JP2004018705A - Synthetic resin composition for accessory, and accessory - Google Patents

Synthetic resin composition for accessory, and accessory Download PDF

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Publication number
JP2004018705A
JP2004018705A JP2002176736A JP2002176736A JP2004018705A JP 2004018705 A JP2004018705 A JP 2004018705A JP 2002176736 A JP2002176736 A JP 2002176736A JP 2002176736 A JP2002176736 A JP 2002176736A JP 2004018705 A JP2004018705 A JP 2004018705A
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JP
Japan
Prior art keywords
synthetic resin
accessory
germanium
resin composition
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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JP2002176736A
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Japanese (ja)
Inventor
Masamichi Nozawa
野沢 正美智
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ASAHI JEWELRY KK
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ASAHI JEWELRY KK
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Application filed by ASAHI JEWELRY KK filed Critical ASAHI JEWELRY KK
Priority to JP2002176736A priority Critical patent/JP2004018705A/en
Publication of JP2004018705A publication Critical patent/JP2004018705A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61NELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N5/00Radiation therapy
    • A61N5/06Radiation therapy using light
    • A61N2005/0658Radiation therapy using light characterised by the wavelength of light used
    • A61N2005/0659Radiation therapy using light characterised by the wavelength of light used infrared
    • A61N2005/066Radiation therapy using light characterised by the wavelength of light used infrared far infrared

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a synthetic resin composition for use in an accessory that has both health promotion function and/or curing function due to the far-infrared effect of germanium and silica, the far-infrared and negative ion effects of tourmaline and a radioactive substance added to intensify the effects. <P>SOLUTION: The synthetic resin composition (100wt%) contains 1-30wt% of germanium, 1-10wt% of tourmaline, 0-10wt% of silica and 1-30wt% of the radioactive substance based on the synthetic resin. The composition is an element for a health accessory and is molded in a shape which fits into a recess formed on the accessory. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は合成樹脂を主たる構成成分とする装身具用合成樹脂組成物とこれを用いた装身具に関するものである。
