JP2004506750A - Detergent composition - Google Patents

Abstract

A hard surface detersive composition for removing cooking, burning and scorching stains from cookware and tableware, wherein the composition comprises an organic amine solvent and is less than about 24.5 mN / m. It has a liquid surface tension and has a pH of less than 10.5 when measured as a 10% distilled aqueous solution. The composition can be used for pre-treatment of dishwashing. The present composition can cleanly remove polymerized fats and oils from metal and glass substrates.

Description

【００４７】
Ｒ^１は平均約７〜約１２個の炭素原子を有する直鎖アルキル炭化水素であり、Ｒ^２は約１〜約４個の炭素原子を有する直鎖アルキル炭化水素であり、Ｒ^３は約１〜約４個の炭素原子を有する直鎖アルキル炭化水素であり、ｘは約１〜約６の整数、ｙは約４〜約１５の整数及びｚは約４〜約２５の整数である。
その他の低曇点非イオン性界面活性剤は、以下の式を有するエーテル末端保護ポリ（オキシアルキル化）である。
Ｒ_ＩＯ（Ｒ_ＩＩＯ）_ｎＣＨ（ＣＨ_３）ＯＲ_ＩＩＩ
Ｒ_Ｉは約７〜約１２個の炭素原子を有する直鎖又は分岐鎖、飽和又は不飽和、置換型又は非置換型、脂肪族又は芳香族の炭化水素基から成る群から選択され、Ｒ_ＩＩは同じ基でも異なる基でもよく、上記のいずれかの分子のうち、分岐鎖又は直鎖状Ｃ_２〜Ｃ_７のアルキレンから成る群から独立して選択され、ｎは１〜約３０の数であり、Ｒ_ＩＩＩは以下の群から選択される。
【００４８】
（ｉ）１〜３個のヘテロ原子を有する４〜８員環の置換型又は非置換型複素環、及び
（ｉｉ）約１〜約３０個の炭素原子を有する直鎖又は分岐鎖、飽和又は不飽和、置換型又は非置換型、環式又は非環式、脂肪族又は芳香族の炭化水素基。
（ｂ）Ｒ^２が（ｉｉ）の場合、（Ａ）Ｒ^１の少なくとも１つがＣ_２〜Ｃ_３アルキレン以外のものであるか、あるいは（Ｂ）Ｒ^２が６〜３０個の炭素原子を有し、更にＲ^２が８〜１８個の炭素原子を有する場合、ＲはＣ_１〜Ｃ_５アルキル以外のものである。
【００４９】
本明細書に好適なその他の成分には、分散性、再付着防止性、汚れ放出性又はその他の洗浄特性の発明を有する有機ポリマーが含まれる。その割合は、組成物の約０．１重量％〜約３０重量％、好ましくは約０．５重量％〜約１５重量％、最も好ましくは約１重量％〜約１０重量％である。本明細書において好ましい再付着防止ポリマーには、ポリマー含有アクリル酸（例えば、ＳｏｋａｌａｎＰＡ３０、ＰＡ２０、ＰＡ１５、ＰＡ１０及びＳｏｋａｌａｎＣＰ１０（ＢＡＳＦ ＧｍｂＨ）、Ａｃｕｓｏｌ４５Ｎ、４８０Ｎ、４６０Ｎ（Ｒｏｈｍ ａｎｄ Ｈａａｓ））、アクリル酸／マレイン酸コポリマー（例えば、ＳｏｋａｌａｎＣＰ５）、及びアクリル／メタクリルコポリマーが含まれる。本明細書において好ましい汚れ放出ポリマーには、アルキル及びヒドロキシアルキルセルロース（米国特許第４，０００，０９３号）、ポリオキシエチレン、ポリオキシプロピレン及びこれらのコポリマー、並びにエチレングリコール、プロピレングリコール及びこれらの混合物のテレフタレートエステルに基づく非イオン性及びアニオン性ポリマーが含まれる。
【００５０】
重金属イオン封鎖剤及び結晶成長阻害剤は、一般に組成物の約０．００５重量％〜約２０重量％、好ましくは約０．１重量％〜約１０重量％、更に好ましくは約０．２５重量％〜約７．５重量％、最も好ましくは約０．５重量％〜約５重量％の割合で本明細書に用いるのに好適である。これらには、例えば、ジエチレントリアミンペンタ（メチレンホスホネート）、エチレンジアミンテトラ（メチレンホスホネート）、ヘキサメチレンジアミンテトラ（メチレンホスホネート）、エチレンジホスホネート、ヒドロキシエチレン−１，１−ジホスホネート、ニトリロトリアセテート、エチレンジアミノテトラアセテート、エチレンジアミン−Ｎ，Ｎ’−ジサクシネートの塩及び遊離酸の形態が挙げられる。
【００５１】
本明細書における組成物は、腐食防止剤を含有することができる。これには、例えば、組成物の約０．０５重量％〜約１０重量％、好ましくは約０．１重量％〜約５重量％の割合で含有される有機銀コーティング剤（とりわけ、Ｗｉｎｔｅｒｓｈａｌｌ（ドイツ、ザルツバーゲン）から市販されているＷｉｎｏｇ７０などのパラフィン）、窒素含有腐食防止剤化合物（例えば、ベンゾトリアゾール及びベンズイマダゾール−英国特許第１，１３７，７４１号参照）、及び組成物の約０．００５重量％〜約５重量％、好ましくは約０．０１重量％〜約１重量％、更に好ましくは約０．０２重量％〜約０．４重量％の割合で含有されるＭｎ（ＩＩ）化合物（とりわけ、有機配位子のＭｎ（ＩＩ）塩）が挙げられる。
【００５２】
本明細書におけるその他の好適な成分には、着色剤、約０．０１％〜約５％の割合で含有される水溶性ビスマス化合物（例えば、酢酸ビスマス及びクエン酸ビスマス）、約０．０１％〜約６％の割合で含有される酵素安定剤（例えば、カルシウムイオン、ホウ酸、プロピレングリコール及び塩素漂白剤捕捉剤）、石灰石鹸分散剤（ＷＯ−Ａ−９３／０８８７７号参照）、石鹸泡抑制剤（ＷＯ−Ａ−９３／０８８７６号及び欧州特許第０，７０５，３２４号参照）、ポリマー染料転移阻害剤、光学的光沢剤、香料、充填剤及び粘土が含まれる。
液体洗剤組成物は、キャリアとして水及びその他の揮発性溶媒を含有することができる。本発明の液体洗剤には、少量の低分子量一級又は二級アルコール（例えば、メタノール、エタノール、プロパノール及びイソプロパノール）を使用することができる。少量で使用されるその他の好適なキャリア溶媒には、グリセロール、プロピレングリコール、エチレングリコール、１，２−プロパンジオール、ソルビトール及びこれらの混合物が含まれる。
【００５３】
臭いマスキングベース
臭いマスキングベース（この単語には、完全処方の臭いマスキング香料又はその中に使用するベース組成物が含まれる）は、イオノン、ジャコウ及び高揮発性香料の混合物であることが好ましい。臭いマスキングベースの濃度は、組成物の約０．００１重量％〜約３重量％、好ましくは約０．００６重量％〜約２．５重量％、更に好ましくは約０．００７５重量％〜約１重量％の範囲であることが好ましい。
【００５４】
臭いマスキングベースのイオノン、ジャコウ及び高揮発性香料は、各成分の沸点の範囲に１つの特徴を有する。イオノン及びジャコウは、１気圧において約２５０℃超過の沸点を有することが好ましい。一方、高揮発性香料成分は、１気圧において約２５０℃未満の沸点を有する。多くの香料物質の沸点は、例えば、「Ｐｅｒｆｕｍｅ ａｎｄ Ｆｌａｖｏｒ Ｃｈｅｍｉｃａｌｓ（Ａｒｏｍａ Ｃｈｅｍｉｃａｌｓ）」（Ｓ． Ａｒｃｔａｎｄｅｒ、著者出版、１９６９年）に開示されている。その他の沸点は、種々の化学ハンドブック及びデータベース（例えば、ｔｈｅ Ｂｅｉｌｓｔｅｉｎ Ｈａｎｄｂｏｏｋ、Ｌａｎｇｅ’ｓ Ｈａｎｄｂｏｏｋ ｏｆ Ｃｈｅｍｉｓｔｒｙ、及びｔｈｅ ＣＲＣ Ｈａｎｄｂｏｏｋ ｏｆ Ｃｈｅｍｉｓｔｒｙ ａｎｄ Ｐｈｙｓｉｃｓ）から得ることができる。異なる圧力（通常、１標準気圧より低い圧力）における沸点だけが提示されている場合、標準圧又は外気圧における沸点は、沸点−圧力計算図表を使用して概算することができる。この沸点−圧力計算図表には、例えば「Ｔｈｅ Ｃｈｅｍｉｓｔ’ｓ Ｃｏｍｐａｎｉｏｎ」（Ａ． Ｊ． Ｇｏｒｄｏｎ及びＲ． Ａ． Ｆｏｒｄ、Ｊｏｈｎ Ｗｉｌｅｙ ＆ Ｓｏｎｓ Ｐｕｂｌｉｓｈｅｒｓ、１９７２年、３０〜３６頁）に記載されているものがある。適用可能な場合には、沸点を分子構造データに基づいてコンピュータプログラムで計算することもできる。このようなプログラムには、例えば「Ｃｏｍｐｕｔｅｒ−Ａｓｓｉｓｔｅｄ Ｐｒｅｄｉｃｔｉｏｎ ｏｆ Ｎｏｒｍａｌ Ｂｏｉｌｉｎｇ Ｐｏｉｎｔｓ ｏｆ Ｐｙｒａｎｓ ａｎｄ Ｐｙｒｒｏｌｅｓ」（Ｄ． Ｔ．Ｓｔａｎｔｏｎら、Ｊ． Ｃｈｅｍ． Ｉｎｆ． Ｃｏｍｐｕｔ． Ｓｃｉ．、３２、１９９２年、３０６〜３１６頁）、「Ｃｏｍｐｕｔｅｒ−Ａｓｓｉｓｔｅｄ Ｐｒｅｄｉｃｔｉｏｎ ｏｆ Ｎｏｒｍａｌ Ｂｏｉｌｉｎｇ Ｐｏｉｎｔｓ ｏｆ Ｆｕｒａｎｓ， Ｔｅｔｒａｈｙｄｒｏｆｕｒａｎｓ， ａｎｄ Ｔｈｉｏｐｈｅｎｅｓ」（Ｄ． Ｔ． Ｓｔａｎｔｏｎら、Ｊ． Ｃｈｅｍ． Ｉｎｆ． Ｃｏｍｐｕｔ． Ｓｃｉ．、３１、１９９２年、３０１〜３１０頁）及びこれらの中で引用している参照文献、並びに「Ｐｒｅｄｉｃｔｉｎｇ Ｐｈｙｓｉｃａｌ Ｐｒｏｐｅｒｔｉｅｓ ｆｒｏｍ Ｍｏｌｅｃｕｌａｒ Ｓｔｒｕｃｔｕｒｅ」（Ｒ． Ｍｕｒｕｇａｎら、Ｃｈｅｍｔｅｃｈ、１９９４年６月、１７〜２３頁）に記述されているものがある。
臭いマスキングベースのイオノン香料、高揮発性香料及びジャコウ成分の各成分について、以下に詳細に記述する。
【００５５】
高揮発性香料
臭いマスキングベースの高揮発性香料は、悪臭溶媒と競合して鼻のレセプター受容体部に到達する香料物質を含有する。これらの高揮発性香料は、脳に最初に認識され、識別される臭いであり、嗅覚における溶媒認識を阻害又はマスクすることに役立つ。高揮発性香料の濃度は、臭いマスキングベースの約１５重量％〜約８５重量％、好ましくは約２０重量％〜約８０重量％、更に好ましくは約３５重量％〜約７５重量％、より好ましくは約４５重量％〜約６５重量％である。
高揮発性香料は、臭いマスキングベースのイオノン及びジャコウ成分より揮発性が高く、１気圧において約２５０℃未満、好ましくは約２３０℃未満、更に好ましくは約２２０℃未満の沸点を有する。これらの高揮発性香料は、約２〜１５個の炭素原子を有するアルデヒド、約３〜１５個の炭素原子を有するエステル、約４〜１２個の炭素原子を有するアルコール、約４〜１３個の炭素原子を有するエーテル、約３〜１２個の炭素原子を有するケトン又はこれらの組み合わせとして分類される。
【００５６】
好適なアルデヒドの例には、ｎ−デシルアルデヒド、１０−ウンデセン−１−アル、ドデカナール、３，７−ジメチル−７−ヒドロキシオクタン−１−アル、２，４−ジメチル−３−シクロヘキセンカルボキシアルデヒド、ベンズアルデヒド、アニスアルデヒド及びこれらの混合物が含まれるが、これらに限定されない。
好適なエーテルの例には、エチルアセテート、シス−３−ヘキセニルアセテート、２，６−ジメチル−２，６−オクタジエン−８−イルアセテート、ベンジルアセテート、１，１−ジメチル−２−フェニルアセテート、２−ペンチルオキシアリルエステル、アリルヘキサノエート、メチル−２−アミノベンゾエート及びこれらの混合物が含まれるが、これらに限定されない。
【００５７】
好適なアルコールの例には、ｎ−オクチルアルコール、β−γ−ヘキセノール、２−トランス−６−シス−ノナジエン−１−オル、３，７−ジメチル−トランス−２，６−オクタジエン−１−オル、３，７−ジメチル−６−オクテン−１−オル、３，７−ジメチル−１，６−オクタジエン−３−オル、２，６−ジメチル−７−オクテン−２−オル、２−フェニルエチルアルコール、２−シス−３，７−ジメチル−２，６−オクタジエン−１−オル、１−メチル−４−イソプロピル−１−シクロヘキセン−８−オル及びこれらの混合物が含まれるが、これらに限定されない。
好適なエーテルの例には、アミルクレゾールオキシド、４−エトキシ−１−メチル−ベンゾール、４−メトキシ−１−メチルベンゼン、メチルフェニルエチルエーテル及びこれらの混合物が含まれるが、これらに限定されない。
【００５８】
好適なケトンの例には、ジメチルアセトフェノン、エチル−ｎ−アミルケトン、２−ヘプタノン、２−オクタノン、３−メチル−２−（シス−２−ペンテン−１−イル）−２−シクロペンテン−１−オン、１−１−メチル−４−イソプロペニル−６−シクロヘキセン−２−オン、パラ−第三級アミルシクロヘキサノン及びこれらの混合物が含まれるが、これらに限定されない。
好ましい高揮発性香料には、２−ペンチルオキシアリルエステル（Ａｌｌｙｌ Ａｍｙｌ Ｇｌｙｃｏｌａｔｅの商標でＩｎｔｅｒｎａｔｉｏｎａｌ Ｆｌａｖｏｒｓ ａｎｄ Ｆｒａｇｒａｎｃｅｓ， Ｉｎｃ．（米国ニューヨーク州ニューヨーク）から市販されている）、ベンズアルデヒド（Ａｍａｎｄｏｌの商標でＲｈｏｎｅ−Ｐｏｕｌｅｎｃ， Ｉｎｃ（米国ニュージャージー州プリンストン）から市販されている）、シス−３−ヘキセニルアセテート（Ｖｅｒｄｕｒａｌ ｅｘｔｒａの商標でＩｎｔｅｒｎａｔｉｏｎａｌ Ｆｌａｖｏｒｓ ａｎｄ Ｆｒａｇｒａｎｃｅｓ， Ｉｎｃ．（米国ニューヨーク州ニューヨーク）から市販されている）、２，６−ジメチル−７−オクテン−２−オル（Ｄｉｈｙｄｒｏｍｙｒｃｅｎｏｌの商標でＩｎｔｅｒｎａｔｉｏｎａｌ Ｆｌａｖｏｒｓ ａｎｄ Ｆｒａｇｒａｎｃｅｓ， Ｉｎｃ．（米国ニューヨーク州ニューヨーク）から市販されている）、パラ−第三級アミルシクロヘキサノン（Ｏｒｉｖｏｎｅの商標でＩｎｔｅｒｎａｔｉｏｎａｌ Ｆｌａｖｏｒｓ ａｎｄ Ｆｒａｇｒａｎｃｅｓ， Ｉｎｃ．（米国ニューヨーク州ニューヨーク）から市販されている）、ｎ−デシルアルデヒド（Ｄｅｃｙｌ Ａｌｄｅｈｙｄｅの商標でＡｃｅｔｏ， Ｃｏｒｐ．（米国ニューヨーク州レークサクセス）から市販されている）及びこれらの混合物が含まれる。
好適な高揮発性香料の例及びそれらの１気圧における沸点は、米国特許第５，９１９，４４０号に開示されているが、これらに限定されない。
【００５９】
イオノン
臭いマスキングベースは、イオノン香料成分（つまり、イオノン又はイオノン混合物）を、臭いマスキングベースの約１５重量％〜約８０重量％、好ましくは約１６重量％〜約６０重量％、更に好ましくは約１６重量％〜約４０重量％の濃度で含有することが好ましい。イオノンは、天然油に由来するか、合成的に作られる香料化学物質においてよく知られた種類であり、典型的に無色又は淡黄色の液体で、森林スミレのような香りを呈する。
【００６０】
臭いマスキングベースに使用するイオノン香料は、１気圧において約２５０℃超過、好ましくは約２５５℃超過、更に好ましくは約２６０℃超過の沸点を有し、このときイオノン香料は、メチルイオノン、αイオノン、βイオノン、γイオノン又はこれらの組み合わせから選択されることが好ましい。
好適なイオノンの例には、１−（２，６，６−トリメチル−２−シクロヘキセン−１−イル）−１，６−ヘプタジエン−３−−オン、２−アリル−パラ−メンテン−（４（８））−オノ−３、擬似アリル−α−イオノン、α−シトリリデンシクロペンタノン、５−（２，６，６−トリメチル−２−シクロヘキセン−１−イル）−４−メチル−４−ペンテン−３−オン、６−（２，６，６−トリメチル−２−シクロヘキセン−１−イル）−１−メチル−５−ヘキセン−４−オン、２，６，６−トリメチルシクロヘキシル−１−ブテノン−３、ジヒドロ−α−イオノン、４−（２，６，６−トリメチルシクロヘキセン−１−イル）−ブタン−２−オン、４−（２−メチレン−６，６−ジメチルシクロヘキシル）−ブタン−２−オン、１−（２，５，６，６−テトラメチル−２−シクロヘキセニル）−ブタン−３−オン、ジヒドロ−β−イロン、ジヒドロ−γ−イロン、５−（２，６，６−トリメチル−２−シクロヘキセニル）−ペンタン−３−オン、シヒドロ−イソ−メチル−β−イオノン、６−（２，６，６−トリメチル−２−シクロヘキセン−１−イル）−５−ヘキセン−４−オン、α−エチル−２，２，６−トリメチルシクロヘキサンブチルアルデヒド、４−メチル−６−（１，１，３−トリメチル−２’−シクロヘキセン−２’−イル）−３，５−ヘキサジエン−２−オン、６，１０−ジメチルウンデカン−２−オン、６−（２，６，６−トリメチル−１−シクロヘキセン−１−イル）−１−メチル−２，５−ヘキサジエン−４−オン、６−（２，６，６−トリメチル−２−シクロヘキセン−１−イル）−１−メチル−２，５−ヘキサジエン−４−オン、４−（２，２，６−トリメチル−２−シクロヘキセン−１−イル）−３−ブテン−２−オン、４−（２，６，６−トリメチル−１−シクロヘキセン−１−イル）−３−ブテン−２−オン、４−（２−メチレン−６，６−ジメチルシクロヘキシル）−３−ブテン−２−オン、エポキシ−２，３−β−イオノン、エチル−２，３−エポキシ−３−メチル−５−（２，６，６−トリメチル−２−シクロヘキセニル）−４−ペンテノエート、α−イオノンアントラニル酸メチル、メチル−２，３−エポキシ−３−メチル−５−（２，６，６−トリメチル−２−シクロヘキセニル）−４−ペンテノエート、４−（２，５，６，６−テトラメチル−２−シクロヘキセン−１−イル）−３−ブテン−２−オン、６−メチル−β−イオノン、６−メチル−γ−イオノン、４−（２，６，６−トリメチル−２−シクロヘキセニル）−２，３−ジメチル−２−ブテン−１−アル、４−（２，６，６−トリメチル−２−シクロヘキセン−１−イル）−３−メチル−３−ブテン−２−オン、５−（２，６，６−トリメチル−２−シクロヘキセン−１−イル）−４−ペンテン−３−オン、５−（２，６，６−トリメチル−１−シクロヘキセン−１−イル）−４−ペンテン−３−オン、４−（２，６，６−トリメチル−３−シクロヘキセン−１−イル）−３−メチル−３−ブテン−２−オン、５−（２−メチレン−６，６−ジメチルシクロヘキシル）−４−ペンテン−３−オン、４−（２−メチレン−６，６−ジメチルシクロヘキシル）−３−メチル−３−ブテン−２−オン、４−（２，３，６，６−テトラメチル−２−シクロヘキセン−１−イル）−３−ブテン−２−オン、４−（２，４，６，６−テトラメチル−２−シクロヘキセン−１−イル）−３−ブテン−２−オン、４−（２，４，６，６−テトラメチル−１−シクロヘキセン−１−イル）−３−ブテン−２−オン、５−メチル−１−（３−メチル−３−シクロヘキセニル）−１，３−ヘキサンジオン、２−メチル−４−（２，６，６−トリメチル−２−シクロヘキセニル）−３−ブテン−１−アル、３−メチル−４−（２，４，６−トリメチル−３−シクロヘキセニル）−３−ブテン−２−オン、４−（２−メチル−５−イソ−プロペニル−１−シクロペンテン−１−イル）−２−ブタノン、４−（２，６，６−トリメチル−７−シクロヘプテニル）−３−ブテン−２−オン、４−（２，６，６−トリメチル−４−シクロヘキセニル）−３−ブテン−２−オン、２，６−ジメチルウンデカ−２，６，８−トリエン−１０−オン、２，６，１２−トリメチル−トリデカ−２，６，８−トリエン−１０−オン、２，６−ジメチルドデカ−２，６，８−トリエン−１０−オン、２，６，９−トリメチルウンデカ−２，６，８−トリエン−１０−オン、４−（２，６，６−トリメチル−２−シクロヘキセン−１−イル）−３−メチル−３−ブテン−２−オン、４−（２，４，６−トリメチル−３−シクロヘキセン−１−イル）−３−ブテン−２−オン、５−（２−メチレン−６，６−ジメチルシクロヘキシル）−４−ペンテン−３−オン及びこれらの混合物が含まれるが、これらに限定されない。
【００６１】
好ましいイオノンには、４−（２，６，６−トリメチル−３−シクロヘキセン−１−イル）−３−メチル−３−ブテン−２−オン（Ｉｓｏｒａｌｄｅｉｎｅの商標でＧｉｖａｕｄａｎ Ｒｏｕｒｅ， Ｃｏｒｐ．（米国ニュージャージー州ティーネック）から市販されている）、５−（２−メチレン−６，６−ジメチルシクロヘキシル）−４−ペンテン−３−オン（γ−メチルイオノンの商標でＧｉｖａｕｄａｎ Ｒｏｕｒｅ， Ｃｏｒｐ．（米国ニュージャージー州ティーネック）から市販されている）、４−（２，２，６−トリメチル−２−シクロヘキセン−１−イル）−３−ブテン−２−オン（α−イオノンの商標でＩｎｔｅｒｎａｔｉｏｎａｌ Ｆｌａｖｏｒｓ ａｎｄ Ｆｒａｇｒａｎｃｅｓ， Ｉｎｃ．（米国ニューヨーク州ニューヨーク）から市販されている）、４−（２，６，６−トリメチル−１−シクロヘキセン−１−イル）−３−ブテン−２−オン（β−イオノンの商標でＩｎｔｅｒｎａｔｉｏｎａｌ Ｆｌａｖｏｒｓ ａｎｄ Ｆｒａｇｒａｎｃｅｓ， Ｉｎｃ．（米国ニューヨーク州ニューヨーク）から市販されている）、４−（２，６，６−トリメチル−２−シクロヘキセン−１−イル）−３−メチル−３−ブテン−２−オン（メチルイオノンの商標でＢｕｓｈ Ｂｏａｋｅ Ａｌｌｅｎ， Ｉｎｃ．（米国ニュージャージー州モントベール）から市販されている）及びこれらの混合物が含まれる。
【００６２】
イオノンは、１つ以上の個別の香料化学物質として、あるいはイオノン香料化学物質を含む香料化学物質の組み合わせから構成される特定香料として、臭いマスキングベースに添加することができる。イオノン特定香料の例には、Ａｌｖａｎｏｎｅ Ｅｘｔｒａ（Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｆｌａｖｏｒｓ ａｎｄ Ｆｒａｇｒａｎｃｅｓ， Ｉｎｃ．（米国ニューヨーク州ニューヨーク）から市販されている）、Ｉｒｉｓｉａ Ｂａｓｅ（Ｆｉｒｍｅｎｉｃｈ， Ｉｎｃ．（米国ニュージャージー州プリンストン）から市販されている）、Ｉｒｉｖａｌ（Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｆｌａｖｏｒｓ ａｎｄ Ｆｒａｇｒａｎｃｅｓ， Ｉｎｃ．（米国ニューヨーク州ニューヨーク）から市販されている）、Ｉｒｉｔｏｎｅ（Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｆｌａｖｏｒｓ ａｎｄ Ｆｒａｇｒａｎｃｅｓ， Ｉｎｃ．（米国ニューヨーク州ニューヨーク）から市販されている）及びこれらの混合物が含まれるが、これらに限定されない。
本明細書に用いるのに好適なその他のイオノン含有物質は、例えば、オジギソウ、スミレ、アヤメ、ニオイイリス及びこれらの混合物などの天然物質である。
【００６３】
臭いマスキングベースに使用するジャコウ及び高揮発性香料も、１つ以上の個別の香料化学物質として、あるいは香料化学物質の組み合わせから構成される特定香料として、臭いマスキングベースに添加することができる。好ましい高揮発性特定香料の例には、Ｃａｓｓｉｓ Ｂａｓｅ３４５−Ｂ（Ｆｉｒｍｅｎｉｃｈ， Ｉｎｃ．（米国ニュージャージー州プリンストン）から市販されている）が含まれるが、これに限定されない。Ｎ好適なイオノン香料の例及びそれらの１気圧における沸点は、米国特許第５，９１９，４４０号に開示されているが、これらに限定されない。
【００６４】
ジャコウ
臭いマスキングベースは、ジャコウ成分を、臭いマスキングベースの約５重量％〜約７０重量％、好ましくは約１５重量％〜約５０重量％、更に好ましくは約２０重量％〜約３５重量％の濃度で含有することが好ましい。ジャコウは香料化学物質のよく知られた種類であり、典型的に無色又は淡黄色の物質で、特有のジャコウようの香りを有する。
臭いマスキングベースに使用するジャコウ成分は、１気圧において約２５０℃超過、好ましくは約２５５℃超過、更に好ましくは約２６０℃超過の沸点を有する必要があり、このときジャコウ成分は、多環式ジャコウ、大環状ジャコウ、ニトロ環式ジャコウ又はこれらの組み合せであることが好ましい。また、ジャコウ成分はそれぞれ、約１２個超過、好ましくは約１３個超過、更に好ましくは約１５個超過の炭素原子を有することが好ましい。
【００６５】
好適な多環式ジャコウには、５−アセチル−１，１，２，３，３，６−ヘキサメチルインダン、４−アセチル−１，１−ジメチル−６−第三級ブチルインダン、７−アセチル−１，１，３，４，４，６−ヘキサメチル−１，２，３，４−テトラヒドロナフタレン、１，１，４，４−テトラメチル−６−エチル−７−アセチル−１，２，３，４−テトラヒドロナフタレン、１，３，４，６，７，８−ヘキサヒドロ−４，６，６，７，８，８−ヘキサメチル−シクロペンタ−γ−２−ベンゾピラン及びこれらの混合物が含まれる。
好適な大環状ジャコウには、シクロペンタデカノリド、シクロペンタデカノロン、シクロペンタデカノン、３−メチル−１−シクロペンタデカノン、シクロヘプタデセン−９−オン−１、シクロヘプタデカノン、シクロヘキサデセン−７−オリド、シクロヘキサデセン−９−オリド、シクロヘキサデカノリド、エチレントリデカンジオエート、１０−オキサヘキサデカノリド、１１−オキサヘキサデカノリド、１２−オキサヘキサデカノリド及びこれらの混合物が含まれる。
【００６６】
好適なニトロ環式ジャコウには、１，１，３，３，５−ペンタメチル−４，６−ジニトロインダン、２，６−ジニトロ−３−メトキシ−１−メチル−４−第三級ブチルベンゼン、２，６−ジメチル−３，５−ジニトロ−４−第三級ブチル−アセトフェノン、２，６−ジニトロ−３，４，５−トリメチル−第三級ブチルベンゼン、２，４，６−トリニトロ−１，３−ジメチル−５−第三級ブチルベンゼン及びこれらの混合物が含まれる。
好ましいジャコウには、１，３，４，６，７，８−ヘキサヒドロ−４，６，６，７，８，８−ヘキサメチル−シクロペンタ−γ−２−ベンゾピラン（Ｇａｌａｘｏｌｉｄｅの商標でＩｎｔｅｒｎａｔｉｏｎａｌ Ｆｌａｖｏｒｓ ａｎｄ Ｆｒａｇｒａｎｃｅｓ， Ｉｎｃ．（米国ニューヨーク州ニューヨーク）から市販されている）、シクロペンタデカノリド（Ｅｘａｌｔｏｌｉｄｅの商標でＦｉｒｍｅｎｉｃｈ， Ｉｎｃ．（米国ニュージャージー州プリンストン）から市販されている）、エチレントリデカンジオエート（Ｅｔｈｙｌｅｎｅ Ｂｒａｓｓｙｌａｔｅの商標でＦｒａｇｒａｎｃｅ Ｒｅｓｏｕｒｃｅ， Ｉｎｃ．（米国ニュージャージー州キーポート）から市販されている）、７−アセチル−１，１，３，４，４，６−ヘキサメチル−１，２，３，４−テトラヒドロナフタレン（Ｔｏｎａｌｉｄの商標でＧｉｖａｕｄａｎ 好適なジャコウの例及びそれらの１気圧における沸点は、米国特許第５，９１９，４４０号に開示されているが、これらに限定されない。
【００６７】
（実施例）
実施例に使用されている略語
実施例において、成分名の略語は次の意味を有する。
【００６８】
【表１】

