟包装品の枚数に特に制限はないが、束としての取り扱いやすさ、帯をとったときの板バネ効果による広がりやすさ、枚数の数えやすさを考慮すると、3枚〜20枚であるのが好ましく、5枚〜15枚であるのがより好ましい。なお、本発明の軟包装品積層束は、上記(a),(b)のいずれの態様においても、軟包装品2A,2Bまたは軟包装品2C,2Dは、上述のように交互に積層されたものであれば、それぞれ同枚数であってもよいし(それぞれ片側ずつに軟包装品が端に配置される)、片方の軟包装品が1枚多くてもよい(1枚多い方の軟包装品が両側の端に配置される)。   There is no particular limitation on the number of soft packages to be laminated in the soft package laminate bundle of the present invention, but the ease of handling as a bundle, the ease of spreading due to the leaf spring effect when strips are taken, and the number of sheets can be easily counted. In view of the above, the number is preferably 3 to 20, more preferably 5 to 15. In addition, the flexible packaged product laminated bundle of the present invention has the flexible packaged product 2A, 2B or the flexible packaged product 2C, 2D laminated alternately as described above in any of the above-described embodiments (a) and (b). As long as the number is the same, the number may be the same (a soft package is placed at the end of each side), or one soft package may be more (one more soft). The package is placed on both ends).

本発明の軟包装品積層束におけるシート状物(軟包装品における包装用フィルムにてシールされた内容物)は、その大きさに特に制限はない。ただし、大きさはシート状物としての取り扱いに適した大きさであるのが好ましく、また、厚すぎると軟包装品の周辺部に比べて中央部の厚さが十分に厚くなって、束にした場合に周辺部に隙間ができることから、本発明の効果を利用する必要性が少なくなる。よって、本発明の軟包装品積層束におけるシート状物の大きさは、一般に20〜25000mmの面積を有する大きさであり、好ましくは100〜15000mmの面積を有する大きさである。また、シート状物の厚みは、一般に0.01mm〜4mmであり、好ましくは0.02mm〜2mmである。またシート状物は、シート状であれば、その外周形状(輪郭)に特に制限はなく、方形状(正方形状、長方形状)、円形状(真円形状、楕円形状)、三角形状、多角形状等種々の形状のものが含まれる。なお、本発明におけるシート状物は、その構成材料として、織布、不織布等正確に厚みを測定することが困難な材料を含んでいてもよく、その場合には、上記と同様のシート状物の取り扱い性及び本発明の利用必要性等を考慮すると、シート状物の単位面積あたりの重量は一般に0.001g/cm〜0.4g/cm、好ましくは0.002g/cm〜0.2g/cmである。 The size of the sheet-like material (the content sealed with the packaging film in the soft package product) in the soft package laminate bundle of the present invention is not particularly limited. However, it is preferable that the size is suitable for handling as a sheet-like material, and if it is too thick, the thickness of the central portion will be sufficiently thick compared to the peripheral portion of the soft packaged product, so that it will become a bundle. In this case, there is a gap in the peripheral portion, so that the necessity of utilizing the effect of the present invention is reduced. Therefore, the size of the sheet-like material in the flexible packaged laminated bundle of the present invention is generally a size having an area of 20 to 25000 mm 2 , and preferably a size having an area of 100 to 15000 mm 2 . The thickness of the sheet-like material is generally 0.01 mm to 4 mm, preferably 0.02 mm to 2 mm. In addition, as long as the sheet-like material is a sheet shape, there is no particular limitation on the outer peripheral shape (contour), and a square shape (square shape, rectangular shape), circular shape (perfect circle shape, elliptical shape), triangular shape, polygonal shape And various other shapes. In addition, the sheet-like material in the present invention may include a material that is difficult to accurately measure the thickness, such as a woven fabric and a non-woven fabric, as a constituent material thereof. In consideration of the handling property and the necessity of using the present invention, the weight per unit area of the sheet is generally 0.001 g / cm 2 to 0.4 g / cm 2 , preferably 0.002 g / cm 2 to 0. 0.2 g / cm 2 .

本発明の軟包装品積層束におけるシート状物として適用できるものとしては、従来より軟包装品に用いられてきたものであれば特に制限されるものではなく、例えば、粘着層に薬物を含有させたテープ製剤(貼付剤)、皮膚(粘膜)保護用粘着テープ等の医療用テープ(小片シート)状製品等のテープ材、ウエットティシュ、美肌パックシート等のシート状衛材製品、メンブレンフィルターなどが挙げられる。中でも、医療現場で使用されることが多く、その際に迅速且つ確実な枚数確認と所要枚数の取り出しを行う必要性が高いことから、テープ材をシート状物として使用するのが特に好適である。   There are no particular restrictions on what can be applied as a sheet-like material in the soft-packaging laminated bundle of the present invention, as long as it has been used in soft-packaging products conventionally. For example, the adhesive layer contains a drug. Tape preparation (patch), tape material for medical tape (small sheet) products such as adhesive tape for skin (mucosal membrane) protection, sheet-like hygiene products such as wet tissue and skin care pack sheets, membrane filters, etc. Can be mentioned. Among them, it is often used in a medical field, and since it is highly necessary to quickly and surely confirm the number of sheets and take out the required number of sheets, it is particularly preferable to use a tape material as a sheet-like material. .

シート状物としてテープ材を用いる場合、その構成は特に限定されないが、たとえば、支持体、粘着剤層、セパレーターの三層構成が一般的である。
支持体としては、その材質は特に限定されるものではないが、皮膚追随性が妨げられないもの、すなわち、皮膚面の伸長に従って伸び縮みしやすいものが好ましく、具体的には、ポリエステル、ナイロン、ポリ塩化ビニリデン、ポリエチレン、ポリプロピレン、ポリ塩化ビニル、エチレン−酢酸ビニル共重合体、ポリテトラフルオロエチレン、サーリンなどの各種プラスチック材料を1種もしくは2種以上を用いて作製された単独フィルム又はこれらの積層フィルム、あるいはこれらのフィルムに織布や不織布などを積層したものを用いることができる。
When a tape material is used as the sheet-like material, the configuration is not particularly limited. For example, a three-layer configuration of a support, an adhesive layer, and a separator is common.
The material of the support is not particularly limited, but is preferably a material that does not hinder skin followability, that is, a material that easily stretches and contracts according to the elongation of the skin surface. Specifically, polyester, nylon, A single film made of one or more kinds of various plastic materials such as polyvinylidene chloride, polyethylene, polypropylene, polyvinyl chloride, ethylene-vinyl acetate copolymer, polytetrafluoroethylene, and surrin, or a laminate thereof. Films or those obtained by laminating woven fabrics or nonwoven fabrics on these films can be used.

粘着剤としては、医療用の粘着剤として用いられているものであれば特に限定されるものではなく、皮膚面に貼着した際に皮膚面にかぶれなどを生じないものが好ましい。例えば、従来より用いられているアクリル系粘着剤やゴム系粘着剤、シリコーン系粘着剤、ビニルエーテル系粘着剤あるいはビニルエステル系粘着剤などの各種粘着剤が用いられる。また、テープ製剤とする場合には、この粘着剤に溶解し得る、たとえば経皮吸収性を有する自体公知の薬物を粘着剤に含有させる。   The pressure-sensitive adhesive is not particularly limited as long as it is used as a medical pressure-sensitive adhesive, and a pressure-sensitive adhesive that does not cause rash on the skin surface when attached to the skin surface is preferable. For example, various pressure-sensitive adhesives such as acrylic pressure-sensitive adhesives, rubber-based pressure-sensitive adhesives, silicone-based pressure-sensitive adhesives, vinyl ether-based pressure-sensitive adhesives, and vinyl ester-based pressure-sensitive adhesives are used. In the case of a tape preparation, for example, a known drug having percutaneous absorption, which can be dissolved in the adhesive, is contained in the adhesive.

セパレーターとしては、通常のセパレーターとして用いられているものであればその材質は特に制限されるものではない。例えば、ポリエチレン、ポリプロピレン、ポリエステル、ポリ塩化ビニル、ポリアミド、エチレン−プロピレン共重合体、ポリスチレンなどの各種プラスチック材料が挙げられ、これらのうち1種もしくは2種以上をブレンドしたプラスチックフィルムが用いられる。また、アルミ箔などの金属フィルムを用いることができ、必要に応じて前記プラスチックフィルムとの積層体を用いてもよい。さらに、上質紙、グラシン紙、パーチメント紙あるいはこれらの剥離紙にポリエチレンなどをラミネートした上質紙などを用いることもできる。   The material of the separator is not particularly limited as long as it is used as a normal separator. Examples thereof include various plastic materials such as polyethylene, polypropylene, polyester, polyvinyl chloride, polyamide, ethylene-propylene copolymer, and polystyrene, and a plastic film obtained by blending one or more of these materials is used. Moreover, metal films, such as aluminum foil, can be used and you may use a laminated body with the said plastic film as needed. Furthermore, high-quality paper, glassine paper, parchment paper, or high-quality paper obtained by laminating polyethylene or the like on these release papers can also be used.

