JP2004083731A - Perfume composition for liquid bathing agent - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a perfume composition for a bathing agent capable of maintaining a constant perfume intensity and quality of perfume for a long time after insertion to warm water in a bath. <P>SOLUTION: This perfume composition for the liquid bathing agent has 2.7-6.0 ClogP and ≥220°C boiling point, and contains ≥50 wt.% one or more perfume compounds selected from alcohols, ethers, aldehydes, ketones, esters, synthetic musks and nitrogen-containing compounds not included in the above compounds. <P>COPYRIGHT: (C)2004,JPO

Description

【００２８】
【表２】

【００２９】
【表３】

【００３０】
【表４】

【００３１】
【表５】

【００３２】
【表６】

【００３３】
【表７】

【００３４】
各表中の成分名の表記は、「合成香料」化学と商品知識、印藤元一著、化学工業日報社、１９９６年３月６日発行、に基づく。
但し、＊印は高砂香料工業株式会社の商品名
Ｍｐは融点である；これらの成分は２５０℃以上のｂ．ｐ．を有している。
【００３５】
本発明の上記表１〜７に記載した、「ＣｌｏｇＰが２．７以上６．０未満、かつ、沸点が２２０℃以上」には該当しない香料化合物としては、例えば、表８の香料化合物を例示することができる。
【００３６】
【表８】

