JP2004188048A - Eating utensil - Google Patents

Eating utensil Download PDF

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Publication number
JP2004188048A
JP2004188048A JP2002361711A JP2002361711A JP2004188048A JP 2004188048 A JP2004188048 A JP 2004188048A JP 2002361711 A JP2002361711 A JP 2002361711A JP 2002361711 A JP2002361711 A JP 2002361711A JP 2004188048 A JP2004188048 A JP 2004188048A
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Japan
Prior art keywords
weight
tableware
fiber powder
wood fiber
biodegradable thermoplastic
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Pending
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JP2002361711A
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Japanese (ja)
Inventor
Toshiyuki Aeba
利行 饗庭
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Individual
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Individual
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Priority to JP2002361711A priority Critical patent/JP2004188048A/en
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  • Biological Depolymerization Polymers (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a low price, strong, safe and harmless eating utensil capable of being biodegraded and not producing harmful substances even if it is discarded and left in the soil without incineration. <P>SOLUTION: The eating utensil is formed by heating and pressure-molding a mixed material comprising 30-70 wt% of non-wood fiber powder made by crushing pulp of poaceous plants such as bamboo and reed and 30-70 wt% of biodegradable thermoplastic resin, or a mixed material comprising 30-70 wt% of non-wood fiber powder, 30-70 wt% of biodegradable thermoplastic resin, a small amount of one or more of a compatibilizing agent, an inorganic filler, an organic pigment and a flame retardant. <P>COPYRIGHT: (C)2004,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
本発明は、特に非木材系の繊維と生分解熱可塑性合成樹脂とを主材料とし、環境資源を保護し、廃棄するに際しても公害問題をも解決し得る食器に関するものである。
【0002】
【従来の技術】
従来の食器は、通常陶器や磁器又は金属で出来たものが一般的であるが、例えば給食用のごとく大量に使用する簡易な食器とか或いは使い捨て食器については、周知のごとくポリプロピレン樹脂等の合成樹脂を成型した皿、椀、カップ、フォークやスプーン等、更には紙を成型したものが多用されている。
【0003】
【発明が解決しようとする課題】
