JP2004108952A - Gas sampling device - Google Patents

Gas sampling device Download PDF

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Publication number
JP2004108952A
JP2004108952A JP2002272392A JP2002272392A JP2004108952A JP 2004108952 A JP2004108952 A JP 2004108952A JP 2002272392 A JP2002272392 A JP 2002272392A JP 2002272392 A JP2002272392 A JP 2002272392A JP 2004108952 A JP2004108952 A JP 2004108952A
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JP
Japan
Prior art keywords
gas
chamber
decreasing
increasing
volume
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2002272392A
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Japanese (ja)
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JP4116378B2 (en
Inventor
Kenji Ichiya
一箭 健治
Shunsuke Mitsuya
三ツ谷 俊介
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dowa Holdings Co Ltd
Original Assignee
Dowa Mining Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dowa Mining Co Ltd filed Critical Dowa Mining Co Ltd
Priority to JP2002272392A priority Critical patent/JP4116378B2/en
Publication of JP2004108952A publication Critical patent/JP2004108952A/en
Application granted granted Critical
Publication of JP4116378B2 publication Critical patent/JP4116378B2/en
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Abstract

<P>PROBLEM TO BE SOLVED: To analyze continuously a component in exhaust gas. <P>SOLUTION: This gas sampling device has a chamber for storing gas having a gas inlet connected to a pipe wherein the gas flows, and a means for increasing or decreasing the chamber volume. The means for increasing or decreasing the chamber volume is a means moving along the chamber inner wall. The chamber is formed by a deformable bag, and the means for increasing or decreasing the chamber volume is a pump for introducing the gas into the bag. The chamber is also equipped with a gas exhaust port connected to an analytical means. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は気体のサンプリング装置、特に、分析を要する排気ガスのサンプリング装置に関するものである。
【0002】
【従来の技術】
廃棄物は焼却炉により焼却され、熱により分解され、焼却ガスと残査とに分かれる。焼却ガスは無害化するために化学処理、フィルター捕集などされる。最終的には煙道を通して無害化した排ガスを大気に放出する。このようにすることは例えば、特開2002−139409号公報で提案されている。
【0003】
廃棄物は、炉への投入時にその組成は一定でなく、また一定にすることが困難である。このため煙道に入る直前に排ガスの成分を検査し、その値の変動により焼却または焼却ガスの無害化処理の制御を行う必要がある。
【0004】
即ち、その処理においては、ガスの組成が変動するのに応じてガス処理装置を制御しなければならない。
【0005】
【発明が解決しようとする課題】
ガスの組成変化を察知するためにはガス分析装置などを用いればよいが、ガス分析装置のなかには、測定対象元素によっては分析値が判明するまで一定の時間を必要とするものがあり、分析している間においても焼却ガスが流出しているため、未分析のガスが流れてしまう空白時間が生じてしまう。これを補うため短時間で測定できるか、空白時間が生じないような測定方法や簡便な装置が望まれている。
【0006】
なお、分析に時間を要する元素を分析する際には、分析機器を複数台用いれば見かけ上の空白時間はより短くなるが、分析機器は高価であることが多く、またメンテナンスも頻発することから新たな問題が発生する。
【0007】
【課題を解決するための手段】
本発明の気体のサンプリング装置は、気体が流通する管に接続される気体導入口を有する気体を貯蔵するチャンバーと、このチャンバーの容積を増減する手段とを備えたことを特徴とする。
【0008】
上記チャンバーの容積を増減する手段は、上記チャンバー内壁に沿って移動する手段であることを特徴とする。
【0009】
上記チャンバーは、変形する袋によって形成され、上記チャンバーの容積を増減する手段が、上記袋内にガスを導入するポンプであることを特徴とする。
【0010】
上記チャンバーは、更に、分析手段に接続される気体排出口を備えることを特徴とする。
【0011】
【発明の実施の形態】
以下図面によって本発明の実施例を説明する。
【0012】
本発明においては、図1に示すように、煙導またはガス送風管1内を流れる特定ガスを、ガスサンプラー2を用いて例えばフロンガスを時間当たり定量に例えば30分間サンプリングした後、サンプルガスの一部を分析用サンプラー3に送り、例えばFID(水素炎イオン化検出器)方式のガスクロマトグラフィー4により分析することで当該特定ガスの濃度を計測すると同時に、ガス送風管1内の当該特定ガスを含むガス全体の流量を渦流量計等の流量計5で連続計測し、得られた当該特定ガスの濃度と、上記ガス全体の流量から当該特定ガスの流量を得るようにする。
【0013】
上記ガスサンプラー2としては、例えばピストン6によってシリンダー7のチャンバーの容積を徐々に拡張することでガス導入管8を通して排ガスを採取するものを用いる。この場合、時間当りの採取量が一定になるように、なお温度補正をかけピストンの移動量を制御すればなお好ましい。
【0014】
このようなガスサンプラー2では、上記ピストン6の移動で上記チャンバーが徐々に拡張する際、サンプリングされたガスがチャンバー内で環流し、撹拌効果が生じ、組成が均一なガスサンプルが生成される。
【0015】
ガスサンプラー2としては変形する袋状のものと、これにガスを導入するポンプとより成るものを用いても良い。
【0016】
なお、ガス導入管8の容積が大きいとガス導入管8内に滞留するガス量がチャンバー容量を越えた場合、チャンバー内がガス導入管内のガスで充満されてしまい、ガス送風管1内を流れるガスを随時吸引することができなくなるため、ガス導入管8は長さ、太さを調整し、極力容積を小さくすることが望ましい。
【0017】
ガス送風管1の構造や設置場所などによりガス導入管の容量がチャンバー容量を越えてしまう場合は、チャンバーの手前に予備チャンバーを設けるか、ガス導入管とガス送風管にさらにバイパス管または吸引機を設ければ、ガス導入管の容量にこだわらずチャンバーへのガスの吸引量を制御できるようになる。
【0018】
予め決めた採取量となったら、ガス弁を制御し、素早くガスサンプラー2のピストン6を押し戻し、ガスを排出する。ガスは、分析用サンプラー3に一旦貯蔵して分析をする。
【0019】
また、ガス成分によっては、配管内が堆積物で閉塞してしまうことがあるが、このようなガス成分の場合には、経路にフラッシング装置を配置し、適宜エアーにより堆積物を除去できるようにする。なお、ガスサンプラー2で、一気にガスを放出(流出)することで、このフラッシング効果をも同時に達成できる。
【0020】
上記ガスクロマトグラフィー4による分析時間は例えばフロンの場合は30分であり、分析終了後直ちにガス送風管1に排出する。
【0021】
【発明の効果】
上記のように本発明の気体のサンプリング装置によれば、ガスサンプラーを用いたため、排ガス成分のほぼ連続的な観測が可能となり、より排ガスの制御が容易となる大きな利益がある。
【図面の簡単な説明】
【図1】本発明の気体のサンプリング装置の説明図である。
【符号の説明】
1 送風管
2 ガスサンプラー
3 分析用サンプラー
4 ガスクロマトグラフィー
5 流量計
6 ピストン
7 シリンダー
8 ガス導入管
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a gas sampling device, and more particularly to a sampling device for exhaust gas requiring analysis.
[0002]
[Prior art]
The waste is incinerated in an incinerator, decomposed by heat and separated into incineration gas and residue. The incineration gas is subjected to chemical treatment, filter collection, etc. to render it harmless. Finally, the detoxified exhaust gas is released to the atmosphere through the flue. This is proposed, for example, in JP-A-2002-139409.
[0003]
The composition of the waste is not constant when it is put into the furnace, and it is difficult to make it constant. For this reason, it is necessary to inspect the components of the exhaust gas immediately before entering the flue, and to control the incineration or detoxification of the incinerated gas based on the fluctuation of the value.
[0004]
That is, in the processing, the gas processing apparatus must be controlled according to the change in the gas composition.
[0005]
[Problems to be solved by the invention]
A gas analyzer may be used to detect a change in gas composition.However, some gas analyzers require a certain amount of time to determine the analysis value depending on the element to be measured. During this time, the incineration gas flows out, so that a blank time occurs in which unanalyzed gas flows. To compensate for this, there is a demand for a measurement method or a simple device that can be measured in a short time or that does not cause a blank time.
[0006]
When analyzing elements that require a long time for analysis, the apparent blank time is shortened by using a plurality of analytical instruments, but the analytical instruments are often expensive and require frequent maintenance. New problems arise.
[0007]
[Means for Solving the Problems]
The gas sampling apparatus according to the present invention is characterized by comprising a gas storage chamber having a gas inlet connected to a pipe through which the gas flows, and a means for increasing or decreasing the volume of the chamber.
[0008]
The means for increasing or decreasing the volume of the chamber is means for moving along the inner wall of the chamber.
[0009]
The chamber is formed by a deformable bag, and the means for increasing or decreasing the volume of the chamber is a pump for introducing gas into the bag.
[0010]
The chamber is further provided with a gas outlet connected to the analysis means.
[0011]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
[0012]
In the present invention, as shown in FIG. 1, a specific gas flowing through a smoke guide or a gas blower tube 1 is sampled, for example, for 30 minutes, using a gas sampler, for example, a fluorocarbon gas per hour. The part is sent to the analysis sampler 3 and analyzed by, for example, gas chromatography 4 of FID (hydrogen flame ionization detector) method to measure the concentration of the specific gas and to include the specific gas in the gas blower tube 1 at the same time. The flow rate of the entire gas is continuously measured by a flow meter 5 such as a vortex flow meter, and the flow rate of the specific gas is obtained from the obtained concentration of the specific gas and the flow rate of the entire gas.
[0013]
As the gas sampler 2, for example, a gas sampler is extracted through a gas introduction pipe 8 by gradually expanding the volume of a chamber of a cylinder 7 by a piston 6. In this case, it is more preferable to control the amount of movement of the piston so that the temperature is corrected so that the sampling amount per time is constant.
[0014]
In such a gas sampler 2, when the chamber is gradually expanded by the movement of the piston 6, the sampled gas circulates in the chamber, causing a stirring effect, and a gas sample having a uniform composition is generated.
[0015]
As the gas sampler 2, a gas sampler having a deformable bag shape and a pump for introducing gas into the bag shape may be used.
[0016]
When the volume of the gas introduction pipe 8 is large and the amount of gas remaining in the gas introduction pipe 8 exceeds the chamber capacity, the inside of the chamber is filled with the gas in the gas introduction pipe and flows through the gas blower pipe 1. Since the gas cannot be sucked at any time, it is desirable to adjust the length and thickness of the gas introduction pipe 8 to minimize the volume.
[0017]
When the capacity of the gas introduction pipe exceeds the capacity of the chamber due to the structure and installation location of the gas blow pipe 1, a spare chamber may be provided in front of the chamber, or a bypass pipe or a suction device may be additionally provided between the gas introduction pipe and the gas blow pipe. Is provided, the amount of gas suction into the chamber can be controlled regardless of the capacity of the gas introduction tube.
[0018]
When the sampling amount reaches a predetermined amount, the gas valve is controlled, the piston 6 of the gas sampler 2 is quickly pushed back, and the gas is discharged. The gas is once stored in the analysis sampler 3 and analyzed.
[0019]
In addition, depending on the gas component, the inside of the pipe may be clogged with the deposit. In the case of such a gas component, a flushing device is arranged in the path so that the deposit can be removed by air as appropriate. I do. The flushing effect can be achieved at the same time by discharging (outflowing) the gas at a stretch by the gas sampler 2.
[0020]
The analysis time by the gas chromatography 4 is, for example, 30 minutes in the case of Freon, and the gas is immediately discharged to the gas blower pipe 1 after the analysis.
[0021]
【The invention's effect】
As described above, according to the gas sampling apparatus of the present invention, since the gas sampler is used, it is possible to observe the exhaust gas component almost continuously, and there is a great advantage that the control of the exhaust gas becomes easier.
[Brief description of the drawings]
FIG. 1 is an explanatory diagram of a gas sampling device of the present invention.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Blower tube 2 Gas sampler 3 Sampler for analysis 4 Gas chromatography 5 Flow meter 6 Piston 7 Cylinder 8 Gas inlet tube

Claims (4)

気体が流通する管に接続される気体導入口を有する気体を貯蔵するチャンバーと、このチャンバーの容積を増減する手段とを備えたことを特徴とする気体のサンプリング装置。A gas sampling device comprising: a gas storage chamber having a gas inlet connected to a pipe through which the gas flows; and a means for increasing or decreasing the volume of the chamber. 上記チャンバーの容積を増減する手段が上記チャンバー内壁に沿って移動する手段であることを特徴とする請求項1記載のサンプリング装置。2. The sampling apparatus according to claim 1, wherein the means for increasing or decreasing the volume of the chamber is means for moving along the inner wall of the chamber. 上記チャンバーが、変形する袋によって形成され、上記チャンバーの容積を増減する手段が、上記袋内にガスを導入するポンプであることを特徴とする請求項1記載の気体のサンプリング装置。2. The gas sampling apparatus according to claim 1, wherein the chamber is formed by a deformable bag, and the means for increasing or decreasing the volume of the chamber is a pump for introducing gas into the bag. 上記チャンバーが、更に、分析手段に接続される気体排出口を備えることを特徴とする請求項1または2記載の気体のサンプリング装置。3. The gas sampling apparatus according to claim 1, wherein the chamber further includes a gas outlet connected to the analysis unit.
JP2002272392A 2002-09-19 2002-09-19 Gas sampling analyzer Expired - Lifetime JP4116378B2 (en)

Priority Applications (1)

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JP4116378B2 JP4116378B2 (en) 2008-07-09

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009222613A (en) * 2008-03-18 2009-10-01 Shimadzu Corp Gas introduction device
CN104236963A (en) * 2013-06-18 2014-12-24 中国石油天然气股份有限公司 Probe for sampling particulate matters in telescopic pipeline and use method of probe

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103630428B (en) * 2013-12-04 2015-12-30 天津开发区合普工贸有限公司 A kind of removable gas on-site sample collection device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009222613A (en) * 2008-03-18 2009-10-01 Shimadzu Corp Gas introduction device
CN104236963A (en) * 2013-06-18 2014-12-24 中国石油天然气股份有限公司 Probe for sampling particulate matters in telescopic pipeline and use method of probe

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