JP2004052173A - High-strength polyester monofilament and method for producing the same - Google Patents

High-strength polyester monofilament and method for producing the same Download PDF

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JP2004052173A
JP2004052173A JP2002212499A JP2002212499A JP2004052173A JP 2004052173 A JP2004052173 A JP 2004052173A JP 2002212499 A JP2002212499 A JP 2002212499A JP 2002212499 A JP2002212499 A JP 2002212499A JP 2004052173 A JP2004052173 A JP 2004052173A
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Japan
Prior art keywords
monofilament
roller
strength
stretching
dtex
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JP2002212499A
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Japanese (ja)
Inventor
Shuji Miyazaki
宮崎 修二
Shiro Ishibai
石灰 司郎
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Unitika Fibers Ltd
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Unitika Fibers Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a high-strength polyester monofilament suitable for a filament for a screen gauze, and having excellent processability and handleability; and to provide a method for producing the monofilament. <P>SOLUTION: The monofilament is obtained by a spin-draw method comprising extruding a polyester polymer from a melt-spinning cap, cooling the extruded polymer, imparting an oil thereto, taking up the resultant filament with the oil, and winding the filament at ≥1,500 m/min while continuously drawing the taken-up filament without winding the filament once. The monofilament has characteristics of (1) 10-40 dtex size, (2) ≥1.380 g/cm<SP>3</SP>density and (3) ≥8.0 cN/dtex strength at break. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、スクリーン紗等の産業資材用途に好適な細繊度の高強度ポリエステルモノフィラメント及びその製造方法に関するものである。
【0002】
【従来の技術】
従来より、ポリエステルは寸法安定性や汎用性に優れるため、マルチフィラメントやモノフィラメント等の繊維状に加工され、衣料用途や産業資材用途に広く用いられている。
【0003】
その用途の一つであるスクリーン紗用に用いられる繊維は、寸法安定性が重要視され従来絹等の天然繊維やステンレス等の無機繊維が使用されていた。しかし、生産性に優れるポリアミドやポリエステル等の繊維状に加工されたものが安価で汎用性があり、中でもポリエステルを主成分としたモノフィラメントは、水分等による寸法変化が少なく、寸法安定性や耐熱性に優れるため、近年、広く用いられるようになってきた。
【0004】
このような用途に使用されるポリエステルモノフィラメントとして、特開平5−286277号公報には、伸度2%時の強度を1.7g/d以上にしたスクリーン紗用ポリエステルモノフィラメント、また、特開平5−295617号公報にはスピンドロー法による製造法が提案されている。
【0005】
しかしながら、これらのモノフィラメント及び製造方法によると、ポリエステルモノフィラメントの切断強度を重要視しておらず、従ってスクリーン紗織物の製織、或いは、製品の取扱い時に切断強度の低いことに起因する糸切れが発生しやすく、加工性や取扱い性において満足できる物性のものではなかった。
【0006】
【発明が解決しようとする課題】
本発明は、上記の問題点を解決し、スクリーン紗用の繊維として好適で、加工性や取扱い性に優れた高強度のポリエステルモノフィラメント及びその製造方法を提供することを技術的な課題とするものである。
【0007】
【課題を解決するための手段】
本発明者らは、上記の課題を解決するために鋭意検討した結果、本発明に到達した。
すなわち、本発明は次の(a)、(b)を要旨とするものである。