本発明の軟包装品積層束における包装用フィルムとしては、無延伸フィルム、一軸延伸フィルム、二軸延伸フィルムのいずれかのフィルムを基材フィルムとして有するものを用いる。フィルム強度の観点からは、二軸延伸フィルムを基材フィルムとして含有する包装用フィルムを用いるのが好ましい。基材フィルムの形成材料としては、公知の樹脂材料を特に制限なく使用することができ、たとえば、ポリエチレンテレフタレート、ポリエチレンナフタレート、ポリプロピレン、ポリビニルアルコール、エチレン−ビニルアルコール共重合体、ポリ塩化ビニリデン、ポリスチレン、ナイロン、セロハン、ポリエチレン、エチレン−酢酸ビニル共重合体、アイオノマー、ポリ塩化ビニル、ポリカーボネートなどが挙げられ、中でも二軸延伸フィルムの形成材料として好適なポリエチレンテレフタレート、ポリエチレンナフタレート、ポリプロピレン、ポリビニルアルコール、エチレン−ビニルアルコール共重合体、ポリ塩化ビニリデン、ポリスチレン、ナイロン、ポリ塩化ビニル、ポリカーボネート、ポリエチレンが好ましく、フィルム強度および価格の面からポリエチレンテレフタレートまたはポリプロピレンが特に好ましい。   As the packaging film in the flexible packaged laminated bundle of the present invention, a film having any of a non-stretched film, a uniaxially stretched film, and a biaxially stretched film as a base film is used. From the viewpoint of film strength, it is preferable to use a packaging film containing a biaxially stretched film as a base film. As a material for forming the base film, known resin materials can be used without any particular limitation. For example, polyethylene terephthalate, polyethylene naphthalate, polypropylene, polyvinyl alcohol, ethylene-vinyl alcohol copolymer, polyvinylidene chloride, polystyrene , Nylon, cellophane, polyethylene, ethylene-vinyl acetate copolymer, ionomer, polyvinyl chloride, polycarbonate, and the like. Ethylene-vinyl alcohol copolymer, polyvinylidene chloride, polystyrene, nylon, polyvinyl chloride, polycarbonate, polyethylene are preferred, and film strength Polyethylene terephthalate or polypropylene from the viewpoint of fine prices are particularly preferred.

なお二軸延伸フィルムの中でもTダイ・テンター法で製造された二軸延伸フィルムを基材フィルムに使用すると、いわゆるボーイング現象を利用して、上述したようなねじれ角度の軟包装品を容易に得ることができるため、好ましい。
すなわち、Tダイ・テンター法の二軸延伸フィルムは、テンター内での幅方向に延伸(横延伸)する工程において、いわゆるボーイング現象のために、フィルムの幅方向で物性の異方性が生じる。ボーイング現象とは、テンターに入る前に、幅方向に引いた直線が、テンターを出ると、フィルム中央部においてフィルムの進行方向とは逆の方向に凸となるような弓形に湾曲する現象である。このようなボーイング現象を起こしたフィルムを用いた包装用フィルムを2枚向かい合わせてシールして軟包装品を作製すると、ねじれが発生するが、ねじれの発生は、従来、外観不良と見なされ、ねじれの発生を極力抑えるための検討がフィルムメーカーにて多くなされてきたものである(たとえば、特開平7−80928号などを参照。)。ボーイング現象により、配向の主軸の傾きが幅方向で異なるので、Tダイ・テンター法の二軸延伸フィルム原反の中央部分から幅方向に関しどれだけ離れた位置から二軸延伸フィルムを取得するか選択することで、Tダイ・テンター法の二軸延伸フィルムを基材フィルムとして用いた包装用フィルムにてシート状物をシールして軟包装品を作製した際に、様々なねじれ角度を有する軟包装品を得ることができる。具体的には、Tダイ・テンター法の二軸延伸フィルム原反中の中央部分を使って作製した包装用フィルムを用いればねじれの殆どない軟包装品を得ることができ、Tダイ・テンター法の二軸延伸フィルム原反の幅方向に関する端に近い部分を使って作製した包装用フィルムを用いれば、ねじれの大きい軟包装品を得ることができる。また、Tダイ・テンター法の二軸延伸フィルム原反の中央部分から同程度離れた位置より二軸延伸フィルムを取得することで、それぞれねじれ角度の絶対値が同程度であり、互いに反対の方向にねじれた軟包装品を得ることができる。
In addition, when a biaxially stretched film manufactured by the T-die / tenter method is used as a base film among biaxially stretched films, a soft packaged product having a twist angle as described above can be easily obtained by utilizing a so-called bowing phenomenon. This is preferable.
That is, the biaxially stretched film of the T-die / tenter method has physical property anisotropy in the width direction of the film due to a so-called bowing phenomenon in the step of stretching in the width direction (lateral stretching) in the tenter. The bowing phenomenon is a phenomenon in which a straight line drawn in the width direction before entering the tenter is bent into an arc shape that protrudes in the direction opposite to the film traveling direction at the center of the film when it exits the tenter. . When a flexible packaging product is produced by sealing two packaging films using such a bowing film face to face, twisting occurs, but the occurrence of twisting is conventionally regarded as a poor appearance, Many studies have been made by film makers to suppress the occurrence of twisting as much as possible (see, for example, JP-A-7-80928). Since the inclination of the main axis of orientation differs in the width direction due to the bowing phenomenon, select how far the biaxially stretched film is obtained from the position in the width direction from the center part of the biaxially stretched film original fabric of the T-die / tenter method Thus, when a flexible packaging product is produced by sealing a sheet with a packaging film using a biaxially stretched film of the T-die / tenter method as a base film, the flexible packaging has various twist angles. Goods can be obtained. Specifically, if a packaging film produced using the central portion of the biaxially stretched film of the T-die / tenter method is used, a soft package with almost no twist can be obtained. If the packaging film produced using the part close | similar to the edge regarding the width direction of this biaxially stretched film original fabric is used, a flexible package product with a large twist can be obtained. Also, by obtaining a biaxially stretched film from a position that is about the same distance from the central portion of the biaxially stretched film of the T-die / tenter method, the absolute values of the twist angles are the same, and the directions opposite to each other. It is possible to obtain a flexible package that is twisted in the shape of a screw.

Tダイ・テンター法の二軸延伸フィルムの二軸延伸フィルム原反中での幅方向の位置に関する製造時情報を二軸延伸フィルムメーカー、包装用フィルムメーカーに確認することで、その包装用フィルムを使用して軟包装品を作製した場合のねじれの向き、角度を選択することができる。Tダイ・テンター法の二軸延伸フィルムの二軸延伸フィルム原反中での幅方向の位置が同じでも、貼り合せるシーラントのコシによって、ねじれの大きさは異なる。従って、各仕様の包装用フィルム毎にTダイ・テンター法二軸延伸フィルムの二軸延伸フィルム原反中での幅方向の位置に関する情報と、各仕様の軟包装品のねじれの向き及び大きさとの関係を予め実験で確認しておくことで、所望のねじれの向き、角度の軟包装品を得ることができる。このようにTダイ・テンター法の二軸延伸フィルムを包装用フィルの基材フィルムに用いると、所望のねじれ角度の軟包装品を容易に得ることができるという利点がある。   Check the manufacturing information about the position in the width direction of the biaxially stretched film of the biaxially stretched film of the T-die / tenter method with the biaxially stretched film manufacturer and the packaging film manufacturer. It is possible to select the direction and angle of twist when a soft package is produced. Even if the position in the width direction of the biaxially stretched film of the T-die / tenter method is the same in the width direction of the biaxially stretched film, the amount of twist differs depending on the stiffness of the sealant to be bonded. Therefore, for each packaging film of each specification, information on the position in the width direction of the biaxially stretched film of the T-die / tenter method biaxially stretched film, and the twist direction and size of the soft packaged product of each specification By confirming the relationship in advance through experiments, a soft package product having a desired twist direction and angle can be obtained. As described above, when the biaxially stretched film of the T-die / tenter method is used for the base film of the packaging fill, there is an advantage that a flexible package product having a desired twist angle can be easily obtained.