この様な従来の簡易な食器は、石油やパルプを大量に使用するので天然資源の浪費や多量の化学薬品の使用等を伴うのみならず、不要となった食器を廃棄処分するときに例えば埋め立て地などで土中に埋没させても何時までも腐敗せず、焼却処分するときには有害ガスを発生するので、環境の破壊や汚染、更には公害問題が発生するという解決すべき課題を有していた。
【0004】
そこで、本発明に於いては、このような簡易な食器の大量使用に際して上記課題を解決するために、安価な植物性材料や未利用材料を利用して大量生産が可能で、製品価格が安く、強靭で且つ安全無害であり、その上、廃棄するに際しても焼却処理する必要が無く、そのまま土中に廃棄、放置しても生分解されて有害物質を発生することのない食器を提供することを目的とする。
【0005】
【課題を解決するための手段】
該目的を達成するために講じた本発明の手段を、実施例の説明と共通の用語により説明すると、請求項1に該当する第1発明の食器は、竹、葦等イネ科植物のパルプを破砕して得た非木材繊維粉末30乃至70重量%と、生分解熱可塑性合成樹脂70乃至30重量%とからなる混合材料を加熱加圧成型してなる食器である。
【0006】
又、請求項2に該当する第2発明の食器は、竹、葦等イネ科植物のパルプを破砕して得た非木材繊維粉末30乃至70重量%と、生分解熱可塑性合成樹脂70乃至30重量%と、少量の添加剤とからなる混合材料を加熱加圧成型してなる食器である。
【0007】
【発明の実施の形態】
上記した本発明の食器を実施するには、使用される非木材繊維粉末はいずれも原材料の植物体を生のままで使用し、抗菌性を有する竹の幹、茎、皮、芯等からなる廃材、或いは葦等イネ科の植物等、非木材系植物の繊維をパルプ化し、該パルプを破砕機で破砕した後、例えばボールミルで略350μm以下(好ましくは250μm以下であることが望ましい)の微粉末とする。
【0008】
生分解熱可塑性樹脂は次のような種類の樹脂が存在する。即ち、1.例えばグリコールと脂肪族ジカルボン酸を主原料とするバイオケミカル高分子系合成樹脂、2.例えば澱粉を主成分とする天然高分子系合成樹脂、3.例えば、微生物が産出する有機酸を重合させた微生物系合成樹脂の3種類に大別される。いずれの生分解熱可塑性樹脂を使用しても良いが、実際に使用するにはバイオケミカル高分子系及び微生物系の合成樹脂が入手し易く安価であり、且つ熱可塑性も付与されているので実用的である。
【0009】
添加剤は製品の質的向上乃至改良を目的として上記主材料に添加する副材料であり、添加剤の種類並びに使用上の適量は以下のようである。混合率は、非木材繊維粉末30乃至70重量%と生分解熱可塑性合成樹脂70乃至30重量%との配合割合に対する数値である。1.非木材繊維粉末と生分解熱可塑性合成樹脂との混和性を良くするための相溶化剤(無水マレイン酸、カルボン酸等の有機酸)0.1乃至3重量%、2.製品にある程度の重量と剛性を付与するための無機質充填材(タルク、石灰石、酸化鉄、炭酸カルシウム等)1乃至30重量%、3.製品を任意の色調に着色するための有機顔料(通常合成樹脂に添加される顔料で可)1乃至30重量%、4.廃材に非燃焼化処理をするための難燃剤(燐酸エステル、メタ硼酸バリウム、硼酸亜鉛、三酸化アンチモン、酸化ジルコン、水酸化アルミニウム等)10乃至30重量%などである。これらの添加剤は、一種類づつ又は二乃至四種類を必要に応じて適当に組み合わせて前記主材料と混合する。
【0010】
上記に基づく主材料と添加剤とを混和した混合材料は、成型温度150℃乃至190℃、成型圧力約500乃至900Kg/cm2、成型時間20秒乃至80秒Sec程度の条件下で成型されてスプーン、フォーク、その他各種形状用途の食器となる。
【0011】
上述した本発明の食器は、従来は廃棄されていた竹、葦など非木材質の廃材から得られる非木材繊維粉末と生分解熱可塑性合成樹脂とを主成分とするので、環境資源の保護に寄与している。又、最終処理に際しては、且つ埋没して微生物による完全生分解をさせることにより廃棄物を消滅させるとともに、非燃焼化を実現したことで炭酸ガスをはじめその他の有害ガスの発生を阻止して、生活環境の汚染や破壊を防止し、環境衛生の浄化に貢献する作用を有する。更に、この食器の生産において、従来の合成樹脂成型機を利用する事が出来るので余分な設備投資は不要であり、前述の廃材利用と相俟って製造費や製品価格を抑制する事を可能とする。その上、有機顔料や無機質充填材の作用で優れた外観と強度とを有するので従来のプラスチック製食器と同等な実用性を備えているとともに、製造価格が低く且つ特殊な廃棄処理を必要としないので使い捨て食器としても有用である。
【0012】
【実施例】
以下本発明の各種の実施例を前記発明の実施の形態欄の記載事項並びに図面に基づいて説明する。図1は第1実施例の外観を示す斜視図、図2は第2実施例の外観を示す斜視図、図3は第3実施例の外観を示す斜視図である。
【0013】
第1実施例は図1に示すようにフォークである。非木材繊維粉末として竹繊維の粉末約22重量%と葦繊維の粉末約22重量%、生分解熱可塑性合成樹脂としてバイオケミカル高分子系合成樹脂であるグリコールと脂肪族ジカルボン酸を原料に縮重合法により合成される共重合ポリエステル(商品名ビオノーレ)約30重量%、及び添加物として相溶化(カルボン酸剤)3.5重量%、無機質充填材(石灰石)11重量%、有機顔料0.5重量%、難燃剤(燐酸エステル)11重量%を混合して成型用の混合材材とする。この混合材料を温度170℃、圧力700Kg/cm2の条件下で28秒かけて成型する。又、図示は省略するが、フォーク以外にスプーン等類似した食器に適用した使用例も存在する。