(a)ポリエステルポリマーを、溶融紡糸口金より紡出した後、冷却し、油剤を付与して引き取り、一旦巻き取ることなく連続して延伸を行いながら、1500m/分以上で巻き取るスピンドロー法で得られるモノフィラメントであって、下記(1)〜(3)の特性を有していることを特徴とする高強度ポリエステルモノフィラメント。
(1)繊度(dtex)  =10〜40
(2)密度(g/cm) ≧1.380
(3)切断強度(cN/dtex) ≧8.0
(b)(a)記載のモノフィラメントの製造方法であって、延伸時にスチームを吹き付けながら延伸を行うことを特徴とする高強度ポリエステルモノフィラメントの製造方法。
【0008】
【発明の実施の形態】
以下、本発明について詳細に説明する。
本発明の高強度ポリエステルモノフィラメントを形成するポリエステルポリマーとしては、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレンナフタレート等を用いることができるが、中でも寸法安定性や耐熱性に優れ、また、汎用性やコスト面からポリエチレンテレフタレート(以下、PETと称す。)が最も好ましい。
【0009】
また、ポリエステルポリマー中には本来の特性や製糸性を損なわない程度であれば、必要に応じて艶消し剤、撥水剤、制電剤、表面改質剤、難燃剤、顔料、着色剤等の添加剤、あるいは、共重合物質が含有されていてもよい。
【0010】
また、その極限粘度〔η〕は、0.8〜1.0が好ましく、0.8未満であると強度が低くなりやすく、また、耐摩耗性も劣るようになり好ましくない。一方、1.0を超えると、熱収縮率が高くなるため寸法安定性が劣るようになり好ましくない。
【0011】
本発明の高強度モノフィラメントは、繊度を10〜40dtexにする必要があり、好ましくは10〜30dtexである。繊度が10dtex未満であると生産性や延伸性が劣るようになる。一方、40dtexを超えると、モノフィラメントの断面における中心部と外層部間で配向度や結晶化度等の差が大きくなることに起因すると思われるが、強度の低いモノフィラメントとなる。
【0012】
次に、モノフィラメントの密度は1.380g/cm以上とし、好ましくは1.385g/cm以上とする。密度が1.380g/cm未満であると、モノフィラメントの切断強度を8.0cN/dtex以上とすることが困難となる。
【0013】
そして、本発明のモノフィラメントは切断強度が8.0cN/dtex以上、好ましくは8.5cN/dtex以上、さらに好ましくは9.0cN/dtex以上である。8.0cN/dtex未満であると、繊度が細いために糸切れしやすくなり、加工性や取扱い性、あるいは耐久性に劣るものとなる。そして、使用される用途が限られ、スクリーン紗用に適さないものとなる。
【0014】
本発明の高強度ポリエステルモノフィラメントは、常用の溶融紡糸装置を用いて製造することが可能であるが、引き取った後一旦巻き取ることなく連続して延伸を行い、1500m/分以上で巻き取るスピンドロー法で得られるものである。巻き取り速度が1500m/分未満になると生産性が劣り好ましくない。
【0015】
また、本発明のモノフィラメントの断面形状は、多角形状等の異形であってもよいが、高強度が得やすいことと耐摩耗性の面からも丸断面形状とすることが好ましい。
【0016】
そして、本発明の製造方法においては、延伸時にスチームを吹き付けながら延伸(スチーム延伸)を行うものである。つまり、通常、ポリエステルマルチフィラメントやポリエステルモノフィラメントをスピンドロー法で延伸する際には、引き取りローラあるいは引き揃えローラをTG(ガラス転移点)以上の温度に加熱して未延伸糸の延伸性の向上を図るものである。しかしながら、この方法で細繊度のモノフィラメントを製造すると、細繊度モノフィラメントは紡糸配向や延伸前の熱処理等による収縮力が小さく、従って、加熱された引き取りローラや引き揃えローラのローラ表面上で糸緩みが起こるため、糸揺れが発生し、均一な熱処理に必要なラップ数での糸掛けが難しくなり、高強度化を行うために常用採用される高倍率の延伸に必要な加熱温度にすることができなくなったり、延伸性が劣るという問題があり、結果的に高強度のポリエステルモノフィラメントを操業性よく、製造することが困難であった。
【0017】
したがって、本発明においては、細繊度のポリエステルモノフィラメントを十分に熱処理を行いながら高倍率での延伸を可能とするために、延伸時にスチームを吹き付けながら延伸を行うものである。これにより、スチーム熱処理を行う前の引き取りローラや引き揃えローラを非加熱としても、高倍率の延伸が可能となる。
【0018】
また、スチーム延伸においては、スチームを連続的に糸条に直接吹き付けて延伸を行うが、その吹き付け装置として用いるスチーム処理機の形状や吹き付け方法は特に限定するものではなく、例えば、対称に配置された直径1.0〜3.0mmの2個のオリフィスから糸条の進行方向に向かって、角度30〜60°でスチームを吹き付ける方法等が挙げられる。また、スチームの圧力や温度は0.05〜0.2Mpa、200〜400℃の範囲とすることが好ましく、延伸速度や繊度に応じてこの範囲内で適宜設定することが好ましい。
【0019】
本発明において、スチーム延伸は、引き取りローラ又は引き揃えローラと、加熱ローラとの間で上記のようにスチームの吹き付けを行った後、ローラ間での延伸を行うことが好ましい。また、スチーム熱処理後の延伸ローラの設置数を複数とし、多段延伸を行ってもよいが、2段目以降の延伸張力が高くなりやすく、糸切れしやすくなるので、1段延伸(引き揃えは含まず)とすることが好ましい。
【0020】
また、延伸倍率としては、3.0〜6.0の範囲とすることが好ましく、延伸速度や繊度に応じてこの範囲内で適宜設定することが好ましい。また、スチーム熱処理した糸条を引き取り、延伸を行う加熱ローラは、延伸性を考慮して150〜250℃の加熱ローラとすることが好ましい。
【0021】
次に、図面を用いて本発明の高強度ポリエステルモノフィラメントの製造方法を説明する。図1は、本発明の製造方法の一実施態様を示す概略工程図である。
