JP2004173587A - Method for disinfecting cooked rice or rice product processed by steps involving heat-treating step - Google Patents

Method for disinfecting cooked rice or rice product processed by steps involving heat-treating step Download PDF

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JP2004173587A
JP2004173587A JP2002343828A JP2002343828A JP2004173587A JP 2004173587 A JP2004173587 A JP 2004173587A JP 2002343828 A JP2002343828 A JP 2002343828A JP 2002343828 A JP2002343828 A JP 2002343828A JP 2004173587 A JP2004173587 A JP 2004173587A
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rice
treatment
water
heat
electrolyzed water
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JP4117183B2 (en
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Seiichiro Isobe
五十部 誠一郎
Kunihiko Uemura
邦彦 植村
Kyoichiro Yoshida
恭一郎 吉田
Shoyu Lee
昌勇 李
Shoyu Kim
湘猷 金
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National Food Research Institute
CJ Corp
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National Food Research Institute
CJ Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for effectively disinfecting a cooked rice or a rice product processed by steps involving a heat-treating step, elementally without using a chemical treatment using chemicals and hardly developing fear of causing deterioration of the quality of the rice. <P>SOLUTION: The method for disinfecting the cooked rice or the rice product processed by the steps involving the heat-treating step involves carrying out a treatment for bringing a raw material rice into contact with an alkaline aqueous solution, and a treatment for soaking the treated rice in a strong acidic water before cooking the rice or heat-treating the rice. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、炊飯米又は加熱処理工程を含む米加工品の殺菌方法に関し、詳しくは炊飯米又は加熱処理工程を含む米加工品について、品質劣化を生じさせることなく、効果的に殺菌する方法に関する。
【0002】
【従来の技術】
米を炊飯又は加工して炊飯米又は米加工品を製造する際には、米の浸漬処理が行われる。通常、米の浸漬処理では、使用する水を米自身が吸水することから、非加熱的な殺菌処理として、薬剤を用いた化学的処理を行うことが困難であり、常温での保蔵が可能な加工では、加熱処理を充分に行うことが一般的であった。
【0003】
しかしながら、130℃を超えるような高温加熱などにより充分に加熱処理を行えば、加熱加工前に混入しているおそれのある耐熱芽胞菌を殺菌することができるものの、高温加熱による米の品質劣化が生じるおそれがある。
【0004】
従って、薬剤を用いた化学的処理ではなく、しかも米の品質劣化が生じるおそれなく、効果的に炊飯米又は加熱処理工程を含む米加工品を殺菌する方法が求められている。
【0005】
ところで希薄食塩水を隔膜を介して電解処理して生成した陽極側の酸性水溶液は殺菌能力のあることが知られている(例えば、特許文献1参照)。
しかしながら、この場合、対象物によっては充分に殺菌効果の出ない場合もあり、また酸性水中の殺菌効果を発現する主成分である有効塩素の臭いやその液の低いpH(pH1.5〜3.1)から処理物の品質低下を生じることもある。特に本発明の処理の対象物である米の場合、このような傾向が顕著であった。
【0006】
【特許文献1】
特許第2626778号
【0007】
【発明が解決しようとする課題】
