JP2005095896A - Apparatus for producing electrolytic water - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an apparatus for producing electrolytic water having no consumption of a salt solution before electrolysis, and low electrical power consumption for the electrolysis. <P>SOLUTION: The inside of a casing 10 is separated into a central salt solution chamber B, and an anode chamber A and a cathode chamber C on both sides thereof by 2 barriers 11 and 13, and an anode 15 and a cathode 16 formed of a metal lathe, or the like, through which a liquid is freely passed are brought closer to respective corresponding barriers, and provided in the anode chamber and the cathode chamber, respectively. A circulating salt solution tank 20 accommodating the salt solution of a predetermined concentration and the salt solution chamber are communicated by a salt solution introduction pipe 21 and a salt solution delivery pipe 22, and the salt solution is circulated by a circulation pump 23. The anode chamber A is provided with a raw water introduction pipe 25a and an acid water removal pipe 26, and the cathode chamber C is provided with a raw water introduction pipe 25b and an alkaline water removal pipe 27. A voltage from a DC power source 17 is applied to the anode and the cathode, the salt solution in the salt solution chamber B is electrolyzed, and acid water and alkaline water to be generated are removed from removal pipes 26 and 27, respectively. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  The present invention relates to an apparatus for producing electrolyzed water used for food processing such as cleaning and sterilization of fresh food, thawing of frozen fish meat, drawing, and hand washing.

  In this type of electrolyzed water production apparatus, for example, as shown in FIG. 3, plate-like anode 3, cathode 4 and casings 1a and 1b are provided on both sides of a spacer 2a stretched with a diaphragm 2 sandwiched between them. A main body is formed by abutting and fixing, and the saline in the diluted saline tank 5 is fed into the anode chamber and the cathode chamber formed by partitioning the diaphragm 2 in the main body by the pump 6 through the supply pipe 7, The electrolyzed water generated in the anode chamber and the cathode chamber by the decomposition is taken out by the acidic water take-out pipe 8a and the alkaline water take-out pipe 8b and used according to the intended use.

  In the conventional electrolyzed water production apparatus as described above, since the supplied saline solution is taken out as it is without being separated from the electrolyzed and unelectrolyzed ones, most of the salt is wasted. There was a problem. In order to reduce such wasteful consumption as much as possible, normally, about 0.1 percent of diluted saline solution is used, so the conductivity of the salt solution is low, which increases the power consumption for performing the predetermined electrolysis. There was also a problem of doing.

  Further, since the diaphragm 2 is directly subjected to a force due to the flow in the anode chamber and the cathode chamber, fluctuations in water pressure, etc., there is a risk of breakage. In order to prevent this, a plurality of reinforcing ribs crossing the diaphragm 2 are provided. Therefore, there is a problem that the effective area of the diaphragm 2 is reduced by that amount and the electrolyzed water production capacity is reduced.

  An object of the present invention is to solve the above-mentioned problem by enabling reuse by circulating salt water that is not electrolyzed.

In order to achieve this object, the present invention forms a salt water chamber between a pair of diaphragms provided apart from each other inside a casing, and separates and forms an anode chamber and a cathode chamber on both sides of the salt water chamber. An electrolytic cell in which an anode and a cathode are respectively disposed in a chamber and a cathode chamber, a direct current power source for supplying a direct current to the anode and the cathode, a circulating salt water tank for storing salt water to be electrolyzed, and a salt water chamber of the electrolytic cell in the salt water chamber A salt water introduction pipe for introducing salt water stored in the circulation salt water tank, a salt water outlet pipe for returning unelectrolyzed salt water from the salt water chamber to the circulation salt water tank, and salt water interposed between the salt water introduction pipe or the salt water outlet pipe Circulation pump for circulation, raw water introduction pipe for introducing raw water into the anode chamber and the cathode chamber, respectively, and acidic water extraction for continuously deriving acidic water generated by electrolysis from the anode chamber in the anode chamber Tube and said In flow-through electrolytic water generator with alkaline water takeout tube to continuously derive the alkaline water produced by electrolysis at the same cathode chamber from electrode chamber,
The present invention provides a flowing water type electrolyzed water generating apparatus characterized in that the circulating salt water tank is provided with a stirring pump for uniformizing the concentration of the saline in the tank.

