JP2005074676A - Porous printing element - Google Patents

Porous printing element Download PDF

Info

Publication number
JP2005074676A
JP2005074676A JP2003304921A JP2003304921A JP2005074676A JP 2005074676 A JP2005074676 A JP 2005074676A JP 2003304921 A JP2003304921 A JP 2003304921A JP 2003304921 A JP2003304921 A JP 2003304921A JP 2005074676 A JP2005074676 A JP 2005074676A
Authority
JP
Japan
Prior art keywords
printing
ink
parts
porous
hardness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2003304921A
Other languages
Japanese (ja)
Other versions
JP4495425B2 (en
Inventor
Hideki Murai
英樹 村井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shachihata Inc
Original Assignee
Shachihata Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shachihata Inc filed Critical Shachihata Inc
Priority to JP2003304921A priority Critical patent/JP4495425B2/en
Publication of JP2005074676A publication Critical patent/JP2005074676A/en
Application granted granted Critical
Publication of JP4495425B2 publication Critical patent/JP4495425B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Landscapes

  • Inking, Control Or Cleaning Of Printing Machines (AREA)
  • Printing Plates And Materials Therefor (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a porous printing element which has a non-collapsible printing part even under an applied excess pressing force; can prevent a printed image from feathering during initial imprinting due to the discharge of a surplus amount of ink; can obtain an irregularity-free deep and clear printed image; and is free from the deterioration of physical property over a long time. <P>SOLUTION: This porous printing element is of a three layer structure such as a printing part, an intermediate part and an ink holding part laminated in that order and has a capillary action relationship of the intermediate part>the printing part>the ink holding part. In addition, the printing part shows an utmost hardness among the three layers. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、インク内蔵タイプの浸透印に使用される連続気泡を有する多孔質印字体に関するものである。     The present invention relates to a porous printed body having open cells used for a penetrating mark with a built-in ink.

無数の連続気泡を有する多孔質体を印材とした多孔質印字体を用いた印判は、捺印の都度スタンプ台を使用することなく連続捺印できるようにした利便性の高いものであって、本出願人も実公昭31−002912号等を開示している。このような多孔質印字体は、比較的高粘度の顔料インキであっても、多量のインキを含有することができ、かつ、良好なインキ吐出量を誇っている。
しかし、従前の多孔質印字体は、無数の連続気泡を有するため硬度が低く、捺印時に過度の押圧力が印字体に加えられると印字面が圧潰されて吸蔵されているスタンプインキが過剰に流出して捺印される印字が太くなったり、滲んだりして、鮮明な捺印を行ない難い欠点があった。
そこで、このような欠点を解決し、印字体の硬度を向上させるために、本出願人はフェノール樹脂を配合した多孔質印字体(特公昭57−50675号)や、有機系合成繊維を混合した多孔質印字体(特開平08−230295号)を提案してきた。
しかしながら、無数の連続気泡を有するスポンジ状印字体でありながら、硬度を高く設定することは難題であると共に、前者は経時的にゴムとフェノール樹脂が分離し始め、スプリング性が低下したり、脆くなってひび割れたりして、多孔質印字体の物性が大きく低下する欠点があるし、後者はゴムと有機系合成繊維にもともと相溶性がなく、経時的にゴムが劣化してくると、脆弱性が増長され、ひび割れなど多孔質印字体の物性が大きく低下する欠点があった。
そこで、従来の添加剤を配合する以外のアプローチによる多孔質印字体の製造が望まれていた。
A stamp using a porous printed material made of a porous material having an infinite number of open cells can be continuously printed without using a stamp stand each time it is printed. Humans have also disclosed No. 31-002912. Such a porous printing body can contain a large amount of ink even if it is a pigment ink having a relatively high viscosity, and boasts a good ink discharge amount.
However, conventional porous prints have innumerable open cells and thus have low hardness, and if excessive pressure is applied to the prints during printing, the print surface is crushed and the stored stamp ink flows out excessively. As a result, the printed mark becomes thicker or smeared, and there is a drawback that it is difficult to perform clear marking.
Therefore, in order to solve such drawbacks and improve the hardness of the printing body, the present applicant mixed a porous printing body (Japanese Patent Publication No. 57-50675) blended with a phenol resin and an organic synthetic fiber. A porous printed body (Japanese Patent Laid-Open No. 08-230295) has been proposed.
However, while it is a sponge-like printed body having countless open cells, it is difficult to set the hardness high, and in the former, the rubber and the phenol resin begin to separate over time, and the spring property decreases or becomes brittle. The physical properties of the porous printed material are greatly reduced due to cracking, and the latter is not compatible with rubber and organic synthetic fibers. As a result, the physical properties of the porous printed material, such as cracks, are greatly reduced.
Therefore, it has been desired to produce a porous printed body by an approach other than blending conventional additives.