【００６９】
以下の実施例では、割合はすべて重量で表す。
【００７０】
実施例１〜１６
実施例１〜１６は、食品の調理汚れ、焼きつき汚れ及び焦げつき汚れを除去しやすくするために、食器洗い前に使用する前処理用組成物について説明する。実施例の組成物を洗い物に適用する。洗い物は、１４０℃で２時間焼いたパイレックス容器のラザーニャ、１５０℃で２時間調理したステンレススチール容器のラザーニャ、１５０℃で２時間調理したステンレススチール容器のポテトとチーズ、１５０℃で２時間調理したステンレススチール容器の卵黄及び１２０℃で１時間調理した後、１８０℃で１時間調理したソーセージといった異なる汚れと異なる基材から構成される。洗い物を実施例の組成物に１０分間浸け置きした後、冷たい水道水ですすぐ。その後、典型的な食器洗い用洗剤組成物で、洗い物を手で、あるいは自動食器洗い機（例えば、Ｂｏｓｃｈ６０３２食器洗い機）で洗浄する（５５℃、下洗いは行わない）。典型的な食器洗い用洗剤組成物は、例えば、アルカリ性成分、ビルダー、酵素、漂白剤、漂白剤触媒、非イオン性界面活性剤、石鹸泡抑制剤、銀腐食防止剤、汚れ懸濁化ポリマーなどを含有する。洗い物を実施例の組成物で処理し、その後、食器洗い機で洗浄したところ、食品の調理汚れ、焼きつき汚れ及び焦げつき汚れがきれいに除去された。
【００７１】
【表２】

【００７２】
【表３】

【００７３】
【表４】

【００７４】
【表５】

【００７５】
実施例はすべて、２５℃における液体表面張力が２４．５ｍＮ／ｍ未満、ｐＨが１２以上及びステンレススチール基材上の重合油脂汚れにおける４５分間の汚れ膨潤指数が少なくとも２００％である。
マスキング香料組成物を以下の表に示す。
【００７６】
【表６】

