JP2005053834A - Solubilizable cosmetic - Google Patents
Solubilizable cosmetic Download PDFInfo
- Publication number
- JP2005053834A JP2005053834A JP2003286267A JP2003286267A JP2005053834A JP 2005053834 A JP2005053834 A JP 2005053834A JP 2003286267 A JP2003286267 A JP 2003286267A JP 2003286267 A JP2003286267 A JP 2003286267A JP 2005053834 A JP2005053834 A JP 2005053834A
- Authority
- JP
- Japan
- Prior art keywords
- carnitine
- cosmetic
- cosmetics
- present
- stickiness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
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- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
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- 210000002510 keratinocyte Anatomy 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
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- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
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- 210000003470 mitochondria Anatomy 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
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- 229920001778 nylon Polymers 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229960002969 oleic acid Drugs 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 229940093430 polyethylene glycol 1500 Drugs 0.000 description 1
- 229940093429 polyethylene glycol 6000 Drugs 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 210000002027 skeletal muscle Anatomy 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
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- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
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- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
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- 230000029663 wound healing Effects 0.000 description 1
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- 239000011787 zinc oxide Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、化粧料に関し、更に詳しくは、べたつきのない優れた保湿性を有する可溶化型化粧料に関する。 The present invention relates to a cosmetic, and more particularly, to a solubilized cosmetic having excellent moisturizing properties without stickiness.
従来、ローション等の可溶化型の透明化粧料には、一般的な皮膚の老化兆候である皮膚表面の乾燥による角質細胞の剥離、シワ,タルミ及びシミの出現、ハリや弾力の喪失などの現象を改善するために、老化して薄くなった表皮の厚さを厚くして、バリア機能を向上させるカルニチンが老化皮膚改善剤として利用されてきた(例えば、特許文献1〜3参照)。しかし、カルニチンは分子内に4級アンモニウム基とカルボキシル基を有する、いわゆるベタイン構造をもっているため、油剤等の配合が少ない可溶化型化粧料において、カルニチンを配合した場合、感触上べたつきが強く感じられやすいという問題点を有していた。 Conventionally, solubilized transparent cosmetics such as lotions have common aging signs such as exfoliation of keratinocytes due to skin surface drying, appearance of wrinkles, tarmi and stains, loss of elasticity and elasticity. In order to improve the above, carnitine that increases the barrier function by increasing the thickness of the aging and thinned epidermis has been used as an aging skin improving agent (see, for example, Patent Documents 1 to 3). However, since carnitine has a so-called betaine structure that has a quaternary ammonium group and a carboxyl group in the molecule, when carnitine is blended in solubilized cosmetics with few blends of oils, etc., stickiness is strongly felt on the touch. It had the problem of being easy.
本発明者は上記の事情に鑑み、カルニチンの有するべたつきを抑え、使用感の良好な化粧料を得るべく鋭意研究した結果、ポリオキシエチレンメチルグルコシド、ポリエチレングリコールからなる群より選択される1種以上とをカルニチンと併用することにより、良好な保湿性を有すると共に、肌に対してフィーリングの良い感触を与え、使用性に優れ、外観の良好な可溶化型化粧料を容易に生成せしめ得ることを見出し、本発明を完成した。 In view of the above circumstances, the present inventor has intensively studied to reduce the stickiness of carnitine and obtain a cosmetic with good usability, and as a result, one or more selected from the group consisting of polyoxyethylene methyl glucoside and polyethylene glycol In combination with carnitine, it has good moisturizing properties, gives a good feeling to the skin, and can easily produce a solubilized cosmetic with excellent usability and good appearance. The present invention has been completed.
従って、本発明の目的は、良好な保湿性を有すると共に、肌に対してフィーリングの良い感触を与え、使用性に優れ、外観の良好(清澄、透明)な可溶化型化粧料を提供することにある。 Accordingly, an object of the present invention is to provide a solubilized cosmetic that has a good moisturizing property, gives a feeling of feeling to the skin, is excellent in usability, and has a good appearance (clear and transparent). There is.
上述の目的は、カルニチン又はその塩と、ポリオキシエチレンメチルグルコシド、ポリエチレングリコールからなる群より選択される1種以上とを含有することを特徴とする可溶化型化粧料によって達成される。 The above-described object is achieved by a solubilized cosmetic material comprising carnitine or a salt thereof and one or more selected from the group consisting of polyoxyethylene methyl glucoside and polyethylene glycol.
