JP2004331899A5 - - Google Patents

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Publication number
JP2004331899A5
JP2004331899A5 JP2003132554A JP2003132554A JP2004331899A5 JP 2004331899 A5 JP2004331899 A5 JP 2004331899A5 JP 2003132554 A JP2003132554 A JP 2003132554A JP 2003132554 A JP2003132554 A JP 2003132554A JP 2004331899 A5 JP2004331899 A5 JP 2004331899A5
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JP
Japan
Prior art keywords
ethylene
polyurethane elastomer
thermoplastic polyurethane
carbon monoxide
vinyl acetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
JP2003132554A
Other languages
Japanese (ja)
Other versions
JP4169631B2 (en
JP2004331899A (en
Filing date
Publication date
Application filed filed Critical
Priority to JP2003132554A priority Critical patent/JP4169631B2/en
Priority claimed from JP2003132554A external-priority patent/JP4169631B2/en
Publication of JP2004331899A publication Critical patent/JP2004331899A/en
Publication of JP2004331899A5 publication Critical patent/JP2004331899A5/ja
Application granted granted Critical
Publication of JP4169631B2 publication Critical patent/JP4169631B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Description

【特許請求の範囲】
【請求項1】
(A)熱可塑性ポリウレタンエラストマーと、
(B)エチレン−酢酸ビニル−一酸化炭素三元共重合体、エチレン−メタクリル酸エステ
ル−一酸化炭素三元共重合体、エチレン−アクリル酸アルキルエステル−一酸化炭素三元
共重合体、エチレン−グリシジルメタクリル酸エステル共重合体、エチレン−アクリル酸
エステル−無水マレイン酸三元共重合体、酢酸ビニルモノマー部が40重量%以上のエチ
レン−酢酸ビニル共重合体のうちの1種以上を含むことを特徴とする熱可塑性ポリウレタ
ンエラストマー組成物。
【請求項2】
(A),(B)からなる樹脂成分100重量部に対し、(C)有機系又は/及び無機系の
機能性添加剤のうちの少なくとも1種の含有量が1重量部以下であることを特徴とする請
求項1に記載の熱可塑性ポリウレタンエラストマー組成物。
【請求項3】
繊維質基材の少なくとも片面に請求項1又は2に記載の熱可塑性ポリウレタンエラストマ
ー組成物層を設けてなることを特徴とする積層体。
【請求項4】
(A)熱可塑性ポリウレタンエラストマーと、
(B)エチレン−酢酸ビニル−一酸化炭素三元共重合体、エチレン−メタクリル酸エステ
ル−一酸化炭素三元共重合体、エチレン−アクリル酸アルキルエステル−一酸化炭素三元
共重合体、エチレン−グリシジルメタクリル酸エステル共重合体、エチレン−アクリル酸
エステル−無水マレイン酸三元共重合体、酢酸ビニルモノマー部が40重量%以上のエチ
レン−酢酸ビニル共重合体のうちの1種以上を混合し、該混合物の軟化、溶融と略同時に
、あるいは軟化、溶融の直前又は直後に、(C)有機系又は/及び無機系の機能性添加剤
を混合することを特徴とする熱可塑性ポリウレタンエラストマー組成物の製造方法。
[Claims]
(1)
(A) a thermoplastic polyurethane elastomer;
(B) ethylene-vinyl acetate-carbon monoxide terpolymer, ethylene-methacrylate-carbon monoxide terpolymer, ethylene-acrylate alkyl ester-carbon monoxide terpolymer, ethylene- A glycidyl methacrylate copolymer, an ethylene-acrylate- maleic anhydride terpolymer, and a vinyl acetate monomer portion containing at least 40% by weight of an ethylene-vinyl acetate copolymer. A thermoplastic polyurethane elastomer composition characterized by the following:
(2)
( C) The content of at least one of the organic and / or inorganic functional additives is 1 part by weight or less based on 100 parts by weight of the resin component composed of (A) and (B). The thermoplastic polyurethane elastomer composition according to claim 1, characterized in that:
(3)
A laminate comprising a fibrous base material provided with the thermoplastic polyurethane elastomer composition layer according to claim 1 or 2 on at least one surface thereof.
(4)
(A) a thermoplastic polyurethane elastomer;
(B) Ethylene-vinyl acetate-carbon monoxide terpolymer, ethylene-methacrylate ester
Ru-carbon monoxide terpolymer, ethylene-alkyl acrylate-carbon monoxide ternary
Copolymer, ethylene-glycidyl methacrylate copolymer, ethylene-acrylic acid
Ester-maleic anhydride terpolymer, ethyl acetate containing at least 40% by weight of vinyl acetate monomer
One or more of a len-vinyl acetate copolymer is mixed, and at the same time as softening and melting of the mixture.
Or (C) an organic or / and inorganic functional additive immediately before or immediately after softening or melting.
And a method for producing a thermoplastic polyurethane elastomer composition.