[0001]
(Industrial applications)
The present invention is in the field of detersive compositions for hard surfaces and in particular to products and methods suitable for removing cooking, burning and burning stains from cookware and tableware.
[0002]
(Background of the Invention)
Cooking, burning and burning stains are one of the most difficult stains to remove from a surface. Traditionally, the removal of cooked, baked and scorched soils from cookware and tableware requires soaking the soiled articles in water prior to mechanical cleaning. It is considered that it is difficult to sufficiently remove cooking dirt, burn-in dirt and burnt dirt only by a method using an automatic dishwasher. The method of washing dishes by hand requires a strong rub to remove cooking, burning and scorching stains, which can be detrimental to safety and the condition of cookware / tableware.
[0003]
It is known in the art to use solvent-containing detersive compositions to facilitate the removal of cooking, burning and burning stains. For example, U.S. Pat. No. 5,102,573 presents a method of treating hard surfaces soiled with cooking soils, baked soils or dried food debris. In this method, a prespot composition is dropped on a soiled article. The composition to be dropped contains a surfactant, a builder, an amine and a solvent. U.S. Pat. No. 5,929,007 presents an aqueous cleaning composition for hard surfaces to remove hardened, dried, or baked greasy deposits. The composition contains a nonionic surfactant, a chelating agent, a caustic, a glycol ether solvent system, an organic amine and an anti-redeposition agent. WO-A-94 / 28108 discloses an aqueous detergent concentrate composition that can be diluted to create a more viscous use solution. This use solution has an effective consistency with the rod-shaped micelle thickener composition, low molecular weight alkyl glycol ether solvent and hard sequestering agent. As an example of its application, a method is described for cleaning a cooking ware having at least one essentially vertical surface covered with baked-on soil of food. However, in practice, none of the inventions has been confirmed to be very effective in removing dirt that has been baked and polymerized from metals and other substrates.
Accordingly, there remains a detersive composition and method for using food cooking soil, baked or burnt soiled cooking utensils and tableware prior to cleaning to make it easier to clean food debris that is difficult to remove. It has been demanded. There is also still a need for detersive compositions and methods that are more effective at removing burn-in stains.
[0004]
(Summary of the Invention)
In a first aspect of the present invention, cooking dirt, burnt dirt and burnt dirt (such as oils, meats, dairy products, fruits, pasta and other foods that are particularly difficult to remove after cooking) are cooked and tableware. A hard surface detersive composition for removal from stainless steel, glass, plastic, wood and ceramic articles, including an organic amine solvent. Generally, the composition has a liquid surface tension of less than about 26 mN / m, preferably less than about 25 mN / m, more preferably less than about 24.5 mN / m, more preferably less than about 24 mN / m, It has a pH of at least 10.5 when measured as a% distilled water solution. The organic amine solvent is present in the compositions herein in an effective amount. The effective amount is an amount capable of functionally removing cooking dirt, burning dirt and burnt dirt. At low liquid surface tension and high pH, the organic amine solvent can act as a swelling, hydrating or other solvating agent for cooking, baked and burnt soils, It is effective. The soil swelling agent herein means that when a substrate on which cooking soil, burn-in soil, and burnt soil is deposited is treated with the soil swelling agent, these soils can be swollen without applying external frictional force. It is considered to be a substance or composition. The soil swelling effect can be represented by a soil swelling index.
[0005]
Preferably, the compositions of the present invention have a pH of at least about 10.5, preferably from about 11 to about 14, more preferably from about 11.5 to about 13.5, when measured as a 10% distilled aqueous solution. When cleaning cooking, burning and burning soils, the cleaning performance is to some extent related to the high pH of the cleaning composition. However, for some acidic stains such as cooking oil, it is desirable to be pre-alkaline in order to keep the pH high. On the other hand, the reserve alkalinity must not be too high so as not to damage the user's skin. Thus, it is preferred that the compositions of the present invention have a pre-alkalineity of less than about 5, preferably less than about 4, and especially less than about 3. "Pre-alkaline" as used herein refers to the ability of a composition to maintain pH alkaline even in the presence of an acid. This is related to the fact that the composition having sufficient reserve alkali can be treated with the added acid to maintain the pH. More specifically, pre-alkalineness is defined as grams of NaOH per 100 cc of product having a pH above 9.5. The preliminary alkalinity of the solution is measured by the following method.
[0006]
The pH 4, 7, and 10 buffers (or buffers in the expected pH range) are used to calibrate the autotitrator Mettler DL77 with the glass pH electrode Mettler DG115-SC. Prepare a 1% solution of the composition to be measured using distilled water. Record the weight of the sample. Measure the pH of the 1% solution and titrate the solution using 0.25N HCl solution until the pH is 9.5. The preliminary alkalinity (RA) is calculated by the following method.
RA = Ratio of NaOH × specific gravity
NaOH ratio = ml of HCl × normality of HCl × 40 × 100 / weight of aliquot titrated sample (g) × 1000
In the composition of the present invention, a surfactant selected from an anionic surfactant, an amphoteric surfactant, a zwitterionic surfactant, a nonionic surfactant, a semipolar surfactant and a mixture thereof is reduced. The addition at a concentration enhances the cleaning action and also helps protect the skin of the user. Preferred surfactant concentrations are from about 0.05% to about 10%, preferably from about 0.09% to about 5%, more preferably from about 0.1% to about 2%. Preferred surfactants for use herein are amine oxide surfactants.
[0007]
The soil swelling index (SSI) is a value obtained by treating a soil with a substance or composition, comparing the thickness of the soil before and after the treatment, and measuring the increased thickness of the soil. Without being limited by theory, it is believed that the increase in soil thickness is due, at least in part, to soil hydration or solvation. When the dirt swells, the dirt can be easily removed with no or minimal force. This minimal force includes, for example, wiping, rinsing, manual or automatic dishwashing. The change in soil thickness is measured and expressed as SSI.
[0008]
The amount of substance or composition required to swell the soil will depend on the nature of the substance or composition and can be determined by routine experimentation. Other conditions that affect soil swelling (eg, pH, temperature and treatment time) can also be determined by routine experimentation. However, a preferred substance or composition herein is an organic amine, which is effective in swelling cooking, burning and burning stains, such as polymerized grease or carbohydrate stains on glass and metal substrates. Contacting the organic amine with the soil at 20 ° C. for up to 45 minutes, preferably up to 30 minutes, more preferably up to 20 minutes, results in at least about 15%, preferably at least about 20%, in a 5% aqueous solution, pH 12.8. %, More preferably at least about 30%, especially at least about 50%. It is also preferred that the organic amine be selected such that the final composition has an SSI of at least about 100%, preferably at least about 200%, more preferably at least about 500%. At this time, the SSI of the final composition is measured as an undiluted stock solution under the same processing time and temperature conditions as described above. Highly preferred soil swelling agents and final compositions herein are those that meet the SSI values required for polymerized oil stains when following the methods described below.
[0009]
In the present specification, SSI is measured by an optical appearance inspection, for example, using a scanning white light interferometer Zygo New View 5030. Prepare a sample of polymerized fat. This sample was obtained by brushing a polymer oil on a stainless steel metal piece with a brush, and the sample preparation method will be described later in a section covering measurement of a polymer oil removal index. Next, an optical appearance inspection is performed on a small droplet of the fat sample having an end thickness of about 10 μm. An image is taken by the scanning white light interferometry and processed (S_i) And after processing (S_f) Measure the thickness of the soiled droplet. An interferometer (Zygo NewView 5030 with a Mirau 20 × objective) separates the incident light into light rays going to a reference surface inside the interferometer and to the sample. After being reflected, the light rays recombine inside the interferometer and reinforce each other (architectural interference) or cancel each other out (destructive interference), resulting in bright and dark interference fringes. The data is recorded using a CCD (Charge Coupled Device) camera, frequency domain analysis is performed with interferometer software, and the data is processed. After that, the obtained image size (pixel) is converted to the actual size (μm or mm). Thickness of dirt on stainless steel pieces (S_i), A metal piece made of stainless steel is immersed in the composition of the present invention at room temperature for a certain period of time, and the above method is repeated to obtain the soil thickness (S)._f) Is measured. If necessary, repeat the operation with a sufficient number of drops and samples to give statistical significance.
[0010]
The SSI is calculated by the following method.
SSI = [(S_f-S_i) / S_i] X 100
The compositions herein are characterized by very low liquid surface tension and contact angles on substrates coated with polymerized fat. In a preferred embodiment of the invention, the composition has an advancing contact angle of less than about 20 °, preferably less than about 10 °, more preferably less than about 5 ° at 25 ° C. on a glass substrate coated with a polymerized fat. Select as shown.
[0011]
The method for measuring the contact angle is as follows. After immersing a sample plate (preparation method will be described later) in a liquid, the sample plate is pulled up and the contact angle is calculated according to the Wilhelmy method. The force applied to the sample is measured according to the immersion depth (using KrussK12 and SystemK121 software of surface tensiometer). This force is proportional to the contact angle of the liquid on the solid surface. The sample plate is prepared as follows. Spray 30-50 g of canola oil into a beaker. A glass slide (3 × 9 × 0.1 cm) is immersed in canola oil to completely cover the surface. This results in a uniformly dispersed oil layer on the surface. Adjust the weight of product formed on the surface of the glass slide until about 0.5 g of oil is released and the oil spreads evenly. After the adjustment, the slide glass is baked at 250 ° C. for 20 minutes and allowed to cool to room temperature.
In another aspect of the present invention, there is provided a cleaning composition for hard surfaces that removes cooking, burning and scorching stains from cookware and tableware, the composition comprising an organic amine solvent, It exhibits an advancing contact angle of less than about 20 °, preferably less than about 10 °, more preferably less than about 5 ° at 25 ° C. on a glass substrate coated with a polymerized fat.
[0012]
The composition of the present invention may further contain a diffusion aid. Organic amines can increase the wettability of soils because the diffusion aids serve to reduce the interfacial tension between the organic amine and the soil. When a diffusion aid is added to the compositions herein, the diffusion aid can lower the surface tension of the composition. At this time, the diffusion aid is preferably one that can lower the surface tension of the composition from the surface tension of the diffusion aid itself. Particularly useful diffusion aids are those that can reduce surface tension to less than about 26 mN / m, preferably less than about 24.5 mN / m, more preferably less than about 24 mN / m, especially less than about 23.5 mN / m. It is. Surface tension is measured herein at 25 ° C.
While not wishing to be bound by theory, it is believed that the organic amine penetrates the soil and hydrates the soil. The diffusion aid promotes the interfacial action between the organic amine and the soil, and helps swell the soil. It is believed that the penetration and swelling of the soil weakens the bond between the soil and the substrate. The resulting composition is particularly effective in removing baked-in polymeric soil from a metal substrate.
[0013]
The diffusion aids used herein can generally be selected from organic solvents, wetting agents and mixtures thereof. In a preferred embodiment, the liquid surface tension of the diffusion aid is less than about 30 mN / m, preferably less than about 28 mN / m, more preferably less than about 26 mN / m, and most preferably less than about 24.5 mN / m. Suitable organic solvents that can function as diffusion aids include alcoholic solvents, glycols and glycol derivatives, and mixtures thereof. A preferred diffusion aid for use herein is a mixture of diethylene glycol monobutyl ether and propylene glycol butyl ether.
As used herein, suitable wetting agents for use as diffusion aids are surfactants, including anionic surfactants, amphoteric surfactants, zwitterionic surfactants, nonionic surfactants. Surfactants and semi-polar surfactants are included. Preferred non-ionic surfactants include silicone surfactants such as Silwet copolymer. Preferred Silwet copolymers include Silwet L-8610, Silwet L-8600, Silwet L-77, Silwet L-7657, Silwet L-7650, Silwet L-7607, Silwet L-7604, Silwet L-7600, Silwet L-7280 and mixtures thereof. Preferred for use herein is Silwet L-77.
[0014]
Other suitable wetting agents include organic amine surfactants, for example, amine oxide surfactants. The amine oxide preferably contains an average of 12 to 18 carbon atoms in the alkyl moiety, and very particularly preferred herein is dodecyl dimethyl amine oxide, tetradecyl dimethyl amine oxide, hexadecyl dimethyl amine oxide and It is a mixture.
Highly preferred hard surface cleaning compositions herein comprise a mixed solvent system, which is based on an organic amine solvent in combination with a co-solvent that acts as a diffusion aid. In addition, from the viewpoint of optimally removing burned-in polymerized soil, a highly preferable composition is preferably a solvent having limited water miscibility (coupling in the present specification) together with a solvent having sufficient water miscibility. Solvent). Both solvents are preferably present in the composition at a certain concentration. In another aspect of the present invention, there is provided a hard surface detersive composition for removing cooking, burning and burning soil from cookware and tableware, wherein the composition comprises from about 10% to about 40%. %, Preferably from about 12% to about 20% of an organic solvent, including from about 1% to about 15% of an organic amine solvent and from about 7% to about 30% of a solvent acting as a diffusion aid; It further contains at least about 3.5% of a water-miscible solvent and at least about 3.5% of a coupling solvent having limited water-miscibility.
[0015]
As used herein, a water-miscible solvent is a solvent that is miscible with water in any proportion at 25 ° C. Coupling solvents with limited miscibility are solvents that are miscible with water at 25 ° C. at a certain fixed ratio, but are immiscible at certain ratios. Preferably, the solvent has a solubility in water of less than about 30% by weight, preferably less than about 20% by weight, at 25 ° C. It is also preferred that the solubility of water in the solvent is less than about 30% by weight at 25 ° C., preferably less than about 20% by weight.
Preferred diffusion aids herein include a mixture of a water-miscible organic solvent and a coupling organic solvent having limited water-miscibility, wherein the ratio of the water-miscible organic solvent to the coupling organic solvent is limited. About 4: 1 to about 1:20, preferably about 2: 1 to about 1: 6, more preferably about 1.5: 1 to about 1: 3. Other suitable diffusion aids are wetting agents having a liquid surface tension of less than about 30 mN / m, preferably less than about 28 mN / m, more preferably less than about 26 mN / m, more preferably less than about 24.5 mN / m. It contains. Preferred humectants are amine oxides. Highly preferred diffusion aids contain a mixture of a coupling solvent and a wetting agent.
