JP2004091355A - Simultaneously spraying type creamy hair dye composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a simultaneously spraying type creamy hair dye composition which gives an excellent sense of use when rinsed, has an excellent conditioning effect when finished, and can temporally stabilize the quantity of the spraying when sprayed. <P>SOLUTION: This simultaneously spraying type creamy hair dye composition which is an aerosol type creamy hair dye composition prepared by charging a creamy hair dye agent into a pressure-resistant container having an inner bag and further charging a compressed gas into a space between the inner bag and the pressure-resistant container and which has a pressing attachment having a mechanism for simultaneously press-spraying both the first creamy hair dye agent containing an alkali agent and a second creamy hair dye agent containing an oxidizer is characterized by formulating an amphoteric polymer into the first agent and/or the second agent. <P>COPYRIGHT: (C)2004,JPO

Description

【００２２】
【表２】

【００２３】
表１及び表２から明らかなように、本発明に係る同時噴出型染毛剤組成物は、すすぎ時の使用感や仕上がりのコンディショニング効果に優れ、且つ、噴出する時その噴出量が経時的に安定であることが認められた。
【００２４】
実施例３（脱色剤）
第１剤　　　　　　　　　　　　　　　　　　　　　　　　　質量％
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
塩化ジメチルジアリルアンモニウム・アクリル酸共重合体液
（商品名：マーコート２８０［オンデオ・ナルコ社製］）　　２．０
セタノール　　　　　　　　　　　　　　　　　　　　　　　４．０
セチル硫酸ナトリウム　　　　　　　　　　　　　　　　　　０．５
ポリオキシエチレンセチルエーテル（５．５Ｅ．Ｏ．）　　　０．３
ポリオキシエチレンセチルエーテル（３０Ｅ．Ｏ．）　　　　０．３
ポリオキシエチレンセチルエーテル（４０Ｅ．Ｏ．）　　　　０．３
強アンモニア水（２８％）　　　　　　　　　　　　　　　　７．０
プロピレングリコール　　　　　　　　　　　　　　　　　１０．０
エデト酸四ナトリウム　　　　　　　　　　　　　　　　　　０．１
パルミチン酸イソプロピル　　　　　　　　　　　　　　　　０．５
ミツロウ　　　　　　　　　　　　　　　　　　　　　　　　０．３
サボンソウエキス　＊３　　　　　　　　　　　　　　　　　０．１
セージエキス　＊３　　　　　　　　　　　　　　　　　　　０．１
海藻エキス　＊３　　　　　　　　　　　　　　　　　　　　０．１
混合植物抽出液（１）　＊１　　　　　　　　　　　　　　　０．１
混合植物抽出液（３）　＊１　　　　　　　　　　　　　　　０．１
混合植物抽出液（６）　＊１　　　　　　　　　　　　　　　０．１
香料　　　　　　　　　　　　　　　　　　　　　　　　　　０．５
純水　　　　　　　　　　　　　　　　　　　　　　　　　ｔｏ　１００
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
初期内圧（窒素ガス）　　　　　　　　　　　　　　　　　０．６ＭＰａ
初期噴出量　　　　　　　　　　　　　　　　　　　　１１．５ｇ／５秒
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
第２剤　　　　　　　　　　　　　　　　　　　　　　　　質量％
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
セタノール　　　　　　　　　　　　　　　　　　　　　　４．０
セチル硫酸ナトリウム　　　　　　　　　　　　　　　　　０．５
ポリオキシエチレンセチルエーテル（５．５Ｅ．Ｏ．）　　０．３
ポリオキシエチレンセチルエーテル（３０Ｅ．Ｏ．）　　　０．３
ポリオキシエチレンセチルエーテル（４０Ｅ．Ｏ．）　　　０．３
ヒドロキシエタンジホスホン酸　　　　　　　　　　　　　０．１
過酸化水素水（３５％）　　　　　　　　　　　　　　　１６．５
リン酸一水素ナトリウム　　　　　　　　　　　　　　　　０．２５
エデト酸二ナトリウム　　　　　　　　　　　　　　　　　０．１
パルミチン酸イソプロピル　　　　　　　　　　　　　　　０．５６
ミツロウ　　　　　　　　　　　　　　　　　　　　　　　０．３５
純水　　　　　　　　　　　　　　　　　　　　　　　　ｔｏ　１００
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
初期内圧（窒素ガス）　　　　　　　　　　　　　　　　０．６ＭＰａ