本発明は、このような従来の欠点を解消するものであって、基本的に薬剤を用いた化学的処理ではなく、しかも米の品質劣化を生じさせるおそれなく、効果的に炊飯米又は加熱処理工程を含む米加工品を殺菌する方法を提供することを目的とするものである。
【0008】
【課題を解決するための手段】
本発明者らは、上記従来の課題を解決するため鋭意検討を重ねた。その結果、驚くべきことに、炊飯又は加熱処理に先立ち、原料米についてアルカリ性水溶液での接触処理及び強酸性水での浸漬処理を行うことにより、目的を達成し得ることを見出し、この知見に基づいて本発明を完成するに至った。
【0009】
すなわち、請求項1に係る本発明は、炊飯米又は加熱処理工程を含む米加工品の殺菌方法において、炊飯又は加熱処理に先立ち、原料米についてアルカリ性水溶液での接触処理及び強酸性水での浸漬処理を行うことを特徴とする、炊飯米又は米加工品の殺菌方法を提供するものである。
請求項2に係る本発明は、アルカリ性水溶液が、食塩無添加の電解水生成装置で得られたアルカリイオン水、食塩添加の電解水生成装置で得られた強アルカリ性水又は水酸化ナトリウム溶液である、請求項1記載の方法を提供するものである。
【0010】
【発明の実施の形態】
次に、本発明の実施の形態を示す。
請求項1に係る本発明は、炊飯米又は米加工品の殺菌方法に関し、炊飯米又は加熱処理工程を含む米加工品の殺菌方法において、炊飯又は加熱処理に先立ち、原料米についてアルカリ性水溶液での接触処理及び強酸性水での浸漬処理を行うことを特徴とするものである。
【0011】
請求項1に係る本発明は、炊飯米又は加熱処理加工を含む米加工品の殺菌方法に関するものである。
請求項1に係る本発明の一方の対象である炊飯米は通常、水に浸漬させておいた原料米を、加熱することにより製造される。また、請求項1に係る本発明のもう一方の対象は、加熱処理工程を含む米加工品、例えば、韓国の伝統食品である餅加工品、米粉菓子などである。このように、請求項1に係る本発明は、いずれも加熱処理工程を含むものである。請求項1に係る本発明は、このような通常の加熱処理工程を経ても殺菌することのできない耐熱性の細菌(耐熱芽胞菌など)を効果的に殺菌するものである。
【0012】
請求項1記載の本発明においては、炊飯又は加熱処理に先立ち、原料米についてアルカリ性水溶液での接触処理及び強酸性水での浸漬処理を行う。ここで原料米としては、籾殻が付いている状態のものであると殺菌効果が充分でないため、籾殻を除去した状態のもの(玄米)或いはそれを搗精した状態のもの(精白米)が用いられる。
アルカリ性水溶液としては様々なものが挙げられ、特に制限がないが、請求項2に記載したように、食塩無添加の電解水生成装置で得られたアルカリイオン水、食塩添加の電解水生成装置で得られた強アルカリ性水又は水酸化ナトリウム溶液が好ましい。
ここで食塩無添加の電解水生成装置で得られたアルカリイオン水、食塩添加の電解水生成装置で得られた強アルカリ性水としては、公知の電解水生成装置で得られるものを用いることができる。
この強アルカリ性水のpHは特に制限はないが、通常、pH10〜12前後のものが用いられる。
【0013】
アルカリ性水溶液での接触処理は、強酸性水での浸漬処理による殺菌処理と組み合わせて行われ、該処理自体単独ではほとんど殺菌効果は得られない。この意味で該処理は予備的な処理といえる。但し、強酸性水での浸漬処理による殺菌処理と組み合わせることにより、顕著な殺菌効果と品質劣化抑制効果を奏することができる。
【0014】
アルカリ性水溶液での接触処理の仕方としては、洗浄、浸漬などの手法があるが、通常、より処理程度の軽い洗浄で充分であり、そのときの洗浄時間も5分間程度の短時間で充分である。また、浸漬する場合には、あまりに長く浸漬しても、殺菌効果等に向上はみられないことから、長くても30分間程度の浸漬とすることが好ましい。アルカリ性水溶液での接触処理の時間は、材料等に合わせて適宜調整すればよい。同様に、接触処理の際のアルカリ性水溶液の使用量も、材料等に合わせて適宜調整すればよい。
【0015】
請求項1記載の本発明においては、原料米について、上記した如きアルカリ性水溶液での接触処理を行うと共に、強酸性水での浸漬処理を行うことが必要である。
アルカリ性水溶液での接触処理と強酸性水での浸漬処理とは、殺菌効果を奏するために、この順序で行うことが必要である。但し、必要に応じて、アルカリ性水溶液での接触処理に先立ち強酸性水で処理しておくことにより予備殺菌を行うこともできるし、或いは強酸性水での浸漬処理の後に再度アルカリ性水溶液で接触処理することにより汚れ落としを行うこともできる。
【0016】
強酸性水での浸漬処理に用いられる強酸性水としては、水溶性電離性無機物質(例えば食塩)添加又は無添加の電解水生成装置で得られた強酸性水(強酸性電解水)が挙げられる。すなわち、一般的には、希薄食塩水を電気分解して陽極側に生成される、次亜塩素酸を含む酸性の水溶液(強酸性電解水)が挙げられる。
この強酸性水のpHは特に制限はないが、あまり酸性度が強すぎないように、pH2.2〜2.7くらいのものが一般に用いられる。
【0017】
強酸性水での浸漬処理の時間としては、1時間程度浸漬しても差し支えないが、一般に30分前後浸漬すれば充分である。強酸性水での浸漬処理の時間は、材料等に合わせて適宜調整すればよい。同様に、浸漬処理の際の強酸性水の使用量も、材料等に合わせて適宜調整すればよい。
【0018】
なお、アルカリ性水溶液での予備接触処理と強酸性水での浸漬処理の前或いは後に、蒸留水での洗浄処理を行うことが好ましい。
蒸留水での洗浄処理は、一般に5分間程度で充分であるが、30分間程度行ってもよい。
【0019】