[0016]
In another aspect of the present invention, there is provided a hard surface detersive composition for removing cooking, burning and scorching stains from cookware and tableware, the composition comprising an organic amine solvent, a restricted organic amine solvent. It contains a water-miscible coupling solvent and a wetting agent and has a liquid surface tension of less than about 26 mN / m, preferably less than about 24.5 mN / m.
The compositions herein further have the property of exhibiting surface tension reducing properties. This property is considered to be important in order to ensure optimal removal performance for polymerized soil. In another aspect of the present invention, there is provided a hard surface detersive composition for removing cooking, burning and scorching soil from cookware and tableware, the composition comprising an organic solvent system and a wetting agent. It contains. At this time, the organic solvent system contains at least an organic amine solvent component, and the wetting agent is effective to lower the surface tension of the solvent system by at least 1 mN / m from the surface tension of the wetting agent.
[0017]
Preferably, the compositions of the present invention have a surface tension of less than about 24 mN / m, preferably less than about 23.5 mN / m.
Suitable organic amine solvents for use herein include alkanolamines, alkylamines, alkyleneamines, and mixtures thereof.
[0018]
The composition of the present invention has the characteristic of exhibiting excellent removal performance for polymerized fats and oils. The compositions of the present invention preferably have a polymerized fat removal index of at least 25%, preferably at least 50%, more preferably at least 75%. The polymerized fat removal index is a measure of the amount of soil removed from the surface by treatment with the composition of the present invention. After soaking the soiled substrate in the composition of the present invention for no more than about 45 minutes at room temperature, preferably no more than about 30 minutes, and more preferably no more than about 20 minutes, the dishwasher is used without the use of detergents or rinses. Wash with. Next, the substrate is dried and weighed, and the removed soil is determined by gravimetric analysis. A soiled substrate is prepared as follows. Wash the stainless steel strip / slide thoroughly with the product of the present invention and rinse thoroughly with water. If necessary, place slides in a 50 ° C. room and dry. The metal strip / slide is allowed to cool to room temperature (about 30 minutes). Measure the weight of the piece / slide. Spray the canola oil into a small beaker or pour in three portions (20-30 ml of canola oil in a 100 ml beaker). Soak a 1 inch brush in canola oil. Rotate the soaked brush and gently press it 4-6 times against the side of the container to remove excess canola oil from both sides of the brush. Apply a thin layer of canola oil to the surface of the metal strip / slide. Thereafter, gently wipe each slide with a dry brush so that only a thin coating of canola oil is applied (two even wipes can remove excess excess well). It is believed that 0.1-0.2 g of dirt is applied to the metal strip / slide by this method. Place the piece of metal / slide on a completely horizontal cookie sheet or oven rack and place in an oven heated to 245 ° C. After baking the slides / metal pieces for 20 minutes, allow to cool to room temperature (about 45 minutes). After cooling, the weight of the metal piece / slide is measured.
[0019]
The solvent-type composition of the present invention is characterized by exhibiting excellent removal performance when directly applied to dirty cooking utensils and tableware. The organic solvent system desirably includes at least one solvent component that acts as a soil swelling agent and has a liquid surface tension of less than about 27 mN / m, preferably less than about 26 mN / m, and more preferably less than about 25 mN / m. In addition, organic solvent systems contain multiple solvent components, the concentration of which is determined by the advancing contact angle of an equivalent composition containing the individual components of the solvent system on a glass substrate coated with a polymerized fat. Preferably, the concentration is such that it has a lower advancing contact angle. Such solvent systems and compositions are formulated to be optimal for removing carbon-rich baked soil from cookware and tableware. Preferably, the composition is in the form of a liquid or gel having a pH of greater than about 9, preferably greater than 10.5, more preferably greater than about 11, as measured at 25 ° C.
[0020]
Apart from the solvent parameters mentioned above, the compositions according to the invention must also meet certain rheological parameters and other performance parameters. These parameters include both properties that allow spraying and properties that allow close contact with the surface. For example, when spraying a product onto a vertical stainless steel surface, it is desirable for the product to have a flow rate of less than about 1 cm / s, preferably less than about 0.1 cm / s. In this case, the product is in the form of a shear thinning fluid and has a shear of about 0 to about 0.8, preferably about 0.3 to about 0.7, more preferably about 0.4 to about 0.6. It has an index (n) (Herschel-Bulkey type). Highly preferred are shear thinning liquids having a shear index of 0.5 or less. On the other hand, the fluid consistency index ranges from about 0.1 to about 50 Pa. sⁿ, But about 1 Pa. sⁿIt is preferably less than. A more preferred fluid consistency index is from about 0.20 to about 0.15 Pa. sⁿIt is. The product is about 0.1 to about 200 Pas, preferably about 0.3 to about 20 Pas at a speed of 3 rpm, as measured on a Brookfield (type LVDII) cylinder cylinder using a 10 ml sample and an S-31 spindle. It is preferable to have a consistency of Particularly useful compositions for use herein are greater than about 1 Pas at a speed of 6 rpm, preferably between about 2 and about 4 Pas, and less than about 2 Pas at a rate of 30 rpm, preferably between about 0.8 and about 1. It has a consistency of less than about 1 Pa s at 2 Pa s and a speed of 60 rpm, preferably from about 0.3 to about 0.5 Pa s. Rheology is measured under room temperature conditions (25 ° C.).
[0021]
Thickener components suitable for use herein include viscoelastic and thixotropic thickener components, the concentration of which is about 0.1% to about 10% by weight, preferably about 0% by weight. 0.25 wt% to about 5 wt%, most preferably about 0.5 wt% to about 3 wt%. Suitable thickener components include polymers having a molecular weight of about 500,000 to about 10,000,000, preferably about 750,000 to about 4,000,000. Preferred crosslinked polycarboxylate polymers are preferably carboxyvinyl polymers. Such compounds are disclosed in U.S. Pat. No. 2,798,053 (July 2, 1957, Brown). This patent also discloses a method for making a carboxyvinyl polymer. Carboxyvinyl polymers are substantially insoluble in volatile liquid organic hydrocarbons and are dimensionally stable upon exposure to air.
[0022]
Other suitable thickener components include inorganic clays (eg, laponite, aluminum silicate, bentonite, fumed silica). Preferred clay thickener components may be natural or synthetic. Preferred synthetic clays include synthetic smectite-type clays commercially available from Southern Clay Products, Inc. under the name Laponite ™. Particularly useful are gel-forming grades such as Laponite RD and sol-forming grades such as Laponite RDS. Naturally occurring clays include certain smectite and attapulgite clays. Mixtures of clay and polymeric thickeners are also suitable for use herein. Preferred for use herein are synthetic smectite-type clays (eg, Laponite and other synthetic clays) having an average platelet size with a maximum diameter of less than about 100 nm. Laponite has a layered structure which, when dispersed in water, takes the form of disc-shaped crystals about 1 nm thick and about 25 nm in diameter. Platelet size is important herein to provide excellent sprayability, stability, rheology and cohesion, as well as desirable aesthetic value.
[0023]
Other types of thickeners that can be used in the present compositions include natural gums such as xanthan gum, carob gum, guar gum and the like. For cellulose-type thickeners, hydroxyethyl and hydroxymethylcellulose (ETHOCEL and METHOCEL®, commercially available from Dow Chemical) can also be used. Natural rubbers are believed to affect droplet size when spraying the composition. When measured using a TSIA Aerosizer, it has been determined that droplets having a geometrically equivalent average diameter of about 3 to about 10 μm, preferably about 4 to about 7 μm, help to reduce odor. . A preferred natural gum for use herein is xanthan gum.
[0024]
Highly preferred herein is a mixture of Laponite and xanthan gum in terms of sprayability, adhesion, stability and soil penetration performance. Furthermore, the mixture of Laponite and xanthan gum increases the aesthetic value of the product, while at the same time reducing the solvent odor.
[0025]
In a preferred embodiment, the hard surface cleaning composition comprises an organic solvent system comprising a solvent component that acts as at least one soil swelling agent, wherein the organic solvent system comprises an alcohol, an amine, an ester, a glycol ether, a glycol. , Terpenes and mixtures thereof and contains at least one organic amine solvent component. Suitable organic solvents are organic amine solvents, including alkanolamines, alkylamines, alkyleneamines, and mixtures thereof, aromatic alcohols, aliphatic alcohols (preferably C₄~ C₁₀), Cycloaliphatic alcohols, and alcohol solvents, including mixtures thereof,₂~ C₃(Poly) alkylene glycols, glycol ethers, glycol esters, and their mixtures, and mixtures thereof selected from organic amine solvents, alcohol solvents, glycols and glycol derivatives. Highly preferred organic amine solvents include 2-aminoalkanol solvents as disclosed in U.S. Patent No. 5,540,846.
[0026]
In a preferred composition of the invention, the organic solvent comprises an organic amine (particularly alkanolamine) solvent and a glycol ether solvent, preferably in a weight ratio of about 3: 1 to about 1: 3. At this time, the glycol ether solvent is ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propylene glycol monobutyl ether, dipropylene glycol monobutyl ether, ethylene glycol phenyl. It is selected from ethers and mixtures thereof. Preferred organic amines for use herein are alkanolamines, especially monoethanolamine, methylamineethanol and 2-amino-2-methylpropanol. In a preferred composition, the glycol ether is a mixture of diethylene glycol monobutyl ether and propylene glycol butyl ether, the weight ratio of which is preferably from about 1: 2 to about 2: 1.
[0027]
Preferred organic solvent systems for use herein have a volatile organic content of greater than 1 mmHg and less than about 50%, preferably less than about 20%, and more preferably less than about 10%. Preferably, the organic solvent is essentially free of solvent components having a boiling point of less than about 150 ° C., a flash point of less than about 50 ° C., preferably less than about 100 ° C., or a vapor pressure greater than about 1 mm Hg. Highly preferred organic solvent systems have a volatile organic content above 0.1 mmHg of less than about 50%, preferably less than about 20%, more preferably less than about 10%, more preferably less than about 4%.
With respect to the solvent parameters, the organic solvent can be selected from the following a) to e).
[0028]
a) at least 20 (Mpa)^1/2Hansen solubility parameter of at least 7 (Mpa)^1/2, Preferably at least 12 (Mpa)^1/2Polarity parameter and at least 10 (Mpa)^1/2Hydrogen bonding solvent having the following hydrogen bonding parameters:
b) at least 20 (Mpa)^1/2Hansen solubility parameter of at least 7 (Mpa)^1/2, Preferably at least 12 (Mpa)^1/2Polarity parameter and 10 (Mpa)^1/2Polar non-hydrogen bonding solvents with hydrogen bonding parameters less than.
c) $ 20 (Mpa)^1/2Hansen solubility parameter of less than 7 (Mpa)^1/2Polarity parameter and at least 10 (Mpa)^1/2Amphiphilic solvent having a hydrogen bonding parameter of
d) $ 7 (Mpa)^1/2Polarity parameter less than and 10 (Mpa)^1/2Non-polar solvents with less than hydrogen bonding parameters.
e) A mixture of these.
[0029]
When an organic solvent is used in the detersive composition, it is generally a problem of the solvent odor. Many consumers do not like solvent odors and consider these odors to be "bad odors." The use of high concentrations of perfume can make such compositions more consumer-friendly. The addition of a high concentration of perfume can alter or reduce any of the unpleasant properties of the composition, but often has the undesirable consequence of perfumery being extinguished. Even when high concentrations of perfume properly alter, mask, or mask the malodor of the composition, these high concentrations of perfume do not necessarily improve the essence or duration of the perfume, so if the perfume volatilizes, It returns to the original stench.
[0030]
It is now known that selecting a combination of perfume substances as defined herein and adding to a composition of the present invention can effectively suppress or mask malodor when using a solvent in the composition. I have. Accordingly, in another aspect, the present invention provides a hard surface detersive composition comprising the above-described organic amine solvent and a perfume or perfume base for solvent odor masking. In general, odor-masking fragrances or fragrance bases contain a mixture of volatile and non-volatile fragrance substances, wherein the concentration of non-volatile fragrance substances (boiling point at 1 atm above 250 ° C) is greater than about 20% by weight. It is preferable that In a preferred embodiment, the perfume or perfume base contains at least 0.001% by weight of ionone or a mixture of ionones (including α, β and γ ionones). Preferred ionones are selected from gamma-methylionone, Alvanone Extra, Irishia Base, Cassis Base 345-B and mixtures thereof. The fragrance or fragrance base may further contain musk. Preferably, musk has a boiling point above about 250 ° C. Preferred musks are selected from Exaltolide Total, Havonolide, and mixtures thereof. The masking perfume or perfume base can further contain a mixture of highly volatile perfume components or components having a boiling point of less than about 250 ° C. Preferred highly volatile perfume ingredients are selected from decyl aldehyde, benzaldehyde, cis-3-hexenyl acetate, allyl amyl glycolate, dihydromyrcenol and mixtures thereof.
[0031]
The composition may further contain cyclodextrin to help control the malodor of the solvent. Cyclodextrins suitable for use herein are those that can selectively absorb molecules that cause malodor in the solvent without adversely affecting odor masking or fragrance molecules. The compositions used herein contain from about 0.1% to about 3%, preferably from about 0.5% to about 2%, by weight of the composition, of cyclodextrin. As used herein, the term "cyclodextrin" refers to an unsubstituted cyclodextrin containing from 6 to 12 glucose units, especially α-cyclodextrin, β-cyclodextrin, γ-cyclodextrin, and / or the like. Include any known cyclodextrin, such as derivatives and / or mixtures thereof. α-Cyclodextrin consists of six glucose units, β-cyclodextrin consists of seven glucose units, and γ-cyclodextrin consists of eight glucose units arranged in a donut-shaped ring. Due to the unique binding and arrangement of glucose units, cyclodextrin has a unique volumetric cavity inside and an inflexible conical molecular structure. This surface is completely hydrophobic, as the "lining" of the inner cavity is formed by hydrogen atoms and glycosidic oxygen atoms. The unique shape and physicochemical properties of the cavity allow the cyclodextrin molecule to absorb (and thus form an inclusion complex) the organic molecule or a portion of the organic molecule that can be incorporated into the cavity. ing. Odor molecules can be incorporated into the cavity.
[0032]
Preferred cyclodextrins are highly water-soluble, and include, for example, α-cyclodextrin and derivatives thereof, γ-cyclodextrin and derivatives thereof, derivatized β-cyclodextrin and / or mixtures thereof. Cyclodextrin derivatives mainly consist of molecules in which some of the OH groups have been converted to OR groups. Cyclodextrin derivatives include, for example, those having a short-chain alkyl group, wherein R is a methyl group or an ethyl group (eg, methylated cyclodextrin and ethylated cyclodextrin), those having a hydroxyalkyl substituent, -CH₂-CH (OH) -CH₃Or -CH₂CH₂-OH (e.g., hydroxypropyl cyclodextrin and / or hydroxyethyl cyclodextrin), branched cyclodextrin (e.g., maltose-bound cyclodextrin), cationic cyclodextrin (e.g., 2-hydroxy-3- ( CH containing dimethylamino) propyl ether, wherein R is a cation at low pH₂-CH (OH) -CH₂-N (CH₃)₂), Quaternary ammonium (for example, a 2-hydroxy-3- (trimethylammonio) propyl ether chloride group), and R is CH₂-CH (OH) -CH₂-N⁺(CH₃)₃Cl⁻Anionic cyclodextrins (eg, carboxymethyl cyclodextrin, cyclodextrin sulfate and cyclodextrin succinylate), amphoteric cyclodextrins (eg, carboxymethyl / quaternary ammonium cyclodextrin), at least one glucopyranose A cyclodextrin whose unit has a 3-6-anhydro-cyclomalto structure (for example, mono-3-6-anhydrocyclodextrin), which is "Optimal Performances with Minimal Chemical Modification of Cyclodextrins" (F. Didiadin and F. Didiadin). Perly, 7th International Cyclodextrin Symposium Proceedings, April 1994, p. 49) Indicated ones and mixtures thereof. Other cyclodextrin derivatives are disclosed in U.S. Pat. No. 3,426,011, U.S. Pat. No. 3,453,257, U.S. Pat. No. 3,453,258, U.S. Pat. No. 3,453,259, U.S. Pat. No. 3,453,260; US Pat. No. 3,459,731; US Pat. No. 3,553,191; US Pat. No. 3,565,887; US Pat. No. 4,535,152; No. 4,616,008, U.S. Pat. No. 4,678,598, U.S. Pat. No. 4,638,058 and U.S. Pat. No. 4,746,734.
