JP2005037020A - Heat accumulation type air conditioner - Google Patents

Heat accumulation type air conditioner Download PDF

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Publication number
JP2005037020A
JP2005037020A JP2003198837A JP2003198837A JP2005037020A JP 2005037020 A JP2005037020 A JP 2005037020A JP 2003198837 A JP2003198837 A JP 2003198837A JP 2003198837 A JP2003198837 A JP 2003198837A JP 2005037020 A JP2005037020 A JP 2005037020A
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Japan
Prior art keywords
heat storage
indoor
cleaning device
connection port
valve
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2003198837A
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Japanese (ja)
Inventor
Kosaku Yagi
浩作 八木
Sadao Sekiya
禎夫 関谷
Junichiro Tezuka
純一郎 手塚
Naoto Katsumata
直登 勝又
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Hitachi Ltd
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Hitachi Ltd
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Filing date
Publication date
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Priority to JP2003198837A priority Critical patent/JP2005037020A/en
Publication of JP2005037020A publication Critical patent/JP2005037020A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a heat accumulation type air conditioner capable of enhancing the cleaning performance and cleaning pipes in a short time. <P>SOLUTION: In the heat accumulation type air conditioner comprises an outdoor unit, a heat accumulation unit and an indoor unit which are pipe-connected to each other. The heat accumulation type air conditioner has a first control valve 61 provided inside the heat accumulation unit between a heat accumulation expansion device 8 and an indoor expansion device 11, a second control valve 62 provided inside the heat accumulation unit between a first heat accumulation control valve 51 and an indoor heat exchanger 12, a first cleaning device connection port 71 provided inside the heat accumulation unit in the middle of the pipe between the first control valve 51 and the indoor expansion device 11, and a second cleaning device connection port 72 provided inside the heat accumulation unit in the middle of the pipe between a second control valve 52 and the indoor heat exchanger 12. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
本発明は、蓄熱式空気調和機に関する。
【0002】
【従来の技術】