実公昭31−002912号公報Japanese Utility Model Publication No. 31-002912 特公昭57−050675号公報Japanese Examined Patent Publication No. 57-050675 特開平08−230295号公報Japanese Patent Application Laid-Open No. 08-230295

本発明は、過度の押圧力が加えられても印字部が圧潰されず、過剰なインキの吐出による初期捺印時の印影の滲みを防止でき、むらのない濃く鮮明な印影を得ることができ、かつ、長時間にわたって物性が低下しない多孔質印字体を提供するものである。   The present invention, even if an excessive pressing force is applied, the printed part is not crushed, can prevent the blurring of the imprint at the initial stamping due to excessive ink discharge, can obtain a dark and clear imprint without unevenness, And the porous printed body which a physical property does not fall over a long time is provided.

印字部、中間部、インキ保持部の順に三層構造からなる多孔質印字体であって、毛細管力が中間部>印字部>インキ保持部の関係を有し、かつ、三層の中で印字部の硬度が最も高いことを特徴とする多孔質印字体。   It is a porous printing body with a three-layer structure in the order of the printing part, intermediate part, and ink holding part, and the capillary force has a relationship of intermediate part> printing part> ink holding part, and printing is performed in three layers. A porous printed material characterized in that the hardness of the part is the highest.

本発明の多孔質印字体は、過剰なインキが中間部に蓄えられるため、印字部のインキ含有量を常に60〜80%程度の適量に保持することができ、よって過剰なインキの吐出による初期捺印時の印影の滲みを防止でき、むらのない濃く鮮明な印影を得ることができる。また、連続で捺印する場合は、ポンプ作用によって中間部から印字部へインキが供給されるので、印字部のインキ含有量を常に60〜80%程度の適量に保持することができ、滲みのない鮮明な印影を連続して得ることができる。また、中間部のインキ含有量が減少すると毛細管力によって、インキ保持部から中間部へインキが移行供給され、中間部は常に100%のインキ含有量を保持できる。
更に、インキ保持部の硬度が相対的に最も低くなるので、クッション作用が働いて柔らかな捺印感触を得ることができる。
Since the porous printing body of the present invention stores excess ink in the intermediate portion, the ink content of the printing portion can be always kept at an appropriate amount of about 60 to 80%, and therefore, the initial amount due to discharge of excessive ink can be maintained. It is possible to prevent blurring of the imprint at the time of stamping and obtain a dark and clear imprint with no unevenness. In the case of continuous printing, since the ink is supplied from the intermediate portion to the printing portion by the pump action, the ink content in the printing portion can always be kept at an appropriate amount of about 60 to 80%, and there is no bleeding. A clear imprint can be obtained continuously. Further, when the ink content in the intermediate portion is reduced, the ink is transferred from the ink holding portion to the intermediate portion by capillary force, and the intermediate portion can always maintain 100% ink content.
Furthermore, since the hardness of the ink holding part is relatively lowest, a cushioning action works and a soft printing feel can be obtained.

本発明の多孔質印字体は、無数の連続気泡を有する多孔質体からなる印字体であって、いわゆる浸透印と称される印判に使用されるものである。印判としては、マスター印字体の穴から日付コマを有する無端ベルト印字体を臨ませた回転印や、住所などを印字体に作成した住所印、氏名などを印字体に作成した氏名印等がある。
特に、本発明の多孔質印字体は、印字部、中間部、インキ保持部の順に三層構造からなる多孔質印字体であって、毛細管力が中間部>印字部>インキ保持部の関係を有し、かつ、三層の中で印字部の硬度が最も高いことを特徴としている。
The porous printed body of the present invention is a printed body composed of a porous body having innumerable open cells, and is used for a so-called penetrating stamp. Stamps include a rotation mark that faces an endless belt print body with date frames from a hole in the master print body, an address mark created on the print body with an address, a name stamp created on the print body, and the like. .
In particular, the porous printing body of the present invention is a porous printing body having a three-layer structure in the order of a printing portion, an intermediate portion, and an ink holding portion, and the capillary force has a relationship of intermediate portion> printing portion> ink holding portion. And the print portion has the highest hardness among the three layers.

