JP2005089340A - Skin cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To prepare a skin cosmetic which has excellent make-up effect sustainability, has good spreadability, when coated, and does not give a sticky sense. <P>SOLUTION: This skin cosmetic comprises an oily component and a polyoxyalkylene-organopolysiloxane alternating block copolymer represented by formula (1) [the organopolysiloxane block represented by the formula: (SiR<SP>1</SP><SB>2</SB>O)<SB>a</SB>SiR<SP>1</SP><SB>2</SB>has an average mol. wt. of ≥10,500, and is contained in an amount of 50 to 99 mass % based on the alternating block copolymer; the average mol. wt. of a polyoxyalkylene block represented by the formula: (C<SB>2</SB>H<SB>4</SB>O)<SB>b1</SB>(C<SB>3</SB>H<SB>6</SB>O)<SB>b2</SB>is 130 to 10,000; the average mol. wt. of the alternating block copolymer is ≥50,000]. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  The present invention relates to a skin cosmetic and, more particularly, to a skin cosmetic that is excellent in the sustainability of a cosmetic effect and that is sufficiently stretched during application and has no stickiness.

  In general, oily cosmetics have good adhesion to the skin and have a long-lasting cosmetic effect, but are applied to the skin due to the oily components (oily components other than silicone oils) constituting the oily cosmetics. It is difficult to extend (spread) and tends to cause stickiness.

  Technology for blending high molecular weight silicone for the purpose of reducing stickiness and making it easier to extend while maintaining the persistence of the cosmetic effect of oily cosmetics (see Patent Document 1); Technology for blending molecular silicone (see Patent Literature 2 and Patent Literature 3); linear polyether-modified silicone (polyoxyalkylene-organopolysiloxane alternating block having an average molecular weight of organopolysiloxane block of 400 to 10,000) A technique (see Patent Document 4 and Patent Document 5) for blending a copolymer) has been proposed.

  However, any of the cosmetics disclosed in Patent Documents 1 to 5 balances the contradictory effects of maintaining the makeup effect and reducing the stickiness and making it easier to extend (improving the spreadability). It cannot be used well.

  As described above, in the conventionally known skin cosmetics, those having a good makeup effect persistence tend to cause a sticky feeling due to insufficient stretch at the time of application. There is no known skin cosmetic that is excellent, has a good elongation at the time of application, and does not cause stickiness.

On the other hand, as a recent trend, cosmetics capable of forming a film excellent in gloss feeling (gloss and gloss) are desired.
JP 10-72319 A JP-A-5-32527 JP-A-5-32534 JP-A-4-234307 (Claim 2, Examples 1 to 4) JP-A-7-277923

  The present invention has been made based on the above situation.

A first object of the present invention is to provide a cosmetic for skin that is excellent in sustainability of a cosmetic effect.
A second object of the present invention is to provide a cosmetic for skin that has good elongation (expandability) at the time of application and does not cause stickiness.
The third object of the present invention is to provide a skin cosmetic that is excellent in the sustainability of the cosmetic effect, has a good elongation (spreadability) at the time of application, and does not cause a sticky feeling.
A fourth object of the present invention is to provide a skin cosmetic that can form a cosmetic film having an excellent gloss feeling (gloss and gloss).
The fifth object of the present invention is to provide a cosmetic for skin having a good feeling of use.

  As a result of intensive studies in order to achieve the above object, the present inventors have found that a polyoxyalkylene-organopolysiloxane having a specific structure and having an average molecular weight of the organopolysiloxane block and an overall average molecular weight of a certain value or more. By using siloxane alternating block copolymer in combination with an oily component, it is possible to obtain a cosmetic for skin that has excellent spreadability at the time of application and has no stickiness while being excellent in durability of the cosmetic effect. The present invention has been completed based on the finding and the findings.

  The skin cosmetic of the present invention comprises an oily component (hereinafter also referred to as “oily component (A)”); a polyoxyalkylene-organopolysiloxane alternating block copolymer represented by the following general formula (1) And “block copolymer (B)”).

[Wherein, R ¹ independently of each other represents a monovalent hydrocarbon group, a hydroxyl group or an alkoxy group free of aliphatic unsaturation, Y ¹ represents a divalent organic group, and R ² represents Independently of each other, a hydrogen atom, a hydroxyl group, a substituted or unsubstituted monovalent hydrocarbon group, an alkoxy group, or a formula: —Y ¹ —O— (C ₂ H ₄ O) _b1 (C ₃ H ₆ O) _b2 -Y ² (Y ² represents a hydrogen atom or a substituted or unsubstituted monovalent hydrocarbon group), a is an integer of 1 or more, b1 is an integer of 1 or more, b2 is 0 or an integer of 1 or more, and c is an integer of 1 or more. The average molecular weight of the organopolysiloxane block represented by the formula:-(SiR ¹ ₂ O) _a SiR ¹ _2- is not less than 10,500, and the organopolysiloxane block is 50 to 50% of the block copolymer (B). 99% by mass, and the polyoxyalkylene block represented by the formula: — (C ₂ H ₄ O) _b1 (C ₃ H ₆ O) _b2 — has an average molecular weight of 130 to 10,000. The average molecular weight of the polymer (B) is 50,000 or more. ]

  In the cosmetic for skin of this invention, it is preferable to contain a block copolymer (B) in the ratio of 0.1-300 mass parts with respect to 100 mass parts of oil-based components (A).

  Moreover, it is preferable to contain a silicone oil as an oil-based component (A).

(1) The cosmetic for skin of the present invention is excellent in the sustainability of the cosmetic effect (makeup lasting effect), has a good elongation at the time of application (extensibility), and does not cause a sticky feeling.
(2) According to the cosmetic for skin of the present invention, it is possible to form a cosmetic film excellent in gloss feeling (gloss / glossiness) and to give a good feeling of use.
(3) The skin cosmetic of the present invention has preferable properties (for example, good adhesion to the skin) of the oily cosmetic.

  The cosmetic for skin of the present invention comprises an oily component (A) and a block copolymer (B) as essential components.

  The oily component (A) constituting the skin cosmetic of the present invention may be solid, semi-solid, or liquid as long as it is used in ordinary cosmetics. For example, natural animals and plants Fats and oils, semi-synthetic fats and oils, hydrocarbon oils, higher alcohols, ester oils, fluorinated oils and silicone oils are included.

