JP2005105305A - Wire for interdental brush, manufacturing method therefor and interdental brush - Google Patents

Wire for interdental brush, manufacturing method therefor and interdental brush Download PDF

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JP2005105305A
JP2005105305A JP2003336930A JP2003336930A JP2005105305A JP 2005105305 A JP2005105305 A JP 2005105305A JP 2003336930 A JP2003336930 A JP 2003336930A JP 2003336930 A JP2003336930 A JP 2003336930A JP 2005105305 A JP2005105305 A JP 2005105305A
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wire
interdental brush
interdental
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brush
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Shin Sumimoto
伸 住本
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an inexpensive wire for an interdental brush having high breaking strength and high elongation properties; a manufacturing method therefor; and an inexpensive interdental brush superior in bending strength and rigidity. <P>SOLUTION: A wire rod for the interdental brush has a chemical composition comprising, by wt.%, 0.08% or less C, 3.0-5.0% Si, 3.0% or less Mn, 4.0-12.0% Ni, 12.0-24.0% Cr, 0.9-2.0% Mo, 0.5-2.0% Cu and the balance iron with an unavoidable impurities. The method for manufacturing the wire for the interdental brush comprises final-drawing the above wire rod with a reduction of 70% or higher, and final stress-relief heat-treating it at 800-1,050°C. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、歯の隙間(以下、歯間という)に挿通して、通常の歯ブラシでは歯垢清掃が困難な歯間部を清掃するのに適した歯間ブラシ用ワイヤ及びその製造方法並びに歯間ブラシに関する。   The present invention relates to an interdental brush wire suitable for cleaning an interdental portion that is difficult to clean with an ordinary toothbrush through a tooth gap (hereinafter referred to as interdental), a manufacturing method thereof, and a tooth. Between brushes.

歯間ブラシは、通常の歯ブラシでは除去できない歯間に生成する歯垢や食べかすを落とすための道具である。その一般的な構造は、図1に示すごとくである。すなわち、歯間ブラシ1は、1本のワイヤ2を先端(図では左端)で折り返し、ワイヤ2の間に多数の毛ブラシ3を挟み込んだ状態で、ワイヤ2を捻って多数の毛ブラシ3を巻き込むように捻り合わせ、毛ブラシ3をワイヤ2の隙間にしっかりと挟み込んでブラシ部を形成してある。そして、一般的に、ワイヤ2にはステンレス鋼線が用いられ、毛ブラシ3の材質としてはナイロン等の樹脂が用いられている。以上のような構造の歯間ブラシを使用する場合、歯間ブラシのブラシ部をワイヤごと歯と歯の間に挿入して前後に動かすことにより、毛ブラシを歯間や歯茎にこすりつけて歯垢や食べかすを除去するものである。   An interdental brush is a tool for removing plaque and food residue generated between teeth that cannot be removed with a normal toothbrush. Its general structure is as shown in FIG. That is, the interdental brush 1 is configured such that one wire 2 is folded at the tip (left end in the drawing) and a large number of bristle brushes 3 are twisted by twisting the wire 2 while the numerous bristle brushes 3 are sandwiched between the wires 2. The bristle brush 3 is firmly sandwiched in the gap between the wires 2 to form a brush part. In general, a stainless steel wire is used for the wire 2 and a resin such as nylon is used as the material of the bristle brush 3. When using an interdental brush with the above structure, insert the brush part of the interdental brush between the teeth and move it back and forth, rubbing the bristle brush between the teeth and gums, and plaque It removes food and food.

ところで、歯間ブラシは、前述のとおり多数の毛ブラシを巻き込むように捻り合わせて製造されるが、捻り加工にはワイヤの伸びが伴うため、ワイヤには高い伸び特性が要求される。具体的には破断伸びで25%以上が必要である。
また、歯間ブラシは、狭い歯間にブラシ部を入れて、歯の両側部分に摺動して使用される。しかも1回の使用で廃棄せずに何回も使用されのが一般的である。このため、曲げ歪みや座屈歪みがワイヤに繰り返し加えられる。従って、ワイヤには、高い曲げ強度および剛性を具備することが要求される。
曲げ強度および剛性はワイヤの破断強度に比例することから、歯間ブラシ用ワイヤは高い破断強度が必要である。具体的には1000MPa以上必要である。
By the way, the interdental brush is manufactured by twisting so that a large number of bristle brushes are wound as described above. However, since the wire is stretched in the twisting process, the wire is required to have high stretch characteristics. Specifically, the elongation at break is required to be 25% or more.
In addition, the interdental brush is used by sliding a brush part between both sides of a tooth with a brush part interposed between narrow teeth. Moreover, it is generally used many times without being discarded in one use. For this reason, bending strain and buckling strain are repeatedly applied to the wire. Accordingly, the wire is required to have high bending strength and rigidity.
Since the bending strength and rigidity are proportional to the breaking strength of the wire, the interdental brush wire requires high breaking strength. Specifically, 1000 MPa or more is necessary.

上記歯間ブラシ用ワイヤとしては、ステンレス鋼線、中でもJIS規格のSUS304のステンレス鋼線が多用されている。しかし、この歯間ブラシ用として使用されているステンレス鋼線は破断強度がせいぜい800MPa程度で、曲げ強度、剛性が充分ではない。前述のとおり、歯間ブラシ用ワイヤには高い破断強度と高い伸び特性が要求されるが、金属ワイヤにおいて破断強度と伸び特性とは反比例する。上記従来の歯間ブラシ用ワイヤの破断強度が800MPa程度であるのは、捻り加工に耐えうる高い伸び特性を得るためである。
この問題を解決する手段として、特開平8−308637号公報には、Co(コバルト)を30〜50%添加したCo合金線を用いた歯間ブラシが、また特開平7−227315号公報にはCoにCr、Ni、Mo、C、Mn、Si、W、Fe、Tiなどの元素を必要量添加したCo合金を用いた歯間ブラシが提案されている。
特開平8−308637号公報 特開平7−227315号公報
As the interdental brush wire, stainless steel wire, in particular, SUS304 stainless steel wire of JIS standard is often used. However, the stainless steel wire used for the interdental brush has a breaking strength of at most about 800 MPa, and the bending strength and rigidity are not sufficient. As described above, the interdental brush wire is required to have a high breaking strength and a high elongation characteristic, but the breaking strength and the elongation characteristic are inversely proportional to each other in the metal wire. The reason why the breaking strength of the conventional interdental brush wire is about 800 MPa is to obtain high elongation characteristics that can withstand twisting.
As means for solving this problem, Japanese Patent Laid-Open No. 8-308637 discloses an interdental brush using a Co alloy wire to which Co (cobalt) is added in an amount of 30 to 50%, and Japanese Patent Laid-Open No. 7-227315 discloses. An interdental brush using a Co alloy in which a necessary amount of elements such as Cr, Ni, Mo, C, Mn, Si, W, Fe, and Ti is added to Co has been proposed.
JP-A-8-308637 JP 7-227315 A

上記Co合金を使用した歯間ブラシ用ワイヤは、高破断強度を有しながら、かつ高い伸び特性を有する。しかし、Coは価格が非常に高い元素で、歯間ブラシの価格が高くなるという欠点を有していた。
本発明は上記事情に鑑みてなされたものであり、安価であって、高破断強度で、かつ高い伸び特性を有する歯間ブラシ用ワイヤを提供すること、およびその製造方法並びに曲げ強度、剛性に優れ、かつ安価である歯間ブラシを提供することを課題とする。
The interdental brush wire using the Co alloy has a high elongation property while having a high breaking strength. However, Co is a very expensive element and has the disadvantage that the price of the interdental brush is high.
The present invention has been made in view of the above circumstances, and provides an interdental brush wire that is inexpensive, has high breaking strength, and has high elongation characteristics, as well as its manufacturing method, bending strength, and rigidity. It is an object to provide an interdental brush that is excellent and inexpensive.

上記課題を解決するために、本発明の歯間ブラシ用ワイヤは、重量%で、C:0.08%以下、Si:3.0〜5.0%、Mn:3.0%以下、Ni:4.0〜12.0%、Cr:12.0〜24.0%、Mo:0.9〜2.0%、Cu:0.5〜2.0%、残部が鉄及び不可避的不純物からなることを特徴とする。   In order to solve the above-mentioned problems, the interdental brush wire of the present invention is, by weight, C: 0.08% or less, Si: 3.0 to 5.0%, Mn: 3.0% or less, Ni : 4.0 to 12.0%, Cr: 12.0 to 24.0%, Mo: 0.9 to 2.0%, Cu: 0.5 to 2.0%, the balance being iron and inevitable impurities It is characterized by comprising.

また、本発明の歯間ブラシ用ワイヤの製造方法は、重量%で、C:0.08%以下、Si:3.0〜5.0%、Mn:3.0%以下、Ni:4.0〜12.0%、Cr:12.0〜24.0%、Mo:0.9〜2.0%、Cu:0.5〜2.0%、残部が鉄及び不可避的不純物からなることを特徴とする歯間ブラシ用ワイヤの製造方法であって、加工度を70%以上とする最終伸線加工と、800〜1050℃での最終歪み取り熱処理工程とを含むことを特徴とする。   Moreover, the manufacturing method of the wire for interdental brushes of this invention is weight%, C: 0.08% or less, Si: 3.0-5.0%, Mn: 3.0% or less, Ni: 4. 0 to 12.0%, Cr: 12.0 to 24.0%, Mo: 0.9 to 2.0%, Cu: 0.5 to 2.0%, the balance being iron and inevitable impurities A method for producing an interdental brush wire characterized by comprising: a final wire drawing process with a working degree of 70% or more; and a final strain removing heat treatment step at 800 to 1050 ° C.

次に、本発明に係る歯間ブラシ用ワイヤの化学組成を限定した理由について説明する。
C:Cは不要な元素であるばかりでなく、含有量が高くなって0.08%を越えると靭性が低下する。よってCの含有量は0.08%以下とする。
Si:本発明で最も重要な元素であり、このSiの動きによって素材の引張強度を増加させ、歯間ブラシ用ワイヤとしての破断強度(曲げ強度、剛性)を向上させるものである。この充分なる破断強度を得るためには、3.0%以上の含有量が必要であるが、5.0%を越えると靭性が低下し、冷間加工性が低下する。よって、Siの含有量の範囲は3.0〜5.0%とする。
Mn:脱酸脱硫剤として添加され、靭性を向上させる作用がある。しかし、3.0%を越えると冷間加工性を低下させる。よって、Mn含有量は、3.0%以下とする。
Ni:耐食性を向上する目的で添加されるが、過剰になると伸線加工性が低下する。よって、Ni含有量の範囲は4.0〜12.0%とする。
Cr:基地に固溶して耐食性を向上させる。このため少なくとも12.0%以上添加する必要があるが、24.0%を越えると冷間加工性が低下する。よって、Cr含有量は12.0〜24.0%とする。
Mo:基地を強化し、靭性を向上させるとともに耐食性を向上させる。このため、0.9%以上必要であるが、2.0%を越えると、逆に靭性が低下する。また、Moは高価であるためコスト高となる。よって、Mo含有量は0.9〜2.0%とする。
Cu:耐食性を向上させる元素である。このため、0.5%以上必要であるが、2.0%を越えると破断強度が低下し、ワイヤが曲げ強度、剛性および疲労強度が低下する。よって、Cu含有量は0.5〜2.0%とする。
Next, the reason why the chemical composition of the interdental brush wire according to the present invention is limited will be described.
C: C is not only an unnecessary element, but if its content increases and exceeds 0.08%, toughness decreases. Therefore, the C content is 0.08% or less.
Si: It is the most important element in the present invention, and the movement of Si increases the tensile strength of the material and improves the breaking strength (bending strength, rigidity) as an interdental brush wire. In order to obtain this sufficient breaking strength, a content of 3.0% or more is necessary, but if it exceeds 5.0%, the toughness is lowered and the cold workability is lowered. Therefore, the range of Si content is set to 3.0 to 5.0%.
Mn: added as a deoxidation desulfurization agent and has an effect of improving toughness. However, if it exceeds 3.0%, the cold workability is lowered. Therefore, the Mn content is 3.0% or less.
Ni: It is added for the purpose of improving the corrosion resistance, but if it is excessive, the wire drawing workability is lowered. Therefore, the range of Ni content is 4.0 to 12.0%.
Cr: Solid solution in the base improves corrosion resistance. For this reason, it is necessary to add at least 12.0% or more, but if it exceeds 24.0%, the cold workability is lowered. Therefore, the Cr content is 12.0 to 24.0%.
Mo: Strengthens the base, improves toughness and improves corrosion resistance. For this reason, 0.9% or more is necessary, but if it exceeds 2.0%, the toughness is conversely reduced. Moreover, since Mo is expensive, the cost increases. Therefore, the Mo content is set to 0.9 to 2.0%.
Cu: An element that improves corrosion resistance. For this reason, 0.5% or more is necessary, but if it exceeds 2.0%, the breaking strength decreases, and the bending strength, rigidity, and fatigue strength of the wire decrease. Therefore, the Cu content is set to 0.5 to 2.0%.

本発明の歯間ブラシ用ワイヤは、Siの含有量を従来のステンレス鋼(Si含有量0.4%程度)に比べ多量に添加することを大きな特徴としている。しかし、Siは鋼材の強度を上げるが、これを多量に含有させると結晶粒が粗大となり靭性が低下する。本発明の歯間ブラシ用ワイヤは、高Si含有量として破断強度を上げ、これによる靭性の低下をMn、Ni、Crの含有量を加減することで結晶粒を微細化して防止するものである。   The interdental brush wire of the present invention is characterized by adding a large amount of Si compared to conventional stainless steel (Si content of about 0.4%). However, Si increases the strength of the steel material, but if it is contained in a large amount, the crystal grains become coarse and the toughness decreases. The interdental brush wire of the present invention increases the breaking strength with a high Si content, and prevents the decrease in toughness by refining the crystal grains by adjusting the contents of Mn, Ni, and Cr. .

本発明の歯間ブラシ用ワイヤは、Co等の高価な元素を添加していないから安価であって、かつ高破断強度で高い伸び特性を有する。また本発明の製造方法によれば、高破断強度で高い伸び特性を有する歯間ブラシ用ワイヤを容易に製造することができる。よって本発明の歯間ブラシ用ワイヤを用いた歯間ブラシは曲げ強度、剛性に優れ、かつ安価である。   The interdental brush wire of the present invention is inexpensive because no expensive element such as Co is added, and has high elongation characteristics with high breaking strength. Moreover, according to the manufacturing method of the present invention, an interdental brush wire having high breaking strength and high elongation characteristics can be easily manufactured. Therefore, the interdental brush using the interdental brush wire of the present invention is excellent in bending strength and rigidity and inexpensive.

本発明の歯間ブラシ用ワイヤは、以下の製造工程で製造される。
すなわち、上記成分組成で線径5.5mm程度の線材を製造し、この線材に溶体化処理、伸線加工を繰り返して、線径1.0mm程度の中間線材を製造し、この中間線材に最終の溶体化処理を施した後、加工度70%以上で所望の線径(0.2〜0.30mm程度)まで最終伸線加工を行う。このワイヤを800〜1050℃で熱処理(歪み取り焼鈍)することによって、本発明に係る破断強度が1000〜1300MPaで破断伸びが25〜40%の歯間ブラシ用ワイヤを製造することができる。
The interdental brush wire of the present invention is manufactured by the following manufacturing process.
That is, a wire rod having a wire diameter of about 5.5 mm is manufactured with the above component composition, and solution treatment and wire drawing are repeated on the wire rod to produce an intermediate wire rod having a wire diameter of about 1.0 mm. After the solution treatment is performed, the final wire drawing is performed to a desired wire diameter (about 0.2 to 0.30 mm) at a processing degree of 70% or more. By subjecting this wire to heat treatment (strain relief annealing) at 800 to 1050 ° C., an interdental brush wire having a breaking strength of 1000 to 1300 MPa and a breaking elongation of 25 to 40% according to the present invention can be produced.

上記製造方法において、加工度を70%以上とし、最終熱処理温度を800〜1050℃としたのは、高加工度によって熱処理前の破断強度をさらに高くし、その後の熱処理で必要な高伸び特性(破断伸び)を得ることを狙ったためで、加工度が70%未満、加熱温度が800〜1050℃の範囲外では、歯間ブラシ用ワイヤとして最適な高強度、高伸び特性が得られないからである。   In the above manufacturing method, the degree of work was set to 70% or more and the final heat treatment temperature was set to 800 to 1050 ° C. because the high breakage strength before heat treatment was further increased due to the high degree of work, and high elongation characteristics required for the subsequent heat treatment ( Because it was aimed at obtaining a breaking elongation), when the degree of processing is less than 70% and the heating temperature is outside the range of 800 to 1050 ° C., the optimum high strength and high elongation characteristics as an interdental brush wire cannot be obtained. is there.

歯間ブラシ用ワイヤの断面形状は、丸形状だけでなく、楕円形状やトラック形状等の偏平形状にするのが好ましい。というのは、偏平形状とするとワイヤの根本部の断面における外接円の面積に対するワイヤの実質断面積比率が大きくなって曲げ強度および剛性がより高くなるからである。   The cross-sectional shape of the interdental brush wire is preferably not only a round shape but also a flat shape such as an elliptical shape or a track shape. This is because, when the shape is flat, the ratio of the substantial cross-sectional area of the wire to the area of the circumscribed circle in the cross section of the base portion of the wire is increased, and the bending strength and rigidity are further increased.

表1に示す5.5mmの線材を製造し、この線材に溶体化処理、伸線加工を繰り返して、線径1.0mmの中間線材を製造し、この中間線材に最終の溶体化処理を施した後、0.25mmまで最終伸線加工(加工度94%)を行った。次に850℃で熱処理することによって歯間ブラシ用ワイヤを製造した。また、従来例としてSUS304の線材も同様に加工(ただし、加工条件はSUS304に適した条件とした)した。   A 5.5 mm wire shown in Table 1 is manufactured, and solution treatment and wire drawing are repeated on this wire to produce an intermediate wire having a wire diameter of 1.0 mm, and the final solution treatment is applied to this intermediate wire. Then, the final wire drawing (working degree 94%) was performed to 0.25 mm. Next, the wire for interdental brushes was manufactured by heat-processing at 850 degreeC. Further, as a conventional example, a SUS304 wire was processed in the same manner (however, the processing conditions were suitable for SUS304).

Figure 2005105305
Figure 2005105305

そして得られたワイヤの破断強度と破断伸びおよび製造途中における伸線加工性を比較した。その結果を表2に示す。伸線加工性はダイスの寿命、断線、キズの発生有無等SUS304と比較して総合的に判断し、SUS304とほぼ同等のものを○、劣るものを×とした。伸線加工性が×のものはその後の破断強度および破断伸びの調査は行わなかった。   And the breaking strength of the obtained wire, breaking elongation, and the wire drawing workability in the middle of manufacture were compared. The results are shown in Table 2. The wire drawing workability was comprehensively judged in comparison with SUS304, such as die life, breakage, and the presence or absence of scratches. When the wire drawing workability was x, the subsequent breaking strength and breaking elongation were not investigated.

Figure 2005105305
Figure 2005105305

表2に示すとおり、本発明の歯間ブラシ用ワイヤは高い破断強度と伸び特性を有することがわかる。 As shown in Table 2, it can be seen that the interdental brush wire of the present invention has high breaking strength and elongation characteristics.