従来の印字部とインキ保持部の二層構造からなる多孔質印字体は、印字部の毛細管力がインキ保持部の毛細管力より大きくなるように設定して、印字体の毛細管力を最大に発揮できるようにしているため、印字体のインキ含有量が常に100%となってしまい、初期捺印の際に印影が滲んでしまっていた。
そこで、本発明では中間部の毛細管力を最も大きくし、続いて印字部の毛細管力が大きく、インキ保持部の毛細管力が最も小さくなるように設定した。このように設定することによって、多孔質印字体に浸透印用インキを含浸させても過剰なインキが中間部に蓄えられるため、印字部のインキ含有量を常に60〜80%程度の適量に保持することができ、よって過剰なインキの吐出による初期捺印時の印影の滲みを防止でき、むらのない濃く鮮明な印影を得ることができることとなった。
また、連続で捺印する場合は、ポンプ作用によって中間部から印字部へインキが供給されるので、印字部のインキ含有量を常に60〜80%程度の適量に保持することができ、滲みのない鮮明な印影を連続して得ることができる。また、中間部のインキ含有量が減少すると毛細管力によって、インキ保持部から中間部へインキが移行供給され、中間部は常に100%のインキ含有量を保持できるのである。
各層の毛細管力の差異は、気孔率を大きくしたり小さくしたり変化させて設定したり、気孔径を大きくしたり小さくしたり変化させて設定し、生じさせている。
A porous print body consisting of a two-layer structure of a conventional print section and ink holding section is set so that the capillary force of the print section is greater than the capillary force of the ink hold section, and maximizes the capillary force of the print body. As a result, the ink content of the printed body was always 100%, and the imprint was blurred during the initial stamping.
Therefore, in the present invention, the capillary force at the intermediate portion is set to be the largest, the capillary force at the printing portion is subsequently increased, and the capillary force at the ink holding portion is set to be the smallest. By setting in this way, even if the porous printing body is impregnated with penetrating ink, excess ink is stored in the middle part, so the ink content of the printed part is always kept at an appropriate amount of about 60 to 80%. Therefore, blurring of the imprint at the initial printing due to excessive ink ejection can be prevented, and a dark and clear imprint with no unevenness can be obtained.
In the case of continuous printing, since the ink is supplied from the intermediate portion to the printing portion by the pump action, the ink content in the printing portion can always be kept at an appropriate amount of about 60 to 80%, and there is no bleeding. A clear imprint can be obtained continuously. Further, when the ink content in the intermediate portion is reduced, the ink is transferred from the ink holding portion to the intermediate portion by capillary force, and the intermediate portion can always maintain 100% ink content.
The difference in capillary force between layers is set by changing the porosity to be larger or smaller, or by setting the pore diameter to be larger or smaller.

また、本発明では、スプリング式硬さ試験C型硬度計の測定値における硬度が、印字部と中間部とインキ保持部の三層の中で印字部が最も高くなるように設定した。中間部とインキ保持部の硬度はどちらが高くても構わないし、また同一の硬度でも良いが、両者とも印字部より低くなければならない。このように設定することによって、中間部及びインキ保持部のクッション作用が働いて柔らかな捺印感触を得ることができることとなる。   Further, in the present invention, the hardness in the measurement value of the spring type hardness test C-type hardness tester is set so that the printed portion is the highest among the three layers of the printed portion, the intermediate portion, and the ink holding portion. Either the intermediate part or the ink holding part may have a higher hardness or the same hardness, but both must be lower than the printing part. By setting in this way, the cushioning action of the intermediate part and the ink holding part works, and a soft seal feeling can be obtained.

ここで、本発明の多孔質印字体は、天然ゴム、SBR、NBR、EPDM、シリコーンゴム等の合成ゴム、ポリエチレン、ポリプロピレン、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリ乳酸等の熱可塑性樹脂、ポリオレフィン系熱可塑性エラストマー、ポリウレタン系熱可塑性エラストマー等の熱可塑性エラストマー、フェノール樹脂等の熱硬化性樹脂など印判用印字体として知られている原材料全てを用いることができ、これら原材料を塩化ナトリウムや炭酸カルシウムなどの可溶材と混練し加硫又は溶融したのち可溶材を溶出して多孔質体とする溶出法や、原材料を発泡材と混練し加硫又は溶融して多孔質体とする発泡法や、粒子化した原材料を加熱圧縮して多孔質体とする燒結法などによって得ることができる。この際、印字部、中間部、インキ保持部の順に三層構造とする必要があり、各層の毛細管力が中間部>印字部>インキ保持部の関係となるように、気孔率や気孔径をそれぞれ調節して毛細管力の差異を生じさせている。また、各層の硬度が印字部>中間部>インキ保持部、印字部>中間部=インキ保持部、印字部>インキ保持部>中間部、の中のどれかの関係となるように多孔質印字体の組成をそれぞれ調節して硬度の差異を生じさせている。
また、本発明に用いられる浸透印用インキは、顔料、染料の着色剤を問わず、揮発性油性インキ、不揮発性油性インキ、水性インキなど印判用インキとして知られているもの全てを用いることができる。
Here, the porous printed body of the present invention includes natural rubber, SBR, NBR, EPDM, silicone rubber and other synthetic rubbers, thermoplastic resins such as polyethylene, polypropylene, polyethylene terephthalate, polybutylene terephthalate, polylactic acid, and polyolefin-based heat. All raw materials known as printing materials for printing such as thermoplastic elastomers, thermoplastic elastomers such as polyurethane-based thermoplastic elastomers, and thermosetting resins such as phenolic resins can be used. An elution method in which a soluble material is kneaded and vulcanized or melted, and then a soluble material is eluted to form a porous body, or a raw material is kneaded with a foaming material and vulcanized or melted to form a porous body, or particleized It can be obtained by, for example, a sintering method in which a raw material is heated and compressed to form a porous body. At this time, it is necessary to have a three-layer structure in the order of the printing portion, the intermediate portion, and the ink holding portion, and the porosity and the pore diameter are set so that the capillary force of each layer is in the relationship of intermediate portion> printing portion> ink holding portion. Each is adjusted to create a difference in capillary force. In addition, the porous mark is set so that the hardness of each layer is in the following relationship: printing part> intermediate part> ink holding part, printing part> intermediate part = ink holding part, printing part> ink holding part> intermediate part The composition of the font is adjusted to create a difference in hardness.
The penetrating ink used in the present invention is not limited to pigments and dye colorants, and all known inks for stamps such as volatile oil inks, nonvolatile oil inks and water-based inks may be used. it can.