  “Natural animal and vegetable oils and fats” and “semi-synthetic oils and fats” used as the oil component (A) include avocado oil, linseed oil, almond oil, ibotarou, eno oil, olive oil, cacao butter, capok wax, kaya oil, carnauba wax, Liver oil, candelilla wax, beef tallow, beef leg fat, beef bone fat, hydrogenated beef tallow, kyounin oil, whale wax, hydrogenated oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sugarcane wax, sasanqua oil, safflower oil , Shea butter, cinnamon oil, cinnamon oil, jojoba wax, shellac wax, turtle oil, soybean oil, tea seed oil, camellia oil, evening primrose oil, corn oil, lard, rapeseed oil, Japanese kiri oil, nukarou, germ oil, horse Fat, Persic oil, Palm oil, Palm kernel oil, Castor oil, Hardened castor oil, Castor oil fatty acid methyl ester, Sunflower oil, Grape oil, Bay Lilow, jojoba oil, macadamia nut oil, beeswax, mink oil, cottonseed oil, cotton wax, owl, owl kernel oil, montan wax, coconut oil, hydrogenated coconut oil, tricoconut oil, fatty acid glyceride, sheep fat, peanut oil, lanolin, liquid lanolin, Reduced lanolin, lanolin alcohol, hard lanolin, lanolin acetate, lanolin fatty acid isopropyl, hexyl laurate, polyoxyethylene (POE) lanolin alcohol ether, POE lanolin alcohol acetate, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether and egg yolk oil, etc. Is mentioned.

  “Hydrocarbon oil” includes ozokerite, squalane, squalene, ceresin, paraffin, paraffin wax, liquid paraffin, liquid isoparaffin, pristane, polyisobutylene, microcrystalline wax, petrolatum, etc .; higher fatty acids include lauric acid, myristic acid, Examples include palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), isostearic acid and erucic acid.

  “Higher alcohol” includes lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyl decanol, octyldodecanol, cetostearyl alcohol, 2-decyltetradecyl Examples thereof include diol, cholesterol, phytosterol, POE cholesterol ether, monostearyl glycerin ether (batyl alcohol) and monooleyl glyceryl ether (ceralkyl alcohol).

  Examples of the “ester oil” include diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, n-alkyl glycol monoisostearate, isocetyl isostearate, trimethylolpropane triisostearate, di-2 -Ethylene glycol ethylhexanoate, cetyl 2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl octanoate, octyldodecyl gum ester, oleyl oleate, oleic acid Octyldodecyl, decyl oleate, neopentyl glycol dicaprate, triethyl citrate, 2-ethylhexyl succinate, amyl acetate, ethyl acetate, butyl acetate, isocetyl stearate, stearate Butyl phosphate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, myristyl lactate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, 2-heptyl undecyl palmitate, 12-hydroxy Cholesteryl stearyl, dipentaerythritol fatty acid ester, isopropyl myristate, octyldodecyl myristate, 2-hexyldecyl myristate, myristyl myristate, hexyldecyl dimethyloctanoate, ethyl laurate, hexyl laurate, N-lauroyl-L- Glutamic acid-2-octyldodecyl ester, diisostearyl malate, etc .; glyceride oils include acetoglyceryl, triisooctanoic acid glyceryl, trii Glyceryl stearate, triisopalmitate, glyceryl monostearate, di-2-heptyl undecanoic acid, glyceryl trimyristate, and the like diglyceryl myristate isostearate.

  Examples of the “fluorinated oil agent” include perfluoropolyether, perfluorodecalin, perfluorooctane and the like.

In the present invention, it is preferable to contain silicone oil as the oil component (A).
Here, examples of the “silicone oil” include dimethylpolysiloxane having a degree of polymerization (the number of silicon in the siloxane chain) of 10 or more and a liquid to gum-like or wax-like one in which a part of the methyl group is substituted. Is mentioned. The siloxane chain may have a branched chain or may be partially crosslinked. Examples of the substituent include a linear or branched alkyl group having 2 to 500 carbon atoms, an aryl group (for example, phenyl group, 2-phenylethyl group), an amino-substituted alkyl group (for example, —C ₃ H ₆ NH ₂ , —C ₃ H ₆ NHC ₂ H ₄ NH ₂ ), sugar derivative groups, glyceryl groups, polyglyceryl groups and the like. Particularly preferred is dimethylpolysiloxane having a polymerization degree of 10 to 400.

The skin cosmetic of the present invention is characterized in that it contains a block copolymer (B) having a specific structure. Here, in the above general formula (1) showing the block copolymer (B), R ¹ is independently a monovalent hydrocarbon group, hydroxyl group or alkoxy group which does not contain aliphatic unsaturation.

  Examples of the monovalent hydrocarbon group free of aliphatic unsaturation include a methyl group, an ethyl group, a propyl group, a butyl group, an octyl group, a dodecyl group, a phenyl group, a phenethyl group, and the like. A phenyl group is preferred.

Examples of the alkoxy group represented by R ¹ include a methoxy group, an ethoxy group, a propoxy group, a butoxy group, an isopropenyloxy group, a methoxyethoxy group, a phenyloxy group, an acetoxy group, a cyclohexyloxy group, and a dodecanyloxy group. And an alkoxy group having 1 to 12 carbon atoms, preferably 1 to 8 carbon atoms, more preferably 1 to 6 carbon atoms, and a methoxy group and an ethoxy group are preferable.

In the general formula (1), the divalent organic group represented by Y ¹ is bonded to the silicon atom constituting the organopolysiloxane block by a carbon-silicon bond, and the polyoxyalkylene block is bonded via an oxygen atom. [Poly (oxyethylene) (oxypropylene) block].

Specific examples of the organic group represented by ^{Y 1, -R 16 -, -} R 16 -CO -, - R 16 -NHCO -, - R 16 -NHCONHR 17 -NHCO- and -R ¹⁶ -OOCNH-R ¹⁷ -NHCO- wherein, R ¹⁶ is an ethylene group, a propylene group, an alkylene group such as butylene group, R ¹⁷ is an alkylene _{group, -C 6 H 4 -, -} C 6 H 4 -C 6 H 4 - , -C ₆ H ₄ —CH ₂ —C ₆ H ₄ —, —C ₆ H ₄ —CH (CH ₃ ) —C ₆ H ₄ — and the like are arylene groups. ].

Suitable organic groups represented by Y ¹ include —CH ₂ CH ₂ —, —CH ₂ CH ₂ CH ₂ —, —CH ₂ CH (CH ₃ ) CH ₂ —, — (CH ₂ ) ₄ —, — _{(CH 2) 2 CO -,} - (CH 2) 3 NHCO -, - (CH 2) 3 NHCONHC 6 H 4 CO- or _{- (CH 2) 3 OOCNHC 6} H 4 NHCO- , and the like. Of _{these, -CH 2 CH 2 -, -} CH 2 CH 2 CH 2 -, - CH 2 CH (CH 3) CH 2 - is an alkylene group such as _{Preferably, -CH 2 CH (CH 3)} CH 2 - is Most preferred.

