JP2003174250A - Printed wiring board, and method for manufacturing the printed wiring board - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a printed wiring board including an electrically conductive connection pin and being excellent in high frequency characteristics. <P>SOLUTION: A single tin layer 74 is applied on a conductor circuit 158 and a via 160, on which a conductive connection pin 98 is mounted through a conductive bonding agent 95. It is hereby possible to more raise a signal transmission speed than a prior art printed wiring board where two metal layers are formed. Further, since there is no nickel layer, the manufacturing cost can be reduced to improve electrical characteristics. <P>COPYRIGHT: (C)2003,JPO

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a printed wiring board that can be suitably used as a package substrate, and more particularly, to a conductive circuit exposed by opening an organic resin insulating layer (solder resist layer) with a conductive adhesive. The present invention relates to a printed wiring board on which conductive connecting pins are attached.

[0002]

2. Description of the Related Art A printed wiring board used as a package substrate is manufactured, for example, by the method disclosed in JP-A-9-130050. A roughened layer is formed on the surface of the conductor circuit of the printed wiring board by electroless plating or etching. Thereafter, an interlayer insulating resin is applied by a roll coater or printing, exposed and developed to form a via hole opening for interlayer conduction, and UV curing and main curing are performed to form an interlayer resin insulating layer. Further, a catalyst such as palladium is attached to the roughened surface obtained by roughening the interlayer insulating layer with an acid or an oxidizing agent. Then, a thin electroless plating film is formed, a pattern is formed on the plating film with a dry film, and after thickening with electrolytic plating, the dry film is peeled off with an alkali and etched to create a conductor circuit. . By repeating this, a build-up multilayer printed wiring board is obtained. Further, a solder resist layer is applied to the outermost layer of the printed wiring board in order to protect the conductor circuit.

As shown in FIG. 16, a conductive connecting pin 39 is provided.
8 is provided, a part of the solder resist layer 370 is opened, and a nickel layer 372 and a gold layer 374 are formed on the exposed conductor circuit (via) 358 to form a solder pad 373. Then, a solder paste serving as a conductive adhesive is printed on the solder pad 373, and reflow is performed to attach the conductive adhesive 395 via the conductive adhesive 395. Here, the reason why the gold layer 374 is formed on the conductor circuit 358 with the nickel layer 272 interposed therebetween is that when the gold layer is formed by electroless plating on the nickel layer, the nickel layer stabilizes the formation of the gold layer. Turn into That is, the diffusion of the gold layer does not occur.

[0004]

A printed wiring board used as a package substrate for an IC chip is required to have improved frequency characteristics. Here, in the printed wiring board having the configuration described above with reference to FIG. 16, if the frequency of the IC chip exceeds 1 GHz, a malfunction easily occurs due to a delay in signal propagation. Further, when the frequency exceeds 3 GHz, the tendency becomes remarkable. The present inventor has studied the cause of this, and the nickel layer 372 and the gold layer 374 are formed on the conductor circuit 358.
It was found that this is because the solder pad 373 is formed by applying the above. That is, it has been found that since the two-layer structure of the nickel layer 372 and the gold layer 374 is adopted, signal propagation delay and increase in resistance value occur at the interface of each layer. Especially, signal delay easily occurs in the nickel layer,
It was found that there are differences compared to other metals.

Further, when the opening diameter of nickel is small, problems are likely to occur in the deposition by plating. Further, the nickel layer 372 increases the manufacturing cost of the printed wiring board. Furthermore, since the nickel layer 372 has high electric resistance,
It deteriorated the electrical characteristics of the printed wiring board. If the connected wiring is in the power supply layer, the amount of power supply to the IC chip increases when the frequency exceeds 1 GHz, which is a high frequency region, and a large capacity is instantaneously supplied. Therefore, the nickel layer hinders the transmission. It is believed that there are times when it does.

The present invention has been made to solve the above problems, and an object thereof is to provide a printed wiring board having conductive connecting pins and excellent in high frequency characteristics, and a method for manufacturing the printed wiring board. Especially.

[0007]

In order to achieve the above object, in the invention of claim 1, a conductive circuit is formed by exposing a part of the organic resin insulating layer by exposing it by interposing a conductive adhesive. Printed wiring board to attach the sex connection pin,
A technical feature is that a single-layer metal layer of tin or a noble metal is formed on the exposed conductor circuit, and a conductive connecting pin is attached with a conductive adhesive interposed.

According to the first aspect of the present invention, since a single metal layer is formed on a conductor circuit and conductive connecting pins are attached with a conductive adhesive interposed, a printed wiring board of the prior art in which two metal layers are formed is used. Also, the propagation speed of the signal can be increased.
Also, since there is no nickel layer, the manufacturing cost can be reduced,
The electrical characteristics can be improved. Further, the power supply is not disturbed even when the power is supplied from the external board such as the daughter board, and the desired power is supplied from the daughter board, so that malfunctions and delays in the initial operation can be suppressed. Further, the adhesion with the solder can be improved.

The printed wiring board in the present invention refers to a core substrate, which is an interlayer having a thickness of about 0.4 to 1 mm and a reinforcing core material impregnated on a resin substrate having a thickness of about 30 μm and not impregnated with the reinforcing core material. A via hole, which is a non-through hole, is formed in the insulating resin layer, and through a solder made of C4,
A flip chip is mounted. On the other hand, it is connected to an external board such as a daughter board via a conductive connection pin which is an external terminal.

In the second aspect, since the noble metal is gold, silver, platinum, or palladium, it has excellent corrosion resistance, and the surface is not easily oxidized or altered. Moreover, when these metals are formed on the roughened conductor circuit, the electrical characteristics such as resistance are improved as compared with the conventional two-layer structure (nickel-gold). It is considered that there is no blocking layer called the nickel layer. By forming gold on the conductor circuit where a part of the organic resin insulating layer is exposed, not only a pad for connecting the conductive connection pin, which is a conductor circuit having excellent corrosiveness, can be obtained,
The metal resistance value in the daughter board, the conductive connection pin, and the conductor layer can be reduced. It becomes difficult to interrupt the power supply. The amount of voltage drop of the power supply can be reduced.
Further, when the solder that has been reflowed and once melted is solidified again, the adhesion and bondability with the pad can be improved. Therefore, even if the reliability test is performed, the decrease in tensile strength is small.

By forming silver on the conductor circuit in which a part of the organic resin insulating layer is exposed, not only a pad for connecting a conductive connecting pin, which is a conductor circuit having excellent corrosiveness, can be obtained, but also silver itself can be formed. Since the electrical conductivity is excellent, the metal resistance value in the daughter board, the conductive connection pin, and the conductor layer can be reduced. It becomes difficult to interrupt the power supply.
The amount of voltage drop of the power supply can be reduced. further,
When the reflowed and once melted solder is solidified again, the adhesiveness and bondability with the pad can be improved. Therefore, even if the reliability test is performed, the decrease in tensile strength is small.

By forming tin on the conductor circuit in which a part of the organic resin insulating layer is exposed, not only a pad for connecting a conductive connecting pin, which is a conductor circuit excellent in corrosiveness, can be obtained, but also a daughter board to a conductive board can be used. The metal resistance value between the sexual connection pin and the conductor layer can be reduced. It becomes difficult to interrupt the power supply. The amount of voltage drop of the power supply can be reduced. Further, when the solder that has been reflowed and once melted is solidified again, the adhesion and bondability with the pad can be improved. Therefore, even if the reliability test is performed, the decrease in tensile strength is small. In particular, when reflow crystallization is carried out when solder containing tin is used,
Since the alloy of the conductive adhesive and the pad is formed, the tensile strength can be improved.