すなわち、本発明は、(A)カルニチン又はその塩と、(B)ポリオキシエチレンメチルグルコシド、数平均分子量600以上のポリエチレングリコールからなる群より選択される1種以上とを含有することを特徴とする可溶化型化粧料に関する。 That is, the present invention is characterized by containing (A) carnitine or a salt thereof and (B) one or more selected from the group consisting of polyoxyethylene methyl glucoside and polyethylene glycol having a number average molecular weight of 600 or more. It relates to a solubilized cosmetic.
好ましくは、(B)成分が酸化エチレン付加モル数が10〜30であるポリオキシエチレンメチルグルコシド、数平均分子量1000〜8000のポリエチレングリコールからなる群より選択される1種以上である上記化粧料である。 Preferably, the component (B) is one or more selected from the group consisting of polyoxyethylene methyl glucoside having an ethylene oxide addition mole number of 10 to 30 and polyethylene glycol having a number average molecular weight of 1000 to 8000. is there.
本発明によれば、良好な保湿性を有すると共に、べたつきが少なく肌に対してフィーリングの良い感触を与え、使用性に優れ、外観の良好(清澄、透明)な可溶化型化粧料を提供することができる。 According to the present invention, there is provided a solubilized cosmetic that has good moisturizing properties, has less stickiness, gives a feeling of feeling to the skin, has excellent usability, and has a good appearance (clear and transparent). can do.
以下、本発明の実施の形態について詳述する。 Hereinafter, embodiments of the present invention will be described in detail.
本発明に用いられる(A)カルニチン(Carnitine)とは、γ−アミノ−β−ヒドロキシブチロベタイン(3−Carboxy−2−Hydroxy−N,N−N,trimethyl−1−propaminium hydroxide、C7H15NO3 )で、骨格筋の塩基性成分として広く存在し、通常はブタ、子牛、ウマの肉から抽出
され、アシルカルニチンの形でミトコンドリアへの脂肪酸輸送に関与し、そこでの脂肪酸酸化を促進する働きのほか、脂肪酸合成促進の作用をすることが知られている。カルニチンは水溶性物質で、化学構造的に光学異性体であり、D型、L型、その混合体であるDL型があり、そのいずれも本発明に使用できる。
(A) Carnitine used in the present invention means γ-amino-β-hydroxybutyrobetaine (3-Carboxy-2-Hydroxy-N, N—N, trimethyl-1-propadium hydroxide, C 7 H 15 NO 3 ), widely present as a basic component of skeletal muscle, usually extracted from pork, calf and horse meat, involved in fatty acid transport to mitochondria in the form of acylcarnitine, where fatty acid oxidation is In addition to the promoting action, it is known to act to promote fatty acid synthesis. Carnitine is a water-soluble substance, is an optical isomer in terms of chemical structure, and includes D-type, L-type, and DL-type that is a mixture thereof, any of which can be used in the present invention.
本発明で(A)成分として用いられるカルニチンは公知の物質であり、医薬品・食品等に用いられており、例えば合成によって得られる。また、カルニチンの塩酸塩である塩化カルニチンをアルカリ成分にて中和することによって、カルニチンが得られる。 Carnitine used as the component (A) in the present invention is a known substance and is used in medicines, foods, etc., and is obtained, for example, by synthesis. Moreover, carnitine can be obtained by neutralizing carnitine chloride, which is a hydrochloride salt of carnitine, with an alkali component.
本発明に利用される(A)成分として用いられるカルニチンの塩としては、塩酸塩、硫酸塩、硝酸塩などの無機塩、アセテート、シトレート、ニコチネート、サリチレートなどの有機酸塩などが挙げられる。汎用性、効果の点から、塩化カルニチンが好ましい。 Examples of the salt of carnitine used as the component (A) used in the present invention include inorganic salts such as hydrochloride, sulfate and nitrate, and organic acid salts such as acetate, citrate, nicotinate and salicylate. Carnitine chloride is preferred from the viewpoint of versatility and effects.
