JP2003287523A - Magnetic force-type oximeter - Google Patents

Magnetic force-type oximeter

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Publication number
JP2003287523A
JP2003287523A JP2002090818A JP2002090818A JP2003287523A JP 2003287523 A JP2003287523 A JP 2003287523A JP 2002090818 A JP2002090818 A JP 2002090818A JP 2002090818 A JP2002090818 A JP 2002090818A JP 2003287523 A JP2003287523 A JP 2003287523A
Authority
JP
Japan
Prior art keywords
magnetic
strain
elastic member
magnetic force
magnetic field
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2002090818A
Other languages
Japanese (ja)
Other versions
JP3775592B2 (en
Inventor
Hideaki Yamagishi
秀章 山岸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yokogawa Electric Corp
Original Assignee
Yokogawa Electric Corp
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Filing date
Publication date
Application filed by Yokogawa Electric Corp filed Critical Yokogawa Electric Corp
Priority to JP2002090818A priority Critical patent/JP3775592B2/en
Publication of JP2003287523A publication Critical patent/JP2003287523A/en
Application granted granted Critical
Publication of JP3775592B2 publication Critical patent/JP3775592B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Investigating Or Analyzing Materials By The Use Of Magnetic Means (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a magnetic force-type oximeter whose workability and reproducibility are enhanced, which expands the degree of freedom of design, which is resistant to a vibration and a shock and whose production cost is reduced. <P>SOLUTION: The magnetic force-type oximeter is composed of a magnetic- field generation means used to generate a magnetic field from oppositely arranged magnetic poles, an elastic member installed so as to be adjacent to the magnetic poles, and a strain detection means used to detect a strain of the elastic member. The oximeter is constituted in such a way that a change in a magnetic force acting across the magnetic poles and the elastic member according to an oxygen concentration in a gas is detected by the strain detection means when the magnetic-field generation means and the elastic member are arranged in the gas containing oxygen. <P>COPYRIGHT: (C)2004,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、例えば煙道中を流
れる混合ガスに含まれる酸素濃度を測定する磁気力式酸
素計に関し、振動や衝撃に対する機能を向上させるとと
もに再現性、均一性及び製造コストを低減した磁気力式
酸素計に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a magnetic force type oximeter for measuring the oxygen concentration contained in a mixed gas flowing in a flue, for example, and has improved reproducibility, uniformity and manufacturing cost while improving the function against vibration and shock. The present invention relates to a magnetic force type oxygen meter with reduced power consumption.

【0002】[0002]

【従来の技術】混合ガス中の酸素濃度の正確な測定は、
広範囲の工業的、臨床的および研究的プロセスにおいて
重要である。そのため、酸素濃度を測定するための装置
が各種提案・開発されている。
2. Description of the Related Art Accurate measurement of oxygen concentration in a mixed gas is
Important in a wide range of industrial, clinical and research processes. Therefore, various devices for measuring the oxygen concentration have been proposed and developed.

【0003】はじめに従来例および本発明で用いる磁気
力式酸素計の測定原理について図4を用いて簡単に説明
する。図4(a)は酸素を含むガス中に磁界発生手段を
配置したときの酸素分子と磁界の関係を示している。
First, the measurement principle of the magnetic force type oxygen meter used in the conventional example and the present invention will be briefly described with reference to FIG. FIG. 4A shows the relationship between oxygen molecules and the magnetic field when the magnetic field generating means is arranged in a gas containing oxygen.

【0004】ここで酸素分子に働くX軸方向の力Fは次
式により表わすことができる。 F=χ・(∂H/∂X)・H χ:酸素の磁化率 H:磁界の強さ ∂H/∂X:磁界の変化率 つまり、図4(b)に示すように磁界が強く、かつその
強さが変化しているところ(磁極の端部 …不均一磁
界)に酸素を引付ける力が作用し、磁極の端部で右向き
の力と左向きの力が押し合ってバランスしている。図4
(c)は磁界(磁石のギャップ)内では引付けられた酸
素の圧力(濃度)が周囲に比較して高くなっている状態
を示している。
The force F acting on the oxygen molecule in the X-axis direction can be expressed by the following equation. F = χ · (∂H / ∂X) · H χ: Magnetic susceptibility of oxygen H: Strength of magnetic field ∂H / ∂X: Rate of change of magnetic field That is, the magnetic field is strong as shown in FIG. 4 (b), And the force that attracts oxygen acts on the place where the strength is changing (the end of the magnetic pole ... non-uniform magnetic field), and the rightward force and the leftward force are balanced against each other at the end of the magnetic pole. . Figure 4
(C) shows a state in which the pressure (concentration) of the attracted oxygen is higher in the magnetic field (gap of the magnet) than in the surroundings.

