JP2005052811A - Tablet for producing acidic reduced water - Google Patents

Tablet for producing acidic reduced water Download PDF

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JP2005052811A
JP2005052811A JP2003314765A JP2003314765A JP2005052811A JP 2005052811 A JP2005052811 A JP 2005052811A JP 2003314765 A JP2003314765 A JP 2003314765A JP 2003314765 A JP2003314765 A JP 2003314765A JP 2005052811 A JP2005052811 A JP 2005052811A
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reduced water
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JP4072787B2 (en
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Hiroto Suzuki
洋斗 鈴木
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HIKARI BERUKOMU KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a simple and easy means for producing a low redox potential water being weakly acidic which is good for health, since, though the low redox potential water, which is called a reduced water, is anti-oxidizing and hence much useful for a human body, most of conventional reduced water is alkaline and thereby has a side effect when taken much. <P>SOLUTION: The weakly acidic reduced water is obtained in a short time only by throwing into water a tablet made by blending a sustained releasing filler with a mixture of a magnesium powder and a solid organic acid at a given compounding ratio. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、これを水に溶かすことによって水の酸化還元電位を低くして、水中に残存する塩素を除去し、人体の活性酸素除去に効果的とされる還元水を提供する飲料用錠剤および錠剤型入浴剤の構成成分にかんする。  The present invention relates to a tablet for beverages that provides reduced water that is effective in removing active oxygen from the human body by reducing the redox potential of water by dissolving it in water, removing chlorine remaining in the water, and Concerning the components of tablet baths.

ミネラル成分や水素種を含む水は一般に酸化還元電位が低く、溶存する塩素を除去したり、活性酸素種を不活性化する傾向があることから身体に良い水とされ、飲料用や浴用として種々の成分の水が還元水を冠する名称を付けられて広く利用されている。通常の水は塩化銀電極測定でプラス200ミリボルトから400ミリボルトであるが電気分解によって得られる還元水は0からマイナス600ミリボルトを示すので通常0ミリボルト以下を還元水と呼称している。還元水はボトルに入った水として市販されるほか、水の電気分解や、ミネラル供給装置付きの市販の製水装置から家庭で作ることが出来る。製水装置のなかで、ミネラル供給による還元水の製法は電気分解法に比べて電源を必要とせず、装置が小型で操作簡単と言う特徴がある。例えば(イ)特開2003−10865「酸性還元水」によればマグネシウム板を含む筒状の装置と有機酸を水中に接触させることによって酸化還元電位が低く酸性に偏った水を得ることが出来る。別の例として(ロ)特開2003−24956「アルカリイオン水の製造方法及び水改質器」によればマグネシウム粉末を収蔵した筒状の装置を水中に投入することによって酸化還元電位が低くアルカリ性に偏った水を得ることが出来る。  Water containing mineral components and hydrogen species generally has low oxidation-reduction potential and tends to remove dissolved chlorine and inactivate active oxygen species. The component water is widely used with the name of reducing water. Ordinary water is from plus 200 millivolts to 400 millivolts as measured by a silver chloride electrode, but the reduced water obtained by electrolysis shows 0 to minus 600 millivolts, so 0 millivolts or less is usually called reduced water. In addition to being marketed as bottled water, the reduced water can be made at home from electrolysis of water and commercial water production equipment with mineral supply equipment. Among water production systems, the method of producing reduced water by supplying minerals does not require a power source as compared with the electrolysis method, and is characterized in that the system is small and easy to operate. For example, according to (a) Japanese Patent Application Laid-Open No. 2003-10865 “acid-reduced water”, water that has a low oxidation-reduction potential and tends to be acidic can be obtained by bringing a cylindrical device including a magnesium plate into contact with an organic acid. . As another example, according to (b) Japanese Patent Application Laid-Open No. 2003-24956 “Method for Producing Alkaline Ionized Water and Water Reformer”, by introducing a cylindrical apparatus storing magnesium powder into water, the oxidation-reduction potential is low and alkaline. You can get water that is biased to

水の酸化還元電位は水素イオン濃度によてよって変化しpH指数が大きくなるほど、即ちアルカリ性になるほど電位は下がって還元傾向になる。しかし前記(イ)特開2003−10865「酸性還元水」の本文で主張するようにpH8を超えるアルカリ性の水は還元水であっても大量に飲料すると身体に有害であって必ずしも抗酸化力を示すとは言えない。  The oxidation-reduction potential of water varies depending on the hydrogen ion concentration, and as the pH index increases, that is, the alkalinity becomes lower, the potential decreases and tends to reduce. However, as claimed in the text of the above (a) Japanese Patent Application Laid-Open No. 2003-10865 “acid-reduced water”, alkaline water exceeding pH 8 is harmful to the body if it is drunk in large quantities even if it is reduced water. I can't say that.