まず、紡出された糸条は、冷却され、油剤を付与された後、未延伸糸Yとして、まず非加熱の第1ローラ1に複数回掛けて引き取られ、引き続いて非加熱の第2ローラ2に複数回掛けて1.005〜1.05倍の引き揃えが行われる。続いてスチーム処理機7でスチームの吹き付けを行った後、150〜250℃に加熱された第3ローラ3に複数回掛けて延伸を行い、その後150〜250℃に加熱された第4ローラ4に複数回掛けて3〜10%の弛緩熱処理を施した後、非加熱の第5ローラ5に複数回掛けて0〜5%の弛緩率で引き取り、速度1500m/分以上でワインダー6に巻き取る。
【0022】
【実施例】
次に、本発明を実施例によって具体的に説明する。
なお、実施例における各物性値は、次の方法で測定した。
(a)PETの極限粘度
フェノールと四塩化エタンとの等重量混合物を溶媒とし、濃度0.5g/dl、温度20℃で測定した。
(b)切断強度、切断伸度
JISL−1017に従い、島津製作所製オートグラフDSS−500を用い、試料長25cm、引っ張り速度30cm/分で測定した。
(c)密度
JISL−1013に従い、密度勾配管法、25℃で測定した。
【0023】
実施例1
常用の溶融紡糸装置に孔径が0.6mm、孔数8個の常用の溶融紡糸口金を装着し、極限粘度〔η〕1.03のPETチップを用い、温度300℃で紡出し、長さ20cm、壁面温度300℃の加熱筒を通過させた後、冷却長150cmの横型冷却装置を用いて、温度15℃、速度0.6m/秒の冷却風を吹き付けて冷却した。油剤を付与した後、非加熱の第1ローラに2回掛けて引き取り、引き続き非加熱の第2ローラに3回掛けて1.03倍の引き揃えを行った後、第3ローラとの間で、対称に配置されたオリフィス径が1.2mm、吹き出し角度45°の8エンド用のスチーム熱処理機を用いて、温度380℃、圧力0.12MPaのスチームを各々のモノフィラメントに吹き付けた。そして、温度210℃の第3ローラに3回掛けて4.8倍の延伸を行った。続いて温度200℃の第4ローラに3回掛けて2%の弛緩熱処理を行い、その後速度3015m/分、非加熱の第5ローラに4回掛けて1.3%の弛緩率で引き取り、速度3000m/分のワインダーに巻き取った。15dtex/1フィラメントの丸断面形状の高強度ポリエステルモノフィラメントを得た。
【0024】
実施例2
吐出量を変更した以外は実施例1と同様に行い、繊度27dtexのモノフィラメントを得た。
【0025】
比較例1
吐出量を変更し、延伸倍率を5.0倍とした以外は実施例1と同様に行い、繊度を50dtexのモノフィラメントを得た。
【0026】
比較例2
第2ローラの温度を80℃に加熱し、スチームを吹き付けず第3ローラとの間で延伸倍率4.4倍の延伸を行った以外は、実施例1と同様に行った。
【0027】
比較例3
第2ローラの温度100℃に加熱し、スチームを吹き付けず第3ローラとの間で延伸倍率4.6倍の延伸を行った以外は、比較例2と同様に行った。
【0028】
実施例1〜2、比較例1〜3で得られたポリエステルモノフィラメントの物性値を表1に示す。
【0029】
【表1】

Figure 2004052173
【0030】
表1から明らかなように、実施例1〜2で得られたモノフィラメントは本発明で規定する繊度、切断強度、密度の物性を満足するものであり、操業性よく得ることができた。
一方、比較例1で得られたモノフィラメントは繊度が太いために、切断強度が低く、密度も低いものであった。また、比較例2〜3ではスチーム延伸を行なわずに、引き揃えローラを加熱してローラ延伸を行ったので、比較例2では引き揃えローラ上での糸揺れを抑えるため、安定操業が可能な温度に設定したが、温度不足のために延伸倍率が低下し、切断強度の劣るモノフィラメントとなった。また、比較例3は延伸倍率を高くするために、引き揃えローラの加熱温度を高くしたために糸揺れが大きくなり、延伸できず、モノフィラメントを得ることができなかった。
【0031】
【発明の効果】
本発明のポリエステルモノフィラメントは、スピンドロー法で得られるものであるため、コストを低く、効率よく得ることができるものであり、細繊度でかつ切断強度の高いものであるので、スクリーン紗用の繊維として好適で、加工性や取扱い性に優れている。
そして、本発明の製造方法によれば、延伸に必要な温度に十分に加熱することができ、操業性よく本発明のモノフィラメントを得ることが可能となる。
【図面の簡単な説明】
【図1】本発明の高強度ポリエステルモノフィラメントの製造方法の一実施態様を示す概略工程図である
【符号の説明】
Y 未延伸糸
1 第1ローラ
2 第2ローラ
3 第3ローラ
4 第4ローラ
5 第5ローラ
6 ワインダー
7 スチーム処理機[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a high-strength polyester monofilament having fineness suitable for use in industrial materials such as screen gauze, and a method for producing the same.
[0002]
[Prior art]
2. Description of the Related Art Conventionally, polyester is excellent in dimensional stability and versatility, and thus is processed into a fibrous form such as a multifilament or a monofilament, and is widely used for clothing and industrial materials.
[0003]