初期噴出量　　　　　　　　　　　　　　　　　　　１２．５ｇ／５秒
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
＊１　「医薬部外品原料規格」（厚生省薬務局審査課監修、薬事日報社平成３年発行）に収載されている。
＊３　「医薬部外品原料規格」（厚生省薬務局審査課監修、薬事日報社平成３年発行）に収載されている。
【００２５】
実施例４（染毛剤）
第１剤　　　　　　　　　　　　　　　　　　　　　　　　質量％
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
アクリルアミド・アクリル酸・塩化ジメチル
ジアリルアンモニウム共重合体液
（商品名：マーコート３３３０［オンデオ・ナルコ社製］）５．０
セタノール　　　　　　　　　　　　　　　　　　　　　　４．２
セチル硫酸ナトリウム　　　　　　　　　　　　　　　　　０．４９
ポリオキシエチレンセチルエーテル（５．５Ｅ．Ｏ．）　　０．３５
ポリオキシエチレンセチルエーテル（３０Ｅ．Ｏ．）　　　０．３５
ポリオキシエチレンセチルエーテル（４０Ｅ．Ｏ．）　　　０．３５
強アンモニア水（２８％）　　　　　　　　　　　　　　　５．０
パラフェニレンジアミン　　　　　　　　　　　　　　　　０．３
パラアミノフェノール　　　　　　　　　　　　　　　　　０．４
オルソアミノフェノール　　　　　　　　　　　　　　　　０．３
メタアミノフェノール　　　　　　　　　　　　　　　　　０．１
チオグリコール酸アンモニウム（５０％）液　　　　　　　０．８
プロピレングリコール　　　　　　　　　　　　　　　　１０．０
エデト酸四ナトリウム　　　　　　　　　　　　　　　　　０．１
パルミチン酸イソプロピル　　　　　　　　　　　　　　　０．５６
ミツロウ　　　　　　　　　　　　　　　　　　　　　　　０．３５
加水分解コムギ末　＊２　　　　　　　　　　　　　　　　０．０１
大豆蛋白加水分解物　＊３　　　　　　　　　　　　　　　０．０１
カロットエキス　＊３　　　　　　　　　　　　　　　　　０．０１
加水分解シルク　＊３　　　　　　　　　　　　　　　　　０．１
香料　　　　　　　　　　　　　　　　　　　　　　　　　０．５
純水　　　　　　　　　　　　　　　　　　　　　　　　ｔｏ　１００
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
初期内圧（窒素ガス）　　　　　　　　　　　　　　　　０．６ＭＰａ
初期噴出量　　　　　　　　　　　　　　　　　　　１１．５ｇ／５秒
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
第２剤　　　　　　　　　　　　　　　　　　　　　　　　質量％
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
セタノール　　　　　　　　　　　　　　　　　　　　　　４．２
セチル硫酸ナトリウム　　　　　　　　　　　　　　　　　０．４９
ポリオキシエチレンセチルエーテル（５．５Ｅ．Ｏ．）　　０．３５
ポリオキシエチレンセチルエーテル（３０Ｅ．Ｏ．）　　　０．３５
ポリオキシエチレンセチルエーテル（４０Ｅ．Ｏ．）　　　０．３５
ヒドロキシエタンジホスホン酸　　　　　　　　　　　　　０．１
過酸化水素水（３５％）　　　　　　　　　　　　　　　１６．５
リン酸一水素ナトリウム　　　　　　　　　　　　　　　　０．２５
エデト酸二ナトリウム　　　　　　　　　　　　　　　　　０．１
パルミチン酸イソプロピル　　　　　　　　　　　　　　　０．５６
ミツロウ　　　　　　　　　　　　　　　　　　　　　　　０．３５
純水　　　　　　　　　　　　　　　　　　　　　　　　ｔｏ　１００
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
初期内圧（窒素ガス）　　　　　　　　　　　　　　　　０．６ＭＰａ
初期噴出量　　　　　　　　　　　　　　　　　　　１２．５ｇ／５秒
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
＊２　「化粧品種別配合成分規格」（厚生省薬務局審査課監修、薬事日報社平成９年発行）に収載されている。
＊３　「医薬部外品原料規格」（厚生省薬務局審査課監修、薬事日報社平成３年発行）に収載されている。
【００２６】
実施例３，４に記載の配合組成でエアゾール型クリーム状脱色剤及び染毛剤を調製した。前記諸試験を実施したところ、すすぎ時の使用感や仕上がりのコンディショニング効果に優れ、且つ、噴出する時その噴出量が経時的に安定であることが認められた。
【００２７】上記の処方中の香料組成は下記のものである。
【表３】

【００２８】
【発明の効果】
以上の説明から明らかなように本発明のエアゾール型クリーム状染毛剤は、すすぎ時の使用感や仕上がりのコンディショニング効果に優れ、且つ、噴出する時その噴出量が経時で安定である同時噴出型クリーム状染毛剤組成物を提供できる。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a co-spout type creamy hair dye composition, and more particularly, is characterized by being excellent in a feeling of use at the time of rinsing and a conditioning effect of a finish, and having a stable spouting amount over time when spouting. And a co-spouting creamy hair dye composition. In the present invention, the hair dye also includes a decolorizing agent.