【0014】
第2実施例は皿形の食器である。本実施例の外観形状を図2に示す。非木材繊維粉末として竹繊維の粉末約22重量%と葦繊維の粉末約22重量%、生分解熱可塑性合成樹脂として天然高分子系合成樹脂である澱粉を主成分とし、変性ポリビニールアルコール等とのポリマーアロイ(商品名マタービー)約30重量%、及び添加物として相溶化剤(カルボン酸)3.5重量%、無機質充填材(炭酸カルシウム)11重量%、有機顔料0.5重量%、難燃剤(硼酸亜鉛)11重量%を混合して成型用の混合材材とする。この混合材料を温度170℃、圧力700Kg/cm2の条件下で28秒かけて成型する。尚、図示は省略するが、同一の材料を使用し、第2実施例と同じように成型することにより、食品包装用容器としたもの、弁当用容器とした使用例も存在する。
【0015】
第3実施例はカップ形の食器である。本実施例の外観形状を図3に示す。非木材繊維粉末として竹繊維の粉末約22重量%と葦繊維の粉末約22重量%、生分解熱可塑性合成樹脂として微生物生産高分子系合成樹脂であるβ−ヒドロキシ酪酸とβ−ヒドロキシ吉草酸からなる微生物産生有機酸の共重合ポリエステル(商品名バイオポール)約30重量%、及び添加物として相溶化剤(無水レイン酸)3.5重量%、無機質充填材(タルク)11重量%、有機顔料0.5%、難燃剤(酸化ジルコン)11重量%を混合して成型用の混合材材とする。この混合材料を温度170℃、圧力700Kg/cm2の条件下で28秒かけて成型する。図3に示す実施例は通常使用されるコーヒーカップであるが、自動販売機等に使用する使い捨てのカップにも応用する事が出来る。
【0016】
以上本発明の代表的と思われる実施例について説明したが、本発明は必ずしもこれらの実施例構造のみに限定されるものではなく、本発明にいう前記の構成要件を備え、かつ、本発明にいう目的を達成し、以下にいう効果を有する範囲内において適宜改変して実施することができるものである。
【0017】
【発明の効果】
本発明にいう食器は、竹の繊維の微粉末と、葦の繊維の微粉末とからなる非木材繊維粉末と生分解熱可塑性合成樹脂とからなる混合物に、相溶化剤、有機顔料、無機質充填材、難燃剤等の添加剤を少量混和した混合材料を加熱加圧して製造されたものであるから、従来は廃棄されていた竹、葦など非木材質の未利用材料を利用しているので環境資源の保護に寄与している。又、最終処理に際しては、焼却せずに埋没したまま放置しておいても、微生物による完全生分解をさせることにより廃棄物を消滅させるとともに、非燃焼化を実現したことで炭酸ガスをはじめその他の有害ガスの発生を阻止して、生活環境の汚染や破壊を防止して環境衛生の浄化を達成する効果を有する。更に、この食器を生産するに際しては従来の合成樹脂成型機を利用する事が出来るので特殊な或いは余分な設備投資は不要であり、前述の未利用材料の使用と相俟って製造費や製品価格を抑制する事を可能とする。その上、有機顔料や無機質充填材の作用で優れた外観と強度とを有するので、従来の食器と同等な実用性を備えているとともに、製造価格が低く且つ特殊な廃棄処理を必要としないので使い捨て食器としても有用であるという効果をも有するに至ったのである。
【図面の簡単な説明】
【図1】本発明の第1実施例の外形を示す斜視図。
【図2】第2実施例の外形を示す斜視図。
【図3】第3実施例の外形を示す斜視図。
【符号の説明】
1 食器
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention particularly relates to tableware mainly composed of non-wood fibers and a biodegradable thermoplastic synthetic resin, which can protect environmental resources and solve pollution problems when disposed.
[0002]
[Prior art]
Conventional tableware is generally made of pottery, porcelain or metal.For example, simple tableware used in large quantities such as for lunch or disposable tableware is made of synthetic resin such as polypropylene resin as is well known. Plates, bowls, cups, forks, spoons, and the like, which are made of, and paper are often used.