上記製水装置(イ)の原理は金属マグネシウム板と有機酸が水中で反応する結果、水素とマグネシウム塩を発生して水の酸化還元電位が低くなる。 一方(ロ)の原理はマグネシウム粉末と水が直接に反応して水素とマグネシウム酸化物ないしマグネシウム水酸化物を発生して(イ)と同様に水の酸化還元電位が下がる。これらの製水装置は取り扱いが手軽であるものの何れも水中に投入する装置であって、装置の定期的な洗浄や修理等の保守が必要となる。  The principle of the water producing apparatus (a) is that a metal magnesium plate and an organic acid react in water. As a result, hydrogen and magnesium salt are generated, and the redox potential of water is lowered. On the other hand, the principle of (b) is that the magnesium powder and water react directly to generate hydrogen and magnesium oxide or magnesium hydroxide, and the redox potential of water decreases as in (a). Any of these water production devices that are easy to handle are devices that are thrown into water, and maintenance such as periodic cleaning and repair of the devices is required.

特別の装置を用いずに、ミネラル塩や水素種を含む物質を水に投入するだけで還元水の実現が図れる方法がある。例えばビタミンCやビタミンE、植物性の抗酸化酵素様物質、コロイド化したミネラル塩やその他の抗酸化酵素様薬剤の殆どは水溶することによって比較的電位の低い還元水となる。しかしこれらの物質は薬剤、ないし健康の為のサプリメントとして生産されている高価な経口服用剤であって、本来服用によって唾液や胃腸、血液の生理活性物質と反応してはじめて抗酸化力を現すものである。即ち洗顔や入浴用としては効果は不明であり、高価であるので日常の飲料用に大量に使用することは出来ない。  There is a method in which reduced water can be realized simply by introducing a substance containing a mineral salt or hydrogen species into water without using a special device. For example, most of vitamin C and vitamin E, plant antioxidant enzyme-like substances, colloidal mineral salts, and other antioxidant enzyme-like drugs are reduced in water to become reduced water with a relatively low potential. However, these substances are expensive drugs for oral use that are produced as medicines or health supplements, and they exhibit antioxidant activity only after reacting with physiologically active substances in saliva, gastrointestinal tract, and blood. It is. That is, the effect is unclear for face washing and bathing, and since it is expensive, it cannot be used in large quantities for daily beverages.

発明が解決しようとする課題Problems to be solved by the invention

錠剤は粉末や液体に比べて持ち運びが便利で、効果が長続きして現れるいわゆる徐放効果を有する利点がある。従来錠剤化した材料を水中に投与するだけで人体に安全で抗酸化作用のある酸性の還元水を実現するものはなかった。その理由は還元性を示すミネラル塩の多くがアルカリ性を示すことによる。錠剤は製造過程で賦形剤、乳化剤等の各種の添加物を必要とし、これらの物質が酸化還元電位とpH値の両方に影響を与えることから、低い電位と適度のpH値を実現することの困難さがあった。  Tablets are more convenient to carry than powders and liquids, and have the advantage of a so-called sustained release effect that lasts longer. Conventionally, there has been nothing that realizes acidic reduced water that is safe and antioxidative for the human body by simply administering the tableted material into water. The reason is that many mineral salts showing reducibility show alkalinity. Tablets require various additives such as excipients and emulsifiers in the manufacturing process, and these substances affect both the redox potential and the pH value, so that a low potential and a moderate pH value must be realized. There were difficulties.

