JP2004059650A5 - - Google Patents

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Publication number
JP2004059650A5
JP2004059650A5 JP2002217060A JP2002217060A JP2004059650A5 JP 2004059650 A5 JP2004059650 A5 JP 2004059650A5 JP 2002217060 A JP2002217060 A JP 2002217060A JP 2002217060 A JP2002217060 A JP 2002217060A JP 2004059650 A5 JP2004059650 A5 JP 2004059650A5
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JP
Japan
Prior art keywords
polyethylene
ethylene
olefin
molecular weight
polymer component
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Pending
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JP2002217060A
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Japanese (ja)
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JP2004059650A (en
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Priority to JP2002217060A priority Critical patent/JP2004059650A/en
Priority claimed from JP2002217060A external-priority patent/JP2004059650A/en
Publication of JP2004059650A publication Critical patent/JP2004059650A/en
Publication of JP2004059650A5 publication Critical patent/JP2004059650A5/ja
Pending legal-status Critical Current

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Claims (4)

少なくとも2種類のポリエチレン(A)と(B)とからなり、ポリエチレン(A)は、クロム化合物担持系触媒を用いて製造された樹脂であり、ポリエチレン(B)は、チタン系触媒を用いて2段重合により製造された樹脂であり、ポリエチレン(A)は、MIが0.01〜10g/10分、密度が940kg/m以上であるエチレン単独重合体もしくはエチレンと炭素数3〜20のα−オレフィンとの共重合体であり、ポリエチレン(B)は、エチレンを単独重合もしくはエチレンと炭素数3〜20のα−オレフィンとを共重合して、MIが10〜300g/10分、密度が960kg/m 以上である低分子量重合体成分を製造した後、エチレンと炭素数3〜20のα−オレフィンとを共重合し、低分子量重合体成分の量に対して0.95〜1.05倍の重量比の高分子量重合体成分を製造することにより得られる、MIが0.03〜1g/10分、密度が958kg/m以下である、エチレンと炭素数3〜20のα−オレフィンとの共重合体であり、組成物中の(B)の量は、20〜80重量%の範囲であり、組成物のMIが0.01〜5g/10分、密度が940〜960kg/mであることを特徴とするポリエチレン組成物。It consists of at least two types of polyethylene (A) and (B). Polyethylene (A) is a resin produced using a chromium compound-supported catalyst, and polyethylene (B) is a resin prepared using a titanium-based catalyst. Polyethylene (A) is a resin produced by step polymerization, and the polyethylene (A) is an ethylene homopolymer having an MI of 0.01 to 10 g / 10 min and a density of 940 kg / m 3 or more, or ethylene and α having 3 to 20 carbon atoms. -Copolymer with olefin, and polyethylene (B) is obtained by homopolymerizing ethylene or copolymerizing ethylene and an α-olefin having 3 to 20 carbon atoms, and MI is 10 to 300 g / 10 min . after producing the low molecular weight polymer component is 960 kg / m 3 or more, copolymerizing a α- olefin of ethylene and 3 to 20 carbon atoms, 0 relative to the amount of low-molecular weight polymer component. Obtained by producing high molecular weight polymer component of 5 to 1.05 times the weight ratio, MI is 0.03~1g / 10 min, density of 958kg / m 3 or less, ethylene and carbon atoms 3 20 α-olefin copolymer, the amount of (B) in the composition is in the range of 20 to 80% by weight, MI of the composition is 0.01 to 5 g / 10 min, and the density is A polyethylene composition, which is 940 to 960 kg / m 3 . ポリエチレン(A)が、有機金属化合物で処理されたクロム化合物担持系触媒と助触媒からなる組み合わせで製造されたものであることを特徴とする、前記請求項1に記載のポリエチレン組成物。  The polyethylene composition according to claim 1, wherein the polyethylene (A) is produced by a combination of a chromium compound-supported catalyst treated with an organometallic compound and a promoter. 該低分子量重合体成分が、0.1重量%以下のα−オレフィンを含む溶媒中で製造されることを特徴とする、前記請求項1〜2に記載のポリエチレン組成物。  The polyethylene composition according to claim 1 or 2, wherein the low molecular weight polymer component is produced in a solvent containing 0.1 wt% or less of an α-olefin. 該低分子量重合体成分の密度が971kg/m以上あることを特徴とする、前記請求項1〜3に記載のポリエチレン組成物。The polyethylene composition according to any one of claims 1 to 3, wherein the density of the low molecular weight polymer component is 971 kg / m 3 or more.
JP2002217060A 2002-07-25 2002-07-25 Polyethylene composition Pending JP2004059650A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2002217060A JP2004059650A (en) 2002-07-25 2002-07-25 Polyethylene composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2002217060A JP2004059650A (en) 2002-07-25 2002-07-25 Polyethylene composition

Publications (2)

Publication Number Publication Date
JP2004059650A JP2004059650A (en) 2004-02-26
JP2004059650A5 true JP2004059650A5 (en) 2005-10-27

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP2002217060A Pending JP2004059650A (en) 2002-07-25 2002-07-25 Polyethylene composition

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JP (1) JP2004059650A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006241451A (en) * 2005-02-07 2006-09-14 Asahi Kasei Chemicals Corp Polyethylene composition

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