従来、空気調和機の冷媒としては、CFCクロロフルオロカーボンやHCFCハイドロクロロフルオロカーボンが用いられてきたが、これらの冷媒が大気中に放出された場合、これらの冷媒に含まれる塩素原子が、オゾン層を破壊する恐れがあり、CFCが全廃され、HCFCについても全廃することが決まっている。これらの冷媒に替わり、塩素原子を含まないHFCハイドロフルオロカーボンが使用されはじめている。
【0003】
しかし、HCFC冷媒使用の空気調和機で使用されていた冷凍機油は、HFC冷媒との相溶性が非常に少ない。また、CFC系冷媒やHCFC系冷媒を使用した空気調和機を、HFC系冷媒を使用する空気調和機に変更する場合、既設配管を利用することが良いが、そのためには冷凍サイクル内を冷凍機油を除去する洗浄を行なう必要がある。そして、配管を洗浄する場合は、室外ユニット、蓄熱ユニット、室内ユニットを順次配管で連結し、室外ユニットの圧縮機を駆動させて室外ユニットと蓄熱ユニットを連結する配管、蓄熱ユニットと室内ユニットを連結する配管の内部を洗浄することが知られ、例えば特開2003−90652号公報に記載されている。
【特許文献1】
特開2003−90652号公報
【0004】
【発明が解決しようとする課題】
上記従来の技術では、蓄熱ユニット内部の弁体による圧力損失により洗浄流体の流速の低下による洗浄性能の低下が起き、蓄熱ユニットから室内ユニットまでの配管洗浄に時間が掛かったり、冷凍機油の付着が多くなったりする。また、蓄熱熱交換器は、複数の配管が並列に配置されるので、洗浄冷媒の流速が落ち、配管洗浄により冷媒中に溶けた油が蓄熱熱交換器に溜まりやすくなる。
【0005】
本発明は、上記従来技術の課題を解決し、洗浄性能を向上し、短時間で配管洗浄を行うことのできる蓄熱式空気調和機を提供することにある。
【0006】
【課題を解決するための手段】
本発明は、圧縮機、室外熱交換器を有する室外ユニットと、蓄熱熱交換器、蓄熱媒体、蓄熱膨張装置、第1蓄熱開閉弁が配管で順次連結された蓄熱ユニットと、室内熱交換器と室内膨張装置を有する室内ユニットと、が配管接続された蓄熱式空気調和機において、前記蓄熱膨張装置と前記室内膨張装置との間であり、前記蓄熱ユニット内部に設けられた第1開閉弁と、前記第1蓄熱開閉弁と前記室内熱交換器との間であり、前記蓄熱ユニット内部に設けられた第2開閉弁と、前記第1開閉弁と前記室内膨張装置との配管途中であり、前記蓄熱ユニット内に設けられた第1洗浄装置接続口と、前記第2開閉弁と前記室内熱交換器との配管途中であり、前記蓄熱ユニット内に設けられた第2洗浄装置接続口と、を備えたものである。
【0007】
また、上記のものにおいて、洗浄装置の吐出側接続口を前記第1洗浄装置接続口へ、洗浄装置の吸入側接続口を前記第2洗浄装置接続口へ接続し、前記洗浄装置を運転するときは前記室内膨張装置を開くことが望ましい。
【0008】
さらに、上記のものにおいて、前記室内ユニットを複数台備え、洗浄装置の吐出側接続口を前記第1洗浄装置接続口へ、洗浄装置の吸入側接続口を前記第2洗浄装置接続口へ接続し、前記洗浄装置を運転するときは前記複数台のうち一部の前記室内膨張装置を開き、他の前記室内膨張装置を閉じることが望ましい。
【0009】
【発明の実施の形態】
以下、図面を参照して実施の形態を説明する。
図1は一実施の形態を示し、室外ユニットは圧縮機1、四方弁2、熱交換器3、室外膨張装置4が順次配管で連結され、蓄熱ユニットは第1蓄熱開閉弁51、第2蓄熱開閉弁52、第3蓄熱開閉弁53、第1開閉弁61、第2開閉弁62、第1洗浄装置接続口71、第2洗浄装置接続口72、蓄熱膨張装置8、蓄熱媒体9、蓄熱熱交換器10で構成され、室内ユニットは室内膨張装置11、室内熱交換器12が順次配管で連結されている。
【0010】
第2蓄熱開閉弁52は室外膨張装置4と室内膨張装置11とを接続する配管途中に配置され、第1開閉弁61は第2蓄熱開閉弁52と室内膨張装置11とを接続する配管途中に配置される。第2開閉弁62は四方弁2と室内熱交換器12との接続配管の途中に配置される。第2蓄熱開閉弁52と第1開閉弁61との接続配管の途中で分岐部と、蓄熱膨張装置8、蓄熱熱交換器10、第3蓄熱開閉弁53と、四方弁2と第1開閉弁62との接続配管の途中の分岐部分と、が順次配管で連結される。
蓄熱熱交換器10と第3蓄熱開閉弁53とを接続する配管途中の分岐部分と、室外膨張装置4と第2蓄熱開閉弁52とを接続する配管途中の分岐部分と、は第1蓄熱開閉弁51を介して連結される。
蓄熱ユニット内部にサイクル配管内の油を除去するためサイクル配管洗浄装置を接続する。そして、接続するための第1洗浄装置接続口71は、第1開閉弁61と室内膨張装置11との配管途中に設けられる。さらに、第2洗浄装置接続口72を第2開閉弁62と室内熱交換器12との配管途中設ける。
【0011】
図2は洗浄装置と室外ユニットと蓄熱ユニットと室内ユニット間の伝送線の配線を示し、伝送線は洗浄装置制御装置、室外ユニット制御装置、蓄熱ユニット制御装置、室内ユニット制御装置を順次連結している。
図3は洗浄装置を示し、洗浄装置には冷媒を循環する冷媒循環装置およびサイクル配管内の油を回収する油回収容器が配置され、洗浄装置吸入側接続口および洗浄装置吐出側接続口が設けられている。
【0012】
図を参照して洗浄方法について以下説明する。
室内ユニットと蓄熱ユニット間を接続する配管は、CFC系冷媒あるいはHCFC冷媒で使用された配管であり、内面には冷凍機油が付着している。また、室外ユニットと蓄熱ユニット間を接続する配管は、新品の配管である。
【0013】
洗浄装置の吐出側接続口を第1洗浄装置接続口71へ、吸入側接続口を第2洗浄装置接続口72に接続し、第1開閉弁61と第2開閉弁62を開ける。第1開閉弁61と第2開閉弁62を開ける動作は、手動または洗浄装置からの指令で行う。