【0002】
【従来の技術】
ゲルマニウムを一つの成分とする装身具用組成物として、特開昭53−43620号公報、特開昭62−20850号公報、特開昭63−14830号公報、特開2000−144283号公報などがある。しかるに、これらはいずれも銀合金であり、ゲルマニウムの他にインジウム、パラジウム、亜鉛、ボロンなどが配合されている。
【0003】
しかるに、これらで開示された装身具用の銀合金については、次のような問題がある。まず、特開昭53−43620号の銀合金については酸化しやすく、また、特開昭62−20850号の銀合金については物質的に不安定であり、さらに、特開昭63−14830号の銀合金については高価になってしまう。特開2000−144283号における銀合金にあっても健康増進の効果の面でなお改良が必要といわれている。
【0004】
一方、この種の装身具としては、指輪やピアスのように身体を装飾するもの、あるいは腕時計のベルトのように物品を身体に装着するものがあり、この他には、健康増進や一定の治療・治癒効果を目的とする装身具が知られているが、通常は、主成分としてはゲルマニウム鉱物がそのまま用いられており、指輪やピアスのような身体の装飾を目的として種々の形に加工することはなかなかできないものである。
【0005】
【発明が解決しようとする課題】
本発明者は、以上の従来技術に鑑みて鋭意開発を行い、装飾に好適な機能と健康増進あるいは治療・治癒機能を兼ね備えた装身具の素材に好適な装身具用合成樹脂組成物及びこれを用いた装身具を提供するものである。
【0006】
【課題を解決するための手段】
本発明の第1は、合成樹脂100重量%に対し、ゲルマニウム1〜30重量%、これにトルマリン0〜20重量%、シリカ0〜20重量%含まれていることを特徴とする装身具用合成樹脂組成物であり、これに放射性鉱物1〜30重量%が含まれるのが好ましい。用いられる合成樹脂は、加工のしやすさや値段の点を加味してシリコン樹脂、ナイロン樹脂、ウレタン樹脂が好んで採用される。これらの樹脂はゲルマニウムなどや放射性鉱物を粉末化した際にかなり多くの量が充填できるという特徴があり、人体に接触してもアレルギ−などを引き起こさないという特徴もある。
【0007】
各配合成分における好ましい範囲は、合成樹脂100重量%に対し、ゲルマニウム3〜15重量%、トルマリン3〜10重量%、シリカ3〜10重量%、放射性鉱物3〜15重量%である。
【0008】
本発明の第2は、身体に装用した状態で、皮膚に接触する外表面の一部又は全部が、前記装身具用合成樹脂組成物で構成されていることを特徴とする装身具である。
【0009】
【発明の実施の形態】
本発明は、ゲルマニウム、トルマリン、シリカの遠赤外効果、ゲルマニウム、トルマリンのマイナスイオン効果、そして、これらの効果をさらに増すために放射性物質を加えたことによってなるものであり、本発明の装身具用合成樹脂組成物及び装身具は、健康増進あるいは治療・治癒機能を兼ね備え、加工性が容易であること、身体に対してアレルギ−などを引き起こさないという安全な材料であるなどの特徴がある。
【0010】
本発明の特徴は、第1のゲルマニウムが有する遠赤外効果、つまり、肩凝り等を治療・治癒する健康増進、治療効果は、基材中でゲルマニウムの微結晶が形成されているときに特に効果的に発揮される。ゲルマニウムの微結晶は微小ながらも結晶であることから、半導体的な性質を持つためであり、特にP型の場合にその効果は大きい。
【0011】
ゲルマニウムを加えたことによる遠赤外効果としては、身体を温め血行を良くするという効果、つまり、肩凝り等を治療・治癒する健康増進、鎮痛や消炎等の治療効果は、特にP型の場合にその効果は大きい。ゲルマニウムは単結晶、多結晶あるいはアモルファスのいずれでも良く、これらの微細粉末を樹脂で成形したものでも良い。
【0012】
ゲルマニウムは、後述する放射性鉱物の添加と相まって、遠赤外線を放射し、これが皮膚を通して人体に作用することにより鎮痛や消炎等のような健康促進・治療等の効果をもたらす。赤外線が生体に照射された場合には、吸収したエネルギーにより生体内で温度上昇が起り、いわゆる温熱効果が発揮される。ところが、波長が100ミクロン程度の遠赤外線の場合には、上記の熱作用に加えて、照射された微弱な電磁波が生体に直接作用し、いわゆる非熱作用が発揮されると言われており、この波長帯の遠赤外線は生体内で大きな減衰を受け、遠赤外線による直接的な非熱作用が及ぶ範囲は皮膚及びその直下の細胞に限定される。しかし、毛細血管や細胞間の物質代謝を通して間接的に、より深い人体内に作用が及ぶので、健康促進や治療等の効果を発揮させることが可能になるものである。なお、後述する放射性鉱物によってマイナスイオンの発生も促され、これによる特徴も付加される。
【0013】
第2のトルマリンは、結晶体で電気石とも言われ、代表的化学式は、3{NaX Al(BO Si O16( OHF)}(X=Mg、Fe、Li)である。このトルマリン結晶体の特性は上記した遠赤外効果だけではなく、各種の優れた特性があり、例えば、トルマリン結晶体の電気特性によりマイナスイオンを発生する特性があり、上記した遠赤外効果などの特性を合わせて活用することによって、血行の促進・改善、細胞の活性化、活性酸素の排除、血液の浄化・弱アルカリ化、体細胞の新陳代謝の促進、免疫機能や自然治癒力の向上等々といった人体の健康増進に優れた効能が得られる。