問題を解決するための手段Means to solve the problem

本発明は上記目的を達成するために請求項1の発明にあっては粒度50メッシュ以上200メッシュ以下の金属マグネシウム粉末を5以上20以下の重量%とし、クエン酸、フマール酸等の固体状有機酸を15以上50以下の重量%とし、その他の成分として賦形剤、乳化剤等、錠剤化にあたって必要なフィラー材料を含んだ酸性還元水生成錠剤とする。ここでマグネシウム粉末の粒度は米国タイラー社の定義によるメッシュ表示に従うものとする。即ちマグネシウムの粒径は約300ミクロン以下70ミクロン以上である。粒径の上限は水中に粉末として短時間の反応後に残留が認められなくなる大きさである。粒径の下限は水中での有機酸との過度の反応によって水素種の徐放性が損なわれることを避ける大きさである。マグネシウム粉末と固体状有機酸との配合比は両者の反応が効率良く行われ、さらには反応後も水の酸性を保つためである。マグネシウム粉末と固体状有機酸の重量%の上限は錠剤の賦形と徐放効果を得るためである。即ちマグネシウム粉末と固体状有機酸全錠剤に占める重量%は70を超えない。また重量%の下限は所要水素種発生反応の下限を意味する。固体状有機酸として好ましくは3価酸のクエン酸が選ばれる。3価の酸は水素種の供給能力が大きく、酸としての働きが持続するためである。  In order to achieve the above object, the present invention provides a solid organic material such as citric acid and fumaric acid in the invention of claim 1, wherein the metal magnesium powder having a particle size of 50 mesh or more and 200 mesh or less is 5 to 20% by weight. Acid-reduced water-generating tablets containing 15 to 50% by weight of acid and containing other filler ingredients such as excipients and emulsifiers as other components required for tableting. Here, the particle size of the magnesium powder follows the mesh display defined by Tyler, USA. That is, the particle size of magnesium is about 300 microns or less and 70 microns or more. The upper limit of the particle size is such that no residue is observed after a short reaction as a powder in water. The lower limit of the particle size is a size that prevents the sustained release of hydrogen species from being impaired by excessive reaction with an organic acid in water. The compounding ratio of the magnesium powder and the solid organic acid is that the reaction of both is performed efficiently, and further, the acidity of water is maintained after the reaction. The upper limit of the weight percent of magnesium powder and solid organic acid is to obtain tablet shaping and sustained release effect. That is, the weight percent of the magnesium powder and the total solid organic acid tablet does not exceed 70. Moreover, the lower limit of weight% means the lower limit of the required hydrogen species generation reaction. A trivalent citric acid is preferably selected as the solid organic acid. This is because the trivalent acid has a large supply capability of hydrogen species and continues to function as an acid.

請求項2の発明にあっては、請求項1のマグネシウム粉末と固体状有機酸の他の成分として炭酸水素塩を5以上20以下の重量%混合し、これを水溶して飲料用の還元水とすることを特徴とする還元水生成錠剤を提供する。請求項1のマグネシウム粉末と固体状有機酸の配合比から請求項1の錠剤は水溶下で反応が進むに従って酸度は低下するものの酸性の侭である。炭酸水素塩はこれを中和するためのものである。その配合比の上限はマグネシウム粉末と固体状有機酸の反応を損なわないためであり、下限は味覚としての酸っぱさを軽減させるために有効な値である。  In the invention of claim 2, the magnesium powder of claim 1 is mixed with 5 to 20% by weight of hydrogen carbonate as the other component of the solid organic acid, and this is dissolved in water to give reduced water for beverages. A reduced water-generating tablet is provided. From the blending ratio of magnesium powder and solid organic acid according to claim 1, the tablet according to claim 1 is acidic but its acidity decreases as the reaction proceeds under water. The bicarbonate is for neutralizing this. The upper limit of the blending ratio is for not impairing the reaction between the magnesium powder and the solid organic acid, and the lower limit is an effective value for reducing the sourness as a taste.