As a fiber used for screen gauze, which is one of the uses, importance has been placed on dimensional stability, and natural fibers such as silk and inorganic fibers such as stainless steel have been conventionally used. However, those processed into fibers such as polyamide and polyester, which are excellent in productivity, are inexpensive and versatile. Among them, monofilaments containing polyester as the main component have little dimensional change due to moisture, etc., dimensional stability and heat resistance. In recent years, it has been widely used.
[0004]
JP-A-5-286277 discloses a polyester monofilament for screen gauze having a strength at an elongation of 2% of 1.7 g / d or more. Japanese Patent Publication No. 295617 proposes a manufacturing method by a spin draw method.
[0005]
However, according to these monofilaments and the production method, the cutting strength of the polyester monofilament is not regarded as important. Therefore, yarn breakage occurs due to the low cutting strength during weaving of screen gauze fabrics or handling of products. It was not a material having satisfactory properties in terms of workability and handleability.
[0006]
[Problems to be solved by the invention]
An object of the present invention is to solve the above problems and provide a high-strength polyester monofilament which is suitable as a fiber for screen gauze and excellent in processability and handleability, and a method for producing the same. It is.
[0007]
[Means for Solving the Problems]
The present inventors have conducted intensive studies to solve the above-mentioned problems, and as a result, have reached the present invention.
That is, the present invention has the following (a) and (b).
(A) A spin draw method in which a polyester polymer is spun from a melt spinneret, cooled, applied with an oil agent, taken up, and continuously stretched without being wound up, and wound up at 1500 m / min or more. A high-strength polyester monofilament which is obtained and has the following characteristics (1) to (3).
(1) Fineness (dtex) = 10 to 40
(2) Density (g / cm 3 ) ≧ 1.380
(3) Cutting strength (cN / dtex) ≧ 8.0
(B) The method for producing a monofilament according to (a), wherein the stretching is performed while spraying steam during the stretching.
[0008]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the present invention will be described in detail.
As the polyester polymer forming the high-strength polyester monofilament of the present invention, polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate and the like can be used, among which dimensional stability and heat resistance are excellent, and versatility and cost considerations To polyethylene terephthalate (hereinafter referred to as PET).