In claim 3, the thickness of the metal layer is 0.0
It is 1 to 3 μm. If the thickness is less than 0.01 μm, a portion that cannot completely cover the conductor circuit is formed, which causes problems in strength and corrosion resistance. This is because the roughened surface is exposed when the metal layer is applied to the conductor circuit on which the roughened layer is formed. Electrical characteristics,
The improvement cannot be confirmed even in strength. On the contrary, 3 μm
If it exceeds, the corrosion resistance and strength are not improved, and the cost becomes too high, which impairs the economical efficiency. Furthermore, variations in thickness are likely to occur, and in some cases differences in characteristics between pads may occur, which may result in defects in electrical characteristics. Desirable thickness is 0.05 to 1 μm. A more desirable range is 0.1 to 0.5 μm. In the meantime, even if the thickness varies, it is within a level at which no problem occurs.

In claim 4, a roughening layer is formed on the surface and the side surface of the conductor circuit. Therefore, the adhesion between the conductor circuit and the organic resin insulating layer is high.

The conductive adhesive is Sn / Pb, Sn / S
It is desirable that the eutectic metal is any one of b, Sn / Ag, and Sn / Ag / Cu. Further, it is desirable that the melting point of the conductive adhesive is solder in the range of 180 to 280 ° C.
This is because, within the temperature range, even if the reflow is performed, the resin substrate does not melt due to the temperature. These solders have good adhesion with the metal layer. When re-solidified after melting, the alloy of solder and single-layer metal is easily formed with certainty, so that the strength is not deteriorated. It is less likely to cause problems in terms of connectivity and electrical connectivity. In the conventional nickel-gold layer, the gold layer is altered due to the formation failure of the nickel layer as the base, and as a result, the alloy formation with the solder is hindered. Therefore, the bonding strength is deteriorated.
Similar results were also obtained using a eutectic metal of Sn / Cu.

In claim 6, the conductive adhesive is Sn
Since it is a eutectic metal of any of / Pb, Sn / Sb, Sn / Ag, or Sn / Ag / Cu and contains tin, it has high adhesion to a metal layer (solder pad) made of tin.

In the method of manufacturing a printed wiring board according to claim 7, at least steps (a) to (c) are performed,
A technical feature of applying a single-layer metal layer on a conductor circuit consisting mainly of copper exposed by opening a part of the organic resin insulating layer and attaching a conductive connecting pin with a conductive adhesive interposed. And (a) a step of immersing the printed wiring board in which the conductor circuit is exposed from the organic resin insulation layer in an etching solution of sulfuric acid-hydrogen peroxide solution, cupric chloride or ferric chloride.
(B) Acid activation step, (c) Tin or noble metal displacement plating step.

According to a seventh aspect of the present invention, since the conductor circuit mainly made of copper is etched and activated by an acid, a single layer metal film made of tin or a noble metal is formed by displacement plating into a shape and size of the conductor circuit. Regardless, it can be formed to be thin and uniform in thickness.

In the eighth aspect, since the noble metal forming the metal layer is soft gold, a single-layer metal film can be formed on the conductor circuit without interposing nickel and without diffusing into copper. . That is, in the prior art, hard gold, which can be wire-bonded to a gold wire, has been continuously used as gold when making a connection by a conductive connection pin. Since hard gold is electroless plated and diffuses into a conductor circuit made of copper, a coating cannot be formed without a nickel layer. Further, it is necessary to provide strength for bonding. On the other hand, in the eighth aspect, it can be directly formed on the conductor circuit made of copper. The conductive connecting pin includes a columnar connecting portion and a plate-like fixing portion, and is made of a metal selected from copper, copper alloy, nickel, tin, zinc, aluminum, and noble metal.

[0020]

BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be described below with reference to the drawings. First, the structure of the printed wiring board according to the first embodiment of the present invention will be described with reference to FIGS. 6 shows a cross section of the printed wiring board 10, and FIG. 7 shows an IC chip 90 on the printed wiring board 10 shown in FIG.
It shows a state where is mounted.

The printed wiring board 10 as shown in FIG.
The build-up wiring layer 80 is formed on the front surface and the back surface of the core substrate 30.
A and 80B are formed. Build-up wiring layer 80
A and 80B are the interlayer resin insulation layer 50 in which the conductor circuit 58 and the via 60 are formed, and the conductor circuit 158 and the via 160.
And the inter-layer resin insulation layer 150 formed with. The buildup wiring layer 80A and the buildup wiring layer 80B are
Connection is made via a through hole 36 formed in the core substrate 30. The solder resist layer 70 is formed on the interlayer resin insulation layer 150.
0, the solder bumps 76 are formed on the conductor circuit 158 and the vias 160 via the upper opening 71U, and the lower opening 7 is formed.
The conductive connection pin 98 is attached to the conductor circuit 158 and the via 160 via 1D.

As shown in FIG. 7, the solder bumps 76 on the upper side of the printed wiring board 10 are the pads 92 of the IC chip 90.
The lower conductive connection pin 95 is connected to a socket of a daughter board (not shown).

As shown in FIG. 8C, which is an enlarged view of a portion surrounded by an ellipse C in FIG. 6, the conductor circuit 158 and the via 1 exposed through the opening 71D of the solder resist 70.
A tin layer (single-layer metal layer) 74 is disposed on 60, and a solder pad 73 is formed. A conductive connecting pin 98 is attached on the solder pad 73 via a conductive adhesive 75.

In the printed wiring board 10 of the first embodiment, the single-layer tin layer 74 is formed on the conductor circuit 158 and the via 160 to form the conductive adhesive 75. Therefore, as described above with reference to FIG. The signal propagation speed can be increased as compared with the prior art printed wiring board in which the metal layers of the layers are formed. Further, since there is no nickel layer, the manufacturing cost and the power source can be reduced.

Here, the tin layer 74 has a thickness of 0.01 to
It is preferably 3.0 μm. If the thickness is less than 0.01 μm, the conductor circuit 158 and the via 160 cannot be completely covered, resulting in problems in strength and corrosion resistance. Conversely,
Even if it exceeds 3.0 μm, there is no improvement in corrosion resistance. Peeling occurs in the film and the strength deteriorates. It is difficult to form the tin layer to have a thickness of 1.0 μm or more by displacement plating. Further, it is desirable that the thickness is 0.05 to 0.5 μm. Within that range, no problem occurs even if some variation occurs.

In the printed wiring board 10 of this embodiment, as shown in FIG.
As shown in (C), a roughened layer 158α is formed on the surfaces of the conductor circuit 158 and the via 160. Therefore, the adhesion between the conductor circuit 158, the via 160 and the solder resist layer 70 is high.

In the first embodiment, the solder bumps 76 and the conductive adhesive 75 are made of Sn / Pb, Sn / Sb, Sn / Pb.
A eutectic metal of Ag or Sn / Ag / Cu,
Solder pad 7 having a tin layer 74 because it contains tin
High adhesion with 3.

Next, the method of manufacturing the printed wiring board described above with reference to FIG. 6 will be described with reference to FIGS.

(1) A copper clad laminate 30A having 18 μm of copper foil 32 laminated on both surfaces of a substrate 30 made of glass epoxy resin or BT (bismaleimide-triazine) resin having a thickness of 0.8 mm is used as a starting material. Yes (Fig. 1
(See (A)). There are 1 inorganic particles such as silica in the resin.
0-40% is included. First, this copper clad laminate 30
After A is drilled and a plating resist is subsequently formed, the substrate 30 is subjected to electroless copper plating to form a through hole 36, and the copper foil is etched in a pattern according to a conventional method. The lower conductor circuits 34 are formed on both surfaces of the substrate 30 (see FIG. 1B).

(2) Substrate 3 on which the lower conductor circuit 34 is formed
0 is washed with water and dried, and then an etching solution is sprayed onto both surfaces of the substrate 30 to etch the surface of the lower conductor circuit 34 and the land surface 36a of the through hole 36, thereby removing the entire lower conductor circuit 34. Roughened surface 3
4α is formed (see FIG. 1C). As the etching solution, a mixture of 10 parts by weight of imidazole copper (II) complex, 7 parts by weight of glycolic acid, 5 parts by weight of potassium chloride and 78 parts by weight of ion-exchanged water is used.

(3) The resin filler 40 containing a cycloolefin resin or an epoxy resin as a main component is applied to the substrate 3
By applying it to both surfaces of No. 0 using a printing machine, it is filled between the lower layer conductor circuits 34 or in the through holes 36, and heated and dried (see FIG. 1D). That is, by this step, the resin filler 40 is filled between the lower layer conductor circuits 34 or in the through holes 36. After that, by belt sander polishing using a belt polishing paper (manufactured by Sankyo Rikagaku Co., Ltd.), the surface of the lower conductor circuit 34 and the land surface 36a of the through hole 36 are polished so that the resin filler 40 does not remain. Buffing is performed to remove scratches caused by sanding. Such a series of polishing is similarly performed on the other surface of the substrate 30. Then, the filled resin filler 40 is cured by heating (see FIG. 2A).

(4) Next, the same etching solution as used in (2) above is sprayed onto both surfaces of the substrate 30 that has been subjected to (3) above to spray the lower layer conductor. By light etching the surface of the circuit 34 and the land surface 36a of the through hole 36, a roughened surface 34β is formed on the entire surface of the lower conductor circuit 34 (FIG. 2).
(See (B)).

(5) Next, a thermosetting cycloolefin resin sheet having a thickness of 50 μm is heated to a temperature of 50 to 150 ° C. and pressure of 5 kg on both surfaces of the substrate which has undergone the above steps.
/ Cm ² under vacuum pressure bonding to provide an interlayer resin insulation layer 50 made of cycloolefin resin (FIG. 2C).
reference). The degree of vacuum during vacuum pressure bonding is 10 mmHg.

(6) Next, the mask 49 having the opening 49a is placed, and the via opening 52 is formed in the interlayer resin insulation layer 50 by the carbon dioxide laser (see FIG. 2D).
Although a laser is used here, the via opening 51 can also be formed by exposure / development processing.

(7) Next, a roughened surface is formed on the insulating layer with an acid or an oxidizing agent (chromic acid, permanganate, etc.). Alternatively, SV-454 manufactured by Nippon Vacuum Technology Co., Ltd.
Plasma treatment is performed using 0 to form a roughened surface 50α on the surface of the interlayer resin insulation layer 50 (see FIG. 3A). At this time, argon gas was used as the inert gas, and the power was 200 W, the gas pressure was 0.6 Pa, and the temperature was 70 ° C.
Plasma treatment is performed for a minute.

(8) After that, sputtering targeting Ni and Cu is performed to form a Ni / Cu metal layer 52 on the surface of the interlayer resin insulation layer 50 (see FIG. 3B). Although sputtering is used here, a metal layer of copper, nickel, or the like may be formed by electroless plating.
In some cases, the electroless plated film may be formed after forming by sputtering.

(9) Next, a photosensitive dry film is attached to the surface of the metal layer 52, a mask is placed, and exposure and development processing is performed to form a resist 54 having a predetermined pattern. Then, the core substrate 30 is dipped in the electrolytic plating solution to remove Ni / C.
A current is caused to flow through the u metal layer 52, electrolytic plating is performed on the resist 54 non-forming portion under the following conditions, and electrolytic plating 56 is deposited (see FIG. 3C).

[Electrolytic plating aqueous solution] Sulfuric acid 2.24 mol / l Copper sulfate 0.26 mol / l Additive (manufactured by Atotech Japan, Kaparaside HL) 19.5 ml / l [Electrolytic plating conditions] Current density 1 A / dm ² Time 120 minutes Temperature 22 ± 2 ℃

(10) Then, the plating resist 54 is changed to 5
After stripping off with% NaOH, the plating resist 54
The Ni / Cu metal layer 52 below is etched and removed by a mixed solution of sulfuric acid and hydrogen peroxide to remove the Ni / Cu metal layer 5
A conductor circuit 58 and a via 60, which are composed of 2 and electrolytic copper plating 56, are formed (FIG. 3D). Then, the etching solution is sprayed onto both surfaces of the substrate 30 to form the conductor circuit 5
8. By etching the surface of the via 60, a roughened layer 58α is formed on the surface (see FIG. 4A).

(11) The above steps (5) to (9) are repeated to obtain the interlayer resin insulation layer 150, the conductor circuit 158 and the via 1.
Form 60. Then, the etching liquid is sprayed on both surfaces of the substrate to etch the surfaces of the conductor circuits 158 and the vias 160, whereby the roughened layer 15 is formed on the entire surface.
8α is formed (see FIG. 4B). As the etching solution, a mixture of 10 parts by weight of imidazole copper (II) complex, 7 parts by weight of glycolic acid, 5 parts by weight of potassium chloride and 78 parts by weight of ion-exchanged water is used.

(12) Next, a cresol novolac type epoxy resin (manufactured by Nippon Kayaku Co., Ltd.), which was dissolved in diethylene glycol dimethyl ether (DMDG) to a concentration of 60% by weight, was acrylated with 50% of epoxy groups. Oligomer (molecular weight 4000) 46.67
15 parts by weight of bisphenol A type epoxy resin (manufactured by Yuka Shell Co., trade name: Epicoat 1001) of 80% by weight dissolved in methyl ethyl ketone, imidazole curing agent (manufactured by Shikoku Kasei Co., trade name: 2E4MZ-CN)
1.6 parts by weight, 3 parts by weight of a polyfunctional acrylic monomer which is a photosensitive monomer (manufactured by Kyoei Chemical Co., Ltd., trade name: R604)
Similarly, polyvalent acrylic monomer (Kyoei Chemical Co., Ltd., trade name:
DPE6A) 1.5 parts by weight, dispersion type antifoaming agent (manufactured by San Nopco, trade name: S-65) 0.71 parts by weight are put in a container, stirred and mixed to prepare a mixed composition, and this mixed composition To the composition, 2.0 parts by weight of benzophenone (manufactured by Kanto Chemical Co., Inc.) as a photogravimetric initiator and 0.2 part by weight of Michler's ketone (manufactured by Kanto Chemical Co., Inc.) as a photosensitizer were added to give a viscosity of 25.
A solder resist composition (organic resin insulating material) adjusted to 2.0 Pa · s at 0 ° C. is obtained. The viscosity was measured with a B type viscometer (DVL-B type manufactured by Tokyo Keiki Co., Ltd.) at 60 rpm, rotor No. 4, and at 6 rpm, rotor N.
According to o.3.

(13) Next, the solder resist composition is applied to both surfaces of the substrate 30 to a thickness of 20 μm, and 70
After performing a drying process under conditions of 20 ° C. for 20 minutes and 70 ° C. for 30 minutes, a photomask having a thickness of 5 mm on which patterns of the solder resist openings 71U and 71D are drawn is brought into close contact with the solder resist layer 70 to 1000 mJ / exposed to UV light of cm ² , developed with DMTG solution, 200μm
The openings 71U and 71D having the diameter of are formed. Then, heat treatment is further performed under the conditions of 80 ° C. for 1 hour, 100 ° C. for 1 hour, 120 ° C. for 1 hour, and 150 ° C. for 3 hours to cure the solder resist layer 70, thereby opening the opening 71.
A solder resist layer 70 having U and 71D and having a thickness of 20 μm is formed (see FIG. 4C). Figure 4
FIG. 8 is an enlarged view of the opening 71D shown in the ellipse C of FIG.
It shows in (A).

(14) Next, the substrate on which the solder resist layer (organic resin insulating layer) 70 is formed is degreased by alkali degreasing. Although alkaline degreasing is used here, neutral degreasing and acidic degreasing can also be performed.

(15) The substrate on which the solder resist layer 70 is formed is dipped in an etching solution of sulfuric acid / hydrogen peroxide solution, cupric chloride or ferric chloride to form openings 71U in the solder resist layer 70. Conductor circuit 1 exposed from 71D
58, the surface layer of the via 160 is removed (see FIG. 5A).

(16) Conductor circuit 1 exposed from openings 71U and 71D of solder resist layer 70 by immersing the substrate on which solder resist layer 70 is formed in acid such as sulfuric acid or hydrochloric acid.
58, the surface potential of the via 160 is adjusted, and the oxide film is removed (see FIG. 5B).

(17) The substrate is dipped in a tin displacement plating solution having the following composition, and openings 71U, 71 are formed from the solder resist.
By forming a tin layer 74 having a thickness of 0.6 μm on the surfaces of the conductor circuit 158 and the via 160 exposed through D, the solder pad 73 is formed (FIGS. 5C and 5C).
FIG. 8B is an enlarged view of a portion surrounded by an ellipse C in the inside. The opening diameter was 600 to 1000 μm.
Here, a tin borofluoride compound is used as the tin displacement plating solution, but tin chloride may be used instead. In the first embodiment, the conductor circuit 15 mainly made of copper is used.
8. Since the via 160 is etched and activated by acid, a single-layer metal film 74 made of tin can be formed by displacement plating. A single-layer metal was formed on both the solder bump forming portion and the external terminal portion. Tin displacement plating solution Thiourea 20 g / l Tin borofluoride (concentration 35% by volume) 80 ml / l Stabilizer (PEG) 5 ml / l Temperature 60 ° C Immersion time 10 minutes

(18) Thereafter, Sn / Pb, Sn / Sb, Sn / Ag, Sn / Ag / C are provided in the opening 71U above the solder resist layer 70 on the surface of the substrate on which the IC chip is mounted.
A solder solder paste made of u or Sn / Cu eutectic metal is printed. Further, Sn / Pb, Sn / Sb, S as the conductive adhesive 75 is provided in the lower opening 71D.
A solder paste made of a eutectic metal of either n / Ag or Sn / Ag / Cu is printed. Next, the conductive connection pin 9
8 is attached to and supported by a suitable pin holding device, and the fixing portion 98A of the conductive connecting pin 98 is brought into contact with the conductive adhesive 75 in the opening 71D. Then, reflow is performed to form the solder bumps 76 in the upper openings 71U and fix the conductive connection pins 98 to the conductive adhesive 75 through the lower openings 71D (see FIG. 6). In the first embodiment, the solder bumps 76 and the conductive adhesive 75 are Sn / Pb, Sn / S.
b, Sn / Ag, Sn / Ag / Cu, Sn / Cu, which is a eutectic metal and contains tin.
The adhesiveness with the solder pad 73 provided with No. 4 is high. As a method of attaching the conductive connecting pin 98, a conductive adhesive 75 formed in a ball shape or the like is placed in the opening 71D, or the conductive adhesive 75 is bonded to the fixing portion 98A to be conductive. The sex connection pin 98 may be attached and then reflowed.

After that, the IC chip 90 is placed so that the solder bumps 76 of the opening 71U on the upper side of the printed wiring board 20 correspond to the solder pads 92 of the IC chip 90, and the IC chip 90 is attached by reflowing. (See FIG. 7).

In the above-described embodiment, the interlayer resin insulation layer 5
As 0 and 150, a cycloolefin resin was used.
Epoxy resins can be used in addition to cycloolefin resins. The epoxy resin includes a sparingly soluble resin,
It contains soluble particles, a curing agent, and other components.
Each will be described below.

The epoxy resin which can be used in the production method of the present invention includes particles soluble in an acid or an oxidizing agent (hereinafter,
Soluble particles) are dispersed in a resin that is hardly soluble in an acid or an oxidant (hereinafter referred to as a hardly soluble resin).
The terms "poorly soluble" and "soluble" used in the present invention are referred to as "soluble" for the sake of convenience, those having a relatively high dissolution rate when immersed in a solution containing the same acid or oxidizing agent for the same time. For convenience, those having a relatively slow dissolution rate are called "poorly soluble".

Examples of the soluble particles include resin particles soluble in an acid or an oxidizing agent (hereinafter, soluble resin particles), inorganic particles soluble in an acid or an oxidizing agent (hereinafter, soluble inorganic particles), acid or an oxidizing agent. Examples thereof include soluble metal particles (hereinafter, soluble metal particles). These soluble particles may be used alone or in combination of two or more kinds.

The shape of the soluble particles is not particularly limited,
Examples thereof include spherical shapes and crushed shapes. Further, it is desirable that the soluble particles have a uniform shape. This is because it is possible to form a roughened surface having unevenness with a uniform roughness.

The average particle diameter of the soluble particles is 0.
1-10 micrometers is desirable. Within this particle size range, 2
You may contain the thing of different particle diameters more than a kind. That is, it contains soluble particles having an average particle size of 0.1 to 0.5 μm and soluble particles having an average particle size of 1 to 3 μm.
This makes it possible to form a more complicated roughened surface,
Excellent adhesion with conductor circuits. In addition, in this invention, the particle diameter of a soluble particle is the length of the longest part of a soluble particle.

Examples of the soluble resin particles include thermosetting resins, thermoplastic resins, and the like, which have a faster dissolution rate than the hardly soluble resin when immersed in a solution containing an acid or an oxidizing agent. It is not particularly limited as long as it is. Specific examples of the soluble resin particles include, for example, those made of epoxy resin, phenol resin, polyimide resin, polyphenylene resin, polyolefin resin, fluororesin, and the like, and may be one of these resins. However, it may be composed of a mixture of two or more kinds of resins.

As the soluble resin particles, resin particles made of rubber may be used. Examples of the rubber include polybutadiene rubber, various modified polybutadiene rubbers such as epoxy-modified, urethane-modified, (meth) acrylonitrile-modified, and (meth) acrylonitrile-butadiene rubber containing a carboxyl group. By using these rubbers, the soluble resin particles are easily dissolved in the acid or the oxidizing agent. That is, when dissolving soluble resin particles using an acid, it is possible to dissolve an acid other than a strong acid, and when dissolving soluble resin particles using an oxidizing agent, permanganese, which has a relatively weak oxidizing power, is dissolved. The acid salt can also be dissolved. Even when chromic acid is used, it can be dissolved at a low concentration. Therefore, the acid and the oxidizing agent do not remain on the resin surface, and as described later, when the catalyst such as palladium chloride is applied after the roughened surface is formed, the catalyst is not applied or the catalyst is oxidized. There is nothing to do.

Examples of the soluble inorganic particles include particles of at least one selected from the group consisting of aluminum compounds, calcium compounds, potassium compounds, magnesium compounds and silicon compounds.

Examples of the aluminum compound include alumina and aluminum hydroxide, and examples of the calcium compound include calcium carbonate and
Examples include calcium hydroxide and the like, examples of the potassium compound include potassium carbonate and the like, examples of the magnesium compound include magnesia, dolomite, basic magnesium carbonate and the like, and examples of the silicon compound include silica and zeolite. Is mentioned. These may be used alone or in combination of two or more.

Examples of the soluble metal particles include, for example,
Copper, nickel, iron, zinc, lead, gold, silver, aluminum,
Examples thereof include particles made of at least one selected from the group consisting of magnesium, calcium and silicon. The surface layer of these soluble metal particles may be coated with a resin or the like in order to ensure insulation.

When two or more kinds of the above soluble particles are mixed and used, the combination of the two kinds of soluble particles to be mixed is preferably a combination of resin particles and inorganic particles. Both can ensure the insulation of the resin film because the conductivity is low, it is easy to adjust the thermal expansion with the poorly soluble resin, cracks do not occur in the interlayer resin insulation layer made of the resin film, This is because peeling does not occur between the interlayer resin insulation layer and the conductor circuit.

The sparingly soluble resin is not particularly limited as long as it can retain the shape of the roughened surface when the roughened surface is formed in the interlayer resin insulating layer using an acid or an oxidizing agent. Examples thereof include thermosetting resins, thermoplastic resins, and composites thereof. Further, it may be a photosensitive resin obtained by imparting photosensitivity to these resins. By using the photosensitive resin, the via opening can be formed in the interlayer resin insulation layer by exposure and development processing. Among these, those containing a thermosetting resin are desirable. This is because the shape of the roughened surface can be maintained by the plating solution or various heat treatments.

Specific examples of the hardly soluble resin include epoxy resin, phenol resin, polyimide resin,
Examples thereof include polyphenylene resin, polyolefin resin and fluororesin. These resins may be used alone or in combination of two or more. Furthermore, an epoxy resin having two or more epoxy groups in one molecule is more desirable. Not only can the roughened surface described above be formed, but also because it has excellent heat resistance, stress concentration does not occur in the metal layer even under heat cycle conditions, and peeling of the metal layer does not easily occur. Because.

Examples of the epoxy resin include cresol novolac type epoxy resin, bisphenol A type epoxy resin, bisphenol F type epoxy resin, phenol novolac type epoxy resin, alkylphenol novolac type epoxy resin, biphenol F type epoxy resin, naphthalene type epoxy resin. Resin, dicyclopentadiene type epoxy resin, epoxidized product of a condensation product of a phenol and an aromatic aldehyde having a phenolic hydroxyl group,
Examples thereof include triglycidyl isocyanurate and alicyclic epoxy resin. These may be used alone or in combination of two or more. As a result, the heat resistance is excellent.

In the resin film used in the present invention, it is desirable that the soluble particles are substantially uniformly dispersed in the sparingly soluble resin. A roughened surface having irregularities of uniform roughness can be formed, and even if a via or a through hole is formed in the resin film, the adhesion of the metal layer of the conductor circuit formed thereon can be secured. Because. Moreover, you may use the resin film which contains a soluble particle only in the surface layer part which forms a roughened surface. As a result, the parts other than the surface layer of the resin film are not exposed to the acid or the oxidizing agent, so that the insulating property between the conductor circuits via the interlayer resin insulating layer is reliably maintained.

In the above resin film, the compounding amount of the soluble particles dispersed in the poorly soluble resin is preferably 3 to 40% by weight based on the resin film. If the content of the soluble particles is less than 3% by weight, it may not be possible to form a roughened surface having desired irregularities, and if it exceeds 40% by weight, when the soluble particles are dissolved using an acid or an oxidizing agent. In addition, the resin film may be dissolved to a deep portion, and the insulation between the conductor circuits via the interlayer resin insulation layer made of the resin film cannot be maintained, which may cause a short circuit.

It is desirable that the resin film contains a curing agent and other components in addition to the soluble particles and the poorly soluble resin. As the curing agent, for example,
Imidazole-based curing agents, amine-based curing agents, guanidine-based curing agents, epoxy adducts of these curing agents, microencapsulations of these curing agents, organics such as triphenylphosphine, tetraphenylphosphonium / tetraphenylborate, etc. Examples thereof include phosphine compounds.

The content of the above curing agent is preferably 0.05 to 10% by weight based on the resin film. 0.
If it is less than 05% by weight, the resin film is insufficiently cured, so that the degree of penetration of the acid or the oxidant into the resin film becomes large, and the insulating property of the resin film may be impaired. On the other hand, if it exceeds 10% by weight, an excessive amount of the curing agent component may modify the composition of the resin, which may lead to a decrease in reliability.

As the above-mentioned other components, for example, a filler such as an inorganic compound or a resin which does not influence the formation of the roughened surface can be mentioned. As the inorganic compound, for example,
Examples of the resin include silica, alumina, dolomite, and the like. Examples of the resin include polyimide resin, polyacrylic resin, polyamideimide resin, polyphenylene resin, melanin resin, and olefin resin. By including these fillers, it is possible to improve the performance of the printed wiring board by matching the coefficient of thermal expansion, improving heat resistance and chemical resistance.

Further, the resin film may contain a solvent. Examples of the solvent include acetone,
Ketones such as methyl ethyl ketone and cyclohexanone,
Aromatic hydrocarbons such as ethyl acetate, butyl acetate, cellosolve acetate, toluene, xylene and the like can be mentioned. These may be used alone or in combination of two or more.

Next, a printed wiring board 110 according to the second embodiment of the present invention will be described with reference to FIG. In the above-described first embodiment, the solder pad 73 is composed of the conductor circuit 158 and the tin layer 74 formed on the via 160. On the other hand, in the second embodiment, the solder pad 73 is composed of the conductor circuit 158 and the gold layer 174 formed on the via 160. In the second embodiment, since the conductor circuit 158 and the via 160 are covered with the noble metal, the solder pad 73 has excellent corrosion resistance. Further, since gold, which has a lower resistance than tin, is used, it is possible to further improve high frequency characteristics as compared with the first embodiment.

Here, the thickness of the gold layer 174 is 0.01 to 3
μm is desirable. If the thickness is less than 0.01 μm, the conductor circuit 158 and the via 160 cannot be completely covered, resulting in problems in strength and corrosion resistance. On the other hand, if the thickness exceeds 3 μm, the corrosion resistance is not improved, peeling occurs in the film, the strength deteriorates, and the cost becomes too expensive, which impairs the economical efficiency.
Desirable thickness is 0.05 to 2 μm. A more desirable range is 0.1 to 1 μm. In the meantime, even if the thickness varies, it is within a level at which no problem occurs.

Next, A.8 used in the method of manufacturing the printed wiring board according to the second embodiment of the present invention. Resin film for interlayer resin insulation layer, B. The resin filler will be described.

A. Preparation of resin film for interlayer resin insulation layer Bisphenol A type epoxy resin (epoxy equivalent 46
9, Epicort 1001) 30 manufactured by Yuka Shell Epoxy Co., Ltd.
40 parts by weight, cresol novolac type epoxy resin (epoxy equivalent 215, Epicron N-673 manufactured by Dainippon Ink and Chemicals, Inc.), triazine structure-containing phenol novolac resin (phenolic hydroxyl equivalent 120, Dainippon Ink and Chemicals Feno Light KA-705
2) 30 parts by weight of 20 parts by weight of ethyl diglycol acetate and 20 parts by weight of solvent naphtha were dissolved by heating while stirring, and epoxidized polybutadiene rubber having a terminal end (Denalex R-45 EPT manufactured by Nagase Kasei Kogyo Co., Ltd.)
Epoxy resin composition containing 15 parts by weight, 1.5 parts by weight of 2-phenyl-4,5-bis (hydroxymethyl) imidazole pulverized product, 2 parts by weight of finely pulverized silica, and 0.5 parts by weight of silicon-based defoaming agent. To prepare. The obtained epoxy resin composition was applied onto a PET film having a thickness of 38 μm by a roll coater so that the thickness after drying was 50 μm, and then dried at 80 to 120 ° C. for 10 minutes to obtain an interlayer resin. A resin film for an insulating layer is produced.

B. Preparation of Resin Filler 100 parts by weight of bisphenol F type epoxy monomer (Yukaka Shell Co., molecular weight: 310, YL983U), the surface of which is coated with a silane coupling agent has an average particle diameter of 1.6 μm and a maximum particle diameter. Is less than 15 μm
iO ₂ spherical particles (manufactured by Adtech, CRS 1101-
170 parts by weight of CE) and 1.5 parts by weight of a leveling agent (Perenol S4 manufactured by San Nopco Co.) were placed in a container and mixed by stirring to have a viscosity of 45 to 4 at 23 ± 1 ° C.
A resin filler of 9 Pa · s is prepared. As a curing agent, an imidazole curing agent (2E4MZ-manufactured by Shikoku Kasei Co., Ltd.
CN) 6.5 parts by weight are used.

Next, the method of manufacturing the printed wiring board described above with reference to FIG. 14 will be described with reference to FIGS.

(1) The starting material is a copper clad laminate 30A in which a copper foil 32 of 18 μm is laminated on both sides of a substrate 30 made of glass epoxy resin or BT (bismaleimide triazine) resin having a thickness of 0.8 mm. (Fig. 9
(See (A)). The resin is blended with inorganic particles such as 10 to 40% silica. First, this copper-clad laminate 30A
Is drilled, electroless plated, and patterned to form lower conductor circuits 34 and through holes 36 on both surfaces of the substrate 30 (FIG. 9B).
reference).

(2) The substrate 30 on which the through holes 36 and the lower conductor circuits 34 are formed is washed with water and dried, and then N
aOH (10 g / l), NaClO ₂ (40 g / l),
Blackening treatment using an aqueous solution containing Na ₃ PO ₄ (6 g / l) as a blackening bath (oxidizing bath), and NaOH (10 g / l)
l) and NaBH ₄ (6 g / l) are used as a reducing bath to carry out a reduction treatment to form a roughened surface 34α on the entire surface of the lower conductor circuit 34 including the through holes 36 (FIG. 9).
(See (C)).

(3) After the resin filler described in the above B is prepared, within 24 hours after preparation by the following method, in the through hole 36 and on the non-formation part of the lower layer conductor circuit 34 on one surface of the substrate 30. A layer of resin filler 40 is formed (FIG. 9).
(D)). That is, first, the resin filler 40 is pushed into the through hole 36 using a squeegee, and then 10
It is dried at 0 ° C. for 20 minutes. Next, a mask in which a portion corresponding to the lower layer conductor circuit 34 non-formation portion is opened is provided on the substrate 3
0, and a squeegee is used to form a layer of the resin filler 40 on the lower layer conductor circuit 34 non-forming portion which is a concave portion,
It is dried at 100 ° C. for 20 minutes. Then substrate 3
One side of 0, # 600 belt sanding paper (Sankyo Rikagaku)
By belt sander polishing using
And the land 36a of the through hole 36 are polished so that the resin filler 40 does not remain, and then buffing is performed to remove scratches due to the belt sander polishing. Such a series of polishing is similarly performed on the other surface of the substrate 30. Then, at 100 ℃ for 1 hour, 150 ℃
The resin filler 40 is cured by heating for 1 hour (see FIG. 10A).

(4) After the substrate 30 is washed with water and acid degreased, an etching solution is sprayed on both surfaces of the substrate 30 to light-etch the surface of the lower conductor circuit 34 and the surface of the land 36a of the through hole 36. By
A roughened surface 34β is formed on the entire surface of the lower layer conductor circuit 34 (see FIG. 10B). As the etching solution, an etching solution (Mec Etch Bond, manufactured by Mec Co., Ltd.) containing 10 parts by weight of imidazole copper (II) complex, 7 parts by weight of glycolic acid, and 5 parts by weight of potassium chloride is used.

(5) On both sides of the substrate 30, a resin film for the interlayer resin insulation layer, which is slightly larger than the substrate 30 prepared in A, is placed on the substrate 30, and the pressure is 4 kgf / cm ² and the temperature is 8
After temporary pressure bonding and cutting at 0 ° C and pressure bonding time of 10 seconds,
Further, the interlayer resin insulation layer 50 is formed by sticking using a vacuum laminator device by the following method (see FIG. 10C). That is, the resin film for the interlayer resin insulation layer is permanently pressure-bonded onto the substrate 30 under the conditions of a vacuum degree of 0.5 Torr, a pressure of 4 kgf / cm ² , a temperature of 80 ° C. and a pressure bonding time of 60 seconds, and then heat-bonded at 170 ° C. for 30 minutes. Let it harden.

(6) Next, the mask 49 having the through holes 49a formed therein is placed, and the via openings 51 are formed in the interlayer resin insulating layer 50 by the carbon dioxide laser (see FIG. 10D). The opening 51 may be formed by exposure / development processing instead of the laser.

(7) Substrate 30 with Via Opening 51 Formed
1 to 80 g of a solution containing 60 g / l of permanganate.
The surface of the interlayer resin insulation layer 50 including the inner wall of the via opening 51 is roughened 5 by immersing it for 0 minute to dissolve and remove the epoxy resin particles existing on the surface of the interlayer resin insulation layer 50.
0α is formed (see FIG. 11A).

(8) Next, the substrate 30 that has undergone the above processing
Is immersed in a neutralizing solution (made by Shipley) and then washed with water. Further, by applying a palladium catalyst to the surface of the substrate 30 that has been roughened (roughening depth 3 μm),
Surface of interlayer resin insulation layer 50 and large via opening 51
The catalyst nucleus is attached to the inner wall surface of the.

(9) Next, the substrate 30 is immersed in an electroless copper plating solution having the following composition to form an electroless copper plating film 53 having a thickness of 0.6 to 3.0 μm on the entire roughened surface 50α. It is formed (see FIG. 11B). [Electroless plating aqueous solution] NiSO ₄ 0.003 mol / l Tartaric acid 0.200 mol / l Copper sulfate 0.030 mol / l HCHO 0.050 mol / l NaOH 0.100 mol / l α, α′-bipyridyl 40 mg / l polyethylene glycol (PEG) 0.10 g / l [electroless plating conditions] 40 minutes at a liquid temperature of 35 ° C

(10) Next, after forming a resist 54 having a predetermined pattern on the substrate 30, electrolytic plating is performed under the following conditions to form an electrolytic plated film 56 (FIG. 11C).
reference). [Electrolytic plating aqueous solution] Sulfuric acid 2.24 mol / l Copper sulfate 0.26 mol / l Additive 19.5 ml / l (Atotech Japan Co., Caparaside HL) [Electrolytic plating conditions] Current density 1 A / dm ² hours 65 minutes temperature 22 ± 2 ℃

(11) After removing the resist 54,
By removing the electroless plated film 53 under the resist 54 by etching, the electroless plated film 53 and the electrolytic plated film 56 are removed.
To form a conductor circuit 58 and a via 60 (FIG. 1).
1 (D)). After that, the etching liquid is sprayed on both surfaces of the substrate 30 to etch the surfaces of the conductor circuits 58 and the vias 60, thereby forming a roughened layer 58α on the surfaces (see FIG. 12A).

(12) The above steps (5) to (11) are repeated to form the interlayer resin insulation layer 150, the conductor circuit 158 and the via 160. Then, the etching liquid is sprayed on both surfaces of the substrate to form the conductor circuit 158 and the via 160.
By etching the surface of the roughened layer 1 on the entire surface
58α is formed (see FIG. 12B). As the etching solution, a mixture of 10 parts by weight of imidazole copper (II) complex, 7 parts by weight of glycolic acid, 5 parts by weight of potassium chloride and 78 parts by weight of ion-exchanged water is used.

(13) Next, a cresol novolac type epoxy resin (manufactured by Nippon Kayaku Co., Ltd.) dissolved in diethylene glycol dimethyl ether (DMDG) to a concentration of 60% by weight was acrylated with 50% epoxy groups. Oligomer (molecular weight 4000) 46.67
15 parts by weight of bisphenol A type epoxy resin (manufactured by Yuka Shell Co., trade name: Epicoat 1001) of 80% by weight dissolved in methyl ethyl ketone, imidazole curing agent (manufactured by Shikoku Kasei Co., trade name: 2E4MZ-CN)
1.6 parts by weight, 4.5 parts by weight of a bifunctional acrylic monomer which is a photosensitive monomer (manufactured by Kyoei Chemical Co., Ltd., trade name: R604), and a polyvalent acrylic monomer (manufactured by Kyoei Chemical Co., Ltd., trade name: DPE6A) 1. 5 parts by weight and 0.71 part by weight of a dispersion type antifoaming agent (manufactured by San Nopco Ltd., trade name: S-65) were placed in a container, stirred and mixed to prepare a mixed composition, and light was applied to the mixed composition. 2.0 parts by weight of benzophenone (manufactured by Kanto Chemical Co., Inc.) as a weight initiator and 0.2 part by weight of Michler's ketone (manufactured by Kanto Chemical Co., Ltd.) as a photosensitizer were added to adjust the viscosity to 2
A solder resist composition (organic resin insulating material) adjusted to 2.0 Pa · s at 5 ° C. is obtained. The viscosity is measured by B
Type viscometer (Tokyo Keiki Co., Ltd., DVL-B type) 60 rpm
In the case of, the rotor No. 4 was used, and in the case of 6 rpm, the rotor No. 3 was used.

(14) Next, on both surfaces of the multilayer wiring board,
20 μm of the solder resist composition prepared in (13)
Apply with the thickness of. Then, at 70 ℃ for 20 minutes, 70 ℃
After performing a drying process for 30 minutes under a condition of, a photomask having a thickness of 5 mm on which a pattern of a solder resist opening is drawn is brought into close contact with the solder resist composition to 1000
It is exposed to ultraviolet rays of mJ / cm ² and developed with a DMTG solution to form openings 71U and 71D. Then, at 80 ° C for 1 hour, 100 ° C for 1 hour, and 120 ° C for 1 hour.
Heat treatment under the conditions of 150 ° C. for 3 hours to cure the solder resist composition, and the opening 71U,
20 μm thick solder resist layer 7 having 71D
0 is formed (see FIG. 12C). As the solder resist composition, a commercially available solder resist composition can also be used. Opening diameter is 600-1000μm
Formed between.

(15) Next, the substrate on which the solder resist layer (organic resin insulating layer) 70 is formed is degreased by alkaline degreasing. Although alkaline degreasing is used here, neutral degreasing and acidic degreasing can also be performed.

(16) The substrate on which the solder resist layer 70 is formed is dipped in an etching solution of sulfuric acid / hydrogen peroxide solution, cupric chloride or ferric chloride to form the conductor circuit 15
8. The surface layer of the via 160 is removed (see FIG. 13A).

(17) The substrate on which the solder resist layer 70 is formed is immersed in an acid such as sulfuric acid or hydrochloric acid to form the conductor circuit 15
8. The surface potential of the via 160 is adjusted and the oxide film is removed (see FIG. 13B).

(18) The substrate is dipped in a gold displacement plating solution having the following composition, and openings 71U and 71D are formed from the solder resist.
The solder pad 73 is formed by forming a gold layer 174 having a thickness of 0.03 to 0.05 μm on the surfaces of the conductor circuit 158 and the via 160 exposed through the via (see FIG. 13C). In the second embodiment, gold cyanide is used as the gold displacement plating solution. Gold layers were formed on both the solder bumps and the external terminals. Gold displacement plating solution Potassium cyanide 6g / l Tetrahydroboric acid 40ml / l Temperature 70 ° C Immersion time 3 minutes

(18) After that, Sn / Sn is formed in the opening 71U of the solder resist layer 70 on the surface of the substrate on which the IC chip is mounted.
Pb, Sn / Sb, Sn / Ag, Sn / Ag / Cu, S
A solder solder paste made of any eutectic metal of n / Cu is printed. Further, Sn / Pb, Sn / Sb, Sn as the conductive adhesive 75 is provided in the opening 71D on the other surface.
/ Ag, Sn / Ag / Cu, or Sn / Cu. Next, the conductive connecting pin 98 is attached to and supported by a suitable pin holding device, and the fixing portion 98A of the conductive connecting pin 98 is fixed to the opening 71D.
It is brought into contact with the conductive adhesive 75 inside. Then, reflow is performed to form the solder bumps 76 in the upper opening 71U and fix the conductive connecting pin 98 to the conductive adhesive 75 through the lower opening 71D (see FIG. 14).

In the second embodiment, since the noble metal forming the metal layer 174 is soft gold, the conductor circuit 158 and the via 1 do not diffuse into copper without interposing nickel.
A single-layer gold film 174 can be formed on 60. That is, in the prior art, hard gold, which can be wire-bonded to a gold wire, has been continuously used as gold when making a connection by a conductive connection pin. Since hard gold is electroless plated and diffuses into a conductor circuit made of copper, a coating cannot be formed without a nickel layer. On the other hand, in the second embodiment, it can be directly formed on the conductor circuit 158 and the via 160 made of copper.
Although gold is used here, platinum or palladium can also be used.

Next, a printed wiring board 210 according to the third embodiment of the present invention will be described with reference to FIG. In the above-described first embodiment, the solder pad 73 is composed of the conductor circuit 158 and the tin layer 74 formed on the via 160. On the other hand, in the third embodiment, the solder pad 73 is composed of the conductor circuit 158 and the silver layer 274 formed on the via 160. In the third embodiment, since the conductor circuit 158 and the via 160 are covered with the noble metal,
The corrosion resistance of the solder pad 73 is excellent. Further, since silver having the lowest resistance is used, it is possible to further improve high frequency characteristics as compared with the first and second embodiments.

Next, the manufacturing process of the printed wiring board of the third embodiment will be described. Since the manufacturing steps (1) to (17) of the third embodiment are the same as those of the second embodiment described above with reference to FIGS. 9 to 13, description will be given from step (18).

(18) The substrate is dipped in a silver displacement plating solution having the following composition, and the openings 71U and 71D are opened from the solder resist.
A silver layer 274 having a thickness of 0.07 to 0.11 μm is disposed on the surfaces of the conductor circuit 158 and the via 160 exposed through
The solder pad 73 is formed (see FIG. 15). In the third embodiment, silver nitrate is used as the silver displacement plating solution. Opening diameter is 60
It was between 0 and 1000 μm. A silver layer was formed on both the solder bump forming portion and the external terminal portion. Silver displacement plating solution Silver nitrate 8 g / l Ammonium compound 30 ml / l Sodium nitrite pentahydrate 60 ml / l Temperature 70 ° C Immersion time 5 minutes

(19) After this, the solder resist layer 70
The silver adhering to the surface of the is washed away.

(20) Then, thereafter, the opening 71U of the solder resist layer 70 on the surface of the substrate on which the IC chip is mounted.
A solder solder paste made of a eutectic metal of Sn / Ag, Sn / Ag / Cu, or Sn / Cu is printed on.
Further, the conductive adhesive 75 is placed in the opening 71D on the other surface.
As a step, a solder paste made of a eutectic metal of Sn / Ag or Sn / Ag / Cu is printed. The conductive connecting pins 98 are then mounted and supported on a suitable pin retainer,
The fixed portion 98A of the conductive connecting pin 98 is brought into contact with the conductive adhesive 75 in the opening 71D. And 200-250
Reflow is performed at ℃ and solder bumps 7 are placed in the upper opening 71U.
6 is formed, and the conductive connecting pin 98 is fixed to the conductive adhesive 75 through the lower opening 71D (see FIG. 15).

In the third embodiment, the solder bumps 76 and the conductive adhesive 75 are made of Sn / Ag, Sn / Ag / C.
Since it is a eutectic metal of either u or Sn / Cu and contains silver, it has high adhesion to the solder pad 73 having the silver layer 274. In the third embodiment, lead-free solder (Sn /
It has good compatibility with Ag and Sn / Ag / Cu), and these solders can be preferably used.

In the first to third embodiments described above, the metal layer of the solder pad is formed by displacement plating, but it may be formed by electroless plating with a catalyst interposed. However, while electroless plating is inexpensive, it tends to be unreacted unless a catalyst is applied, and it is difficult to control the film thickness.

As a comparative example, a nickel layer (thickness: 5 μm) was formed on a gold layer (thickness: 0.03 μm) as an exposed metal pad of a conductor circuit which is almost the same as that of the first embodiment.
m) was formed.

The tensile strengths of the conductive connection pins were measured before and after the reliability test of the first, second, third, and comparative examples, respectively, and dummy ICs were mounted to drop the voltage of the power supply. The results of measuring the amounts are compared and shown as a chart in FIG. Further, FIG. 17A shows a correlation diagram between thickness and strength of gold. Strength is about 12.0 from 0.03μm
When it approaches the N / pin and exceeds 3 μm, peeling occurs in the film and strength deterioration begins. Similar trends were seen for other metals (silver, tin, platinum, palladium).

The tensile strength was measured by sandwiching the direct tip end of the conductive connecting pin, pulling in the vertical direction, and breaking. As a result, in the examples, no problems were found in the tensile strength, the operation test, and the voltage drop amount at that time, regardless of the composition of the solder. in addition,
The amount of voltage drop is also a numerical value at which malfunction may occur.
Since there was no drop above (V), it is determined that no malfunction occurred. Further, since the amount of decrease in tensile strength after the reliability test was also 2-4%, there was no problem in terms of strength. On the other hand, in the comparative example, the tensile strength was lower than that in the example, and the decrease amount after the reliability test was about 12%. There was a problem in terms of adhesion strength between the conductive connection pin and the solder pad. The amount of voltage drop may exceed 0.1 (V), which may cause malfunction.

[0105]

As described above, according to the present invention, since a single metal layer is formed on the conductor circuit to form the solder pad, 2
The signal propagation speed can be increased as compared with the prior art printed wiring board in which the metal layers of the layers are formed. Moreover, since there is no nickel layer, the manufacturing cost can be reduced and the electrical characteristics can be improved.

[Brief description of drawings]

1A, 1B, 1C and 1D are manufacturing process diagrams of a printed wiring board according to a first embodiment of the present invention.

2 (A), (B), (C), and (D) are manufacturing process diagrams of a printed wiring board according to the first embodiment of the present invention.

3 (A), (B), (C), and (D) are manufacturing process diagrams of a printed wiring board according to the first embodiment of the present invention.

4 (A), (B) and (C) are manufacturing process diagrams of a printed wiring board according to the first embodiment of the present invention.

5 (A), (B), and (C) are manufacturing process diagrams of a printed wiring board according to the first embodiment of the present invention.

FIG. 6 is a cross-sectional view of a printed wiring board according to the first embodiment of the present invention.

FIG. 7 shows a printed wiring board according to the first embodiment of the present invention, which is I
It is sectional drawing which shows the state which mounted the C chip.

8A, 8B, and 8C are enlarged cross-sectional views of a solder pad portion of a printed wiring board.

9 (A), (B), (C), and (D) are manufacturing process diagrams of a printed wiring board according to a second embodiment of the present invention.

10A, 10B, 10C, and 10D are manufacturing process diagrams of a printed wiring board according to a second embodiment of the present invention.

11 (A), (B), (C) and (D) are manufacturing process diagrams of a printed wiring board according to a second embodiment of the present invention.

12A, 12B, and 12C are manufacturing process diagrams of a printed wiring board according to a second embodiment of the present invention.

13 (A), (B), and (C) are manufacturing process diagrams of a printed wiring board according to a second embodiment of the present invention.

FIG. 14 is a sectional view of a printed wiring board according to a second embodiment of the present invention.

FIG. 15 is a sectional view of a printed wiring board according to a third embodiment of the present invention.

FIG. 16 is a cross-sectional view of a connection portion of a conductive connection pin of a conventional printed wiring board.

FIG. 17 (A) is a graph showing tensile strength,
(B) is a graph showing a voltage drop.

FIG. 18 is a chart comparing the tensile strength and the voltage drop amount of the example and the comparative example.

[Explanation of symbols]

30 core substrate 34 Lower layer conductor circuit 36 through hole 40 resin filler 50 interlayer resin insulation layer 58 Conductor circuit 60 vias 70 Solder resist layer 71U, 71D opening 73 Solder pad 74 Tin layer (metal layer) 75 Conductive adhesive 76 Solder bump 80A, 80B Build-up wiring layer 90 IC chip 92 Solder pad 94 Daughter Board 98 Conductive connection pin 150 interlayer resin insulation layer 158 Conductor circuit 158α roughening layer 160 vias 174 Gold layer (metal layer) 274 Silver layer (metal layer)

Claims (9)

[Claims] 1. A printed wiring board for mounting a conductive connection pin on a conductor circuit, which is exposed by opening a part of an organic resin insulating layer, with a conductive adhesive interposed, in the exposed conductor circuit, A printed wiring board, characterized in that a single metal layer of tin or a noble metal is applied and conductive connecting pins are attached with a conductive adhesive interposed. 2. The printed wiring board according to claim 1, wherein the noble metal is any one of gold, silver, platinum, and palladium. 3. The printed wiring board according to claim 1, wherein the metal layer has a thickness of 0.01 to 3 μm. 4. The roughened layer is formed on the surface of the conductor circuit, according to claim 1.
Printed wiring board. 5. The conductive adhesive is Sn / Pb, Sn
The eutectic metal of any one of / Sb, Sn / Ag, and Sn / Ag / Cu. 6. The conductive adhesive is Sn / Pb, Sn
The eutectic metal of any one of / Sb, Sn / Ag, and Sn / Ag / Cu, and the metal layer is tin. The printed wiring board according to claim 1, wherein the metal layer is tin. 7. The conductive adhesive is Sn / Ag, Sn
The eutectic metal of any one of / Ag / Cu and the metal layer is silver, the printed wiring board according to claim 1. 8. A single-layer metal layer is formed on a conductor circuit mainly made of copper, which is exposed by opening a part of the organic resin insulating layer, through at least steps (a) to (c).
Manufacturing method of printed wiring board to which conductive connecting pin is attached with conductive adhesive interposed: (a) The printed wiring board in which the conductor circuit is exposed from the organic resin insulating layer is treated with sulfuric acid-hydrogen peroxide solution, second chloride. A step of immersing in an etching solution of either copper or ferric chloride,
(B) acid activation step, (c) tin or noble metal displacement plating to apply the single metal layer on the conductor circuit. 9. The method of manufacturing a printed wiring board according to claim 8, wherein the noble metal forming the metal layer is soft gold.