本発明における包装用フィルムは、上記基材フィルム自身がシール(ヒートシール)可能なものであれば当該基材フィルムのみからなるものであってもよいし、必要に応じ、当該基材フィルムを含む複数枚のフィルムで構成されていてもよい。すなわち、基材フィルム以外に、シールのためのシーラントを有していてもよいし、その他、アルミ箔や紙などを積層していてもよいし、その表面にポリ塩化ビニリデンやアルミナなどをコーティングしてもよい。また、アルミニウムや酸化アルミニウムやケイ素酸化物を蒸着してもよい。繰り返し曲げ応力試験における1回目曲げ応力最大値が0.01N/15mm幅/2枚〜2.0N/15mm幅/2枚であり、2回目曲げ応力最大値が1回目曲げ応力最大値の80%以上である、後述する本発明において好適な包装用フィルムであって、しかも良好なヒートシール性を両立させた包装用フィルムを実現し得る観点からは、基材フィルムとシーラントとを必須とする多層構造の複合フィルムにて包装用フィルムを形成するのが好ましい。   The packaging film in the present invention may be composed only of the base film as long as the base film itself can be sealed (heat sealed), and includes the base film as necessary. It may be composed of a plurality of films. In other words, in addition to the base film, it may have a sealant for sealing, or may be laminated with aluminum foil or paper, and the surface thereof is coated with polyvinylidene chloride or alumina. May be. Further, aluminum, aluminum oxide, or silicon oxide may be deposited. The first bending stress maximum value in the repeated bending stress test is 0.01 N / 15 mm width / 2 sheets to 2.0 N / 15 mm width / 2 sheets, and the second bending stress maximum value is 80% of the first bending stress maximum value. From the viewpoint of realizing a packaging film suitable for the present invention, which will be described later, and having a good heat-sealing property, a multilayer film essentially including a base film and a sealant. It is preferred to form the packaging film with a composite film of structure.

シーラントとしては、ヒートシール性が良好で、包装用フィルム全体に適度な曲げ応力を付与できる材質であれば特に制限はなく、ポリアクリロニトリル、ポリエチレン、セロハン、無延伸ポリプロピレン、非晶質コポリエステルなどを用いることができる。なお、粘着剤中に薬物を含有するテープ製剤をシート状物として用いる場合には、薬物の吸着を低減する目的より、シーラントとしてポリアクリロニトリルを用いるのが好ましい。シーラントを有する場合、該シーラントと基材フィルムとの接着手段は、接着剤を用いるものであっても熱融着を利用するものであってもよい。   The sealant is not particularly limited as long as it has a good heat sealing property and can impart an appropriate bending stress to the entire packaging film, such as polyacrylonitrile, polyethylene, cellophane, unstretched polypropylene, and amorphous copolyester. Can be used. In the case where a tape preparation containing a drug in the adhesive is used as a sheet, it is preferable to use polyacrylonitrile as a sealant for the purpose of reducing drug adsorption. When it has a sealant, the means for adhering the sealant and the substrate film may be one using an adhesive or utilizing heat fusion.

このような包装用フィルムにてシート状物をシールすることで、軟包装品を得ることができる。シールの方法は、通常、ヒートシールすることで行うが、包装用フィルムでシート状物を覆った状態で密封できるのであれば、ヒートシールによらなくともよく、例えば、接着剤でシールしてもよい。ボーイング現象によるねじれ発現の促進に加熱処理が必要な場合は、ヒートシールであれば、シールと加熱処理を同時に行えるので好ましいが、接着剤によるシールと加熱処理を別工程として行うこともできる。シールのパターンは何でもよく、公知の四方シール、三方シール、センターシールなどの形態にてシート状物を袋状に形成できるものであればよい。シール幅は1mm〜20mmの範囲で任意に選択できる。シールのゴザ目の形状も平型、波状型、網状型、斜網状型、三線シール型など任意に選択できる。   A flexible package can be obtained by sealing a sheet-like material with such a packaging film. The sealing method is usually performed by heat sealing. However, if sealing can be performed in a state where the sheet-like material is covered with a packaging film, heat sealing is not necessary, for example, sealing with an adhesive is possible. Good. When heat treatment is required to promote twisting due to the bowing phenomenon, heat sealing is preferable because the sealing and the heat treatment can be performed simultaneously, but the sealing with the adhesive and the heat treatment can also be performed as separate steps. Any pattern may be used as long as the sheet-like material can be formed into a bag shape in the form of a known four-way seal, three-way seal, center seal or the like. The seal width can be arbitrarily selected in the range of 1 mm to 20 mm. The shape of the goblet of the seal can be arbitrarily selected from a flat shape, a wave shape, a mesh shape, an oblique mesh shape, a three-wire seal shape, and the like.

上記のように基材フィルムがTダイ・テンター法の二軸延伸フィルムである包装用フィルムを用いてシート状物をシールすることで、ボーイング現象による軟包装品のねじれが発生し、本発明における軟包装品2A、2C及び2Dを容易に得ることができる。   As described above, by twisting the sheet-like material using the packaging film in which the base film is a biaxially stretched film of the T-die / tenter method, twisting of the flexible package due to the bowing phenomenon occurs, and in the present invention The flexible packaged products 2A, 2C and 2D can be easily obtained.

また本発明においては、二軸延伸フィルムを基材フィルムとして用いない場合であっても、包装用フィルムにてシート状物をシールする際に、包装用フィルムにねじれを付与し得る形状としたヒートシール金型にて挟み込んでヒートシールして軟包装品を得るようにすることでも、ねじれ(ねじれ角度)を有する軟包装品を得ることができ、また、ヒートシール金型の形状を調整することで、適宜のねじれ角度を得ることができる。かかるヒートシール金型としては、例えば、図8に示すように、その中央部に包装用フィルムで覆われたシート状物が収容される凹部が形成された上側金型41及び下側金型42を、それぞれのヒートシール面41A及び42Aにおける2組の対向するコーナー部のうちの一方の対向するコーナー部(41aと41b、42cと42d)が最も出っ張り、他方の対向するコーナー部(41cと41d、42aと42b)が最も凹み、隣り合うコーナー部間が傾斜面となる形状にして、双方のヒートシール面41Aと42Aがピッタリと合さるように(包装用フィルムを挟まない状態で一様に密着するように)面加工を施した金型50を挙げることができる。この金型50のようなヒートシール面に出っ張り部(凹部)を設けた金型の出っ張り部(凹部)の位置、大きさ等を適宜変更することで、金型でヒートシールして成型した軟包装品のねじれの向き、大きさを変えることができる。   Further, in the present invention, even when a biaxially stretched film is not used as a base film, when sealing a sheet-like material with a packaging film, the heat is made to give a twist to the packaging film. It is possible to obtain a flexible package product having a twist (twist angle) by adjusting the shape of the heat seal mold by also sandwiching with a seal mold and heat-sealing to obtain a flexible package product. Thus, an appropriate twist angle can be obtained. As such a heat seal mold, for example, as shown in FIG. 8, an upper mold 41 and a lower mold 42 in which a concave portion in which a sheet-like material covered with a packaging film is accommodated is formed at the center. Of the two opposing corners on each of the heat sealing surfaces 41A and 42A, one opposing corner (41a and 41b, 42c and 42d) protrudes the most, and the other opposing corner (41c and 41d). , 42a and 42b) are the most concave, and the shape between the adjacent corners is an inclined surface, so that both heat seal surfaces 41A and 42A fit perfectly (with no packaging film sandwiched) A die 50 which has been subjected to surface processing (to be in close contact) can be mentioned. By appropriately changing the position, size, etc. of the protruding portion (recessed portion) of the mold provided with a protruding portion (recessed portion) on the heat-sealing surface such as the mold 50, the soft seal molded by heat sealing with the mold. The direction and size of twist of the package can be changed.