【0005】図2は磁気力式酸素計の従来例の検出部の
原理構成を示す図、図3(a)は図2のZ視図、図3
(b)は酸素圧力とダンベルの挙動を示す模式図であ
る。これらの図において10a,10bは先端がくさび
状に形成された2対の磁石であり、それぞれが所定の距
離(a)を隔てるとともに先端部分が所定の距離(b)
を隔てて対向して配置されている。これらの磁石には矢
印方向(図では上から下)に磁力線が生じている。
FIG. 2 is a view showing the principle configuration of a detection unit of a conventional example of a magnetic force type oxygen meter, FIG. 3 (a) is a Z view of FIG. 2, and FIG.
(B) is a schematic diagram showing the behavior of oxygen pressure and dumbbells. In these drawings, reference numerals 10a and 10b denote two pairs of magnets each having a wedge-shaped tip, each of which is separated by a predetermined distance (a) and whose tip portion is a predetermined distance (b).
Are arranged to face each other. Lines of magnetic force are generated in these magnets in the arrow direction (from top to bottom in the figure).

【0006】11(a,b)はガラス製の球のなかにN
ガス等を封入した一対のダンベル球である。これらの
ダンベル球は支持棒12の両端に固定され対向するくさ
び状磁石の先端同士を結ぶ線に対して所定の距離(c)
をずらした状態(図3a参照)で空間に水平に配置され
ている。
11 (a, b) is N in a glass ball
It is a pair of dumbbell spheres containing 2 gases. These dumbbell spheres are fixed at both ends of the support rod 12 and have a predetermined distance (c) with respect to the line connecting the tips of the wedge-shaped magnets facing each other.
Are horizontally arranged in the space in a shifted state (see FIG. 3a).

【0007】13は支持棒(ダンベル球)の中心から十
字状に設けられた支持棒で支持棒12と13が交差する
部分に光学ミラー14が固定されている。15は光源、
16はフォトダイオードであり、光源15から出射した
光が光学ミラー14に反射してフォトダイオード16に
入射するようになっている。なお、前記支持棒12,1
3は例えばPtワイヤで形成されている。
Reference numeral 13 is a support rod provided in a cross shape from the center of the support rod (dumbbell sphere), and an optical mirror 14 is fixed to a portion where the support rods 12 and 13 intersect. 15 is a light source,
Reference numeral 16 is a photodiode, and light emitted from the light source 15 is reflected by the optical mirror 14 and enters the photodiode 16. The support rods 12 and 1 are
3 is formed of, for example, a Pt wire.

【0008】上述の構成において、この酸素計をサンプ
ルガス中に配置すると、サンプルガスに含まれる酸素ガ
スは対向する磁石間で形成される磁界に引寄せられ他の
領域との間及びダンベル球に封入されたガス(実施例で
はN2)の間に密度差が発生する。
When the oximeter is placed in the sample gas in the above-mentioned configuration, the oxygen gas contained in the sample gas is attracted to the magnetic field formed between the magnets facing each other and to the other regions and to the dumbbell sphere. A density difference occurs between the enclosed gas (N2 in the example).

【0009】その結果、図3(b)に示すように、くさ
び磁石の先端付近に酸素が吸引されてその部分の酸素密
度が上昇し、ダンベル内と外に密度差が発生し、ダンベ
ル球が矢印方向に移動する力を受け、支持棒12が回転
力を受けて変位する。この変位によりミラーで反射する
光源15からの光の方向が変化しフォトダイオード16
はその変化を電気出力の変化として検出する。そして変
化の大きさはサンプルに含まれる酸素ガスに比例する。
As a result, as shown in FIG. 3 (b), oxygen is sucked in the vicinity of the tip of the wedge magnet and the oxygen density in that part rises, causing a difference in density inside and outside the dumbbell, and the dumbbell ball The support rod 12 receives the rotational force and is displaced by the force moving in the arrow direction. Due to this displacement, the direction of the light from the light source 15 reflected by the mirror changes and the photodiode 16
Detects the change as a change in electric output. The magnitude of the change is proportional to the oxygen gas contained in the sample.