【0014】
尚、遠赤外効果を有する素材として、安価な第3のシリカも用いることが可能であり、得られた合成樹脂組成物も安価になるという特徴がある。
【0015】
勿論、従来の合成樹脂に用いられる種々の副資材がそのまま配合され得ることは当然であり、装身具としての硬度を調整したり、腐食を抑えたり、加工性を高めたりすることも可能である。
【0016】
第4にゲルマニウム、トルマリン、シリカの遠赤外線の放射を活発にするため、更にはゲルマニウム、トルマリンから発するマイナスイオンの促進のため、放射線鉱物を含ませたものであり、放射性鉱物は、例えばウラン、トリウム、イットリウムなどの放射性元素を含む鉱物である。その例としては、燐灰ウラン石、ベタフォ石、カルノ−石、ユ−クセン石、フェルグソン石、ガドリン石、グリファイト石、メタ燐重土ウラン石、モナズ石、サマルスキ石、閃ウラン鉱、ウラノビライト、ウラノトリアナイト、ゼノタイムなどが挙げられる。これらから放出する放射線により特にゲルマニウムの遠赤外線の放射は更に活発となり、優れた鎮痛や消炎等の効果をもたらすものである。
【0017】
なお、配合割合の低い場合にはその効果は十分でなく、一方、配合割合の高い組成にあっては、合成樹脂への混入に手間取ったり、樹脂がもろくなったり、ひび割れが生じやすくなるという欠点があり配合割合に限界がある。
【0018】
第2発明の装身具は、皮膚に接触する外表面の一部又は全部が上記の装身具用合成樹脂で構成されていることを特徴とするもので、かかる装身具としては、例えばネックレス、ブレスレット、バングル、指輪などがあるが、ビ−ズ状の球体を多数作成し、これを適当な糸にて繋ぎ合わせた装身具も例示される。尚、装身具全体が本発明の装身具用合成樹脂で形成されていても、表面のみを本発明の装身具用合成樹脂で構成されていても良い。装身具そのものを形どる場合には、モ−ルド内に合成樹脂の架橋前の半液状体を充填し、これを架橋させて装身具を構成することになる。
【0019】
【実施例】
以下、実施例をもって更に詳細に説明する。
図1は本発明の装身具としてのバングルAであり、装身具用素子に適用した例である。図2はその一部断面図である。連接された装身具駒1、1、‥の内側(身体に接触する側)には円形の窪み2が形成されており、これに本発明の素子10が嵌め込まれ、接着剤などによって固定される。
【0020】
図3は本発明の合成樹脂組成物にて形成した素子の一例を示す斜視図であり、全体がタブレット状をなしている。この素子を形成する材料としては、シリコン樹脂100重量%に対し、ゲルマニウム10重量%、トルマリン5重量%、シリカ5重量%、放射性鉱物(ベタフォ石)10重量%が含まれており、装身具における窪みに嵌入可能なタブレット型に形成したものである。なお、各成分は粒子径0.1mm以下の粉末状とし、シリコン樹脂が架橋する前の半液状の時に混入し前記粉末が均一になるように攪拌し、その後、所定のモ−ルド内に注入して加圧下にて架橋し、素子10を得たものである。
【0021】
図4は全体が例えば18Kによって構成されるバングルBであり、その内周側に間隔をもって前記の例で示した素子10が取り付けられている。この素子10もバングルBに設けた溝内に嵌め合わされている。
【0022】
なお、前記した装身具駒1やバングルBそのものを本発明の合成樹脂にて構成することも可能であり、勿論、他の装身具を得ることも可能であり、合成樹脂の柔軟性を利用して断面が円形、楕円形、正方形、長方形などの環状のネックレスやブレスレットとすることもできる。
【0023】
図4は更に別例の装身具の例であり、上記合成樹脂組成物により球体(直径5mm)21を形成しこれにワイヤ−22を通してネックレス20を制作した。
【0024】
このネックレス20を用いて遠赤外効果を試験した。室温(22℃)の環境で43歳の男性の首にネックレスをかけて10分間放置し、サーモグラフィ(温度分解能:0.1℃、アビオニクス社製)で正面から皮膚温度を観察した。
合成樹脂中の配合がゲルマニウムのみであるが場合、0.7℃の温度上昇が見られた。次に放射性好物のみを配合した場合には0.2〜0.3℃の温度上昇が見られた。最後に本発明の場合には、1℃の温度上昇が見られ、その効果が確認できた。
【0025】
【発明の効果】
本発明によれば、合成樹脂内に配合したゲルマニウム、トルマリン、シリカによる遠赤外効果やマイナスイオンの発生によって人体における肩こりの解消や鎮痛や消炎等のような健康促進・治療等の効果が発揮でき、特に放射性好物を配合したことにより遠赤外効果が増進されることとなり、装飾機能と健康志向機能を兼ね備えた樹脂組成物及びこれを材料とした装身具が得られた。
【図面の簡単な説明】
【図1】図1は本発明によって得られた素子を用いた装身具である。
【図2】図2はその一部断面図である。
【図3】図3は本発明によって得られた素子を用いた別の装身具である。
【図4】図4は本発明によって得られた素子の斜視図である。
【図5】図5は本発明によって得られた装身具の斜視図である。
【符号の説明】
1‥装身具駒、
2‥装身具駒に形成した窪み、
10‥装身具用素子、
20‥装身具(ネックレス)
A、B‥バングル。
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a synthetic resin composition for jewelry containing a synthetic resin as a main component, and an ornament using the same.