本発明における軟包装品は、シート状物を包装用フィルムでシールしてなるものであるので、その形状はシート状である。軟包装品の外周形状(輪郭)は、特に制限されるものではなく、方形状(正方形状、長方形状)、円形状(真円形状、楕円形状)、三角形状、多角形状などが挙げられるが、方形状の軟包装品を使用するのが好ましい。なお、外周形状(輪郭)が方形状とは、外周形状(輪郭)が概ね方形であるならば、その四つの角の少なくともいずれかを丸めた形状や、辺が直線状ではなく波線状、凹凸線、ジグザグ線(鋸刃状)、曲線状であるようなものも包含するものとする。このような外周形状(輪郭)が方形状の軟包装品を用いることで、これらを積層し束ねた際に、互いに隣接する軟包装品同士のねじれ角度が異なっていても、束にして保管や移送しているときに隣接する軟包装品同士のねじれの向きがずれることがなく、帯を外したときに板ばね効果を確実に発現することができる。特に、方形状の角の部分により板ばね効果を効果的に発現することができるので、好適な形状である。また、外周形状(輪郭)が方形状の軟包装品を用いることで、包装用フィルムロールの幅方向及び長手方向と平行となるように、軟包装品の各辺を隣接配置して切り出せば、切り落として捨てる部分の面積を小さくすることができ、シート状物をシールする際の包装用フィルムの歩留りが向上する。   Since the soft package in the present invention is formed by sealing a sheet-like material with a packaging film, the shape thereof is a sheet. The outer peripheral shape (contour) of the flexible package is not particularly limited, and examples thereof include a square shape (square shape, rectangular shape), a circular shape (perfect circle shape, elliptical shape), a triangular shape, and a polygonal shape. It is preferable to use a rectangular soft package. In addition, if the outer peripheral shape (contour) is a square shape, if the outer peripheral shape (contour) is generally a square shape, the shape in which at least one of the four corners is rounded, the side is not a straight line, a wavy line shape, an uneven shape Also included are lines, zigzag lines (sawtooth), and curves. By using soft packaging products having a rectangular outer shape (contour), even when they are stacked and bundled, even if the twist angles of adjacent soft packaging products are different, they can be stored in a bundle. The direction of twisting between adjacent soft packaging products does not shift when transporting, and the leaf spring effect can be reliably exhibited when the band is removed. In particular, the leaf spring effect can be effectively expressed by the square corners, which is a preferable shape. Moreover, if the outer peripheral shape (contour) is a rectangular-shaped soft packaging product, and cuts out each side of the flexible packaging product so that it is parallel to the width direction and the longitudinal direction of the packaging film roll, The area of the portion to be cut off and discarded can be reduced, and the yield of the packaging film when sealing the sheet-like material is improved.

軟包装品の大きさも特に制限されるものではないが、上記の外周形状(輪郭)が方形状である場合、各辺の長さが2.0cm〜20cmから選ばれるような大きさであるのが好ましい。いずれかの辺の長さが2.0cm未満であると、帯状物を外した際に互いに隣接する軟包装品同士の隙間が小さくなり、軟包装品の取り出し性や数え易さの効果が小さくなる傾向にあるためであり、また、いずれかの辺の長さが20cmよりも大きいと、軟包装品の全体にたわみが生じ、ねじれ形状を保持できず、帯状物を外した際の板ばね効果を充分に発揮できなくなる虞があるためである。なお、本発明における軟包装品は、取扱い性が良好で、板バネ効果を発揮できるような適度なコシとするために、その厚みが0.004cm〜0.5cmであるのが好ましく、0.005cm〜0.3cmであるのがより好ましい。   The size of the flexible package is not particularly limited, but when the outer peripheral shape (contour) is a square shape, the length of each side is selected from 2.0 cm to 20 cm. Is preferred. If the length of either side is less than 2.0 cm, the gap between the soft packaging products adjacent to each other when the strip is removed becomes small, and the effect of ease of taking out and counting of the soft packaging products is small. In addition, if the length of any side is larger than 20 cm, the entire flexible package is bent, the twisted shape cannot be maintained, and the leaf spring when the strip is removed This is because the effect may not be sufficiently exhibited. In addition, the flexible package in the present invention preferably has a thickness of 0.004 cm to 0.5 cm in order to obtain an appropriate stiffness that is easy to handle and can exhibit the leaf spring effect. More preferably, it is 005 cm to 0.3 cm.

なお、本発明の軟包装品積層束における包装用フィルムは、繰り返し曲げ応力試験における1回目曲げ応力最大値が0.01N/15mm幅/2枚〜2.0N/15mm幅/2枚(さらに好適には、0.05N/15mm幅/2枚〜1.5N/15mm幅/2枚)であり、2回目曲げ応力最大値が1回目曲げ応力最大値の80%以上(さらに好適には、85%以上)であるものを使用するのが、好ましい。1回目曲げ応力最大値が0.01N/15mm幅/2枚未満である包装用フィルムを用いると、ねじれた形状の軟包装品を作製しても、軟包装品の板ばね効果が弱くなる傾向にあり、好ましくない。また、1回目曲げ応力最大値が2.0N/15mm幅/2枚を越える包装用フィルムを用いると、ねじれた形状の軟包装品を積層して帯び掛けする際に強い力が必要になり、作業性が悪くなる傾向にあるため好ましくない。また、2回目曲げ応力最大値が1回目曲げ応力最大値の80%よりも小さい包装用フィルムを用いると、ねじれた形状の軟包装品を作製しても、積層品束の状態での保管中にねじれた形状が変形して固定されてしまうので、帯状物を外しても軟包装品作製当初のねじれ形状を復元できなくなってしまう虞があるため好ましくない。   In addition, the packaging film in the soft package laminate bundle of the present invention has a first bending stress maximum value of 0.01 N / 15 mm width / 2 sheets to 2.0 N / 15 mm width / 2 sheets in a repeated bending stress test (more suitable) Is 0.05 N / 15 mm width / 2 sheets to 1.5 N / 15 mm width / 2 sheets, and the second bending stress maximum value is 80% or more of the first bending stress maximum value (more preferably, 85 % Or more) is preferably used. When a packaging film having a first bending stress maximum value of less than 0.01 N / 15 mm width / 2 sheets is used, the leaf spring effect of the flexible package tends to be weak even if a twisted flexible package is produced. This is not preferable. In addition, if a packaging film having a maximum bending stress of 2.0N / 15mm width / 2 sheets at the first time is used, a strong force is required when stacking and wrapping twisted flexible packaging products. Since workability tends to deteriorate, it is not preferable. In addition, when a packaging film having a maximum second bending stress value smaller than 80% of the first bending stress maximum value is used, it is still stored in a laminated product bundle state even if a twisted flexible packaging product is produced. Since the twisted shape is deformed and fixed, it may not be possible to restore the twisted shape at the beginning of the production of the flexible package even if the strip is removed.

図6は、本発明における包装用フィルムの繰り返し曲げ応力試験を模式的に示す図である。かかる試験は、具体的には、以下の手順にて行う。
図6に示すように、圧縮応力測定試験機21(たとえば、SUN RHEO METER CR−150、CR−200D、SUN SCIENTIFIC CO.,LTD)のステージ22上に金属ブロック23を固定し、その上にもう1個の金属ブロック24を置き、2つの金属ブロック23,24の間に試料を挟める状態にする。圧縮応力試験機21の圧力検知部に板状の金属治具25(22mm×46mm×3mm)を取り付け、金属治具25の側面と金属ブロック23,24の側面とを平行にし、その隙間を正確に試験用包装用フィルム2枚分の厚み+1.0mmに調整する。
FIG. 6 is a diagram schematically showing a repeated bending stress test of the packaging film in the present invention. Specifically, this test is performed according to the following procedure.
As shown in FIG. 6, a metal block 23 is fixed on a stage 22 of a compressive stress measurement tester 21 (for example, SUN RHEO METER CR-150, CR-200D, SUN SCIENTIFIC CO., LTD). One metal block 24 is placed and the sample is sandwiched between the two metal blocks 23 and 24. A plate-shaped metal jig 25 (22 mm × 46 mm × 3 mm) is attached to the pressure detection part of the compressive stress testing machine 21 so that the side surface of the metal jig 25 and the side surfaces of the metal blocks 23 and 24 are parallel to each other, and the gap is accurately determined. The thickness is adjusted to +1.0 mm for two test packaging films.