[0033]
A highly water-soluble cyclodextrin is defined as having a solubility in water of at least about 10 g in 100 ml of water at room temperature, preferably at least about 20 g in 100 ml of water at room temperature, and more preferably at least about 25 g in 100 ml of water at room temperature. Certain cyclodextrins. Examples of preferred water-soluble cyclodextrin derivatives suitable for use herein include hydroxypropyl α-cyclodextrin, methylated α-cyclodextrin, methylated β-cyclodextrin, hydroxyethyl β-cyclodextrin and hydroxypropyl β. -Cyclodextrin. The hydroxyalkylcyclodextrin derivative preferably has a degree of substitution of about 1 to about 14, more preferably about 1.5 to about 7, wherein the total number of OR groups per cyclodextrin is defined as the degree of substitution. Methylated cyclodextrin derivatives usually have a degree of substitution of about 1 to about 18, preferably about 3 to about 16. A known methylated β-cyclodextrin is heptakis-2,6-di-O-methyl-β-cyclodextrin, commonly known as DIMEB, wherein each glucose unit has a degree of substitution of about 14 Having a methyl group. An even more readily purchased preferred methylated β-cyclodextrin is a randomly methylated β-cyclodextrin having a degree of substitution of about 12.6. Preferred cyclodextrins are described, for example, in the American Maize-Products Company and Wacker Chemicals (USA), Inc. It is commercially available from.
[0034]
The compositions of the present invention are particularly useful when applied directly in pre-treating cookware or tableware that has been soiled with cooking residues, baked-on or scorched (or other dry soils). The composition is applied to the soiled substrate in the form of a spray or foam before washing or rinsing or wiping the dishes automatically or manually. Pre-treated cookware or tableware may be very slippery and as a result may be difficult to handle during and after rinsing. This can be solved by using divalent cations. Such divalent cations include, for example, magnesium salts and calcium salts, particularly suitable for use herein is magnesium chloride. When about 0.01% to about 5%, preferably about 0.1% to about 3%, more preferably about 0.4% to about 2% by weight of the magnesium salt is added, a pretreatment Slippery properties of cookware or tableware surfaces can be eliminated without adversely affecting the stability of the physical properties of the composition. The compositions of the present invention can also be used as automatic dishwashing detergent compositions or components thereof.
[0035]
In a method aspect, the present invention provides a method of removing cooking, scorching and scorching soil from cookware and tableware, the method comprising cooking with the cleaning composition for hard surfaces of the present invention. Treating utensils / tableware. Also provided is a method of removing polymerized oils or carbohydrates from cooking, burning and burning stains from metal cooking utensils and tableware, the method comprising cooking with the hard surface cleaning composition of the present invention. Treating utensils / tableware. These methods include the step of pretreating cookware / tableware with the composition of the present invention prior to automatically or manually cleaning the dishes. If desired, after applying the cleaning composition of the present invention, cover the soiled substrate with a cling film and swell the soil to facilitate the process of removing cooking, burning and scorching soil. Can be. Preferably, the cling film is applied for about 1 hour or more, preferably about 6 hours or more.
[0036]
(Detailed description of the invention)
The present invention contemplates hard surface cleaning compositions for pre-treating cooking utensils and tableware soiled with cooking, burning, and scorching soils to facilitate subsequent cleaning. These effects are mainly obtained by adding an organic amine solvent which swells the stain to the composition. The present invention also envisages a method for removing the dirt described above.
The soil swelling agent is a substance or a composition having an effect of swelling the above-described cooking soil, burn-in soil and burn-in soil. Preferred soil swelling agents for use herein include organic amine solvents.
The diffusion aid is a substance or a composition having the property of reducing the surface tension as described above. Diffusion aids suitable for use herein include surfactants such as silicone surfactants and amine oxide surfactants, especially those having a surface tension of less than about 25 mN / m, organic solvents and the like. Of mixtures.
[0037]
In general, the organic solvents used herein must be selected to be compatible with the various components of cookware / tableware and automatic dishwashers. In addition, the solvent system should have less than about 50%, preferably less than about 30%, more preferably less than about 10%, more preferably less than about 4% by weight of the solvent system above 1 mmHg (preferably above 0.1 mmHg). It has a volatile organic content of less than 10% and must be used efficiently and safely. Also, the odor of the solvent system must be very mild and pleasant. Individual organic solvents as used herein generally have a boiling point above about 150 ° C., a flash point above about 50 ° C., preferably below 100 ° C., and less than about 1 mm Hg at 25 ° C., preferably below 0.1 mm Hg and atmospheric pressure. Has a vapor pressure of less than. In addition, each organic solvent is approximately 500 cm³/ Mol, preferably about 250 cm³/ Mol, more preferably about 200 cm³It is preferred to have a molar volume of less than / mol. These molar volumes are preferred from the viewpoint of optimally penetrating the soil and swelling the soil.
[0038]
Solvents that can be used herein include the following i) to v). i) alcohol. For example, benzyl alcohol, 1,4-cyclohexanedimethanol, 2-ethyl-1-hexanol, furfuryl alcohol, 1,2-hexanediol and other similar substances. ii) amine. For example, alkanolamines (eg, primary alkanolamines (monoethanolamine, monoisopropanolamine, diethylethanolamine, ethyldiethanolamine, β-aminoalkanol), secondary alkanolamines (diethanolamine, diisopropanolamine, 2- (methylamino) ethanol) ), Tertiary alkanolamines (triethanolamine, triisopropanolamine)), alkylamines (primary alkylamines (monomethylamine, monoethylamine, monopropylamine, monobutylamine, monopentylamine, cyclohexylamine), secondary alkylamines ( Dimethylamine)), alkyleneamines (primary alkyleneamines (ethylenediamine, propylenediamine)) and other similar substances. iii) esters. For example, ethyl lactate, methyl ester, ethyl acetoacetate, ethylene glycol monobutyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate and other similar substances. iv) glycol ether. For example, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propylene glycol butyl ether and other similar substances. v) glycol. For example, propylene glycol, diethylene glycol, hexylene glycol (2-methyl-2,4-pentanediol), triethylene glycol, compositions and dipropylene glycol and other similar substances and mixtures thereof.
[0039]
Preferred solvents for use herein as soil swelling agents include alkanolamines (especially monoethanolamine), β-aminoalkanols (especially 2-amino-2-methylpropanol (β- The lowest molecular weight among aminoalkanols minimizes the reactivity of the amine groups)) and mixtures thereof.
Preferred solvents for use herein as diffusion aids include glycols and glycol ethers, especially diethylene glycol monobutyl ether, propylene glycol butyl ether, and mixtures thereof.
[0040]
Apart from soil swelling agents and diffusion aids, the hard surface cleaning compositions herein can contain additional components. This includes surfactants other than the above-mentioned wetting agents, builders, enzymes, bleaching agents, alkaline components, thickeners, stabilizing components, fragrances, abrasives, and the like. The composition may also contain an organic solvent having a carrier or diluting function (as opposed to swelling or spreading of soil), or other specific function. The composition can be provided from any suitable container. The containers include, for example, bottles (bottles with pumps, squeeze bottles), paste dispensers, capsules, pouches and multi-compartment pouches.
[0041]
Surfactant
In the compositions and methods of the present invention for use in automatic dishwashing, it is preferred that the detergent surfactant be low foaming, alone or in combination with other ingredients (ie, soap suds suppressors). In the compositions and methods of the present invention, detergent surfactants are foaming for direct application and low foaming for use in automatic dishwashing for use in hard surface cleaning or dishwashing pretreatment. It is preferable that Surfactants suitable herein include anionic surfactants such as alkyl sulfates, alkyl ether sulfates, alkyl benzene sulfonates, alkyl glyceryl sulfonates, alkyl and alkenyl sulfonates, alkyl ethoxy carboxylate, N-acyl There are sarcosinates, N-acyl taurates, alkyl succinates and sulfosuccinates, and the like, in which the alkyl, alkenyl or acyl moiety has a C₅~ C₂₀, Preferably C₁₀~ C₁₈Linear or branched), cationic surfactants such as chlorine esters (US Pat. No. 4,228,042, US Pat. No. 4,239,660, and US Pat. No. 4,260) No. 529) and Mono C₆~ C₁₆N-alkyl or alkenyl ammonium surfactants, the remaining N-positions of which are substituted with methyl, hydroxyethyl or hydroxypropyl groups), low and high cloud point nonionic surfactants And mixtures thereof (eg, nonionic alkoxylated surfactants (especially C₆~ C₁₈Ethoxylates derived from primary alcohols), ethoxylated to propoxylated alcohols (eg, Poly-Tergent® SLF18 from Olin Corporation), epoxy end-capped poly (oxyalkylated) alcohols (eg, from Olin Corporation). Poly-Tergent (R) SLF18B, see WO-A-94 / 22800), ether-terminated poly (oxyalkylated) alcohol surfactants and block polyoxyethylene-polyoxypropylene polymer compounds (e.g. BASF-Wyandotte) PLURONIC®, REVERSED PLURONIC®, and TETRON, commercially available from Corp. Corp. (Wyandotte, MI). IC (registered trademark)), amphoteric surfactants (for example, C₁₂~ C₂₀(Preferred amine oxides for use herein include lauryl dimethyl amine oxide and hexadecyl dimethyl amine oxide) and alkyl amphoteric carboxylic acid surfactants (eg, Miranol ™ C2M) ), Amphoteric surfactants (eg, betaine and sultaine) and mixtures thereof. Surfactants suitable herein are, for example, U.S. Pat. No. 3,929,678, U.S. Pat. No. 4,259,217, EP 0,414,549, WO-A-93 / 08876. And WO-A-93 / 08874. Surfactants typically comprise from about 0.2% to about 30%, more preferably from about 0.5% to about 10%, most preferably from about 1% to about 5% by weight of the composition. Exists in the proportion of Preferred surfactants for use herein in automatic dishwashing are low foaming agents, low cloud point nonionic surfactants, and high foaming and low cloud point nonionic surfactants (this (Which acts as a soap suds suppressor).
[0042]
builder
Suitable builders for use in the detersive compositions herein include water-soluble builders such as citrate, carbonate and polyphosphate (eg, sodium tripolyphosphate and sodium tripolyphosphate hexahydrate, tripolyline). Mixtures of potassium silicate and sodium and potassium tripolyphosphate)) and partially water-soluble or insoluble builders (eg crystalline layered silicates (EP 0,164,514 and EP 0,293,640)) and Aluminosilicates (such as zeolites A, B, P, X, HS, and MAP) are included. The builder is typically present at from about 1% to about 80%, preferably from about 10% to about 70%, most preferably from about 20% to about 60% by weight of the composition.
Preferred compositions for use herein contain silicates to prevent damage to aluminum and certain painted surfaces. SiO₂: Na₂Amorphous sodium silicate having a ratio of O of 1.8-3.0, preferably 1.8-2.4, most preferably 2.0 can also be used herein. However, from the standpoint of long-term storage stability, very preferred are compositions containing less than about 22%, preferably less than about 15%, of total silicates (amorphous and crystalline).
[0043]
enzyme
Suitable enzymes herein include bacterial and fungal cellulases (eg, Carezyme and Celluzyme (Novo Nordisk A / S)), peroxidases, lipases (eg, Amano-P (Amano Pharmaceutical Co.), M1Lipase®). And Lipomax (registered trademark) (Gist-Brocades), and Lipolase (registered trademark) and Lipolase Ultra (registered trademark) (Novo)), cutinases, proteases (for example, Esperase (registered trademark), Alcalase (registered trademark), Durazym ( (Registered trademark), and Savinase (registered trademark) (Novo), and Maxatase (registered trademark), Maxacal (registered trademark), Prope ase®, and Maxapem® (Gist-Brocades), α and β amylases (eg, Purafect Ox Am® (Genencor), and Termamyl®, Ban®, Fungamyl®, Duramyl® and Natalase® (Novo)) and mixtures thereof. The enzyme is added herein in a globular, granular, or cogranular form and is preferably present as a pure enzyme, typically at a level of from about 0.0001% to about 2% by weight of the composition. .
[0044]
bleach
Suitable bleaches herein include chlorine bleaches and oxygen bleaches, especially inorganic perhydrate salts such as sodium perborate monohydrate and tetrahydrate and controlling release rates (E.g., see GB 1,466,799 for sulfate / carbonate coatings), organic peroxoacid bleach precursor and / or transition metal coating bleach. Includes preformed organic peroxoacids with agent catalysts (particularly manganese or cobalt) and mixtures thereof. The inorganic perhydrate salt typically comprises from about 1% to about 40%, preferably from about 2% to about 30%, more preferably from about 5% to about 25% by weight of the composition. Add in. Preferred peroxoacid bleach precursors for use herein include precursors of perbenzoic acid and substituted perbenzoic acids, cationic peroxoacid precursors, peracetic acid precursors (eg, TAED, acetoxy) Sodium benzenesulfonate and pentaacetylglucose), pernonanoic acid precursors (e.g., sodium 3,5,5-trimethylhexanoyloxybenzenesulfonate (iso-NOBS) and sodium nonanoyloxybenzenesulfonate (NOBS)), Amide-substituted alkyl peroxo acid precursors (EP 0,170,386) and benzoxazine peroxo acid precursors (EP 0,332,294 and EP 0,482,807) Is included. The bleach precursor is typically added at about 0.5% to about 25%, preferably about 1% to about 10%, by weight of the composition. On the other hand, the preformed organic peroxoacid is typically added at a level of from about 0.5% to about 25%, preferably from about 1% to about 10%, by weight of the composition. Preferred bleach catalysts for use herein include triazacyclononane manganese and related complexes (US Pat. No. 4,246,612, US Pat. No. 5,227,084), bispyridylamine Co, Cu , Mn, Fe and related complexes (US Pat. No. 5,114,611), and pentamine acetate cobalt (III) and related complexes (US Pat. No. 4,810,410).
[0045]
Low cloud point nonionic surfactant and soap suds suppressor
Suitable suds suppressors for use herein include nonionic surfactants having a low cloud point. "Cloud point", as used herein, is a known property of nonionic surfactants that occurs with surfactants that become less soluble as the temperature increases, and is the temperature at which different phases appear. Called the "cloud point" (see Kirk Othmer, pages 360-362). As used herein, a "low cloud point" nonionic surfactant is less than 30C, preferably less than about 20C, more preferably less than about 10C, and most preferably less than about 7.5C. Is defined as a nonionic surfactant-based component having a cloud point of Typical low cloud point nonionic surfactants include nonionic alkoxylated surfactants (especially ethoxylates derived from primary alcohols) and polyoxypropylene / polyoxyethylene / polyoxypropylene (PO / EO). / PO) reverse block polymers. These low cloud point nonionic surfactants also include, for example, ethoxylated to propoxylated alcohols (eg, Poly-Tergent® SLF18 from Olin Corporation) and epoxy end-capped poly (oxyalkylated). Alcohols (eg, Poly-Tergent® SLF18B series from Olin Corporation, described as nonionics in US Pat. No. 5,576,281).
Preferred low cloud point surfactants are ether capped poly (oxyalkylated) suds suppressors having the formula:
[0046]
Embedded image