In the general formula (1), R ² are each independently a hydrogen atom, a hydroxyl group, a substituted or unsubstituted monovalent hydrocarbon group, an alkoxy group or the _{^{formula,: -Y 1 -O- (C 2}} H ₄ O) _b1 (C ₃ H ₆ O) _b2 -Y ² (Y ² represents a hydrogen atom or a substituted or unsubstituted monovalent hydrocarbon group, and Y ¹ is as defined above.) It is group represented by these.

Examples of the substituted or unsubstituted monovalent hydrocarbon group represented by R ² include a methyl group, an ethyl group, a propyl group, an aminopropyl group, a glycidoxypropyl group, a butyl group, a pentyl group, a hexyl group, and an octyl group. And alkyl groups having 1 to 12 carbon atoms, preferably 1 to 8 carbon atoms, more preferably 1 to 6 carbon atoms, such as dodecyl group; vinyl group, propenyl group, butenyl group, pentenyl group, hexenyl group and octenyl group An alkenyl group having 2 to 8 carbon atoms, preferably 2 to 6 carbon atoms, such as a cycloalkyl group having 3 to 8 carbon atoms, preferably 5 to 7 carbon atoms such as a cyclopropyl group, a cyclopentyl group and a cyclohexyl group; 1 to 8 carbon atoms such as trifluoropropyl group, perfluorooctylethyl group, chloropropyl group and pentachlorooctyl group, preferably 1 to 6 halogenated alkyl groups; aliphatic acyl groups having 1 to 18, preferably 1 to 7 carbon atoms such as acetyl, propionyl, pentanoyl and octanoyl; benzoyl and benzylcarbonyl Aromatic acyl groups having 7 to 15 carbon atoms, preferably 7 to 11 carbon atoms; aryls having 6 to 14 carbon atoms, preferably 6 to 10 carbon atoms such as phenyl, tolyl, xylyl and naphthyl groups And an aralkyl group having 7 to 15 carbon atoms, preferably 7 to 11 carbon atoms such as a benzyl group and a phenethyl group. Of these, a methyl group and a phenyl group are preferred.

In the group represented by the formula: —Y ¹ —O— (C ₂ H ₄ O) _b1 (C ₃ H ₆ O) _b2 —Y ² (group constituting R ² ), Y ² represents a hydrogen atom or a substituent. Alternatively, it represents an unsubstituted monovalent hydrocarbon group. Examples of the substituted or unsubstituted monovalent hydrocarbon group represented by Y ² include the same groups as those exemplified as those represented by R ² above.

Suitable groups represented by Y ² include —CH═CH ₂ , —CH ₂ CH═CH ₂ , —CH ₂ C (CH ₃ ) ═CH ₂ , — (CH ₂ ) ₂ —CH═CH _{2 and the} like. An alkenyl group, a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, and an acetyl group.

  In the said General formula (1), a is an integer greater than or equal to 1, Preferably it is an integer of 140-1350, More preferably, it is an integer of 160-400.

  b1 is an integer greater than or equal to 1, Preferably it is an integer of 3-220, More preferably, it is an integer of 7-60.

  b2 is an integer of 0 or 1 or more, preferably an integer of 0 to 170, more preferably an integer of 0 to 50.

  c is an integer greater than or equal to 1, Preferably it is an integer of 5-50, More preferably, it is an integer of 10-50.

The average molecular weight of the organopolysiloxane block represented by the formula:-(SiR ¹ ₂ O) _a SiR ¹ _2- is usually not less than 10,500, preferably 10,500 to 100,000, more preferably 12, 000 to 30,000.

  Skin cosmetics containing a block copolymer having an average molecular weight of the organopolysiloxane block of less than 10,500 are inferior in elongation at the time of application (extensibility) and sustainability of the cosmetic effect. In addition, such a cosmetic for skin cannot form a cosmetic film having a good gloss feeling.

  The constituent ratio of the organopolysiloxane block (total amount) in the block copolymer (B) is usually 50 to 99% by mass, preferably 70 to 99% by mass, and more preferably 90 to 99% by mass.

  Depending on the cosmetic for skin containing a block copolymer having an organopolysiloxane block constituent ratio of less than 50% by mass, the elongation at the time of application (extensibility) and the durability of the cosmetic effect are inferior. On the other hand, even with a cosmetic for skin containing a block copolymer having a constituent ratio exceeding 99% by mass, the sustainability of the cosmetic effect is insufficient, and makeup collapse tends to occur.

The average molecular weight of the polyoxyalkylene block represented by the formula: — (C ₂ H ₄ O) _b1 (C ₃ H ₆ O) _b2 — is usually 130 to 10,000, preferably 310 to 5,000, More preferably, it is set to 440-3,000.

  Any of a skin cosmetic containing a block copolymer having an average molecular weight of a polyoxyalkylene block of less than 130 and a skin cosmetic containing a block copolymer having an average molecular weight of more than 10,000, It becomes inferior in the elongation (spreadability) at the time of application and the sustainability of the cosmetic effect.

In the polyoxyalkylene block constituting the block copolymer (B), the oxyethylene group (—C ₂ H ₄ O—) and the oxypropylene group (—C ₃ H ₆ O—) may be bonded at random. It may be combined in a block shape.
In the above formula showing a suitable polyoxyalkylene block, the repeating number (b1 / b2) is preferably (3 to 220/0 to 170), more preferably (7 to 60/0 to 50), Particularly preferably (10 to 35/0 to 35).

  The average molecular weight of the block copolymer (B) is usually 50,000 or more, preferably 55,000 or more, more preferably 100,000 to 2,000,000, particularly preferably 150,000 to 1,000. , 000.

  Depending on the cosmetic for skin containing a block copolymer having an average molecular weight of less than 50,000, the durability of the cosmetic effect cannot be sufficiently exhibited.

  As a content rate of the block copolymer (B) in the skin cosmetics of this invention, it is preferable that it is 0.1-300 mass parts with respect to 100 mass parts of oil-based components (A), More preferably, it is 0. .3 to 200 parts by mass, particularly preferably 0.3 to 100 parts by mass.

  When the content of the block copolymer (B) is too small, the object of the present invention cannot be sufficiently achieved. On the other hand, when this content ratio is excessive, the suitable feel by the oil-based component (A) and the appearance when finished may be hindered.

  The skin cosmetic of the present invention can contain various components constituting a normal cosmetic as optional components depending on the purpose. Examples of such optional components include surfactants. Such surfactants include anionic, cationic, nonionic and amphoteric ones, but are not particularly limited in the present invention, so long as they are used in ordinary cosmetics. Any of these can be used.