【0010】[0010]

【発明が解決しようとする課題】しかしながら、上記従
来技術においては、磁気ダンベル11をガラスで形成
し、このガラス球にN2ガスを封入している。また、ダ
ンベルは白金線により支持されているので振動や衝撃に
対して極めて弱く、サンプルガスを酸素計に導入する際
の突入圧でダンベルの支持構造(図示省略)が破壊され
るという問題があった。また、ダンベル球の作製は手作
業によるものであり、加工性が悪く再現性にも問題があ
った。
However, in the above-mentioned conventional technique, the magnetic dumbbell 11 is made of glass, and N2 gas is enclosed in the glass ball. Further, since the dumbbell is supported by the platinum wire, it is extremely weak against vibration and shock, and there is a problem that the dumbbell support structure (not shown) is destroyed by the rush pressure when the sample gas is introduced into the oximeter. It was Further, the dumbbell spheres are manufactured by hand, and the processability is poor and there is a problem in reproducibility.

【0011】本発明はこのような問題点を解決するため
になされたもので、特性の優れた磁気力式の利点は損な
わずシリコンの微細加工技術利用することで、加工性と
再現性を向上させ設計の自由度を拡大させ、振動や衝撃
に強く製造コストの低減が可能な磁気力式酸素計を実現
することを目的とする。
The present invention has been made to solve the above problems, and improves the workability and reproducibility by utilizing the fine processing technology of silicon without impairing the advantages of the magnetic force type having excellent characteristics. The purpose is to realize a magnetic force type oxygen meter that expands the degree of freedom in design, is resistant to vibration and shock, and can reduce manufacturing costs.

【0012】[0012]

【課題を解決するための手段】このような問題点を解決
するために請求項1においては、磁気力式酸素計におい
て、対向して配置された磁極から磁界を発生する磁界発
生手段と、前記磁極に近接して設けられた弾性部材と、
この弾性部材の歪を検出する歪検出手段と、からなり、
これら磁界発生手段と弾性部材を酸素を含むガス中に配
置したときにガス中の酸素濃度に応じて前記磁極と弾性
部材の間に作用する磁気力変化を前記歪検出手段により
検出するように構成したことを特徴とする。
In order to solve such a problem, in a magnetic force type oximeter, a magnetic field generating means for generating a magnetic field from magnetic poles arranged facing each other is provided. An elastic member provided close to the magnetic pole,
And a strain detecting means for detecting the strain of the elastic member,
When the magnetic field generating means and the elastic member are arranged in a gas containing oxygen, a change in magnetic force acting between the magnetic pole and the elastic member is detected by the strain detecting means according to the oxygen concentration in the gas. It is characterized by having done.

【0013】請求項2においては、請求項1記載の磁気
力式酸素計において、前記弾性部材は、少なくとも一端
がシリコン基板に設けた梁により支持され、シリコンの
微細加工技術により形成されていることを特徴とする。
According to a second aspect of the present invention, in the magnetic force type oxygen meter according to the first aspect, at least one end of the elastic member is supported by a beam provided on a silicon substrate and is formed by a silicon fine processing technique. Is characterized by.

【0014】請求項3においては、請求項1記載の磁気
力式酸素計において、前記歪検出手段は拡散形半導体ス
トレンゲージ、振動式歪ゲージ、電極間容量式歪検出器
の少なくとも一つを含むことを特徴とする。
According to a third aspect of the present invention, in the magnetic force type oxygen meter according to the first aspect, the strain detecting means includes at least one of a diffusion type semiconductor strain gauge, a vibration type strain gauge, and an interelectrode capacitance type strain detector. It is characterized by

【0015】請求項4においては、請求項1記載の磁気
力式酸素計において、歪検出手段からの信号と電流回路
を用いて、前記歪を打ち消すための反力生成機構を備え
たことを特徴とする。
According to a fourth aspect of the present invention, in the magnetic force type oxygen meter according to the first aspect, a reaction force generation mechanism for canceling the strain is provided by using a signal from the strain detecting means and a current circuit. And

【0016】[0016]