軟包装品のヒートシールしていない部分の包装用フィルムを20mm×15mmサイズで2枚切り出して試料26とし、試料26の内面(軟包装品の状態での内面)同士を向かい合わせて、2枚を重ねる。この2枚重ねの試料26を上記の金属ブロック23,24の間に挟んで固定する。このとき、2枚重ねの試料26の半分を金属ブロックに挟み、金属ブロック23,24の外側に10mm×15mmの2枚重ねの試料26が出る状態とする。
この状態で、ステージ22を100mm/minの速度で上昇させ、金属治具25と金属ブロック23,24の隙間部分で2枚重ねの試料26を折り曲げ、そのときの曲げ応力の最大値を測定する。金属治具25の下端を基準位置として、試料取り付け位置が基準位置の下部10mmの位置にある状態からスタートし、試料取り付け位置が基準位置の上部10mmの位置に来るまでステージを上昇させて、1回目曲げ応力最大値を測定する。
その後、ステージ22をスタート位置(試料取り付け位置が基準位置の下部10mmの位置にある状態)に戻し、再度、試料取り付け位置が基準位置の上部10mmの位置に来るまでステージ22を上昇させて、2回目曲げ応力最大値を測定する。そして、2回目曲げ応力最大値の1回目曲げ応力最大値に対する比率(%)を求める。
このようにして、上記包装用フィルムの1回目曲げ応力最大値、ならびに2回目曲げ応力最大値の1回目曲げ応力最大値に対する比率(%)を測定することができる。
Cut two pieces of packaging film of the unwrapped portion of the flexible package in 20 mm × 15 mm size to make the sample 26, and the inner surface of the sample 26 (the inner surface in the state of the soft package) face each other, two sheets Repeat. The two stacked samples 26 are sandwiched and fixed between the metal blocks 23 and 24 described above. At this time, half of the two-layer sample 26 is sandwiched between the metal blocks, and the 10-mm × 15-mm two-layer sample 26 comes out of the metal blocks 23 and 24.
In this state, the stage 22 is raised at a speed of 100 mm / min, the two-layered sample 26 is bent at the gap between the metal jig 25 and the metal blocks 23 and 24, and the maximum value of the bending stress at that time is measured. . Starting from a state where the lower end of the metal jig 25 is the reference position and the sample mounting position is 10 mm below the reference position, the stage is raised until the sample mounting position is 10 mm above the reference position. Measure the maximum bending stress.
Thereafter, the stage 22 is returned to the start position (the state where the sample mounting position is at the lower 10 mm position of the reference position), and the stage 22 is raised again until the sample mounting position reaches the upper 10 mm position of the reference position. Measure the maximum bending stress. Then, the ratio (%) of the second bending stress maximum value to the first bending stress maximum value is obtained.
Thus, the first bending stress maximum value of the packaging film and the ratio (%) of the second bending stress maximum value to the first bending stress maximum value can be measured.

本発明の軟包装品積層束において、複数枚の軟包装品を束ねるための帯状物としては、従来より軟包装品積層束の帯状物として使用されてきたものを特に制限なく用いることができ、たとえば、二軸延伸ポリプロピレンフィルム、二軸延伸ポリエステルフィルム、二軸延伸ナイロンフィルム、ポリエチレンコートクラフト紙、などの長尺物を用いることができる。中でも、安価で、帯として十分な強度があり、ヒートシール性、切断性も良好であることから、二軸延伸ポリプロピレンフィルムの長尺物を帯状物として用いるのが好ましい。このような帯状物を、積層した軟包装体の周りに巻いて、たとえばヒートシールすることで、本発明の軟包装品積層束を作製することができる。   In the flexible packaged laminated bundle of the present invention, as a band for bundling a plurality of soft packaged products, those conventionally used as a band of a flexible packaged laminated bundle can be used without particular limitation, For example, long materials such as a biaxially stretched polypropylene film, a biaxially stretched polyester film, a biaxially stretched nylon film, and a polyethylene-coated kraft paper can be used. Among them, it is preferable to use a long biaxially stretched polypropylene film as the band because it is inexpensive, has sufficient strength as a band, and has good heat sealability and cutability. By winding such a band-like material around the laminated soft package and heat-sealing it, for example, the soft package laminate bundle of the present invention can be produced.

本発明の軟包装品積層束は、工業的には、2連自動包装機のそれぞれの連で、ねじれ角度の異なる軟包装品を作製し、それらを合流させて、それぞれの連で作製した軟包装品を交互に積層し、帯状物にて束ねることで生産することができる。あるいは、2連自動包装機の双方でねじれの向きが同じで、実質的に正方形の軟包装品を作製し、片方の連の軟包装品を90°回転させて、もう一方の連で作製した軟包装品と交互に積層し、束ねることでも生産できる。
また、1連自動包装機で、あるねじれ角度の軟包装品を作製してストックしておき、その後、別のねじれ角度の軟包装品を作製しこれもまたストックし、その後、2種類の軟包装品を交互に積層して、帯状物にて束ねることでも生産することができる。さらにまた、1連自動包装機で1°〜20°のねじれ角度でねじれている実質的に正方形の軟包装品を作製し、この半分を90°回転させて、逆向きねじれの軟包装品とし、ねじれ角度が2種類の軟包装品を交互に積層し、帯状物で束ねることでも生産できる。
The laminated bundle of soft packaging products of the present invention is industrially produced by producing soft packaging products with different twist angles in each series of two automatic packaging machines, and joining them together to produce the soft packaging products produced in each series. It can be produced by alternately stacking packaged products and bundling them with strips. Alternatively, the twisting direction is the same in both of the two automatic packaging machines, and a substantially square flexible packaging product is produced, and one of the flexible packaging products is rotated by 90 ° and produced in the other series. It can also be produced by alternately laminating and bundling with soft packaging.
In addition, a single automatic packaging machine produces and stocks a soft package product with a certain twist angle, and then creates a soft package product with another twist angle and stocks it, and then two types of soft packages. It can also be produced by alternately stacking packaged products and bundling them with strips. Furthermore, a substantially square soft packaging product that is twisted at a twist angle of 1 ° to 20 ° is produced by a single automatic packaging machine, and this half is rotated by 90 ° to obtain a soft packaging product of reverse twist. It can also be produced by alternately laminating two types of flexible packaging products with two twist angles and bundling them with strips.

図7は、本発明の軟包装品積層束1,1’を箱体6に収容したところを簡略化して示す図である。本発明の軟包装品積層束1,1’は、帯状物3を外した後の軟包装品同士の広がりを大きく保つ目的で、たとえば一方で全面に開口した箱体であって、開口を有する側を上側とし、その反対側の下側の底部が開口を有する側よりも狭い空間を有するような箱体6に収容してもよい。このような箱体6に、帯状物3を外した状態の軟包装品積層束1,1’を立てるなどすることで、さらに各軟包装品2を取り出しやすく、また、軟包装品の枚数確認をし易くしてもよい。   FIG. 7 is a schematic view showing a state where the flexible packaged laminated bundles 1 and 1 ′ of the present invention are accommodated in the box body 6. The soft-packaging product stack 1, 1 'of the present invention is, for example, a box that is opened on the entire surface and has an opening for the purpose of keeping the spread of the soft-packaging products after the strip 3 is removed. You may accommodate in the box 6 which makes a side the upper side and has a space where the bottom part of the lower side on the opposite side has a narrower space than the side which has an opening. It is easier to take out each soft package 2 by setting up the stacks 1 and 1 'of the soft package with the strip 3 removed from the box 6, and confirming the number of soft packages It may be easy to do.

以下に実施例を示し、本発明を具体的に説明するが、本発明は下記の実施例に制限されるものではない。   EXAMPLES Hereinafter, the present invention will be specifically described with reference to examples. However, the present invention is not limited to the following examples.

実施例1
窒素雰囲気下でアクリル酸5重量部、アクリル酸2−エチルヘキシルエステル95重量部を共重合させて得られたアクリル系共重合体40重量部に、日局リドカイン60重量部を酢酸エチル中で配合し、これを75μm厚のポリエステル製のセパレーター上に乾燥後の厚みが20μmとなるように塗布、乾燥して粘着剤層を形成した後、この粘着剤層を12μm厚のポリエステルフィルムに貼り合わせて貼付剤を得た。これを3cm×5cmの大きさに裁断し、貼付剤のシート状物を作製した。
次に、「Tダイ・テンター法二軸延伸ポリエステルフィルム(12μm厚)/接着剤層/ポリアクリロニトリルフィルム(20μm厚)」の包装用フィルムで、ポリアクリロニトリルフィルム側を内側にして、貼付剤のシート状物(3cm×5cmサイズ)を挟み込んでヒートシールし、四方ヒートシール包装してなる断面方形状の軟包装品(5cm×7cmサイズ、シール幅:5mm)を作製した。この際、Tダイ・テンター法二軸延伸ポリエステルフィルム原反(4.5m幅)の幅方向一方側の端寄り部分(幅方向一方側の端から1.0m離れた付近)の二軸延伸ポリエステルフィルムを基材フィルムとして用いて作製された包装用フィルムを使用し、表材と裏材として向かい合わせてヒートシールした。このとき表材と裏材の包装用フィルムの幅方向、長手方向は一致させた。この結果、Tダイ・テンター法二軸延伸ポリエステルフィルムのボーイング現象によりねじれ角度+14°の軟包装品を得た。
同様にして、Tダイ・テンター法二軸延伸ポリエステルフィルム原反(4.5m幅)の幅方向他方側の端寄り部分(幅方向他方側の端から1.3m離れた付近)の二軸延伸ポリエステルフィルムを基材フィルムとして用いて作製された包装用フィルムを用いて、ねじれ角度−10°の軟包装品を得た。
ねじれ角度+14°の軟包装品とねじれ角度−10°の軟包装品とを交互に5枚ずつ積層し、合計10枚とし、25mm幅、40μm厚の二軸延伸ポリプロピレンフィルムで軟包装品の長辺中央部の周りを巻いてヒートシールして結束し、軟包装品積層束を得た。
Example 1
60 parts by weight of JP lidocaine was blended in ethyl acetate with 40 parts by weight of an acrylic copolymer obtained by copolymerizing 5 parts by weight of acrylic acid and 95 parts by weight of 2-ethylhexyl acrylate in a nitrogen atmosphere. Then, this was coated on a 75 μm thick polyester separator so that the thickness after drying was 20 μm, dried to form an adhesive layer, and then this adhesive layer was bonded to a 12 μm thick polyester film and pasted. An agent was obtained. This was cut into a size of 3 cm × 5 cm to prepare a patch sheet.
Next, a “T die / tenter method biaxially stretched polyester film (12 μm thick) / adhesive layer / polyacrylonitrile film (20 μm thick)” packaging film, with the polyacrylonitrile film side facing inward, The product (3 cm × 5 cm size) was sandwiched and heat-sealed, and a four-sided heat-sealed packaged cross-sectional soft package product (5 cm × 7 cm size, seal width: 5 mm) was produced. At this time, the biaxially stretched polyester of the T die / tenter method biaxially stretched polyester film raw material (4.5m width) near the end on one side in the width direction (near 1.0m away from the end on the one side in the width direction) A packaging film produced using the film as a base film was used, and heat-sealed face-to-face as a backing material. At this time, the width direction and the longitudinal direction of the front and back packaging films were matched. As a result, a flexible package product having a twist angle of + 14 ° was obtained due to the bowing phenomenon of the T-die tenter method biaxially stretched polyester film.
Similarly, biaxial stretching of the T die / tenter method biaxially stretched polyester film raw material (4.5m width) nearer the other side in the width direction (around 1.3m away from the width direction other side) Using a packaging film produced using a polyester film as a base film, a flexible packaging product having a twist angle of −10 ° was obtained.
A flexible package with a twist angle of + 14 ° and a flexible package with a twist angle of -10 ° are alternately laminated to form a total of 10 pieces, and the length of the flexible package is 25 mm wide and 40 μm thick biaxially oriented polypropylene film. Around the central part of the side, it was heat-sealed and bound to obtain a flexible packaged laminated bundle.