【0014】
洗浄装置の運転を始めると、洗浄装置の制御装置から、室内膨張装置11の制御情報が伝送線で送られ、室内膨張装置11が開き、洗浄装置の冷媒循環装置が駆動し洗浄用の冷媒であるCFC系またはHCHC系の冷媒が蓄熱ユニットと室内ユニット間の配管内を流れ、冷媒が配管内面に付着している冷凍機油を溶かすとともに、冷媒の流れにより、洗浄装置内に設置されている油回収容器に油が溜められる。洗浄装置の制御装置で洗浄完了と判断すると室内膨張装置11の制御情報が伝送線で送られ、室内膨張装置11が閉じられる。
【0015】
また、図4に示されるように、複数台の室内ユニットが接続された場合は、室内ユニットaのみ室内膨張装置11が開き、室内ユニットb、室内ユニットcの室内膨張装置11は閉じたまたとする。この指令は洗浄装置運転を始めた時、洗浄装置の制御装置から伝送線で送られ、洗浄装置の冷媒循環装置が駆動し洗浄運転が開始される。
室内ユニットaと蓄熱ユニット間の配管が洗浄完了すると、室内ユニットbと蓄熱ユニット間との配管洗浄を開始すべく、室内ユニットbのみ室内膨張装置11が開き、室内ユニットa、室内ユニットcの室内膨張装置11は閉じたまたとする。このように、複数台室内ユニットが接続された洗浄運転を実施する場合は、1台のみ室内ユニットの室内膨張装置を開け、他の室内ユニットの室内膨張装置は閉じておくような動作となる。
【0016】
以上、蓄熱ユニットと室内ユニット間を連結する配管内の洗浄運転を行うことにより、洗浄流体が蓄熱ユニット内部の弁体による圧力損失により洗浄流体の流速の低下による洗浄性能の低下を防ぐことができる。
【0017】
【発明の効果】
本発明によれば、洗浄性能を向上し、短時間で配管洗浄を行うことができる。
【図面の簡単な説明】
【図1】本発明による一実施の形態を示す空気調和機のブロック図。
【図2】一実施の形態による空気調和機及び洗浄装置の制御装置を連結する伝送線の接続を示すブロック図。
【図3】一実施の形態による洗浄装置を示すブロック図。
【図4】他の実施の形態による空気調和機を示すブロック図。
【符号の説明】
1…圧縮機、2…四方弁、3…室外熱交換器、4…室外膨張装置、51…第1蓄熱開閉弁、52…第2蓄熱開閉弁、53…第3蓄熱開閉弁、61…第1開閉弁、62…第2開閉弁、71…第1洗浄装置接続口、72…第2洗浄装置接続口、8…蓄熱膨張装置、9…蓄熱媒体、10…蓄熱熱交換器、11…室内膨張装置、12…室内熱交換器。
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a heat storage type air conditioner.
[0002]
[Prior art]
Conventionally, CFC chlorofluorocarbons and HCFC hydrochlorofluorocarbons have been used as air conditioner refrigerants. When these refrigerants are released into the atmosphere, chlorine atoms contained in these refrigerants cause the ozone layer. There is a risk of destruction, and CFC is completely abolished, and HCFC is also abolished. Instead of these refrigerants, HFC hydrofluorocarbons not containing chlorine atoms are beginning to be used.
[0003]
However, the refrigerating machine oil used in the air conditioner using the HCFC refrigerant has very little compatibility with the HFC refrigerant. In addition, when an air conditioner that uses a CFC refrigerant or an HCFC refrigerant is changed to an air conditioner that uses an HFC refrigerant, it is preferable to use an existing pipe. It is necessary to perform cleaning to remove the. When cleaning the piping, connect the outdoor unit, the heat storage unit, and the indoor unit sequentially with the piping, and drive the outdoor unit compressor to connect the outdoor unit and the heat storage unit. It is known to clean the inside of piping to be performed, and is described in, for example, Japanese Patent Application Laid-Open No. 2003-90652.
[Patent Document 1]
Japanese Patent Laid-Open No. 2003-90652
[Problems to be solved by the invention]
In the above-described conventional technology, the pressure loss due to the valve body inside the heat storage unit causes a decrease in the cleaning performance due to a decrease in the flow rate of the cleaning fluid, and it takes time to clean the piping from the heat storage unit to the indoor unit, and the refrigeration oil adheres. It will increase. In addition, since a plurality of pipes are arranged in parallel in the heat storage heat exchanger, the flow rate of the cleaning refrigerant is decreased, and oil dissolved in the refrigerant by the pipe cleaning is easily accumulated in the heat storage heat exchanger.
[0005]
The present invention provides a regenerative air conditioner that solves the above-mentioned problems of the prior art, improves the cleaning performance, and can perform pipe cleaning in a short time.
[0006]
[Means for Solving the Problems]
The present invention includes a compressor, an outdoor unit having an outdoor heat exchanger, a heat storage heat exchanger, a heat storage medium, a heat storage expansion device, a heat storage unit in which a first heat storage on-off valve is sequentially connected by piping, an indoor heat exchanger, In a heat storage air conditioner piped to an indoor unit having an indoor expansion device, a first on-off valve provided between the heat storage expansion device and the indoor expansion device and provided inside the heat storage unit; Between the first heat storage on-off valve and the indoor heat exchanger, in the middle of piping between the second on-off valve provided inside the heat storage unit, the first on-off valve and the indoor expansion device, A first cleaning device connection port provided in the heat storage unit, and a second cleaning device connection port provided in the heat storage unit that is in the middle of piping between the second on-off valve and the indoor heat exchanger. It is provided.
[0007]
In the above, when the cleaning device is operated by connecting the discharge side connection port of the cleaning device to the first cleaning device connection port and the suction side connection port of the cleaning device to the second cleaning device connection port. It is desirable to open the indoor expansion device.
[0008]
Further, in the above, the apparatus includes a plurality of the indoor units, the discharge side connection port of the cleaning device is connected to the first cleaning device connection port, and the suction side connection port of the cleaning device is connected to the second cleaning device connection port. When operating the cleaning device, it is preferable that some of the plurality of indoor expansion devices are opened and the other indoor expansion devices are closed.
[0009]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, embodiments will be described with reference to the drawings.
FIG. 1 shows an embodiment, in which an outdoor unit includes a compressor 1, a four-way valve 2, a heat exchanger 3, and an outdoor expansion device 4 sequentially connected by piping, and a heat storage unit includes a first heat storage on-off valve 51 and a second heat storage. On-off valve 52, third heat storage on-off valve 53, first on-off valve 61, second on-off valve 62, first cleaning device connection port 71, second cleaning device connection port 72, heat storage expansion device 8, heat storage medium 9, heat storage heat The indoor unit includes an indoor expansion device 11 and an indoor heat exchanger 12 that are sequentially connected by piping.
[0010]
The second heat storage on / off valve 52 is arranged in the middle of the piping connecting the outdoor expansion device 4 and the indoor expansion device 11, and the first on-off valve 61 is in the middle of the piping connecting the second heat storage on / off valve 52 and the indoor expansion device 11. Be placed. The second on-off valve 62 is disposed in the middle of the connection pipe between the four-way valve 2 and the indoor heat exchanger 12. A branch portion, a heat storage expansion device 8, a heat storage heat exchanger 10, a third heat storage on-off valve 53, a four-way valve 2, and a first on-off valve in the middle of a connection pipe between the second heat storage on-off valve 52 and the first on-off valve 61 The branch portion in the middle of the connection pipe to 62 is sequentially connected by the pipe.
A branch part in the middle of the pipe connecting the heat storage heat exchanger 10 and the third heat storage on / off valve 53 and a branch part in the middle of the pipe connecting the outdoor expansion device 4 and the second heat storage on / off valve 52 are the first heat storage on / off. The valve 51 is connected.