【発明の実施の形態】以下、図面を用いて本発明を詳細
に説明する。図1(a,b)は本発明の実施形態の一例
を示す原理構成図であり、図(a)は要部断面構成図、
(b)は歪計測チップの要部平面構成図である。これら
の図において、1は磁界印加装置であり、この磁界印加
装置1の磁極はくさび状に形成されAで示す部分に磁界
が生じている状態を示している。
DETAILED DESCRIPTION OF THE INVENTION The present invention will be described in detail below with reference to the drawings. FIG. 1A and FIG. 1B are principle configuration diagrams showing an example of an embodiment of the present invention, and FIG.
FIG. 3B is a plan view of a principal portion of the strain measurement chip. In these drawings, reference numeral 1 denotes a magnetic field applying device, and the magnetic poles of the magnetic field applying device 1 are formed in a wedge shape and a magnetic field is generated in a portion indicated by A.

【0017】2はシリコンチップを公知のシリコン微細
加工技術により形成した歪計測チップである。この例で
はチップ2の中央部に浮子3を形成し、この浮子3を薄
肉状に形成した4本の支持梁4により支持した状態とさ
れている。5は例えば拡散半導体ストレンゲージであ
り、浮子部3の変位を最大に感じる支持梁3の根元に形
成されている。
Reference numeral 2 is a strain measurement chip formed by a known silicon microfabrication technique. In this example, the float 3 is formed in the center of the chip 2, and the float 3 is supported by four support beams 4 formed in a thin shape. Reference numeral 5 denotes, for example, a diffusion semiconductor strain gauge, which is formed at the base of the support beam 3 where the displacement of the floating portion 3 is maximized.

【0018】図では省略するがストレンゲージ5の抵抗
変化はブリッジなどの公知の電気回路を介して電気信号
として検出される。なお、磁界印加装置1は先端のくさ
び状の部分が浮子3の中心部分に位置するように配置さ
れる。
Although not shown in the figure, the resistance change of the strain gauge 5 is detected as an electric signal through a known electric circuit such as a bridge. The magnetic field applying device 1 is arranged so that the wedge-shaped portion at the tip is located at the center of the float 3.

【0019】上述の構成において、磁界発生部分にサン
プルガスを導入すると、サンプルガスに含まれる酸素濃
度に関連して酸素が磁界発生部分に引きつけられ、その
部分のガス密度が上昇する。この密度の上昇は浮子3に
対して磁気浮力を与えることとなり、図の場合浮子3を
下方に押し下げる力となる。
In the above structure, when the sample gas is introduced into the magnetic field generation portion, oxygen is attracted to the magnetic field generation portion in relation to the oxygen concentration contained in the sample gas, and the gas density of that portion increases. This increase in the density gives a magnetic buoyancy to the float 3, and in the case of the figure, it is a force to push the float 3 downward.

【0020】浮子3が下方に押し下げられると支持梁4
の根元に形成されたストレンゲージの抵抗が変化する。
この抵抗変化はブリッジなどの公知の電気回路を介して
電気信号として検出される。この場合サンプルガスは磁
石のくさび部分と浮子の間を流れるように導入され、浮
子の動きは流れるサンプルガスに含まれる酸素ガスの濃
度に対応した変位となる。
When the float 3 is pushed down, the support beam 4
The resistance of the strain gauge formed at the root of the changes.
This resistance change is detected as an electric signal through a known electric circuit such as a bridge. In this case, the sample gas is introduced so as to flow between the wedge portion of the magnet and the float, and the movement of the float causes a displacement corresponding to the concentration of oxygen gas contained in the flowing sample gas.

【0021】なお、浮子の移動は弾性体の変形に基づく
が、作用する力が増大すると変位量が比例して増大せ
ず、一般的には飽和傾向が現れる。このため高濃度酸素
計測時に、信号の飽和現象が現れるため、従来、直線化
の装置などを必要とした。これを解決する手段として、
図1(b)に示すように、歪計測チップ表面の浮子部分
に電流回路6を設け、歪検出手段からの信号とその電流
回路6を用いて、歪を打ち消すための反力生成機構を備
えることができる。
The movement of the float is based on the deformation of the elastic body, but when the acting force increases, the displacement amount does not increase proportionally, and a saturation tendency generally appears. For this reason, a signal saturation phenomenon appears when measuring high-concentration oxygen, and conventionally, a linearization device or the like has been required. As a means to solve this,
As shown in FIG. 1 (b), a current circuit 6 is provided in the float portion on the surface of the strain measuring chip, and a signal from the strain detecting means and a reaction force generating mechanism for canceling the strain by using the current circuit 6 are provided. be able to.