[0002]
[Prior art]
An aerosol cream hair dye of the simultaneous ejection type has also been proposed in Japanese Patent Application Laid-Open No. 12-297018. This aerosol-type creamy hair dye does not cause any particular problem when the first agent as the hair dye and the second agent as the oxidizing agent are used separately, but the first and second agents are simultaneously used. In the case of spraying, it is necessary to adjust the blowing amount. Furthermore, in view of the consumer's use, the amount of the squirt needs to be stable over time. However, when the creamy hair dye is simply filled into a pressure-resistant container having an inner bag, and further, a compressed gas is filled between the inner bag and the pressure-resistant container, the amount of squirted over time is evaluated. Often changed, and it was found that it was difficult to prepare an undiluted solution having a stable ejection amount over time. In addition, when various conditioning agents were blended in order to improve the usability, it was found that the conditioning effect was not exhibited and the stability of the ejection amount over time could not be maintained.
[0003]
[Problems to be solved by the invention]
Under such circumstances, an object of the present invention relates to a co-spout type creamy hair dye composition, and more specifically, has an excellent feeling in use during rinsing and a conditioning effect of the finish, and the amount of spout when squirting is time-dependent. Another object of the present invention is to provide a co-spouting creamy hair dye composition characterized by being stable to water.
[0004]
[Means for Solving the Problems]
The present inventor has conducted intensive studies to solve the above-mentioned problems, and as a result, the simultaneous ejection type creamy hair dye composition described later is excellent in the use feeling at the time of rinsing and the conditioning effect of the finish, and The present inventors have found that the amount of squirt is stable with time and completed the present invention.
[0005]
That is, the present invention provides an aerosol-type cream-like hair dye composition in which a cream-like hair dye is filled in a pressure-resistant container having an inner bag, and further, a compressed gas is filled between the inner bag and the pressure-resistant container. Simultaneous ejection type hair dyeing having a press attachment of a mechanism for simultaneously ejecting both the first and second creamy hair dyes containing an alkali agent and the second creamy hair dye containing an oxidizing agent by pressing. A simultaneous ejection type creamy hair dye composition characterized by comprising an amphoteric polymer in the first and / or second agent composition.
[0006]
Further, the amphoteric polymer is a copolymer of dimethyldiallylammonium chloride and acrylic acid, or a copolymer of dimethyldiallylammonium chloride and acrylic acid and acrylamide, or methacrylamidopropyltrimethylammonium chloride, acrylic acid and methyl acrylate And a co-spout type hair dye composition which is a copolymer comprising
[0007]
Further, there is provided a simultaneous jet type creamy hair dye composition characterized by containing 0.3 to 3% by mass of an amphoteric polymer as a pure component.
[0008]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the present invention will be described in detail.
[0009]
Specific examples of the amphoteric polymer in the present invention include, for example, a monoalkyl acetic acid amphoteric product of a dialkylaminoethyl methacrylate / alkyl methacrylate copolymer (trade name: Yuka Former 301, AM-75, SM [manufactured by Mitsubishi Chemical Corporation]). , Hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer (trade name: Amphomer 28-4910, LV-71 [manufactured by National Starch]), dimethyldiallylammonium chloride / acrylic acid copolymer Dimethyldiallylammonium chloride / acrylic acid / acrylamide copolymer, methacrylamidopropyltrimethylammonium chloride / acrylic acid / methyl acrylate copolymer (trade name: Mercoat 280, 295, 3330, 3331, 2) 01 [manufactured by Ondeo Narco] and the like, and dimethyldiallylammonium chloride / acrylic acid copolymer, dimethyldiallylammonium chloride / acrylic acid / acrylamide copolymer, methacrylamidopropyltrimethylammonium chloride / acrylic acid / acrylic acid An acid methyl copolymer is preferable, and a dimethyldiallylammonium chloride / acrylic acid copolymer is particularly preferable. Among them, a dimethyldiallylammonium chloride and acrylic acid having a mass ratio of 95: 5 to 80:20 are preferable.