以下、本発明の多孔質印字体を実施例を用いながら詳細に説明する。図1は実施例1を図示したものである。
本実施例の多孔質印字体は、NBR製多孔質ゴムの印字部1とNBR製多孔質ゴムの中間部2とNBR製多孔質ゴムのインキ保持部3の三層構造となっており、印字部1は厚さ0.5mm、硬度60°(スプリング式硬さ試験C型硬度計の測定値)、気孔率70%、気孔径40〜60μmに設定してあり、中間部2は厚さ1.0mm、硬度50°(スプリング式硬さ試験C型硬度計の測定値)、気孔率80%、気孔径30〜40μmに設定してあり、インキ保持部3は厚さ2.0mm、硬度40°(スプリング式硬さ試験C型硬度計の測定値)、気孔率90%、気孔径150〜250μmに設定してあって、毛細管力が中間部>印字部>インキ保持部の関係を有し、かつ、硬度が印字部>中間部>インキ保持部の関係を有するように設定してある。
具体的には、次のように製造した。
原料NBR100部、硫黄5部、亜鉛華5部、加硫促進剤5部、軟化剤30部、カーボンブラック50部、老化防止剤2部、40〜60μmの塩化ナトリウム500部、50〜60μmのバレイショデンプン100部を混練してマスターバッチAとし、これを厚さ0.5mmの平板状のシートAとした。これとは別に、原料NBR100部、硫黄5部、亜鉛華5部、加硫促進剤5部、軟化剤30部、カーボンブラック50部、老化防止剤2部、30〜40μmの塩化ナトリウム700部、30〜40μmのバレイショデンプン100部を加え混練してマスターバッチBとし、これを厚さ1.0mmの平板状のシートBとした。また、これとは別に、原料NBR100部、硫黄5部、亜鉛華5部、加硫促進剤5部、軟化剤30部、カーボンブラック50部、老化防止剤2部、150〜250μmの塩化ナトリウム900部、70〜100μmのバレイショデンプン100部を加え混練してマスターバッチCとし、これを厚さ2.0mmの平板状のシートCとした。
次に、シートA、シートB、シートCの順番で重ね合わせ、これを平滑な金型内に収容し、次いで、200kg/cm程度の圧力を加えて熱盤間に挟圧し、120℃の温度下で60分間加硫した。加硫後離型して、塩化ナトリウム、バレイショデンプンが完全に除去されるまで充分に水洗し、脱水乾燥して多孔質ゴムシートとした。
このようにして製造された多孔質ゴムシートは、シートAとシートBとシートCが一体化した一枚のシートとなり、シートA側から炭酸ガスレーザ加工機にて深度1.0mmまで彫刻した後、所要のサイズに切断すると、シートC部分は多量のインキを吸蔵するインキ保持部をなし、シートA部分は印面を形成した印字部をなした多孔質ゴム印字体を得ることができた。
Hereinafter, the porous printed body of the present invention will be described in detail with reference to Examples. FIG. 1 illustrates the first embodiment.
The porous printing body of this example has a three-layer structure of a printing part 1 made of NBR porous rubber, an intermediate part 2 of NBR porous rubber, and an ink holding part 3 made of NBR porous rubber. Part 1 has a thickness of 0.5 mm, a hardness of 60 ° (measured by a spring-type hardness test C-type hardness meter), a porosity of 70%, and a pore diameter of 40 to 60 μm. 0.0 mm, hardness 50 ° (measured value of spring type hardness test C-type hardness meter), porosity 80%, pore diameter 30-40 μm, ink holding part 3 is 2.0 mm thick, hardness 40 ° (Spring hardness test C-type hardness tester), porosity 90%, pore diameter 150-250μm, capillary force has the relationship of middle part> printing part> ink holding part In addition, the hardness is set to have a relationship of printing portion> intermediate portion> ink holding portion.
Specifically, it was manufactured as follows.
Raw material NBR 100 parts, sulfur 5 parts, zinc white 5 parts, vulcanization accelerator 5 parts, softener 30 parts, carbon black 50 parts, anti-aging agent 2 parts, 40-60 μm sodium chloride 500 parts, 50-60 μm potato 100 parts of starch was kneaded to prepare a master batch A, which was a flat sheet A having a thickness of 0.5 mm. Apart from this, the raw material NBR 100 parts, sulfur 5 parts, zinc white 5 parts, vulcanization accelerator 5 parts, softener 30 parts, carbon black 50 parts, anti-aging agent 2 parts, 30-40 μm sodium chloride 700 parts, 100 parts of potato starch having a size of 30 to 40 μm was added and kneaded to prepare a master batch B, which was a flat sheet B having a thickness of 1.0 mm. Separately, the raw material NBR 100 parts, sulfur 5 parts, zinc white 5 parts, vulcanization accelerator 5 parts, softener 30 parts, carbon black 50 parts, anti-aging agent 2 parts, sodium chloride 900 of 150-250 μm Part, 100 parts of 70-100 μm potato starch was added and kneaded to make a master batch C, which was a flat sheet C having a thickness of 2.0 mm.
Next, the sheet A, the sheet B, and the sheet C are overlapped in this order, and this is accommodated in a smooth mold. Then, a pressure of about 200 kg / cm 2 is applied and sandwiched between the heating plates, Vulcanization was carried out for 60 minutes under temperature. After vulcanization, the mold was released, washed thoroughly with water until sodium chloride and potato starch were completely removed, dehydrated and dried to obtain a porous rubber sheet.
The porous rubber sheet produced in this way becomes a single sheet in which the sheet A, the sheet B, and the sheet C are integrated, and after engraving from the sheet A side to a depth of 1.0 mm by a carbon dioxide laser processing machine, When cut to the required size, the sheet C part formed an ink holding part that occludes a large amount of ink, and the sheet A part obtained a porous rubber printed body having a printing part on which a printing surface was formed.