このようにしてアルカリ性水溶液での予備接触処理と強酸性水での浸漬処理とを行った後に、炊飯又は加熱処理して、炊飯米又は米加工品を製造することができる。
炊飯又は加熱処理は、常法により行えばよく、処理条件も常法における処理条件と同様にすればよい。
【0020】
このようにして製造された炊飯米又は米加工品は、加熱処理前に混入しているおそれのある耐熱芽胞菌が効果的に殺菌されているばかりか、著しい高温加熱処理を施す必要がないため、該処理による米の品質劣化が生じるおそれがない。
【0021】
【実施例】
以下において、実施例により本発明を詳しく説明するが、本発明はこれらに限定されるものではない。
【0022】
実施例1
供試米としては、市販されている精白米(2001年茨城産コシヒカリ)を使用した。
供試水には、蒸留水(図中、D/W 又は Distilled Water と表記した。)と、水道水を電解水生成装置(ホシザキ電機、ROX−20TA)で電解処理して得られる強酸性電解水(図中、AcEW と表記した。)と、同じく水道水を電解水生成装置(ホシザキ電機、ROX−20TA)で電解処理して得られる強アルカリ性電解水(図中、AlEW と表記した。)の3種を使用した。
精白米20gを各々100mlずつビーカーに採取して、50mlの供試水を加えて5分間攪拌し、洗米を行った。
次に、このビーカーに新たに供試水を加え、1時間浸漬した後、ステンレス製金網かごを使用して水切りを行った。
水切り後、pH測定機(HORIBA製、pHメーターD−22)を用いてのpHの測定、及び色差計(CHROMA−meter CR300)を用いての色差測定を行った。
電解水の微生物に対する殺菌効果を向上させるために、流水で洗米、浸漬を行った後、一般細菌数と耐熱性細菌数の変化を測定した。耐熱性細菌は、80℃で10分間処理した後、培養し、検出した。
【0023】
供試水による原料米の品質を評価するために、洗米、浸漬後、原料米のpHと色差を測定した。結果をそれぞれ図1と図2に示す。なお、図2中のL value (L値)は明るさを示し、a value (a値)は赤色を示し、b value (b値)は黄色を示している。
図1に示したように、原料米のpHは7.1程度の中性領域であり、蒸留水処理した場合(D/W 又は Distilled Water)には、pHの変化はあまり見られなかったが、強酸性電解水で1時間浸漬した場合(AcEW )には、pHが3.4に低下し、また、強アルカリ電解水で浸漬した場合(AlEW )には、pH9.4に変化した。
これに対して、電解水の組み合わせ処理として、まず強アルカリ電解水で5分間洗米し、強酸性電解水で30分間1次浸漬し、蒸留水で30分間2次浸漬した場合(AlEW→AcEW→D/W)には、図1に示したように、pH6.0に変化した。
これは、浸漬中に電解水が米に吸収されてpHの変化が起きたと考えられた。
【0024】
また、図2から明らかなように、単独の電解水で浸漬した場合では、強酸性電解水での処理(AcEW )により米の褐色化が認められ、また、強アルカリ電解水(AlEW )での処理により米の緑色化が認められた。これは、米のヌカ層に存在するタンパク質と炭水化物などが、pHの影響で変色したためと考えられた。
しかし、図2から明らかなように、電解水の組み合わせ処理を行うことにより、蒸留水処理と同様に変色は認められなかった。
以上の図1と図2に示す結果から、電解水の組み合わせ処理(AlEW→AcEW→D/W)を行うことにより、品質を損なわずに米の前処理が可能であることが明らかとなった。
【0025】
次に、殺菌試験の結果を図3に示す。図中、「Common−micro」と表記したのが一般細菌数を示しており「Heat−resist」と表記したのが耐熱性細菌数を示している。
図3中、Aが原料米、BがpH11.7の強アルカリ電解水(AlEW )での洗浄処理を行った場合、CがpH11.7の強アルカリ電解水(AlEW )での洗浄処理を行った後に強酸性電解水で1時間浸漬した場合(AcEW )、DがpH6.8の蒸留水で洗浄処理した(D/W)後に強酸性電解水で1時間浸漬した場合(AcEW )、EがpH2.7の強酸性電解水で洗浄処理した(AcEW )後に強酸性電解水で浸漬処理した場合(AcEW )のそれぞれの細菌数を示している。
電解水で処理した結果、強アルカリ電解水で洗浄し、強酸性電解水で浸漬した場合(図3中、Cの場合)、微生物の殺菌効果に優れていることが確認された。
これは、電解水の電解還元効果、有効塩素の殺菌効果と急激なpH変化等の外部環境の変化による微生物の適正生育条件の変化に起因するためと考えられる。
【0026】
実施例2
米に混在する菌数が、洗米、浸漬中にどの程度減少するかを確認するために、蒸留水を使用して韓国風餅の製造工程に適用し、加熱処理までの工程別に微生物の変化を測定した。その結果を図4に示す。
図4中、Aが原料米、BがpH6.8の蒸留水(D/W)での洗浄処理を行った場合、Cが次に蒸留水で30分間1次浸漬した場合(D/W)、Dが次いでpH6.8の蒸留水に2次浸漬した場合(D/W)、Eがさらに副材料の添加、粉砕を行った場合のそれぞれの細菌数を示しており、Fがさらに100℃、30分間の加熱処理を行った場合、Gが110℃、30分間の加熱処理を行った場合、Hが130℃、30分間の加熱処理を行った場合のそれぞれの細菌数を示している。
【0027】
図4によれば、蒸留水を使用して通常の洗浄処理、浸漬処理を行うことによっては、原料米中の一般細菌、耐熱性細菌はあまり減少しないし、また、最終的な加熱加工処理において、耐熱性細菌の胞子の殺菌を行うためには、110℃、30分間を超えるような高温加熱処理を施す必要があることが分かる。
【0028】
実施例3
