JP2005040662A - Wastewater evaporation apparatus - Google Patents

Wastewater evaporation apparatus Download PDF

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Publication number
JP2005040662A
JP2005040662A JP2003200457A JP2003200457A JP2005040662A JP 2005040662 A JP2005040662 A JP 2005040662A JP 2003200457 A JP2003200457 A JP 2003200457A JP 2003200457 A JP2003200457 A JP 2003200457A JP 2005040662 A JP2005040662 A JP 2005040662A
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JP
Japan
Prior art keywords
hot air
evaporation
evaporation tower
wastewater
passage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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JP2003200457A
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Japanese (ja)
Inventor
Akio Ishimaru
昭夫 石丸
Shinichi Kunihisa
伸一 國久
Yusuke Hosoyama
裕介 細山
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Parker Engineering Co Ltd
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Parker Engineering Co Ltd
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Filing date
Publication date
Application filed by Parker Engineering Co Ltd filed Critical Parker Engineering Co Ltd
Priority to JP2003200457A priority Critical patent/JP2005040662A/en
Publication of JP2005040662A publication Critical patent/JP2005040662A/en
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  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a wastewater evaporation apparatus wherein a mist collection filter is prevented from being clogged by suppressing sedimentation of sludge on the mist collection filter. <P>SOLUTION: The wastewater evaporation apparatus is equipped with a hot air producing furnace, an evaporation column communicating with the hot air producing furnace through a hot air passage, a drain passage extending from the bottom part of the evaporation column to the upper part of the evaporation column and the upper part of the hot air producing furnace, a pump arranged on the way of the drain passage, a spray nozzle attached to the end part on the side of the hot air producing furnace of the drain passage and the mist collection filter arranged above the end part on the side of the hot air producing furnace of the drain passage within the evaporation column. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
本発明は、表面処理設備や塗装設備から排出される排水の蒸発装置に関するものである。
【0002】
【従来の技術】