[0010]
When these amphoteric polymers are less than 0.3% by mass as a pure component, they may not exhibit a feeling of use at the time of rinsing or a conditioning effect, and if the amount exceeds 3% by mass, the expected effect is not further increased. Since the ejection amount may become unstable with time, it is preferably 0.3 to 3% by mass.
[0011]
The co-spout type creamy hair dye composition of the present invention includes oxidation dyes, alkali agents, oxidizing agents, hydrocarbons, waxes, animal and vegetable oils, natural or synthetic oils, as long as the effects of the present invention are not impaired. Molecules, higher alcohols, higher fatty acids, organic solvents or penetration enhancers, polyhydric alcohols, esters, ethers, cationic surfactants, amphoteric surfactants, anionic surfactants, silicones, cationic Polymers, anionic polymers, protein derivatives and amino acids, preservatives, chelating agents, stabilizers, antioxidants, pH adjusters, various plant extracts, crude drug extracts, vitamins, pigments, flavors, ultraviolet absorbers, etc. Can be appropriately blended.
[0012]
In addition, the simultaneous ejection type creamy hair dye composition of the present invention can be used as a decolorizing agent when an oxidation dye is not blended.
[0013]
As the pressure-resistant container used in the present invention, an inner surface of a container made of a material generally used for aerosol containers such as tinplate and aluminum is coated with an epoxy resin, a phenol resin, an epoxy urea resin, a polyamide imide resin, an epoxy amino resin, and an epoxy resin. Those coated with a single layer or multiple layers with a resin having chemical resistance such as an amine resin are preferable. As the inner bag, those having elasticity are preferred, and high-density or low-density polyethylene, saponified ethylene / vinyl acetate copolymer, polyethylene terephthalate, polypropylene, polyacrylonitrile, and other synthetic resin products, and products obtained by laminating these products And those having low jet gas permeability are particularly preferred. Further, the inner surface of the inner bag can be used after being coated with the above-mentioned resin having chemical resistance.
[0014]
Attachments that can be simultaneously pressed include those described in JP-A-11-59746, JP-A-10-101157, and JP-A-2000-297018, and those shown in FIGS. There is no particular limitation as long as two or more aerosol container stems can be simultaneously pressed by one pressing operation.
[0015]
As the compressed gas used in the present invention, dimethyl ether, liquefied petroleum gas, nitrogen gas, alternative chlorofluorocarbon and the like can be used without particular limitation as long as they are generally used for aerosol products. Nitrogen gas is preferable from the viewpoint of preventing deterioration.
[0016]
【Example】
Hereinafter, the present invention will be described specifically with reference to Examples, but the present invention is not limited thereto. Prior to the examples, the evaluation method used in the examples will be described.
[0017]
1. Changes in the amount of spouting over time after filling Example and comparative examples were filled with a stock solution prepared inside the inner bag of a pressure container having a high-density polyethylene inner bag. The space was filled with nitrogen gas. The packing was stored in a thermostat at 45 ° C. for 3 months, and the initial ejection amount was measured. The evaluation criteria are as follows.
：: Change in initial ejection amount is less than 10% compared to the initial ejection amount immediately after filling. ×: Change in initial ejection amount is 10% or more compared to the initial ejection amount immediately after filling.
2. Evaluation method of use feeling at the time of rinsing and unity at the time of finish Example, a stock solution prepared according to the formulation described in Comparative Example was filled inside the inner bag of a pressure-resistant container having an inner bag made of high-density polyethylene, and further, the inner bag And the pressure vessel were filled with nitrogen gas. In addition, model formulations of the first and second agents shown below were similarly prepared. The hair of the panel (10 persons) is divided into left and right halves, attached to an attachment that can be sprayed and used at the same time in combination with the model prescription of the first agent and the second agent, applied to one side as a control, and applied to the other side The ones described in the examples and comparative examples and the model formulations of the first and second agents were combined, attached to an attachment that could be simultaneously ejected and used, and applied to the other. For the feeling of use at the time of rinsing and the unity at the time of finishing, a paired evaluation was performed on a scale of 5 out of 5 when the control was 3 points.