米製品の保存で懸念される耐熱胞子に対する電解水の殺菌効果を比較、殺菌についてより明確に検討するために、耐熱芽胞菌( Bacillus subtilis )胞子懸濁液を原料米に撒いた後、蒸留水、電解水を使用し、洗米、浸漬処理をしたときの生菌数の変化を測定した。胞子を米に撒くために10cfu/mlの胞子液100mlを200gの原料米に噴霧し、10分間放置した後、これを供試水で処理して洗米、浸漬処理したときの微生物挙動を図5に示す。
【0029】
図5中、Aが原料米;BがpH6.8の蒸留水で洗浄処理した場合(D/W);CがpH6.8の蒸留水で洗浄処理した(D/W)後にpH6.8の蒸留水に30分間1次浸漬した場合(D/W);DがpH6.8の蒸留水で洗浄処理し(D/W)、次いでpH6.8の蒸留水に浸漬した(D/W)後にpH6.8の蒸留水に30分間2次浸漬した場合(D/W);EがpH11.7の強アルカリ電解水(AlEW )での洗浄処理を行った場合;FがpH11.7の強アルカリ電解水(AlEW )での洗浄処理を行った後に強酸性電解水で30分間浸漬した場合(AcEW );GがpH11.7の強アルカリ電解水(AlEW )での洗浄処理を行った後に強酸性電解水で30分間浸漬し(AcEW )、次いでpH6.8の蒸留水に30分間浸漬した場合(D/W)のそれぞれの細菌数を示している。
【0030】
図5によれば、通常処理を想定した蒸留水処理では、最終的に一般細菌数と耐熱性細菌数は、それぞれ約10分の1から100分の1程度の低下にとどまるに過ぎないことが分かる。
これに対して、アルカリ性水溶液での予備接触処理と強酸性水での浸漬処理を行う本発明の方法では、一般細菌数で約1000分の1、耐熱性細菌では1万分の1と、ほぼ検出限界以下までの殺菌が可能であることを示している。
従って、本発明の方法が、特に耐熱性細菌の殺菌に効果的であり、これを実施することで炊飯米や米の加熱加工品の微生物安全性を品質を損なうことなく確保できることが期待できる。
【0031】
【発明の効果】
請求項1〜2に係る本発明の方法によれば、炊飯又は加熱処理に先立ち、原料米についてアルカリ性水溶液での予備接触処理及び強酸性水での浸漬処理を行うことにより、米の品質劣化を生じさせるおそれなく、効果的に炊飯米又は加熱処理加工を含む米加工品を殺菌することができる。
すなわち、請求項1〜2に係る本発明の方法は、非加熱的な殺菌処理法でありながら、通常の炊飯又は加熱処理を施すことにより、本来通常の炊飯又は加熱処理を施すだけでは殺菌することのできない、加熱加工前に混入しているおそれのある耐熱芽胞菌などの耐熱性細菌を効果的に殺菌することができる。このように請求項1〜2に係る本発明の方法は、著しい高温加熱処理を施す必要がないため、該処理による米の品質劣化が生じるおそれがない。
【0032】
また、酸性水処理を行った場合、塩素臭がその後の加熱処理で加工した米について嗜好性を低下させたり、さらにはその液の低いpHから、変色など処理物の品質低下を生じさせたりしていたが、請求項1〜2に係る本発明の方法によれば、炊飯又は加熱処理後に得られる炊飯米又は米加工品は、臭いや色等が通常のものと遜色ない程度のものであり、嗜好性を低下させるおそれはなく、また、変色など処理物の品質低下を生じさせるおそれもない。
しかも、請求項1〜2に係る本発明の方法では、殺菌処理に使用するアルカリ性水溶液及び強酸性水に含まれる化学的成分は微量であり、基本的に薬剤を用いた化学的処理ではないため、安全性についても心配がない。
なお、本発明は、炊飯米又は加熱処理工程を含む米加工品の殺菌方法に関するものであるが、野菜など農産物においても電解水の適用可能性が考えられる。
【図面の簡単な説明】
【図1】実施例1におけるpHの測定結果を示すグラフである。
【図2】実施例1における色差の測定結果を示すグラフである。
【図3】実施例1における殺菌試験の結果を示すグラフである。
【図4】実施例2における工程別の微生物の変化の測定結果を示すグラフである。
【図5】実施例3における一般細菌数と耐熱性細菌数の測定結果を示すグラフである。
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a method for sterilizing cooked rice or processed rice including a heat treatment step, and more particularly to a method for effectively sterilizing cooked rice or processed rice including a heat treatment step without causing quality deterioration. .
[0002]
[Prior art]
When cooking or processing rice to produce cooked rice or processed rice, the rice is immersed. Usually, in rice immersion treatment, it is difficult to perform chemical treatment using chemicals as non-heat sterilization treatment because rice itself absorbs water used, and storage at room temperature is possible In processing, it has been general to perform a sufficient heat treatment.