  In the flowing water type electrolyzed water generating device according to the present invention configured as described above, unelectrolyzed salt water is repeatedly used by circulating between the salt water chamber and the circulating salt water tank without entering the anode chamber or the cathode chamber. , Salt is not wasted. Moreover, since there is no such wasteful consumption, salt water with a high concentration can be used, thereby increasing the conductivity of the salt water, so that power consumption for performing a necessary amount of electrolysis is reduced. In particular, since the concentration of the salt water stored in the circulating salt water tank becomes uniform due to the provision of the agitation pump, the concentration of the saline solution circulated and supplied to the salt water chamber by the concentration meter provided in the circulating salt water tank is accurately determined. It is possible to maintain the desired characteristics of the acidic water and the alkaline water respectively generated in the anode chamber and the cathode chamber by always supplying a salt solution of a predetermined concentration to the salt water chamber.

  The present invention will be described below with reference to the embodiments shown in FIGS.

  As shown in FIGS. 1 and 2, the inside of the casing 10 whose main part is made of an insulating material is partitioned by two diaphragms 11 and 13 provided in parallel to each other, and salt water between the diaphragms 11 and 13. The chamber B, the anode chamber A between the diaphragm 11 and the casing 10, and the cathode chamber C between the diaphragm 13 and the casing 10 are separated. Each of the diaphragms 11 and 13 having substantially the same structure is a semipermeable membrane made of, for example, polyfucavinylidene titanium oxide using a polyethylene non-woven fabric as an aggregate, and its outer peripheral edge is a frame-like diaphragm holding body 12, 14 made of vinyl chloride. Are integrally formed and reinforced. An anode 15 is provided adjacent to the anode chamber A side of the diaphragm 11 with almost no gap, and a cathode 16 is provided adjacent to the cathode chamber C side of the diaphragm 13 with almost no gap. Each of the electrodes 15 and 16 is made of a rigid plate-shaped metal lath, is fixedly supported by the casing 10, and is connected to a DC power supply 17 for electrolysis. The electrodes 15 and 16 are not limited to metal laths, and may be a metal mesh, punched metal, or a large number of rod-shaped materials arranged in a lattice shape, as long as the liquid can pass freely. Is given.

  As shown mainly in FIG. 1, the bottom of the salt water chamber B and the bottom of the circulating salt water tank 20 are communicated with each other by a salt water introducing pipe 21 provided with a circulation pump 23, and the top of the salt water chamber B and the top of the circulating salt water tank 20 are throttled 24. Are communicated by a salt water outlet pipe 22. A concentrated salt water tank 30 for storing saturated saline is connected to the upper part of the circulating salt water tank 20 via a communication pipe 31 provided with an on-off valve 32, and a water supply pipe (not shown) provided with an on-off valve is connected. If the saline concentration detected by the densitometer 35 provided in the circulating salt water tank 20 is out of a predetermined range (for example, 10 to 20%), the opening / closing valve 32 or the opening / closing valve of the water supply pipe is opened and the inside of the circulating salt water tank 20 is opened. The saline concentration is maintained within a predetermined range. The circulating salt water tank 20 is provided with a stirring pump 34 for making the concentration inside the circulating salt water tank 20 uniform. A salt tank 33 for supplying salt to the concentrated salt water tank 30 is provided above the concentrated salt water tank 30.

  As shown in FIG. 1, the raw water supply pipe 25 connected to the water pipe and provided with the control valve 28 is branched into two raw water introduction pipes 25a and 25b. The raw water introduction pipes 25a and 25b are respectively connected to the anode chamber A and the raw water introduction pipe 25a and 25b. It communicates with the bottom of the cathode chamber C. An acidic water extraction pipe 26 and an alkaline water extraction pipe 27 are communicated with the upper part of the anode chamber A and the cathode chamber C, respectively. The dimensional relationship in the explanatory diagram of FIG. 1 is different from the actual one for the sake of illustration, and the casing 10 is displayed larger than the actual compared to the circulating salt water tank 20, the concentrated salt water tank 30, the salt tank 33, and the like. Yes.