表面処理設備の排水の蒸発装置が特許文献1等に開示されている。従来の蒸発装置は図1に示すように、熱風発生炉を兼ねる蒸発塔1を備えている。蒸発塔1の側壁に、塗装設備乾燥炉の廃熱の取入口1aと外気取入口1bとが形成され、バーナー2が取り付けられている。蒸発塔1の天井壁に、排気ファン3と排気ダクト4とが取り付けられている。蒸発塔1の底部から蒸発塔1の上部へ排水パイプ5が延びている。排水パイプ5の途上にポンプ6が配設されている。排水パイプ5の蒸発塔上部側端部にスプレーノズル7が取り付けられている。蒸発塔1内に且つスプレーノズル7の上方にミスト捕集フィルター8が配設されている。蒸発塔1の底部には、図示しない表面処理設備や塗装設備から流入した排水が貯留されている。
上記構成を有する従来の蒸発装置においては、外気取入口から吸引された外気が乾燥炉廃熱やバーナー燃焼熱により加熱されて、蒸発塔1内で熱風が生成される。熱風は蒸発塔1内を上昇し、スプレーノズル7から噴霧される排水ミストを加熱し、排水ミスト中の水分を蒸発させる。析出したスラッジは蒸発塔1底部に貯留された排水中に落下する。排水ミストの一部は蒸発せず熱風に連行されて上昇するが、ミスト捕集フィルター8によって捕集される。排水から分離された水蒸気は排ガスとともに排気ファン3に吸引され、排気ダクト4を介して蒸発装置から排出される。
【0003】
【特許文献1】特開平8−218189
【0004】
【発明が解決しようとする課題】
図1に示す従来の蒸発装置には、以下の問題があった。
▲1▼析出したスラッジが全て蒸発塔1底部に貯留された排水中に戻るので、蒸発塔内の排水中のスラッジ濃度が高く、ミスト捕集フィルター8でスラッジが析出し易く、ミスト捕集フィルターが目詰まりし易い。
▲2▼多量の排水ミストがミスト捕集フィルターによって捕集されるので、ミスト捕集フィルター8でスラッジが析出し易く、ミスト捕集フィルターが目詰まりし易い。
本発明は上記問題に鑑みてなされたものであり、ミスト捕集フィルターでのスラッジ析出が抑制され、ミスト捕集フィルターの目詰まりが抑制された排水の蒸発装置を提供することを目的とする。
【0005】
【課題を解決するための手段】
上記課題を解決するために、本発明においては、熱風発生炉と、熱風通路を介して熱風発生炉に連通する蒸発塔と、蒸発塔の底部から蒸発塔上部と熱風発生炉上部とへ延びる排水通路と、排水通路の途上に配設されたポンプと、排水通路の熱風発生炉上部側端部に取り付けられたスプレーノズルと、蒸発塔内に且つ排水通路の蒸発塔上部側端部より上方に配設されたミスト捕集フィルターとを備えることを特徴とする排水蒸発装置を提供する。
本発明においては、熱風発生炉内で発生した熱風が熱風通路を通って蒸発塔へ流入し、排水通路の蒸発塔上部側端部から吐出する排水中の水分を蒸発させる。析出したスラッジは蒸発塔の底部に貯留された排水中に戻る。蒸発塔の底部に貯留された排水の一部は、熱風発生炉内でミスト化される。排水ミスト中の水分が蒸発することにより析出したスラッジは、落下して熱風発生炉の底部に堆積し、蒸発塔の底部に貯留された排水中には戻らない。この結果、蒸発塔の底部に貯留された排水中のスラッジ濃度の上昇が抑制され、ミスト捕集フィルターでのスラッジ析出が抑制され、ミスト捕集フィルターの目詰まりが抑制される。
【0006】
本発明の好ましい態様においては、蒸発装置は、蒸発塔内に且つ排水通路の蒸発塔上部側端部より下方に配設された多孔板を備える。
排水を多孔板から滴下させることにより、排水と熱風との十分な接触面積が確保されつつ蒸発塔内での排水ミストの発生が抑制され、ミスト捕集フィルターでのスラッジ析出が抑制され、ミスト捕集フィルターの目詰まりが抑制される。
【0007】
本発明の好ましい態様においては、蒸発装置は、上下方向に互いに間隔を隔てて配設された複数の多孔板を備える。
複数の多孔板を上下方向に互いに間隔を隔てて配設することにより、熱風と排水との接触面積が増加し、排水の蒸発効率が向上する。
【0008】
本発明の好ましい態様においては、蒸発装置は、複数の多孔板によって形成された蛇行通路を備える。
蛇行通路を熱風が流れることにより、蒸発塔内での熱風の滞留時間が増加し、蒸発塔の温度が上昇し、排水の蒸発効率が向上する。
【0009】
【発明の実施の形態】
本発明の実施例に係る排水蒸発装置を説明する。
図2に示すように、本実施例に係る排水蒸発装置は、熱風発生炉11を備えている。熱風発生炉11の囲壁に、図示しない塗装設備乾燥炉の廃熱の取入口11aと外気取入口11bとが形成され、バーナー12が取り付けられている。熱風発生炉11は、熱風通路13を介して、蒸発塔14に連通している。
蒸発塔14の天井壁に、排気ファン15と排気ダクト16とが取り付けられている。蒸発塔14の底部から蒸発塔14の上部へ排水パイプ17が延びている。排水パイプ17の途上にポンプ18が配設されている。ポンプ18よりも下流で排水パイプ17から分岐する排水パイプ19が、熱風発生炉11の上部へ延びている。排水パイプ19の熱風発生炉上部側端部にスプレーノズル20が取り付けられている。
【0010】
蒸発塔14内に且つ排水パイプ17の蒸発塔上部側端部の下方に、上下方向に互いに間隔を隔てて、複数の多孔板21が配設されている。多孔板21の一辺は蒸発塔14の側壁に固定されている。多孔板21の残余の三辺には堰板21aが固定されている。複数の多孔板21により、蛇行熱風通路22が形成されている。蒸発塔14内に且つ排水パイプ17の蒸発塔上部側端部の上方に、ミスト捕集フィルター23が配設されている。
蒸発塔14の底部には、図示しない表面処理設備や塗装設備から流入した排水が貯留されている。
【0011】
上記構成を有する排水蒸発装置においては、外気取入口11bから吸引された外気が乾燥炉廃熱やバーナー燃焼熱により加熱されて、熱風発生炉11内で熱風が生成される。熱風はスプレーノズル20から噴霧される排水ミストを加熱し、排水ミスト中の水分を蒸発させる。析出したスラッジは熱風発生炉11の底部に堆積する。熱風発生炉11の底部に堆積したスラッジは蒸発塔14へは戻らない。熱風発生炉11の底部に堆積したスラッジは定期的に除去される。
水蒸気は熱風と共に熱風通路13を通って蒸発塔14へ流入し、蛇行熱風通路22を通って上昇する。
【0012】
排水パイプ17の蒸発塔上部側端部から吐出した排水が、最上段の多孔板21上に溜まり、多孔板21に形成された多数の小孔から下方の蛇行熱風通路22内へ滴下する。滴下した排水は順次下方の多孔板21上に溜まり、順次下方の蛇行熱風通路221内へ滴下し、最終的に蒸発塔14の底部に貯留された排水中に戻る。蛇行熱風通路22内を落下する排水の水滴が、蛇行熱風通路22内を上昇する熱風に接触して加熱され、排水中の水分が蒸発する。析出したスラッジは下方の多孔板21上に溜まった排水中に落下し、最終的に蒸発塔14の底部に貯留された排水中に戻る。
【0013】
排水パイプ17の蒸発塔上部側端部から吐出した排水の一部はミスト化し、蒸発塔14内を上昇する熱風に連行されて上昇するが、ミスト捕集フィルター23に捕集される。
排水から分離された水蒸気は排ガスとともに排気ファン15に吸引され、排気ダクト16を介して排水蒸発装置から排出される。
【0014】
蒸発塔14の底部に貯留された排水の一部が、熱風発生炉11内でミスト化され、排水ミスト中の水分が蒸発することにより析出したスラッジが、落下して熱風発生炉11の底部に堆積し、蒸発塔14の底部に貯留された排水中に戻らないことにより、蒸発塔14の底部に貯留された排水中のスラッジ濃度の上昇が抑制され、ミスト捕集フィルター23でのスラッジ析出が抑制され、ミスト捕集フィルター23の目詰まりが抑制される。
【0015】
排水を多孔板21から滴下させることにより、排水と熱風との十分な接触面積が確保されつつ蒸発塔14内での排水ミストの発生が抑制され、ミスト捕集フィルター23でのスラッジ析出が抑制され、ミスト捕集フィルター23の目詰まりが抑制される。
複数の多孔板21を上下方向に互いに間隔を隔てて配設することにより、熱風と排水との接触面積が増加し、排水の蒸発効率が向上する。
蛇行熱風通路22を熱風が流れることにより、蒸発塔14内での熱風の滞留時間が増加し、蒸発塔14の温度が上昇し、排水の蒸発効率が向上する。
【0016】
【発明の効果】
以上説明したごとく、本発明においては、蒸発塔の底部に貯留された排水の一部が熱風発生炉内でミスト化され、排水ミスト中の水分が蒸発することにより析出したスラッジが、熱風発生炉の底部に堆積し蒸発塔の底部に貯留された排水中に戻らないことにより、蒸発塔の底部に貯留された排水中のスラッジ濃度の上昇が抑制され、ミスト捕集フィルターでのスラッジ析出が抑制され、ミスト捕集フィルターの目詰まりが抑制される。
【図面の簡単な説明】
【図1】従来の排水蒸発装置の断面図である。
【図2】本発明の実施例に係る排水蒸発装置の断面図である。
【符号の説明】
1、14 蒸発塔
5、17、19 排水パイプ
7、20 スプレーノズル
8、23 ミスト捕集フィルター
11 熱風発生炉
13 熱風通路
21 多孔板
22 蛇行熱風通路
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an evaporation device for drainage discharged from a surface treatment facility or a coating facility.
[0002]
[Prior art]
An apparatus for evaporating wastewater from a surface treatment facility is disclosed in Patent Document 1 and the like. As shown in FIG. 1, the conventional evaporator includes an evaporation tower 1 that also serves as a hot-air generating furnace. On the side wall of the evaporation tower 1, a waste heat intake port 1a and an outside air intake port 1b of the coating equipment drying furnace are formed, and a burner 2 is attached. An exhaust fan 3 and an exhaust duct 4 are attached to the ceiling wall of the evaporation tower 1. A drain pipe 5 extends from the bottom of the evaporation tower 1 to the top of the evaporation tower 1. A pump 6 is disposed in the middle of the drain pipe 5. A spray nozzle 7 is attached to the upper end of the drainage pipe 5 on the evaporation tower. A mist collecting filter 8 is disposed in the evaporation tower 1 and above the spray nozzle 7. At the bottom of the evaporation tower 1, wastewater that flows from a surface treatment facility and a painting facility (not shown) is stored.
In the conventional evaporation apparatus having the above configuration, the outside air sucked from the outside air inlet is heated by the drying furnace waste heat or the burner combustion heat, and hot air is generated in the evaporation tower 1. The hot air rises in the evaporation tower 1, heats the waste water mist sprayed from the spray nozzle 7, and evaporates the water in the waste water mist. The precipitated sludge falls into the wastewater stored at the bottom of the evaporation tower 1. A portion of the drainage mist does not evaporate and is entrained by hot air and rises, but is collected by the mist collection filter 8. The water vapor separated from the waste water is sucked together with the exhaust gas by the exhaust fan 3 and discharged from the evaporator through the exhaust duct 4.
[0003]
[Patent Document 1] JP-A-8-218189
[0004]
[Problems to be solved by the invention]
The conventional evaporator shown in FIG. 1 has the following problems.
(1) Since all the precipitated sludge returns to the wastewater stored at the bottom of the evaporation tower 1, the sludge concentration in the wastewater in the evaporation tower is high, and the mist collection filter 8 tends to precipitate the mist collection filter. Is prone to clogging.
(2) Since a large amount of waste water mist is collected by the mist collecting filter, sludge is likely to be deposited by the mist collecting filter 8, and the mist collecting filter is likely to be clogged.
This invention is made | formed in view of the said problem, and it aims at providing the evaporation apparatus of the waste_water | drain which the sludge precipitation by the mist collection filter was suppressed and the clogging of the mist collection filter was suppressed.
[0005]
[Means for Solving the Problems]
In order to solve the above problems, in the present invention, a hot air generating furnace, an evaporation tower communicating with the hot air generating furnace via a hot air passage, and drainage extending from the bottom of the evaporation tower to the upper part of the evaporation tower and the upper part of the hot air generating furnace. A passage, a pump disposed in the middle of the drainage passage, a spray nozzle attached to the upper end of the hot air generating furnace of the drainage passage, and the upper part of the drainage passage above the upper end of the evaporation tower. Provided is a wastewater evaporation apparatus comprising a mist collecting filter disposed.
In the present invention, the hot air generated in the hot air generating furnace flows into the evaporation tower through the hot air passage, and evaporates the water in the wastewater discharged from the upper end of the evaporation passage in the drainage passage. The deposited sludge returns to the wastewater stored at the bottom of the evaporation tower. Part of the wastewater stored at the bottom of the evaporation tower is misted in a hot air generator. The sludge deposited by the evaporation of water in the waste water mist falls and accumulates at the bottom of the hot air generator, and does not return to the waste water stored at the bottom of the evaporation tower. As a result, an increase in the sludge concentration in the wastewater stored at the bottom of the evaporation tower is suppressed, sludge precipitation on the mist collection filter is suppressed, and clogging of the mist collection filter is suppressed.
[0006]
In a preferred aspect of the present invention, the evaporation apparatus includes a perforated plate disposed in the evaporation tower and below the upper end of the drainage passage on the upper side of the evaporation tower.
By dripping the wastewater from the perforated plate, the generation of wastewater mist in the evaporation tower is suppressed while ensuring a sufficient contact area between the wastewater and hot air, and sludge precipitation in the mist collection filter is suppressed, and mist trapping is achieved. Clogging of the collecting filter is suppressed.
[0007]
In a preferred aspect of the present invention, the evaporation apparatus includes a plurality of perforated plates that are spaced apart from each other in the vertical direction.
By disposing a plurality of perforated plates in the vertical direction at intervals, the contact area between the hot air and the drainage increases, and the drainage evaporation efficiency improves.
[0008]
In a preferred aspect of the present invention, the evaporation apparatus includes a meandering passage formed by a plurality of perforated plates.
When hot air flows through the meandering passage, the residence time of the hot air in the evaporation tower increases, the temperature of the evaporation tower rises, and the efficiency of drainage evaporation improves.
[0009]
DETAILED DESCRIPTION OF THE INVENTION
A drainage evaporation apparatus according to an embodiment of the present invention will be described.
As shown in FIG. 2, the wastewater evaporation apparatus according to the present embodiment includes a hot air generating furnace 11. On the surrounding wall of the hot air generating furnace 11, a waste heat intake port 11 a and an outside air intake port 11 b of a painting facility drying furnace (not shown) are formed, and a burner 12 is attached. The hot air generating furnace 11 communicates with the evaporation tower 14 via the hot air passage 13.
An exhaust fan 15 and an exhaust duct 16 are attached to the ceiling wall of the evaporation tower 14. A drain pipe 17 extends from the bottom of the evaporation tower 14 to the top of the evaporation tower 14. A pump 18 is disposed in the middle of the drain pipe 17. A drain pipe 19 that branches from the drain pipe 17 downstream of the pump 18 extends to the upper part of the hot air generating furnace 11. A spray nozzle 20 is attached to the upper end of the hot air generating furnace of the drain pipe 19.
[0010]
A plurality of perforated plates 21 are arranged in the evaporation tower 14 and below the upper end portion of the drainage pipe 17 on the upper side of the evaporation tower, spaced apart from each other in the vertical direction. One side of the perforated plate 21 is fixed to the side wall of the evaporation tower 14. A dam plate 21 a is fixed to the remaining three sides of the porous plate 21. A serpentine hot air passage 22 is formed by the plurality of perforated plates 21. A mist collection filter 23 is disposed in the evaporation tower 14 and above the upper end portion of the drain pipe 17 on the upper side of the evaporation tower.
At the bottom of the evaporation tower 14, waste water flowing from a surface treatment facility and a painting facility (not shown) is stored.
[0011]
In the wastewater evaporation apparatus having the above configuration, the outside air sucked from the outside air inlet 11 b is heated by the drying furnace waste heat or the burner combustion heat, and hot air is generated in the hot air generating furnace 11. The hot air heats the waste water mist sprayed from the spray nozzle 20 and evaporates the water in the waste water mist. The precipitated sludge accumulates at the bottom of the hot air generator 11. Sludge accumulated at the bottom of the hot air generator 11 does not return to the evaporation tower 14. Sludge accumulated at the bottom of the hot air generator 11 is periodically removed.
The steam flows together with the hot air into the evaporation tower 14 through the hot air passage 13 and rises through the meandering hot air passage 22.
[0012]
The drainage discharged from the upper end of the evaporation pipe 17 of the drainage pipe 17 collects on the uppermost porous plate 21 and drops into the meandering hot air passage 22 below from a large number of small holes formed in the porous plate 21. The dropped drainage is successively accumulated on the lower porous plate 21, dropped in the meandering hot air passage 221 and finally returned to the drainage stored in the bottom of the evaporation tower 14. The water droplets of the waste water falling in the meandering hot air passage 22 are heated in contact with the hot air rising in the meandering hot air passage 22 and the water in the waste water evaporates. The deposited sludge falls into the wastewater accumulated on the lower porous plate 21 and finally returns to the wastewater stored at the bottom of the evaporation tower 14.
[0013]
A part of the waste water discharged from the upper end of the evaporation tower 17 of the drain pipe 17 becomes mist and is raised by hot air rising in the evaporation tower 14, but is collected by the mist collecting filter 23.
The water vapor separated from the waste water is sucked into the exhaust fan 15 together with the exhaust gas, and is discharged from the waste water evaporator through the exhaust duct 16.
[0014]
Part of the wastewater stored at the bottom of the evaporation tower 14 is misted in the hot air generating furnace 11, and sludge deposited as a result of evaporation of water in the wastewater mist falls to the bottom of the hot air generating furnace 11. By accumulating and not returning to the wastewater stored at the bottom of the evaporation tower 14, an increase in the sludge concentration in the wastewater stored at the bottom of the evaporation tower 14 is suppressed, and sludge precipitation on the mist collecting filter 23 is prevented. The clogging of the mist collecting filter 23 is suppressed.
[0015]
By dripping the waste water from the perforated plate 21, generation of waste water mist in the evaporation tower 14 is suppressed while ensuring a sufficient contact area between the waste water and hot air, and sludge precipitation in the mist collecting filter 23 is suppressed. The clogging of the mist collecting filter 23 is suppressed.