本発明で用いられる(A)成分全体の含有量は、化粧料の総量を基準として、0.01〜10質量%(以下、%と略記する)が好ましく、特に好ましくは0.1〜5%である。当該範囲内であれば、保湿効果が特に高く、べたつき抑制効果が特に優れており、肌に対する感触も良好だからである。 The content of the entire component (A) used in the present invention is preferably 0.01 to 10% by mass (hereinafter abbreviated as%), particularly preferably 0.1 to 5%, based on the total amount of the cosmetic. It is. If it is within the range, the moisturizing effect is particularly high, the stickiness suppressing effect is particularly excellent, and the skin feel is also good.
本発明で(B)成分として用いられるポリオキシエチレンメチルグルコシド、数分子量600以上のポリエチレングリコールもまた、化粧品原料として公知の物質である。例えば、ポリエチレンメチルグルコシドとしては、NIKKOL BMG−10、NIKKOL BMG−20(日光ケミカルズ社製)、Glucam E−10、Glucam E−20(池田物産社製)が挙げられる。また、ポリエチレングリコールとしては、数平均分子量200〜20000のものが、三洋化成、日本油脂、第一工業製薬、ライオンなどから販売されている。 Polyoxyethylene methyl glucoside used as component (B) in the present invention and polyethylene glycol having a molecular weight of 600 or more are also known materials for cosmetics. Examples of the polyethylene methyl glucoside include NIKKOL BMG-10, NIKKOL BMG-20 (manufactured by Nikko Chemicals), Glucam E-10, and Glucam E-20 (manufactured by Ikeda Bussan). Polyethylene glycol having a number average molecular weight of 200 to 20,000 is sold by Sanyo Chemical, Nippon Oil, Daiichi Kogyo Seiyaku, Lion, and others.
ポリオキシエチレンメチルグルコシドとしては、酸化エチレン付加モル数が10〜30のものが好ましく、さらに好ましくは酸化エチレン付加モル数が15〜25のものである。数平均分子量600以上のポリエチレングリコールとしては、数平均分子量1000〜8000のものが好ましく、さらに好ましくは4000〜6000である。当該範囲内であれば、べたつき抑制効果が特に優れており、肌に対する感触も良好だからである。 The polyoxyethylene methyl glucoside preferably has an ethylene oxide addition mole number of 10 to 30, and more preferably an ethylene oxide addition mole number of 15 to 25. The polyethylene glycol having a number average molecular weight of 600 or more is preferably a number average molecular weight of 1000 to 8000, more preferably 4000 to 6000. If it is within the range, the stickiness-inhibiting effect is particularly excellent and the skin feel is also good.
本発明で用いられる(B)成分全体の含有量は、化粧料の総量を基準として、0.001〜10%が好ましく、特に好ましくは0.1〜5%である。当該範囲内であれば、べたつき抑制効果が特に優れており、コスト的にも有利だからである。 The content of the entire component (B) used in the present invention is preferably 0.001 to 10%, particularly preferably 0.1 to 5%, based on the total amount of the cosmetic. If it is within the range, the stickiness suppressing effect is particularly excellent, and it is advantageous in terms of cost.
本発明の化粧料は、上述した成分を必須の構成成分とするが、当該組成物には本発明の目的を損なわない範囲で、他の成分、例えば、陰イオン性界面活性剤、両性界面活性剤、非イオン性界面活性剤、粘剤、防腐剤、香料、保湿剤、生理活性成分、塩類、溶媒、酸化防止剤、キレート剤、中和剤、pH調整剤、昆虫忌避剤、酵素等の成分を適宜配合することができる。 The cosmetic of the present invention has the above-described components as essential components, but other components such as an anionic surfactant and an amphoteric surfactant are included in the composition as long as the object of the present invention is not impaired. Agents, nonionic surfactants, adhesives, preservatives, fragrances, moisturizers, physiologically active ingredients, salts, solvents, antioxidants, chelating agents, neutralizing agents, pH adjusters, insect repellents, enzymes, etc. Components can be appropriately blended.
以下に他の配合成分の具体例を示すが、これらに限られるものではない。 Specific examples of other compounding components are shown below, but are not limited thereto.