[0009]
In addition, a matting agent, a water-repellent agent, an antistatic agent, a surface modifier, a flame retardant, a pigment, a coloring agent, etc. may be used in the polyester polymer as long as the original properties and the spinning properties are not impaired. Or a copolymer material may be contained.
[0010]
Further, the intrinsic viscosity [η] is preferably 0.8 to 1.0, and if it is less than 0.8, the strength tends to be low, and the abrasion resistance is also poor, which is not preferable. On the other hand, if it exceeds 1.0, the heat shrinkage rate becomes high and the dimensional stability becomes poor, which is not preferable.
[0011]
The high-strength monofilament of the present invention needs to have a fineness of 10 to 40 dtex, preferably 10 to 30 dtex. When the fineness is less than 10 dtex, productivity and stretchability become poor. On the other hand, if it exceeds 40 dtex, it is thought that the difference in the degree of orientation and crystallinity between the central part and the outer layer part in the cross section of the monofilament increases, but the monofilament has low strength.
[0012]
Next, the density of the monofilament is set to 1.380 g / cm 3 or more, and preferably 1.385 g / cm 3 or more. If the density is less than 1.380 g / cm 3 , it is difficult to make the cutting strength of the monofilament 8.0 cN / dtex or more.
[0013]
The monofilament of the present invention has a cutting strength of 8.0 cN / dtex or more, preferably 8.5 cN / dtex or more, more preferably 9.0 cN / dtex or more. If it is less than 8.0 cN / dtex, the fineness is too small to easily break the yarn, resulting in poor workability, handleability, or durability. In addition, the applications to be used are limited, and it is not suitable for screen gauze.
[0014]
The high-strength polyester monofilament of the present invention can be produced using a conventional melt spinning apparatus. However, after drawing, it is continuously drawn without being wound once, and is drawn at 1500 m / min or more. It is obtained by law. If the winding speed is less than 1500 m / min, the productivity is inferior, which is not preferable.
[0015]
The cross-sectional shape of the monofilament of the present invention may be an irregular shape such as a polygonal shape. However, it is preferable that the monofilament has a round cross-sectional shape from the viewpoint of high strength and wear resistance.
[0016]
Then, in the production method of the present invention, stretching (steam stretching) is performed while spraying steam at the time of stretching. That is, when a polyester multifilament or a polyester monofilament is drawn by the spin draw method, usually, the take-up roller or the draw-out roller is heated to a temperature of TG (glass transition point) or higher to improve the drawability of the undrawn yarn. It is intended. However, when a monofilament of fineness is manufactured by this method, the shrinkage force of the fineness monofilament due to spinning orientation or heat treatment before drawing is small, and therefore, the yarn looseness on the roller surface of the heated take-up roller or the aligning roller is reduced. Because of this, yarn sway occurs, making it difficult to thread with the number of wraps required for uniform heat treatment, and making it possible to set the heating temperature required for high-magnification stretching that is commonly used to increase strength. There is a problem that the polyester monofilament disappears or the drawability is poor, and as a result, it is difficult to produce a high-strength polyester monofilament with good operability.
[0017]
Therefore, in the present invention, the stretching is performed while spraying steam at the time of stretching, in order to enable stretching at a high magnification while sufficiently heat treating the polyester monofilament having a fine fineness. Thereby, even when the take-up roller and the aligning roller before performing the steam heat treatment are not heated, stretching at a high magnification can be performed.
[0018]
In the steam drawing, the steam is continuously blown directly onto the yarn to perform drawing.However, the shape and the spraying method of the steam processing machine used as the spraying device are not particularly limited, and, for example, are arranged symmetrically. A method of spraying steam at an angle of 30 to 60 ° from two orifices having a diameter of 1.0 to 3.0 mm toward the traveling direction of the yarn. Further, the pressure and temperature of the steam are preferably in the range of 0.05 to 0.2 Mpa and 200 to 400 ° C., and are preferably set appropriately within this range according to the stretching speed and the fineness.
[0019]
In the present invention, the steam stretching is preferably performed by spraying steam between the take-up roller or the aligning roller and the heating roller as described above, and then performing stretching between the rollers. In addition, a plurality of stretching rollers may be installed after the steam heat treatment, and multi-stage stretching may be performed. However, the stretching tension in the second and subsequent stages is likely to be high and yarn breakage is likely to occur. Is not included).