[0003]
However, if the heat treatment is sufficiently performed by heating at a high temperature exceeding 130 ° C., the heat-resistant spores which may be mixed before the heat processing can be sterilized, but the quality deterioration of the rice due to the high temperature heating is reduced. May occur.
[0004]
Therefore, there is a need for a method of effectively sterilizing cooked rice or a processed rice product including a heat treatment step, which is not a chemical treatment using a chemical, and has no risk of deterioration of rice quality.
[0005]
By the way, it is known that an acidic aqueous solution on the anode side generated by electrolytically treating a diluted saline solution through a diaphragm has a sterilizing ability (for example, see Patent Document 1).
However, in this case, depending on the object, there may be a case where the bactericidal effect is not sufficiently obtained, and the odor of available chlorine, which is a main component exhibiting the bactericidal effect in acidic water, and the low pH of the solution (pH 1.5-3. From 1), the quality of the processed product may be reduced. In particular, in the case of rice which is an object of the treatment of the present invention, such a tendency was remarkable.
[0006]
[Patent Document 1]
Patent No. 2662678 [0007]
[Problems to be solved by the invention]
The present invention is intended to solve such conventional disadvantages, and is not basically a chemical treatment using chemicals, and furthermore, there is no fear of causing deterioration of rice quality, and rice cooked rice or heat treatment can be effectively performed. It is an object of the present invention to provide a method for sterilizing a processed rice product including a process.
[0008]
[Means for Solving the Problems]
The present inventors have conducted intensive studies to solve the above-mentioned conventional problems. As a result, it was surprisingly found that prior to rice cooking or heat treatment, the raw rice was subjected to contact treatment with an alkaline aqueous solution and immersion treatment in strongly acidic water, thereby achieving the object, and based on this finding. Thus, the present invention has been completed.
[0009]
That is, the present invention according to claim 1 is a method for sterilizing a processed rice product including a cooked rice or heat treatment step, wherein the raw rice is contacted with an alkaline aqueous solution and immersed in strongly acidic water prior to the rice cooking or heat treatment. It is intended to provide a method for sterilizing cooked rice or processed rice, which is characterized by performing a treatment.
According to a second aspect of the present invention, the alkaline aqueous solution is an alkaline ionized water obtained by an electrolyzed water generator without salt, a strongly alkaline water or a sodium hydroxide solution obtained by an electrolyzed water generator with salt added. , A method according to claim 1.
[0010]
BEST MODE FOR CARRYING OUT THE INVENTION
Next, an embodiment of the present invention will be described.
The present invention according to claim 1 relates to a method for sterilizing cooked rice or processed rice, and in a method for sterilizing cooked rice or processed rice including a heat treatment step, prior to cooking or heating, the raw rice is treated with an alkaline aqueous solution. The contact treatment and the immersion treatment in strongly acidic water are performed.
[0011]
The present invention according to claim 1 relates to a method for sterilizing cooked rice or processed rice including heat treatment.
Cooked rice which is one object of the present invention according to claim 1 is usually produced by heating raw rice immersed in water. Another object of the present invention according to claim 1 is a processed rice product including a heat treatment process, for example, a processed rice cake and rice flour confectionery which are Korean traditional foods. As described above, the present invention according to claim 1 includes the heat treatment step. The present invention according to claim 1 effectively sterilizes heat-resistant bacteria (such as heat-resistant spores) that cannot be sterilized even through such a normal heat treatment step.
[0012]
In the present invention, prior to the rice cooking or heating treatment, the raw rice is subjected to a contact treatment with an alkaline aqueous solution and a dipping treatment with strongly acidic water. Here, as the raw rice, since the sterilization effect is not sufficient if the rice is in a state where rice husks are attached, a rice from which rice husks have been removed (brown rice) or a rice milled state (milled rice) is used. .
As the alkaline aqueous solution, various ones can be mentioned, and there is no particular limitation. However, as described in claim 2, the alkaline ionized water obtained by the electrolyzed water generation device without salt, the electrolyzed water generation device with salt added, The resulting strongly alkaline water or sodium hydroxide solution is preferred.
Here, as the alkaline ionized water obtained by the electrolyzed water generating apparatus without salt and the strongly alkaline water obtained by the electrolyzed water generating apparatus with added salt, those obtained by a known electrolyzed water generating apparatus can be used. .
The pH of the strongly alkaline water is not particularly limited, but usually, a pH of about 10 to 12 is used.
[0013]
The contact treatment with an alkaline aqueous solution is performed in combination with a sterilization treatment by immersion treatment in strongly acidic water, and the treatment itself hardly provides a sterilization effect. In this sense, the process can be said to be a preliminary process. However, a remarkable sterilizing effect and a quality deterioration suppressing effect can be obtained by combining with a sterilizing treatment by immersion treatment in strongly acidic water.