[0003]
[Problems to be solved by the invention]
Such conventional simple dishes use a large amount of petroleum and pulp, which not only wastes natural resources and uses a large amount of chemicals, but also disposes of unnecessary dishes, for example, in landfills. Even if it is buried in the ground, it does not rot for a long time and emits harmful gas when incinerated.Therefore, there is a problem to be solved that causes environmental destruction, pollution, and pollution problems. Was.
[0004]
Therefore, in the present invention, in order to solve the above-mentioned problem when using such simple tableware in large quantities, mass production is possible using inexpensive plant materials and unused materials, and product prices are low. To provide tableware that is tough, safe and harmless, does not need to be incinerated when disposed of, and does not biodegrade and generate harmful substances even when disposed and left in the soil as it is. With the goal.
[0005]
[Means for Solving the Problems]
Means of the present invention taken to achieve the object will be described in terms of common terms with the description of the embodiment. The tableware of the first invention corresponding to claim 1 is a pulp of a grass plant such as bamboo or reed. This is a tableware obtained by heating and pressing a mixed material comprising 30 to 70% by weight of non-wood fiber powder obtained by crushing and 70 to 30% by weight of a biodegradable thermoplastic synthetic resin.
[0006]
The tableware according to the second aspect of the present invention is characterized in that 30 to 70% by weight of non-wood fiber powder obtained by crushing pulp of grasses such as bamboo and reed, and 70 to 30 biodegradable thermoplastic synthetic resins. This is a tableware obtained by heating and pressing a mixed material consisting of a weight% and a small amount of additives.
[0007]
BEST MODE FOR CARRYING OUT THE INVENTION
In order to carry out the above-mentioned tableware of the present invention, the non-wood fiber powder used is a raw material of a raw plant body, and is composed of a bamboo stem, stem, skin, core, etc. having antibacterial properties. After pulping fibers of non-wood-based plants such as waste materials or grasses such as reeds, and crushing the pulp with a crusher, for example, the fineness of about 350 μm or less (preferably 250 μm or less) is obtained by a ball mill. Powder.
[0008]
The following types of biodegradable thermoplastic resins exist. That is, 1. For example, a biochemical polymer-based synthetic resin containing glycol and an aliphatic dicarboxylic acid as main raw materials; 2. For example, a natural polymer synthetic resin containing starch as a main component; For example, it is roughly classified into three types of microbial synthetic resins obtained by polymerizing organic acids produced by microorganisms. Any biodegradable thermoplastic resin may be used, but practical use is practical because biochemical polymer and microbial synthetic resins are readily available and inexpensive, and have thermoplasticity. It is a target.
[0009]
Additives are secondary materials added to the above-mentioned main materials for the purpose of improving or improving the quality of products, and the types of additives and the appropriate amounts in use are as follows. The mixing ratio is a numerical value based on the mixing ratio of 30 to 70% by weight of the non-wood fiber powder and 70 to 30% by weight of the biodegradable thermoplastic synthetic resin. 1. Compatibilizer (organic acid such as maleic anhydride, carboxylic acid, etc.) for improving the miscibility between the non-wood fiber powder and the biodegradable thermoplastic synthetic resin, 0.1 to 3% by weight; 2. 1 to 30% by weight of an inorganic filler (talc, limestone, iron oxide, calcium carbonate, etc.) for imparting a certain weight and rigidity to the product. 3. 1 to 30% by weight of an organic pigment for coloring the product in an arbitrary color tone (usually a pigment added to a synthetic resin); 10 to 30% by weight of a flame retardant (phosphate ester, barium metaborate, zinc borate, antimony trioxide, zircon oxide, aluminum hydroxide, etc.) for decombusting waste materials. These additives are mixed with the main material one by one or two to four types in an appropriate combination as needed.
[0010]
The mixed material obtained by mixing the main material and the additive based on the above is molded under the conditions of a molding temperature of 150 ° C. to 190 ° C., a molding pressure of about 500 to 900 kg / cm 2 , and a molding time of about 20 seconds to 80 seconds Sec. Spoons, forks, and other types of tableware.
[0011]
Since the above-described tableware of the present invention is mainly composed of non-wood fiber powder and biodegradable thermoplastic synthetic resin obtained from non-woody waste materials such as bamboo and reeds which have been conventionally discarded, it is useful for protecting environmental resources. Is contributing. In addition, at the time of final treatment, and by burying it and completely biodegrading it by microorganisms to eliminate waste, and by realizing non-combustion, the generation of carbon dioxide gas and other harmful gases is prevented, It has the effect of preventing pollution and destruction of the living environment and contributing to the purification of environmental hygiene. In addition, in the production of this tableware, it is possible to use a conventional synthetic resin molding machine, so no extra capital investment is required, and in conjunction with the use of waste materials described above, it is possible to reduce manufacturing costs and product prices. And In addition, it has excellent appearance and strength due to the action of organic pigments and inorganic fillers, so it has the same practicality as conventional plastic tableware, is low in production cost, and does not require special disposal. Therefore, it is also useful as disposable tableware.
[0012]
【Example】
Hereinafter, various embodiments of the present invention will be described with reference to the description of the embodiments of the present invention and the drawings. FIG. 1 is a perspective view showing the appearance of the first embodiment, FIG. 2 is a perspective view showing the appearance of the second embodiment, and FIG. 3 is a perspective view showing the appearance of the third embodiment.
[0013]
The first embodiment is a fork as shown in FIG. About 22% by weight of bamboo fiber powder and about 22% by weight of reed fiber powder as non-wood fiber powder, and biodegradable thermoplastic synthetic resin degenerated from glycol and aliphatic dicarboxylic acid, which are biochemical polymer synthetic resins Approximately 30% by weight of a copolymerized polyester (Bionore, trade name) synthesized by a synthetic method, 3.5% by weight of a compatibilizing agent (carboxylic acid agent), 11% by weight of an inorganic filler (limestone), and 0.5% of an organic pigment. % By weight and 11% by weight of a flame retardant (phosphate ester) to obtain a mixture material for molding. The mixed material is molded at a temperature of 170 ° C. and a pressure of 700 kg / cm 2 for 28 seconds. In addition, although not shown, there is a use example applied to similar tableware such as a spoon other than a fork.
[0014]
The second embodiment is a dish-shaped tableware. FIG. 2 shows the appearance of this embodiment. About 22% by weight of bamboo fiber powder and about 22% by weight of reed fiber powder as non-wood fiber powder, and starch, which is a natural polymer synthetic resin as a biodegradable thermoplastic synthetic resin, is used as a main component. About 30% by weight of a polymer alloy (trade name: Matterby), 3.5% by weight of a compatibilizer (carboxylic acid) as an additive, 11% by weight of an inorganic filler (calcium carbonate), 0.5% by weight of an organic pigment, and 11% by weight of a flame retardant (zinc borate) is mixed to form a mixed material for molding. The mixed material is molded at a temperature of 170 ° C. and a pressure of 700 kg / cm 2 for 28 seconds. Although not shown in the drawings, the same material is used and molded in the same manner as in the second embodiment to form a food packaging container or a lunch container.
[0015]
The third embodiment is a cup-shaped tableware. FIG. 3 shows the appearance of this embodiment. About 22% by weight of bamboo fiber powder and about 22% by weight of reed fiber powder as non-wood fiber powder, and biodegradable thermoplastic synthetic resin from microbial polymer synthetic resins β-hydroxybutyric acid and β-hydroxyvaleric acid About 30% by weight of a microbial organic acid-produced organic acid (trade name: Biopol), 3.5% by weight of a compatibilizer (leic anhydride), 11% by weight of an inorganic filler (talc), and an organic pigment 0.5% and 11% by weight of a flame retardant (zirconium oxide) are mixed to form a mixed material for molding. The mixed material is molded at a temperature of 170 ° C. and a pressure of 700 kg / cm 2 for 28 seconds. The embodiment shown in FIG. 3 is a commonly used coffee cup, but can be applied to a disposable cup used for a vending machine or the like.