陰イオン性界面活性剤としては、直鎖あるいは分岐鎖脂肪酸塩、α−アシルスルホン酸塩、アルキルスルホン酸塩、アルキルアリルスルホン酸塩、アルキルナフタレンスルホン酸塩、アルキル硫酸塩、アルキルエーテル硫酸塩、アルキルアミド硫酸塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシエチレンアルキルアミドエーテル硫酸塩、アルキルリン酸塩、アルキルアミドリン酸塩、アルキロイルアルキルタウリン塩、N−アシルアミノ酸塩、スルホコハク酸塩、パーフルオロアルキルリン酸エステル等が挙げられる。 Examples of the anionic surfactant include linear or branched fatty acid salts, α-acyl sulfonates, alkyl sulfonates, alkyl allyl sulfonates, alkyl naphthalene sulfonates, alkyl sulfates, alkyl ether sulfates, Alkylamide sulfate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkylamide ether sulfate, alkyl phosphate, alkylamide phosphate, alkyloylalkyl taurine salt, N-acyl amino acid salt, sulfosuccinate, Examples thereof include fluoroalkyl phosphate esters.
両性界面活性剤としては、グリシン型、アミノプロピオン酸型、カルボキシベタイン型、スルホベタイン型、スルホン酸型、硫酸型、リン酸型等が挙げられる。 Examples of amphoteric surfactants include glycine type, aminopropionic acid type, carboxybetaine type, sulfobetaine type, sulfonic acid type, sulfuric acid type, and phosphoric acid type.
非イオン性界面活性剤としては、脂肪酸アルカノールアミド、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルエステル、ショ糖脂肪酸エステル、ポリグリセリン脂肪酸エステル、アルキルアミンオキシド等が挙げられる。 Nonionic surfactants include fatty acid alkanolamide, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene alkyl ester, sucrose fatty acid ester, polyglycerin fatty acid ester, alkyl An amine oxide etc. are mentioned.
油剤としては、通常化粧料に用いられる揮発性および不揮発性の油剤、溶剤および樹脂が挙げられ、常温で液体、ペースト、固体のいずれの形態であっても構わない。油剤の例としては、例えばセチルアルコール、イソステアリルアルコール、ラウリルアルコール、ヘキサデシルアルコール、オクチルドデカノール等の高級アルコール、イソステアリン酸、ウンデシレン酸、オレイン酸等の脂肪酸、ミリスチン酸ミリスチル、ラウリン酸ヘキシル、ミリスチン酸オクチルドデシル、オレイン酸デシル、ミリスチン酸イソプロピル、ジメチルオクタン酸へキシルデシル、モノステアリン酸グリセリン、トリオクタン酸グリセリン、フタル酸ジエチル、モノステアリン酸エチレングリコール、オキシステアリン酸オクチル等のエステル類、ステアリン酸コレステリル、オレイン酸コレステリル、分岐脂肪酸コレステリル等のコレステロールエステル、流動パラフィン、ワセリン、スクワラン等の炭化水素、ラノリン、還元ラノリン、カルナバロウ等のロウ、ミンク油、カカオ脂、ヤシ油、パーム核油、ツバキ油、ゴマ油、ヒマシ油、オリーブ油等の油脂、ジメチルポリシロキサン、環状ジメチルポリシロキサン、メチルフェニルポリシロキサン等のシリコーン油等が挙げられる。 Examples of the oil agent include volatile and non-volatile oil agents, solvents, and resins that are usually used in cosmetics, and may be in the form of liquid, paste, or solid at room temperature. Examples of oils include higher alcohols such as cetyl alcohol, isostearyl alcohol, lauryl alcohol, hexadecyl alcohol, octyldodecanol, fatty acids such as isostearic acid, undecylenic acid, oleic acid, myristyl myristate, hexyl laurate, myristine Octyldodecyl acid, decyl oleate, isopropyl myristate, hexyl decyl dimethyloctanoate, glyceryl monostearate, glyceryl trioctanoate, diethyl phthalate, ethylene glycol monostearate, octyl oxystearate, cholesteryl stearate, Cholesterol esters such as cholesteryl oleate and branched fatty acid cholesteryl, hydrocarbons such as liquid paraffin, petroleum jelly and squalane, lanoli Waxes such as reduced lanolin, carnauba wax, mink oil, cacao butter, palm oil, palm kernel oil, camellia oil, sesame oil, castor oil, olive oil, dimethylpolysiloxane, cyclic dimethylpolysiloxane, methylphenylpolysiloxane, etc. Silicone oil etc. are mentioned.