  Specific examples of the anionic surfactant include fatty acid soaps such as sodium stearate and triethanolamine palmitate, alkyl ether carboxylic acids and salts thereof, condensates of amino acids and fatty acids, alkane sulfonates. Alkene sulfonate, fatty acid ester sulfonate, fatty acid amide sulfonate, formalin condensation sulfonate, alkyl sulfate ester, secondary higher alcohol sulfate, alkyl and allyl ether sulfate, fatty acid Sulfate ester of ester, sulfate ester of fatty acid alkylol amide, sulfate ester salt such as funnel oil, alkyl phosphate, ether phosphate, alkyl allyl ether phosphate, amide phosphate, N-acyl amino acid activity Agents etc. That.

  Here, as a suitable anionic surfactant, fatty acid soap, α-acyl sulfonate, alkyl sulfonate, alkyl allyl sulfonate, alkyl naphthalene sulfonate, alkyl sulfate, polyoxyethylene alkyl ether sulfate , Alkylamide sulfate, alkyl phosphate, alkylamide phosphate, alkyloylalkyltaurine salt, N-long chain acylamino acid salt, polyoxyethylene alkyl ether phosphate and the like.

  Examples of the cationic surfactant include amine salts such as alkylamine salts, polyamines and amino alcohol fatty acid derivatives, alkyl quaternary ammonium salts, aromatic quaternary ammonium salts, pyridium salts, imidazolium salts and the like.

  Here, as suitable cationic surfactants, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, behenyldimethylhydroxyethylammonium chloride, stearyldimethylbenzylammonium chloride, distearyldimethylammonium chloride, lauryltrimethylammonium chloride And quaternary ammonium salts such as myristyldimethylbenzylammonium chloride, lanolin fatty acid aminopropylethyldimethylammonium ethyl sulfate and cetyltriethylammonium methyl sulfate.

  Nonionic surfactants include sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycolic acid ester, polyethylene glycolic acid ester, sucrose acid ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, poly Oxyethylene alkyl phenyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxy Ethylene phytostanol ether, polyoxyethylene phytosterol ether, polyoxyethylene Cholestanol ether, polyoxyethylene cholesteryl ether, alkanol amide, sugar ether and sugar amide.

  Here, suitable nonionic surfactants include polyoxyethylene alkyl ether, alkylallyl polyoxyethylene ether, alkylolamide, alkylglycerin ether type polyoxyethylene ether, propylene glycol ester polyoxyethylene ether, polyoxyethylene Ethylene fatty acid ester, glycerin and fatty acid ester polyoxyethylene ether, fatty acid sorbitan ester polyoxyethylene ether, sorbitol polyoxyethylene fatty acid ester, sucrose ester, polyoxyethylene fatty acid amide, polyoxyethylene alkylamine, poly Oxyalkylene-organopolysiloxane copolymer [excluding block copolymer (B). ] Etc. are illustrated.

  Examples of amphoteric surfactants include betaine type (carboxybetaine / sulfobetaine), amide betaine type, aminocarboxylate type, and imidazoline derivative type.

  In the cosmetic for skin of the present invention, powders and colorants can be used depending on the purpose. If such powders and colorants are used in normal cosmetics, their shapes (spherical, needle-like, plate-like, etc.), particle diameters (fog-like, fine particles, pigment grade, etc.), particles Any structure can be used regardless of the structure (porous, nonporous, etc.). Examples thereof include powders such as inorganic powders, organic powders, and surfactant metal salt powders, colored pigments, pearl pigments, tar dyes, metal powder pigments, and colorants such as natural dyes.

  Specific examples of the inorganic powder include titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, mica, kaolin, sericite, muscovite. , Synthetic mica, phlogopite, saucite, biotite, lithia mica, silicic acid, anhydrous silicic acid, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, strontium silicate, tungstic acid Examples thereof include metal salts, hydroxyapatite, vermiculite, hydrite, bentonite, montmorillonite, hectorite, zeolite, ceramic powder, dicalcium phosphate, alumina, aluminum hydroxide, boron nitride, and silica.

Specific examples of organic powders include polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoroethylene powder, polymethylmethacrylate powder, cellulose, silk powder, nylon Powder, 12 nylon, 6 nylon, silicone powder, styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, vinyl resin, urea resin, phenol resin, fluororesin, silicon resin, acrylic resin, melamine resin, epoxy resin , Polycarbonate resin, microcrystalline fiber powder, starch powder, lauroyl lysine and the like. Furthermore, an organic powder mainly composed of a — [Si—O—] _n — skeleton is also preferable. In this case, a part of the molecule may have a —Si (CH ₂ ) _m —Si— bond.

  Specific examples of the surfactant metal salt powder (metal soap) include zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, zinc cetyl phosphate, calcium cetyl phosphate, and zinc cetyl phosphate. Sodium etc. are mentioned.

  Specific examples of colored pigments include inorganic red pigments such as iron oxide, iron hydroxide and iron titanate, inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as yellow iron oxide and loess, black iron oxide, Inorganic black pigments such as carbon black, inorganic purple pigments such as manganese violet and cobalt violet, inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide and cobalt titanate, inorganic blue pigments such as bitumen and ultramarine, and tar systems Examples include raked pigments, raked natural pigments, and synthetic resin powders obtained by combining these powders.

  Specific examples of pearl pigments include titanium oxide-coated mica, bismuth oxychloride, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, fish scale foil, and titanium oxide-coated colored mica; metal powder pigments include aluminum powder and copper powder And stainless steel powder.

  As tar pigments, Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227, Red No. 228, Red 230, Red 401, Red 505, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Yellow 204, Yellow 401, Blue 1, Blue 2, Blue 201, Blue 404 Green No. 3, Green No. 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, Orange No. 207, etc .; natural pigments include carminic acid, laccaic acid, and calsamine , Bradylin, crocin and the like.

  These powders can be combined with powders or treated with general oils, silicone oils, fluorine compounds, surfactants, etc., as long as the effects of the present invention are not impaired. Or two or more of them can be used.

  In the skin cosmetic of the present invention, at least one compound having an alcoholic hydroxyl group in the molecular structure may be used depending on the purpose. Examples of alcohols that can be added in the present invention include lower alcohols such as ethanol and isopropanol, sugar alcohols such as sorbitol and maltose, and examples of sterols include cholesterol, sitosterol, phytosterol, and lanosterol. In the present invention, it is particularly preferable to use a water-soluble monohydric alcohol and / or a water-soluble polyhydric alcohol.