【００３７】
本発明においては、本発明で用いられる香料成分を主成分とする天然精油も使用することができ、これら香料成分を５０質量％以上含有する精油が好ましい。例えば、アニス油、スターアニス油、フェンネル油、樟脳油、シトロネラ油、クミン油、ローズ油、パルマローズ油、ゲラニウム油等が挙げられる。
これらの香料成分は、１種又は２種以上用いることができ、液体入浴剤用香料組成物中に５０質量％以上、特に６０質量％以上配合するのが、より香りが長時間一定の香質を維持する効果は得られるので好ましい。
【００３８】
本発明の液体入浴剤用香料組成物に、上記香料成分の他に使用することができる香料としては、特に制限はなく、合成香料及び天然香料いずれも用いることができる。例えば、「Ａｒｃｔａｎｄｅｒ　　Ｓ．，“Ｐｅｒｆｕｍｅ　　ａｎｄ　　Ｆｌａｖｏｒ　　Ｃｈｅｍｉｃａｌｓ”，ｐｕｂｌｉｓｈｅｄ　　ｂｙ　　ｔｈｅ　　ａｕｔｈｏｒ，Ｍｏｎｔｃｌａｉｒ，Ｎ．Ｊ．（Ｕ．Ｓ．Ａ．）１９６９年」に記載されているような広い範囲の香料成分を使用することができる。
【００３９】
代表的な天然香料としては、例えば、アニシード、イランイラン、エレミ、オリス、オレンジ、ガルバナム、クラリーセージ、クローブ、コリアンダー、サンダルウッド、シトロネラ、シナモン、ジャスミン、スペアーミント、セダーウッド、ゼラニウム、セロリ、タンジェリン、トンカビーンズ、ネロリ、バイオレット、パチョリ、ピーチ、ベチバー、ペチグレン、ペパーミント、ペルーバルサム、ベルガモット、ユーカリ、ライラック、ラズベリー、ラベンダー、リリーオブザバレー、レモン、レモングラス、ライム、ローズなどの天然精油；アンバー、カストリウム、シベット、ムスクなどの動物性チンキ等が挙げられる。
【００４０】
代表的な合成香料としては、例えば、ピネン、リモネン、カリオフィレン、ロンギホレン、ミルセンなどの炭化水素類；シス−３−ヘキセノール、ｐ−ｔ−ブチロシクロヘキサノール、リナロール、ジヒドロリナロール、テトラヒドロリナロール、テトラヒドロミルセノール、メントール、イソボルネオール、イソカンフィルシクロヘキサノール、ファルネソール、ベンジルアルコール、α−フェニルエチルアルコール、β−フェニルエチルアルコール、フェノキシエチルアルコール、シンナミックアルコール、アミルシンナミックアルコール、チモール、オイゲノールなどのアルコール類；シネオール、エストラゴール、β−ナフチルメチルエーテル、ジフェニルオキサイド、セドリルメチルエーテル、イソアミルフェニルエチルエーテル、アンブロキサン（Ｈｅｎｋｅｌ社）、グリサイバ（ＩＦＦ社）、ジヒドロローズオキサイド、リモネンオキサイド、メントフラン、アンバーコア（花王株式会社）などのエーテル類；シトロネラール、シトラール、ヒドロキシシトロネラール、ジメチルテトラヒドロベンズアルデヒド、マイラックアルデヒド（ＩＦＦ社）、コバノール（高砂香料工業株式会社）、ベルンアルデヒド（Ｇｉｖａｕｄａｎ社）、ベンズアルデヒド、スザラール（高砂香料工業株式会社）、シンナミックアルデヒド、メチルシンナミックアルデヒド、バニリン、エチルバニリン、ヘリオトロピン、ヘリオブーケ（高砂香料工業株式会社）などのアルデヒド類；ジヒドロジャスミン、ヘディオン（Ｆｉｒｍｅｎｉｃｈ社）、シクロテン、カシュメラン（ＩＦＦ社）、カルボン、メントン、イソロンギホラノン、ラズベリーケトン、アセトフェノン、などのケトン類；クマリン、ギ酸リナリル、ギ酸シトロネリル、リナリルアセテート、シトロネリルアセテート、ゲラニルアセテート、テロペニルアセテート、セドリルアセテート、２−ｔ−ブチルシクロヘキシルアセテート（ベルドックス；ＩＦＦ社）、ベンジルアセテート、フェニルアリルアセテート、スチラリルアセテート、イソアミルアセテート、ローズフェノン、ジャスマール（ＩＦＦ社）、ベンジルベンゾエート、ベンジルサリチレート、ヘキシルサリチレート、メチルアトラレート、メチルアンスラニレート、エチルアンスラニレート、フルテート（花王株式会社）などのエステル類；ムスコン、ムスコール、シベトン、シクロペンタデカノン、シクロヘキサデカノン、シクロペンタデカノリド、エチレンドデカンジオエート、セレストリド（ＩＦＦ社）、トラセオライド（Ｑｕｅｓｔ　Ｉｎｔｅｒｎａｔｉｏｎａｌ社）などのムスク類等がそれぞれ挙げられる。
【００４１】
これらの香料は単独で用いてもよいし、２種以上を調合して調合香料として用いてもよい。
また、通常使用される香料保留剤の１種又は２種以上を配合しても良く、例えば、プロピレングリコール、グリセリン、ヘキシレングリコール、ジプロピレングリコール、ベンジルベンゾエート、トリエチルシトレート、ジエチルフタレート、ハーコリン（アビエチン酸メチル）等と併用することも可能である。
【００４２】
さらに、生薬成分を１種又は２種以上を配合して利用することができる。生薬成分を配合することにより、生薬成分の香りのマスキングのほか、液体入浴剤用香料組成物の有する効能効果と生薬成分が有する効能効果の相乗効果が期待できる、用いることができる生薬成分としては、一般に入浴剤に使用される生薬成分を適宜に添加することができる［周知・慣用技術集（香料）第三部　香粧品用香料　４・３・３　入浴剤　平成１３年６月１５日発行］。
【００４３】
本発明の液体入浴剤用香料組成物は、（１）製品状態では油性であって浴湯に投入すると油性成分が浴湯に白濁分散するタイプの液体入浴剤組成物、（２）低級アルコールや多価アルコールを主成分とした透明タイプの液体入浴剤で浴湯に投入時も透明に溶解するタイプの液体入浴剤組成物、（３）製品そのものが乳液状で、浴湯に投入した時も白濁するタイプの液体入浴剤組成物のいずれにも用いることができる。
【００４４】
本発明の液体入浴剤用香料組成物は、表１〜７の成分の１種又は２種以上に加えて、従来より液体入浴剤用香料組成物に配合されている種々の香料成分を、必要とする香調などに応じて適宜選択して使用することができる。
本発明の液体入浴剤用香料組成物の各種液体入浴剤への配合量は、特に制限されず、また香料や香粧品組成物の種類によって異なる。従って、この配合量は、これらの種類や組み合わせを特定して調製を行うことによって、容易に決定することができる。本発明の液体入浴剤用香料組成物は、入浴湯に良好な嗜好性、持続性と適度な香り強度を付与するため、液体入浴剤に賦香するもので、液体入浴剤中に、０．１〜１０質量％、好ましくは、０．５〜５質量％、より好ましくは１〜３質量％となるように配合する。
【００４５】
本発明の液体入浴剤には、油性成分、多価アルコール、炭素数２〜３の低級アルコール、界面活性剤を、その液体入浴剤のタイプに応じて、適宜配合することができる。
本発明の液体入浴剤に用いられる油性成分としては、スクワラン、流動パラフィン、イソステアリン酸、ホホバ油等の入浴剤一般に使用される油性成分を使用することができる。
【００４６】
本発明の液体入浴剤に用いられる多価アルコールとしては、グリセリン、ジプロピレングリコール、ヘキシレングリコール、プロピレングリコール、１，３−ブチレングリコール等が挙げられる。
本発明の液体入浴剤に用いられる炭素数２〜３の低級アルコールとしては、エチルアルコール、イソプロピルアルコール等が挙げられる。
【００４７】
本発明の液体入浴剤に用いられる界面活性剤としては、一般的に入浴剤に使用できる界面活性剤であれば特に限定されるものではない。また、液体入浴剤のタイプにより、油性成分を乳化又は可溶化するために用いられる界面活性剤を適宜に使用すればよい。
【００４８】
本発明の液体入浴剤組成物には、必要に応じて他の任意原料成分を配合することができ、例えば、その浴剤の目的とする効能、効果に応じてビタミン類、生薬類、色素類などから選ばれる一種又は二種以上の原料を適宜選択して配合することができる。
【００４９】
ビタミン類としては、レチノール、チアミン、リボフラビン、ピリドキシン、シアノコバラミン、アスコルビン酸、コレカルシフェロール、トコフェロール、カルニチン、フェルラ酸、オロット酸、γ−オキザノールなどが挙げられる。
生薬類としては、センキュウ、トウヒ、ケイガイ、ショウキョウ、オウガン、オウレン、サンシン、ガイヨウ、アロエ、ケイヒ、シャクヤク、カンゾウ、チンピ、カミツレ、マロニエ、ショウブなどが挙げられる。
【００５０】
色素類としては、赤色１０４号の（１）、赤色１０５号の（１）、赤色１０６号、青色１号、青色２号、赤色２１３号、赤色２１４号、赤色２３０号の（１）、赤色２３１号、赤色２３２号、だいだい色２０５号、黄色２０２号の（１）、青色２０２号、青色２０３号などが挙げられる。
【００５１】
本発明の液体入浴剤の製造方法としては、特に限定されないが、一般に液体入浴剤を製造する方法を用いることができる［周知・慣用技術集（化粧料及び類似品）Ｖ　浴用剤　昭和５９年８月２１日発行］。
なお、液体入浴剤としては、（１）製品状態では油性であって浴湯に投入すると油性成分が浴湯に白濁分散するタイプの液体入浴剤組成物、（２）低級アルコールや多価アルコールを主成分とした透明タイプの液体入浴剤で浴湯に投入時も透明に溶解するタイプの液体入浴剤組成物、（３）製品そのものが乳液状で、浴湯に投入した時も白濁するタイプの液体入浴剤組成物のいずれにも用いることができ、製品状態で液体の入浴剤であれば特に制限することなく使用することができる。
【００５２】
【実施例】
以下に実施例を挙げて本発明を具体的に説明するが、本発明はこれらによって限定されものではない。
【００５３】
実施例１及び比較例１
実施例１及び比較例１として表９に示す配合の液体入浴剤香料組成物を調製した。
【００５４】
【表９】

【００５５】
表９中、１〜２０の香料成分は表１〜７記載の成分で、かつ本発明の液体入浴剤用香料組成物の香りの特徴であるフローラルフルーティーの骨格を形成する成分であり、表９中、２１〜３０の香料成分はフルーティーフローラルのニオイを修飾し、香りの嗜好性等を上げるための成分である。
実施例１及び比較例１の両組成物から２１〜３０の香料成分を除いてしまうと液体入浴剤用香料としての価値が著しく低下してしまうことが判明しており、このことから、表９中の２１〜３０の香料成分（前記表８記載の成分）と、表９中の１〜２０の成分（前記表１〜７に記載の成分）とは、本発明の液体入浴剤用香料組成物における必須成分であることが確認された。
【００５６】
また、前記組合せからなる香料組成物においては、液体浴剤用香料組成物中における表１〜７の香料成分の合計量と表８の香料成分の合計量の関係が特定の量比であることが、入浴剤を浴湯に投入してから長時間一定の香り強度と香質を維持することに関与することも判明した。
このことを明かにするために、実施例１では、ジャスミン用香気成分として、本発明の条件を満足する前記表５の香料成分であるジヒドロジャスモン酸メチル１００ｍｇと、前記表８記載の香料成分である酢酸ベンジル８０ｍｇとを使用し、一方、比較例１の香料組成物においては、前記表８記載の香料成分である酢酸ベンジル１８０ｍｇを使用した。
また、ローズ用香気成分として、実施例１では前記表１記載の香料成分であるゲラニオール６０ｍｇと、前記表１記載のシトロネロール４０ｍｇと、前記表８記載のβ−フェニルエチルアルコール１４０ｍｇを使用し、他方、比較例１では前記表８記載の香料成分であるβ−フェニルエチルアルコール２９０ｍｇを使用した。
さらに、全体の香調を維持するために、実施例１の組成物においては、前記表５記載の成分である酢酸ｐ−ｔｅｒｔ−ブチルシクロヘキシル１２０ｍｇを使用し、比較例１の組成物においては同成分を７０ｍｇ使用して、両組成物における各成分の合計量を１０００ｍｇに調整した。
実施例１と比較例１の両組成物における前記表１〜７に記載されている香料成分の合計量と前記表８記載の香料成分の合計量の比率は、表９に記載したとおりである。
【００５７】
実施例２及び比較例２
次に、下記表１０記載の白濁タイプの液体入浴剤を調製し、これに、実施例１の液体入浴剤用香料組成物を添加した「白濁タイプ液体入浴剤１」（実施例２）、及び比較例１の液体入浴剤用香料組成物を添加した「白濁タイプ液体入浴剤２」（比較例２）を調製した。
【００５８】
【表１０】

【００５９】
「白濁タイプ液体入浴剤１」（実施例２）及び「白濁タイプ液体入浴剤２」（比較例２）について、専門パネル８名により、液体入浴剤の香りの「持続性」及び「香調の変化」を評価した。
「持続性」の評価は、液体入浴剤３０ｇを４０℃の湯２００Ｌを入れた浴槽中に添加し撹拌分散させた後、１時間４０℃に保ち，次に１時間後に新たに同一条件で液体入浴剤を投入し、一時間経過の浴槽と新たに入浴剤を投入した浴槽のニオイ強度を以下の５段階で比較評価することによって行った。
【００６０】
５段階評価尺度
５：投入直後の浴槽のニオイと同等の強度
４：投入直後の浴槽のニオイに比べ若干弱い
３：投入直後の浴槽のニオイに比べやや弱い
２：投入直後の浴槽のニオイに比べ弱い
１：投入直後の浴槽のニオイに比べ非常に弱い又は殆ど匂わない
【００６１】
上記評価値が５の場合は、投入直後のニオイ強度と投入後１時間を経過した浴槽のニオイ強度が同じとなり極めて持続性がよいことを示す。また、評価値が３程度であっても十分実用価値がある強度であるが、３未満の評価値になった場合には、入浴剤として必要なニオイ強度は既に無くなっていると判断できるものである。以下、表１１にその結果を示す。
【００６２】
「香調の変化」の評価は、前述の持続性の評価と全く同じ方法で行い、以下の５段階評価によって行った。以下、表１１にその結果を示す。
５段階評価尺度
５：投入直後の浴槽のニオイと同等の香質である
４：投入直後の浴槽のニオイに比べ若干変化がみられる
３：投入直後の浴槽のニオイに比べやや変化がみられる
２：投入直後の浴槽のニオイに比べ変化している
１：投入直後の浴槽のニオイに比べ著しく変化又は殆ど匂わない
【００６３】
評価値が５の場合は、投入直後のニオイと投入後１時間を経過した浴槽のニオイは香調的に変化が全くないことを示す。また、評価値が３以上であれば十分実用価値があると判断できるが、３未満の評価値になった場合には、香りの変化が大きく本来の香調が維持できていないものと判断できる。
【００６４】
【表１１】

【００６５】
表１１に示した結果から明らかなように、実施例１の液体入浴剤用香料組成物を用いた「白濁タイプ液体入浴剤１」（実施例２）の場合は、非常に良好な持続性を示し、香りの変化も殆ど起きていないことが明らかである。一方、比較例１の液体入浴剤用香料組成物を用いた「白濁タイプ液体入浴剤２」（比較例２）の場合では、持続性の低下が激しく、また、香りの質も大きく変化し、全くことなるベースノートだけの香りとなり明らかな劣化を示している。
【００６６】
実施例３〜４及び比較例３〜４
実施例３及び比較例３として表１２に示すフローラルブーケ調の液体入浴剤用香料組成物を調製した。
次に、表１３の乳液タイプ液体入浴剤を調製し、これに、実施例３の液体入浴剤用香料組成物を用いた「乳液タイプ液体入浴剤１」（実施例４）、及び比較例３の液体入浴剤用香料組成物を用いた「乳液タイプ液体入浴剤２」（比較例４）を各々調製した。
このように調製された液体入浴剤を実施例１に示した方法と同じ方法で評価した。その結果を表１４に示す。
【００６７】
【表１２】

【００６８】
【表１３】

【００６９】
【表１４】

【００７０】
表１３に示した結果から明らかなように、実施例３の液体入浴剤用香料組成物を用いた「乳液タイプ液体入浴剤１」（実施例４）の場合は、非常に良好な持続性を示し、香りの変化も殆ど起きていないことが明らかである。一方、比較例３の液体入浴剤用香料組成物を用いた白濁タイプ液体入浴剤２」（比較例４）の場合では、持続性の低下が激しく、又、香りの質も大きく変化している。
【００７１】
実施例５〜６及び比較例５〜６
実施例５及び比較例５として表１５に示すハーバルグリーン調の液体入浴剤用香料組成物を調製した。
次に、表１６の透明ローションタイプ液体入浴剤を調製し、これに、実施例５の液体入浴剤用香料組成物を用いた「透明ローションタイプ液体入浴剤１」（実施例６）、及び比較例５の液体入浴剤用香料組成物を用いた「透明ローションタイプ液体入浴剤２」（比較例６）を各々調製した。
このように調製させた液体入浴剤６０ｇを４０℃の湯２００Ｌを入れた浴槽中に添加し撹拌分散させた後、１時間４０℃に保つ。次に１時間後に新たに同一の条件で液体入浴剤を投入し、一時間経過の浴槽と新たに入浴剤を投入した浴槽のニオイ強度を実施例１〜２に示した方法と同じ方法で評価した。その結果を表１７に示す。
【００７２】
【表１５】

【００７３】
【表１６】

【００７４】
【表１７】

【００７５】
表１７に示した結果から明らかなように、実施例５の液体入浴剤用香料組成物を用いた「液体ローションタイプ液体入浴剤１」（実施例６）の場合は、良好な持続性、香調の変化も非常に少ない結果であった。一方、比較例５の液体入浴剤用香料組成物を用いた「液体ローションタイプ液体入浴剤２」（比較例６）の場合では、持続性、香調変化とも激しく明らかな劣化がみられた。
【００７６】
【発明の効果】
本発明の液体入浴剤用香料組成物によれば、液体入浴剤の香りに良好な持続性と安定性を与えることができる。また、液体入浴剤の組成に影響されない香料組成物を容易に調合できる。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a perfume composition for a liquid bath agent. More specifically, a fragrance composition for a liquid bath agent, in which the fragrance during bathing maintains a constant strength and diffusivity, and the scent lasts almost without change, a production method thereof, and a fragrance composition for the liquid bath agent The present invention relates to a liquid bath preparation containing
[0002]
[Prior art]
Conventionally, as a method of maintaining a constant strength and quality of the scent for a long time after putting the bath agent into the bath water, for example, a method of impregnating and dispersing a fragrance into a porous substance such as calcium silicate or dextrin, (Japanese Patent Application Laid-Open No. 54-140742), a method of blending an organic acid containing adipic acid, a carbonate and a specific flavor component (Japanese Patent Application Laid-Open No. 3-109317), (JP-A-5-17338), a method of delaying volatilization from water by inclusion and complex formation of perfume molecules with cyclodextrin (JP-A-50-63126, JP-A-50-63126) No. 63-8309).
However, these methods are all powder or tablet baths, and are not reports on liquid baths.
[0003]
Further, as a liquid bath agent, a liquid bath agent having dispersion stability and good persistence by blending ethanol, a polyhydric alcohol having a specific gravity of 1 or less, and an oily component mainly comprising a fragrance (Japanese Patent Application Laid-Open No. No. 35448).
However, since this liquid bath agent is a five-component system containing a surfactant having an HLB of 10 or less in addition to a fragrance, ethanol, a polyhydric alcohol, and an oily component, it is necessary to obtain good dispersion stability and persistence. However, there is a problem in that the balance of the amounts of the respective components is important, and if the balance of the amounts is broken, it is not possible to obtain favorable stability and sustainability. Therefore, there has been a demand for a liquid bath agent having a simpler system and good fragrance persistence.
[0004]
On the other hand, in the recent bath salt market, there is a strong demand for a bath salt having not only a warm bath effect but also a skin care function such as moisturizing, and the liquid bath salt market suitable for this is rapidly expanding. In the case of such a liquid bath agent, since the fragrance component is solubilized by the incorporation of the surfactant, the necessary fragrance cannot be diffused at the time of bathing, and sufficient fragrance intensity can be obtained. There was a problem that it was difficult.
By the way, the purpose of using a bath salt in a general household is to enjoy the scent by relaxing or refreshing by the scent, and even if the family takes a bath in order, the hot water is dirty and does not produce an unpleasant odor. It is in. However, liquid bath agents have a problem that it is extremely difficult to maintain a constant scent for a long time as described above in a simple system.
[0005]
[Problems to be solved by the invention]
Therefore, an object of the present invention is to provide a perfume composition for a liquid bath agent, in which a family can enjoy bathing by maintaining a constant strength and fragrance for a long time after pouring into a bath water satisfying the above demand. And a liquid bath containing the same.
[0006]
[Means for Solving the Problems]
Under these circumstances, the present inventors have conducted intensive studies in order to achieve the above-mentioned object, and as a result, by performing a combination of specific fragrance compounds that have been extremely selected, the scent is kept constant for a long time after being put into the bath water. The present inventors have found a bath agent capable of maintaining strength and flavor and completed the present invention.
That is, the present invention includes the following inventions.
[0007]
(1) Included in alcohols, ethers, aldehydes, ketones, esters, synthetic musks and the above compounds having a ClogP of 2.7 or more and less than 6.0 and a boiling point of 220 ° C. or more. A perfume composition for a liquid bath additive, comprising at least 50% by mass of one or more perfume compounds selected from nitrogen-free compounds.
[0008]
(2) The alcohols include cedrol, patchouli alcohol, α-santalol, carvacrol, dihydromyrcenol, bacdanol, citronellol, isoeugenol, (E)-(R) -2-ethyl-4- (2, 2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol (= levosandol), 2-methyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl 2.) A perfume composition for a liquid bath agent according to (1), comprising one or more perfume compounds selected from 2-buten-1-ol (= sandalmysole) and 9-decene-1-ol.
[0009]
(3) The perfume composition for a liquid bath additive according to (1), wherein the ethers comprise one or more perfume compounds selected from diphenyl oxide, naphthyl methyl ether, anethole and naphthyl ethyl ether.
[0010]
(4) the aldehydes are α-amylcinnamic aldehyde, α-amyl cinnamaldehyde dimethyl acetal, α-hexyl cinnamic aldehyde, lilial, 10-undecenal, undecanal, 2-methylundecanal, dodecanal, cuminaldehyde The fragrance composition for a liquid bath preparation according to (1), comprising one or more fragrance compounds selected from cyclamenaldehyde and citral.
[0011]
(5) The ketone is one selected from benzophenone, α-iron, damacenone, damascon, α-dynascon, yonone, iso-E-spar, cis-jasmon, methylnaphthylketone, methylyonone and acetylsedren. The perfume composition for liquid bath preparation according to (1), comprising two or more perfume compounds.
[0012]
(6) The esters are allyl cyclohexylpropionate, isoamyl benzoate, allyl cinnamate, isoamyl salicylate, benzyl salicylate, p-tert-butylcyclohexyl acetate, ceryl acetate, ceryl formate, cinnamyl cinnamate, γ-dodeca Lactone, geranyl anthranilate, geranyl phenylacetate, hexenyl salicylate, hexyl salicylate, linalyl benzoate, phenylethyl benzoate, δ-undecalactone, vetiveryl acetate, δ-nonalactone, isobornyl acetate, geranyl acetate, linalyl acetate, γ-un Decalactone, ethyl 3-methyl-3-phenylglycidate, tricyclodecenyl propionate, cyclohexyl salicylate, methyl N-methylanthranilate, dimethylbenzylcarbinyl acetate, cinnamon One or more fragrance compounds selected from ethyl, methyl dihydrojasmonate, cis-3-hexenyl salicylate, phenylpropyl isovalerate and ethyl 2,2,6-trimethyl-cyclohexanecarboxylate (= tesarone) (1) The perfume composition for a liquid bath agent according to (1).
[0013]
(7) The synthetic musks are selected from ambrettolide, exaltolide, 10-oxahexadecanolide, 11-oxahexadecanolide, phantolide, cyclohexadecenone, galaxolide, ethylene brassate, tonalide and musk ketone The perfume composition for liquid bath preparation according to (1), comprising one or more perfume compounds.
[0014]
(8) The liquid bath additive according to (1), wherein the nitrogen-containing compounds not included in the above-mentioned compounds are one or more kinds of fragrance compounds selected from aurantiol, isobutylquinoline, and geranyl nitrile. Perfume composition.
[0015]
(9) A liquid bath preparation containing the flavoring composition for a liquid bath preparation according to any one of (1) to (8) in an amount of 0.01 to 10% by mass.
[0016]
(10) The liquid bath preparation according to (9), wherein the liquid bath preparation is transparent.
[0017]
(11) The liquid bath preparation according to (9), wherein the liquid bath preparation is an emulsion.
[0018]
(12) The liquid bath preparation according to any one of (9) to (11), wherein the liquid bath preparation becomes an emulsion in bath water.
[0019]
(13) The liquid bath preparation according to any one of (9) to (12), wherein the liquid bath preparation becomes milky white turbid in bath water.
[0020]
(14) The liquid bath preparation according to any one of (9) to (11), wherein the liquid bath preparation is transparently dissolved in bath water.
[0021]
(15) The liquid bath agent according to any one of (9) to (14), wherein the liquid bath agent contains an oil component, a polyhydric alcohol, and a surfactant.
[0022]
(16) The liquid bath agent according to any one of (9) to (14), wherein the liquid bath agent contains purified water, a lower alcohol having 2 to 3 carbon atoms, a polyhydric alcohol, and a surfactant. Liquid bath salts.
[0023]
(17) The liquid bath preparation according to any one of (9) to (14), wherein the liquid bath preparation contains purified water, an oily component, a polyhydric alcohol, and a surfactant.
[0024]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the present invention will be described in more detail.
[0025]
The fragrance compound used in the present invention includes alcohols, ethers, aldehydes, ketones, esters, synthetic musks and the above-mentioned alcohols each having a ClogP of 2.7 or more and less than 6.0 and a boiling point of 220 ° C. or more. Nitrogen-containing compounds not included in the compounds.
A fragrance compound having a ClogP of less than 2.7 has high hydrophilicity, and is dissolved in the bath water when the bath water is supplied, and cannot be volatilized as necessary to feel sufficient odor intensity. In addition, since a fragrance compound having a ClogP of 6.0 or more has an extremely low affinity for water, when it is put into a bath water, it is immediately dissolved without dissolving in the bath water, so that the odor intensity immediately after the addition becomes strong. The odor intensity cannot be maintained for a long time, and the change over time is large. Further, a fragrance compound having a boiling point of less than 220 ° C. has a high volatility and thus hardly remains in a bath water, so that the fragrance possessed by the fragrance compound cannot be maintained.
[0026]
Here, ClogP is a 1-octanol / water partition coefficient of a chemical substance, and refers to a value calculated by an f-value method (hydrophobic fragment constant method). Specifically, it is determined by decomposing the chemical structure of the compound into its structural elements, and integrating the hydrophobic fragment constant (f value) of each fragment (CLOGP3 Reference Manual Daily Lightware 4.34, Albert Leo, David Weininger). , Version 1, March 1994).
Further, the boiling point of the above-mentioned perfume compound is described in, for example, “Synthetic Perfume Chemistry and Product Knowledge, Chemical Daily, March 6, 1996”.
As such a fragrance component, for example, the compounds in Tables 1 to 7 can be exemplified.
[0027]
[Table 1]

[0028]
[Table 2]

[0029]
[Table 3]

[0030]
[Table 4]

[0031]
[Table 5]

[0032]
[Table 6]

[0033]
[Table 7]

[0034]
The description of the component names in each table is based on "Synthetic Fragrance" Chemistry and Product Knowledge, Motoichi Indo, published by Chemical Daily, March 6, 1996.
However, * mark is a trade name of Takasago International Corporation Mp is melting point; these components are b. p. have.
[0035]
Examples of the perfume compounds described in Tables 1 to 7 of the present invention that do not correspond to “ClogP of 2.7 or more and less than 6.0 and a boiling point of 220 ° C. or more” include, for example, perfume compounds of Table 8. can do.
[0036]
[Table 8]

[0037]
In the present invention, natural essential oils containing the fragrance component used in the present invention as a main component can also be used, and an essential oil containing 50% by mass or more of these fragrance components is preferable. Examples include anise oil, star anise oil, fennel oil, camphor oil, citronella oil, cumin oil, rose oil, palmarose oil, geranium oil and the like.
One or more of these fragrance components can be used, and when blended in the fragrance composition for a liquid bath additive in an amount of 50% by mass or more, particularly 60% by mass or more, a fragrance having a constant scent for a long time Is preferable since the effect of maintaining the above is obtained.
[0038]
The fragrance that can be used in the fragrance composition for a liquid bath additive of the present invention in addition to the fragrance component is not particularly limited, and any of a synthetic fragrance and a natural fragrance can be used. For example, a wide range of perfume ingredients are used as described in "Arcander S.," Perfume and Flavor Chemicals ", published by the author, Montclair, NJ (U.S.A.) 1969". can do.
[0039]
Representative natural fragrances include, for example, aniseed, ylang-ylang, elemi, oris, orange, galvanum, clary sage, clove, coriander, sandalwood, citronella, cinnamon, jasmine, spearmint, cedarwood, geranium, celery, tangerine, tonka bean , Neroli, violet, patchouli, peach, vetiver, pettigren, peppermint, peruvian balsam, bergamot, eucalyptus, lilac, raspberry, lavender, lily of the valley, lemon, lemongrass, lime, rose and other natural essential oils; amber, castorium, Animal tinctures such as civet, musk and the like can be mentioned.
[0040]
Representative synthetic fragrances include, for example, hydrocarbons such as pinene, limonene, caryophyllene, longifolene, myrcene; cis-3-hexenol, pt-butycyclocyclohexanol, linalool, dihydrolinalool, tetrahydrolinalool, tetrahydromil Alcohols such as senol, menthol, isoborneol, isocampyl cyclohexanol, farnesol, benzyl alcohol, α-phenylethyl alcohol, β-phenylethyl alcohol, phenoxyethyl alcohol, cinamic alcohol, amylcinamic alcohol, thymol, eugenol Cineole, estragole, β-naphthyl methyl ether, diphenyl oxide, cetyl methyl ether, isoamyl phenyl ethyl ether, Ethers such as bromoxane (Henkel), glyciva (IFF), dihydrorose oxide, limonene oxide, mentfuran, amber core (Kao Corporation); citronellal, citral, hydroxycitronellal, dimethyltetrahydrobenzaldehyde, mylacaldehyde (IFF), Covanol (Takasago International), benzaldehyde (Givaudan), benzaldehyde, Suzal (Takasago International), cinnamaldehyde, methylcinnamic aldehyde, vanillin, ethyl vanillin, heliotropin, heliobuquet Aldehydes such as (Takasago International Corporation); dihydrojasmine, hedion (Firmenich), cycloten, cashmeren (IFF), Ketones such as rubon, menthone, isolongifolanone, raspberry ketone, acetophenone; coumarin, linalyl formate, citronellyl formate, linalyl acetate, citronellyl acetate, geranyl acetate, teropenyl acetate, sedryl acetate, 2-t-butyl Cyclohexyl acetate (Beldox; IFF), benzyl acetate, phenylallyl acetate, styralyl acetate, isoamyl acetate, rosephenone, jasmar (IFF), benzyl benzoate, benzyl salicylate, hexyl salicylate, methyl atolarate, Esters such as methyl anthranilate, ethyl anthranilate, and furtate (Kao Corporation); muscone, muscole, civetone, cyclopentadecanone, Examples thereof include musks such as cyclohexadecanonone, cyclopentadecanolide, ethylene dodecandioate, celestride (IFF), and traseolide (Quest International).
[0041]
These flavors may be used alone, or two or more kinds may be blended and used as a blended flavor.
One or more commonly used perfume retaining agents may be blended. For example, propylene glycol, glycerin, hexylene glycol, dipropylene glycol, benzyl benzoate, triethyl citrate, diethyl phthalate, hercoline ( (Abietic acid methyl) and the like can also be used in combination.
[0042]
Furthermore, one or more crude drug components can be used in combination. By blending the crude drug component, besides masking of the fragrance of the crude drug component, a synergistic effect of the efficacy effect of the perfume composition for liquid bath additives and the efficacy effect of the crude drug component can be expected. It is possible to appropriately add a crude drug component commonly used in bath salts [Known and Collected Techniques (Fragrances) Part 3 Fragrances for Cosmetics 4.3.3 Bath salts Issued on June 15, 2001] .
[0043]
The perfume composition for a liquid bath additive according to the present invention comprises: (1) a liquid bath agent composition of a type which is oily in a product state and which disperses an oily component in the bath water when it is put into a bath water; A liquid bath preparation composition that is a transparent liquid bath preparation containing polyhydric alcohol as a main component and dissolves transparently even when put into bath water. (3) The product itself is an emulsion and can be put into bath water. It can be used in any of the liquid bath compositions of the cloudy type.
[0044]
The perfume composition for a liquid bath additive of the present invention requires various perfume components conventionally blended in a perfume composition for a liquid bath agent in addition to one or more of the components shown in Tables 1 to 7. Can be appropriately selected and used according to the incense tone to be used.
The amount of the perfume composition for a liquid bath agent of the present invention to be added to various liquid bath agents is not particularly limited, and varies depending on the type of the perfume or the cosmetic composition. Therefore, this amount can be easily determined by specifying these types and combinations and preparing them. The perfume composition for a liquid bath additive of the present invention imparts aroma to a liquid bath agent in order to impart good palatability, persistence and appropriate scent intensity to the bath water. It is blended so as to be 1 to 10% by mass, preferably 0.5 to 5% by mass, and more preferably 1 to 3% by mass.
[0045]
An oil component, a polyhydric alcohol, a lower alcohol having 2 to 3 carbon atoms, and a surfactant can be appropriately added to the liquid bath agent of the present invention depending on the type of the liquid bath agent.
As the oil component used in the liquid bath agent of the present invention, oil components generally used such as squalane, liquid paraffin, isostearic acid, jojoba oil and the like can be used.
[0046]
Examples of the polyhydric alcohol used in the liquid bath agent of the present invention include glycerin, dipropylene glycol, hexylene glycol, propylene glycol, 1,3-butylene glycol and the like.
Examples of the lower alcohol having 2 to 3 carbon atoms used in the liquid bath additive of the present invention include ethyl alcohol and isopropyl alcohol.
[0047]
The surfactant used in the liquid bath agent of the present invention is not particularly limited as long as it is a surfactant generally usable for a bath agent. Further, a surfactant used for emulsifying or solubilizing an oil component may be appropriately used depending on the type of the liquid bath agent.
[0048]
In the liquid bath additive composition of the present invention, other optional ingredients can be blended as necessary. For example, vitamins, herbal medicines, and pigments depending on the intended effect and effect of the bath agent One or two or more raw materials selected from the above can be appropriately selected and blended.
[0049]
Examples of vitamins include retinol, thiamine, riboflavin, pyridoxine, cyanocobalamin, ascorbic acid, cholecalciferol, tocopherol, carnitine, ferulic acid, orotic acid, and γ-oxanol.
Examples of crude drugs include Senkyu, Spruce, Kaigai, Ginger, Ogan, Ouren, Sanshin, Gaio, Aloe, Cahiche, Peonies, Licorice, Chimpi, Chamomile, Maronier, Shobu and the like.
[0050]
Examples of the pigments include Red No. 104 (1), Red No. 105 (1), Red No. 106, Blue No. 1, Blue No. 2, Red 213, Red No. 214, Red No. 230 (1), and Red. No. 231, Red No. 232, Orange No. 205, Yellow No. 202 (1), Blue No. 202, Blue No. 203 and the like.
[0051]
Although the method for producing the liquid bath agent of the present invention is not particularly limited, a method for producing a liquid bath agent can be generally used [Known and Commonly Used Techniques (Cosmetics and Similar Products) V Bath Agent 1984] Issued on March 21].
In addition, as a liquid bath additive, (1) a liquid bath agent composition of a type which is oily in a product state, and when put into bath water, an oily component is turbidly dispersed in the bath water, (2) a lower alcohol or a polyhydric alcohol. A liquid bath additive composition that is a transparent liquid bath agent containing a main component and that dissolves transparently even when put into bath water. (3) A product that is itself a milky liquid and becomes cloudy when put into bath water. It can be used in any of the liquid bath preparation compositions, and can be used without particular limitation as long as it is a liquid bath preparation in a product state.
[0052]
【Example】
Hereinafter, the present invention will be described specifically with reference to Examples, but the present invention is not limited thereto.
[0053]
Example 1 and Comparative Example 1
As Example 1 and Comparative Example 1, a liquid bath additive flavor composition having the composition shown in Table 9 was prepared.
[0054]
[Table 9]

[0055]
In Table 9, the fragrance components 1 to 20 are the components described in Tables 1 to 7 and are components that form the skeleton of floral fruity which is a characteristic of the fragrance of the fragrance composition for a liquid bath additive of the present invention. Among them, the fragrance components 21 to 30 are components for modifying the odor of the fruity floral and increasing the palatability of the fragrance.
It has been found that removing 21 to 30 perfume components from both compositions of Example 1 and Comparative Example 1 would significantly reduce the value as a perfume for a liquid bath additive. 21 to 30 perfume components (components described in Table 8 above) and 1 to 20 components in Table 9 (components described in Tables 1 to 7) described above, the perfume composition for a liquid bath agent of the present invention. It was confirmed that it was an essential component in the product.
[0056]
In the fragrance composition comprising the combination, the relationship between the total amount of the fragrance components in Tables 1 to 7 and the total amount of the fragrance components in Table 8 in the fragrance composition for a liquid bath agent is a specific ratio. However, it was also found that it was involved in maintaining a constant fragrance intensity and fragrance for a long time after the bath agent was put into the bath.
In order to make this clear, in Example 1, as the fragrance component for jasmine, 100 mg of methyl dihydrojasmonate, which is the fragrance component of Table 5 that satisfies the conditions of the present invention, and the fragrance component shown in Table 8 were used. 80 mg of benzyl acetate was used, while 180 mg of benzyl acetate, which is a fragrance component shown in Table 8, was used in the fragrance composition of Comparative Example 1.
In addition, in Example 1, geraniol 60 mg as a fragrance component shown in Table 1 above, 40 mg of citronellol shown in Table 1 above, and 140 mg of β-phenylethyl alcohol shown in Table 8 were used as the fragrance component for rose. In Comparative Example 1, 290 mg of β-phenylethyl alcohol, which is a fragrance component shown in Table 8, was used.
Further, in order to maintain the overall fragrance, the composition of Example 1 used 120 mg of p-tert-butylcyclohexyl acetate, which is the component shown in Table 5, and the composition of Comparative Example 1 used the same. Using 70 mg of the components, the total amount of each component in both compositions was adjusted to 1000 mg.
The ratio between the total amount of the fragrance components described in Tables 1 to 7 and the total amount of the fragrance components described in Table 8 in both compositions of Example 1 and Comparative Example 1 is as described in Table 9. .
[0057]
Example 2 and Comparative Example 2
Next, a cloudy-type liquid bath agent shown in Table 10 below was prepared, and a “cloudy-type liquid bath agent 1” (Example 2) in which the fragrance composition for a liquid bath agent of Example 1 was added thereto, and "A cloudy type liquid bath agent 2" (Comparative Example 2) to which the flavoring composition for a liquid bath agent of Comparative Example 1 was added was prepared.
[0058]
[Table 10]

[0059]
With regard to the “white turbid type liquid bath agent 1” (Example 2) and the “white turbid type liquid bath agent 2” (Comparative Example 2), the “persistence” and “scent-like Change "was evaluated.
The evaluation of “persistence” was made by adding 30 g of a liquid bath additive into a bath containing 200 L of 40 ° C. water, stirring and dispersing the mixture, maintaining the temperature at 40 ° C. for 1 hour, and then newly adding the liquid under the same conditions after 1 hour. The bathing agent was charged, and the odor intensity of the bathtub after one hour elapsed and the bathtub into which the bathing agent was newly charged were compared and evaluated in the following five stages.
[0060]
Five-grade scale 5: Strength equivalent to odor of bath tub immediately after loading 4: Slightly weaker than odor of bath tub just after loading 3: Slightly weaker than odor of bath tub just after loading 2: Compared to odor of bath tub just after loading Weak 1: Very weak or hardly smelling compared to the odor in the bathtub immediately after being put in
When the above-mentioned evaluation value is 5, the odor intensity immediately after the charging and the odor intensity of the bathtub after 1 hour from the charging are the same, indicating that the durability is extremely good. In addition, even if the evaluation value is about 3, the strength is practically sufficient, but if the evaluation value is less than 3, it can be determined that the odor intensity required as a bath agent has already been lost. is there. The results are shown in Table 11 below.
[0062]
The evaluation of the “change in incense tone” was performed in exactly the same manner as the evaluation of the above-mentioned persistence, and was performed according to the following five-step evaluation. The results are shown in Table 11 below.
Five-grade scale 5: The fragrance is equivalent to the odor of the bath tub immediately after being put in 4: A slight change is seen compared to the odor of the bath tub just after putting 3: A slight change is seen compared to the odor of the bath tub just after putting 2 : Changed compared to the odor in the bathtub immediately after being put in 1: Notably changed or hardly smelled compared to the odor in the bathtub just after put in
When the evaluation value is 5, the odor immediately after the addition and the odor in the bathtub after 1 hour from the addition have no change in the incense. In addition, when the evaluation value is 3 or more, it can be determined that there is sufficient practical value. However, when the evaluation value is less than 3, it can be determined that the scent change is large and the original fragrance cannot be maintained. .
[0064]
[Table 11]

[0065]
As is evident from the results shown in Table 11, in the case of "white turbid type liquid bath agent 1" (Example 2) using the fragrance composition for a liquid bath agent of Example 1, a very good persistence was obtained. It is clear that almost no change in the scent occurred. On the other hand, in the case of “cloudy type liquid bath agent 2” (Comparative Example 2) using the liquid bath agent fragrance composition of Comparative Example 1, the persistence was drastically reduced, and the quality of the fragrance also changed significantly. The scent of the base note is completely different, indicating a clear deterioration.
[0066]
Examples 3 and 4 and Comparative Examples 3 and 4
As Example 3 and Comparative Example 3, floral bouquet-like perfume compositions for liquid bath additives shown in Table 12 were prepared.
Next, an emulsion type liquid bath agent shown in Table 13 was prepared, and “Emulsion type liquid bath agent 1” (Example 4) using the liquid bath agent flavor composition of Example 3 and Comparative Example 3 were prepared. "Emulsion type liquid bath agent 2" (Comparative Example 4) using each of the perfume compositions for liquid bath agent was prepared.
The liquid bath preparation thus prepared was evaluated by the same method as that shown in Example 1. Table 14 shows the results.
[0067]
[Table 12]

[0068]
[Table 13]

[0069]
[Table 14]