[0002]
[Prior art]
JP-A-53-43620, JP-A-62-20850, JP-A-63-14830, JP-A-2000-144283, and the like include compositions for accessories that contain germanium as one component. . However, these are all silver alloys, and contain indium, palladium, zinc, boron, and the like in addition to germanium.
[0003]
However, the silver alloys for accessories disclosed in these publications have the following problems. First, the silver alloy of JP-A-53-43620 is easily oxidized, and the silver alloy of JP-A-62-20850 is materially unstable. Silver alloys are expensive. It is said that the silver alloy disclosed in JP-A-2000-144283 is still required to be improved in terms of health promotion effects.
[0004]
On the other hand, there are ornaments of this type that decorate the body such as rings and earrings, or those that attach articles to the body like a belt of a wrist watch. Jewelry aimed at healing effects is known, but usually, the main component is germanium mineral as it is, and it is not possible to process it into various shapes for the purpose of decorating the body such as rings and earrings It is not easy to do.
[0005]
[Problems to be solved by the invention]
The present inventor has made intensive developments in view of the above prior art, and used a synthetic resin composition for an accessory suitable for a material of an accessory having both a function suitable for decoration and a health promotion or treatment / healing function, and using the same. It is to provide accessories.
[0006]
[Means for Solving the Problems]
According to a first aspect of the present invention, there is provided a synthetic resin for jewelry, comprising 1 to 30% by weight of germanium, 0 to 20% by weight of tourmaline, and 0 to 20% by weight of silica based on 100% by weight of the synthetic resin. Composition, preferably containing 1 to 30% by weight of the radioactive mineral. As the synthetic resin to be used, silicon resin, nylon resin, and urethane resin are preferably used in consideration of ease of processing and price. These resins are characterized in that they can be filled in a considerably large amount when powdered of germanium or the like or radioactive minerals, and have the characteristic that they do not cause allergies even when they come into contact with the human body.
[0007]
The preferred ranges of the respective components are 3 to 15% by weight of germanium, 3 to 10% by weight of tourmaline, 3 to 10% by weight of silica, and 3 to 15% by weight of radioactive mineral with respect to 100% by weight of the synthetic resin.
[0008]
A second aspect of the present invention is an accessory which is characterized in that, when worn on the body, a part or all of the outer surface that comes into contact with the skin is made of the synthetic resin composition for accessory.
[0009]
BEST MODE FOR CARRYING OUT THE INVENTION
The present invention, the far-infrared effect of germanium, tourmaline, silica, the negative ion effect of germanium, tourmaline, and, by adding a radioactive material to further enhance these effects, for the accessory of the present invention The synthetic resin composition and accessories are characterized by having a function of promoting health or treating and healing, being easy to process, and being a safe material that does not cause allergies to the body.
[0010]
A feature of the present invention is that the far-infrared effect of the first germanium, that is, health promotion for treating and healing stiff shoulders and the like, and the therapeutic effect is particularly effective when microcrystals of germanium are formed in the base material. Effectively demonstrated. This is because germanium microcrystals have a semiconductor property because they are small but crystalline, and the effect is particularly large in the case of P-type.
[0011]
As far-infrared effects by adding germanium, the effect of warming the body and improving blood circulation, that is, the health promotion effect of treating and healing stiff shoulders, and the therapeutic effect of analgesia and anti-inflammatory, especially in the case of P-type The effect is great. Germanium may be any of single crystal, polycrystal or amorphous, and may be formed by molding these fine powders with a resin.