[0047]
R¹Is a straight chain alkyl hydrocarbon having an average of about 7 to about 12 carbon atoms;²Is a linear alkyl hydrocarbon having from about 1 to about 4 carbon atoms;³Is a linear alkyl hydrocarbon having from about 1 to about 4 carbon atoms, x is an integer from about 1 to about 6, y is an integer from about 4 to about 15 and z is an integer from about 4 to about 25. is there.
Another low cloud point nonionic surfactant is an ether end-capped poly (oxyalkylated) having the formula:
R_IO (R_IIO)_nCH (CH₃) OR_III
R_IIs selected from the group consisting of straight or branched, saturated or unsaturated, substituted or unsubstituted, aliphatic or aromatic hydrocarbon groups having about 7 to about 12 carbon atoms;_IIMay be the same or different groups, and may be a branched or straight-chain C₂~ C₇Independently selected from the group consisting of alkylenes, wherein n is a number from 1 to about 30;_IIIIs selected from the following group:
[0048]
(I) a 4- to 8-membered substituted or unsubstituted heterocyclic ring having 1 to 3 heteroatoms, and
(Ii) straight or branched, saturated or unsaturated, substituted or unsubstituted, cyclic or acyclic, aliphatic or aromatic hydrocarbon groups having about 1 to about 30 carbon atoms.
(B) R²Is (ii), (A) R¹At least one of the C₂~ C₃Other than alkylene, or (B) R²Has 6 to 30 carbon atoms and further R²Has 8 to 18 carbon atoms, R is C₁~ C₅Other than alkyl.
[0049]
Other components suitable herein include organic polymers having an invention of dispersibility, anti-redeposition, soil release or other cleaning properties. The proportion is from about 0.1% to about 30%, preferably from about 0.5% to about 15%, most preferably from about 1% to about 10% by weight of the composition. Preferred antiredeposition polymers herein include polymer-containing acrylic acids (eg, Sokalan PA30, PA20, PA15, PA10 and Sokalan CP10 (BASF GmbH), Acusol 45N, 480N, 460N (Rohm and Haas)), acrylic acid / maleic acid. Copolymers (eg, Sokalan CP5), and acrylic / methacrylic copolymers are included. Preferred soil release polymers herein include alkyl and hydroxyalkyl celluloses (US Pat. No. 4,000,093), polyoxyethylene, polyoxypropylene and copolymers thereof, and ethylene glycol, propylene glycol and mixtures thereof. Non-ionic and anionic polymers based on terephthalate esters of
[0050]
Heavy sequestering agents and crystal growth inhibitors generally comprise from about 0.005% to about 20%, preferably from about 0.1% to about 10%, more preferably about 0.25% by weight of the composition. From about 0.5% to about 7.5%, most preferably from about 0.5% to about 5%, by weight. These include, for example, diethylenetriaminepenta (methylenephosphonate), ethylenediaminetetra (methylenephosphonate), hexamethylenediaminetetra (methylenephosphonate), ethylenediphosphonate, hydroxyethylene-1,1-diphosphonate, nitrilotriacetate, ethylenediaminotetraacetate , Ethylenediamine-N, N'-disuccinate salts and free acid forms.
[0051]
The compositions herein can contain a corrosion inhibitor. This includes, for example, organic silver coatings (for example, Wintershall (Germany), which comprise from about 0.05% to about 10%, preferably from about 0.1% to about 5%, by weight of the composition. (Paraffins such as Winog 70, commercially available from Salzbergen), nitrogen-containing corrosion inhibitor compounds (see, for example, benzotriazole and benzimidazole-British Patent No. 1,137,741), and about 0.1% of the composition. Mn (II) compound in an amount of from 005% to about 5% by weight, preferably from about 0.01% to about 1% by weight, more preferably from about 0.02% to about 0.4% by weight. (Especially, Mn (II) salts of organic ligands).
[0052]
Other suitable components herein include colorants, water-soluble bismuth compounds (e.g., bismuth acetate and bismuth citrate) in a proportion of about 0.01% to about 5%, about 0.01% Enzyme stabilizers (e.g., calcium ions, boric acid, propylene glycol and chlorine bleach scavengers), lime soap dispersants (see WO-A-93 / 08877), soap bubbles Includes inhibitors (see WO-A-93 / 08876 and EP 0,705,324), polymeric dye transfer inhibitors, optical brighteners, perfumes, fillers and clays.
Liquid detergent compositions can contain water and other volatile solvents as carriers. Small amounts of low molecular weight primary or secondary alcohols (eg, methanol, ethanol, propanol and isopropanol) can be used in the liquid detergents of the present invention. Other suitable carrier solvents used in small amounts include glycerol, propylene glycol, ethylene glycol, 1,2-propanediol, sorbitol and mixtures thereof.
[0053]
Smell masking base
The odor masking base (this word includes the fully formulated odor masking fragrance or the base composition used therein) is preferably a mixture of ionone, musk and a highly volatile fragrance. The concentration of the odor masking base may range from about 0.001% to about 3%, preferably from about 0.006% to about 2.5%, more preferably from about 0.0075% to about 1% by weight of the composition. Preferably it is in the range of weight%.
[0054]
Odor masking based ionones, musk and highly volatile fragrances have one feature in the range of boiling points of each component. Preferably, the ionone and musk have a boiling point at about one atmosphere greater than about 250 ° C. On the other hand, highly volatile fragrance ingredients have a boiling point of less than about 250 ° C. at one atmosphere. The boiling points of many perfumery substances are disclosed, for example, in "Perfume and Flavor Chemicals (Aroma Chemicals)" (S. Arctander, Author Publishing, 1969). Other boiling points can be obtained from various chemical handbooks and databases (e.g., the Beilstein Handbook, Language's Handbook of Chemistry, and the CRC Handbook of Chemistry and Physics). Where only boiling points at different pressures (typically less than one standard pressure) are provided, the boiling point at standard pressure or ambient pressure can be estimated using a boiling point-pressure calculation chart. This boiling point-pressure calculation chart is described in, for example, "The Chemist's Companion" (AJ Gordon and RA Ford, John Wiley & Sons Publishers, 1972, pp. 30-36). There is. Where applicable, boiling points can also be calculated by computer programs based on molecular structure data. Such programs include, for example, "Computer-Assisted Prediction of Normal Boiling Points of Pyrans and Pyrroles" (DT Stanton et al., J. Chem. Inf. Comput. 32, 19-32, 1993, Sci. 32, 1991-32). ), "Computer-Assisted Prediction of Normal Boiling Points of Furans, Tetrahydrofurans, and Thiophenes" (D.T. Stanton et al., J. Chem. 1st to 30th. And the "Predicting Physi" cal Properties from Molecular Structure "(R. Murugan et al., Chemtech, June 1994, pp. 17-23).
The components of the odor masking-based ionone fragrance, the highly volatile fragrance and the musk component are described in detail below.
[0055]
Highly volatile fragrance
Odor masking-based highly volatile perfumes contain perfume substances that compete with malodorous solvents and reach the nasal receptor receptors. These highly volatile fragrances are odors that are first recognized and recognized by the brain and serve to inhibit or mask solvent recognition in the sense of smell. The concentration of the highly volatile fragrance is from about 15% to about 85% by weight of the odor masking base, preferably from about 20% to about 80%, more preferably from about 35% to about 75%, more preferably From about 45% to about 65% by weight.
Highly volatile fragrances are more volatile than the odor masking based ionone and musk ingredients and have a boiling point at 1 atmosphere of less than about 250 ° C, preferably less than about 230 ° C, more preferably less than about 220 ° C. These highly volatile fragrances include aldehydes having about 2 to 15 carbon atoms, esters having about 3 to 15 carbon atoms, alcohols having about 4 to 12 carbon atoms, about 4 to 13 carbon atoms. It is classified as an ether having carbon atoms, a ketone having about 3 to 12 carbon atoms, or a combination thereof.
[0056]
Examples of suitable aldehydes include n-decylaldehyde, 10-undecen-1-al, dodecanal, 3,7-dimethyl-7-hydroxyoctane-1-al, 2,4-dimethyl-3-cyclohexenecarboxaldehyde, Includes, but is not limited to, benzaldehyde, anisaldehyde and mixtures thereof.
Examples of suitable ethers include ethyl acetate, cis-3-hexenyl acetate, 2,6-dimethyl-2,6-octadien-8-yl acetate, benzyl acetate, 1,1-dimethyl-2-phenyl acetate, 2 -Pentyloxyallyl ester, allyl hexanoate, methyl-2-aminobenzoate and mixtures thereof.
[0057]
Examples of suitable alcohols are n-octyl alcohol, β-γ-hexenol, 2-trans-6-cis-nonadien-1-ol, 3,7-dimethyl-trans-2,6-octadien-1-ol 3,7-dimethyl-6-octen-1-ol, 3,7-dimethyl-1,6-octadien-3-ol, 2,6-dimethyl-7-octen-2-ol, 2-phenylethyl alcohol , 2-cis-3,7-dimethyl-2,6-octadien-1-ol, 1-methyl-4-isopropyl-1-cyclohexen-8-ol and mixtures thereof, but are not limited thereto.
Examples of suitable ethers include, but are not limited to, amyl resole oxide, 4-ethoxy-1-methyl-benzol, 4-methoxy-1-methylbenzene, methylphenylethyl ether, and mixtures thereof.
[0058]
Examples of suitable ketones include dimethylacetophenone, ethyl-n-amyl ketone, 2-heptanone, 2-octanone, 3-methyl-2- (cis-2-penten-1-yl) -2-cyclopenten-1-one. , 1-1-methyl-4-isopropenyl-6-cyclohexen-2-one, para-tertiary amylcyclohexanone and mixtures thereof.
Preferred highly volatile fragrances include 2-pentyloxyallyl ester (commercially available from International Flavors and Fragrances, Inc. under the trademark Allyl Amyl Glycolate, New York, NY) and benzaldehyde (Rhone-Poulenc under the trademark Amandol). , Inc. (commercially available from Princeton, NJ), cis-3-hexenyl acetate (commercially available from International Flavors and Fragrances, Inc. (New York, NY) under the trademark Verdural extra), 2,6. -Dimethyl-7-octen-2-ol (trademark of Dihydromyrcenol, Inter) National Flavors and Fragrances, Inc. (commercially available from New York, NY), para-tertiary amyl cyclohexanone (commercially available from International Flavors and Fragrances, Inc. (New York, NY) under the trademark Orivone). ), N-decyl aldehyde (commercially available from Aceto, Corp. (Lake Success, NY) under the trademark Decyl Aldehyde) and mixtures thereof.
Examples of suitable highly volatile fragrances and their boiling points at 1 atmosphere are disclosed in, but not limited to, US Pat. No. 5,919,440.
[0059]
Ionone
The odor masking base may contain about 15% to about 80%, preferably about 16% to about 60%, more preferably about 16% by weight of the ionic mask of the odorant masking base (i.e., the ionone or ionon mixture). % To about 40% by weight. Ionone is a well-known class of perfume chemicals derived from natural oils or made synthetically, and is typically a colorless or pale yellow liquid that exhibits a forest violet-like scent.
[0060]
The ionone fragrance used in the odor masking base has a boiling point at 1 atmosphere of greater than about 250 ° C., preferably greater than about 255 ° C., and more preferably greater than about 260 ° C., wherein the ionone fragrance is methylionone, α-ionone, β-ionone. It is preferred to be selected from ionone, gamma ionone or a combination thereof.
Examples of suitable ionones include 1- (2,6,6-trimethyl-2-cyclohexen-1-yl) -1,6-heptadien-3-one, 2-allyl-para-menthen- (4 ( 8))-Ono-3, pseudoallyl-α-ionone, α-citrylidenecyclopentanone, 5- (2,6,6-trimethyl-2-cyclohexen-1-yl) -4-methyl-4-pentene -3-one, 6- (2,6,6-trimethyl-2-cyclohexen-1-yl) -1-methyl-5-hexen-4-one, 2,6,6-trimethylcyclohexyl-1-butenone- 3, dihydro-α-ionone, 4- (2,6,6-trimethylcyclohexen-1-yl) -butan-2-one, 4- (2-methylene-6,6-dimethylcyclohexyl) -butan-2- ON, 1- (2,5 , 6-Tetramethyl-2-cyclohexenyl) -butan-3-one, dihydro-β-iron, dihydro-γ-iron, 5- (2,6,6-trimethyl-2-cyclohexenyl) -pentane-3 -One, sihydro-iso-methyl-β-ionone, 6- (2,6,6-trimethyl-2-cyclohexen-1-yl) -5-hexen-4-one, α-ethyl-2,2,6 -Trimethylcyclohexanebutyraldehyde, 4-methyl-6- (1,1,3-trimethyl-2'-cyclohexen-2'-yl) -3,5-hexadien-2-one, 6,10-dimethylundecane-2 -One, 6- (2,6,6-trimethyl-1-cyclohexen-1-yl) -1-methyl-2,5-hexadien-4-one, 6- (2,6,6-trimethyl-2- Cyclohe Xen-1-yl) -1-methyl-2,5-hexadien-4-one, 4- (2,2,6-trimethyl-2-cyclohexen-1-yl) -3-buten-2-one, -(2,6,6-trimethyl-1-cyclohexen-1-yl) -3-buten-2-one, 4- (2-methylene-6,6-dimethylcyclohexyl) -3-buten-2-one, Epoxy-2,3-β-ionone, ethyl-2,3-epoxy-3-methyl-5- (2,6,6-trimethyl-2-cyclohexenyl) -4-pentenoate, methyl α-ionone anthranilate Methyl-2,3-epoxy-3-methyl-5- (2,6,6-trimethyl-2-cyclohexenyl) -4-pentenoate, 4- (2,5,6,6-tetramethyl-2- Cyclohexen-1-yl) -3 -Buten-2-one, 6-methyl-β-ionone, 6-methyl-γ-ionone, 4- (2,6,6-trimethyl-2-cyclohexenyl) -2,3-dimethyl-2-butene- 1-al, 4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -3-methyl-3-buten-2-one, 5- (2,6,6-trimethyl-2-cyclohexene -1-yl) -4-penten-3-one, 5- (2,6,6-trimethyl-1-cyclohexen-1-yl) -4-penten-3-one, 4- (2,6,6 -Trimethyl-3-cyclohexen-1-yl) -3-methyl-3-buten-2-one, 5- (2-methylene-6,6-dimethylcyclohexyl) -4-penten-3-one, 4- ( 2-methylene-6,6-dimethylcyclohexyl) -3-me Tyl-3-buten-2-one, 4- (2,3,6,6-tetramethyl-2-cyclohexen-1-yl) -3-buten-2-one, 4- (2,4,6, 6-tetramethyl-2-cyclohexen-1-yl) -3-buten-2-one, 4- (2,4,6,6-tetramethyl-1-cyclohexen-1-yl) -3-buten-2 -One, 5-methyl-1- (3-methyl-3-cyclohexenyl) -1,3-hexanedione, 2-methyl-4- (2,6,6-trimethyl-2-cyclohexenyl) -3- Buten-1-al, 3-methyl-4- (2,4,6-trimethyl-3-cyclohexenyl) -3-buten-2-one, 4- (2-methyl-5-iso-propenyl-1- Cyclopenten-1-yl) -2-butanone, 4- (2,6,6-trimethyl 7-cycloheptenyl) -3-buten-2-one, 4- (2,6,6-trimethyl-4-cyclohexenyl) -3-buten-2-one, 2,6-dimethylundeca-2,6, 8-trien-10-one, 2,6,12-trimethyl-trideca-2,6,8-trien-10-one, 2,6-dimethyldodeca-2,6,8-trien-10-one, , 6,9-Trimethylundeca-2,6,8-trien-10-one, 4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -3-methyl-3-butene-2 -One, 4- (2,4,6-trimethyl-3-cyclohexen-1-yl) -3-buten-2-one, 5- (2-methylene-6,6-dimethylcyclohexyl) -4-pentene- 3-one and mixtures thereof, But it is not limited to these.
[0061]
Preferred ionones include 4- (2,6,6-trimethyl-3-cyclohexen-1-yl) -3-methyl-3-buten-2-one (Givaudan Rule, Corp., New Jersey, U.S.A. under the trademark Isolaldine). Commercially available from Teaneck, Inc.), 5- (2-methylene-6,6-dimethylcyclohexyl) -4-penten-3-one (a trademark of Givaudan Roure, Corp., Teaneck, NJ, U.S.A.). ), 4- (2,2,6-trimethyl-2-cyclohexen-1-yl) -3-buten-2-one (trade name International Flavors and Fragrances, Inc. under the trademark α-ionone). New York, New York, USA) Commercially available), 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -3-buten-2-one (International Flavors and Fragrances, Inc. under the trademark β-ionone. Commercially available from New York, NY), 4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -3-methyl-3-buten-2-one (Bush Boke Allen under the trademark methylionone). Inc. (commercially available from Montvale, NJ) and mixtures thereof.
[0062]
Ionone can be added to the odor masking base as one or more individual perfume chemicals or as a specific perfume composed of a combination of perfume chemicals including the ionone perfume chemicals. Examples of ionone-specific fragrances include Alvanone Extra (commercially available from International Flavors and Fragrances, Inc., New York, NY) and Irishia Base (commercially available from Firmenich, Inc., Princeton, NJ, USA). , Irival (commercially available from International Flavors and Fragrances, Inc., New York, NY), Iritone (commercially available from International Flavors and Fragrances, Inc., New York, NY) and mixtures thereof. But not limited to these.
Other suitable ionone-containing substances for use herein are, for example, natural substances such as lycopodium, violets, irises, scented irises and mixtures thereof.
[0063]
Musk and highly volatile fragrances used in the odor masking base can also be added to the odor masking base as one or more individual fragrance chemicals or as specific fragrances composed of a combination of fragrance chemicals. Examples of preferred highly volatile specific fragrances include, but are not limited to, Cassis Base 345-B (commercially available from Firmenich, Inc., Princeton, NJ, USA). Examples of N suitable ionone flavors and their boiling points at 1 atmosphere are disclosed in, but not limited to, US Pat. No. 5,919,440.
[0064]
Musk
The odor masking base may contain the musk component at a concentration of about 5% to about 70%, preferably about 15% to about 50%, more preferably about 20% to about 35% by weight of the odor masking base. It is preferred to contain. Musk is a well-known class of perfume chemicals, typically a colorless or pale yellow substance with a characteristic musk-like scent.
The musk component used in the odor masking base must have a boiling point at 1 atmosphere of greater than about 250 ° C., preferably greater than about 255 ° C., and more preferably greater than about 260 ° C., wherein the musk component is a polycyclic musk , Macrocyclic musk, nitrocyclic musk or a combination thereof. It is also preferred that the musk components each have more than about 12, preferably more than about 13, and more preferably more than about 15 carbon atoms.
[0065]
Suitable polycyclic musks include 5-acetyl-1,1,2,3,3,6-hexamethylindane, 4-acetyl-1,1-dimethyl-6-tert-butylindane, 7-acetyl -1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene, 1,1,4,4-tetramethyl-6-ethyl-7-acetyl-1,2,3 , 4-tetrahydronaphthalene, 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethyl-cyclopenta-γ-2-benzopyran and mixtures thereof.
Suitable macrocyclic musks include cyclopentadecanolide, cyclopentadecanolone, cyclopentadecanone, 3-methyl-1-cyclopentadecanone, cycloheptadecen-9-one-1, cycloheptadecanone, Cyclohexadecene-7-olide, cyclohexadecene-9-olide, cyclohexadecanolide, ethylene tridecandioate, 10-oxahexadecanolide, 11-oxahexadecanolide, 12-oxahexadecanolide and These mixtures are included.
[0066]
Suitable nitrocyclic musks include 1,1,3,3,5-pentamethyl-4,6-dinitroindane, 2,6-dinitro-3-methoxy-1-methyl-4-tert-butylbenzene, 2,6-dimethyl-3,5-dinitro-4-tert-butyl-acetophenone, 2,6-dinitro-3,4,5-trimethyl-tert-butylbenzene, 2,4,6-trinitro-1 , 3-dimethyl-5-tert-butylbenzene and mixtures thereof.
Preferred musks include 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethyl-cyclopenta-γ-2-benzopyran (International Flavors and Fragrances, trade name of Galaxolide, Inc. (commercially available from New York, NY), cyclopentadecanolide (commercially available from Firmenich, Inc. (Princeton, NJ, USA) under the trademark Exaltolide), ethylene tridecandioate (Ethylene Brasylate). 7-Acetyl-1,1,3,4,4,6-hexamethyl- under the trademark of Fragrance Resource, Inc. (Keyport, NJ, USA) 1,2,3,4-Tetrahydronaphthalene (Givaudan under the trademark Tonalid) Examples of suitable musks and their boiling points at 1 atmosphere are disclosed in, but not limited to, US Pat. No. 5,919,440. .
[0067]
(Example)
Abbreviations used in the examples
In the examples, the abbreviations of the component names have the following meanings.
[0068]
[Table 1]

[0069]
In the following examples, all proportions are expressed by weight.
[0070]
Examples 1 to 16
Examples 1 to 16 describe a pretreatment composition used before washing dishes in order to make it easier to remove cooking stains, burning stains and scorching stains on food. The composition of the example is applied to the wash. Laundry in Pyrex containers baked at 140 ° C for 2 hours, lasagna in stainless steel containers cooked at 150 ° C for 2 hours, potatoes and cheese in stainless steel containers cooked at 150 ° C for 2 hours, and cooked at 150 ° C for 2 hours It consists of different stains and different substrates such as egg yolk in a stainless steel container and sausages cooked at 120 ° C. for 1 hour and then at 180 ° C. for 1 hour. The wash is soaked in the composition of the example for 10 minutes and then rinsed with cold tap water. The wash is then washed by hand or with an automatic dishwasher (eg, Bosch 6032 dishwasher) with a typical dishwashing detergent composition (55 ° C., no pre-washing). Typical dishwashing detergent compositions include, for example, alkaline components, builders, enzymes, bleaches, bleach catalysts, nonionic surfactants, suds suppressors, silver corrosion inhibitors, soil suspending polymers, and the like. contains. The washes were treated with the compositions of the examples and then washed in a dishwasher to remove cooked, baked and scorched stains of the food.
[0071]
[Table 2]

[0072]
[Table 3]

[0073]
[Table 4]

[0074]
[Table 5]

[0075]
All examples have a liquid surface tension at 25 ° C. of less than 24.5 mN / m, a pH of 12 or more and a 45 minute soil swelling index for polymerized grease soils on stainless steel substrates of at least 200%.
The masking perfume compositions are shown in the table below.
[0076]
[Table 6]

Claims (48)

A cleaning composition for hard surfaces that removes cooking, burning or scorching soil from cooking utensils and tableware, comprising an organic amine solvent and having a liquid surface tension of less than about 24.5 mN / m. Wherein said composition has a pH of at least 10.5 when measured as a 10% distilled aqueous solution. The composition according to claim 1, wherein the composition has a pH of about 11 to about 14, preferably about 12 to about 13, when measured as a 10% distilled water solution. A composition according to claim 1 or 2, wherein the composition has a pre-alkalineity of less than about 5, preferably less than about 4, more preferably less than about 3. The composition comprises about 0.05 surfactant selected from anionic surfactants, amphoteric surfactants, zwitterionic surfactants, nonionic surfactants, semipolar surfactants and mixtures thereof. A composition according to any one of the preceding claims, containing from about 0.1 to about 10%, preferably from about 0.1 to about 2%. 5. The composition of any of claims 1-4, wherein the composition exhibits an advancing contact angle of less than about 20 ° at 25 ° C, preferably less than about 10 °, more preferably less than about 5 °, on a glass substrate coated with the polymerized fat. The composition according to claim 1. CLAIMS 1. A cleaning composition for hard surfaces that removes cooking dirt, burnt dirt or charred dirt from cooking utensils and tableware, comprising 25% on a glass substrate containing an organic amine solvent and coated with a polymerized fat. Such a composition that exhibits an advancing contact angle at less than about 20 °, preferably less than about 10 °, more preferably less than about 5 ° C. The composition according to any one of the preceding claims, wherein the composition has a soil swell index of at least about 100%, preferably at least about 200%, more preferably at least about 500%. A cleaning composition for hard surfaces that removes cooking, burning or scorching soil from cookware and tableware, comprising an organic amine solvent and comprising at least about 100%, preferably at least about 200%, More preferably, said composition having a soil swell index of at least about 500%. The composition according to any one of claims 1 to 8, further comprising a diffusion aid selected from an organic solvent, a wetting agent, and a mixture thereof. A composition according to claim 9, wherein the diffusion aid has a liquid surface tension of less than about 30 mN / m, preferably less than about 28 mN / m, more preferably less than about 26 mN / m. A cleaning composition for hard surfaces that removes cooking, burning or scorching stains from cookware and tableware, comprising about 1 to about 15% organic amine solvent and about 7 to about 30% diffusion. It contains from about 10% to about 40%, preferably from about 12% to about 20%, of an organic solvent, including a solvent acting as an auxiliary, and at least about 3.5% of a water-miscible solvent and about 3.5% restriction The composition comprising a water-miscible coupling solvent. The composition according to any one of claims 9 to 11, wherein the diffusion aid contains one or more organic solvent components selected from alcohol solvents, glycols, glycol derivatives, and mixtures thereof. The diffusion aid comprises a mixture of a water miscible organic solvent and a coupling organic solvent having limited water miscibility, wherein the ratio of the water miscible organic solvent to the coupling organic solvent is about 4: 13. The composition according to any one of claims 9 to 12, wherein the composition is from 1 to about 1:20, preferably from about 2: 1 to about 1: 6, more preferably from about 1.5: 1 to about 1: 3. . 14. A method according to any one of claims 9 to 13, wherein the diffusion aid comprises a wetting agent having a liquid surface tension of less than about 30 mN / m, preferably less than about 28 mN / m, more preferably less than about 26 mN / m. Composition. The composition according to any one of claims 9 to 14, wherein the diffusion aid comprises an amine oxide wetting agent. CLAIMS 1. A hard surface cleaning composition for removing cooking soil, burning soil or burning soil from cooking utensils and tableware, comprising an organic amine solvent, a coupling solvent having limited water miscibility and a wetting agent. The above composition, wherein the composition has a liquid surface tension of less than about 24.5 mN / m. A cleaning composition for hard surfaces that removes cooking dirt, burnt dirt or burnt dirt from cooking utensils and tableware, comprising an organic solvent system and a wetting agent, wherein the organic solvent system is preferably at least The above composition comprising an organic amine solvent component, wherein the wetting agent is effective to reduce the surface tension of the solvent system by at least 1 mN / m below the surface tension of the wetting agent. A cleaning composition for hard surfaces that removes cooking dirt, burning dirt or charred dirt from cooking utensils and tableware, comprising an organic solvent system and a wetting agent, wherein the organic solvent system comprises at least an organic amine. A solvent and a coupling solvent having at least one limited water miscibility, wherein the wetting agent is effective to reduce the surface tension of the solvent system by at least 1 mN / m below the surface tension of the wetting agent. object. 19. The composition according to any one of the preceding claims, wherein the hard surface detersive composition has a liquid surface tension of less than about 24 mN / m, preferably less than about 23.5 mN / m. 20. The composition according to any one of the preceding claims, wherein the organic amine solvent is selected from alkanolamines, alkylamines, alkyleneamines and mixtures thereof. 21. The composition according to any of the preceding claims, wherein the composition has a polymerized fat removal index of at least 25%, preferably at least 50%, more preferably at least 75%. A cleaning composition for hard surfaces that removes cooking dirt, burning dirt or burnt dirt from foods from cooking utensils and tableware, preferably comprising an organic solvent system containing at least an organic amine solvent component, and comprising: In the form of a liquid or gel having a liquid surface tension of less than 27 mN / m, preferably less than about 26 mN / m, more preferably less than about 25 mN / m, and having a pH greater than about 10.5, preferably greater than about 11 One such composition. A cleaning composition for hard surfaces that removes cooking dirt, burning dirt, or scorched dirt from foods from cooking utensils and tableware, comprising an organic solvent system, wherein the organic solvent system is coated with a polymerized fat or oil. Containing a plurality of solvent components, preferably including at least an organic amine solvent component, at a concentration such that it has an advancing contact angle less than the advancing contact angle of an equivalent composition containing the individual components of the solvent system on a dried glass substrate. The composition described above. A shear index (n) of about 0.3 to about 0.7, preferably about 0.4 to about 0.6, and about 0.20 to about 0.15 Pa.s. A composition according to any one of claims 1 to 23 in the form of a shear thinning fluid having a consistency index of s ^n. 25. The composition according to any of the preceding claims, wherein the composition sprayed on the vertical stainless steel surface has a flow rate of less than about 1 cm / s, preferably less than about 0.1 cm / s. The composition according to any one of claims 1 to 25, further comprising a thickener selected from a synthetic smectite-type clay, natural rubbers, and a mixture thereof. CLEANING COMPOSITION FOR RIGHT SURFACES FOR REMOVING FOOD COOKING, BURNING OR BURNING FOOD FROM COOKING EQUIPMENT AND TABLET EQUIPMENT, COMPRISING ORGANIC SOLVENT AND SYNTHETIC SMEKTITE TYPE HAVING AVERAGE PLATE SIZE <100 nm Such a composition comprising a clay thickener. The composition comprises an organic solvent system selected from alcohols, amines, esters, glycol ethers, glycols, terpenes and mixtures thereof, wherein at least one organic amine solvent component is included therein. A composition according to any one of the preceding claims. The organic solvent system, alkanolamines, alkyl amines, organic amine solvents including alkylene amines and mixtures thereof, aromatic alcohols, aliphatic alcohols (preferably C ₄ -C _10), cycloaliphatic alcohols and mixtures thereof alcohol solvent containing, (poly) alkylene glycol C ₂ -C _3, glycol ethers, glycol esters and glycol and glycol derivatives including mixtures thereof, and organic amine solvent, an alcohol solvent, the mixture is selected from glycols and glycol derivatives 29. The composition of claim 28, which is selected. The organic solvent comprises an organic amine (particularly alkanolamine, more particularly 2-aminoalkanol) solvent and a glycol ether solvent, preferably in a weight ratio of about 3: 1 to about 1: 3, wherein the glycol ether solvent is ethylene glycol Selected from monobutyl ether, diethylene glycol monobutyl ether, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propylene glycol monobutyl ether, dipropylene glycol monobutyl ether, ethylene glycol phenyl ether and mixtures thereof. A composition according to claim 28 or 29. 31. The composition according to any one of claims 28 to 30, wherein the glycol ether is a mixture of diethylene glycol monobutyl ether and propylene glycol butyl ether, preferably in a weight ratio of about 1: 2 to about 2: 1. 32. The composition according to any one of claims 28 to 31, wherein the organic solvent has a volatile organic content of less than about 50%, preferably less than about 20%, more preferably less than about 10% above 1 mmHg. 33. The method of any of claims 28 to 32, wherein the organic solvent is essentially free of solvent components having a boiling point of less than about 150 ° C, a flash point of less than about 50 ° C, preferably less than 100 ° C, or a vapor pressure of greater than about 1 mmHg. A composition according to claim 1. The composition according to any one of claims 1 to 33, which is in the form of a composition for pretreatment of dishwashing. 35. The composition according to any one of claims 1 to 34, which is in the form of an automatic dishwashing detergent composition. The composition according to any one of claims 1 to 35, further comprising a salt having a divalent cation, particularly magnesium. 37. The composition according to any one of claims 1 to 36, further comprising a perfume or perfume base for solvent odor masking. 38. The composition of claim 37, wherein the perfume or perfume base contains at least 0.001% by weight of ionone or a mixture of ionones. 39. The composition according to claim 38, wherein the ionone or mixture of ionones is selected from natural ionone-containing substances such as lycopodium, violets, irises, odorants and mixtures thereof. 40. The composition according to any one of claims 37 to 39, wherein the perfume or perfume base further comprises musk having a boiling point above about 250 <0> C. 41. The composition of any one of claims 37 to 40, wherein the perfume or perfume base further comprises a highly volatile perfume component or mixture of components having a boiling point of less than about 250 <0> C. 42. The composition according to any one of claims 1 to 41, further comprising a cyclodextrin malodor control agent. CLAIMS 1. A cleaning composition for hard surfaces which removes cooking dirt, burnt dirt or burnt dirt from foods from cooking utensils and tableware, which composition comprises an organic solvent system and a cyclodextrin malodor control agent. A method for removing cooking dirt, burnt dirt or charred dirt from cooking utensils and tableware, comprising the cleaning composition for hard surfaces according to any one of claims 1 to 43. Such a method, comprising treating the eating utensil. A cleaning composition for hard surfaces according to any one of claims 1 to 43, which is a method for removing cooking dirt, burning dirt or burnt dirt of polymerized fats and oils from metal cooking utensils and tableware. Such a method, comprising treating the cookware / tableware with an object. 44. A cleaning composition for hard surfaces according to any one of claims 1 to 43, which is a method for removing cooking dirt, burning dirt or burning dirt of carbohydrates from metal cooking utensils and tableware. The above method comprising treating cookware / tableware with. 47. The method according to any one of claims 44 to 46, comprising the step of pre-treating the cookware / tableware with the cleaning composition for hard surfaces before washing the dishes manually or automatically. Prior to manual or automatic washing of dishes, cookware / tableware is pre-treated with a hard surface cleaning composition and the cookware / tableware pretreated until the soil is sufficiently swollen is cleaned. 48. The method according to any one of claims 44 to 47, comprising the step of covering with a cling film.