【0022】即ち、酸素濃度に対応して浮子3が変位す
ると歪ゲージ5に抵抗変化が生じて出力が変化する。こ
の出力変化を電気回路6にフィードバックし浮子の変位
を打ち消すような電流を流し、この電流を新たな信号と
すれば、浮子の変位を伴うことなく直線性が確保でき、
広範囲の酸素濃度を検出することができる。
That is, when the float 3 is displaced in accordance with the oxygen concentration, the strain gauge 5 changes its resistance and the output changes. If this output change is fed back to the electric circuit 6 and a current that cancels the displacement of the float is flown, and this current is used as a new signal, linearity can be secured without displacement of the float,
A wide range of oxygen concentrations can be detected.

【0023】本発明の以上の説明は、説明および例示を
目的として特定の好適な実施例を示したに過ぎない。例
えば本実施例では浮子を4本の支持梁により支持したが
1〜3でも4本以上であってもよく、ストレンゲージに
適切な電気信号が生じればよい。また、歪の検出手段と
してはストレンゲージの他、振動式歪ゲージ、電極間容
量式歪検出器を用いてもよい。したがって本発明はその
本質から逸脱せずに多くの変更、変形をなし得ることは
当業者に明らかである。特許請求の範囲の欄の記載によ
り定義される本発明の範囲は、その範囲内の変更、変形
を包含するものとする。
The foregoing description of the invention has been shown by way of illustration only of particular preferred embodiments for purposes of illustration and illustration. For example, in the present embodiment, the float is supported by four support beams, but it may be one to three or four or more as long as an appropriate electric signal is generated in the strain gauge. In addition to the strain gauge, a vibration type strain gauge or an inter-electrode capacitance type strain detector may be used as the strain detecting means. Therefore, it is obvious to those skilled in the art that the present invention can be subjected to many changes and modifications without departing from the essence thereof. The scope of the present invention, which is defined by the description in the scope of claims, includes changes and modifications within the scope.

【0024】[0024]

【発明の効果】以上述べたように、本発明によれば、対
向して配置された磁極から磁界を発生する磁界発生手段
と、前記磁極に近接して設けられた弾性部材と、この弾
性部材の歪を検出する歪検出手段と、からなり、これら
磁界発生手段と弾性部材を酸素を含むガス中に配置した
ときにガス中の酸素濃度に応じて前記磁極と弾性部材の
間に作用する磁気力変化を前記歪検出手段により検出す
るように構成したので、特性の優れた磁気力式の利点は
損なわず、シリコンの微細加工技術を利用して歪計測チ
ップを形成することで、加工性と再現性を向上させ設計
の自由度を拡大させ、振動や衝撃に強く製造コストの低
減が可能な磁気力式酸素計を実現することができる。
As described above, according to the present invention, the magnetic field generating means for generating a magnetic field from the magnetic poles arranged to face each other, the elastic member provided near the magnetic pole, and the elastic member. And a magnetic field acting between the magnetic pole and the elastic member according to the oxygen concentration in the gas when the magnetic field generating means and the elastic member are arranged in a gas containing oxygen. Since the force change is detected by the strain detecting means, the advantage of the magnetic force type having excellent characteristics is not impaired, and the strain measuring chip is formed by using the fine processing technology of silicon, thereby improving the workability. It is possible to realize a magnetic force type oxygen meter that improves reproducibility, expands the degree of freedom in design, is resistant to vibration and shock, and can reduce manufacturing costs.

【0025】[0025]

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の磁気力式酸素計の実施形態の一例を示
す構成図である。
FIG. 1 is a configuration diagram showing an example of an embodiment of a magnetic force type oximeter of the invention.

【図2】従来の磁気力式酸素計の一例を示す構成図であ
る。
FIG. 2 is a configuration diagram showing an example of a conventional magnetic force type oxygen meter.

【図3】磁気力式酸素計の原理を示す説明図である。FIG. 3 is an explanatory diagram showing the principle of a magnetic force type oxygen meter.

【図4】磁気力式酸素計の原理を示す説明図である。FIG. 4 is an explanatory diagram showing the principle of a magnetic force type oxygen meter.