粉体の例としては、赤色201号、黄色4号、青色1号、黒色401号等の色素、黄色4号Alレーキ、黄色203号Baレーキ等のレーキ色素、ナイロンパウダー、シルクパウダー、シリコーンパウダー、セルロースパウダー、シリコーンエラストマー球状粉体、ポリエチレン末等の樹脂、黄酸化鉄、赤色酸化鉄、酸化クロム、カーボンブラック、群青、紺青等の有色顔料、酸化亜鉛、酸化チタン等の白色顔料、タルク、マイカ、セリサイト、カオリン等の体質顔料、雲母チタン等のパール顔料等の顔料、硫酸バリウム、炭酸カルシウム、炭酸マグネシウム、珪酸マグネシウム等の金属塩、シリカ、アルミナ等の無機粉体、ベントナイト、スメクタイト、窒化ホウ素等が挙げられる。これらの粉体の形状球状、棒状、針状、板状、不定形状、燐片状、紡錘状等)に特に制限はない。 Examples of powders include red No. 201, yellow No. 4, blue No. 1 and black No. 401 pigments, yellow No. 4 Al lake, yellow No. 203 Ba lake and other lake pigments, nylon powder, silk powder and silicone powder. , Cellulose powder, silicone elastomer spherical powder, resin such as polyethylene powder, yellow iron oxide, red iron oxide, chromium oxide, carbon black, colored pigments such as ultramarine and bitumen, white pigments such as zinc oxide and titanium oxide, talc, Body pigments such as mica, sericite and kaolin, pigments such as pearl pigments such as titanium mica, metal salts such as barium sulfate, calcium carbonate, magnesium carbonate and magnesium silicate, inorganic powders such as silica and alumina, bentonite, smectite, Examples thereof include boron nitride. There are no particular restrictions on the shape of these powders, such as spherical shape, rod shape, needle shape, plate shape, irregular shape, flake shape, and spindle shape.
生理活性成分としては、皮膚に塗布した場合に皮膚に何らかの生理活性を与える物質が挙げられる。例えば、老化防止剤、紫外線防御剤、ひきしめ剤、抗酸化剤、保湿剤、血行促進剤、抗菌剤、殺菌剤、乾燥剤、冷感剤、温感剤、ビタミン類、アミノ酸、創傷治癒促進剤、刺激緩和剤、鎮痛剤、細胞賦活剤、酵素成分等が挙げられる。 Examples of the physiologically active ingredient include substances that impart some physiological activity to the skin when applied to the skin. For example, anti-aging agents, UV protection agents, squeeze agents, antioxidants, moisturizers, blood circulation promoters, antibacterial agents, bactericides, desiccants, cooling agents, warming agents, vitamins, amino acids, wound healing promoters , Stimulation mitigating agents, analgesics, cell activators, enzyme components and the like.
本発明の可溶化型化粧料とは、外観が透明〜半透明状の化粧料であり、好ましくは波長700nmの光の透過率が80%以上である化粧料である。これら可溶化型化粧料は常法
に従って製造することができる。また、本発明の可溶化型化粧料は、基礎化粧料、ボデイ化粧料などとして好適に用いることができる。例えば、整肌化粧水、拭き取り化粧水、柔軟化粧水、アクネトリートメントローション、アフターシェーブローション、二層型コンディショニングローション、ヘアトニック等として有用である。尚、本発明の化粧料は、一般の化粧料に限定されるものではなく、医薬部外品、指定医薬部外品、外用医薬品等を包含するものである。
The solubilized cosmetic of the present invention is a cosmetic having a transparent to translucent appearance, and preferably has a light transmittance of 80% or more at a wavelength of 700 nm. These solubilized cosmetics can be produced according to a conventional method. Moreover, the solubilized cosmetics of the present invention can be suitably used as basic cosmetics, body cosmetics and the like. For example, it is useful as skin conditioning lotion, wiping lotion, soft lotion, acne treatment lotion, after shave lotion, two-layer conditioning lotion, hair tonic and the like. The cosmetics of the present invention are not limited to general cosmetics, but include quasi drugs, designated quasi drugs, topical drugs and the like.
実施例1〜9、比較例1〜6
以下、実施例及び比較例によって、本発明を具体的に説明する。また、本発明はこれら実施例に限定されるものではない。
Examples 1-9, Comparative Examples 1-6
Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples. The present invention is not limited to these examples.