実施例2
Tダイ・テンター法二軸延伸ポリエステルフィルム原反(4.5m幅)の幅方向中央部(幅方向一方の端、他方側の端からそれぞれ2.25m離れた付近)の二軸延伸ポリエステルフィルムを基材フィルムとして用いて作製された包装用フィルムを用いた以外は実施例1と同様にして、ねじれ角度0°の軟包装品を作製した。こうして得られたねじれ角度0°の軟包装品と、実施例1で作製したねじれ角度+14°の軟包装品とを交互に5枚ずつ積層し、合計10枚とし、25mm幅、40μm厚の二軸延伸ポリプロピレンフィルムで軟包装品の長辺中央部の周りを巻いてヒートシールして結束し、軟包装品積層束を得た。
Example 2
A biaxially stretched polyester film at the center in the width direction of the T-die / tenter biaxially stretched polyester film (4.5m width) (near 2.25m away from one end in the width direction and the other end). A flexible packaging product having a twist angle of 0 ° was produced in the same manner as in Example 1 except that the packaging film produced using the base film was used. The thus obtained soft package product with a twist angle of 0 ° and the soft package product with a twist angle of + 14 ° produced in Example 1 were alternately laminated to form a total of 10 sheets, with a total width of 25 mm and a thickness of 40 μm. An axially stretched polypropylene film was wound around the central part of the long side of the soft package, heat sealed and bound to obtain a soft package multilayer bundle.

実施例3
高分子量ポリイソブチレン(粘度平均分子量:99万)28.5重量部、低分子量ポリイソブチレン(粘度平均分子量:6万)43重量部、ポリブテン(粘度平均分子量:1260)8.5重量部、脂環族系石油樹脂(軟化点:100℃)20重量部をヘキサンに溶解して、ポリイソブチレン系粘着剤溶液を調製し、この溶液に粘着剤層中のツロブテロール含有率が10%となるようにツロブテロールを添加、混合して十分に攪拌した後、75μm厚のポリエステル製ライナー上に乾燥後の厚みが20μmとなるように塗布乾燥し、粘着剤層を形成した。次にポリエステルフィルム(6μm)/ポリエステル不織布(20g/m)の積層支持体のポリエステルフィルム側に粘着剤層を貼り合わせて貼付剤を作製した。この貼付剤を16mm×16mmサイズに打ち抜いて、貼付剤のシート状物を作製した。
次に「Tダイ・テンター法二軸延伸ポリエステルフィルム(12μm厚)/印刷層/接着剤層/ポリアクリロニトリルフィルム(30μm厚)」の包装用フィルムでポリアクリロニトリルフィルム側を内側にして、貼付剤のシート状物(16mm×16mm)を挟み込んでヒートシールし、四方ヒートシール包装してなる断面方形状の軟包装品(47mm×47mmサイズ、シール幅:5mm)を作製した。この際、Tダイ・テンター法二軸延伸ポリエステルフィルム原反(4.5m幅)の幅方向一方側の端寄り部分(幅方向一方側の端から1.5m離れた付近)の二軸延伸ポリエステルフィルムを基材フィルムとして用いて作製された包装用フィルムを表材と裏材として向かい合わせてヒートシールした。このとき表材と裏材の包装用フィルムの幅方向、長手方向は一致させた。この結果、Tダイ・テンター法二軸延伸ポリエステルフィルムのボーイング現象によりねじれ角度+5°の軟包装品を得た。
こうして得られたねじれ角度+5°の軟包装品と、このねじれ角度+5°の軟包装品を厚み方向に関する中心軸線まわりに90°向きを変えることでねじれ角度−5°とした軟包装品とを交互に5枚ずつ積層し、合計10枚とし、25mm幅、40μm厚の二軸延伸ポリプロピレンフィルムで軟包装品の長辺中央部の周りを巻いてヒートシールして結束し、軟包装品積層束を得た。
Example 3
28.5 parts by weight of high molecular weight polyisobutylene (viscosity average molecular weight: 990,000), 43 parts by weight of low molecular weight polyisobutylene (viscosity average molecular weight: 60,000), 8.5 parts by weight of polybutene (viscosity average molecular weight: 1260), alicyclic A polyisobutylene-based pressure-sensitive adhesive solution is prepared by dissolving 20 parts by weight of a group petroleum resin (softening point: 100 ° C.) in hexane, and tulobuterol is added to this solution so that the content of tulobuterol in the pressure-sensitive adhesive layer is 10%. Were added, mixed and sufficiently stirred, and then applied and dried on a 75 μm thick polyester liner so that the thickness after drying was 20 μm to form an adhesive layer. Next, an adhesive layer was bonded to the polyester film side of the laminated support of polyester film (6 μm) / polyester nonwoven fabric (20 g / m 2 ) to prepare a patch. This patch was punched into a size of 16 mm × 16 mm to prepare a sheet of patch.
Next, with the packaging film of “T-die / tenter biaxially stretched polyester film (12 μm thick) / printing layer / adhesive layer / polyacrylonitrile film (30 μm thick)”, A sheet-like product (16 mm × 16 mm) was sandwiched and heat-sealed, and a soft packaged product (47 mm × 47 mm size, seal width: 5 mm) having a square cross-section formed by four-side heat-sealing packaging was produced. At this time, the biaxially stretched polyester of the end portion on the one side in the width direction of the T-die / tenter biaxially stretched polyester film (4.5 m width) (near 1.5 m away from the end on the one side in the width direction) The packaging film produced using the film as a base film was heat-sealed face-to-face as a front material and a backing material. At this time, the width direction and the longitudinal direction of the front and back packaging films were matched. As a result, a flexible package product having a twist angle of + 5 ° was obtained due to the bowing phenomenon of the T-die tenter method biaxially stretched polyester film.
The thus obtained soft package product with a twist angle of + 5 ° and the soft package product with a twist angle of −5 ° by changing the direction of the soft package product with the twist angle of + 5 ° 90 ° around the central axis in the thickness direction. Laminate 5 sheets alternately to make a total of 10 sheets, roll around the center of the long side of the flexible package with a 25mm wide, 40μm thick biaxially stretched polypropylene film, heat seal and bind, Got.