【符号の説明】[Explanation of symbols]

1 磁界印加装置 2 歪計測チップ 3 浮子 4 支持梁 5 ストレンゲージ 6 電流回路 1 Magnetic field application device 2 Strain measurement chip 3 float 4 support beams 5 Strain gauge 6 current circuit

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】対向して配置された磁極から磁界を発生す
る磁界発生手段と、 前記磁極に近接して設けられた弾性部材と、この弾性部
材の歪を検出する歪検出手段と、からなり、これら磁界
発生手段と弾性部材を酸素を含むガス中に配置したとき
にガス中の酸素濃度に応じて前記磁極と弾性部材の間に
作用する磁気力変化を前記歪検出手段により検出するよ
うに構成したことを特徴とする磁気力式酸素計。
1. A magnetic field generating means for generating a magnetic field from magnetic poles arranged to face each other, an elastic member provided close to the magnetic pole, and a strain detecting means for detecting strain of the elastic member. When the magnetic field generating means and the elastic member are arranged in a gas containing oxygen, a change in magnetic force acting between the magnetic pole and the elastic member depending on the oxygen concentration in the gas is detected by the strain detecting means. A magnetic force type oximeter characterized by being constructed.
【請求項2】前記弾性部材は、少なくとも一端がシリコ
ン基板に設けた梁により支持され、シリコンの微細加工
技術により形成されていることを特徴とする請求項1記
載の磁気力式酸素計。
2. The magnetic force type oximeter according to claim 1, wherein at least one end of the elastic member is supported by a beam provided on a silicon substrate and is formed by a fine processing technique of silicon.
【請求項3】前記歪検出手段は拡散形半導体ストレンゲ
ージ、振動式歪ゲージ、電極間容量式歪検出器の少なく
とも一つを含むことを特徴とする請求項1記載の磁気力
式酸素計。
3. The magnetic force type oximeter according to claim 1, wherein the strain detecting means includes at least one of a diffusion type semiconductor strain gauge, a vibration type strain gauge, and an interelectrode capacitance type strain detector.
【請求項4】歪検出手段からの信号と電流回路を用い
て、前記歪を打ち消すための反力生成機構を備えたこと
を特徴とする請求項1記載の磁気力式酸素計。
4. The magnetic force type oximeter according to claim 1, further comprising a reaction force generating mechanism for canceling the strain by using a signal from the strain detecting means and a current circuit.
JP2002090818A 2002-03-28 2002-03-28 Magnetic force oxygen meter Expired - Fee Related JP3775592B2 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1424553A3 (en) * 2002-11-29 2004-10-13 ABB PATENT GmbH Device with suspension of a probe.
DE102006056046A1 (en) * 2006-11-28 2008-05-29 Abb Ag Paramagnetic oxygen sensor, has piezo-resistive unit to detect elastic deformation in area of suspension, where elastic deformation is caused by measuring effect, and oxygen concentration in gas is determined by signal processing technique
US8447373B2 (en) 2008-06-09 2013-05-21 The Board Of Trustees Of The University Of Illinois Apparatus and method for measuring a characteristic of a composition reactive to a magnetic field
CN106053688A (en) * 2016-06-28 2016-10-26 上海化工研究院 Super-miniature reactor for GC-MS headspace sampling qualitative analysis
RU2710081C1 (en) * 2019-05-15 2019-12-24 Сергей Иванович Ивандаев Density meter

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1424553A3 (en) * 2002-11-29 2004-10-13 ABB PATENT GmbH Device with suspension of a probe.
DE102006056046A1 (en) * 2006-11-28 2008-05-29 Abb Ag Paramagnetic oxygen sensor, has piezo-resistive unit to detect elastic deformation in area of suspension, where elastic deformation is caused by measuring effect, and oxygen concentration in gas is determined by signal processing technique
DE102006056046B4 (en) * 2006-11-28 2009-04-02 Abb Ag Paramagnetic oxygen sensor
US8447373B2 (en) 2008-06-09 2013-05-21 The Board Of Trustees Of The University Of Illinois Apparatus and method for measuring a characteristic of a composition reactive to a magnetic field
CN106053688A (en) * 2016-06-28 2016-10-26 上海化工研究院 Super-miniature reactor for GC-MS headspace sampling qualitative analysis
RU2710081C1 (en) * 2019-05-15 2019-12-24 Сергей Иванович Ивандаев Density meter

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