  Next, the operation of the above embodiment will be described.

  At the start of use of the electrolyzed water production apparatus, first, the on-off valve 32 and the on-off valve of the water supply pipe are opened to supply saturated saline and tap water to the circulating salt water tank 20 and at the same time, the stirring pump 34 is operated to operate the circulating salt water tank 20. The internal concentration is made uniform, both open / close valves are controlled within a predetermined concentration range based on the saline concentration detected by the concentration meter 35, and both open / close valves are closed when the water level in the circulating salt water tank 20 reaches a predetermined level. . Next, the circulation pump 23 is operated to feed the saline in the circulating salt water tank 20 into the salt water chamber B through the salt water introducing pipe 21 and return to the circulating salt water tank 20 through the salt water outlet pipe 22 to circulate the saline. . Subsequently, the control valve 28 of the raw water supply pipe 25 is opened, and the raw water from the water pipe is sent into the anode chamber A and the cathode chamber C, and is discharged from the acidic water take-out pipe 26 and the alkaline water take-out pipe 27.

  If power for electrolysis from the DC power source 17 is supplied to the anode 15 and the cathode 16 in this state, chlorine ions (anions) in the saline solution in the salt water chamber B pass through the diaphragm 11 and enter the anode chamber A, where the anode 15 When it comes into contact with it, it loses its electric power and becomes chlorine. Part of this chlorine is dissolved in the water near the anode 15 as it is, and part of it reacts with water to produce hypochlorous acid or hypochlorite ions, which give an effective chlorine concentration with a bactericidal action. Part of the remaining chlorine is liberated as hydrochloric acid or chlorine gas. As a result, the water in the vicinity of the anode 15 becomes acidic, and the acidic water composed of these components passes through the anode 15 through which liquid can freely pass and spreads in the anode chamber A. Sodium ions (cations) in the salt water in the salt water chamber B pass through the diaphragm 13 and enter the cathode chamber C to contact the cathode 16 to lose their valence, react with the water in the vicinity of the cathode 16 and react with caustic soda and liberation. Hydrogen is generated to make the water near the cathode 16 alkaline. The water that has become alkaline passes through the cathode 16 through which liquid can freely pass and spreads in the cathode chamber C. The acidic water and alkaline water generated in the anode chamber A and the cathode chamber C in this way are sent out from the acidic water take-out pipe 26 and the alkaline water take-out pipe 27 and used for their respective purposes.

  The salt water that has not been electrolyzed in the salt water chamber B is hardly blocked by the diaphragms 11 and 13 and enters the anode chamber A or the cathode chamber C, and most of the salt water returns to the circulating salt water tank 20 from the salt water outlet pipe 22. Then, the water is again fed into the salt water chamber B from the salt water introduction pipe 21 by the circulation pump 23 and repeatedly circulated for use. Accordingly, the unelectrolyzed saline is hardly discharged from the acidic water take-out pipe 26 and the alkaline water take-out pipe 27, so that the salt is not wasted. Further, since there is no wasteful consumption of salt, a saline solution having a high concentration can be used. As a result, the conductivity of the salt solution is increased, so that power consumption for performing a necessary amount of electrolysis is reduced.

  In the state in which the saline in the circulating salt water tank 20 is circulated through the salt water chamber B by the circulation pump 23, the water pressure in the salt water chamber B is increased by the degree of the throttle 24 provided in the salt water outlet pipe 22, and this throttle 24 is appropriately set. To set the water pressure in the salt water chamber B higher than the water pressure in the anode chamber A and the cathode chamber C. Due to the difference in water pressure, the diaphragms 11 and 13 are pressed and held against the anode 15 and the cathode 16 provided adjacent to each other over the entire area, and the force applied to the diaphragms 11 and 13 is received by the anode 15 and the cathode 16. Accordingly, since it is not necessary for each diaphragm 11 and 13 to receive the force applied thereto, it is not necessary to provide reinforcing ribs across each diaphragm 11 and 13, and there is no decrease in electrolyzed water production capacity due to a decrease in the effective area of the diaphragm.