A cycle piping cleaning device is connected to the heat storage unit to remove oil in the cycle piping. The first cleaning device connection port 71 for connection is provided in the middle of the piping between the first on-off valve 61 and the indoor expansion device 11. Furthermore, the 2nd washing | cleaning apparatus connection port 72 is provided in the middle of piping of the 2nd on-off valve 62 and the indoor heat exchanger 12. FIG.
[0011]
FIG. 2 shows the wiring of the transmission line between the cleaning device, the outdoor unit, the heat storage unit, and the indoor unit. The transmission line connects the cleaning device control device, the outdoor unit control device, the heat storage unit control device, and the indoor unit control device in order. Yes.
FIG. 3 shows a cleaning device. The cleaning device is provided with a refrigerant circulation device that circulates a refrigerant and an oil recovery container that recovers oil in the cycle piping, and is provided with a cleaning device suction side connection port and a cleaning device discharge side connection port. It has been.
[0012]
The cleaning method will be described below with reference to the drawings.
The pipe connecting the indoor unit and the heat storage unit is a pipe used for a CFC refrigerant or HCFC refrigerant, and refrigeration oil is attached to the inner surface. Further, the pipe connecting the outdoor unit and the heat storage unit is a new pipe.
[0013]
The discharge side connection port of the cleaning device is connected to the first cleaning device connection port 71, the suction side connection port is connected to the second cleaning device connection port 72, and the first on-off valve 61 and the second on-off valve 62 are opened. The operation of opening the first on-off valve 61 and the second on-off valve 62 is performed manually or by a command from the cleaning device.
[0014]
When the operation of the cleaning device is started, control information of the indoor expansion device 11 is sent from the control device of the cleaning device via a transmission line, the indoor expansion device 11 is opened, the refrigerant circulation device of the cleaning device is driven, and the cleaning refrigerant is used. A certain CFC-based or HCHC-based refrigerant flows through the pipe between the heat storage unit and the indoor unit, and the refrigerant dissolves the refrigeration oil adhering to the inner surface of the pipe. Oil is collected in the collection container. When the control device of the cleaning device determines that the cleaning is completed, control information for the indoor expansion device 11 is sent via a transmission line, and the indoor expansion device 11 is closed.
[0015]
As shown in FIG. 4, when a plurality of indoor units are connected, the indoor expansion device 11 is opened only for the indoor unit a, and the indoor expansion devices 11 of the indoor units b and c are closed. To do. This command is sent from the control device of the cleaning device via a transmission line when the cleaning device operation is started, and the refrigerant circulation device of the cleaning device is driven to start the cleaning operation.
When the piping between the indoor unit a and the heat storage unit is completely cleaned, the indoor expansion device 11 is opened only in the indoor unit b to start the piping cleaning between the indoor unit b and the heat storage unit, and the indoor units a and c The expansion device 11 is also closed. As described above, when the cleaning operation in which a plurality of indoor units are connected is performed, the operation is performed such that only one indoor expansion device of the indoor unit is opened and the indoor expansion devices of the other indoor units are closed.
[0016]
As described above, by performing the cleaning operation in the pipe connecting the heat storage unit and the indoor unit, it is possible to prevent the cleaning fluid from being deteriorated due to the decrease in the flow rate of the cleaning fluid due to the pressure loss due to the valve body inside the heat storage unit. .
[0017]
【The invention's effect】
According to the present invention, it is possible to improve the cleaning performance and perform pipe cleaning in a short time.
[Brief description of the drawings]
FIG. 1 is a block diagram of an air conditioner showing an embodiment according to the present invention.
FIG. 2 is a block diagram showing the connection of transmission lines that connect the control device for the air conditioner and the cleaning device according to one embodiment.
FIG. 3 is a block diagram showing a cleaning device according to one embodiment.
FIG. 4 is a block diagram showing an air conditioner according to another embodiment.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Compressor, 2 ... Four-way valve, 3 ... Outdoor heat exchanger, 4 ... Outdoor expansion apparatus, 51 ... 1st heat storage on-off valve, 52 ... 2nd heat storage on-off valve, 53 ... 3rd heat storage on-off valve, 61 ... 1st DESCRIPTION OF SYMBOLS 1 ... On-off valve, 62 ... 2nd on-off valve, 71 ... 1st washing | cleaning apparatus connection port, 72 ... 2nd washing | cleaning apparatus connection port, 8 ... Thermal storage expansion apparatus, 9 ... Thermal storage medium, 10 ... Thermal storage heat exchanger, 11 ... Indoor Expansion device, 12 ... indoor heat exchanger.