[0070]
As is clear from the results shown in Table 13, in the case of "Emulsion type liquid bath agent 1" (Example 4) using the perfume composition for a liquid bath agent of Example 3, a very good persistence was obtained. It is clear that almost no change in scent occurred. On the other hand, in the case of the cloudy type liquid bath agent 2 using the perfume composition for a liquid bath agent of Comparative Example 3 (Comparative Example 4), the sustainability is drastically reduced and the quality of the scent is also greatly changed. .
[0071]
Examples 5-6 and Comparative Examples 5-6
As Example 5 and Comparative Example 5, the herbal green tone perfume compositions for liquid bath additives shown in Table 15 were prepared.
Next, a transparent lotion type liquid bath agent shown in Table 16 was prepared, and the "transparent lotion type liquid bath agent 1" (Example 6) using the liquid bath agent perfume composition of Example 5 was prepared. "Transparent lotion type liquid bath agent 2" (Comparative Example 6) using the liquid bath agent perfume composition of Example 5 was prepared.
60 g of the liquid bath preparation thus prepared is added to a bath containing 200 L of hot water at 40 ° C., and the mixture is stirred and dispersed, and then kept at 40 ° C. for 1 hour. Next, after 1 hour, a liquid bath agent was newly added under the same conditions, and the odor intensity of the bathtub after 1 hour and the bathtub into which the bath agent was newly added was evaluated by the same method as shown in Examples 1 and 2. did. Table 17 shows the results.
[0072]
[Table 15]

[0073]
[Table 16]

[0074]
[Table 17]

[0075]
As is clear from the results shown in Table 17, in the case of “liquid lotion type liquid bath agent 1” (Example 6) using the liquid bath agent perfume composition of Example 5, good persistence and fragrance were obtained. The change in tone was also very small. On the other hand, in the case of “Liquid lotion type liquid bath additive 2” (Comparative Example 6) using the perfume composition for a liquid bath additive of Comparative Example 5, both the persistence and the change in fragrance were clearly deteriorated.
[0076]
【The invention's effect】
ADVANTAGE OF THE INVENTION According to the fragrance | flavor composition for liquid bath additives of this invention, good persistence and stability can be provided to the fragrance of a liquid bath agent. In addition, a fragrance composition that is not affected by the composition of the liquid bath agent can be easily prepared.

Claims (17)

Alcohols, ethers, aldehydes, ketones, esters, synthetic musks, and nitrogen-containing compounds not having any of the above compounds having a ClogP of 2.7 or more and less than 6.0 and a boiling point of 220 ° C. or more. A perfume composition for a liquid bath agent comprising 50% by mass or more of one or more perfume compounds selected from compounds. The alcohols include cedrol, patchouli alcohol, α-santalol, carvacrol, dihydromyrcenol, bacdanol, citronellol, isoeugenol, (E)-(R) -2-ethyl-4- (2,2,3 -Trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol, 2-methyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1- The perfume composition for a liquid bath additive according to claim 1, comprising one or more perfume compounds selected from all and 9-decene-1-ol. The perfume composition for a liquid bath agent according to claim 1, wherein the ethers comprise one or more perfume compounds selected from diphenyl oxide, naphthyl methyl ether, anethole and naphthyl ethyl ether. The aldehydes are α-amylcinnamic aldehyde, α-amylcinnamic aldehyde dimethyl acetal, α-hexyl cinnamic aldehyde, lilial, 10-undecenal, undecanal, 2-methylundecanal, dodecanal, cuminaldehyde, cyclamenaldehyde The fragrance composition for a liquid bath preparation according to claim 1, comprising one or more fragrance compounds selected from citral and citral. The ketones are one or more selected from benzophenone, α-iron, damasenone, damascon, α-dynascon, yonone, iso-E-spar, cis-jasmon, methylnaphthylketone, methylyonone and acetylsedrene. The perfume composition for a liquid bath preparation according to claim 1, comprising a perfume compound of the formula: The esters may be allyl cyclohexylpropionate, isoamyl benzoate, allyl cinnamate, isoamyl salicylate, benzyl salicylate, p-tert-butylcyclohexyl acetate, ceryl acetate, ceryl formate, cinnamyl cinnamate, γ-dodecalactone, anthranil Geranyl acid, geranyl phenylacetate, hexenyl salicylate, hexyl salicylate, linalyl benzoate, phenylethyl benzoate, δ-undecalactone, vetiveryl acetate, δ-nonalactone, isobornyl acetate, geranyl acetate, linalyl acetate, γ-undecalactone, Ethyl 3-methyl-3-phenylglycidate, tricyclodecenyl propionate, cyclohexyl salicylate, methyl N-methylanthranilate, dimethylbenzylcarbinyl acetate, ethyl cinnamate And at least one fragrance compound selected from methyl, dihydrojasmonate, cis-3-hexenyl salicylate, phenylpropyl isovalerate and ethyl 2,2,6-trimethyl-cyclohexanecarboxylate. A fragrance composition for a liquid bath additive according to the above. The synthetic musks are one selected from the group consisting of ambrettolide, exaltolide, 10-oxahexadecanolide, 11-oxahexadecanolide, phantolide, cyclohexadecenone, galaxolide, ethylene brasilate, tonalide, and musk ketone. The perfume composition for a liquid bath additive according to claim 1, comprising two or more perfume compounds. The perfume composition for a liquid bath agent according to claim 1, wherein the nitrogen-containing compounds not contained in the above-mentioned compounds are one or more perfume compounds selected from aurantol, isobutylquinoline and geranylnitrile. object. A liquid bath agent comprising the flavoring composition for a liquid bath agent according to any one of claims 1 to 8 in an amount of 0.01 to 10% by mass. The liquid bath preparation according to claim 9, wherein the liquid bath preparation is transparent. The liquid bath preparation according to claim 9, wherein the liquid bath preparation is an emulsion. The liquid bath preparation according to any one of claims 9 to 11, wherein the liquid bath preparation becomes an emulsion in bath water. The liquid bath preparation according to any one of claims 9 to 12, wherein the liquid bath preparation becomes milky white turbid in bath water. The liquid bath agent according to any one of claims 9 to 11, wherein the liquid bath agent is transparently dissolved in bath water. The liquid bath agent according to any one of claims 9 to 14, wherein the liquid bath agent contains an oil component, a polyhydric alcohol, and a surfactant. The liquid bath preparation according to any one of claims 9 to 14, wherein the liquid bath preparation contains purified water, a lower alcohol having 2 to 3 carbon atoms, a polyhydric alcohol, and a surfactant. The liquid bath agent according to any one of (9) to (14), wherein the liquid bath agent contains purified water, an oily component, a polyhydric alcohol, and a surfactant.