[0014]
As a method of the contact treatment with the alkaline aqueous solution, there are methods such as washing and immersion. Usually, a lighter treatment is sufficient, and a washing time of about 5 minutes is sufficient. . In the case of immersion, even if it is immersed for an excessively long time, the bactericidal effect and the like are not improved. Therefore, the immersion is preferably performed for at most about 30 minutes. The time of the contact treatment with the alkaline aqueous solution may be appropriately adjusted according to the material and the like. Similarly, the amount of the alkaline aqueous solution used in the contact treatment may be appropriately adjusted according to the material and the like.
[0015]
According to the first aspect of the present invention, it is necessary for the raw rice to be subjected to the contact treatment with the alkaline aqueous solution as described above and to the immersion treatment with the strongly acidic water.
The contact treatment with the alkaline aqueous solution and the immersion treatment with the strongly acidic water need to be performed in this order in order to exhibit a sterilizing effect. However, if necessary, pre-sterilization can be performed by treating with a strong acidic water prior to the contact treatment with the alkaline aqueous solution, or contact treatment with the alkaline aqueous solution again after the immersion treatment with the strong acidic water. By doing so, dirt can be removed.
[0016]
Examples of the strongly acidic water used for the immersion treatment in the strongly acidic water include strongly acidic water (strongly acidic electrolyzed water) obtained by using an electrolyzed water generator with or without the addition of a water-soluble ionizable inorganic substance (eg, salt). Can be That is, in general, an acidic aqueous solution containing hypochlorous acid (strongly acidic electrolyzed water) generated on the anode side by electrolyzing a dilute saline solution is exemplified.
The pH of the strongly acidic water is not particularly limited, but a pH of about 2.2 to 2.7 is generally used so that the acidity is not too strong.
[0017]
The time of the immersion treatment in the strongly acidic water may be about one hour, but generally about 30 minutes suffices. The time of the immersion treatment in the strongly acidic water may be appropriately adjusted according to the material and the like. Similarly, the amount of strongly acidic water used in the immersion treatment may be appropriately adjusted according to the material and the like.
[0018]
It is preferable to perform a washing treatment with distilled water before or after the pre-contact treatment with the alkaline aqueous solution and the immersion treatment with the strongly acidic water.
Washing with distilled water is generally sufficient for about 5 minutes, but may be performed for about 30 minutes.
[0019]
After performing the preliminary contact treatment with the alkaline aqueous solution and the immersion treatment with the strongly acidic water in this way, the cooked rice or cooked rice product can be manufactured by cooking or heating.
The cooking or heating treatment may be performed by a conventional method, and the processing conditions may be the same as the processing conditions in the conventional method.
[0020]
The cooked rice or processed rice product thus produced is not only effectively sterilized by heat-resistant spores that may be mixed before the heat treatment, but also does not need to be subjected to a remarkably high-temperature heat treatment. In addition, there is no possibility that the quality of rice is deteriorated by the treatment.
[0021]
【Example】
Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited thereto.
[0022]
Example 1
As the test rice, commercially available polished rice (Koshihikari from Ibaraki, 2001) was used.
The test water was distilled water (indicated as D / W or Distilled Water in the figure) and strong acid electrolysis obtained by subjecting tap water to electrolytic treatment with an electrolyzed water generator (Hoshizaki Electric, ROX-20TA). Water (denoted as AcEW in the drawing) and strongly alkaline electrolyzed water (denoted as AlEW in the drawing) obtained by subjecting tap water to electrolytic treatment with an electrolyzed water generator (Hoshizaki Electric, ROX-20TA). Were used.
20 g of the polished rice was collected in a beaker of 100 ml each, 50 ml of test water was added thereto, and the mixture was stirred for 5 minutes to wash the rice.
Next, test water was newly added to the beaker, immersed for 1 hour, and then drained using a stainless steel wire mesh basket.
After draining, the pH was measured using a pH meter (manufactured by HORIBA, pH-22 D-22), and the color difference was measured using a color difference meter (CHROMA-meter CR300).
In order to improve the bactericidal effect of the electrolyzed water on microorganisms, the rice was washed and immersed in running water, and then the changes in the number of general bacteria and the number of heat-resistant bacteria were measured. The thermostable bacteria were treated at 80 ° C. for 10 minutes, then cultured and detected.
[0023]
In order to evaluate the quality of the raw rice with the test water, the pH and color difference of the raw rice were measured after washing and dipping. The results are shown in FIGS. 1 and 2, respectively. In FIG. 2, L value (L value) indicates brightness, a value (a value) indicates red, and b value (b value) indicates yellow.
As shown in FIG. 1, the pH of the raw rice is in a neutral region of about 7.1, and when treated with distilled water (D / W or Distilled Water), the change in pH is not so much observed. The pH dropped to 3.4 when immersed in strongly acidic electrolyzed water for 1 hour (AcEW), and changed to 9.4 when immersed in strongly alkaline electrolyzed water (AlEW).