実施例4
実施例1と同様にして作製した貼付剤を5cm×5cmサイズに打ち抜き、貼付剤のシート状物を作製した。
次に「二軸延伸ポリエステルフィルム(12μm厚)/ポリエチレンフィルム(15μm厚)/アルミニウム(7μm厚)/接着剤層/ポリアクリロニトリルフィルム(20μm厚)」の包装用フィルムでポリアクリロニトリルフィルム側を内側にして、上記作製した貼付剤のシート状物(5cm×5cmサイズ)を挟み込んでヒートシールし、四方ヒートシール包装してなる断面方形状の軟包装品(7cm×7cmサイズ、シール幅5mm)を作製した。この際、金型(上側金型、下側金型)には、図8に示す、ヒートシール面を含む衝合側面が各辺が7cmの正方形で、ヒートシール面における一方の一組の対向するコーナー部の高さが他方の一組の対向するコーナー部の高さよりも6mm(すなわち、70sin5°(mm))だけ高い位置になるように加工形成した金型を用いることで、ねじれ角度+10°の軟包装品を得た。
こうして得られたねじれ角度+10°の軟包装品と、このねじれ角度+10°の軟包装品を厚み方向に関する中心軸線まわりに90°向きを変えることでねじれ角度−10°とした軟包装品とを交互に5枚ずつ積層し、合計10枚とし、25mm幅、40μm厚の二軸延伸ポリプロピレンフィルムで軟包装品の長辺中央部の周りを巻いてヒートシールして結束し、軟包装品積層束を得た。
Example 4
The patch prepared in the same manner as in Example 1 was punched into a size of 5 cm × 5 cm to prepare a sheet of the patch.
Next, with the packaging film of “biaxially stretched polyester film (12 μm thick) / polyethylene film (15 μm thick) / aluminum (7 μm thick) / adhesive layer / polyacrylonitrile film (20 μm thick)” Then, the prepared patch sheet (5 cm × 5 cm size) is sandwiched and heat-sealed, and a four-side heat-sealed soft package product (7 cm × 7 cm size, seal width 5 mm) is produced. did. At this time, the molds (upper mold and lower mold) are shown in FIG. 8 in which the abutting side including the heat seal surface is a square having a side of 7 cm, and one set of opposing surfaces on the heat seal surface. By using a mold that is processed and formed so that the height of the corner portion to be moved is 6 mm higher than the height of the other pair of opposing corner portions (that is, 70 sin 5 ° (mm)), the twist angle +10 A soft packaged product was obtained.
A soft package product with a twist angle of + 10 ° thus obtained and a soft package product with a twist angle of −10 ° by changing the direction of the soft package product with a twist angle of + 10 ° 90 ° around the central axis in the thickness direction. Laminate 5 sheets alternately to make a total of 10 sheets, roll around the center of the long side of the flexible package with a 25mm wide, 40μm thick biaxially stretched polypropylene film, heat seal and bind, Got.

実施例5
窒素雰囲気下でアクリル酸5重量部、アクリル酸2−エチルヘキシルエステル95重量部を共重合させて得られたアクリル系共重合体100重量部に、トリオレイン酸ソルビタン50重量部、架橋剤としての三官能性イソシアネート(日本ポリウレタン社製、コロネートHL)0.15重量部を酢酸エチル中で配合し、これを75μm厚のポリエステル製のセパレーター上に乾燥後の厚みが60μmとなるように塗布、乾燥して粘着剤層を形成した。次にポリエステルフィルム(2μm)/ポリエステル不織布(12g/m)の積層支持体のポリエステル不織布側に粘着剤層を貼り合わせて貼付剤を作製した。これを9cm×9cmの大きさに裁断し、貼付剤のシート状物を作製した。
次に「二軸延伸ポリプロピレンフィルム(60μm厚)/接着剤層/無延伸ポリプロピレンフィルム(50μm厚)」の包装用フィルムで無延伸ポリプロピレンフィルム側を内側にして、上記作製した貼付剤のシート状物(9cm×9cmサイズ)を挟み込んでヒートシールし、四方ヒートシール包装してなる断面方形状の軟包装品(12cm×12cmサイズ、シール幅:5mm)を作製した。この際、金型(上側金型、下側金型)には、図8に示す、ヒートシール面を含む衝合側面が各辺が12cmの正方形で、ヒートシール面における一方の一組の対向するコーナー部の高さが他方の一組の対向するコーナー部の高さよりも10mm(すなわち、120sin5°(mm))だけ高い位置になるように加工形成した金型を用いることで、ねじれ角度+10°の軟包装品を得た。
こうして得られたねじれ角度+10°の軟包装品と、このねじれ角度+10°の軟包装品を厚み方向に関する中心軸線まわりに90°向きを変えることでねじれ角度−10°とした軟包装品とを交互に5枚ずつ積層し、合計10枚とし、25mm幅、40μm厚の二軸延伸ポリプロピレンフィルムで軟包装品の長辺中央部の周りを巻いてヒートシールして結束し、軟包装品積層束を得た。
Example 5
In 100 parts by weight of an acrylic copolymer obtained by copolymerizing 5 parts by weight of acrylic acid and 95 parts by weight of 2-ethylhexyl acrylate in a nitrogen atmosphere, 50 parts by weight of sorbitan trioleate, and three as a crosslinking agent. 0.15 parts by weight of functional isocyanate (manufactured by Nippon Polyurethane Co., Ltd., Coronate HL) is blended in ethyl acetate, and this is applied to a 75 μm thick polyester separator so that the thickness after drying is 60 μm and dried. Thus, an adhesive layer was formed. Next, an adhesive layer was bonded to the polyester nonwoven fabric side of the laminated support of polyester film (2 μm) / polyester nonwoven fabric (12 g / m 2 ) to prepare a patch. This was cut into a size of 9 cm × 9 cm to prepare a patch sheet.
Next, with the packaging film of “biaxially oriented polypropylene film (60 μm thickness) / adhesive layer / unstretched polypropylene film (50 μm thickness)”, the non-stretched polypropylene film side faces inward, and the sheet of the patch prepared above (9 cm × 9 cm size) was sandwiched and heat-sealed, and a four-sided heat-sealed packaged soft package product (12 cm × 12 cm size, seal width: 5 mm) was produced. At this time, the molds (upper mold and lower mold) are shown in FIG. 8 in which the abutting side surfaces including the heat seal surface are squares each having a side of 12 cm, and one set of opposing surfaces on the heat seal surface. By using a mold that is processed and formed so that the height of the corner portion to be raised is 10 mm higher than the height of the other pair of opposing corner portions (that is, 120 sin 5 ° (mm)), the twist angle +10 A soft packaged product was obtained.
A soft package product with a twist angle of + 10 ° thus obtained and a soft package product with a twist angle of −10 ° by changing the direction of the soft package product with a twist angle of + 10 ° 90 ° around the central axis in the thickness direction. Laminate 5 sheets alternately to make a total of 10 sheets, roll around the center of the long side of the flexible package with a 25mm wide, 40μm thick biaxially stretched polypropylene film, heat seal and bind, Got.

実施例6
包装用フィルムとして、二軸延伸ポリプロピレンフィルムの単層フィルム(40μm厚)を用いた以外は、実施例4と同様にして軟包装品積層束を作製した。
Example 6
A flexible package laminate was produced in the same manner as in Example 4 except that a bilayer oriented polypropylene film monolayer film (40 μm thickness) was used as the packaging film.

比較例1
実施例2で作製したねじれ角度0°の軟包装品を10枚積層し、25mm幅、40μm厚の二軸延伸ポリプロピレンフィルムで軟包装品の長辺中央部の周りを巻いてヒートシールして結束し、軟包装品積層束を得た。
Comparative Example 1
Ten soft-packaging products with a twist angle of 0 ° produced in Example 2 were laminated, and the biaxially stretched polypropylene film having a width of 25 mm and a thickness of 40 μm was wrapped around the central part of the long side of the soft-packaging product and heat-sealed to bind. Thus, a flexible packaged laminated bundle was obtained.

比較例2
実施例1で作製したねじれ角度+14°の軟包装品を10枚積層し、25mm幅、40μm厚の二軸延伸ポリプロピレンフィルムで軟包装品の長辺中央部の周りを巻いてヒートシールして結束し、軟包装品積層束を得た。
Comparative Example 2
Ten soft packaging products having a twist angle of + 14 ° produced in Example 1 were laminated, and the biaxially stretched polypropylene film having a width of 25 mm and a thickness of 40 μm was wrapped around the central portion of the long side of the flexible packaging product and heat-sealed to bind. Thus, a flexible packaged laminated bundle was obtained.