[0016]
Although the embodiments that are considered to be representative of the present invention have been described above, the present invention is not necessarily limited to only the structures of the embodiments, but includes the above-described constituent features of the present invention, and The above-mentioned object can be achieved, and can be carried out with appropriate modifications within a range having the following effects.
[0017]
【The invention's effect】
The tableware according to the present invention comprises a mixture of non-wood fiber powder composed of fine powder of bamboo fiber, fine powder of reed fiber and biodegradable thermoplastic synthetic resin, a compatibilizer, an organic pigment, and an inorganic filler. It is manufactured by heating and pressurizing a mixed material in which a small amount of additives such as wood and flame retardant are mixed, so it uses non-woody unused materials such as bamboo and reeds that had been discarded in the past. Contributes to the protection of environmental resources. Also, at the time of final treatment, even if it is left buried without being incinerated, it is completely biodegraded by microorganisms, eliminating waste and realizing non-combustion. This has the effect of preventing the generation of harmful gases, preventing pollution and destruction of the living environment, and purifying environmental sanitation. Further, in producing this tableware, a conventional synthetic resin molding machine can be used, so no special or extra capital investment is required. It is possible to control the price. In addition, because it has excellent appearance and strength due to the action of organic pigments and inorganic fillers, it has the same practicality as conventional tableware, is low in production cost, and does not require special disposal treatment. They also have the effect of being useful as disposable tableware.
[Brief description of the drawings]
FIG. 1 is a perspective view showing an outer shape of a first embodiment of the present invention.
FIG. 2 is a perspective view showing an outer shape of a second embodiment.
FIG. 3 is a perspective view showing an outer shape of a third embodiment.
[Explanation of symbols]
1 tableware

Claims (4)

竹、葦等イネ科植物のパルプを破砕して得た非木材繊維粉末30乃至70重量%と、生分解熱可塑性合成樹脂70乃至30重量%とからなる混合材料を加熱加圧成型してなる食器。A mixed material consisting of 30 to 70% by weight of non-wood fiber powder obtained by crushing pulp of grasses such as bamboo and reed and 70 to 30% by weight of biodegradable thermoplastic synthetic resin is formed by heating and pressing. Tableware. 竹、葦等イネ科植物のパルプを破砕して得た非木材繊維粉末30乃至70重量%と、生分解熱可塑性合成樹脂70乃至30重量%と、少量の添加剤とからなる混合材料を加熱加圧成型してなる食器。A mixed material comprising 30 to 70% by weight of non-wood fiber powder obtained by crushing pulp of grasses such as bamboo and reed, 70 to 30% by weight of biodegradable thermoplastic synthetic resin, and a small amount of additives is heated. Tableware made by pressing. 上記添加剤が、相溶化剤、無機質充填材、有機顔料、難燃剤、又はこの内の1乃至複数種類から選定したものである請求項2記載の食器。3. The tableware according to claim 2, wherein the additive is selected from a compatibilizer, an inorganic filler, an organic pigment, a flame retardant, and one or more of them. 上記非木材繊維粉末の粒子の大きさが350μm以下である請求項1又は2に記載の食器。The tableware according to claim 1, wherein the size of the particles of the non-wood fiber powder is 350 μm or less.
JP2002361711A 2002-12-13 2002-12-13 Eating utensil Pending JP2004188048A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2135894A1 (en) * 2008-05-27 2009-12-23 Wu, Jui-Liang Biodegradable fibrous material composition
CN102229177A (en) * 2011-04-28 2011-11-02 中华人民共和国台州出入境检验检疫局 Tableware containing bamboo fibers and making method thereof
CN113712412A (en) * 2020-05-26 2021-11-30 亮宇国际有限公司 Biodegradable tableware containing no polylactic acid

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2135894A1 (en) * 2008-05-27 2009-12-23 Wu, Jui-Liang Biodegradable fibrous material composition
CN102229177A (en) * 2011-04-28 2011-11-02 中华人民共和国台州出入境检验检疫局 Tableware containing bamboo fibers and making method thereof
CN113712412A (en) * 2020-05-26 2021-11-30 亮宇国际有限公司 Biodegradable tableware containing no polylactic acid

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