JP2004075986A5 - - Google Patents
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- JP2004075986A5 JP2004075986A5 JP2003167896A JP2003167896A JP2004075986A5 JP 2004075986 A5 JP2004075986 A5 JP 2004075986A5 JP 2003167896 A JP2003167896 A JP 2003167896A JP 2003167896 A JP2003167896 A JP 2003167896A JP 2004075986 A5 JP2004075986 A5 JP 2004075986A5
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- JP
- Japan
- Prior art keywords
- ring
- rings
- substituent
- atom
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 125000001424 substituent group Chemical group 0.000 description 16
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 description 8
- 125000003373 pyrazinyl group Chemical group 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 6
- -1 phthalocyanine compound Chemical class 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 239000002184 metal Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
Description
【請求項1】 下記一般式(I)で表されるフタロシアニン化合物を含有することを特徴とするインク。
【化1】
一般式(I)中、X1〜X4およびY1〜Y4は、それぞれ独立に、炭素原子または窒素原子を表す。
A1〜A4は、それぞれ独立に、X1〜X4およびY1〜Y4と共に芳香族環あるいはヘテロ環(更に他の環と縮合環を形成しても良い)を形成するのに必要な原子群を表す。(但し、各A、X、Yから成る4つの環の全てが同時に芳香族環になることはない。また各A、X、Yから成る4つの環の全てが同時にピリジン環の場合、ピリジン環内の各X、Yに隣接する原子の何れか一方が窒素原子であるピリジン環は除く。また各A、X、Yから成る4つの環の全てが同時にピラジン環の場合、ピラジン環内の各X、Yに隣接する原子の両方が窒素原子であるピラジン環は除く)。また、A1〜A4は置換基を有してもよい。A1〜A4のうち少なくとも1つは、あるいはA1〜A4の置換基のうち少なくとも1つはイオン性親水性基を置換基として有する。
Mは、水素原子、金属元素、金属酸化物、金属水酸化物、または金属ハロゲン化物を表す。
1. An ink comprising a phthalocyanine compound represented by the following general formula (I).
Embedded image
In the general formula (I), X 1 to X 4 and Y 1 to Y 4 each independently represent a carbon atom or a nitrogen atom.
A 1 to A 4 are each independently required to form an aromatic ring or a hetero ring (which may form a condensed ring with another ring) together with X 1 to X 4 and Y 1 to Y 4. Atomic group. (However, all of the four rings consisting of A, X, and Y are not all aromatic rings at the same time. When all of the four rings consisting of A, X, and Y are simultaneously pyridine rings, Excluding a pyridine ring in which one of the atoms adjacent to each of X and Y is a nitrogen atom. A pyrazine ring in which both atoms adjacent to X and Y are nitrogen atoms). A 1 to A 4 may have a substituent. At least one of A 1 to A 4 may alternatively at least one of the substituents of A 1 to A 4 has as a substituent an ionic hydrophilic group.
M represents a hydrogen atom, a metal element, a metal oxide, a metal hydroxide, or a metal halide.
【請求項2】 一般式(I)で表されるフタロシアニン化合物が、下記一般式(II)で表されるフタロシアニン化合物であることを特徴とする請求項1に記載のインク。
【化2】
一般式(II)中、Q1〜Q4、R1〜R4は、それぞれ独立に、炭素原子、窒素原子、硫黄原子、酸素原子、または燐原子を表す。E1〜E4はそれぞれ独立に、Q1〜Q4およびR1〜R4と共に芳香族環あるいはヘテロ環(更に他の環と縮合環を形成しても良い)を形成するのに必要な原子群を表す。(但し、各E、Q、Rから成る4つの環の全てが同時に芳香族環になることはない。また、その4つの環の全てが同時にピリジン環の場合、各Q及びRの何れか一方が窒素原子であるピリジン環は除く。また、その4つ環の全てが同時にピラジン環の場合、各Q及びRの両方が窒素原子であるピラジン環は除く)。また、E1〜E4は置換基を有してもよい。但し、E1〜E4のうち少なくとも1つは、あるいはE1〜E4の置換基のうち少なくとも1つはイオン性親水性基を置換基として有する。Mは、一般式(I)の場合と同義である。
2. The ink according to claim 1, wherein the phthalocyanine compound represented by the general formula (I) is a phthalocyanine compound represented by the following general formula (II).