On the other hand, as a combination treatment of electrolyzed water, rice is first washed for 5 minutes with strongly alkaline electrolyzed water, immersed in strongly acidic electrolyzed water for 30 minutes, and then immersed in distilled water for 30 minutes (AlEW → AcEW → D / W), the pH changed to 6.0 as shown in FIG.
This was thought to be because the electrolyzed water was absorbed by the rice during the immersion and the pH changed.
[0024]
As is clear from FIG. 2, when immersed in a single electrolyzed water, the browning of the rice was recognized by the treatment with the strongly acidic electrolyzed water (AcEW), and the rice was immersed in the strongly alkaline electrolyzed water (AlEW). Greening of rice was observed by the treatment. This was thought to be due to the discoloration of proteins and carbohydrates in the rice bran layer under the influence of pH.
However, as is clear from FIG. 2, the discoloration was not recognized by the combined treatment of the electrolyzed water as in the distilled water treatment.
From the results shown in FIGS. 1 and 2 above, it was clarified that by performing the combined treatment of the electrolyzed water (AlEW → AcEW → D / W), the pretreatment of rice was possible without deteriorating the quality. .
[0025]
Next, the results of the sterilization test are shown in FIG. In the figure, "Common-micro" indicates the number of general bacteria, and "Heat-resist" indicates the number of heat-resistant bacteria.
In FIG. 3, when A is a raw rice, and B is a cleaning treatment with strongly alkaline electrolyzed water (AlEW) having a pH of 11.7, C is a cleaning treatment performed with strongly alkaline electrolyzed water having a pH of 11.7 (AlEW). After immersion in strongly acidic electrolyzed water for 1 hour (AcEW), washing with distilled water having a pH of 6.8 (D / W), and then immersing in strongly acidic electrolyzed water for 1 hour (AcEW), E The numbers of bacteria are shown in the case where the bacteria were washed (AcEW) with strongly acidic electrolyzed water having a pH of 2.7 and then immersed in strongly acidic electrolyzed water (AcEW).
As a result of the treatment with the electrolyzed water, it was confirmed that when washed with strongly alkaline electrolyzed water and immersed in strongly acidic electrolyzed water (C in FIG. 3), the microorganism was excellent in the bactericidal effect.
This is considered to be due to changes in the appropriate growth conditions of the microorganisms due to changes in the external environment such as the electrolytic reduction effect of the electrolyzed water, the bactericidal effect of available chlorine, and a sudden pH change.
[0026]
Example 2
Distilled water was applied to the process of producing Korean-style rice cakes in order to check how much the number of bacteria mixed in rice decreased during washing and immersion. It was measured. The result is shown in FIG.
In FIG. 4, A is a raw rice, B is a cleaning treatment with distilled water (D / W) having a pH of 6.8, and C is a primary immersion in distilled water for 30 minutes (D / W). , D are then immersed in distilled water having a pH of 6.8 (D / W), E is the number of bacteria when additional materials are added and pulverized, and F is 100 ° C. , 30 minutes of heat treatment, G indicates the number of bacteria when 110 ° C. and 30 minutes of heat treatment are performed, and H indicates the number of bacteria when heat treatment is performed at 130 ° C. and 30 minutes.
[0027]
According to FIG. 4, general bacteria and heat-resistant bacteria in the raw rice do not decrease so much by performing normal washing treatment and immersion treatment using distilled water, and in the final heat processing. It can be seen that in order to sterilize spores of heat-resistant bacteria, it is necessary to perform high-temperature heat treatment at 110 ° C. for more than 30 minutes.
[0028]
Example 3
In order to compare the sterilization effect of electrolyzed water on heat-resistant spores which may be a concern during storage of rice products and to examine the sterilization more clearly, a suspension of heat-resistant spores (Bacillus subtilis) spores is spread on raw rice and then distilled water. The change in the number of viable bacteria when rice was washed and immersed using electrolyzed water was measured. In order to spread spores on rice, 100 ml of a spore solution of 10 8 cfu / ml is sprayed on 200 g of raw rice, left for 10 minutes, treated with test water, washed with rice, and subjected to microbial behavior when immersed. As shown in FIG.
[0029]
In FIG. 5, A is a raw rice; B is washed with distilled water having a pH of 6.8 (D / W); C is washed with distilled water having a pH of 6.8 (D / W); When immersed in distilled water for 30 minutes (D / W); D is washed with distilled water having a pH of 6.8 (D / W), and then immersed in distilled water having a pH of 6.8 (D / W). When secondary immersed in distilled water of pH 6.8 for 30 minutes (D / W); E is a washing treatment with strongly alkaline electrolyzed water (AlEW) having a pH of 11.7; F is a strong alkali having a pH of 11.7. When immersed in strongly acidic electrolyzed water for 30 minutes after performing a cleaning process with electrolyzed water (AlEW) (AcEW); After performing a cleaning process with strongly alkaline electrolyzed water (AlEW) having G of pH 11.7, strongly acidic Immersed in electrolyzed water for 30 minutes (AcEW) and then in distilled water of pH 6.8 for 30 minutes If immersed respectively show the number of bacteria (D / W).