[0012]
Germanium emits far-infrared rays in combination with the addition of a radioactive mineral, which will be described later, and acts on the human body through the skin, thereby providing health promotion / treatment such as analgesia and anti-inflammation. When the living body is irradiated with infrared rays, a temperature rise occurs in the living body due to the absorbed energy, and a so-called thermal effect is exhibited. However, in the case of far-infrared light having a wavelength of about 100 microns, it is said that, in addition to the above-mentioned heat effect, the applied weak electromagnetic wave directly acts on the living body, so-called non-heat effect is exerted. Far-infrared rays in this wavelength band are greatly attenuated in vivo, and the range of direct non-thermal action by far-infrared rays is limited to the skin and cells immediately below it. However, the effect is deeper in the human body indirectly through the metabolism of substances between capillaries and cells, so that effects such as health promotion and treatment can be exhibited. In addition, the generation of negative ions is promoted by the radioactive mineral described later, and a feature due to this is also added.
[0013]
The second tourmaline is crystalline and also called tourmaline, and its typical chemical formula is 3 {NaX 3 Al 6 (BO 3 ) 3 Si 6 O 16 (OHF) 4 } (X = Mg, Fe, Li) is there. The properties of this tourmaline crystal have not only the above-mentioned far-infrared effect but also various excellent properties.For example, there is a property of generating negative ions due to the electric properties of the tourmaline crystal, and the above-mentioned far-infrared effect and the like. Utilizing the characteristics of the two together, it promotes and improves blood circulation, activates cells, eliminates active oxygen, purifies blood and weakens alkali, promotes metabolism of somatic cells, improves immune function and natural healing power, etc. It is possible to obtain excellent effects on promoting human health.
[0014]
In addition, as a material having the far-infrared effect, inexpensive third silica can be used, and the resulting synthetic resin composition has a feature of being inexpensive.
[0015]
Of course, it is natural that various auxiliary materials used in the conventional synthetic resin can be blended as it is, and it is also possible to adjust the hardness of the accessory, suppress corrosion, and enhance workability.
[0016]
Fourth, germanium, tourmaline, and radioactive minerals are included in order to activate far-infrared radiation of silica and further to promote negative ions emitted from germanium and tourmaline. The radioactive minerals include, for example, uranium, It is a mineral containing radioactive elements such as thorium and yttrium. Examples include apatite uranium, betapheite, carnolite, uxenite, feldssonite, gadolinite, glyphiteite, metaphosphate heavy uranium, monazite, samarskiite, uraniumite, uranovirite , Uranotrianite, xenotime and the like. Radiation emitted from these elements makes the radiation of far-infrared rays of germanium particularly active and brings about effects such as excellent analgesia and anti-inflammation.
[0017]
In addition, when the compounding ratio is low, the effect is not sufficient.On the other hand, in a composition having a high compounding ratio, it takes time to mix into the synthetic resin, the resin becomes brittle, and cracks are easily generated. There is a limit on the mixing ratio.
[0018]
The accessory of the second invention is characterized in that part or all of the outer surface that comes into contact with the skin is made of the above-described synthetic resin for accessories, and examples of such accessories include a necklace, a bracelet, a bangle, and the like. Although there are rings and the like, there is also exemplified an accessory in which a large number of bead-shaped spheres are formed and connected with an appropriate thread. The entire accessory may be formed of the synthetic resin for the accessory of the present invention, or only the surface may be formed of the synthetic resin for the accessory of the present invention. In order to form the jewelry itself, the mold is filled with a semi-liquid material of the synthetic resin before crosslinking, and this is crosslinked to form the jewelry.
[0019]
【Example】
Hereinafter, the present invention will be described in more detail with reference to examples.
FIG. 1 shows a bangle A as an accessory of the present invention, which is an example applied to an accessory for an accessory. FIG. 2 is a partial sectional view thereof. A circular depression 2 is formed inside the connected jewelry pieces 1, 1,... (Side in contact with the body), into which the element 10 of the present invention is fitted and fixed with an adhesive or the like.
[0020]
FIG. 3 is a perspective view showing an example of an element formed of the synthetic resin composition of the present invention, and has a whole tablet shape. As a material for forming this element, 100% by weight of silicon resin, 10% by weight of germanium, 5% by weight of tourmaline, 5% by weight of silica, and 10% by weight of radioactive mineral (betapholite) are included. It is formed into a tablet type that can be fitted into a tablet. Each component is in the form of a powder having a particle diameter of 0.1 mm or less, mixed when the silicone resin is in a semi-liquid state before crosslinking, and stirred so that the powder becomes uniform, and then injected into a predetermined mold. The element 10 was obtained by crosslinking under pressure.
[0021]
FIG. 4 shows a bangle B composed entirely of, for example, 18K, and the elements 10 shown in the above example are attached to the inner peripheral side thereof at intervals. This element 10 is also fitted in a groove provided in the bangle B.
[0022]
Note that the accessory piece 1 and the bangle B itself can be made of the synthetic resin of the present invention, and of course, other accessories can be obtained, and the cross section can be obtained by utilizing the flexibility of the synthetic resin. However, a circular necklace or a bracelet such as a circle, an oval, a square, and a rectangle can also be used.
[0023]
FIG. 4 shows still another example of an accessory, in which a sphere (diameter: 5 mm) 21 was formed from the above synthetic resin composition, and a necklace 20 was produced through a wire 22.
[0024]
Using this necklace 20, the far-infrared effect was tested. In a room temperature (22 ° C.) environment, a 43-year-old man was put on a necklace around his neck and allowed to stand for 10 minutes, and the skin temperature was observed from the front by thermography (temperature resolution: 0.1 ° C., manufactured by Avionics).
When the composition in the synthetic resin was only germanium, a temperature rise of 0.7 ° C. was observed. Next, when only a radioactive favorite was added, a temperature rise of 0.2 to 0.3 ° C. was observed. Finally, in the case of the present invention, a temperature rise of 1 ° C. was observed, and the effect was confirmed.
[0025]
【The invention's effect】
According to the present invention, germanium, tourmaline and silica blended in a synthetic resin exhibit effects such as far-infrared effects and negative ions that promote health and treat health such as stiff shoulders, analgesia and anti-inflammatory effects in the human body. In particular, the addition of a radioactive favorite enhances the far-infrared effect, resulting in a resin composition having both a decorative function and a health-oriented function, and an ornament using the same as a material.
[Brief description of the drawings]
FIG. 1 is an ornament using an element obtained by the present invention.
FIG. 2 is a partial cross-sectional view thereof.
FIG. 3 is another accessory using the element obtained according to the present invention.
FIG. 4 is a perspective view of an element obtained according to the present invention.
FIG. 5 is a perspective view of an accessory obtained according to the present invention.
[Explanation of symbols]
1 ‥ Jewelry pieces,
2) The depression formed in the jewelry piece,
10cm element for accessories,
20cm jewelry (necklace)
A, B @ Bangle.

Claims (4)

合成樹脂100重量%に対し、ゲルマニウム1〜30重量%、トルマリン0〜20重量%、シリカ0〜20重量%が含まれいることを特徴とする装身具用合成樹脂組成物。A synthetic resin composition for jewelry, comprising 1 to 30% by weight of germanium, 0 to 20% by weight of tourmaline, and 0 to 20% by weight of silica based on 100% by weight of the synthetic resin. 合成樹脂100重量%に対し、放射性鉱物1〜30重量%が含まれている請求項1記載の装身具用合成樹脂組成物。The synthetic resin composition for accessories according to claim 1, wherein the radioactive mineral is contained in an amount of 1 to 30% by weight based on 100% by weight of the synthetic resin. 合成樹脂がシリコン樹脂、ナイロン樹脂、ウレタン樹脂である請求項1又は2記載の装身具用合成樹脂組成物。The synthetic resin composition for an accessory according to claim 1 or 2, wherein the synthetic resin is a silicone resin, a nylon resin, or a urethane resin. 身体に装用した状態で、皮膚に接触する外表面の一部又は全部が、請求項1乃至3記載の装身具用合成樹脂組成物で構成されていることを特徴とする装身具。A personal accessory comprising a part or all of the outer surface that comes into contact with the skin when worn on the body is made of the synthetic resin composition for personal accessories according to any one of claims 1 to 3.
JP2002176736A 2002-06-18 2002-06-18 Synthetic resin composition for accessory, and accessory Pending JP2004018705A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10182626B2 (en) 2014-09-08 2019-01-22 BISCO CO., Ltd. Body ornament manufacturing method, body ornament-molding die and body ornament

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10182626B2 (en) 2014-09-08 2019-01-22 BISCO CO., Ltd. Body ornament manufacturing method, body ornament-molding die and body ornament

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