JP2005047164A - Woody decorative member and its production method - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a woody decorative member which when it is obtained by lapping a woody decorative sheet on the surface of a substrate, when flexibility is demonstrated and excellent lapping is made possible, holds large surface strength after the lapping, exhibits a high-grade appearance, and does not diffuse a volatile organic substance and a method for producing the member. <P>SOLUTION: The woody decorative sheet 3 is obtained in which a moisture curable urethane hot melt resin of at least 80 durometer A hardness after curing is applied on the surface of a woody thin plate 1 and made to penetrate into the thin plate 1 by hot pressing, and the resin-coated layer 2 is also formed on the surface. The woody decorative member is produced by lapping the woody decorative sheet 3 on the substrate 4 before the hot melt resin is cured completely. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  The present invention relates to a wooden decorative member used as various furniture, furniture, and building materials, and a method for manufacturing the same.

  Conventionally, as a wood decorative member used for furniture materials and building materials, etc., a wooden thin plate with a thickness of 1 mm or less is pasted on the surface of a base material such as a sawn timber or plywood, and the surface of this wooden thin plate is a transparent resin A film formed by overlaying a film and then applying a paint such as urethane resin is widely known (see, for example, Patent Document 1).

JP-A-8-1869 ((pages 2 to 5)).

  However, in order to give the above-mentioned wooden decorative member lapping suitability by bending, if the resin forming the coating layer on the surface is hard, the tensile stress of the curved portion generated during bending will cause Since cracks and cracks will occur, it is necessary to use a soft resin as the resin for forming the coating layer and to exhibit the extensibility to adapt to the tension, so that the surface of the wooden decorative member However, there is a problem that damage such as scratches easily occurs and the commercial value is remarkably lowered.

  The present invention has been made in view of the problems as described above, and the purpose thereof is to exhibit good lapping suitability and maintain excellent surface hardness after lapping, and in addition to design. Provided is a safe wooden decorative member that exhibits a high-grade appearance with a deep depth, and that does not have the risk of releasing volatile organic substances during or after manufacturing, and a manufacturing method that can efficiently produce this wooden decorative member. It is in.

  In order to achieve the above object, according to the wood decorative member of the present invention, a moisture-curable urethane hot melt resin coating layer is provided on the surface of a woody thin plate, and the moisture is contained inside. A wooden decorative sheet that has been infiltrated and filled with a curable urethane-based hot melt resin is wrapped on the substrate at the stage before the above-mentioned moisture-curable urethane-based hot-melt resin has an isocyanate reaction rate of 90% or less. It has the structure which becomes.

  In the wood decorative member configured as described above, the invention according to claim 2 is characterized in that a veneer single plate having a thickness of 0.15 to 0.5 mm is used as the wood thin plate.

Further, as described in claim 3, the moisture curable urethane-based hot melt resin has a durometer A hardness (JIS K 6253) after the reaction hardening of 80 or more. 4. As described in claim 5, the moisture-curable urethane-based hot melt resin is non-yellowing type or hard yellowing type and has a thickness of 100 μm.
The total light transmittance is 70% or more when reactively cured to a thickness of.

The invention according to claim 6 is a method for producing the above-mentioned wooden decorative member, wherein a moisture-curable urethane-based hot melt resin is applied to the surface of the wooden thin plate at a rate of 20 to 100 g / m ^{2, and is} applied to the wooden thin plate by hot pressure. Wood that is filled with 2g / m ² or more of the coating amount of the above moisture curable urethane hot melt resin, and has a coating layer of 15g / m ² or more of moisture curable urethane hot melt resin remaining on the surface. A decorative sheet is produced, and this wood decorative sheet is used as a base material, and the moisture curing type urethane hot melt resin has an isocyanate reaction rate of 90% or less and is lapped at a stage before complete reaction curing. It is.

  In the method for manufacturing a wooden decorative member, the invention according to claim 7 is that the moisture-curable urethane hot melt resin is applied to the surface of the wooden thin plate, and then the application surface is hot-pressed via a release material or a release agent. The invention is characterized in that a part of the moisture-curable urethane-based hot melt resin is infiltrated into the inside of the wood thin plate by applying heat pressure to the inside of the wood thin plate. It is characterized by softening the moisture-curable urethane hot melt resin by heating to a base material and lapping the substrate in this softened state.