[0030]
According to FIG. 5, in the distilled water treatment assuming the normal treatment, the number of general bacteria and the number of heat-resistant bacteria ultimately decrease only by about one tenth to one hundredth, respectively. I understand.
On the other hand, in the method of the present invention in which the preliminary contact treatment with the alkaline aqueous solution and the immersion treatment with the strongly acidic water are performed, the number of general bacteria is about 1/1000, and the number of heat-resistant bacteria is about 1/1000, which is almost detected. This indicates that sterilization below the limit is possible.
Therefore, the method of the present invention is particularly effective for sterilizing heat-resistant bacteria, and it can be expected that the microbial safety of cooked rice and heat-processed rice can be ensured without impairing the quality by performing the method.
[0031]
【The invention's effect】
According to the method of the present invention according to claims 1 and 2, prior to cooking or heating, rice is subjected to a preliminary contact treatment with an alkaline aqueous solution and a dipping treatment with strongly acidic water to reduce the quality of rice. It is possible to effectively sterilize cooked rice or cooked rice including heat treatment without fear of causing it.
That is, the method of the present invention according to claims 1 and 2 is a non-heat sterilization treatment method, but by performing normal rice cooking or heat treatment, sterilization is performed only by performing normal rice cooking or heat treatment. It is possible to effectively sterilize heat-resistant bacteria such as heat-resistant spores that may not be able to be mixed before heating. As described above, the method of the present invention according to claims 1 and 2 does not need to perform a remarkable high-temperature heat treatment, so that there is no possibility that the quality of rice is deteriorated by the treatment.
[0032]
In addition, when acid water treatment is performed, chlorine odor lowers the palatability of rice processed by the subsequent heat treatment, and further, due to the low pH of the liquid, the quality of the processed material such as discoloration is reduced. However, according to the method of the present invention according to claims 1 and 2, the cooked rice or processed rice product obtained after cooking or heat treatment is such that the smell, color, and the like are not inferior to normal ones. There is no risk of lowering the palatability, and there is no risk of lowering the quality of the processed product such as discoloration.
Moreover, in the method of the present invention according to claims 1 and 2, the chemical components contained in the alkaline aqueous solution and the strongly acidic water used in the sterilization treatment are trace amounts, and are not basically chemical treatments using drugs. There is no worry about safety.
The present invention relates to a method for sterilizing cooked rice or a processed rice product including a heat treatment step. However, the possibility of applying electrolyzed water to agricultural products such as vegetables is considered.
[Brief description of the drawings]
FIG. 1 is a graph showing measurement results of pH in Example 1.
FIG. 2 is a graph showing measurement results of color differences in Example 1.
FIG. 3 is a graph showing the results of a sterilization test in Example 1.
FIG. 4 is a graph showing measurement results of changes in microorganisms for each step in Example 2.
FIG. 5 is a graph showing the measurement results of the number of general bacteria and the number of thermostable bacteria in Example 3.

Claims (2)

炊飯米又は加熱処理工程を含む米加工品の殺菌方法において、炊飯又は加熱処理に先立ち、原料米についてアルカリ性水溶液での接触処理及び強酸性水での浸漬処理を行うことを特徴とする、炊飯米又は米加工品の殺菌方法。In a method for sterilizing a cooked rice or a processed rice product including a heat treatment step, prior to the rice cooking or heat treatment, the raw rice is subjected to a contact treatment with an alkaline aqueous solution and a dipping treatment with strongly acidic water. Or a method of sterilizing processed rice. アルカリ性水溶液が、食塩無添加の電解水生成装置で得られたアルカリイオン水、食塩添加の電解水生成装置で得られた強アルカリ性水又は水酸化ナトリウム溶液である、請求項1記載の方法。The method according to claim 1, wherein the alkaline aqueous solution is alkaline ionized water obtained by an electrolyzed water generator without salt, strong alkaline water or a sodium hydroxide solution obtained by an electrolyzed water generator with salt added.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015188361A (en) * 2014-03-28 2015-11-02 日清食品ホールディングス株式会社 Processed rice and production method thereof
JP2016182102A (en) * 2015-03-27 2016-10-20 日清食品ホールディングス株式会社 Processed rice
CN110122775A (en) * 2019-06-04 2019-08-16 浙江五芳斋实业股份有限公司 A kind of manufacture craft of rice cake
WO2021164364A1 (en) * 2020-02-20 2021-08-26 江南大学 Sterilization method for fresh-keeping wet rice noodles

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015188361A (en) * 2014-03-28 2015-11-02 日清食品ホールディングス株式会社 Processed rice and production method thereof
JP2016182102A (en) * 2015-03-27 2016-10-20 日清食品ホールディングス株式会社 Processed rice
CN110122775A (en) * 2019-06-04 2019-08-16 浙江五芳斋实业股份有限公司 A kind of manufacture craft of rice cake
WO2021164364A1 (en) * 2020-02-20 2021-08-26 江南大学 Sterilization method for fresh-keeping wet rice noodles

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