次に、当該多孔質ゴム印字体に500〜2000mPa・S(25℃)の高粘度の浸透印用インキを吸蔵させたところ、印字部の過剰なインキは中間部に吸収され、印字部のインキ含有量を60〜80%程度に保持することができ、中間部及びインキ保持部は100%のインキ含有量とすることができた。次に、捺印したところ、印字部のインキ含有量が若干少なめなので、過剰なインキの吐出による初期捺印時の印影の滲みもなく、むらのない濃く鮮明な印影を得ることができた。
また、捺印後はポンプ作用によって中間部から印字部へインキが供給されるので、印字部のインキ含有量を常に60〜80%程度の適量に保持することができ、連続で捺印しても滲みのない鮮明な印影を連続して得ることができた。
また、中間部のインキ含有量が減少すると毛細管力によって、インキ保持部から中間部へインキが移行供給されるので、中間部は常に100%のインキ含有量を保持できた。
また、印字部の硬度が最も硬いので、シャープな輪郭の印影を得ることができ、続いて中間部、インキ保持部と硬度が小さくなっているので、両者のクッション作用が働いて柔らかな捺印感触を得ることができると共に、中間部から印字部へのポンプ作用を妨げることはなかった。
Next, when the porous rubber printing body is filled with 500 to 2000 mPa · S (25 ° C.) high-viscosity ink, the excess ink in the printing area is absorbed in the middle area, and the ink content in the printing area is contained. The amount could be maintained at about 60 to 80%, and the intermediate portion and the ink holding portion could have an ink content of 100%. Next, as a result of printing, since the ink content in the printed portion was slightly less, there was no blurring of the imprint at the initial printing due to excessive ink ejection, and a dark and clear imprint with no unevenness could be obtained.
In addition, after printing, ink is supplied from the intermediate part to the printing part by the pump action, so that the ink content of the printing part can always be kept at an appropriate amount of about 60 to 80%, and even if it is continuously printed, the ink bleeds. It was possible to obtain a clear imprint without any defects.
Further, when the ink content in the intermediate part is reduced, the ink is transferred from the ink holding part to the intermediate part by capillary force, so that the intermediate part can always keep the ink content of 100%.
In addition, since the hardness of the printed part is the hardest, it is possible to obtain a sharply imprinted image, and since the hardness of the intermediate part and the ink holding part is small, the cushioning action of both parts works, and the soft impression of printing And the pumping action from the intermediate part to the printing part was not hindered.