  The skin cosmetic of the present invention can also contain a water-soluble polymer as a thickener, suspending agent, or emulsion stabilizer. Water-soluble polymers include gum arabic, tragacanth, galactan, carob gum, guar gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), starch (rice, corn, potato, wheat), algae colloid, trant gum, locust bean Plant polymers such as gum, microbial polymers such as xanthan gum, dextran, succinoglucan and pullulan, animal polymers such as collagen, casein, albumin and gelatin, starches such as carboxymethyl starch and methylhydroxypropyl starch Polymer, methylcellulose, ethylcellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, nitro Cellulose polymers such as roulose, sodium cellulose sulfate, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, alginic acid polymers such as sodium alginate and propylene glycol alginate, vinyl polymers such as polyvinyl methyl ether and carboxyvinyl polymer, poly Oxyethylene polymers, polyoxyethylene polyoxypropylene copolymer polymers, acrylic polymers such as sodium polyacrylate, polyethyl acrylate, polyacrylamide, other synthetic water-soluble polymers such as polyethyleneimine and cationic polymers, Inorganic water such as bentonite, magnesium aluminum silicate, montmorillonite, beidellite, nontronite, saponite, hectorite, silicic anhydride There is such as sex polymer.

  Examples of the anionic water-soluble polymer include arabic gum, carrageenan, pectin, xanthan gum, sodium alginate, carboxyvinyl polymer, dermatan sulfate, keratan sulfate, heparan sulfate, and salts thereof.

  Further, as cationic water-soluble polymers, cation-modified cellulose ether derivatives [polymer JR (UC), etc.], cationic starch, cationized guar gum derivatives, diallyldimethylammonium chloride polymers [Mercoat, etc. ], Polyacrylic acid derivative quaternary ammonium [Cartex (National Starch etc.)], polyamide derivative quaternary ammonium (Sandoz etc.), polyoxyethylene polyalkylene polyamine [Polycoat (HENKEL) etc.] etc. are mentioned.

  In addition, as an amphoteric water-soluble polymer, a copolymer of a monomer having an anionic group such as a carboxyl group or a sulfonic acid group and a monomer having a basic nitrogen, a polymer or copolymer of a carboxybetaine monomer, Those obtained by introducing an anionic group such as a carboxyl group or a sulfonic acid group into a cationic polymer, those obtained by introducing a basic nitrogen-containing group into an anionic polymer, and monomers and anions having a nonionic group such as acrylamide. And a copolymer of a monomer having a functional group and a monomer having a basic nitrogen-containing group. As the amphoteric water-soluble polymer, commercially available ones can be used, and examples thereof include acrylic acid / diallyl quaternary ammonium salt / acrylamide copolymer such as Marquat Plus 3330 (manufactured by CALGON).

  Examples of nonionic water-soluble polymers include galactan, methylcellulose, methylhydroxypropylcellulose, hydroxypropylcellulose, hydroxyethylcellulose, and dextrin.

  The skin cosmetic of the present invention can also contain a film forming agent such as polyvinyl alcohol and polyvinyl pyrrolidone, which are also water-soluble polymers.

  In addition to the above-mentioned components, the skin cosmetic of the present invention includes components that are used in ordinary cosmetics within a range that does not interfere with the effects of the present invention, such as water, film-forming agents, oil-soluble gelling agents, and organic modifications. Clay minerals, resins, UV absorbers, UV scattering agents, moisturizers, antiseptics, antibacterial agents, fragrances, chemicals, salts, antioxidants, pH adjusters, chelating agents, cooling agents, anti-inflammatory agents, skin beautifying ingredients ( Whitening agents, cell activators, rough skin improvers, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, proteins or protein degradation products, diluents (solvents) ) And the like can be added.

  Examples of oil-soluble gelling agents include metal soaps such as aluminum stearate, magnesium stearate, zinc myristate, amino acid derivatives such as N-lauroyl-L-glutamic acid, α, γ-di-n-butylamine, and dextrin palmitate Dextrin stearate, dextrin fatty acid ester such as 2-ethylhexanoic acid palmitate, sucrose fatty acid ester such as sucrose palmitate, sucrose stearate, sorbitol such as monobenzylidene sorbitol, dibenzylidene sorbitol Organic modified clay minerals such as benzylidene derivatives, dimethylbenzyl dodecyl ammonium montmorillonite clay, and dimethyl dioctadecyl ammonium montmorillonite clay And a gelling agent selected from the above.

  Examples of UV absorbers include benzoic acid UV absorbers such as paraaminobenzoic acid, anthranilic acid UV absorbers such as methyl anthranilate, salicylic acid UV absorbers such as methyl salicylate, octyl paramethoxycinnamate, and paramethoxysilicate. Cinnamic acid ultraviolet absorbers such as 2-ethylhexyl cinnamate, benzophenone ultraviolet absorbers such as 2,4-dihydroxybenzophenone, urocanic acid ultraviolet absorbers such as ethyl urocanate, 4-t-butyl-4 ′ − And dibenzoylmethane-based ultraviolet absorbers such as methoxy-dibenzoylmethane.

  As humectants, glycerin, sorbitol, ethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, glucose, xylitol, maltitol, polyethylene glycol, hyaluronic acid, chondroitin sulfate, pyrrolidone carboxylate, polyoxyethylene Examples include methyl glucoside and polyoxypropylene methyl glucoside.

  Preservatives and antibacterial agents include paraoxybenzoic acid alkyl esters, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, etc. Antibacterial agents include benzoic acid, salicylic acid, coal acid, sorbic acid, alkyl paraoxybenzoate Examples include esters, parachlorometacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, photosensitizer, phenoxyethanol, ethyl paraben, and butyl paraben.

  Antioxidants include tocopherol, butylhydroxyanisole, dibutylhydroxytoluene, phytic acid, etc. pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium bicarbonate , Ammonium bicarbonate, etc., as a chelating agent, alanine, sodium edetate, sodium polyphosphate, sodium metaphosphate, phosphoric acid, etc., as a refreshing agent, L-menthol, camphor, etc., as an anti-inflammatory agent, allantoin, Examples thereof include glycyrrhizic acid and salts thereof, glycyrrhetinic acid and stearyl glycyrrhetinate, tranexamic acid, and azulene.

  As skin beautifying ingredients, placenta extract, whitening agents such as arbutin, glutathione, and yukinoshita extract, royal jelly, photosensitizer, cholesterol derivatives, cell activators such as calf blood extract, rough skin improver, nonyl acid wallenyl amide, Nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, caffeine, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, Examples include blood circulation promoters such as acetylcholine, verapamil, cephalanthin, γ-oryzanol and sodium dextran sulfate, skin astringents such as zinc oxide and tannic acid, and antiseborrheic agents such as sulfur and thianthol.

  Vitamins include vitamin A oil, retinol, retinol acetate, retinol palmitate, vitamin A2 such as riboflavin, riboflavin butyrate, flavin adenine nucleotide, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine tripalmi Vitamin B6 such as tate, vitamin B12 and derivatives thereof, vitamin B such as vitamin B15 and derivatives thereof, L-ascorbic acid, L-ascorbic acid dipalmitate, L-ascorbic acid-2-sodium sulfate, L- Vitamin C such as ascorbic acid phosphate diester dipotassium, vitamin D such as ergocalciferol, cholecalciferol, α-tocopherol, β-tocopherol, γ-tocopherol, dl-acetate Vitamin E such as tocopherol, dl-α-tocopherol nicotinate, dl-α-tocopherol succinate, nicotinic acid such as vitamin H, vitamin P, nicotinic acid, benzyl nicotinate, nicotinamide, calcium pantothenate, D -Pantothenic alcohols such as pantothenyl alcohol, pantothenyl ethyl ether, acetyl pantothenyl ethyl ether, and biotin. Examples of amino acids include glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, and tryptophan.Nucleic acids include deoxyribonucleic acid, and hormones include estradiol. , Etenyl estradiol and the like.

  Examples of the protein or protein degradation product include soy protein, silk fibroin, and elastin in addition to the gelatin and collagen described above.

  As a diluent (solvent), in addition to the above-mentioned lower alcohol, tetrachlorodifluoroethane, polysiloxane having 2 to 9 carbon atoms (for example, linear dimethylpolysiloxane having 2 to 9 carbon atoms, cyclic having 4 to 5 carbon atoms) Dimethylpolysiloxane, and those obtained by substituting some of these methyl groups with phenyl groups).

The cosmetic for skin of the present invention includes emulsions such as water-in-oil emulsions and oil-in-water emulsions.
The cosmetic for skin of the present invention can have various forms such as oil, cream, mousse, gel, wax, and stick according to the purpose of use.

  EXAMPLES Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited by these.

  The following block copolymers (B-1) to (B-4) were prepared as block copolymers (B) used in the following examples.

[Block copolymer (B-1)]
A block copolymer represented by the general formula (1).
[In the general formula (1), R ¹ represents a methyl group;
Y ¹ represents a group represented by the formula: —CH ₂ CH (CH ₃ ) CH ₂ —;
R ² is a group represented by the formula: —CH ₂ CH (CH ₃ ) CH ₂ —O— (C ₂ H ₄ O) ₁₄ —CH ₂ C (CH ₃ ) ═CH ₂ ;
a is 199;
b1 is 14;
b2 is 0;
c is 13;
The average molecular weight of the organopolysiloxane block is 14,900, and the organopolysiloxane block constitutes 95.7% by mass of the block copolymer (B-1);
The average molecular weight of the polyoxyalkylene block is 610;
The average molecular weight of this block copolymer (B-1) is 218,000. ]

[Block copolymer (B-2)]
A block copolymer represented by the general formula (1).
[In the general formula (1), R ¹ represents a methyl group;
Y ¹ represents a group represented by the formula: —CH ₂ CH (CH ₃ ) CH ₂ —;
R ² is represented by the formula: —CH ₂ CH (CH ₃ ) CH ₂ —O— (C ₂ H ₄ O) ₂₃ (C ₃ H ₆ O) ₆ —CH ₂ C (CH ₃ ) ═CH _2. Group;
a is 160;
b1 is 23;
b2 is 6;
c is 7;
The average molecular weight of the organopolysiloxane block is 12,000, and the organopolysiloxane block constitutes 88.7% by mass of this block copolymer (B-2);
The average molecular weight of the polyoxyalkylene block is 1,360;
The average molecular weight of this block copolymer (B-2) is 109,000. ]

[Block copolymer (B-3)]
A block copolymer represented by the general formula (1).
[However, in the general formula (1), R ¹ is a methyl group;
Y ¹ represents a group represented by the formula: —CH ₂ CH (CH ₃ ) CH ₂ —;
R ² is represented by the formula: —CH ₂ CH (CH ₃ ) CH ₂ —O— (C ₂ H ₄ O) ₂₀ (C ₃ H ₆ O) ₃₅ —CH ₂ C (CH ₃ ) ═CH _2. Group;
a is 141;
b1 is 20;
b2 is 35;
c is 24;
The average molecular weight of the organopolysiloxane block is 10,600, and the organopolysiloxane block constitutes 77.8% by mass of the block copolymer (B-3);
The average molecular weight of the polyoxyalkylene block is 2,900;
The average molecular weight of this block copolymer (B-3) is 343,000. ]

[Block copolymer (B-4)]
A block copolymer represented by the general formula (1).
[In the general formula (1), R ¹ represents a methyl group;
Y ¹ represents a group represented by the formula: —CH ₂ CH (CH ₃ ) CH ₂ —;
R ² is represented by the formula: —CH ₂ CH (CH ₃ ) CH ₂ —O— (C ₂ H ₄ O) ₄₆ (C ₃ H ₆ O) ₁₅ —CH ₂ C (CH ₃ ) ═CH _2. Group;
a is 385;
b1 is 46;
b2 is 15;
c is 29;
The average molecular weight of the organopolysiloxane block is 28,500, and the organopolysiloxane block constitutes 90.7% by mass of this block copolymer (B-4);
The average molecular weight of the polyoxyalkylene block is 2,900;
The average molecular weight of this block copolymer (B-4) is 949,000. ]

  The following modified silicones (b-1) and (b-2) were prepared as modified silicones used in the following comparative examples instead of the block copolymer (B).

[Modified silicone (b-1)]
A linear modified silicone (polyoxyalkylene-dimethylpolysiloxane alternating block copolymer) represented by the following chemical formula (1).

  In the modified silicone (b-1), the average molecular weight of the organopolysiloxane block is 3,100 (less than 10,500), and this organopolysiloxane block comprises 58.1% by mass of the modified silicone (b-1). The average molecular weight of the polyoxyalkylene block is 1,360; the average molecular weight of the modified silicone (b-1) is 10,300 (less than 50,000).

[Modified silicone (b-2)]
A linear modified silicone represented by the following chemical formula (2).

  In the modified silicone (b-2), the average molecular weight of the organopolysiloxane block is 3,100 (less than 10,500), and this organopolysiloxane block comprises 70.8% by mass of the modified silicone (b-2). The average molecular weight of the polyoxyalkylene block is 610; the average molecular weight of the modified silicone (b-2) is 4,200 (less than 50,000).

<Examples 1-2 and Comparative Examples 1-2 (preparation examples of lip gloss)>
In accordance with the formulation shown in Table 1 below, each component was sufficiently stirred, melted and mixed at 90 ° C., poured into a mold, and cooled and solidified in the mold to produce a lip gloss (skin cosmetic). . The obtained lip gloss was taken out of the mold and filled into a container.

  For each of the obtained lip glosses, 10 women with a makeup history of 10 years or more are panelists, and the spread at the time of application (extensibility), no stickiness, the degree of gloss (gloss), and the durability of the makeup effect [Evaluation as “good” when a state (makeup effect) similar to that immediately after application is maintained after 4 hours from application. Sensory evaluation of the following four items was performed. The evaluation criteria are as follows.

〔Evaluation criteria〕
“◎”: 9 or more people evaluated as good.
“◯”: 6 to 8 people evaluated as good.
“△”: 3 to 5 people evaluated as good.
“X”: 0 to 2 people evaluated as good.

[The unit of the numerical value is “part by mass”. (*) Indicates an oil component. ]

<Examples 3-6 and Comparative Examples 3-4 (preparation examples of lipstick)>
According to the formulation shown in Table 2 below, a lipstick (a skin cosmetic of the present invention) was produced as follows.
First, ceresin, microcrystalline wax, polyethylene powder, glyceryl tri-2-ethylhexanoate, glycerin triisostearate, block copolymer (B) or modified silicone (comparative example), liquid isoparaffin, and malic acid Diisostearyl, squalane, and vitamin E are heated and melt mixed, and then red 201, red 202, red 104 aluminum lake, iron oxide, and titanium oxide are added in a roll mill. Mix evenly, heat and remelt it, add fragrance and colored mica titanium, mix, deaerate, fill into a container, cool this to make lipstick (skin cosmetic) Manufactured.

  For each of the obtained lipsticks, 10 women with a makeup history of 10 years or more were panelists, the elongation at the time of application (extensibility), and the durability of the makeup effect (comparison at 4 hours after application and at the time of application) ) Sensory evaluation of two items. The evaluation criteria are as follows.

〔Evaluation criteria〕
“◎”: 8 or more people evaluated as good.
“◯”: 6 to 7 people evaluated as good.
“△”: 3 to 5 people evaluated as good.
“X”: 0 to 2 people evaluated as good.

[The unit of the numerical value is “part by mass”. (*) Indicates an oil component. ]

<Example 7 (Example of preparation of lotion)>
In accordance with Formulation A shown below, each component was sufficiently stirred and melted at 70 to 80 ° C., and then cooled to produce a lotion (skin cosmetic composition of the present invention). The lotion thus obtained was easy to apply because of its good elongation.

[Formulation A]
(1) Liquid paraffin (oil component) 2.0 parts by mass (2) Cetyl octoate (oil component) 10.0 parts by mass (3) Decamethylcyclopentasiloxane “VS-7158” (Nihon Unicar Co., Ltd.) 60.0 parts by mass (4) Block copolymer (B-1) 20.0 parts by mass (5) Methylphenylpolysiloxane (oil component) “FZ-209” (manufactured by Nippon Unicar Co., Ltd.) ... 8.0 parts by mass

<Example 8 (preparation example of sunscreen emulsion)>
In accordance with the formulation B shown below, a sunscreen emulsion (skin cosmetic of the present invention) was produced as follows.
First, each of the oil phase component [following (1) to (11)] and the aqueous phase component [following (12) to (13)] is heated to 60 ° C. and melted, and then the oil phase component (melt). An aqueous phase component (melt) was added to the mixture, emulsified with a homomixer, and then degassed and cooled to produce a sunscreen emulsion.
The sunscreen emulsion thus obtained had good elongation at the time of application and had a good feeling during use.

[Compound formulation B]
(1) 2-ethylhexyl paramethoxycinnamate: 5.0 parts by mass (2) Titanium dioxide (hydrophobized product): 5.0 parts by mass (3) Zinc oxide (hydrophobized product): 9.0 parts by mass Part (4) Squalane (oil component) 20.0 parts by mass (5) Decamethylcyclopentasiloxane 23.0 parts by mass (6) Block copolymer (B-1) 2.0 parts by mass (7) Glycerin diisostearate 2.0 parts by mass (8) Organically modified montmorillonite 0.5 parts by mass (9) Methyl paraoxybenzoate 0.05 parts by mass (10) Propylparaoxybenzoate 0.05 parts by mass (11) Perfume… appropriate amount
(12) Purified water: 28.4 parts by mass (13) 1,3-butylene glycol: 5.0 parts by mass

<Example 9 (preparation example of sun oil)>
In accordance with the formulation C shown below, sansu oil (skin cosmetic of the present invention) was produced as follows.
First, after thoroughly mixing isopropyl myristate, dimethylsiloxane, and block copolymer (B-1), 2-methoxyhexyl paramethoxycinnamate, liquid isoparaffin, antioxidant, and fragrance are added. The sun oil was produced by stirring the system. The sun oil thus obtained had good elongation at the time of application and had a good feeling of use.

[Formulation C]
(1) 2-methoxyhexyl paramethoxycinnamate 2.0 parts by mass (2) Liquid isoparaffin (oil-based component) 53.0 parts by mass (3) Isopropyl myristylate (oil-based component) 10.0 parts by mass (4 ) Dimethylsiloxane (10 mm ² / s) (oil-based component) 30.0 parts by mass (5) Block copolymer (B-1) 5.0 parts by mass (6) Antioxidant ... Appropriate amount (7) Fragrance ... Appropriate amount

<Example 10 (Preparation Example of Foundation)>
According to the formulation D shown below, a foundation (a skin cosmetic according to the present invention) was produced as follows.
First, bentonite is dispersed in propylene glycol to prepare a dispersion, and this dispersion is added to purified water and treated with a homomixer at 70 ° C., to which polyoxyethylene sorbitan monostearate and triethanolamine are added. In addition, the mixture was further stirred. Thereafter, talc, titanium dioxide, bengara, yellow iron oxide, and black iron oxide were added with stirring, and the mixture was homomixed at 70 ° C. Next, the preservative, stearic acid, isohexadecyl alcohol, glyceryl monostearate, liquid lanolin, liquid paraffin, and block copolymer (B-1) were uniformly melted at 70 to 80 ° C. The mixture was gradually added, homomixed at 70 ° C., cooled to 45 ° C., added with a fragrance, cooled to room temperature, and degassed to produce a foundation.
The foundation thus obtained had good elongation at the time of application and was excellent in the durability of the makeup effect (makeup lasting).

[Compound formulation D]
(1) Talc ... 3.0 parts by mass (2) Titanium dioxide ... 5.0 parts by mass (3) Bengala ... 0.5 parts by mass (4) Yellow iron oxide ... 1.4 parts by mass (5) Black iron oxide ... 0.1 parts by mass (6) Bentonite 0.5 parts by mass (7) Polyoxyethylene sorbitan monostearate 0.9 parts by mass (8) Triethanolamine 1.0 parts by mass (9) Propylene glycol 10 0.0 part by mass (10) Purified water: 41.4 parts by mass (11) Preservative: appropriate amount
(12) Stearic acid (oil-based component) ... 2.2 parts by mass (13) Isohexadecyl alcohol (oil-based component) ... 7.0 parts by mass (14) Glycerin monostearate ... 2.0 parts by mass (15) Liquid lanolin (Oil component): 2.0 parts by mass (16) Liquid paraffin (Oil component): 8.0 parts by mass (17) Block copolymer (B-1): 8.0 parts by mass (18) Fragrance: Appropriate amount

<Example 11 (Preparation example of mascara)>
According to the formulation E shown below, mascara (skin cosmetic of the present invention) was produced as follows.
First, light liquid isoparaffin, solid paraffin, block copolymer (B-1), lanolin wax, sorbitan sesquioleate, preservative, and perfume are mixed, and this mixture is heated to 70 ° C. did. On the other hand, after adding iron oxide (black) to purified water and dispersing with a homomixer, a polyacrylate emulsion was added, and this aqueous solution was heated to 70 ° C. The aqueous solution was added to the mixture and uniformly emulsified and dispersed with a homomixer, and then degassed and cooled to produce a mascara.
The mascara thus obtained was easy to adhere to the eyelashes, had a glossy feeling (gloss), and was excellent in the sustainability of the cosmetic effect.

[Formulation prescription E]
(1) Iron oxide (black) ... 10.0 parts by mass (2) Purified water ... 10.0 parts by mass (3) Polyacrylate emulsion ... 30.0 parts by mass (4) Light liquid isoparaffin (oil component) ... 30.0 parts by mass (5) Solid paraffin (oil-based component) 5.0 parts by mass (6) Block copolymer (B-1) ... 3.0 parts by mass (7) Lanolin wax (oil-based component) 0 parts by mass (8) Sorbitan sesquioleate: 4.0 parts by mass (9) Preservative: appropriate amount
(10) Fragrance ... Appropriate amount

<Example 12 (preparation example of sunscreen gel)>
In accordance with Formulation F shown below, a sunscreen gel (a cosmetic for skin of the present invention) was produced as follows.
First, the organically modified montmorillonite was added to a part of liquid paraffin to swell, and then dispersed uniformly by vigorous stirring. Next, to this dispersion, the remainder of liquid paraffin, octyl paramethoxycinnamate, olive oil, block copolymer (B-2), BHT (antioxidant), colorant, and fragrance Was added and mixed uniformly to produce a sunscreen gel.
The sunscreen gel thus obtained did not feel sticky and had good elongation during application.

[Formulation F]
(1) Octyl paramethoxycinnamate 2.0 parts by mass (2) Liquid paraffin (oil component) 68.0 parts by mass (3) Olive oil (oil component) 20.0 parts by mass (4) Organic modification Montmorillonite: 5.0 parts by mass (5) Block copolymer (B-2): 5.0 parts by mass (6) BHT (antioxidant): Appropriate amount
(7) Coloring agent ... appropriate amount
(8) Fragrance ... appropriate amount

<Example 13 (Example of preparation of massage cream)>
According to the formulation G shown below, a massage cream (skin cosmetic of the present invention) was produced as follows.
First, purified water, 1,3 butylene glycol, and borax were heated and mixed at 70 ° C. to prepare an aqueous solution. On the other hand, petrolatum, solid paraffin, liquid paraffin, block copolymer (B-2), and beeswax are mixed by heating, and then glycerol monostearate, POE (20) sorbitan monolaurate, An antiseptic, an antioxidant, and a fragrance were added and mixed and maintained at 70 ° C. The aqueous solution was gradually added to this mixture, pre-emulsified, and the emulsified particles were made uniform with a homomixer, and then deaerated and cooled to produce a massage cream.
The massage cream thus obtained did not have a sticky feeling and had a good elongation when applied.

[Formulation prescription G]
(1) Purified water ... 20.8 parts by mass (2) 1,3 butylene glycol ... 4.0 parts by mass (3) Borax ... 0.2 parts by mass (4) Petrolatum (oil component) ... 10.0 parts by mass (5) Solid paraffin (oil component): 5.0 parts by mass (6) Liquid paraffin (oil component): 41.0 parts by mass (7) Block copolymer (B-2): 5.0 parts by mass (8 ) Beeswax (oil-based component) ... 10.0 parts by mass (9) Glycerol monostearate ... 2.0 parts by mass (10) POE (20) Sorbitan monolaurate ... 2.0 parts by mass (11) Preservatives ... Appropriate amount
(12) Antioxidant: appropriate amount
(13) Fragrance ... Appropriate amount

The product form of the skin cosmetic of the present invention is not particularly limited, and can be used as various cosmetics. For example, it can be suitably used as lipstick, lip balm, lip gloss, lotion, eyeliner, mascara, foundation, undermake, UV protection cream, sun oil, sunscreen emulsion, sunscreen gel, massage cream, hair conditioner, etc. it can.

Claims (3)

(A) an oil component;
(B) A cosmetic for skin containing a polyoxyalkylene-organopolysiloxane alternating block copolymer represented by the following general formula (1).

[In the formula, R ¹ represents independently of one another, a monovalent hydrocarbon radical free of aliphatic unsaturation, a hydroxy group or an alkoxy group,
Y ¹ represents a divalent organic group,
R ² is independently of each other a hydrogen atom, a hydroxyl group, a substituted or unsubstituted monovalent hydrocarbon group, an alkoxy group, or a formula: —Y ¹ —O— (C ₂ H ₄ O) _b1 (C ₃ H ^{_{6 O) b2 -Y 2 (Y}} 2 represents a monovalent hydrocarbon group hydrogen atom or a substituted or unsubstituted.) with a group represented by,
a is an integer of 1 or more,
b1 is an integer of 1 or more,
b2 is 0 or an integer of 1 or more,
c is an integer of 1 or more.
The average molecular weight of the organopolysiloxane block represented by the formula:-(SiR ¹ ₂ O) _a SiR ¹ _2- is 10,500 or more,
The organopolysiloxane block constitutes 50 to 99% by mass of this block copolymer,
The average molecular weight of the polyoxyalkylene block represented by the formula: — (C ₂ H ₄ O) _b1 (C ₃ H ₆ O) _b2 — is 130 to 10,000,
The average molecular weight of this block copolymer is 50,000 or more. ]   The cosmetic for skin according to claim 1, comprising 0.1 to 300 parts by mass of the polyoxyalkylene-organopolysiloxane alternating block copolymer with respect to 100 parts by mass of the oil component. The skin cosmetic according to claim 1 or 2, which contains silicone oil as the oil component.