本発明は、上記の知見に基づいてなされたものであって、その要旨は、
(A)熱可塑性ポリウレタンエラストマー(TPU)と、
(B)エチレン−酢酸ビニル−一酸化炭素三元共重合体(E−VA−CO)、エチレン−メタクリル酸エステル−一酸化炭素三元共重合体(E−MA−CO)、
エチレン−アクリル酸アルキルエステル−一酸化炭素三元共重合体(E−AAE−CO)、エチレン−グリシジルメタクリル酸エステル共重合体(E−GMA)、エチレン−アクリル酸エステル−無水マレイン酸三元共重合体(E−AE−MAH)、酢酸ビニルモノマー部(VA)が40重量%以上のエチレン−酢酸ビニル共重合体(E−VA)のうちの1種以上
を含むことを特徴とする熱可塑性ポリウレタンエラストマー組成物にある。
また、上記の(A)、(B)成分からなる樹脂成分に、(C)成分として有機系又は/及 び無機系の機能性添加剤を配合してもよい。
この有機系又は/及び無機系の添加剤の含有量は、(A),(B)からなる樹
脂成分100重量部に対し1重量部以下とすることが好ましい。
The present invention has been made based on the above findings, the gist of which is
(A) a thermoplastic polyurethane elastomer (TPU);
(B) ethylene-vinyl acetate-carbon monoxide terpolymer (E-VA-CO), ethylene-methacrylate-carbon monoxide terpolymer (E-MA-CO),
Ethylene-acrylic acid alkyl ester-carbon monoxide terpolymer (E-AAE-CO), ethylene-glycidyl methacrylate copolymer (E-GMA), ethylene-acrylate- maleic anhydride terpolymer Thermoplastic polymer characterized by containing one or more of polymer (E-AE-MAH) and ethylene-vinyl acetate copolymer (E-VA) in which vinyl acetate monomer part (VA) is 40% by weight or more. In a polyurethane elastomer composition.
Further, the above-mentioned (A), a resin component consisting of the component (B) may be blended with organic or /及 beauty inorganic functional additives as the component (C).
The content of the organic or / and inorganic additive is preferably 1 part by weight or less based on 100 parts by weight of the resin component composed of (A) and (B).

また、本発明は、繊維質基材の少なくとも片面に上記の熱可塑性ポリウレタンエラストマー層を設けてなることを特徴とする積層体をも要旨とする。
さらにまた、本発明は、(A)熱可塑性ポリウレタンエラストマーの軟化、溶融と略同時 に、あるいは軟化、溶融の直前又は直後に、(C)有機系又は/及び無機系の機能性添加 剤と混合することを特徴とする熱可塑性ポリウレタンエラストマー組成物の製造方法に関 する。
The gist of the present invention also provides a laminate characterized in that the thermoplastic polyurethane elastomer layer is provided on at least one surface of a fibrous base material.
Furthermore, mixing the present invention, the softening of the (A) thermoplastic polyurethane elastomer, the melting and substantially simultaneously, or softening, immediately before or after the melting, and (C) an organic and / or inorganic functional additives it related to method for producing a thermoplastic polyurethane elastomer composition, characterized in that.

JP2003132554A 2003-05-12 2003-05-12 Laminate using thermoplastic polyurethane elastomer composition and method for producing the laminate Expired - Lifetime JP4169631B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2003132554A JP4169631B2 (en) 2003-05-12 2003-05-12 Laminate using thermoplastic polyurethane elastomer composition and method for producing the laminate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2003132554A JP4169631B2 (en) 2003-05-12 2003-05-12 Laminate using thermoplastic polyurethane elastomer composition and method for producing the laminate

Publications (3)

Publication Number Publication Date
JP2004331899A JP2004331899A (en) 2004-11-25
JP2004331899A5 true JP2004331899A5 (en) 2006-01-19
JP4169631B2 JP4169631B2 (en) 2008-10-22

Family

ID=33507364

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2003132554A Expired - Lifetime JP4169631B2 (en) 2003-05-12 2003-05-12 Laminate using thermoplastic polyurethane elastomer composition and method for producing the laminate

Country Status (1)

Country Link
JP (1) JP4169631B2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9752022B2 (en) 2008-07-10 2017-09-05 Avery Dennison Corporation Composition, film and related methods
AU2011222600A1 (en) 2010-03-04 2012-10-04 Avery Dennison Corporation Non-PVC film and non-PVC film laminate
MX346688B (en) 2012-02-20 2017-03-29 Avery Dennison Corp Multilayer film for multi-purpose inkjet systems.
CA2935150A1 (en) 2013-12-30 2015-07-09 Avery Dennison Corporation Polyurethane protective film

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