図2に示す本実施例2の多孔質印字体は、SBR製多孔質ゴムの印字部11とSBR製多孔質ゴムの中間部12とSBR製多孔質ゴムのインキ保持部13の三層構造となっており、印字部1は厚さ0.5mm、硬度60°(スプリング式硬さ試験C型硬度計の測定値)、気孔率70%、気孔径40〜60μmに設定してあり、中間部2は厚さ1.0mm、硬度40°(スプリング式硬さ試験C型硬度計の測定値)、気孔率80%、気孔径30〜40μmに設定してあり、インキ保持部3は厚さ2.0mm、硬度50°(スプリング式硬さ試験C型硬度計の測定値)、気孔率90%、気孔径150〜250μmに設定してあって、毛細管力が中間部>印字部>インキ保持部の関係を有し、かつ、硬度が印字部>インキ保持部>中間部の関係を有するように設定してある。
具体的には、次のように製造した。
原料SBR100部、硫黄5部、亜鉛華5部、加硫促進剤5部、軟化剤30部、カーボンブラック50部、老化防止剤2部、40〜60μmの塩化ナトリウム500部、50〜60μmのバレイショデンプン100部を混練してマスターバッチAとし、これを厚さ0.5mmの平板状のシートAとした。これとは別に、原料SBR100部、硫黄5部、亜鉛華5部、加硫促進剤5部、軟化剤30部、カーボンブラック50部、老化防止剤2部、30〜40μmの塩化ナトリウム900部、30〜40μmのバレイショデンプン100部を加え混練してマスターバッチBとし、これを厚さ1.0mmの平板状のシートBとした。また、これとは別に、原料SBR100部、硫黄5部、亜鉛華5部、加硫促進剤5部、軟化剤30部、カーボンブラック50部、老化防止剤2部、150〜250μmの塩化ナトリウム500部、70〜100μmのバレイショデンプン100部を加え混練してマスターバッチCとし、これを厚さ2.0mmの平板状のシートCとした。
次に、シートA、シートB、シートCの順番で重ね合わせ、これを平滑な金型内に収容し、次いで、200kg/cm程度の圧力を加えて熱盤間に挟圧し、120℃の温度下で60分間加硫した。加硫後離型して、塩化ナトリウム、バレイショデンプンが完全に除去されるまで充分に水洗し、脱水乾燥して多孔質ゴムシートとした。
このようにして製造された多孔質ゴムシートは、シートAとシートBとシートCが一体化した一枚のシートとなり、シートA側から炭酸ガスレーザ加工機にて深度1.5mmまで彫刻した後、所要のサイズに切断すると、シートC部分は多量のインキを吸蔵するインキ保持部をなし、シートA部分は印面を形成した印字部をなした多孔質ゴム印字体を得ることができた。
The porous printing body of Example 2 shown in FIG. 2 has a three-layer structure of a printing part 11 made of SBR porous rubber, an intermediate part 12 made of SBR porous rubber, and an ink holding part 13 made of SBR porous rubber. The printing portion 1 is set to have a thickness of 0.5 mm, a hardness of 60 ° (measured value of a spring type hardness test C-type hardness meter), a porosity of 70%, and a pore diameter of 40 to 60 μm. 2 is set to a thickness of 1.0 mm, a hardness of 40 ° (measured value of a spring-type hardness test C-type hardness meter), a porosity of 80%, and a pore diameter of 30 to 40 μm. 0.0 mm, hardness 50 ° (measured value of spring type hardness test C-type hardness meter), porosity 90%, pore diameter 150-250 μm, capillary force is intermediate part> printing part> ink holding part And the hardness has a relationship of printing part> ink holding part> intermediate part It is the sea urchin set.
Specifically, it was manufactured as follows.
Raw material SBR 100 parts, sulfur 5 parts, zinc white 5 parts, vulcanization accelerator 5 parts, softener 30 parts, carbon black 50 parts, anti-aging agent 2 parts, 40-60 μm sodium chloride 500 parts, 50-60 μm potato 100 parts of starch was kneaded to prepare a master batch A, which was a flat sheet A having a thickness of 0.5 mm. Separately from this, the raw material SBR 100 parts, sulfur 5 parts, zinc white 5 parts, vulcanization accelerator 5 parts, softener 30 parts, carbon black 50 parts, anti-aging agent 2 parts, 30-40 μm sodium chloride 900 parts, 100 parts of potato starch having a size of 30 to 40 μm was added and kneaded to prepare a master batch B, which was a flat sheet B having a thickness of 1.0 mm. Separately from this, the raw material SBR 100 parts, sulfur 5 parts, zinc white 5 parts, vulcanization accelerator 5 parts, softener 30 parts, carbon black 50 parts, anti-aging agent 2 parts, sodium chloride 500 to 150-250 μm Part, 100 parts of 70-100 μm potato starch was added and kneaded to make a master batch C, which was a flat sheet C having a thickness of 2.0 mm.
Next, the sheet A, the sheet B, and the sheet C are overlapped in this order, and this is accommodated in a smooth mold. Then, a pressure of about 200 kg / cm 2 is applied and sandwiched between the heating plates, Vulcanization was carried out for 60 minutes under temperature. After vulcanization, the mold was released, washed thoroughly with water until sodium chloride and potato starch were completely removed, dehydrated and dried to obtain a porous rubber sheet.
The porous rubber sheet produced in this way becomes a single sheet in which the sheet A, the sheet B, and the sheet C are integrated, and after engraving from the sheet A side to a depth of 1.5 mm with a carbon dioxide laser processing machine, When cut to the required size, the sheet C part formed an ink holding part that occludes a large amount of ink, and the sheet A part could obtain a porous rubber printed body having a printing part on which a printing surface was formed.