実施例及び比較例で得られた可溶化型化粧料は、分光光度計にて波長700nmで測定したとき蒸留水の透過率を100%とした場合その透過率が80%以上のものである。また、以下に本発明で用いた官能評価方法について記載する。 The solubilized cosmetics obtained in Examples and Comparative Examples have a transmittance of 80% or more when the transmittance of distilled water is 100% when measured with a spectrophotometer at a wavelength of 700 nm. The sensory evaluation method used in the present invention is described below.
[官能評価]
表1、表2に示す組成の化粧水を常法により調製した。これをパネラー10名に使用させ、保湿感、べたつきに関して以下の評価基準に従って評価を行い、全パネラーの合計点数をもって評価結果とした。従って、各項目とも点数が高いほど「保湿感がある」あるいは「べたつきがない」ことを示す。結果を表2に合わせて示す。
[sensory evaluation]
Lotions having the compositions shown in Tables 1 and 2 were prepared by a conventional method. This was used by 10 panelists, and the moisturizing feeling and stickiness were evaluated according to the following evaluation criteria, and the total score of all panelists was used as the evaluation result. Accordingly, the higher the score for each item, the more “moisturizing feeling” or “no stickiness”. The results are shown in Table 2.
<保湿感>
評価基準 点数
非常に保湿感を感じる 5
かなり保湿感を感じる 4
やや保湿感を感じる 3
ほとんど保湿感を感じない 2
保湿感を感じない 1
<Moisturizing feeling>
Evaluation criteria Score very moisturizing 5
I feel quite moisturizing 4
I feel a little moisturizing 3
I hardly feel moisturizing 2
Does not feel moisturizing 1
<べたつき>
評価基準 点数
べたつきを感じない 5
ほとんどべたつきを感じない 4
ややべたつきを感じる 3
かなりべたつきを感じる 2
非常にべたつきを感じる 1
<Stickiness>
Evaluation criteria Do not feel sticky points 5
Almost no stickiness 4
I feel a little sticky 3
I feel quite sticky 2
I feel very sticky 1
表2より、本発明の化粧料である実施例1〜9は、本発明の構成要件を満たさない比較例1〜6の化粧料と比較して、保湿感を有しながらもべたつきが少ないことがわかる。 From Table 2, Examples 1-9 which are the cosmetics of this invention should have little moisturizing feeling compared with the cosmetics of Comparative Examples 1-6 which do not satisfy the structural requirements of this invention. I understand.
実施例10
下記に示す組成の化粧水を常法により調製した。上記保湿感及びべたつきに関して評価したところ、保湿感が良好で、かつべたつきが少なく使用感に優れていることが確認された。
(化粧水) (質量%)
カルチニン 1.0
エタノール 10.0
ポリオキシエチレン硬化ヒマシ油(60E.O.) 1.0
グリセリン 3.0
1,3−ブチレングリコール 2.0
ジプロピレングリコール 3.0
ポリエチレングリコール1500 1.0
POE(10)メチルグルコシド 1.0
カルボキシビニルポリマー 0.1
キサンタンガム 0.1
リン酸水素ナトリウム 0.05
リン酸二水素カリウム 0.05
エデト酸二ナトリウム 0.05
メチルパラベン 0.1
香料 0.05
精製水 総量を100とする残量
Example 10
A lotion having the composition shown below was prepared by a conventional method. As a result of evaluation on the moisturizing feeling and stickiness, it was confirmed that the moisturizing feeling was good, the stickiness was small, and the feeling of use was excellent.
(Lotion) (mass%)
Carcinine 1.0
Ethanol 10.0
Polyoxyethylene hydrogenated castor oil (60 EO) 1.0
Glycerin 3.0
1,3-butylene glycol 2.0
Dipropylene glycol 3.0
Polyethylene glycol 1500 1.0
POE (10) methyl glucoside 1.0
Carboxyvinyl polymer 0.1
Xanthan gum 0.1
Sodium hydrogen phosphate 0.05
Potassium dihydrogen phosphate 0.05
Edetate disodium 0.05
Methylparaben 0.1
Fragrance 0.05
Purified water Remaining amount of 100
実施例11
下記に示す組成の整肌化粧水を常法により調製した。上記保湿感及びべたつきに関して評価したところ、保湿感が良好で、かつべたつきが少なく使用感に優れていることが確認された。
(整肌化粧水) (質量%)
カルニチン 1.0
ポリオキシエチレン硬化ヒマシ油(60E.O.) 1.0
ポリエチレングリコール6000 1.0
POE(20)メチルグルコシド 1.0
カルボキシビニルポリマー 0.15
香料 0.05
パラオキシ安息香酸メチル 0.1
精製水 総量を100とする残量
Example 11
A skin conditioning lotion having the composition shown below was prepared by a conventional method. As a result of evaluation on the moisturizing feeling and stickiness, it was confirmed that the moisturizing feeling was good, the stickiness was small, and the feeling of use was excellent.