比較例3
二軸延伸ポリエステルフィルム原反(4.5m幅)の幅方向中央部(幅方向一方の端から2.0m離れた付近)の二軸延伸ポリエステルフィルムを用いて作製された包装用フィルムを用いた以外は実施例1と同様にして、ねじれ角度+2°の軟包装品を作製した。こうして得られたねじれ角度+2°の軟包装品と、実施例1で作製したねじれ角度+14°の軟包装品とを交互に5枚ずつ積層し、合計10枚とし、25mm幅、40μm厚の二軸延伸ポリプロピレンフィルムで軟包装品の長辺中央部の周りを巻いてヒートシールして結束し、軟包装品積層束を得た。
Comparative Example 3
The packaging film produced using the biaxially stretched polyester film of the biaxially stretched polyester film (4.5m width) in the center in the width direction (near 2.0m away from one end in the width direction) was used. Except for the above, a soft package with a twist angle of + 2 ° was produced in the same manner as in Example 1. The thus obtained flexible packaging product with a twist angle of + 2 ° and the flexible packaging product with a twist angle of + 14 ° produced in Example 1 were alternately laminated in a stack of 10 pieces, for a total of 10 pieces, 25 mm width and 40 μm thickness. An axially stretched polypropylene film was wound around the central part of the long side of the soft package, heat sealed and bound to obtain a soft package multilayer bundle.

比較例4
二軸延伸ポリエステルフィルム原反(4.5m幅)の幅方向一方側の端寄り部分(幅方向一方の端から0.3m離れた付近)の二軸延伸ポリエステルフィルムを用いて作製された包装用フィルムを用いた以外は実施例1と同様にして、ねじれ角度25°の軟包装品を作製した。また、二軸延伸ポリエステルフィルム原反(4.5m幅)の幅方向他方側の端寄り部分(幅方向他方の端から0.3m離れた付近)の二軸延伸ポリエステルフィルムを用いて作製された包装用フィルムを用いた以外は実施例1と同様にして、ねじれ角度−25°の軟包装品を作製した。こうして得られたねじれ角度+25°の軟包装品と、ねじれ角度−25°の軟包装品とを交互に5枚ずつ積層し、合計10枚とし、25mm幅、40μm厚の二軸延伸ポリプロピレンフィルムで軟包装品の長辺中央部の周りを巻いてヒートシールして結束し、軟包装品積層束を得た。
Comparative Example 4
For packaging made by using a biaxially stretched polyester film of a biaxially stretched polyester film (4.5m width) near the end on one side in the width direction (near 0.3m away from one end in the width direction) A flexible package with a twist angle of 25 ° was produced in the same manner as in Example 1 except that the film was used. In addition, the biaxially stretched polyester film (4.5m width) was produced using the biaxially stretched polyester film of the end portion on the other side in the width direction (near 0.3m away from the other end in the width direction). A flexible package with a twist angle of −25 ° was produced in the same manner as in Example 1 except that the packaging film was used. The thus obtained flexible packaging product with a twist angle of + 25 ° and the flexible packaging product with a twist angle of −25 ° were alternately laminated in a total of 10 sheets to make a total of 10 biaxially oriented polypropylene films with a width of 25 mm and a thickness of 40 μm. The flexible packaged product was wound around the central part of the long side, heat-sealed and bound to obtain a flexible packaged product bundle.

上記の各実施例および各比較例にて得た軟包装品積層束について、図6を参照して上記説明したように包装用フィルムの繰り返し曲げ応力試験を行い、それぞれ、包装用フィルムの1回目曲げ応力最大値、ならびに2回目曲げ応力最大値の1回目曲げ応力最大値に対する比率(%)を測定した。
また、軟包装品1枚の外観、束ね易さ、帯を外した後の枚数の数え易さ、所望枚数の取り出しやすさを官能評価した。
結果を、表1に示す。
For the flexible packaged product bundles obtained in each of the above examples and comparative examples, a repeated bending stress test of the packaging film was performed as described above with reference to FIG. The bending stress maximum value and the ratio (%) of the second bending stress maximum value to the first bending stress maximum value were measured.
Further, sensory evaluation was performed on the appearance, ease of bundling, ease of counting the number of sheets after removing the band, and ease of taking out the desired number of sheets.
The results are shown in Table 1.

Figure 2005112437
Figure 2005112437

本発明の好ましい一例の軟包装品積層束1を簡略化して示す図である。It is a figure which simplifies and shows the flexible packaged goods laminated bundle 1 of a preferable example of this invention. ねじれ角度の絶対値が1°〜20°の軟包装品とねじれ角度が0°の軟包装品とを交互に積層してなる態様((a)の態様)の軟包装品積層束を簡略化して示す図である。Simplified stacking bundle of flexible packaging products (aspect (a)) in which soft packaging products having an absolute value of twist angle of 1 ° to 20 ° and soft packaging products having a twist angle of 0 ° are alternately laminated. FIG. ねじれ角度が+1°〜+20°の軟包装品とねじれ角度が−20°〜−1°の軟包装品を交互に積層してなる態様((b)の態様)の軟包装品積層束を簡略化して示す図である。Simplified stacking bundle of soft packaging products in a mode ((b) mode) in which soft packaging products having a twist angle of + 1 ° to + 20 ° and soft packaging products having a twist angle of −20 ° to −1 ° are alternately laminated. FIG. 本発明における軟包装品のねじれ角度を測定する方法を模式的に示す図である。It is a figure which shows typically the method to measure the twist angle of the flexible package goods in this invention. 本発明に使用される軟包装品について模式的に示す図である。It is a figure which shows typically about the soft package used for this invention. 本発明における包装用フィルムの繰り返し曲げ応力試験を模式的に示す図である。It is a figure which shows typically the repeated bending stress test of the film for packaging in this invention. 本発明の軟包装品積層束1,1’を箱体6に収容したところを簡略化して示す図である。It is a figure which simplifies and shows the place which accommodated the soft package laminated bundle 1, 1 'of this invention in the box body 6. FIG. 本発明において軟包装品にねじれを付与するために使用するヒートシール金型の一例の概略斜視図であり、図中の斜線部分がヒートシール面である。It is a schematic perspective view of an example of the heat seal metal mold | die used in order to provide a twist to a flexible package in this invention, and the shaded part in a figure is a heat seal surface.

符号の説明Explanation of symbols

1,1’ 軟包装品積層束
2,2’ 軟包装品
3 帯状物
1, 1 'Laminated bundle of soft packaging products 2, 2' Soft packaging product 3 Strips

Claims (4)

シート状物を包装用フィルムにてシールしてなる軟包装品を複数枚積層し、帯状物で束ねた軟包装品積層束であって、以下の(a)または(b)の積層構造を有する軟包装品積層束。
(a)ねじれ角度の絶対値が1°〜20°の軟包装品とねじれ角度が0°の軟包装品とを交互に積層した積層構造、
(b)ねじれ角度の絶対値が20°以下のねじれの向きが正方向の軟包装品とねじれ角度の絶対値が20°以下のねじれの向きが負方向の軟包装品とを交互に積層した積層構造であって、各隣接する軟包装品間のねじれ角度の差が1°以上である積層構造。
A soft-packaging product laminate bundle in which a plurality of soft-packaging products obtained by sealing a sheet-like material with a packaging film and bundled with a belt-like material, and has the following laminated structure (a) or (b) Flexible packaged laminated bundle.
(A) a laminated structure in which soft packaging products having an absolute value of twist angle of 1 ° to 20 ° and soft packaging products having a twist angle of 0 ° are alternately laminated;
(B) A soft package with a positive twist direction with an absolute value of 20 degrees or less and a soft package with a negative twist direction with an absolute value of 20 degrees or less alternately stacked. A laminated structure, wherein the difference in twist angle between each adjacent flexible package is 1 ° or more.
各軟包装品の包装用フィルムは、1回目曲げ応力最大値が0.01N/15mm幅/2枚〜2.0N/15mm幅/2枚であって、かつ2回目曲げ応力最大値が1回目曲げ応力最大値の80%以上である請求項1に記載の軟包装品積層束。   The packaging film of each soft packaged product has a first bending stress maximum value of 0.01 N / 15 mm width / 2 sheets to 2.0 N / 15 mm width / 2 sheets and a second bending stress maximum value of the first time. The laminated bundle of flexible packages according to claim 1, which is 80% or more of the maximum bending stress. 軟包装品の外周形状(輪郭)が方形状である、請求項1または2に記載の軟包装品積層束。   The soft-packaging product laminated bundle according to claim 1 or 2, wherein the outer peripheral shape (contour) of the soft-packaging product is a square shape. シート状物がテープ材である、請求項1〜3のいずれかに記載の軟包装品積層束。   The flexible packaged laminated bundle according to any one of claims 1 to 3, wherein the sheet-like material is a tape material.
JP2003351365A 2003-10-09 2003-10-09 Flexible packaged stack Expired - Fee Related JP4171390B2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
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JP2016175664A (en) * 2015-03-19 2016-10-06 朋和産業株式会社 Package

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016175664A (en) * 2015-03-19 2016-10-06 朋和産業株式会社 Package

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