：: 4 points or more and 5 points or less Δ: 2 points or more and less than 4 points x: less than 2 points
1st agent model prescription mass%
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Cetanol 4.0
Isopropyl isostearate 0.55
Salami beeswax 0.35
Sodium cetyl sulfate 0.5
Polyoxyethylene cetyl ether (5.5 EO) 0.35
Polyoxyethylene cetyl ether (30 EO) 0.7
Strong ammonia water 5.0
Paraphenylenediamine 0.4
Para-aminophenol 0.3
Metaaminophenol 0.1
Ammonium thioglycolate solution 0.4
Propylene glycol 10.0
Tetrasodium edetate 0.1
Yellow 202 (1) 0.01
Fragrance 0.4
Pure water to 100
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Initial internal pressure (nitrogen gas) 0.5MPa
Initial ejection amount 9.5g / 5sec --------------------------------------------------------------------------
2nd agent model formula mass%
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Cetanol 4.0
Sodium cetyl sulfate 0.5
Isopropyl palmitate 0.5
Beeswax 0.35
Polyoxyethylene cetyl ether (5.5 EO) 0.35
Polyoxyethylene cetyl ether (30EO) 0.35
Polyoxyethylene cetyl ether (40EO) 0.35
Hydroxyethanediphosphonic acid 0.1
Hydrogen peroxide solution (35%) 16.5
Sodium monohydrogen phosphate 0.25
Disodium edetate 0.1
Pure water to 100
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Initial internal pressure (nitrogen gas) 0.55MPa
Initial squirt amount 10.5g / 5s --------------------------------------------------------------------------
[0020]
The stock solutions and the aerosol-type creamy hair dyes of Examples 1 and 2 and Comparative Examples 1 to 6 were prepared, and the above-described tests were performed. Tables 1 and 2 show the respective compositions and test results. All units of the stock solution in the table are mass%.
[0021]
[Table 1]

[0022]
[Table 2]

[0023]
As is clear from Tables 1 and 2, the co-spout type hair dye composition according to the present invention is excellent in the use feeling and the conditioning effect of the finish at the time of rinsing, and the spouting amount when spouting out with time. It was found to be stable.
[0024]
Example 3 (bleaching agent)
1st agent mass%
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Dimethyldiallylammonium chloride / acrylic acid copolymer solution (trade name: Marcoat 280 [manufactured by Ondeo Narco]) 2.0
Cetanol 4.0
Sodium cetyl sulfate 0.5
Polyoxyethylene cetyl ether (5.5 EO) 0.3
Polyoxyethylene cetyl ether (30EO) 0.3
Polyoxyethylene cetyl ether (40EO) 0.3
Strong ammonia water (28%) 7.0
Propylene glycol 10.0
Tetrasodium edetate 0.1
Isopropyl palmitate 0.5
Beeswax 0.3
Soapwort extract * 3 0.1
Sage extract * 3 0.1
Seaweed extract * 3 0.1
Mixed plant extract (1) * 1 0.1
Mixed plant extract (3) * 1 0.1
Mixed plant extract (6) * 1 0.1
Fragrance 0.5
Pure water to 100
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Initial internal pressure (nitrogen gas) 0.6MPa
Initial eruption amount 11.5g / 5 seconds -----------------------------------------------------------
2nd agent mass%
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Cetanol 4.0
Sodium cetyl sulfate 0.5
Polyoxyethylene cetyl ether (5.5 EO) 0.3
Polyoxyethylene cetyl ether (30EO) 0.3
Polyoxyethylene cetyl ether (40EO) 0.3
Hydroxyethanediphosphonic acid 0.1
Hydrogen peroxide solution (35%) 16.5
Sodium monohydrogen phosphate 0.25
Disodium edetate 0.1
Isopropyl palmitate 0.56
Beeswax 0.35
Pure water to 100
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Initial internal pressure (nitrogen gas) 0.6MPa
Initial eruption amount 12.5 g / 5 sec ------------------------------------------------------------------------------------
* 1 It is listed in “Quasi-drug raw material standards” (Supervised by the Examination Division of the Pharmaceutical Affairs Bureau, Ministry of Health and Welfare, published by Yakuji Nipposha 1991).