(Skin conditioning lotion) (mass%)
Carnitine 1.0
Polyoxyethylene hydrogenated castor oil (60 EO) 1.0
Polyethylene glycol 6000 1.0
POE (20) methyl glucoside 1.0
Carboxyvinyl polymer 0.15
Fragrance 0.05
Methyl paraoxybenzoate 0.1
Purified water Remaining amount of 100
実施例12
下記に示す組成のアフターシェーブローションを常法により調製した。本アフターシェーブローションは、ひげそり後に使用した時、仕上がりはなめらかで、べたつきが少なく、清涼感のあるさっぱりとした良好な感触が得られた。
(アフターシェーブローション) (質量%)
カルチニン 2.0
エタノール 30.0
香料 0.05
イソプロピルメチルフェノール 0.01
ビタミンA 0.05
ポリオキシエチレン硬化ヒマシ油(60E.O.) 1.0
ポリエチレングリコール4000 1.0
POE(20)メチルグルコシド 1.0
カルボキシビニルポリマー 0.15
アルキル変性カルボキシビニルポリマー 0.15
キサンタンガム 0.1
精製水 総量を100とする残量
Example 12
An after shave lotion having the composition shown below was prepared by a conventional method. This after-shave lotion, when used after shaving, had a smooth finish, little stickiness, and a refreshing and refreshing feel.
(After Shave Lotion) (mass%)
Carcinine 2.0
Ethanol 30.0
Fragrance 0.05
Isopropylmethylphenol 0.01
Vitamin A 0.05
Polyoxyethylene hydrogenated castor oil (60 EO) 1.0
Polyethylene glycol 4000 1.0
POE (20) methyl glucoside 1.0
Carboxyvinyl polymer 0.15
Alkyl-modified carboxyvinyl polymer 0.15
Xanthan gum 0.1
Purified water Remaining amount of 100
実施例13
下記に示す組成の二層型コンディショニングローションを常法により調製した。本二層型コンディショニングローションは所要振盪回数4回にして、分離していた粉体層と水層とが均一に混和し、懸濁液を生成した。さらに静置後1時間後、透明の水層部と淡赤色の粉体層部の二層に明瞭に分離した美しい外観を呈した。また、本二層型コンディショニングローションは、使用時にべたつき感がなく、しっとりとした仕上がり感が得られた。
(二層型コンディショニングローション) (質量%)
カルニチン 1.0
エチルアルコール 10.0
香料 0.1
ポリオキシエチレン硬化ヒマシ油(60E.O.) 1.0
グリセリン 3.0
硫酸亜鉛 0.3
亜鉛華 1.0
ベンガラ 0.01
タルク 1.0
炭酸ナトリウム 0.2
ポリエチレングリコール4000 1.0
POE(20)メチルグルコシド 1.0
カルボキシビニルポリマー 0.15
アルキル変性カルボキシビニルポリマー 0.15
精製水 総量を100とする残量
Example 13
A two-layer conditioning lotion having the composition shown below was prepared by a conventional method. In this two-layer conditioning lotion, the required number of shakings was four times, and the separated powder layer and aqueous layer were uniformly mixed to form a suspension. Furthermore, 1 hour after standing, a beautiful appearance was clearly separated into two layers of a transparent water layer portion and a light red powder layer portion. In addition, this two-layer conditioning lotion did not feel sticky when used, and gave a moist finish.