[0020]
The stretching ratio is preferably in the range of 3.0 to 6.0, and is preferably set appropriately within this range according to the stretching speed and fineness. In addition, it is preferable that the heating roller that takes out the yarn subjected to the steam heat treatment and performs stretching is a heating roller at 150 to 250 ° C. in consideration of stretchability.
[0021]
Next, a method for producing a high-strength polyester monofilament of the present invention will be described with reference to the drawings. FIG. 1 is a schematic process chart showing one embodiment of the production method of the present invention.
First, the spun yarn is cooled and applied with an oil agent, and thereafter, is unwound as a non-drawn yarn Y by first hanging it over the unheated first roller 1 a plurality of times, and subsequently unheated second roller 1 2 is multiplied a plurality of times to perform the alignment of 1.005 to 1.05 times. Subsequently, after steam is sprayed by the steam processing machine 7, the film is stretched by being applied to the third roller 3 heated to 150 to 250 ° C. a plurality of times, and then to the fourth roller 4 heated to 150 to 250 ° C. After applying a relaxation heat treatment of 3 to 10% by applying a plurality of times, it is applied to the non-heated fifth roller 5 by a plurality of times and is taken up at a relaxation rate of 0 to 5%, and is wound around a winder 6 at a speed of 1500 m / min or more.
[0022]
【Example】
Next, the present invention will be described specifically with reference to examples.
In addition, each physical property value in an Example was measured by the following method.
(A) Intrinsic Viscosity of PET Using an equal weight mixture of phenol and ethane tetrachloride as a solvent, the measurement was performed at a concentration of 0.5 g / dl and a temperature of 20 ° C.
(B) Cutting strength and cutting elongation Measured according to JISL-1017, using a Shimadzu Autograph DSS-500 at a sample length of 25 cm and a tensile speed of 30 cm / min.
(C) Density The density was measured at 25 ° C. according to JISL-1013 by a density gradient tube method.
[0023]
Example 1
A conventional melt spinning apparatus having a hole diameter of 0.6 mm and 8 holes was attached to a conventional melt spinning apparatus, and a PET chip having an intrinsic viscosity [η] of 1.03 was spun at a temperature of 300 ° C. and a length of 20 cm. After passing through a heating cylinder having a wall surface temperature of 300 ° C., cooling was performed by blowing cooling air at a temperature of 15 ° C. and a speed of 0.6 m / sec using a horizontal cooling device having a cooling length of 150 cm. After applying the oil agent, the unheated first roller is applied twice to take it off, and then the unheated second roller is applied three times to perform 1.03 times alignment, and then between the third roller and the unheated second roller. Using a symmetrically disposed orifice diameter of 1.2 mm and a blowing angle of 45 °, a steam heat treatment machine for eight ends, steam of 380 ° C. and pressure of 0.12 MPa was sprayed on each monofilament. Then, the film was stretched 4.8 times by applying it to a third roller at a temperature of 210 ° C. three times. Subsequently, a relaxation heat treatment of 2% is performed by applying the heat to the fourth roller at a temperature of 200 ° C. three times, and then the heat treatment is performed at a speed of 3015 m / min four times by a non-heated fifth roller at a relaxation rate of 1.3%. It was wound on a winder of 3000 m / min. A high-strength polyester monofilament having a round cross-sectional shape of 15 dtex / 1 filament was obtained.
[0024]
Example 2
A monofilament having a fineness of 27 dtex was obtained in the same manner as in Example 1 except that the discharge amount was changed.
[0025]
Comparative Example 1
A monofilament having a fineness of 50 dtex was obtained in the same manner as in Example 1 except that the discharge amount was changed and the stretching ratio was set to 5.0 times.
[0026]
Comparative Example 2
The procedure was performed in the same manner as in Example 1 except that the temperature of the second roller was heated to 80 ° C., and the stretching was performed at a stretching ratio of 4.4 times with the third roller without spraying steam.
[0027]
Comparative Example 3
The procedure was performed in the same manner as in Comparative Example 2 except that the second roller was heated to 100 ° C. and stretched 4.6 times with the third roller without spraying steam.
[0028]
Table 1 shows the physical property values of the polyester monofilaments obtained in Examples 1 and 2 and Comparative Examples 1 to 3.