  If the salt in the salt water chamber B and the circulating salt water tank 20 is consumed due to the production of the electrolyzed water and the concentration of the saline decreases, the concentration meter 35 detects this and opens the on-off valve 32 to set the concentration of the saline to a predetermined value. Keep within range. As a result, the water level in the circulating salt water tank 20 rises, and the amount exceeding the predetermined water level is discharged from an overflow pipe (not shown). Further, the water in the anode chamber A and the cathode chamber C flows into the salt water chamber B through the diaphragms 11 and 13 due to the difference in osmotic pressure, and this also raises the water level in the circulating salt water tank 20. The portion exceeding the predetermined water level is discharged from the overflow pipe. Inflow from the anode chamber A and the cathode chamber C into the salt water chamber B due to the difference in osmotic pressure is suppressed by increasing the water pressure on the salt water chamber B side as described above.

  The pH, effective chlorine concentration, redox potential (ORP), etc. of acidic water used for food processing manufactured as described above are adjusted by the control valve 28 to adjust the flow rate of water passing through the anode chamber A. Can be controlled. These values can also be controlled by the composition of the anode 15, the voltage applied by the DC power source 17, the concentration and temperature of the saline solution, and the like.

  In the above-described embodiment, the salt water outlet pipe 22 is provided with the throttle 24 to increase the water pressure in the salt water chamber B. However, the water pressure in the salt water chamber B may be increased by setting the circulating salt water tank 20 higher than the casing 10. . Further, in the above embodiment, two completely separated diaphragms 11 and 13 are used, but the mutually facing portions of one tubular diaphragm are attached to the inner surfaces facing the casing 10 over a certain width, You may make it isolate | separate the inside of the casing 10 into the center salt water chamber B and the anode chamber A and the cathode chamber C of the both sides by the two parts of the stretched membrane. Moreover, although the said Example demonstrated about the case where salt solution was used as an electrolysis solution, this invention is applicable also when using the solution of another salt as an electrolysis solution.

BRIEF DESCRIPTION OF THE DRAWINGS It is whole explanatory drawing of one Example of the electrolyzed water manufacturing apparatus by this invention. It is a cross-sectional view which mainly shows the casing of the Example shown in FIG. 1, and its internal structure. It is explanatory drawing of an example of the electrolyzed water manufacturing apparatus by a prior art.

Explanation of symbols

DESCRIPTION OF SYMBOLS 10 ... Casing, 11, 13 ... Diaphragm, 15 ... Anode, 16 ... Cathode, 17 ... DC power supply, 20 ... Circulating salt water tank, 21 ... Salt water introduction pipe, 22 ... Salt water outlet pipe, 23 ... Circulation pump, 25a, 25b ... Raw water introduction pipe, 26 ... acid water take-out pipe, 27 ... alkaline water take-out pipe, A ... anode chamber, B ... salt water chamber, C ... cathode chamber.

Claims (1)

A salt water chamber is formed between a pair of diaphragms provided apart from each other inside the casing, and an anode chamber and a cathode chamber are separately formed on both sides of the salt water chamber, and an anode and a cathode are respectively arranged in the anode chamber and the cathode chamber. An installed electrolytic cell, a direct current power source for supplying a direct current to the anode and the cathode, a circulating salt water tank for storing the salt water to be electrolyzed, and the salt water stored in the circulating salt water tank into the salt water chamber of the electrolytic cell. A salt water introduction pipe, a salt water outlet pipe for refluxing unelectrolyzed salt water from the salt water chamber to the circulating salt water tank, a circulation pump for circulating salt water through the salt water inlet pipe or the salt water outlet pipe, and the anode chamber; A raw water introduction tube for introducing raw water into the cathode chamber, an acidic water extraction tube for continuously deriving acidic water generated by electrolysis from the anode chamber in the anode chamber, and a cathode chamber from the cathode chamber Electrolysis at Therefore, in flow-electrolyzed water generator with alkaline water takeout tube for continuously deriving the generated alkaline water,
A flowing water type electrolyzed water generating apparatus, wherein the circulating salt water tank is provided with a stirring pump for equalizing the concentration of the saline solution in the tank.

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