Embedded image
In the general formula (II), Q 1 to Q 4 and R 1 to R 4 each independently represent a carbon atom, a nitrogen atom, a sulfur atom, an oxygen atom, or a phosphorus atom. E 1 to E 4 are each independently required to form an aromatic ring or a hetero ring (which may form a condensed ring with another ring) together with Q 1 to Q 4 and R 1 to R 4. Represents an atomic group. (However, all of the four rings consisting of E, Q, and R are not simultaneously aromatic rings. When all of the four rings are pyridine rings at the same time, any one of each of Q and R is used.) Excluding a pyridine ring in which is a nitrogen atom, and when all four rings are pyrazine rings at the same time, excluding a pyrazine ring in which both Q and R are nitrogen atoms). E 1 to E 4 may have a substituent. Provided that at least one of E 1 to E 4 are, or at least one of substituents E 1 to E 4 has as a substituent an ionic hydrophilic group. M has the same meaning as in formula (I).
【請求項3】 一般式(II)で表されるフタロシアニン化合物が、下記一般式(III)で表されるフタロシアニン化合物であることを特徴とする請求項1〜2に記載のインク。
【化3】
一般式(III)中、Q1〜Q4、P1〜P4、W1〜W4、R1〜R4は、それぞれ独立に、(=C(J1)−及びまたは−N=)、(=C(J2)−及びまたは−N=)、(=C(J3)−及びまたは−N=)、(=C(J4)−及びまたは−N=)を表す。J1〜J4はそれぞれ独立に、水素原子及びまたは置換基を表す。但し、(Q1、P1、W1、R1)、(Q2、P2、W2、R2)、(Q3、P3、W3、R3)、(Q4、P4、W4、R4)から成る環{A環:(A)、B環:(B)、C環:(C)、D環:(D)}の4つ全てが同時に芳香族環になることはない。また、その環の4つ全てが同時にピリジン環の場合は、(Q1及びR1)且つ(Q2及びR2)且つ(Q3及びR3)且つ(Q4及びR4)の何れか一方が窒素原子であるピリジン環は除く。また、その環の4つ全てが同時にピラジン環の場合、(Q1及びR1)且つ(Q2 及びR2)且つ(Q3及びR3)且つ(Q4及びR4)の両方が窒素原子であるピラジン環は除く。また、J1〜J4が置換基を表す場合は、更に置換基を有してもよい。J1〜J4のうち少なくとも1つは、あるいJ1〜J4が有する置換基のうち少なくとも1つはイオン性親水性基を置換基として有する。Mは、一般式(II)の場合と同義である。
3. The ink according to claim 1, wherein the phthalocyanine compound represented by the general formula (II) is a phthalocyanine compound represented by the following general formula (III).
Embedded image
In the general formula (III), Q 1 to Q 4 , P 1 to P 4 , W 1 to W 4 , and R 1 to R 4 each independently represent (= C (J 1 )-and / or -N =). represents - (and or -N = = C (J 4) ) (= C (J 2) - - and or -N =), (= C ( J 3) and or -N =),. J 1 to J 4 each independently represent a hydrogen atom and / or a substituent. However, (Q 1 , P 1 , W 1 , R 1 ), (Q 2 , P 2 , W 2 , R 2 ), (Q 3 , P 3 , W 3 , R 3 ), (Q 4 , P 4) , W 4 , R 4 ) {A ring: (A), B ring: (B), C ring: (C), D ring: (D)} are all aromatic rings at the same time. Never. When all four of the rings are pyridine rings at the same time, any of (Q 1 and R 1 ), (Q 2 and R 2 ), (Q 3 and R 3 ) and (Q 4 and R 4 ) Excludes pyridine rings, one of which is a nitrogen atom. Also, when all four of the rings are pyrazine rings simultaneously, both (Q 1 and R 1 ) and (Q 2 and R 2 ) and (Q 3 and R 3 ) and (Q 4 and R 4 ) are nitrogen Except for the pyrazine ring, which is an atom. When J 1 to J 4 represent a substituent, they may further have a substituent. At least one of J 1 through J 4, at least one of the substituents that have J 1 through J 4 has has as a substituent an ionic hydrophilic group. M has the same meaning as in formula (II).
【請求項10】
【化6】
一般式(III)中、Q1〜Q4、P1〜P4、W1〜W4、R1〜R4は、それぞれ独立に、(=C(J1)−及びまたは−N=)、(=C(J2)−及びまたは−N=)、(=C(J3)−及びまたは−N=)、(=C(J4)−及びまたは−N=)を表す。J1〜J4はそれぞれ独立に、水素原子及びまたは置換基を表す。但し、(Q1、P1、W1、R1)、(Q2、P2、W2、R2)、(Q3、P3、W3、R3)、(Q4、P4、W4、R4)から成る環{A環:(A)、B環:(B)、C環:(C)、D環:(D)}の4つ全てが同時に芳香族環になることはない。また、その4つ環の全てが同時にピリジン環の場合は、(Q1及びR1)且つ(Q2及びR2)且つ(Q3及びR3)且つ(Q4及びR4)の何れか一方が窒素原子であるピリジン環は除く。また、その4つの環の全てが同時にピラジン環の場合、(Q1及びR1)且つ(Q2及びR2)且つ(Q3及びR3)且つ(Q4及びR4)の両方が窒素原子であるピラジン環は除く。また、J1〜J4が置換基を表す場合は、更に置換基を有してもよい。J1〜J4のうち少なくとも1つは、あるいJ1〜J4が有する置換基のうち少なくとも1つはイオン性親水性基を置換基として有する。Mは、一般式(II)の場合と同義である。
10.
Embedded image
In the general formula (III), Q 1 to Q 4 , P 1 to P 4 , W 1 to W 4 , and R 1 to R 4 each independently represent (= C (J 1 )-and / or -N =). represents - (and or -N = = C (J 4) ) (= C (J 2) - - and or -N =), (= C ( J 3) and or -N =),. J 1 to J 4 each independently represent a hydrogen atom and / or a substituent. However, (Q 1 , P 1 , W 1 , R 1 ), (Q 2 , P 2 , W 2 , R 2 ), (Q 3 , P 3 , W 3 , R 3 ), (Q 4 , P 4) , W 4 , R 4 ) {A ring: (A), B ring: (B), C ring: (C), D ring: (D)} are all aromatic rings at the same time. Never. When all of the four rings are pyridine rings at the same time, any of (Q 1 and R 1 ) and (Q 2 and R 2 ) and (Q 3 and R 3 ) and (Q 4 and R 4 ) Excludes pyridine rings, one of which is a nitrogen atom. Also, when all of the four rings are pyrazine rings simultaneously, both (Q 1 and R 1 ) and (Q 2 and R 2 ) and (Q 3 and R 3 ) and (Q 4 and R 4 ) are nitrogen Except for the pyrazine ring, which is an atom. When J 1 to J 4 represent a substituent, they may further have a substituent. At least one of J 1 through J 4, at least one of the substituents that have J 1 through J 4 has has as a substituent an ionic hydrophilic group. M has the same meaning as in formula (II).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003167896A JP2004075986A (en) | 2002-06-19 | 2003-06-12 | Phthalocyanine compound, ink containing the same. method for ink jet recording and method for image forming |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002178767 | 2002-06-19 | ||
JP2003167896A JP2004075986A (en) | 2002-06-19 | 2003-06-12 | Phthalocyanine compound, ink containing the same. method for ink jet recording and method for image forming |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2004075986A JP2004075986A (en) | 2004-03-11 |
JP2004075986A5 true JP2004075986A5 (en) | 2007-04-26 |
Family
ID=32032527
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2003167896A Abandoned JP2004075986A (en) | 2002-06-19 | 2003-06-12 | Phthalocyanine compound, ink containing the same. method for ink jet recording and method for image forming |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2004075986A (en) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4509938B2 (en) * | 2003-08-27 | 2010-07-21 | 山本化成株式会社 | Tetraazaporphyrin compounds |
JP4516744B2 (en) * | 2003-12-18 | 2010-08-04 | 富士フイルム株式会社 | Phthalocyanine compound, ink, ink jet recording method, and image forming method |
JP2005220253A (en) * | 2004-02-06 | 2005-08-18 | Konica Minolta Holdings Inc | Coloring composition, ink jet recording liquid and ink jet recording method and color toner |
JP4659403B2 (en) | 2004-07-15 | 2011-03-30 | 富士フイルム株式会社 | Phthalocyanine compound, ink, ink jet recording method, and image forming method |
CN101384670B (en) * | 2006-02-10 | 2013-06-05 | 日本化药株式会社 | Novel porphyrazine dye, ink, ink set, and colored material |
KR101321889B1 (en) * | 2006-04-07 | 2013-10-25 | 니폰 가야꾸 가부시끼가이샤 | Porphyrazine dye, ink, ink set, and colored matter |
CN101631834B (en) | 2007-03-14 | 2014-10-22 | 日本化药株式会社 | Novel porphyrazine dye, ink, ink set, and colored material |
US7981204B2 (en) | 2007-12-28 | 2011-07-19 | Nippon Kayaku Kabushiki Kaisha | Porphyrazine coloring matter and ink composition containing the same |
JP5414322B2 (en) * | 2008-03-28 | 2014-02-12 | 富士フイルム株式会社 | Mixed crystal and colored pigment dispersion composition |
TW201005045A (en) * | 2008-06-30 | 2010-02-01 | Nippon Kayaku Kk | Porphyrazine pigment, ink composition and colored article |
JP2010030196A (en) | 2008-07-30 | 2010-02-12 | Fujifilm Corp | Inkjet recording method |
JP2010030197A (en) | 2008-07-30 | 2010-02-12 | Fujifilm Corp | Inkjet recording method |
EP2321372B1 (en) | 2008-08-22 | 2012-12-05 | FUJIFILM Imaging Colorants Limited | Azaphthalocyanines and their use in ink-jet printing |
JP2010077285A (en) | 2008-09-26 | 2010-04-08 | Fujifilm Corp | Ink set and method for forming image |
GB0823267D0 (en) | 2008-12-20 | 2009-01-28 | Fujifilm Imaging Colorants Ltd | Azaphthalocyanines and their use in ink-jet printing |
WO2010073603A1 (en) | 2008-12-25 | 2010-07-01 | 日本化薬株式会社 | Porphyrazine dye, ink composition containing same, and colored material |
CA2758708C (en) | 2009-04-15 | 2016-09-13 | Nippon Kayaku Kabushiki Kaisha | Porphyrazine coloring matter, ink composition containing the same and colored product |
KR101729346B1 (en) | 2009-06-12 | 2017-04-21 | 닛뽄 가야쿠 가부시키가이샤 | Porphyrazine coloring matter, ink composition, recording method, and colored object |
JP5553448B2 (en) * | 2010-02-19 | 2014-07-16 | 日本化薬株式会社 | Porphyrazine coloring matter, ink composition containing the same, and coloring agent |
JP2010196062A (en) * | 2010-03-23 | 2010-09-09 | Fujifilm Corp | Phthalocyanine compound, ink, inkjet recording method, and image forming method |
-
2003
- 2003-06-12 JP JP2003167896A patent/JP2004075986A/en not_active Abandoned
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