JP2004122088A - Hydrogen water and manufacturing method of the same - Google Patents

Hydrogen water and manufacturing method of the same Download PDF

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Publication number
JP2004122088A
JP2004122088A JP2002294192A JP2002294192A JP2004122088A JP 2004122088 A JP2004122088 A JP 2004122088A JP 2002294192 A JP2002294192 A JP 2002294192A JP 2002294192 A JP2002294192 A JP 2002294192A JP 2004122088 A JP2004122088 A JP 2004122088A
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Japan
Prior art keywords
water
hydrogen
cluster size
gas
hydrogen water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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JP2002294192A
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Japanese (ja)
Inventor
Yukio Hirose
広瀬 幸雄
Kenji Yamazaki
山崎 憲治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TOMIO KEISHA KK
Eco Japan Co Ltd
Asahi Engineering Co Ltd Fukuoka
Original Assignee
TOMIO KEISHA KK
Eco Japan Co Ltd
Asahi Engineering Co Ltd Fukuoka
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Application filed by TOMIO KEISHA KK, Eco Japan Co Ltd, Asahi Engineering Co Ltd Fukuoka filed Critical TOMIO KEISHA KK
Priority to JP2002294192A priority Critical patent/JP2004122088A/en
Publication of JP2004122088A publication Critical patent/JP2004122088A/en
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  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a hydrogen water having a low oxidation-reduction potential of the water itself by dissolving hydrogen gas, generated from city gas and alcohol, etc., in water without adding minerals, such as calcium, sodium, magnesium, and potassium, or vitamin C to water. <P>SOLUTION: In the manufacturing method of the hydrogen water, a high frequency current is impressed to water to reduce its cluster size, the hydrogen gas is dissolved in the water having the reduced cluster size under a pressure of 0.1 MPa to 2.0 MPa and plasma is applied to the city gas or the alcohol. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、飲料用、医療用、産業用に用いられる水素水とその製造法に関する。
【0002】
【従来の技術】
従来から、電気分解法と浸透膜法により水素水を製造する方法が既知である。これら方法は何れも水を酸素水と水素水に分離し水素水を得る方法であるが、この水素水に含有される水素は1ppmに過ぎない。この水素水の酸化還元電位は−100mVから−200mV程度であり、人体への還元効果と、精密機械やIC部品の洗浄効果において充分な効果を得難い。
【0003】
又特許文献1においては、イオン交換樹脂と、トルマリン及び特定の金属の混合物と、マイナス電子を有する岩石とを順次通過させ、アルカリイオン水又は還元水と称する水素水を製造する方法を開示している。
【0004】
この水素水の酸化還元電位は+250mVから−250mVであるとしているが、平均的には−100mV程度が限界であり、上記と同様、人体への還元効果と、精密機械やIC部品の洗浄効果において充分な効果を得難い。
【0005】
又特許文献2に示すように、これら水素水の酸化還元電位を低くするために、カルシウム、ナトリウム、マグネシウム、カリウム等のミネラル分又はビタミンC等を水に添加して電気分解することが提案されているが、水にミネラル分又はビタミンC等の添加が必要不可欠であるばかりか、実際には上記カルシウム、ナトリウム、マグネシウム、カリウム等のミネラル分又はビタミンCの添加による酸化還元電位の低下では、これらを添加せずに水そのものの酸化還元電位を低下させた場合に比べその効用において著しく劣る。
【0006】
【特許文献1】
特開平7−号132284号公報
【0007】
【特許文献2】
特開2002−18439号公報
【0008】
【発明が解決しようとする課題】
本発明は水に対し水素が5ppmから10ppm溶解せる、即ち酸化還元電位に換算すると−300mVから−800mVの、上記還元効果と洗浄効果において顕著な水素水とその製造法を提供する。
【0009】
【課題を解決するための手段】
本発明に係る水素水は、クラスターサイズを縮小した水に水素ガスを溶解させた水素水であって、酸化還元電位が−300mVから−800mVである水素水である。
【0010】
上記酸化還元電位である水素水は水のPHが6から9である時に最も有効である。
【0011】
上記水素水の製造法として、水に高周波電流を印加し、好ましくは水に1kHZから100kHZの高周波電流を印加してクラスターサイズを縮小し、該クラスターサイズを縮小した水に水素ガスを0.1MPaから2.0MPaの圧力下で溶解させる方法を採る。これにより水に対する水素ガスの溶解量を著しく増大する。
【0012】
又上記水に水素ガスを溶解させる工程において、触媒としてトルマリン又は貴宝石又は貴陽石又はこれら何れかの表面に金属触媒の微粒子を付着させたものを使用する。これらは自らマイナスイオンを発生し、酸化還元電位を向上せしめる役割を果たすと同時に、自ら水と反応し電気分解を惹起して水素を発生し、その溶解を助長する。又クラスターサイズを縮小する作用も有している。
【0013】
上記水素ガスは都市ガス又はアルコールにプラズマを当て生成したものである。
【0014】
上記水素水のクラスターサイズは該水素水に磁気、好ましくは20,000ガウスから50,000ガウスを照射することにより、より有効に維持される。
【0015】
一般的に水素水はこれを飲料用として用いると、体内の活性酸素を除去し免疫力を高めるという医療的効果があることが知られている。
【0016】
本発明に係る水素水は、特許文献2に示す如きカルシウム、ナトリウム、マグネシウム、カリウム等のミネラル分又はビタミンC等を水に添加する必要がなく、水に都市ガスやアルコール等から生成した水素ガスを一定の圧力下で溶解せしめることにより、水そのものの酸化還元電位が非常に低い水素水が得られる。
【0017】
上記のカルシウム、ナトリウム、マグネシウム、カリウム等のミネラル分及びビタミンC等が含まれていない水素水は、特に医療用や産業用に使用される水として適切である。
【0018】
【発明の実施の形態】
本発明に係る水素水は、クラスターサイズを縮小した水に水素ガスを溶解させた水素水であって、酸化還元電位が−300mVから−800mVである水素水である。
【0019】
上記酸化還元電位である水素水は水のPHが6から9である時に最も有効である。
【0020】
上記水素ガスは都市ガス又はアルコールにプラズマを当て生成したものである。
【0021】
以下上記水素水の製造法を図1のフローチャートに基づいて説明する。
【0022】
この方法は水に高周波電流を印加し、好ましくは水に1kHZから100kHZの高周波電流を印加してクラスターサイズを縮小し、該クラスターサイズを縮小した水に水素ガスを0.1MPaから2.0MPaの圧力下で溶解させる方法を採る。これにより水に対する水素ガスの溶解量を著しく増大する。
【0023】
詳述すると水道水、地下水、河川水、海水を原料水とし、この原料水を不純物除去装置を通して上記原料水中に含まれている無機物のイオン、細菌、塵埃等を除去し、所謂純水を得る。
【0024】
上記不純物除去装置としては、逆浸透膜装置、海水の淡水化装置、イオン交換樹脂装置、水沸騰装置等を用いる。
【0025】
次に医療用水素水又は産業用水素水である場合には、好ましくは溶存酸素除去装置を用いて原料水中に溶解している酸素を除去し、次のクラスター水製造装置へ供する。又飲料用水素水である場合には、この溶存酸素除去装置を通さずに、次のクラスター水製造装置へ供しても良い。
【0026】
而してクラスター水製造装置によって前記の如く、水に高周波電流を印加し、好ましくは水に1kHZから100kHZの高周波電流を印加してクラスターサイズを縮小する。
【0027】
又他の方法として上記高周波電流を印加する装置を用いずに、水にトルマリン又は貴宝石又は貴陽石又はこれら何れかの表面に金属触媒の微粒子を付着させたものを接触させ、クラスターサイズを縮小する。
【0028】
例えば水道水では水の分子が100個位集まって一つの塊として存在するが、上記クラスター水製造装置によりこれを50個程度に縮小する。
【0029】
次に水素ガス溶解装置により上記クラスターサイズを縮小した水に0.1MPaから2.0MPaまで加圧した水素ガスを添加し、同水に水素ガスを溶解せしめる。即ちクラスターサイズを縮小した水に水素ガスを0.1MPaから2.0MPaの圧力下で溶解せしめる。
【0030】
上記水素ガスは水素ガス製造装置により、都市ガス又はアルコール(メタノール、エタノール等)にプラズマを照射し生成したものである。都市ガスの利用は極めて容易であり、又アルコールは入手性に富み、安全性が高く有用である。
【0031】
上記水素ガス溶解装置により上記水に水素ガスを溶解させる工程において、触媒としてトルマリン又は貴宝石又は貴陽石又はこれら何れかの表面に金属触媒の微粒子を付着させたものを使用する。これらは自らマイナスイオンを発生し、酸化還元電位を向上せしめる役割を果たすと同時に、自ら水と反応し電気分解を惹起して水素を発生し、その溶解を助長する。又上記の通りクラスターサイズを縮小する作用も有している。
【0032】
次に上記水素ガスを溶解せしめたクラスターサイズ縮小水に磁化装置により磁気、好ましくは20,000ガウスから50,000ガウスの磁気を照射することにより磁化し、上記クラスターサイズを安定に維持する。よって目的とする水素水を得る。
【0033】
上記水素水の製造法によれば、電位測定器(東京都新宿区高田馬場1−29−10の東亜ディーケーケー株式会社製のORP計)を用いて測定した酸化還元電位が、−300mVから−800mVの水素水を得られることが判明した。
【0034】
酸化還元電位と水素の溶解量(ppm)とは略比例して推移することが知られており、この酸化還元電位の測定によって水素の溶解量を推測することができる。この推測に基づくと上記方法によって製造された水素水の水素ガスの溶解量は5ppmから10ppmであると予測され、従来想定し難い水素溶解量を有する水素水が得られる。
【0035】
【発明の効果】
本発明に係る水素水は、特許文献2に示す如きカルシウム、ナトリウム、マグネシウム、カリウム等のミネラル分又はビタミンC等を水に添加する必要がなく、水に都市ガスやアルコール等から生成した水素ガスを一定の圧力下で溶解せしめることにより、水そのものの酸化還元電位が非常に低い水素水が得られる。
【0036】
この水素水は人体や動植物への還元効果が著しく高く、加えて微粒子物体の洗浄効果が顕著であり、飲料用、医療用、産業用の水素水としてその機能を遺憾なく発揮する。
【図面の簡単な説明】
【図1】本発明に係る水素水の製造工程を示すフローチャート。
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to hydrogen water used for beverages, medical uses, and industrial uses, and a method for producing the same.
[0002]
[Prior art]
Conventionally, a method of producing hydrogen water by an electrolysis method and a permeable membrane method is known. Each of these methods is a method of separating water into oxygen water and hydrogen water to obtain hydrogen water, but the hydrogen water contained in the hydrogen water is only 1 ppm. The oxidation-reduction potential of this hydrogen water is about -100 mV to -200 mV, and it is difficult to obtain a sufficient effect on the reduction effect on the human body and the cleaning effect on precision machines and IC parts.
[0003]
Patent Document 1 discloses a method for producing hydrogen water called alkali ion water or reduced water by sequentially passing an ion exchange resin, a mixture of tourmaline and a specific metal, and a rock having negative electrons. I have.
[0004]
The oxidation-reduction potential of this hydrogen water is assumed to be from +250 mV to -250 mV, but on average is limited to about -100 mV. As described above, the reduction effect on the human body and the cleaning effect on precision machinery and IC parts are similar. It is difficult to obtain a sufficient effect.
[0005]
Further, as shown in Patent Document 2, in order to lower the oxidation-reduction potential of these hydrogen waters, it has been proposed to add minerals such as calcium, sodium, magnesium, potassium or the like or vitamin C or the like to water and perform electrolysis. However, the addition of minerals or vitamin C to water is not only indispensable, but in fact, the reduction of the oxidation-reduction potential due to the addition of minerals such as calcium, sodium, magnesium and potassium or vitamin C, The effect is remarkably inferior to the case where the oxidation-reduction potential of water itself is lowered without adding these.
[0006]
[Patent Document 1]
JP-A-7-132284
[Patent Document 2]
JP-A-2002-18439
[Problems to be solved by the invention]
The present invention provides a hydrogen water in which 5 to 10 ppm of hydrogen is dissolved in water, that is, -300 mV to -800 mV in terms of oxidation-reduction potential, which is remarkable in the above-mentioned reduction effect and cleaning effect, and a method for producing the same.
[0009]
[Means for Solving the Problems]
The hydrogen water according to the present invention is hydrogen water obtained by dissolving hydrogen gas in water having a reduced cluster size, and has a redox potential of -300 mV to -800 mV.
[0010]
Hydrogen water having the above oxidation-reduction potential is most effective when the pH of water is 6 to 9.
[0011]
As a method for producing the hydrogen water, a high-frequency current is applied to water, preferably a high-frequency current of 1 kHz to 100 kHz is applied to the water to reduce the cluster size, and 0.1 MPa of hydrogen gas is applied to the water having the reduced cluster size. From 2.0 to 2.0 MPa. This significantly increases the amount of hydrogen gas dissolved in water.
[0012]
In the step of dissolving hydrogen gas in water, tourmaline, precious jewelry, precious stone or any of these is used as a catalyst with fine particles of a metal catalyst adhered thereto. These generate negative ions by themselves and play a role in improving the oxidation-reduction potential, and at the same time, react with water to cause electrolysis to generate hydrogen, thereby promoting its dissolution. It also has the effect of reducing the cluster size.
[0013]
The hydrogen gas is generated by applying plasma to city gas or alcohol.
[0014]
The cluster size of the hydrogen water is more effectively maintained by irradiating the hydrogen water with magnetism, preferably 20,000 to 50,000 gauss.
[0015]
It is generally known that hydrogen water, when used for drinking, has a medical effect of removing active oxygen in the body and enhancing immunity.
[0016]
Hydrogen water according to the present invention does not require addition of minerals such as calcium, sodium, magnesium, potassium or vitamin C, etc. to water as shown in Patent Document 2, and hydrogen gas generated from city gas or alcohol in water Is dissolved under a constant pressure, whereby hydrogen water having a very low oxidation-reduction potential of water itself can be obtained.
[0017]
Hydrogen water which does not contain minerals such as calcium, sodium, magnesium, potassium, etc. and vitamin C is suitable as water used especially for medical and industrial uses.
[0018]
BEST MODE FOR CARRYING OUT THE INVENTION
The hydrogen water according to the present invention is hydrogen water obtained by dissolving hydrogen gas in water having a reduced cluster size, and has a redox potential of -300 mV to -800 mV.
[0019]
Hydrogen water having the above oxidation-reduction potential is most effective when the pH of water is 6 to 9.
[0020]
The hydrogen gas is generated by applying plasma to city gas or alcohol.
[0021]
Hereinafter, the method for producing hydrogen water will be described with reference to the flowchart of FIG.
[0022]
In this method, a high-frequency current is applied to water, preferably, a high-frequency current of 1 kHz to 100 kHz is applied to water to reduce the cluster size, and hydrogen gas of 0.1 MPa to 2.0 MPa is applied to the water having the reduced cluster size. The method of dissolving under pressure is adopted. This significantly increases the amount of hydrogen gas dissolved in water.
[0023]
Specifically, tap water, groundwater, river water, and seawater are used as raw water, and the raw water is removed through an impurity removing device to remove inorganic ions, bacteria, dust, and the like contained in the raw water, thereby obtaining so-called pure water. .
[0024]
As the impurity removing device, a reverse osmosis membrane device, a desalination device for seawater, an ion exchange resin device, a water boiling device and the like are used.
[0025]
Next, in the case of medical hydrogen water or industrial hydrogen water, oxygen dissolved in the raw water is preferably removed by using a dissolved oxygen removing device, and then supplied to the next cluster water producing device. In the case of drinking hydrogen water, the hydrogen water may be supplied to the next cluster water producing apparatus without passing through the dissolved oxygen removing apparatus.
[0026]
As described above, a high-frequency current is applied to water by the cluster water producing apparatus, preferably, a high-frequency current of 1 kHz to 100 kHz is applied to water to reduce the cluster size.
[0027]
As another method, the cluster size is reduced by contacting water with tourmaline, precious gem, precious stone, or any of these having metal catalyst fine particles adhered to the surface thereof without using the device for applying the high-frequency current. I do.
[0028]
For example, in tap water, about 100 water molecules gather and exist as one lump, but the cluster water producing apparatus reduces the number to about 50.
[0029]
Next, hydrogen gas pressurized from 0.1 MPa to 2.0 MPa is added to the water having the reduced cluster size by a hydrogen gas dissolving apparatus, and the hydrogen gas is dissolved in the water. That is, hydrogen gas is dissolved in water having a reduced cluster size under a pressure of 0.1 MPa to 2.0 MPa.
[0030]
The hydrogen gas is generated by irradiating city gas or alcohol (methanol, ethanol, etc.) with plasma by a hydrogen gas producing apparatus. Use of city gas is extremely easy, and alcohol is highly available, safe and useful.
[0031]
In the step of dissolving hydrogen gas in the water using the hydrogen gas dissolving apparatus, tourmaline, precious jewelry, precious stone, or any of these having metal catalyst fine particles adhered to the surface thereof is used as a catalyst. These generate negative ions by themselves and play a role in improving the oxidation-reduction potential, and at the same time, react with water to cause electrolysis to generate hydrogen, thereby promoting its dissolution. As described above, it also has the function of reducing the cluster size.
[0032]
Next, the cluster size-reduced water in which the hydrogen gas is dissolved is magnetized by irradiating it with magnetism, preferably from 20,000 gauss to 50,000 gauss, by a magnetizing device to maintain the cluster size stably. Therefore, the desired hydrogen water is obtained.
[0033]
According to the method for producing hydrogen water, the oxidation-reduction potential measured using a potential measuring device (ORP meter manufactured by Toa DKK Inc., 1-29-10, Takadanobaba, Shinjuku-ku, Tokyo) is -300 mV to -800 mV. It was found that hydrogen water could be obtained.
[0034]
It is known that the oxidation-reduction potential and the dissolved amount (ppm) of hydrogen change substantially in proportion. By measuring the oxidation-reduction potential, the dissolved amount of hydrogen can be estimated. Based on this estimation, it is predicted that the amount of hydrogen gas dissolved in the hydrogen water produced by the above method is from 5 ppm to 10 ppm, and hydrogen water having a hydrogen dissolution amount that is hardly supposed to be obtained conventionally can be obtained.
[0035]
【The invention's effect】
Hydrogen water according to the present invention does not require addition of minerals such as calcium, sodium, magnesium, potassium or vitamin C, etc. to water as shown in Patent Document 2, and hydrogen gas generated from city gas or alcohol in water Is dissolved under a constant pressure, whereby hydrogen water having a very low oxidation-reduction potential of water itself can be obtained.
[0036]
This hydrogen water has a remarkably high effect of reducing the human body, animals and plants, and has a remarkable cleaning effect on fine particles, and thus can be fully used as hydrogen water for drinking, medical use, and industry.
[Brief description of the drawings]
FIG. 1 is a flowchart showing a process of producing hydrogen water according to the present invention.

Claims (6)

クラスターサイズを縮小した水に水素ガスを溶解させた水素水であって、酸化還元電位が−300mVから−800mVであることを特徴とする水素水。Hydrogen water obtained by dissolving hydrogen gas in water having a reduced cluster size, wherein the oxidation-reduction potential is from -300 mV to -800 mV. 上記水のPHが6から9であることを特徴とする請求項1記載の水素水。The hydrogen water according to claim 1, wherein the pH of the water is from 6 to 9. 水に高周波電流を印加してクラスターサイズを縮小し、該クラスターサイズを縮小した水に水素ガスを0.1MPaから2.0MPaの圧力下で溶解させたことを特徴とする水素水の製造法。A method for producing hydrogen water, comprising applying a high-frequency current to water to reduce the cluster size, and dissolving hydrogen gas in the water having the reduced cluster size under a pressure of 0.1 MPa to 2.0 MPa. 水に水素ガスを溶解させる工程において、触媒としてトルマリン又は貴宝石又は貴陽石又はこれら何れかの表面に金属触媒の微粒子を付着させたものを使用することを特徴とする請求項3の水素水の製造法。4. The process according to claim 3, wherein in the step of dissolving the hydrogen gas in water, tourmaline, precious gem, or precious stone or any one of which has fine particles of a metal catalyst adhered thereto is used as a catalyst. Manufacturing method. 上記水素ガスは都市ガス又はアルコールにプラズマを当て生成したものであることを特徴とする請求項3又は4記載の水素水の製造法。5. The method for producing hydrogen water according to claim 3, wherein the hydrogen gas is generated by applying plasma to city gas or alcohol. 上記水素水に磁気を照射してクラスターサイズを維持することを特徴とする請求項3又は4又は5記載の水素水の製造法。The method for producing hydrogen water according to claim 3, wherein the hydrogen water is irradiated with magnetism to maintain a cluster size.
JP2002294192A 2002-10-07 2002-10-07 Hydrogen water and manufacturing method of the same Pending JP2004122088A (en)

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JP2005296939A (en) * 2004-03-15 2005-10-27 Japan Organo Co Ltd Method and apparatus for producing active oxygen removal water
WO2006051588A1 (en) * 2004-11-10 2006-05-18 Wataru Murota Reducing beverage and process for producing the same
WO2006082655A1 (en) * 2005-02-07 2006-08-10 Wataru Murota Reducing perfume and process for producing the same
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JPWO2006061880A1 (en) * 2004-12-06 2008-06-05 渉 室田 Reducing lotion and method for producing the same
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JP2014016088A (en) * 2012-07-09 2014-01-30 Yukio Hirose Active hydrogen containing ice
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JP2005000901A (en) * 2003-06-12 2005-01-06 Hiroshima Kasei Ltd Method of maintaining oxidation-reduction potential of water at from -400 millivolt to -600 millivolt
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JPWO2006061880A1 (en) * 2004-12-06 2008-06-05 渉 室田 Reducing lotion and method for producing the same
WO2006082655A1 (en) * 2005-02-07 2006-08-10 Wataru Murota Reducing perfume and process for producing the same
JPWO2006082655A1 (en) * 2005-02-07 2008-06-26 渉 室田 Reducing perfume and method for producing the same
WO2007021034A1 (en) * 2005-08-19 2007-02-22 Shigeo Ohta Scavenger of harmful active oxygen and/or free radical in living body
JP5106110B2 (en) * 2005-08-19 2012-12-26 成男 太田 Remove harmful active oxygen and / or free radicals in vivo
US9050278B2 (en) 2005-08-19 2015-06-09 Shigeo Ohta Scavenger of in vivo harmful reactive oxygen species and/or free radicals
JP2007077035A (en) * 2005-09-12 2007-03-29 Hiromaito Co Ltd Reducing aqueous composition
JP2007253131A (en) * 2006-03-27 2007-10-04 Takaoka Kasei Kogyo Kk Functional water containing anti-oxidant
WO2007116889A1 (en) * 2006-04-03 2007-10-18 Yuugen Kaisya Joho Kagaku Kenkyusyo Free radical scavenging hydrogen solution, and method and apparatus for producing the same
JP2008239598A (en) * 2007-02-27 2008-10-09 I'rom Holdings Co Ltd Liquid composition
JP2010005530A (en) * 2008-06-26 2010-01-14 Osamu Hirota Hydrogen-containing mineral water and its production method
JP2013123667A (en) * 2011-12-13 2013-06-24 Naoyuki Yada Hydrogen water producing system and hydrogen water producing method
JP2014016088A (en) * 2012-07-09 2014-01-30 Yukio Hirose Active hydrogen containing ice
KR101370129B1 (en) 2013-09-24 2014-03-26 (주)이노게이트 Hydrogen abundant water making apparatus with function to adjust dissolved hydrogen
KR101777452B1 (en) * 2015-03-26 2017-09-26 강성만 Straight Male Hydrogen Reduction of Water Production Device and Manufacturing Method thereof and thereof use
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