Claims (3)

圧縮機、室外熱交換器を有する室外ユニットと、蓄熱熱交換器、蓄熱媒体、蓄熱膨張装置、第1蓄熱開閉弁が配管で順次連結された蓄熱ユニットと、室内熱交換器と室内膨張装置を有する室内ユニットと、が配管接続された蓄熱式空気調和機において、
前記蓄熱膨張装置と前記室内膨張装置との間であり、前記蓄熱ユニット内部に設けられた第1開閉弁と、
前記第1蓄熱開閉弁と前記室内熱交換器との間であり、前記蓄熱ユニット内部に設けられた第2開閉弁と、
前記第1開閉弁と前記室内膨張装置との配管途中であり、前記蓄熱ユニット内に設けられた第1洗浄装置接続口と、
前記第2開閉弁と前記室内熱交換器との配管途中であり、前記蓄熱ユニット内に設けられた第2洗浄装置接続口と、
を備えたことを特徴とした蓄熱式空気調和機。
An outdoor unit having a compressor, an outdoor heat exchanger, a heat storage heat exchanger, a heat storage medium, a heat storage expansion device, a heat storage unit in which a first heat storage on / off valve is sequentially connected by piping, an indoor heat exchanger, and an indoor expansion device In the regenerative air conditioner in which the indoor unit has a pipe connection,
A first on-off valve provided between the heat storage expansion device and the indoor expansion device and provided inside the heat storage unit;
A second on-off valve provided between the first heat storage on-off valve and the indoor heat exchanger, and provided inside the heat storage unit;
In the middle of piping between the first on-off valve and the indoor expansion device, a first cleaning device connection port provided in the heat storage unit,
In the middle of piping between the second on-off valve and the indoor heat exchanger, a second cleaning device connection port provided in the heat storage unit,
A regenerative air conditioner characterized by comprising
請求項1に記載のものにおいて、洗浄装置の吐出側接続口を前記第1洗浄装置接続口へ、洗浄装置の吸入側接続口を前記第2洗浄装置接続口へ接続し、前記洗浄装置を運転するときは前記室内膨張装置を開くことを特徴とする蓄熱式空気調和機。2. The apparatus according to claim 1, wherein the discharge side connection port of the cleaning device is connected to the first cleaning device connection port, the suction side connection port of the cleaning device is connected to the second cleaning device connection port, and the cleaning device is operated. A regenerative air conditioner is characterized in that when the indoor expansion device is opened. 請求項1に記載のものにおいて、前記室内ユニットを複数台備え、洗浄装置の吐出側接続口を前記第1洗浄装置接続口へ、洗浄装置の吸入側接続口を前記第2洗浄装置接続口へ接続し、前記洗浄装置を運転するときは前記複数台のうち一部の前記室内膨張装置を開き、他の前記室内膨張装置を閉じることを特徴とする蓄熱式空気調和機。2. The apparatus according to claim 1, comprising a plurality of the indoor units, wherein a discharge-side connection port of the cleaning device is connected to the first cleaning device connection port, and a suction-side connection port of the cleaning device is connected to the second cleaning device connection port. When connecting and operating the said washing | cleaning apparatus, some said indoor expansion apparatuses are opened among these units | sets, and the said other indoor expansion apparatus is closed, The thermal storage air conditioner characterized by the above-mentioned.
JP2003198837A 2003-07-18 2003-07-18 Heat accumulation type air conditioner Pending JP2005037020A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007105425A1 (en) * 2006-02-23 2007-09-20 Daikin Industries, Ltd. Method of recovering refrigerator oil

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007105425A1 (en) * 2006-02-23 2007-09-20 Daikin Industries, Ltd. Method of recovering refrigerator oil
AU2007225990B2 (en) * 2006-02-23 2010-02-11 Daikin Industries, Ltd. Method for the recovery of refrigeration oil

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