(Two-layer conditioning lotion) (mass%)
Carnitine 1.0
Ethyl alcohol 10.0
Fragrance 0.1
Polyoxyethylene hydrogenated castor oil (60 EO) 1.0
Glycerin 3.0
Zinc sulfate 0.3
Zinc flower 1.0
Bengala 0.01
Talc 1.0
Sodium carbonate 0.2
Polyethylene glycol 4000 1.0
POE (20) methyl glucoside 1.0
Carboxyvinyl polymer 0.15
Alkyl-modified carboxyvinyl polymer 0.15
Purified water Remaining amount of 100
実施例14
下記に示す組成のヘアートニックを常法により調製した。本ヘアートニックは、頭皮及び毛髪がしっとりとなめらかに仕上がり、べたつき感がなく、良好な感触が得られた。
(ヘアートニック) (質量%)
カルニチン 0.5
エタノール 30.0
ポリオキシエチレン硬化ヒマシ油(60E.O.) 1.0
エストラジオール 0.001
香料 0.1
D−パントテニルアルコール 0.1
ポリエチレングリコール4000 1.0
POE(20)メチルグルコシド 1.0
カルボキシビニルポリマー 0.15
精製水 総量を100とする残量
Example 14
A hair tonic having the composition shown below was prepared by a conventional method. This hair artic finished with a moist and smooth scalp and hair, no stickiness, and a good feel.
(Heartnic) (mass%)
Carnitine 0.5
Ethanol 30.0
Polyoxyethylene hydrogenated castor oil (60 EO) 1.0
Estradiol 0.001
Fragrance 0.1
D-pantothenyl alcohol 0.1
Polyethylene glycol 4000 1.0
POE (20) methyl glucoside 1.0
Carboxyvinyl polymer 0.15
Purified water Remaining amount of 100
尚、上記実施例中で用いられた香料は、下記香料処方のものである。 In addition, the fragrance | flavor used in the said Example is a thing of the following fragrance | flavor prescription.
以上記載のごとく、本発明は、(A)カルニチン又はその塩と、(B)ポリオキシエチレンメチルグルコシド、数平均分子量600以上のポリエチレングリコールからなる群より選択される1種以上とを含有することを特徴とする化粧料に関し、保湿性に優れ、しかもべたつきが少なく肌に対してフィーリングの良い感触を与え、使用性に優れ、外観(清澄、透明)の良好な化粧料を得ることができる。
また、本発明の化粧料は、基礎化粧料、ボデイ化粧料などとして好適に用いることができる。尚、本発明の化粧料は、一般の化粧料に限定されるものではなく、医薬部外品、指定医薬部外品、外用医薬品等を包含するものである。
As described above, the present invention contains (A) carnitine or a salt thereof and (B) one or more selected from the group consisting of polyoxyethylene methyl glucoside and polyethylene glycol having a number average molecular weight of 600 or more. As for the cosmetics characterized by the above, it is possible to obtain cosmetics with excellent moisture retention, low stickiness, good feeling on the skin, excellent usability, and good appearance (clear, transparent). .
Moreover, the cosmetics of the present invention can be suitably used as basic cosmetics, body cosmetics and the like. The cosmetics of the present invention are not limited to general cosmetics, but include quasi drugs, designated quasi drugs, topical drugs and the like.
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JP2011132192A (en) * | 2009-12-25 | 2011-07-07 | Kao Corp | Hair dye composition |
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JP2011132192A (en) * | 2009-12-25 | 2011-07-07 | Kao Corp | Hair dye composition |
JP2011132191A (en) * | 2009-12-25 | 2011-07-07 | Kao Corp | Hair cosmetic |
JP2011184386A (en) * | 2010-03-10 | 2011-09-22 | Nippon Menaade Keshohin Kk | Transparent liquid-form skin external preparation |
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JPWO2018117172A1 (en) * | 2016-12-21 | 2019-10-31 | 株式会社 資生堂 | Water-in-oil emulsified cosmetic |
JP7094227B2 (en) | 2016-12-21 | 2022-07-01 | 株式会社 資生堂 | Water-in-oil emulsified cosmetics |
US11510863B2 (en) | 2016-12-21 | 2022-11-29 | Shiseido Company, Ltd. | Water-in-oil emulsion cosmetics |
JP2020066617A (en) * | 2018-10-19 | 2020-04-30 | 富士フイルム株式会社 | Aqueous gel cosmetic |
JP7074647B2 (en) | 2018-10-19 | 2022-05-24 | 富士フイルム株式会社 | Aqueous gel cosmetic |
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