次に、当該多孔質ゴム印字体に500〜2000mPa・S(25℃)の高粘度の浸透印用インキを吸蔵させたところ、印字部の過剰なインキは中間部に吸収され、印字部のインキ含有量を60〜80%程度に保持することができ、中間部及びインキ保持部は100%のインキ含有量とすることができた。次に、捺印したところ、印字部のインキ含有量が若干少なめなので、過剰なインキの吐出による初期捺印時の印影の滲みもなく、むらのない濃く鮮明な印影を得ることができた。
また、捺印後はポンプ作用によって中間部から印字部へインキが供給されるので、印字部のインキ含有量を常に60〜80%程度の適量に保持することができ、連続で捺印しても滲みのない鮮明な印影を連続して得ることができた。
また、中間部のインキ含有量が減少すると毛細管力によって、インキ保持部から中間部へインキが移行供給されるので、中間部は常に100%のインキ含有量を保持できた。
また、印字部の硬度が最も硬いので、シャープな輪郭の印影を得ることができ、また中間部の硬度が最も小さくなっているので、中間部のクッション作用が働いて柔らかな捺印感触を得ることができると共に、中間部から印字部へのポンプ作用を妨げることはなかった。
以上の通り、本実施例の多孔質印字体は、インキ吸蔵量も充分で、滲みやかすれのない鮮明な捺印を長期間にわたって行なうことができた。
Next, when the porous rubber printing body is filled with 500 to 2000 mPa · S (25 ° C.) high-viscosity ink, the excess ink in the printing area is absorbed in the middle area, and the ink content in the printing area is contained. The amount could be maintained at about 60 to 80%, and the intermediate portion and the ink holding portion could have an ink content of 100%. Next, as a result of printing, since the ink content in the printed portion was slightly less, there was no blurring of the imprint at the initial printing due to excessive ink ejection, and a dark and clear imprint with no unevenness could be obtained.
In addition, after printing, ink is supplied from the intermediate part to the printing part by the pump action, so that the ink content of the printing part can always be kept at an appropriate amount of about 60 to 80%, and even if it is continuously printed, the ink bleeds. It was possible to obtain a clear imprint without any defects.
Further, when the ink content in the intermediate part is reduced, the ink is transferred from the ink holding part to the intermediate part by capillary force, so that the intermediate part can always keep the ink content of 100%.
In addition, since the hardness of the printed part is the hardest, it is possible to obtain an imprint with a sharp outline, and since the hardness of the intermediate part is the smallest, the cushioning action of the intermediate part works to obtain a soft printing feel. The pumping action from the intermediate part to the printing part was not hindered.
As described above, the porous printed material of this example had a sufficient ink occlusion amount, and was able to perform clear printing without bleeding or fading over a long period of time.

実施例1の断面イメージ図。FIG. 3 is a cross-sectional image diagram of Example 1. 実施例2の断面イメージ図。FIG. 6 is a cross-sectional image diagram of Example 2.

符号の説明Explanation of symbols

1 印字部
2 中間部
3 インキ保持部
11 印字部
12 中間部
13 インキ保持部
DESCRIPTION OF SYMBOLS 1 Printing part 2 Intermediate part 3 Ink holding part 11 Printing part 12 Intermediate part 13 Ink holding part

Claims (1)

印字部、中間部、インキ保持部の順に三層構造からなる多孔質印字体であって、毛細管力が中間部>印字部>インキ保持部の関係を有し、かつ、三層の中で印字部の硬度が最も高いことを特徴とする多孔質印字体。   It is a porous printing body with a three-layer structure in the order of the printing part, intermediate part, and ink holding part, and the capillary force has a relationship of intermediate part> printing part> ink holding part, and printing is performed in three layers. A porous printed material characterized in that the hardness of the part is the highest.
JP2003304921A 2003-08-28 2003-08-28 Porous printed material Expired - Fee Related JP4495425B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2003304921A JP4495425B2 (en) 2003-08-28 2003-08-28 Porous printed material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2003304921A JP4495425B2 (en) 2003-08-28 2003-08-28 Porous printed material

Publications (2)

Publication Number Publication Date
JP2005074676A true JP2005074676A (en) 2005-03-24
JP4495425B2 JP4495425B2 (en) 2010-07-07

Family

ID=34408480

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2003304921A Expired - Fee Related JP4495425B2 (en) 2003-08-28 2003-08-28 Porous printed material

Country Status (1)

Country Link
JP (1) JP4495425B2 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1731323A3 (en) * 2005-06-07 2007-01-17 Brother Kogyo Kabushiki Kaisha Printing material, method of manufacturing the printing material and stamp having the printing material
JP2007107113A (en) * 2005-10-11 2007-04-26 Hiroyuki Yobiko Method for fixing pattern with stamp, spraying agent to be used therefor, stamp and spraying agent
JP2012252942A (en) * 2011-06-06 2012-12-20 Yazaki Corp Device and method for marking electric wire
JP2013256031A (en) * 2012-06-11 2013-12-26 Shachihata Inc Invertible ink stamp
JP2013256032A (en) * 2012-06-11 2013-12-26 Shachihata Inc Invertible ink stamp
CN103481684A (en) * 2012-06-11 2014-01-01 沙奇哈塔株式会社 Invertible ink stamp and method of manufacturing same
JP2014240154A (en) * 2013-06-12 2014-12-25 シヤチハタ株式会社 Ink self-feeding type seal