次に表1に示す実施例2の材料を用いて最終伸線加工度及び最終歪み取り熱処理温度を変化させて、破断強度と破断伸びを比較した。その結果を表3に示す。   Next, using the materials of Example 2 shown in Table 1, the final wire drawing degree and the final strain removal heat treatment temperature were changed, and the breaking strength and breaking elongation were compared. The results are shown in Table 3.

Figure 2005105305
Figure 2005105305

表3に示すとおり、本発明の特定範囲内で製造した歯間ブラシ用ワイヤは、最適な高強度と高い伸び特性を有することが判明した。   As shown in Table 3, it was found that the interdental brush wire manufactured within the specific range of the present invention has optimum high strength and high elongation characteristics.

さらに、本発明の歯間ブラシ用ワイヤを用いて歯間ブラシを製造し、実際に使用してその性能を確認したところ、従来のステンレス鋼線を用いた歯間ブラシに比べて高い性能を有することが確認できた。   Furthermore, when the interdental brush was manufactured using the interdental brush wire of the present invention and the performance was confirmed by actually using it, it has higher performance than the conventional interdental brush using a stainless steel wire. I was able to confirm.

歯間ブラシに適用できる。   Applicable to interdental brushes.

歯間ブラシの一般的構造を示す概略側面図である。It is a schematic side view which shows the general structure of an interdental brush.

符号の説明Explanation of symbols

1 歯間ブラシ
2 ワイヤ
3 毛ブラシ
1 Interdental brush 2 Wire 3 Bristle brush

Claims (3)

重量%で、C:0.08%以下、Si:3.0〜5.0%、Mn:3.0%以下、Ni:4.0〜12.0%、Cr:12.0〜24.0%、Mo:0.9〜2.0%、Cu:0.5〜2.0%、残部が鉄及び不可避的不純物からなることを特徴とする歯間ブラシ用ワイヤ。 C: 0.08% or less, Si: 3.0-5.0%, Mn: 3.0% or less, Ni: 4.0-12.0%, Cr: 12.0-24. An interdental brush wire comprising 0%, Mo: 0.9 to 2.0%, Cu: 0.5 to 2.0%, and the balance consisting of iron and inevitable impurities. 重量%で、C:0.08%以下、Si:3.0〜5.0%、Mn:3.0%以下、Ni:4.0〜12.0%、Cr:12.0〜24.0%、Mo:0.9〜2.0%、Cu:0.5〜2.0%、残部が鉄及び不可避的不純物からなることを特徴とする歯間ブラシ用ワイヤの製造方法であって、加工度を70%以上とする最終伸線加工と、800〜1050℃での最終歪み取り熱処理工程とを含むことを特徴とする歯間ブラシ用ワイヤの製造方法。 C: 0.08% or less, Si: 3.0-5.0%, Mn: 3.0% or less, Ni: 4.0-12.0%, Cr: 12.0-24. 0%, Mo: 0.9-2.0%, Cu: 0.5-2.0%, the balance consisting of iron and inevitable impurities, a method for producing an interdental brush wire, A method for producing an interdental brush wire, comprising: a final wire drawing process with a degree of processing of 70% or more; and a final distortion removing heat treatment step at 800 to 1050 ° C. 請求項1に記載の歯間ブラシ用ワイヤを用いてなる歯間ブラシ。

An interdental brush using the interdental brush wire according to claim 1.

JP2003336930A 2003-09-29 2003-09-29 Wire for interdental brush, manufacturing method therefor and interdental brush Pending JP2005105305A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113136531A (en) * 2021-04-15 2021-07-20 鞍钢股份有限公司 Powder metallurgy stainless steel and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113136531A (en) * 2021-04-15 2021-07-20 鞍钢股份有限公司 Powder metallurgy stainless steel and preparation method thereof
CN113136531B (en) * 2021-04-15 2022-06-14 鞍钢股份有限公司 Powder metallurgy stainless steel

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