* 3 Listed in “Quasi-drug raw material standards” (supervised by the Examination Division of the Pharmaceutical Affairs Bureau, Ministry of Health and Welfare, published by Yakuji Nippo 1991).
[0025]
Example 4 (hair dye)
1st agent mass%
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer solution (trade name: Marcoat 3330 [manufactured by Ondeo Narco]) 5.0
Cetanol 4.2
Sodium cetyl sulfate 0.49
Polyoxyethylene cetyl ether (5.5 EO) 0.35
Polyoxyethylene cetyl ether (30EO) 0.35
Polyoxyethylene cetyl ether (40EO) 0.35
Strong ammonia water (28%) 5.0
Paraphenylenediamine 0.3
Para-aminophenol 0.4
Orthoaminophenol 0.3
Metaaminophenol 0.1
Ammonium thioglycolate (50%) solution 0.8
Propylene glycol 10.0
Tetrasodium edetate 0.1
Isopropyl palmitate 0.56
Beeswax 0.35
Hydrolyzed wheat powder * 2 0.01
Soybean protein hydrolyzate * 3 0.01
Carrot extract * 3 0.01
Hydrolyzed silk * 3 0.1
Fragrance 0.5
Pure water to 100
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Initial internal pressure (nitrogen gas) 0.6MPa
Initial eruption amount 11.5g / 5 seconds -----------------------------------------------------------
2nd agent mass%
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Cetanol 4.2
Sodium cetyl sulfate 0.49
Polyoxyethylene cetyl ether (5.5 EO) 0.35
Polyoxyethylene cetyl ether (30EO) 0.35
Polyoxyethylene cetyl ether (40EO) 0.35
Hydroxyethanediphosphonic acid 0.1
Hydrogen peroxide solution (35%) 16.5
Sodium monohydrogen phosphate 0.25
Disodium edetate 0.1
Isopropyl palmitate 0.56
Beeswax 0.35
Pure water to 100
−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−
Initial internal pressure (nitrogen gas) 0.6MPa
Initial eruption amount 12.5 g / 5 sec ------------------------------------------------------------------------------------
* 2 It is listed in the “Composition type specifications for cosmetic varieties” (supervised by the Examination Division of the Pharmaceutical Affairs Bureau, Ministry of Health and Welfare, published by Yakuji Nippo, 1997).
* 3 Listed in “Quasi-drug raw material standards” (supervised by the Examination Division of the Pharmaceutical Affairs Bureau, Ministry of Health and Welfare, published by Yakuji Nippo 1991).
[0026]
An aerosol-type cream bleaching agent and a hair dye were prepared according to the composition described in Examples 3 and 4. When the above-mentioned tests were carried out, it was confirmed that the use feeling during rinsing and the conditioning effect of the finish were excellent, and that the amount of squirting when jetting was stable over time.
The perfume composition in the above formulation is as follows.
[Table 3]

[0028]
【The invention's effect】
As is clear from the above description, the aerosol-type creamy hair dye of the present invention is excellent in the usability at the time of rinsing and the conditioning effect of the finish, and when jetted, the spouting amount is stable over time. A creamy hair dye composition can be provided.

Claims (4)

An aerosol-type cream-like hair dye composition in which a creamy hair dye is filled inside a pressure-resistant container having an inner bag, and a compressed gas is further filled between the inner bag and the pressure-resistant container. A simultaneous ejection type hair dye composition having a press attachment of a mechanism for simultaneously ejecting by pressing both a creamy hair dye first agent and a creamy hair dye second agent containing an oxidizing agent. A simultaneous jet cream hair dye composition comprising a first agent and / or a second agent mixed with an amphoteric polymer. Amphoteric polymer is a copolymer consisting of dimethyldiallylammonium chloride and acrylic acid, or a copolymer consisting of dimethyldiallylammonium chloride and acrylic acid and acrylamide, or from methacrylamidopropyltrimethylammonium chloride and acrylic acid and methyl acrylate The co-spout type hair dye composition according to claim 1, which is a copolymer comprising: The simultaneous jetting cream hair dye composition according to claim 1 or 2, wherein the amphoteric polymer is incorporated as a pure component in an amount of 0.3 to 3% by mass. The amphoteric polymer is a copolymer comprising dimethyldiallylammonium chloride and acrylic acid in a mass ratio of 95: 5 to 80:20, and the copolymer is added as a pure component in an amount of 0.3 to 3% by mass. The simultaneous jet type creamy hair dye composition according to claim 1, characterized in that: