JP2003277787A - Method for manufacturing grease composition - Google Patents

Method for manufacturing grease composition

Info

Publication number
JP2003277787A
JP2003277787A JP2002089008A JP2002089008A JP2003277787A JP 2003277787 A JP2003277787 A JP 2003277787A JP 2002089008 A JP2002089008 A JP 2002089008A JP 2002089008 A JP2002089008 A JP 2002089008A JP 2003277787 A JP2003277787 A JP 2003277787A
Authority
JP
Japan
Prior art keywords
oil
weight
fatty acid
fat
oils
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2002089008A
Other languages
Japanese (ja)
Inventor
Masaki Fujimura
昌樹 藤村
Keiji Sakaguchi
啓二 坂口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanegafuchi Chemical Industry Co Ltd
Original Assignee
Kanegafuchi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanegafuchi Chemical Industry Co Ltd filed Critical Kanegafuchi Chemical Industry Co Ltd
Priority to JP2002089008A priority Critical patent/JP2003277787A/en
Publication of JP2003277787A publication Critical patent/JP2003277787A/en
Pending legal-status Critical Current

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  • Edible Oils And Fats (AREA)
  • Fats And Perfumes (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for manufacturing a grease composition for a processed grease that can maintain shape retaining properties and smoothness, even when formulated with a large amount of a grease having small crystallization speed such as palm oil. <P>SOLUTION: This grease composition is manufactured by adding, to 100 wt.% of a grease, 0.05-3.0 wt.% of a polyglycerol ester of a fatty acid wherein the average polymerization degree of glycerin is ≥7, the average esterification degree of the fatty acid is ≥6, and not less than 50 wt.% of the fatty acid constituents is behenic acid. <P>COPYRIGHT: (C)2004,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、油脂組成物の製造
方法に関する。さらに詳しくは、特定のポリグリセリン
脂肪酸エステルを油脂に添加することにより、油脂の結
晶化促進、さらには結晶微細化を行う油脂組成物の製造
方法に関する。
TECHNICAL FIELD The present invention relates to a method for producing an oil and fat composition. More specifically, the present invention relates to a method for producing an oil / fat composition in which a specific polyglycerin fatty acid ester is added to the oil / fat to promote crystallization of the oil / fat and further to refine the crystal.

【0002】[0002]

【従来の技術】従来、マーガリンやショートニング等に
代表される加工油脂製品(油脂組成物)に用いられる油
脂においては、パーム油、菜種油等の植物油脂と牛脂、
ラード、乳脂、魚油等の動物油脂に、水素添加された硬
化油、分別油等を混合して、油脂の結晶性を促進した
り、結晶の微細化を行い油脂組成物の保型性、滑らかさ
等の物性を向上していた。ところが、近年、O157、
狂牛病、ダイオキシン、環境ホルモン、遺伝子組み換え食
品、或いは食品アレルギーなど、食品の安全性等に関わ
る新しい問題が頻繁に発生している。こういった現状に
対応すべく、マーガリンやショートニング等の加工油脂
メーカーも牛脂、ラード、魚油といった動物油脂をでき
るだけ避けようとする動きがあり、植物油脂を主体に加
工油脂を製造している。植物油脂の中でもアレルゲン物
質を含有せず、しかも遺伝子組み換えの可能性がなく比
較的安価なパーム油は、特に多用されているのが現状で
ある。ところが、パーム油は結晶化が非常に遅く、しか
も粗大結晶を作りやすいため加工油脂の保型性が低下し
て作業性を損ねたり、製造後経日的に硬さが変化した
り、滑らかさが低下して、ざらついた感じになったり、
ぼそぼそした物性になってしまうという問題を生じる恐
れがあった。このため、結晶化の非常に速い油脂、例え
ば、パーム油の極度硬化油、ハイエルシン酸菜種油の極
度硬化油、硬化牛脂等を油脂に対して1〜3重量%程度
使用して油脂自体の結晶性を高めることがこれまでしば
しばなされてきた。しかし、こういった極度硬化油を使
用すると非常に融点が高いこと(通常60℃以上のもの
が多い)がマーガリンそのものの口溶けなどに悪影響し
て、食感を損ねる等の問題があった。
2. Description of the Related Art Conventionally, oils and fats used in processed oils and fats products (oil and fat composition) represented by margarine, shortening and the like include vegetable oils and fats such as palm oil and rapeseed oil and beef tallow,
Animal oils such as lard, milk fat, and fish oil are mixed with hydrogenated hydrogenated oil, fractionated oil, etc. to promote the crystallinity of oils and fats, and to refine the crystals to maintain the shape and smoothness of oil and fat compositions. The physical properties such as Sa were improved. However, in recent years, O157,
New problems related to food safety such as mad cow disease, dioxins, environmental hormones, genetically modified foods, and food allergies are frequently occurring. In order to cope with this situation, manufacturers of processed fats and oils such as margarine and shortening are also trying to avoid animal fats and oils such as beef tallow, lard, and fish oil as much as possible. Among the vegetable oils and fats, palm oil, which does not contain allergen substances and has no possibility of gene recombination and which is relatively inexpensive, is currently in widespread use. However, palm oil is extremely slow to crystallize, and because it is easy to form coarse crystals, the shape retention of processed oils and fats deteriorates workability, the hardness changes with time after production, and smoothness Is lowered, and it becomes rough,
There was a possibility that the problem that the physical properties would become messy would occur. For this reason, oils and fats that crystallize very rapidly, such as extremely hardened oil of palm oil, extremely hardened oil of rapeseed oil of hyersinic acid, hardened beef tallow, etc., are used in an amount of about 1 to 3% by weight based on the fat and oil. It has often been done so far. However, when such an extremely hardened oil is used, the extremely high melting point (usually 60 ° C. or higher in many cases) adversely affects the melting of margarine itself in the mouth, etc., and there is a problem that the texture is impaired.

【0003】[0003]

【発明が解決しようとする課題】本発明はこのような現
状に鑑み、パーム油等の結晶化速度の小さい油脂を多く
配合した加工油脂においても保型性、滑らかさを維持す
ることのできる油脂組成物の製造方法を提供することを
目的とするものである。
SUMMARY OF THE INVENTION In view of the above situation, the present invention is a processed fat and oil containing a large amount of fat and oil having a low crystallization rate, such as palm oil, which can maintain shape retention and smoothness. It is intended to provide a method for producing a composition.

【0004】[0004]

【課題を解決するための手段】本発明者らは上記の目的
を達成するために鋭意研究を重ねた結果、特定のポリグ
リセリン脂肪酸エステルを油脂に添加することにより上
記課題を解決できることを見出し、本発明を完成するに
至った。即ち、本発明は、グリセリンの平均重合度が7
以上、脂肪酸の平均エステル化度が6以上であって、構
成脂肪酸の50%以上がベヘン酸よりなるポリグリセリ
ン脂肪酸エステルを油脂100重量%に対して0.05
重量%以上、3.0重量%以下の範囲で添加することを
特徴とする油脂組成物の製造方法に関する。好ましい実
施態様としては、油脂組成物100重量%中、油相部が
30重量%以上、100重量%以下である油脂組成物の
製造方法に関する。
Means for Solving the Problems As a result of intensive studies to achieve the above object, the present inventors have found that the above problems can be solved by adding a specific polyglycerin fatty acid ester to fats and oils, The present invention has been completed. That is, in the present invention, the average degree of polymerization of glycerin is 7
As described above, the polyglycerin fatty acid ester in which the average degree of esterification of fatty acid is 6 or more and 50% or more of the constituent fatty acid is behenic acid is 0.05 with respect to 100% by weight of oil and fat.
The present invention relates to a method for producing an oil / fat composition, which is added in the range of not less than 3.0% by weight and not more than 3.0% by weight. A preferred embodiment relates to a method for producing an oil / fat composition in which the oil phase portion is 30% by weight or more and 100% by weight or less in 100% by weight of the oil / fat composition.

【0005】[0005]

【発明の実施の形態】以下、本発明につき、詳細に説明
する。
BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below.

【0006】本発明におけるポリグリセリン脂肪酸エス
テルとは、グリセリンの平均重合度が7以上、脂肪酸の
平均エステル化度が6以上であって、構成脂肪酸の50
%以上がベヘン酸よりなる乳化剤であり、かかるポリグ
リセリン脂肪酸エステルの配合量は油脂100重量%に
対して0.05重量%以上、3.0重量%以下の範囲で
添加することが好ましく、更に好ましい範囲は0.1重
量%以上、1.0重量%以下であり、より更に好ましい
範囲は0.2重量%以上、0.5重量%以下である。使
用量が0.05重量%以上及び3.0重量%以下であれ
ば、油脂の結晶化、結晶の微細化が満足に得られ、油脂
組成物自体の保型性が向上し、なめらかな物性が得られ
る。さらに本発明には上記乳化剤の他、さらにマーガリ
ン製品の乳化を行うため、あるいはマーガリン、ショー
トニング製品の安定性、品質をさらに向上するため、グ
リセリン脂肪酸エステル、レシチン、ソルビタン脂肪酸
エステル、ステアロイル乳酸カルシウム(CSL)、蔗
糖脂肪酸エステル、等の乳化剤を併用することができ
る。
The polyglycerin fatty acid ester in the present invention means that the average degree of polymerization of glycerin is 7 or more, the average degree of esterification of fatty acid is 6 or more, and the constituent fatty acid is 50 or more.
% Or more is an emulsifier composed of behenic acid, and it is preferable that the polyglycerin fatty acid ester is added in an amount of 0.05% by weight or more and 3.0% by weight or less based on 100% by weight of oil and fat. A preferred range is 0.1% by weight or more and 1.0% by weight or less, and an even more preferred range is 0.2% by weight or more and 0.5% by weight or less. When the amount used is 0.05% by weight or more and 3.0% by weight or less, crystallization of fats and oils and finer crystals are satisfactorily obtained, the shape retention of the fats and oils composition itself is improved, and the physical properties are smooth. Is obtained. Further, in addition to the emulsifiers described above, the present invention further emulsifies margarine products, or further improves the stability and quality of margarine and shortening products, in order to further improve glycerin fatty acid ester, lecithin, sorbitan fatty acid ester, and stearoyl calcium lactate (CSL). ), Sucrose fatty acid ester, etc. can be used together.

【0007】本発明における油脂組成物とは、いわゆる
マーガリン、ショートニングといった加工油脂製品のこ
とをいい、カレールー、シチュールー等の固形ルー製
品、チョコレート製品、フライオイル、スプレーオイル
等は含まない。かかる油脂組成物における油相の配合量
は油脂組成物100重量%中、30重量%以上、100
重量%以下が好ましく、更に好ましい範囲は40重量%
以上、100重量%以下である。油相が30重量%以上
及び100重量%以下であれば、ポリグリセリン脂肪酸
エステルの油脂に対する結晶化促進、結晶の微細化効果
が満足に得られ、油脂組成物自体の保型性が向上し、滑
らかな物性が得られる。
The oil and fat composition in the present invention means processed oil and fat products such as so-called margarine and shortening, and does not include solid roux products such as curry roux and stew roux, chocolate products, frying oil and spray oil. The blending amount of the oil phase in such an oil / fat composition is 30% by weight or more, 100% by weight in 100% by weight of the oil / fat composition.
Weight% or less is preferable, and more preferable range is 40% by weight.
As described above, the content is 100% by weight or less. When the oil phase is 30% by weight or more and 100% by weight or less, the crystallization acceleration of the polyglycerin fatty acid ester to the oil and fat, the effect of refining the crystals can be satisfactorily obtained, and the shape retention of the oil and fat composition itself is improved, Smooth physical properties can be obtained.

【0008】本発明における油脂組成物に用いられる油
脂は、食用に適するものであれば特に限定されないが、
例えば、コーン油、サフラワー油、胡桃油、芥子油、向
日葵油、綿実油、菜種油、大豆油、辛子油、カポック
油、米糠油、胡麻油、落花生油、えごま油、紫蘇油、オ
リーブ油、椿油、ひまし油、やし油、パーム油、パーム
核油、カカオ脂、シア脂、ボルネオ脂等の植物油脂や、
魚油、鯨油、牛脂、豚脂、乳脂等の動物油脂が挙げら
れ、また、それらの硬化油、エステル交換油、分別油等
から目的に応じて適宜選択し、これを単独で、あるいは
組み合わせて使用することができる。
The fat and oil used in the fat and oil composition of the present invention is not particularly limited as long as it is edible.
For example, corn oil, safflower oil, walnut oil, mustard oil, sunflower oil, cottonseed oil, rapeseed oil, soybean oil, pepper oil, kapok oil, rice bran oil, sesame oil, peanut oil, sesame oil, shiso oil, olive oil, camellia oil, castor oil , Vegetable oils such as palm oil, palm oil, palm kernel oil, cocoa butter, shea butter and borneo butter,
Animal oils and fats such as fish oil, whale oil, beef tallow, lard, and milk fat are listed, and they are appropriately selected from hardened oils, transesterified oils, fractionated oils and the like according to the purpose, and these are used alone or in combination. can do.

【0009】本発明に用いられる油脂組成物は、例えば
以下のようにして製造することができる。まず、油脂中
に乳化剤としてグリセリンの平均重合度が7以上、脂肪
酸の平均エステル化度が6以上であって、構成脂肪酸の
50%以上がベヘン酸よりなるポリグリセリン脂肪酸エ
ステル、及びグリセリン脂肪酸エステル、レシチン等を
加え、70℃に加熱、溶解したものを油相とする。一
方、水に食塩、脱脂粉乳等を加え、十分混合した後に7
0℃に加熱して殺菌し、水相とする。油相中に水相を徐
々に加えて油中水型に乳化した後冷却して油中水型に乳
化した油脂組成物を得る。
The oil / fat composition used in the present invention can be produced, for example, as follows. First, an average degree of polymerization of glycerin as an emulsifier in fats and oils is 7 or more, an average degree of esterification of fatty acids is 6 or more, and 50% or more of the constituent fatty acids are behenic acid. Lecithin and the like are added, heated to 70 ° C. and dissolved to obtain an oil phase. On the other hand, add salt, skim milk powder, etc. to water, mix well, and then
Heat to 0 ° C. for sterilization to obtain an aqueous phase. A water phase is gradually added to the oil phase to emulsify it into a water-in-oil type, and then cooled to obtain an oil-fat composition emulsified in a water-in-oil type.

【0010】[0010]

【実施例】以下に実施例を示し、本発明をより具体的に
説明するが、本発明はこれらの実施例に何ら限定される
ものではない。なお、実施例において部は重量部であ
る。 (実施例1〜8、比較例1〜8) マーガリン 表1、表2に示す配合により、食用油脂に所定の乳化剤
を加えて混合し、70℃まで加温、溶解したものを油相
とした。一方、水に食塩、脱脂粉乳を加えて溶解し、7
0℃まで加温したものを水相とした。油相中に水相を徐
々に加えて油中水型に乳化した後通常のマーガリン製造
工程に従い、冷却、捏和により油脂組成物(マーガリ
ン)を得た。これらをそれぞれ冷蔵庫(5℃)に入れて
2ヶ月放置し、組織状態・物性(滑らかさ・硬さ)、口
溶け(食感)を製品15℃に戻した状態で官能評価を行
った。結果を表1(実施例)、表2(比較例)に示し
た。
The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples. In the examples, parts are parts by weight. (Examples 1 to 8 and Comparative Examples 1 to 8) Margarine According to the formulations shown in Tables 1 and 2, a predetermined emulsifier was added to edible oil and fat, and the mixture was heated to 70 ° C and dissolved to obtain an oil phase. . On the other hand, add salt and skim milk powder to water and dissolve,
What was heated to 0 ° C. was used as an aqueous phase. The water phase was gradually added to the oil phase to emulsify it into a water-in-oil type, followed by cooling and kneading in accordance with a usual margarine production process to obtain an oil and fat composition (margarine). These were put in a refrigerator (5 ° C.) and allowed to stand for 2 months, and the organoleptic evaluation was performed in a state where the texture, physical properties (smoothness / hardness), and melting in mouth (texture) were returned to 15 ° C. of the product. The results are shown in Table 1 (Example) and Table 2 (Comparative Example).

【0011】[0011]

【表1】 [Table 1]

【0012】[0012]

【表2】 (実施例9〜14、比較例9〜12) ショートニン
グ 表3に示す配合により、食用油脂に所定の乳化剤を加え
て混合し、70℃まで加熱、溶解した後、通常のショー
トニング製造工程に従い、冷却、捏和し、窒素ガスを封
入して油脂組成物(ショートニング)を得た。これらを
それぞれ20℃で3ヶ月間放置し、組織状態・物性(滑
らかさ、硬さ)、口溶け(食感)について官能評価を行
った。結果を表3に示した。
[Table 2] (Examples 9 to 14 and Comparative Examples 9 to 12) Shortening According to the formulation shown in Table 3, a predetermined emulsifier was added to edible oil and fat, mixed, heated to 70 ° C and dissolved, and then cooled according to a normal shortening production process. The mixture was kneaded and filled with nitrogen gas to obtain an oil / fat composition (shortening). These were left to stand at 20 ° C. for 3 months, and subjected to sensory evaluation with respect to tissue state / physical properties (smoothness, hardness) and melting in mouth (texture). The results are shown in Table 3.

【0013】[0013]

【表3】 [Table 3]

【0014】[0014]

【発明の効果】以上の結果からも明らかなように、グリ
セリンの平均重合度が7以上、脂肪酸の平均エステル化
度が6以上であって、構成脂肪酸の50%以上がベヘン
酸よりなるポリグリセリン脂肪酸エステルを油脂に所定
量添加することにより、適度な硬さと滑らかな物性が得
られるだけでなく、口溶けの良い食感を有した油脂組成
物を製造することが可能となる。
As is clear from the above results, polyglycerin in which the average degree of polymerization of glycerin is 7 or more, the average degree of esterification of fatty acids is 6 or more, and 50% or more of the constituent fatty acids are behenic acid By adding a predetermined amount of the fatty acid ester to the fat or oil, not only suitable hardness and smooth physical properties can be obtained, but also a fat and oil composition having a mouth-feeling good texture can be produced.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 グリセリンの平均重合度が7以上、脂肪
酸の平均エステル化度が6以上であって、構成脂肪酸の
50%以上がベヘン酸よりなるポリグリセリン脂肪酸エ
ステルを油脂100重量%に対して0.05重量%以
上、3.0重量%以下の範囲で添加することを特徴とす
る油脂組成物の製造方法。
1. A polyglycerin fatty acid ester having an average degree of polymerization of glycerin of 7 or more, an average degree of esterification of fatty acids of 6 or more, and 50% or more of constituent fatty acids being behenic acid, relative to 100% by weight of fats and oils. A method for producing an oil / fat composition, characterized in that it is added in a range of 0.05% by weight or more and 3.0% by weight or less.
【請求項2】 油脂組成物100重量%中、油相部が3
0重量%以上、100重量%以下である請求項1記載の
油脂組成物の製造方法。
2. The oil phase portion is 3% in 100% by weight of the oil / fat composition.
The method for producing an oil and fat composition according to claim 1, wherein the content is 0% by weight or more and 100% by weight or less.
JP2002089008A 2002-03-27 2002-03-27 Method for manufacturing grease composition Pending JP2003277787A (en)

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Country Status (1)

Country Link
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Cited By (7)

* Cited by examiner, † Cited by third party
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JP2005054092A (en) * 2003-08-06 2005-03-03 Sakamoto Yakuhin Kogyo Co Ltd Inhibitor for oozing out oil and fat
JP2008212036A (en) * 2007-03-02 2008-09-18 Adeka Corp Oil and fat composition for noodle skin
JP2010047634A (en) * 2008-08-19 2010-03-04 Fuji Oil Co Ltd Method for depositing fine crystals of fat and oil
JP2012082236A (en) * 2010-10-06 2012-04-26 Taiyo Kagaku Co Ltd Oil and fat solidifying agent
CN103002748A (en) * 2010-07-12 2013-03-27 J-制油株式会社 Oil or fat composition
JP2015012848A (en) * 2013-07-08 2015-01-22 日清オイリオグループ株式会社 Coating chocolate
JP2018191592A (en) * 2017-05-18 2018-12-06 理研ビタミン株式会社 Curing inhibitor for palm oil and fat

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JP2015012848A (en) * 2013-07-08 2015-01-22 日清オイリオグループ株式会社 Coating chocolate
JP2018191592A (en) * 2017-05-18 2018-12-06 理研ビタミン株式会社 Curing inhibitor for palm oil and fat
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