By disposing the plurality of perforated plates 21 in the vertical direction at intervals, the contact area between the hot air and the drainage increases, and the drainage evaporation efficiency improves.
When hot air flows through the meandering hot air passage 22, the residence time of the hot air in the evaporation tower 14 increases, the temperature of the evaporation tower 14 rises, and the evaporation efficiency of waste water improves.
[0016]
【The invention's effect】
As described above, in the present invention, a portion of the wastewater stored at the bottom of the evaporation tower is misted in the hot air generating furnace, and the sludge precipitated by the evaporation of water in the wastewater mist is the hot air generating furnace. By not returning to the wastewater accumulated at the bottom of the evaporation tower and stored at the bottom of the evaporation tower, the increase in sludge concentration in the wastewater stored at the bottom of the evaporation tower is suppressed, and sludge precipitation on the mist collecting filter is suppressed. Thus, clogging of the mist collecting filter is suppressed.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view of a conventional waste water evaporator.
FIG. 2 is a cross-sectional view of a wastewater evaporation apparatus according to an embodiment of the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1,14 Evaporation tower 5,17,19 Drain pipe 7,20 Spray nozzle 8,23 Mist collection filter 11 Hot-air generation furnace 13 Hot-air channel | path 21 Porous board 22 Meandering hot-air channel | path

Claims (4)

熱風発生炉と、熱風通路を介して熱風発生炉に連通する蒸発塔と、蒸発塔の底部から蒸発塔上部と熱風発生炉上部とへ延びる排水通路と、排水通路の途上に配設されたポンプと、排水通路の熱風発生炉上部側端部に取り付けられたスプレーノズルと、蒸発塔内に且つ排水通路の蒸発塔上部側端部より上方に配設されたミスト捕集フィルターとを備えることを特徴とする排水蒸発装置。Hot air generating furnace, an evaporation tower communicating with the hot air generating furnace via the hot air passage, a drainage passage extending from the bottom of the evaporation tower to the upper part of the evaporation tower and the upper part of the hot air generating furnace, and a pump disposed in the middle of the drainage passage A spray nozzle attached to the upper end of the hot air generating furnace of the drainage passage, and a mist collecting filter disposed in the evaporation tower and above the upper end of the upper side of the drainage passage of the drainage passage. A wastewater evaporation device. 蒸発塔内に且つ排水通路の蒸発塔上部側端部より下方に配設された多孔板を備えることを特徴とする請求項1に記載の排水蒸発装置。The wastewater evaporation apparatus according to claim 1, further comprising a perforated plate disposed in the evaporation tower and below the upper end of the drainage passage on the upper side of the evaporation tower. 上下方向に互いに間隔を隔てて配設された複数の多孔板を備えることを特徴とする請求項2に記載の排水蒸発装置。The waste water evaporation apparatus according to claim 2, comprising a plurality of perforated plates arranged at intervals in the vertical direction. 複数の多孔板によって形成された蛇行通路を備えることを特徴とする請求項3に記載の排水蒸発装置。The drainage evaporator according to claim 3, further comprising a meandering passage formed by a plurality of perforated plates.
JP2003200457A 2003-07-23 2003-07-23 Wastewater evaporation apparatus Pending JP2005040662A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112744882A (en) * 2021-01-22 2021-05-04 嘉兴港区工业污水处理有限公司 Recycling system of toxic and harmful degradation-resistant wastewater
CN117125761A (en) * 2023-09-06 2023-11-28 河北金科环保设备有限公司 Evaporation tower for desulfurization wastewater
KR102662139B1 (en) * 2023-11-13 2024-05-02 덕산실업(주) Purification method and purification apparatus of nmp

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112744882A (en) * 2021-01-22 2021-05-04 嘉兴港区工业污水处理有限公司 Recycling system of toxic and harmful degradation-resistant wastewater
CN117125761A (en) * 2023-09-06 2023-11-28 河北金科环保设备有限公司 Evaporation tower for desulfurization wastewater
CN117125761B (en) * 2023-09-06 2024-03-12 河北金科环保设备有限公司 Evaporation tower for desulfurization wastewater
KR102662139B1 (en) * 2023-11-13 2024-05-02 덕산실업(주) Purification method and purification apparatus of nmp

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