  Further, in the above-described method for producing a wooden decorative member, the invention according to claim 9 is that the wooden thin plate is a single veneer sliced with a thickness of 0.15 to 0.5 mm, and the moisture curing applied to the surface of the wooden thin plate. The urethane type hot-melt resin is a non-yellowing or hard yellowing resin having a high transparency with a total light transmittance of 70% or more when cured to a thickness of 100 μm.

  According to the first aspect of the present invention, the wood decorative sheet formed by applying and filling the moisture curable urethane hot melt resin on the wood thin plate has flexibility before the moisture curable urethane hot melt resin is completely cured. Since the wrapping is applied to the base material when it has, even if the base material has an uneven bent surface, a wooden product member with high commercial value can be provided by accurately wrapping the wooden decorative sheet along the bent surface. In addition, the moisture-hardening urethane hot-melt resin coating layer that has been cured after lapping processing increases the surface hardness, makes it difficult to cause damage such as scratches and deepens oil soaked after curing. In addition, it exhibits an excellent appearance with high design and high performance, and in addition, moisture-curing urethane hot melt resin is a solvent-free resin. No possibility to dissipate sexual organic compounds, when used in furniture and fittings and the like can be improved indoor environment.

  As the wood thin plate, as described in claim 2, since a veneer single plate sliced to a thickness of 0.15 to 0.5 mm is used, it has a thickness that does not impair the depth of wood. Excellent design properties can be imparted and flexibility suitable for lapping can be exhibited without causing cracks and the like.

Further, according to the invention of claim 3, the durometer A hardness (JIS K) after reaction hardening of the moisture-curing urethane hot melt resin applied and filled in the wood thin plate.
6253) is 80 or more, the surface hardness of the wooden decorative member can be formed on a resin coating layer that exhibits abrasion resistance with a hardness that is difficult to be scratched.

  Furthermore, as described in claims 4 and 5, the moisture-curable urethane-based hot melt resin applied and filled on a thin wood plate has a total light transmittance when reacted and cured to a thickness of 100 μm. Because there is a non-yellowing or hard-yellowing resin with high transparency of 70% or more, it can exhibit excellent transparency over a long period of time and improve the shine and depth inherent in the wood thin plate A woody decorative sheet can be obtained.

According to the method for producing a wooden decorative member, as described in claim 6, first, a moisture-curable urethane-based hot melt resin is applied to the surface of the wooden thin plate at a rate of 20 to 100 g / m ^2, and the wooden material is applied by hot pressure. 2g / m ² or more of the coating amount of the above moisture curable urethane hot melt resin is infiltrated into the thin plate, and a moisture curable urethane hot melt resin coating layer of 15g / m ² or more is left on the surface. As the wood decorative sheet is manufactured, the resin coating layer on the surface of the wooden thin plate can be firmly integrated with the wooden thin plate by the resin that has penetrated and filled into the wooden thin plate, as well as the wet feeling on the wooden thin plate. An excellent appearance such as a feeling of depth can be given, and in addition, the above-mentioned wet feeling and depth feeling can be given further by the resin coating layer on the surface, and further, a moisture-curing urethane system for wood thin plates Ho The moisture-curable urethane-based hot melt resin can exhibit good lapping performance before being cured on the woody decorative sheet depending on the amount of the melt applied and the amount of penetration of the tmelt resin.
Obtainable.

  Next, a moisture-curable urethane hot melt resin is applied to and penetrates the surface and inside of the thin wood plate as described above, and the isocyanate reaction rate of the moisture-curable urethane hot melt resin is 90% or less. Since it wraps on the base material before it is completely reaction-cured, moisture-curing urethane hot melt resin has the property that it takes time until it completely cures, and it will solidify when it appears to cool. Even if the substrate has a curved surface, lapping can be performed smoothly and accurately on the substrate, which enables continuous production of the wooden decorative member and is suitable for mass production.

  In the method for manufacturing a wooden decorative member, according to the invention according to claim 7, after the moisture-curable urethane-based hot melt resin is applied to the surface of the wooden thin plate, the applied surface is heated via a release material or a release agent. Since it is characterized by allowing moisture-curing urethane hot melt resin to permeate the inside of the wood thin plate by hot pressing with a pressure roll, it is efficient to apply and permeate the moisture-curing urethane hot melt resin to the wood thin plate It can be done well and reliably.

  Furthermore, according to the invention according to claim 8, when the wooden decorative sheet is wrapped on the base material, the wooden decorative sheet is preheated to a temperature of 40 to 100 ° C. so as to be moisture-curable urethane-based hot Since the melt resin is softened and lapping is performed on the base material in this softened state, the surface of the base material such as furniture having an uneven surface or curved surface is in close contact with the uneven surface or curved surface. Thus, a lapping process can be easily performed, and a wooden decorative member having an excellent commercial value can be manufactured.

  In addition, as described above, the moisture-curable urethane-based hot melt resin that is applied to and penetrates a thin wood plate is a non-yellowing type having a high transparency with a total light transmittance of 70% or more when cured to a thickness of 100 μm. Or because it is a hard yellowing resin, the woody sheet has a high-quality appearance that improves the feeling of shine and depth inherent in the wood thin plate, and exhibits excellent transparency over a long period of time. A decorative sheet can be obtained.

  Next, an embodiment of the present invention will be described with reference to the drawings. FIG. 1 is a simplified enlarged longitudinal sectional view showing an example of a wooden decorative member A of the present invention. The wooden decorative member A is a surface of a wooden thin plate 1. The wood decorative sheet 3 is provided with a moisture curable urethane-based hot melt resin coating layer 2 and the moisture curable urethane-based hot melt resin infiltrated and filled into the wood sheet 1. The surface is subjected to lapping through an adhesive 5.

  The wood thin plate 1 is a veneer veneer obtained by slicing wood to a thickness of 0.15 to 0.5 mm. The veneer veneer may be a hardwood veneer, a softwood veneer, or an artificial veneer. In order to enable continuous production of the woody decorative sheet 3, it is preferable to form the veneer single plate 1 into a strip-like long sheet by a bad joint or a finger joint. At this time, a backing sheet (not shown) made of a fibrous sheet such as a nonwoven fabric may be attached to the back surface of the long sheet via an adhesive to reinforce the sheet.

  When the thickness of the wood sheet 1 is 0.15 mm or less, the finger joint is difficult and the sense of depth of the wood is insufficient and the design is deteriorated. When the thickness is 0.5 mm or more, the flexibility of the wood decorative sheet 3 is improved. When the lapping is performed on the base material 4 because the flexibility is hindered, particularly when the lapping is performed along the curved surface portion, the wooden decorative sheet 3 is liable to be cracked. Therefore, as described above, the thickness is 0.15 to 0.15. Use one in the mm range. Moreover, you may decorate the said wooden thin plate 1 previously by known methods, such as coloring, decoloring, direct printing, and transfer, as needed.

  As the moisture curable urethane hot melt resin to be applied to the surface of the wood thin plate 1, one having a durometer A hardness (JIS K 6253) of 80 or more after reaction curing is used. If it is softer than this hardness, the hardness when the resin is cured is insufficient, wear resistance and scratch resistance are lowered, and the surface is easily scratched. Since the moisture-curable urethane-based hot melt resin takes time to be completely cured, even when a hard moisture-curable urethane-based hot melt resin is used, the surface of the wood thin plate 1 is coated and filled (penetrated). It becomes possible to perform lapping before the resin is completely cured.

  Further, as the moisture curable urethane hot melt resin, a non-yellowing type or a hardly yellowing type resin is used. The ease of yellowing of the moisture-curable urethane-based hot melt resin is determined by the type of isocyanate used when synthesizing this resin, and therefore the following isocyanates are generally used.

  That is, examples of the hardly yellowing type include xylylene isocyanate (XDI) and tetramethylxylylene diisocyanate (TMXDI), which are types in which an isocyanate group having an aromatic ring is not directly bonded to the aromatic ring. Non-yellowing types include aliphatic or alicyclic isophorone diisocyanate (IPDI), hexamethylene diisocyanate (HMDI), and the like.

  Also, when synthesizing moisture-curable urethane-based hot melt resins, yellowing type isocyanates such as tolylene diisocyanate (TDI) and diphenylmethane diisocyanate (MDI) are used, and UV absorbers and light stabilizers are added to this. There is also a method of making it difficult to yellow. The ultraviolet absorber used may be a known one, for example, a paraaminobenzoic acid type such as octylparadimethylbenzoate, a benzophenone derivative such as oxybenzone, a methoxycinnamic acid derivative, a salicylic acid derivative, or an inorganic cerium oxide. is there.

  In addition, the moisture curable urethane hot melt resin is a highly transparent resin with a total light transmittance (JIS K 7105) of 70% or more when cured to a thickness of 100 μm. The improvement is generally performed by increasing the amorphous component. In addition, if the total light transmittance is less than 70% when moisture-curing urethane hot melt resin is cured to a thickness of 100 μm, the luster and depth (depth) inherent to wood will disappear. Therefore, it is not preferable. This moisture curable urethane hot melt resin may be arbitrarily colored so that the total light transmittance does not fall below 70%.

  Thus, the non-yellowing type or hard yellowing type moisture curable urethane-based hot melt resin adjusted so that the total light transmittance when cured to a thickness of 100 μm is 70% or more is applied to the wood thin plate 1. After the coating on the surface, the moisture-curing urethane hot melt resin is infiltrated and filled into the wooden thin plate 1 by hot pressing, and the coated layer 2 of this resin is formed on the surface of the wooden thin plate 1. A decorative sheet 3 is obtained (see FIG. 2). At this time, the heat pressure for infiltrating and impregnating the moisture curable urethane hot melt resin (liquid resin) into the thin wood plate 1 is such that the temperature of the moisture curable urethane hot melt resin is in the range of 80 to 150 ° C. The viscosity of the resin during the hot pressing is set to be in the range of 500 to 10,000 mPa · s. When the viscosity is less than 500 mPa · s, the average molecular weight of the components in the moisture-curable urethane hot melt resin must be reduced, and the time until the surface of the thin wood plate 1 impregnated with the resin does not become sticky, That is, the tack free time becomes longer and hinders the subsequent process, but if the viscosity is higher than 10,000 mPa · s, the penetration of the resin liquid into the wooden thin plate 1 is deteriorated, and the resulting wooden decorative sheet is designed. It is not possible to give an excellent depth.

When applying the moisture-curable urethane-based hot melt resin to the surface of the thin wood plate 1, the moisture-curable urethane-based hot melt resin is heated to 90 to 140 ° C. and melted. , Using a known coating means such as a slit coater, a hot roll coater, or a cone coater. The application amount of the moisture curable urethane hot melt resin applied to the surface of the thin wood plate 1 by such application means is in the range of 20 to 100 g / m ² .

  The wood sheet 1 having the surface coated with the moisture-curable urethane hot melt resin is hot-pressed by a hot-pressing means such as a hot press, a continuous hot-pressing press, or a heating roll. It is preferable to perform hot-pressure treatment with a heating roll.

  In this case, the moisture curable urethane hot melt resin is applied to the surface of the thin wood plate 1, and then a release material such as a release film or release paper is placed thereon, and further the moisture curable type is heated by the heating roll. A urethane-based hot melt resin is hot-pressed to infiltrate and fill the wood thin plate 1 and the resin coating layer 2 is formed on the surface. In addition, when the moisture-curable urethane-based hot melt resin is cooled and solidified after the heat and pressure treatment, the release material is easily peeled off from the surface of the wooden thin plate 1, so that the release material can be reused. Become. Further, without using such a release material, a release agent is coated on the heating roll, and the moisture-curable urethane-based hot melt resin applied to the surface of the wooden thin plate 1 with this heating roll is hot-pressed. Good.

The temperature at the time of hot pressing by the heating roll is in the temperature range of 80 to 150 ° C., although it varies depending on the speed of the production line, that is, the speed of loading the long wooden thin plate 1 sent to the heating roll and the temperature of the wooden thin plate 1. , pressure is 10~100 N / cm ^2. In addition, the material of this hot-press roll is not particularly limited, but if you want to finish the conduit part of the wooden thin plate 1 open, use a rubber-based roll such as elastic silicon, and if you want to finish the conduit part closed For example, a hard roll made of steel may be used.

In this way, the moisture content type urethane hot melt resin applied to the surface within the range of 20 to 100 g / m ² is hot-pressed to the inside of the thin wood plate 1 to have an application amount of 2 g / m ² or more, Penetration and filling are performed, but the temperature and pressure at the time of hot pressing are adjusted so that a coating layer 2 of a moisture-curable urethane-based hot melt resin of at least 15 g / m ² (15 μm thickness) or more remains on the surface of the wooden thin plate 1. . If the impregnation amount (filling amount) of the moisture-curable urethane-based hot melt resin into the wooden thin plate 1 is not ² g / m ² or more, the wooden thin plate 1 has a high-quality appearance design and basis such as a wet feeling and a deep feeling. The lapping performance for the material 4 cannot be obtained.

  Since the moisture-curable urethane-based hot melt resin is solvent-free, it does not dissipate harmful volatile organic substances, and apparently solidifies when cooled after application. Continuous production of the member A becomes possible. Furthermore, since the moisture curable urethane hot melt resin is not a thermoplastic type which is a general hot melt, the woody decorative sheet 3 having excellent heat resistance can be obtained.

  Next, the wood decorative sheet 3 obtained by the above steps is superimposed on the surface of a base material 4 such as furniture or joinery made of MDF (medium specific gravity wood fiber board), plywood, inorganic board, etc., with an adhesive 5 interposed therebetween. The wooden decorative member A is manufactured by lapping.

  When the wooden decorative sheet 3 is wrapped on the base material 4, the moisture curable urethane hot melt resin is heated by the heat applied to the moisture curable urethane hot melt resin applied to the surface of the wooden thin plate 1. The reaction proceeds to such an extent that it does not remelt, and the level of isocyanate reaction used in synthesizing this resin is 90% or less, that is, the wooden decorative sheet 3 before the resin is completely reacted and cured is flexible and flexible. A lapping process is performed at a stage where there is a property. The isocyanate reaction rate can be calculated from the peak intensity ratio of the isocyanate group and the methylene group using an infrared absorption spectacle.

  In addition, lapping is performed by a pro-lamination laminator or the like. At that time, the moisture-curable urethane-based hot melt resin softened by applying the wood decorative sheet 3 to the wood sheet 1 by heating to 40-100 ° C. is softened. Do it above. Thus, after wrapping the wooden decorative sheet 3 on the base material 4, the moisture-curable urethane hot melt resin is completely reacted and cured to obtain the wooden decorative member A. Next, specific examples and comparative examples of the present invention will be shown.

A red oak veneer sliced to a thickness of 0.25 mm was longitudinally connected by a finger joint, and a non-woven fabric was adhered to the back surface thereof to produce a continuous veneer sheet. Next, on the surface of this continuous veneer sheet, a light brown colored total light transmittance of 85%, a melt viscosity of 2,000 mPa · s (120 ° C.) is non-yellowing and has a cured durometer A hardness (JIS K 6253). ) Is a moisture-curable urethane-based hot melt resin having a temperature of 90 ° C. and heated to 120 ° C. and applied to a thickness of 50 g / m ² (50 μm) by a hot melt roll coater. Furthermore, after release paper is layered on this coating layer, it is continuously pressed at a linear pressure of 40 N / cm with a silicon rubber roll heated to 120 ° C, and moisture-curing urethane hot melt resin penetrates into the veneer sheet. I let you. Thereafter, the release paper was peeled off to obtain a woody decorative sheet obtained by impregnating the veneer sheet with a moisture-curable urethane hot melt resin. At this time, a layer of 30 g / m ² (30 μm) of moisture-curing urethane hot melt resin was formed on the surface of the wooden decorative sheet.

A base comprising a medium specific gravity fiber board having a curved surface shape with a radius of curvature of 3 mm while heating the woody decorative sheet thus obtained to 80 ° C. before the moisture-curing urethane hot melt resin is completely cured. The target woody decorative member was obtained by lapping the material. At the time of this lapping, the wooden decorative sheet has very high flexibility and does not cause cracks or cracks, and its appearance is very designable with a wet feeling like an oil finish. there were. Furthermore, when the moisture-curing urethane hot melt resin is completely cured, the pencil hardness of the surface of the wooden decorative member is HB, and the amount of volatile organic compound (VOC) emitted by the small chamber (ADPAC) method is 300 μg. / m ³ or less. Further, in the fading test (xenon lamp irradiation for 48 hours), the color difference ΔE was 2.8 and hardly changed.

[Comparative Example 1]
A medium specific gravity fiber board having a curved shape with a corner radius of curvature of 3 mm, a wood decorative sheet obtained by applying a moisture curing urethane hot melt resin to a veneer sheet obtained under the same conditions as in Example 1 and infiltrating it. When wrapping a base material made of the material, after completely curing the moisture-curing urethane hot melt resin, the wrapping process was performed, and the wooden decorative sheet cracked on the curved surface of the corner of the base material. I have.

[Comparative Example 2]
A wooden decorative member was obtained by the same production method as in Example 1 except that a moisture-curing urethane hot melt resin having a durometer A hardness (JIS K 6253) of 70 after reaction curing was used. The obtained wooden decorative member had a soft surface pencil hardness of 2B.

It is a simple expansion longitudinal cross-sectional view of a part of woody decorative member. It is a simple expansion longitudinal cross-sectional view of a part of woody decorative sheet.

Explanation of symbols

A Wood decorative material 1 Wood thin plate 2 Coating layer 3 Wood decorative sheet 4 Base material

Claims (9)

  A moisture-curable urethane hot melt resin coating layer is provided on the surface of the wood thin plate, and the moisture-curable urethane hot melt resin is infiltrated and filled therein. A wooden decorative member, which is obtained by wrapping a base material in a stage before completion of curing with an isocyanate reaction rate of 90% or less in a hot-melt resin.   2. The wooden decorative member according to claim 1, wherein the wooden thin plate is a veneer single plate sliced to a thickness of 0.15 to 0.5 mm.   2. The woody decorative member according to claim 1, wherein the durometer A hardness (JIS K 6253) of the moisture-curing urethane hot melt resin after reaction curing is 80 or more.   The woody decorative member according to claim 1 or 3, wherein the moisture-curable urethane-based hot melt resin is non-yellowing type or hard yellowing type.   The moisture curable urethane-based hot melt resin has a total light transmittance of 70% or more when reactively cured to a thickness of 100 μm, according to claim 1, 3 or 4. Wooden decorative material. Applying 20-100 g / m ² of moisture curable urethane hot melt resin on the surface of the wood sheet, and 2 g / m ² of the coating amount of the moisture curable urethane hot melt resin in the wood sheet by hot pressure. A wooden decorative sheet is manufactured by filling the above and leaving a coating layer of a moisture curable urethane hot melt resin of 15 g / m ² or more on the surface, and using the wooden decorative sheet as a base material, the moisture curable urethane A method for producing a wooden decorative member, characterized in that lapping is performed at a stage prior to complete reaction hardening of an isocyanate reaction rate of a hot-melt resin of 90% or less.   After applying moisture-curing urethane hot melt resin to the surface of the wood thin plate, the coated surface is hot-pressed with a hot-pressing roll via a release agent or release agent, and part of the moisture-curing urethane hot melt resin is treated with wood. The method for producing a woody decorative member according to claim 6, wherein the material penetrates into the thin plate.   The woody decorative sheet is heated to 40 to 100 ° C to soften the moisture-curing urethane hot melt resin, and the substrate is lapped in this softened state. The manufacturing method of the wooden decorative member as described in any one of Claims 1-3. The wood thin plate consists of a single veneer sliced to a thickness of 0.15-0.5mm. The moisture-curable urethane-based hot melt resin applied to the surface of this wood thin plate is the total light when cured to a thickness of 100 μm. 9. The method for producing a woody decorative member according to claim 6, 7 or 8, which is a non-yellowing or hard-yellowing resin having a high transparency with a transmittance of 70% or more.

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