JP2005071755A5 - - Google Patents

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JP2005071755A5
JP2005071755A5 JP2003298981A JP2003298981A JP2005071755A5 JP 2005071755 A5 JP2005071755 A5 JP 2005071755A5 JP 2003298981 A JP2003298981 A JP 2003298981A JP 2003298981 A JP2003298981 A JP 2003298981A JP 2005071755 A5 JP2005071755 A5 JP 2005071755A5
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water
conductive layer
repellent conductive
component
polymer electrolyte
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JP2003298981A
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JP4301397B2 (en
JP2005071755A (en
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高分子電解質膜と、
前記高分子電解質膜の両側のそれぞれに配置された2つの電極とを備え、
前記2つの電極の少なくとも一方の電極は、前記高分子電解質膜側から順に配置された、触媒層と、所定の撥水性と所定の接着性を有する樹脂を樹脂主成分とする第二の撥水性導電層と、前記所定の撥水性よりも強い撥水性と前記所定の接着性よりも弱い接着性を有する樹脂を樹脂主成分とする第一の撥水性導電層と、ガス拡散層で構成されており、
前記第一の撥水性導電層の樹脂主成分は、テトラフルオロエチレン成分またはテトラフルオロエチレンの同族体の共重合体成分であり、
前記第二の撥水性導電層の樹脂主成分は、ポリフッ化ビニリデン成分である、燃料電池用膜電極接合体。
A polymer electrolyte membrane;
Two electrodes disposed on both sides of the polymer electrolyte membrane,
At least one electrode of the two electrodes is a second water repellency mainly composed of a resin having a catalyst layer and a predetermined water repellency and a predetermined adhesive property, which are arranged in order from the polymer electrolyte membrane side. A conductive layer, a first water-repellent conductive layer mainly composed of a resin having water repellency stronger than the predetermined water repellency and adhesiveness weaker than the predetermined adhesiveness, and a gas diffusion layer. And
The resin main component of the first water-repellent conductive layer is a tetrafluoroethylene component or a copolymer component of a homolog of tetrafluoroethylene,
The fuel cell membrane electrode assembly , wherein the resin main component of the second water repellent conductive layer is a polyvinylidene fluoride component .
前記それぞれの電極のうちのカソード側の電極は、
前記高分子電解質膜側から順に配置された、前記触媒層と、前記第二の撥水性導電層と、前記第一の撥水性導電層と、前記ガス拡散層で構成されている、請求項1記載の燃料電池用膜電極接合体。
Of the respective electrodes, the cathode side electrode is:
The polymer electrolyte membrane side of disposed in this order, and the catalyst layer, the a second water repellent conductive layer, wherein the first water repellent conductive layer, and a said gas diffusion layer, claim 1 fuel cell membrane electrode assembly of serial placement.
高分子電解質膜と、
前記高分子電解質膜の両側のそれぞれに配置された2つの電極とを備え、
前記2つの電極の少なくとも一方の電極は、前記高分子電解質膜側から順に配置された、触媒層と、ポリフッ化ビニリデン成分とポリテトラフルオロエチレン成分を樹脂主成分とする撥水性導電層と、ガス拡散層で構成されている、燃料電池用膜電極接合体。
A polymer electrolyte membrane;
Two electrodes disposed on both sides of the polymer electrolyte membrane,
At least one of the two electrodes includes a catalyst layer, a water repellent conductive layer mainly composed of a polyvinylidene fluoride component and a polytetrafluoroethylene component, and a gas, arranged in order from the polymer electrolyte membrane side. A membrane electrode assembly for a fuel cell, comprising a diffusion layer.
前記2つの電極のうちのカソード側の電極は、
前記高分子電解質膜側から順に配置された、前記触媒層と、前記撥水性導電層と、前記ガス拡散層で構成されている、請求項に記載の燃料電池用膜電極接合体。
Of the two electrodes, the cathode side electrode is:
The membrane electrode assembly for a fuel cell according to claim 3 , comprising the catalyst layer, the water-repellent conductive layer, and the gas diffusion layer, which are arranged in order from the polymer electrolyte membrane side.
両面に触媒層を形成させた高分子電解質膜の両側から、撥水性導電層を表面に形成させた2つのガス拡散層を、それぞれ、前記触媒層と前記撥水性導電層が向き合うように熱圧着法により接合する、燃料電池用膜電極接合体の製造方法において、
前記撥水性導電層を表面に形成させた2つの前記ガス拡散層の少なくとも一方の前記撥水性導電層は、前記ガス拡散層側から順に、所定の撥水性と所定の接着性を有する樹脂を樹脂主成分とする第一の撥水性導電層と、前記所定の撥水性よりも弱い撥水性と前記所定の接着性よりも強い接着性を有する樹脂を樹脂主成分とする第二の撥水性導電層とを配置して構成する、燃料電池用膜電極接合体の製造方法。
Two gas diffusion layers with a water-repellent conductive layer formed on the surface from both sides of the polymer electrolyte membrane with catalyst layers formed on both sides are thermocompression bonded so that the catalyst layer and the water-repellent conductive layer face each other. In the manufacturing method of a fuel cell membrane electrode assembly,
The water-repellent conductive layer of at least one of the two gas diffusion layers having the water-repellent conductive layer formed on the surface is made of resin having predetermined water repellency and predetermined adhesiveness in order from the gas diffusion layer side. A first water-repellent conductive layer having a main component, and a second water-repellent conductive layer having a resin as a main component, a resin having a water repellency weaker than the predetermined water repellency and an adhesiveness stronger than the predetermined adhesiveness A method for producing a membrane electrode assembly for a fuel cell.
前記第一の撥水性導電層の樹脂主成分は、テトラフルオロエチレン成分またはテトラフルオロエチレンの同族体の共重合体成分であり、
前記第二の撥水性導電層の樹脂主成分は、ポリフッ化ビニリデン成分である、請求項に記載の燃料電池用膜電極接合体の製造方法。
The resin main component of the first water-repellent conductive layer is a tetrafluoroethylene component or a copolymer component of a homolog of tetrafluoroethylene,
The method for producing a fuel cell membrane electrode assembly according to claim 5 , wherein the resin main component of the second water-repellent conductive layer is a polyvinylidene fluoride component.
前記ガス拡散層に配置されている前記第二の撥水性導電層は、前記第一の撥水性導電層上に塗布により形成されている、請求項またはに記載の燃料電池用膜電極接合体の製造方法。 The membrane electrode joint for fuel cells according to claim 5 or 6 , wherein the second water-repellent conductive layer disposed in the gas diffusion layer is formed on the first water-repellent conductive layer by coating. Body manufacturing method. 両面に触媒層を形成させた高分子電解質膜の両側から、撥水性導電層を表面に形成させた2つのガス拡散層を、それぞれ、前記触媒層と前記撥水性導電層が向き合うように熱圧着法により接合する、燃料電池用膜電極接合体の製造方法において、
前記撥水性導電層を表面に形成させた2つの前記ガス拡散層の少なくとも一方の前記撥水性導電層は、ポリフッ化ビニリデン成分とポリテトラフルオロエチレン成分を樹脂主成分とする、燃料電池用膜電極接合体の製造方法。
Two gas diffusion layers with a water-repellent conductive layer formed on the surface from both sides of the polymer electrolyte membrane with catalyst layers formed on both sides are thermocompression bonded so that the catalyst layer and the water-repellent conductive layer face each other. In the manufacturing method of a fuel cell membrane electrode assembly,
A fuel cell membrane electrode, wherein at least one of the two gas diffusion layers having the water-repellent conductive layer formed on the surface thereof, the water-repellent conductive layer includes a polyvinylidene fluoride component and a polytetrafluoroethylene component as resin main components. Manufacturing method of joined body.
JP2003298981A 2003-08-22 2003-08-22 Membrane electrode assembly for fuel cell and method for producing the same Expired - Fee Related JP4301397B2 (en)