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50919A (en) * 1973-05-07 1975-01-08
JPS57188391A (en) * 1981-05-15 1982-11-19 Bando Chem Ind Ltd Porous material for stamp and manufacture thereof
JPH09327963A (en) * 1996-06-07 1997-12-22 Shiyachihata Kogyo Kk Endless printing belt for rotary rubber seal
JP2000247006A (en) * 1999-03-04 2000-09-12 Shachihata Inc Stamp
JP2000280592A (en) * 1999-03-31 2000-10-10 Brother Ind Ltd Stamp unit
JP2004195736A (en) * 2002-12-17 2004-07-15 Mitsubishi Pencil Co Ltd Printing body for saturation seal and its manufacturing method
JP2004268384A (en) * 2003-03-07 2004-09-30 Brother Ind Ltd Stamping unit

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50919A (en) * 1973-05-07 1975-01-08
JPS57188391A (en) * 1981-05-15 1982-11-19 Bando Chem Ind Ltd Porous material for stamp and manufacture thereof
JPH09327963A (en) * 1996-06-07 1997-12-22 Shiyachihata Kogyo Kk Endless printing belt for rotary rubber seal
JP2000247006A (en) * 1999-03-04 2000-09-12 Shachihata Inc Stamp
JP2000280592A (en) * 1999-03-31 2000-10-10 Brother Ind Ltd Stamp unit
JP2004195736A (en) * 2002-12-17 2004-07-15 Mitsubishi Pencil Co Ltd Printing body for saturation seal and its manufacturing method
JP2004268384A (en) * 2003-03-07 2004-09-30 Brother Ind Ltd Stamping unit

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1731323A3 (en) * 2005-06-07 2007-01-17 Brother Kogyo Kabushiki Kaisha Printing material, method of manufacturing the printing material and stamp having the printing material
JP2007107113A (en) * 2005-10-11 2007-04-26 Hiroyuki Yobiko Method for fixing pattern with stamp, spraying agent to be used therefor, stamp and spraying agent
JP2012252942A (en) * 2011-06-06 2012-12-20 Yazaki Corp Device and method for marking electric wire
JP2013256031A (en) * 2012-06-11 2013-12-26 Shachihata Inc Invertible ink stamp
JP2013256032A (en) * 2012-06-11 2013-12-26 Shachihata Inc Invertible ink stamp
CN103481684A (en) * 2012-06-11 2014-01-01 沙奇哈塔株式会社 Invertible ink stamp and method of manufacturing same
JP2014240154A (en) * 2013-06-12 2014-12-25 シヤチハタ株式会社 Ink self-feeding type seal

Also Published As

Publication number Publication date
JP4495425B2 (en) 2010-07-07

Similar Documents

Publication Publication Date Title
CA1105213A (en) Printing material composed of open-cell sponge rubber and process for preparation thereof
NO140659B (en) MARKING DEVICE.
GB2235654A (en) Picture forming apparatus.
JP2989453B2 (en) Porous rubber stamp with continuous pores
JP4495425B2 (en) Porous printed material
US6119596A (en) Pre-inked marking structures and method of assembling same to a stamped mount
DE2421765B2 (en) Stamp material based on natural or synthetic rubber
JP2005096154A (en) Self-inking rubber stamp
ATE406266T1 (en) METHOD FOR PRODUCING INK-CONTAINING STAMPS AND STAMP ELEMENT
JP5552610B2 (en) Method for producing molded article made of porous synthetic resin
JP7403764B2 (en) Connected seal stamp
JP5464461B2 (en) Porous rubber stamp having open cells and method for producing the same
JP4101671B2 (en) Porous rubber print with open cells
JP4847066B2 (en) Manufacturing method of stamp materials
GB2388817A (en) A porous resin stamp containing phthalocyanine pigments, and a method of manufacturing the same
JP3715042B2 (en) Rubber print
JP2000198259A (en) Rubber stamp and manufacture thereof
JPS5929606B2 (en) Method for manufacturing sponge rubber body with open cells
US6862987B2 (en) Porous resin stamp
JP2001205911A (en) Color stamp for continuous stamping
JPS5928193B2 (en) Sponge rubber printed material with open cells
JP2004090546A (en) Porous rubber stamping body with open cell
JPS5923008Y2 (en) porous rubber stamp
JP6094942B2 (en) Porous rubber print
JP3660071B2 (en) Rubber printed body and method for producing the same

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060711

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20080326

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20090817

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20100329

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20100409

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

Ref document number: 4495425

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130416

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130416

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130416

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140416

Year of fee payment: 4

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees