JP2004099677A - Lost circulation preventing material and method for construction using the same lost circulation preventing material - Google Patents

Lost circulation preventing material and method for construction using the same lost circulation preventing material Download PDF

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Publication number
JP2004099677A
JP2004099677A JP2002260931A JP2002260931A JP2004099677A JP 2004099677 A JP2004099677 A JP 2004099677A JP 2002260931 A JP2002260931 A JP 2002260931A JP 2002260931 A JP2002260931 A JP 2002260931A JP 2004099677 A JP2004099677 A JP 2004099677A
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Japan
Prior art keywords
sludge
material according
lost circulation
preventing
synthetic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2002260931A
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Japanese (ja)
Inventor
Saburo Ishii
石井 三郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tachibana Material Co Ltd
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Tachibana Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tachibana Material Co Ltd filed Critical Tachibana Material Co Ltd
Priority to JP2002260931A priority Critical patent/JP2004099677A/en
Publication of JP2004099677A publication Critical patent/JP2004099677A/en
Pending legal-status Critical Current

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a lost circulation preventing material affording the lost circulation preventing material having excellent dispersibility at a low cost by using a mixture of a fiber material such as pulp fibers with a highly water absorbing synthetic resin material and further the lost circulation preventing material effectively preventing the leakage of a material subjected to lost circulation such as muddy water, cement milk or mortar and useful as a stabilizer, a mud additive/a super mud material or a lubricant when construction of various kinds of civil engineering works is carried out by using the mixture and to provide a method for construction using the lost circulation preventing material. <P>SOLUTION: The lost circulation preventing material preventing the leakage of a material subjected to the lost circulation such as the muddy water, cement milk or mortar is produced by mixing the fiber material such as pulp fibers with the highly water absorbing synthetic resin material. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
この発明は、土木工事等に用いられる逸泥防止材及びこの逸泥防止材を用いた土木工事等の施工法に関する。
【0002】
【従来の技術】
土木工事現場で使用する泥水やセメントミルク或はモルタルが、砂質土層などの土粒子間隙が大きい土中に漏出し逸する場合がある。これを防止するため、従来では、天然繊維、合成繊維、無機繊維等の繊維類の他に、クルミ粒、綿の実、ベントナイトの粒や塊等が使用されており、これらを被逸失材に適量混合することで、土中の比較的大きな間隙に目詰材として機能し、被逸失材が漏出しないように一般的に用いられている。
【0003】
【従来技術の課題】
しかしながら、従来逸泥材として用いられている繊維類は、比重が軽いものが多く、泥水やセメントミルク、モルタル等の被逸失材等に混合しても、これらの繊維類が被逸失材の上部に浮き上がり易く、分散させるのが非常に難しい、という問題を有していた。このため、従来では、浮き上がり防止の前処理として、予め繊維に水を吸収させて混合を良好にするようにしているが、工程が増えるため、作業時間がかかり、また、分散作業も非常に煩雑である、という課題を有していた。最近では、水の吸収が良好な圧縮されたパルプを用いたものもあるが、清水では吸水性が良好であっても、泥水やセメントミルク、モルタルに対する分散性は、従来品と同様に良好ではないことが本出願人の実験からも確認されている。
【0004】
【特許文献1】
特公平1−35032号公報
【0005】
この発明は、かかる現状に鑑み鋭意研究をした結果、例えば、紙おむつや生理用品の材料である繊維材と高分子ポリマー等の高吸水合成樹脂材との混合物を用いることで、分散性に優れた逸泥防止材を廉価に得ることができ、また、これを用いることで、泥水やセメントミルク、モルタル等の被逸失材の漏出を有効に防止することができ、各種土木工事の施工の際に用いられる安定液や加泥材・超泥材或は滑材として有用な逸泥防止材及びこの逸泥防止材を用いた施工法を提供しようとするものである。
【0006】
【課題を解決するための手段】
上記目的を達成するため、この発明にあっては、泥水やセメントミルク、モルタル等の被逸失材の漏出を防止する逸泥防止材を、繊維材に高吸水性合成樹脂材を混合して構成したことを特徴とするものである。
【0007】
この発明に用いられる前記繊維材としては、パルプ綿、故紙、廃パルプ等のパルプ繊維が好適であるが、綿花、石綿、綿くずを用いることもでき、これらを単独で、或はこれらを適宜の比率で混合して用いることができる。
【0008】
また、この発明に用いられる前記高吸水性合成樹脂材(デンプン−アクリロニトリル共重合体)としては、ポリビニルアルコール/ポリアクリル酸系若しくはポリアクリル酸ナトリウム系の高吸水性ポリマーを用いることができる。
【0009】
この高吸水性ポリマーは、周知のように、イオン性官能基を導入した高分子網目からなる乾燥ゲルで、水に触れるとこれらイオン性官能基が解離し、これが自重の数百倍から千倍にも達する膨潤度を生み出すことが知られている。当然、解離はゲルがおかれるpHや塩濃度などの条件に依存するため、ポリビニルアルコール/ポリアクリル酸系若しくはポリアクリル酸ナトリウム系の高吸水性ポリマーの他に、本逸泥防止材が添加される被逸失材のイオン雰囲気における条件に応じたその他の高吸水性ポリマーを適宜選択して用いることもできる。
【0010】
繊維材、特にパルプ繊維は、比重が軽く、液面に浮き易く、また、製品としての嵩も高いため、圧縮された製品が多い。そのため、パルプ繊維の間に高吸水性合成樹脂材を混入することで、高吸水性合成樹脂材が50〜500倍の吸水を早期に開始してパルプ繊維の間隙を押し広げるように膨潤して分散し、短時間で泥水やセメントミルク、モルタル等の被逸失材中に分散する。勿論、パルプ繊維材の他に、綿花、石綿、綿くずを用いても、同様である。
【0011】
また、前記逸泥防止材を廉価に得るために、この発明にあっては、前記パルプ繊維材と吸水性合成樹脂材を、紙おむつ或は生理用品の製造過程で発生した廃材を用いて形成するのが望ましい。
【0012】
この発明に係る逸泥防止材において、前記繊維材と高吸水性合成樹脂材の混合比は、繊維材100重量部に対して吸水性合成樹脂材を5重量部以上混合することで、繊維材の分散性を良好に保つためにも望ましい。5重量部以下では、繊維材の良好な分散性は得られない。
【0013】
このように構成されてなる逸泥防止材は、例えば、場所打ち杭、連続壁、リバース杭、BH杭用の安定液として用い、泥水シールド又は泥水推進工事用の安定液として、或は、泥土圧シールド或は泥土圧推進工事用の加泥材または超泥材として用い、また、モルタル杭、ソイル杭、アンカー用のセメントミルク或はモルタルとして用い、さらには、推進工事用の滑材として用いることができる。このように、この発明に係る逸泥防止材は、各種土木工事における泥水やセメントミルク、モルタル等の被逸失材の漏出を有効に防止することができる。
【0014】
【発明の効果】
この発明は、以上説明したように、繊維材と高分子ポリマー等の高吸水性合成樹脂材との混合物で逸泥防止材を構成したので、土木現場などで使用する泥水やセメントミルク、モルタル等の被逸失材に繊維材の浮き上がりを確実に防止して短時間で分散させることができるため、被逸失材の土中への漏出を確実に防止することができ、また、原材料として紙おむつや生理用品の製造過程で廃棄される廃材を用いることができるので、この種の逸泥防止材を廉価に得ることができる。また、この発明に係る逸泥防止材を、例えば、各種土木工事の施工の際に用いられる安定液や加泥材・超泥材或は滑材として用いることで、施工を早期に、かつ、短時間で行うことができ、施工コストを大幅に低減することができる等、幾多の優れた効果を奏する。
【0015】
【実施例1】
紙おむつ廃材であるパルプ繊維100重量部に、これも紙おむつ廃材に含有されているポリアクリル酸系の高吸水性ポリマー10重量部を混合して本発明に係る逸泥防止材を生成した。
そして、本発明に係る逸泥防止材を建築現場の場所打ち杭工事に使用した。当現場では礫層があり、当初より逸泥が十分に予想された。
本発明の逸泥防止材を、先ず、清水1000L(リットル)に対し5kg添加し、添加後15秒程で逸泥防止材は均一に分散した。その後、CMC、ベントナイトを添加し安定液を生成し使用した。
本発明に係る逸泥防止材が未使用では、泥水80m3の掘削に対し、7.3m3の逸泥があったが、本発明に係る逸泥防止剤を使用した時の逸泥は1.5m3と大きく減少し、非常に優れた逸泥効果が得られることが確認できた。
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a sludge preventing material used for civil engineering work and the like, and a construction method for civil engineering work and the like using the sludge preventing material.
[0002]
[Prior art]
Muddy water, cement milk, or mortar used at a civil engineering work site may leak into soil having a large gap between soil particles such as a sandy soil layer. In order to prevent this, conventionally, in addition to fibers such as natural fibers, synthetic fibers, and inorganic fibers, walnut grains, cotton nuts, bentonite grains and lumps, and the like have been used. By mixing an appropriate amount, it functions as a clogging material in a relatively large gap in the soil, and is generally used so that the lost material does not leak.
[0003]
[Prior Art Issues]
However, many fibers conventionally used as lost materials have a low specific gravity, and even when mixed with lost materials such as muddy water, cement milk, mortar, etc., these fibers remain above the lost materials. And it is very difficult to disperse. For this reason, in the past, as a pretreatment for preventing lifting, water was previously absorbed into the fibers to improve the mixing, but the number of steps increased, which required a long working time, and the dispersion work was also very complicated. Was a problem. Recently, there are also those using compressed pulp with good water absorption, but even if the fresh water has good water absorption, the dispersibility in muddy water, cement milk, mortar is not as good as the conventional product It has been confirmed from the applicant's experiment that there is none.
[0004]
[Patent Document 1]
JP-B 1-35032 [0005]
As a result of intensive studies in view of the current situation, the present invention has excellent dispersibility, for example, by using a mixture of a fiber material that is a material for disposable diapers and sanitary articles and a highly water-absorbing synthetic resin material such as a polymer polymer. It is possible to obtain anti-lodging material at low cost, and by using it, it is possible to effectively prevent leakage of lost material such as muddy water, cement milk, mortar, etc. An object of the present invention is to provide a sludge preventing material useful as a stabilizing liquid, a sludge material, a super sludge material or a lubricating material, and a construction method using the sludge preventing material.
[0006]
[Means for Solving the Problems]
In order to achieve the above object, according to the present invention, a sludge preventing material for preventing leakage of lost materials such as muddy water, cement milk, mortar, etc. is constituted by mixing a highly water-absorbing synthetic resin material with a fiber material. It is characterized by having done.
[0007]
As the fibrous material used in the present invention, pulp fibers such as pulp cotton, waste paper, and waste pulp are preferable, but cotton, asbestos, and cotton lint can also be used, and these can be used alone or appropriately. Can be used in mixture.
[0008]
Further, as the superabsorbent synthetic resin material (starch-acrylonitrile copolymer) used in the present invention, a polyvinyl alcohol / polyacrylic acid-based or sodium polyacrylate-based superabsorbent polymer can be used.
[0009]
As is well known, this superabsorbent polymer is a dry gel consisting of a polymer network into which ionic functional groups have been introduced, and when it comes into contact with water, these ionic functional groups dissociate, which is several hundred to 1,000 times their own weight. It is known to produce a degree of swelling that reaches even Naturally, the dissociation depends on conditions such as the pH and salt concentration at which the gel is placed. Therefore, in addition to the polyvinyl alcohol / polyacrylic acid-based or sodium polyacrylate-based superabsorbent polymer, the present sludge preventing material is added. Other superabsorbent polymers depending on the conditions of the lost material in the ionic atmosphere can be appropriately selected and used.
[0010]
Fibrous materials, especially pulp fibers, have a low specific gravity, easily float on the liquid surface, and have a high bulk as a product, so that there are many compressed products. Therefore, by mixing the highly water-absorbing synthetic resin material between the pulp fibers, the highly water-absorbing synthetic resin material starts to absorb water 50 to 500 times at an early stage and swells to expand the gap of the pulp fiber. Disperses and quickly disperses in lost material such as muddy water, cement milk, mortar, etc. Of course, the same applies to the use of cotton, asbestos, and cotton waste in addition to the pulp fiber material.
[0011]
Further, in order to obtain the sludge preventing material at a low cost, in the present invention, the pulp fiber material and the water-absorbing synthetic resin material are formed by using waste materials generated in a process of manufacturing a disposable diaper or a sanitary article. It is desirable.
[0012]
In the sludge preventing material according to the present invention, the mixing ratio of the fibrous material and the highly water-absorbing synthetic resin material is such that at least 5 parts by weight of the water-absorbing synthetic resin material is mixed with respect to 100 parts by weight of the fiber material. It is also desirable to keep the dispersibility of the satisfactorily. If the amount is less than 5 parts by weight, good dispersibility of the fiber material cannot be obtained.
[0013]
The sludge preventing material thus configured is used, for example, as a stabilizer for cast-in-place piles, continuous walls, reverse piles, and BH piles, as a stabilizer for muddy water shield or muddy water propulsion work, or as muddy soil. Used as a pressurized shield or a muddy material or a super muddy material for mud pressure propulsion work, used as mortar pile, soil pile, cement milk or mortar for anchor, and further used as a lubricating material for propulsion work be able to. As described above, the sludge prevention material according to the present invention can effectively prevent leakage of lost materials such as muddy water, cement milk, and mortar in various types of civil engineering work.
[0014]
【The invention's effect】
As described above, the present invention comprises a mixture of a fibrous material and a highly water-absorbing synthetic resin material such as a high-molecular polymer to constitute the anti-sludge material, so that muddy water, cement milk, mortar, etc. The fiber material can be reliably prevented from floating on the lost material, and can be dispersed in a short period of time, so that the lost material can be reliably prevented from leaking into the soil. Since waste materials discarded in the manufacturing process of the article can be used, this kind of sludge prevention material can be obtained at low cost. Further, by using the anti-lodging material according to the present invention as, for example, a stabilizing liquid or a muddy material / super-mud material or a sliding material used in the construction of various civil works, the construction can be performed early, and It can be performed in a short time, and has many excellent effects such as a great reduction in construction cost.
[0015]
Embodiment 1
100 parts by weight of pulp fiber, which is waste paper diaper, was mixed with 10 parts by weight of a polyacrylic acid-based superabsorbent polymer also contained in waste paper diaper to produce a sludge preventing material according to the present invention.
And the sludge prevention material according to the present invention was used for cast-in-place pile construction at a construction site. There was a gravel layer at this site, and lost mud was expected from the beginning.
First, 5 kg of the sludge preventing material of the present invention was added to 1000 L (liter) of fresh water, and about 15 seconds after the addition, the sludge preventing material was uniformly dispersed. Thereafter, CMC and bentonite were added to produce and use a stable liquid.
When the sludge preventing material according to the present invention was not used, there was 7.3 m3 of sludge against excavation of 80 m3 of muddy water, but 1.5 m3 when using the sludge preventing agent of the present invention. , And it was confirmed that a very excellent sludge effect was obtained.

Claims (10)

繊維材に高吸水性合成樹脂材を混合してなる逸泥防止材。An anti-sludge material made by mixing a highly water-absorbing synthetic resin material with a fiber material. 前記繊維材は、パルプ綿、綿花、故紙、廃パルプ、石綿、綿くずのいずれか、或はこれらの組み合わせで構成されることを特徴とする請求項1に記載の逸泥防止材。The sludge preventing material according to claim 1, wherein the fiber material is made of any one of pulp cotton, cotton, waste paper, waste pulp, asbestos, and cotton waste, or a combination thereof. 前記高吸水性合成樹脂材は、ポリビニルアルコール/ポリアクリル酸系若しくはポリアクリル酸ナトリウム系の高吸水性ポリマーであることを特徴とする請求項1に記載の逸泥防止材。The sludge preventive material according to claim 1, wherein the superabsorbent synthetic resin material is a polyvinyl alcohol / polyacrylic acid-based or sodium polyacrylate-based superabsorbent polymer. 前記繊維材と高吸水性合成樹脂材は、紙おむつ或は生理用品の製造過程で生じた廃材を用いることを特徴とする請求項1乃至請求項3のいずれかに記載の逸泥防止材。The sludge preventing material according to any one of claims 1 to 3, wherein the fibrous material and the highly water-absorbing synthetic resin material are waste materials produced in a process of manufacturing a disposable diaper or a sanitary article. 前記繊維材100重量部に対して高吸水性合成樹脂材を5重量部以上混合することを特徴とする請求項1乃至請求項4のいずれかに記載の逸泥防止材。The sludge preventing material according to any one of claims 1 to 4, wherein 5 parts by weight or more of a superabsorbent synthetic resin material is mixed with 100 parts by weight of the fiber material. 請求項1乃至請求項5のいずれかに記載の逸泥防止材を、場所打ち杭、連続壁、リバース杭、BH杭用の安定液として用いることを特徴とする逸泥防止材を用いた施工法。Construction using a sludge preventive material according to any one of claims 1 to 5, wherein the sludge preventive material according to any one of claims 1 to 5 is used as a stabilizing solution for cast-in-place piles, continuous walls, reverse piles, and BH piles. Law. 請求項1乃至請求項5のいずれかに記載の逸泥防止材を、泥水シールド又は泥水推進工事用の安定液として用いることを特徴とする逸泥防止材を用いた施工法。A construction method using a sludge preventive material, characterized in that the sludge preventive material according to any one of claims 1 to 5 is used as a mud shield or a stabilizing liquid for muddy water propulsion work. 請求項1乃至請求項5のいずれかに記載の逸泥防止材を、泥土圧シールド或は泥土圧推進工事用の加泥材または超泥材として用いることを特徴とする逸泥防止材を用いた施工法。A sludge preventing material according to any one of claims 1 to 5, wherein the sludge preventing material is used as a mud pressure shield or a mud material or a super mud material for mud pressure propulsion work. Construction method. 請求項1乃至請求項5のいずれかに記載の逸泥防止材を、モルタル杭、ソイル杭、アンカー用のセメントミルク或はモルタルとして用いることを特徴とする逸泥防止材を用いた施工法。A construction method using a sludge preventive material, wherein the sludge preventive material according to any one of claims 1 to 5 is used as a mortar pile, a soil pile, cement milk for an anchor or mortar. 請求項1乃至請求項5のいずれかに記載の逸泥防止材を、推進工事用の滑材として用いることを特徴とする逸泥防止材を用いた施工法。A construction method using a sludge preventive material, wherein the sludge preventive material according to any one of claims 1 to 5 is used as a slipper for propulsion work.
JP2002260931A 2002-09-06 2002-09-06 Lost circulation preventing material and method for construction using the same lost circulation preventing material Pending JP2004099677A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013024878A1 (en) 2011-08-17 2013-02-21 学校法人早稲田大学 Stable liquid composition of swollen superabsorbent polymer for ground excavation and construction method using same
US9200148B2 (en) 2010-12-15 2015-12-01 3M Innovative Properties Company Controlled degradation fibers
WO2019131952A1 (en) 2017-12-28 2019-07-04 三菱ケミカル株式会社 Sealing material for underground treatment, underground treatment method, and method for sealing well wall

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9200148B2 (en) 2010-12-15 2015-12-01 3M Innovative Properties Company Controlled degradation fibers
WO2013024878A1 (en) 2011-08-17 2013-02-21 学校法人早稲田大学 Stable liquid composition of swollen superabsorbent polymer for ground excavation and construction method using same
WO2019131952A1 (en) 2017-12-28 2019-07-04 三菱ケミカル株式会社 Sealing material for underground treatment, underground treatment method, and method for sealing well wall
US11230659B2 (en) 2017-12-28 2022-01-25 Mitsubishi Chemical Corporation Filling material for underground treatment, underground treatment method and filling well wall method

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