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JP2005071755A5 true JP2005071755A5 (en) 2006-09-14
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Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4530892B2 (en) * 2005-03-28 2010-08-25 三洋電機株式会社 Polymer electrolyte fuel cell
KR100825196B1 (en) * 2005-03-28 2008-04-24 산요덴키가부시키가이샤 Fuel cell
JP4530893B2 (en) * 2005-03-28 2010-08-25 三洋電機株式会社 Polymer electrolyte fuel cell
US7608334B2 (en) * 2005-03-29 2009-10-27 3M Innovative Properties Company Oxidatively stable microlayers of gas diffusion layers
JP2006318790A (en) * 2005-05-13 2006-11-24 Tomoegawa Paper Co Ltd Solid polymer type fuel cell, gas diffusion electrode therefor, and its manufacturing method
JP5298412B2 (en) 2006-08-24 2013-09-25 トヨタ自動車株式会社 Fuel cell
WO2008093795A1 (en) * 2007-01-31 2008-08-07 Asahi Glass Company, Limited Solid polymer type fuel cell membrane electrode junction assembly, solid polymer type fuel cell and their manufacturing method
JP2008192328A (en) * 2007-01-31 2008-08-21 Asahi Glass Co Ltd Polymer electrolyte fuel cell and its manufacturing method
JP5228378B2 (en) * 2007-06-04 2013-07-03 旭硝子株式会社 Membrane electrode assembly for polymer electrolyte fuel cell and method for producing the same
JP2008192330A (en) * 2007-01-31 2008-08-21 Asahi Glass Co Ltd Membrane electrode junction for polymer electrolyte fuel cell and its manufacturing method
US20100098991A1 (en) * 2007-02-28 2010-04-22 Tomoegawa Co., Ltd. Gas Diffusion Electrode For Polymer Electrolyte Fuel Cell, Membrane-Electrode Assembly For Polymer Electrolyte Fuel Cell, Production Method Therefor, And Polymer Electrolyte Fuel Cell
JP5515230B2 (en) * 2008-03-25 2014-06-11 Jsr株式会社 Membrane electrode assembly for stationary or portable fuel cell, stationary or portable fuel cell, and resin paste for gas diffusion layer of stationary or portable fuel cell
JP5391968B2 (en) * 2009-09-29 2014-01-15 株式会社Gsユアサ Gas diffusion layer for polymer electrolyte fuel cell and method for producing the same
US8778557B2 (en) * 2011-01-18 2014-07-15 Panasonic Corporation Membrane electrode assembly for fuel cell and fuel cell using the same
JP5883301B2 (en) 2011-02-07 2016-03-15 日本バイリーン株式会社 Moisture management sheet, gas diffusion sheet, membrane-electrode assembly, and polymer electrolyte fuel cell
JP5862485B2 (en) * 2012-07-02 2016-02-16 トヨタ自動車株式会社 Method for forming gas diffusion layer for fuel cell
CN114566653B (en) * 2021-09-08 2023-01-31 中自环保科技股份有限公司 Non-uniform catalyst layer, membrane electrode and preparation method thereof

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