請求項3の発明にあっては、請求項1のマグネシウム粉末と固体状有機酸の他の成分としてマグネシウム塩、水溶性クレイの何れかまたは両方を10以上40以下の重量%混合することを特徴とする入浴用錠剤を提供する。入浴剤としての錠剤は浴槽水に沈むことが必要条件である。その理由は還元水の元になる水素種は、水中投入後直ちにガスとなって水中を浮上するので錠剤が常に水底にあることが浴槽水全体を還元する上で効果的となる。しかるに金属マグネシウムや有機酸の多くは比重が2以下でこれらの基本材料で錠剤を構成しただけでは錠剤の見かけ上の比重は小さく、特に水中投入時の反応によって水素種ガスが表面に付着すると、錠剤全体が水面上に浮上して発生する水素種を空中に逃がしてしまうこととなる。マグネシウム塩、水溶性クレイの多くは比重が2以上で比較的重く、これを錠剤の構成要素とすることによって錠剤の比重を大きくし、確実に水中に沈む効果を得ることが出来る。またマグネシウム塩、水溶性クレイは基礎材料のマグネシウム粉末と固体状有機酸を包むフィラーの役割を持つので水素種ガスの発生を遅らせる徐放剤の役割を担うことにもなる。請求項に示した重量%の下限は10は錠剤の沈降を確実にする値であり、上限の40は過度の徐放効果を防止するためである。  In the invention of claim 3, the magnesium powder of claim 1 and any one or both of magnesium salt and water-soluble clay as other components of the solid organic acid are mixed in an amount of 10 to 40% by weight. A bath tablet is provided. It is a necessary condition that tablets as bathing agents sink into bath water. The reason for this is that the hydrogen species, which is the source of the reducing water, becomes gas immediately after being introduced into the water and floats in the water. Therefore, it is effective for reducing the entire bath water that the tablet is always at the bottom of the water. However, most metal magnesium and organic acids have a specific gravity of 2 or less, and the apparent specific gravity of the tablet is small just by constituting a tablet with these basic materials. Especially when hydrogen species gas adheres to the surface due to the reaction when it is poured into water, The hydrogen species generated when the whole tablet floats on the water surface will escape to the air. Many of the magnesium salts and water-soluble clays have a specific gravity of 2 or more and are relatively heavy. By using this as a component of the tablet, the specific gravity of the tablet can be increased and the effect of sinking in water can be obtained. Magnesium salts and water-soluble clays also serve as a sustained release agent that delays the generation of hydrogen species gas because they have the role of a filler that encloses magnesium powder as a basic material and a solid organic acid. The lower limit of 10% by weight indicated in the claims is a value that ensures the sedimentation of the tablet, and the upper limit of 40 is to prevent an excessive sustained release effect.

発明の効果The invention's effect

請求項1に記載された発明にあっては水に投入することによって水素種の発生反応が起きて水の酸化還元電位を下げ、酸性の還元水を実現する錠剤を提供する。本発明は従来の電気分解や金属材料からなる発生装置を使うことなく酸性の還元水生成の目的を達成する。従来のアルカリ性還元水が有する多量飲用時の有害性を解消し、、抗酸化作用に優れ、かつ整腸作用のある飲料用に適した水を多量で安定に効率的に得ることができる。また本発明になる酸性還元水は人体にとって不足しがちなマグネシウムをイオンの形で取り込んでいるため、人体のミネラルバランスを良くする効果がある。  According to the first aspect of the present invention, there is provided a tablet that realizes acidic reduced water by introducing hydrogen species into a water to cause generation reaction of hydrogen species to lower the redox potential of water. The present invention achieves the purpose of producing acidic reduced water without using conventional electrolysis or a generator made of a metal material. It eliminates the harmful effects of conventional alkaline reduced water when drinking in large quantities, and can stably and efficiently obtain a large amount of water that is excellent in antioxidant action and suitable for drinks having an intestinal regulating action. Further, the acidic reduced water according to the present invention incorporates magnesium, which tends to be insufficient for the human body, in the form of ions, and therefore has an effect of improving the mineral balance of the human body.

請求項2に記載された発明にあっては請求項1で実現される酸性還元水の酸度を弱酸性ないし中和することによって飲用時の酸っぱさを緩和し、酸度を意識することなく飲用することができる。ここで示された方法は単にpH調整剤としてではなく、使用される有機酸の働きを損なわない条件となる。  In the invention described in claim 2, the acidity of the acid-reduced water realized in claim 1 is weakly acidified or neutralized to reduce sourness at the time of drinking and drink without being aware of the acidity. be able to. The method shown here is not merely a pH adjuster, but is a condition that does not impair the function of the organic acid used.

請求項3に記載された発明にあっては請求項1で実現される酸性還元水の入浴剤としての効果を大きくしたものである。即ち水中での水素種の発生を効率化し、少量の錠剤で充分な抗酸化性を持った水を作り、直接皮膚表面に抗酸化作用を及ぼしあるいは皮膚表面から体内への吸収によって全身への同様の効果をもたらす。  In the invention described in claim 3, the effect of the acidic reduced water bathing agent realized in claim 1 is increased. In other words, the generation of hydrogen species in water is made more efficient, water with sufficient antioxidant properties is made with a small amount of tablets, and it has an antioxidant effect directly on the skin surface or is absorbed by the body from the skin surface. Bring about the effect.

以下、本発明の実施例について飲料用、入浴用の各々の錠剤の基本構成と構造について説明する。 表1は飲料用錠剤の構成成分を表す。
表2は入浴用錠剤の構成成分を表す。
Hereinafter, the basic structure and structure of each tablet for beverages and bathing will be described with respect to examples of the present invention. Table 1 shows the components of the beverage tablet.
Table 2 shows the components of the tablet for bathing.

Figure 2005052811
Figure 2005052811

Figure 2005052811
Figure 2005052811

錠剤の大きさや形状は任意であるが飲料用としてはコップ一杯の水200ccに投入する量を目安として1個の大きさを表1の材料構成として例えば円形の5ミリメートル径、厚さ2ミリメートルが還元水を作るために充分な量である。入浴用としては浴槽水量を300リットルを目安として、1個の大きさを表2の材料構成とし円形30ミリメートル径、厚さは10ミリメートルの大きさが浴槽水全体を還元するために充分な量であるが、入浴時間や水の交換等を考慮して錠剤の追加投入をすることが可能である。The size and shape of the tablet is arbitrary, but for beverages, the amount of water poured into 200 cc of water is used as a guideline. The amount is sufficient to make reduced water. For bathing, the amount of bath water is 300 liters as a guide, and the size of one piece is the material composition shown in Table 2 and the diameter is 30 millimeters and the thickness is 10 millimeters. However, it is possible to add tablets in consideration of bathing time and water exchange.

Claims (3)

粒度50メッシュ以上200メッシュ以下の金属マグネシウム粉末を5以上20以下の重量%とし、クエン酸、フマール酸等の固体状有機酸を15以上50以下の重量%とし、その他の成分として賦形剤、乳化剤等錠剤化にあたって必要な材料を含んだ酸性還元水生成錠剤。  Metal magnesium powder having a particle size of 50 mesh or more and 200 mesh or less is 5 to 20% by weight, solid organic acid such as citric acid or fumaric acid is 15 to 50% by weight, and other ingredients are excipients, Acid-reduced water-generating tablets containing materials necessary for tableting, such as emulsifiers. 請求項1において、その他の成分として炭酸水素塩を5以上20以下の重量%混合し、これを水溶して飲料用の還元水とすることを特徴とする還元水生成錠剤。  2. A reduced water-generating tablet according to claim 1, wherein 5 to 20% by weight of a bicarbonate is mixed as the other component, and this is dissolved in water to obtain reduced water for beverages. 請求項1において、その他の成分としてマグネシウム塩、水溶性クレイの何れかまたは両方を10以上40以下の重量%混合することを特徴とする入浴用錠剤。  2. The tablet for bathing according to claim 1, wherein any one or both of a magnesium salt and a water-soluble clay is mixed as a component in an amount of 10 to 40% by weight.
JP2003314765A 2003-08-05 2003-08-05 Acid-reduced water-generating tablets Expired - Fee Related JP4072787B2 (en)

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JP2012171871A (en) * 2011-02-17 2012-09-10 Suiso Kenko Igaku Labo Kk Bath agent
JP2013128882A (en) * 2011-12-21 2013-07-04 Nikko Kasei Kk Hydrogen water producing apparatus
JP2015205791A (en) * 2014-04-18 2015-11-19 ニッコ−化成株式会社 Hydrogen generation agent, hydrogen generator, and method of producing hydrogen containing liquid
JP6162268B1 (en) * 2016-01-26 2017-07-12 コーベビオケミア株式会社 Method for producing hydrogen generator
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