[0029]
[Table 1]
Figure 2004052173
[0030]
As is clear from Table 1, the monofilaments obtained in Examples 1 and 2 satisfy the physical properties of fineness, cutting strength and density specified in the present invention, and were obtained with good operability.
On the other hand, since the monofilament obtained in Comparative Example 1 had a large fineness, the monofilament had low cutting strength and low density. Further, in Comparative Examples 2 and 3, since the drawing roller was heated and the roller was drawn without performing the steam drawing, in Comparative Example 2, the yarn sway on the drawing roller was suppressed, so that stable operation was possible. Although the temperature was set, the draw ratio was lowered due to insufficient temperature, and a monofilament having poor cutting strength was obtained. In Comparative Example 3, since the heating temperature of the drawing roller was increased in order to increase the draw ratio, the yarn sway was increased, and the drawing could not be performed, and a monofilament could not be obtained.
[0031]
【The invention's effect】
Since the polyester monofilament of the present invention is obtained by the spin draw method, the cost is low, and it can be obtained efficiently. And is excellent in processability and handleability.
According to the production method of the present invention, the monofilament of the present invention can be sufficiently heated to a temperature required for stretching, and has good operability.
[Brief description of the drawings]
FIG. 1 is a schematic process diagram showing one embodiment of a method for producing a high-strength polyester monofilament of the present invention.
Y Undrawn yarn 1 First roller 2 Second roller 3 Third roller 4 Fourth roller 5 Fifth roller 6 Winder 7 Steam processing machine

Claims (2)

ポリエステルポリマーを、溶融紡糸口金より紡出した後、冷却し、油剤を付与して引き取り、一旦巻き取ることなく連続して延伸を行いながら、1500m/分以上で巻き取るスピンドロー法で得られるモノフィラメントであって、下記(1)〜(3)の特性を有していることを特徴とする高強度ポリエステルモノフィラメント。
(1)繊度(dtex)  =10〜40
(2)密度(g/cm) ≧1.380
(3)切断強度(cN/dtex) ≧8.0
A monofilament obtained by spin-drawing, in which a polyester polymer is spun from a melt spinneret, then cooled, an oil agent is applied and taken off, and the film is wound at 1500 m / min or more while being continuously stretched without being wound. A high-strength polyester monofilament having the following characteristics (1) to (3).
(1) Fineness (dtex) = 10 to 40
(2) Density (g / cm 3 ) ≧ 1.380
(3) Cutting strength (cN / dtex) ≧ 8.0
請求項1記載のモノフィラメントの製造方法であって、延伸時にスチームを吹き付けながら延伸を行うことを特徴とする高強度ポリエステルモノフィラメントの製造方法。The method for producing a monofilament according to claim 1, wherein the stretching is performed while spraying steam during the stretching.
JP2002212499A 2002-07-22 2002-07-22 High-strength polyester monofilament and method for producing the same Pending JP2004052173A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006169680A (en) * 2004-12-17 2006-06-29 Toray Ind Inc Method for producing polyester monofilament for screen gauze and monofilament
JP2010084272A (en) * 2008-09-30 2010-04-15 Toray Ind Inc Method for producing fine polyester monofilament
JP2011006799A (en) * 2009-06-23 2011-01-13 Teijin Fibers Ltd Polyester monofilament for screen gauze and method for producing the same
JP2011006800A (en) * 2009-06-23 2011-01-13 Teijin Fibers Ltd Polyester monofilament for screen gauze and method for producing the same
CN111719190A (en) * 2020-06-23 2020-09-29 陈志祥 Production process of superfine denier single-board ring-blown POY

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006169680A (en) * 2004-12-17 2006-06-29 Toray Ind Inc Method for producing polyester monofilament for screen gauze and monofilament
JP2010084272A (en) * 2008-09-30 2010-04-15 Toray Ind Inc Method for producing fine polyester monofilament
JP2011006799A (en) * 2009-06-23 2011-01-13 Teijin Fibers Ltd Polyester monofilament for screen gauze and method for producing the same
JP2011006800A (en) * 2009-06-23 2011-01-13 Teijin Fibers Ltd Polyester monofilament for screen gauze and method for producing the same
CN111719190A (en) * 2020-06-23 2020-09-29 陈志祥 Production process of superfine denier single-board ring-blown POY

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