JP2003165783A - Lightweight porous sintered compact and method for producing the same - Google Patents

Lightweight porous sintered compact and method for producing the same

Info

Publication number
JP2003165783A
JP2003165783A JP2001361039A JP2001361039A JP2003165783A JP 2003165783 A JP2003165783 A JP 2003165783A JP 2001361039 A JP2001361039 A JP 2001361039A JP 2001361039 A JP2001361039 A JP 2001361039A JP 2003165783 A JP2003165783 A JP 2003165783A
Authority
JP
Japan
Prior art keywords
weight
sintered body
raw material
porous sintered
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001361039A
Other languages
Japanese (ja)
Other versions
JP3816376B2 (en
Inventor
Tsukasa Kamio
典 神尾
Koichi Kawamura
弘一 川村
Eiichi Koyama
栄一 小山
Yoshiharu Nishino
善春 西野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suminoe Textile Co Ltd
Original Assignee
Suminoe Textile Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suminoe Textile Co Ltd filed Critical Suminoe Textile Co Ltd
Priority to JP2001361039A priority Critical patent/JP3816376B2/en
Publication of JP2003165783A publication Critical patent/JP2003165783A/en
Application granted granted Critical
Publication of JP3816376B2 publication Critical patent/JP3816376B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method where a lightweight, porous sintered compact is produced by using chaff ash, which is disposed as unused wastes, as a raw material. <P>SOLUTION: A raw material composition, which comprises chaff ash, inorganic aggregate, cement and water, is molded. Next, after being subjected to an aging process where hydration reaction of the cement proceeds, the molded body is burned at a high temperature so that the porous sintered compact is obtained. Silica rock or silicate is preferably used as the inorganic aggregate, and the burning temperature is preferably set at 800-1,500°C. <P>COPYRIGHT: (C)2003,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】この発明は、従来有効利用の
途が殆どなかったもみ殻灰を原料にして、例えば濾過
材、吸着フィルター、バイオテクノロジー分野等での担
持体等として用いられる軽量多孔質焼結体及びその製造
方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention uses a rice husk ash as a raw material, which has hardly been used effectively in the past, and is used as a filter material, an adsorption filter, a lightweight porous material used as a carrier in the field of biotechnology, etc. The present invention relates to a sintered body and a method for manufacturing the same.

【0002】[0002]

【従来の技術】従来より、食器、衛生器、或いは電気、
電子材料等の工業製品として用いられている陶磁器は、
粘土、セリサイト、ロウ石等の可塑性原料を用いてこれ
を高温焼成により焼結または溶融せしめて製造されてい
るが、これらの可塑性原料が近年枯渇化の傾向にあり、
この分野においては新たな代替原料の開発が急務となっ
ている。また、従来の陶磁器は一般に重いものが多く、
新たな用途の拡がりに伴って軽量化の要請も多くなって
きている。
2. Description of the Related Art Conventionally, tableware, sanitary equipment, or electricity,
Ceramics used as industrial products such as electronic materials,
Clay, sericite, a raw material such as wax stone is manufactured by sintering or melting it by high temperature firing, but these plastic raw materials tend to be depleted in recent years,
There is an urgent need to develop new alternative raw materials in this field. In addition, conventional ceramics are generally heavy,
With the spread of new applications, there are increasing demands for weight reduction.

【0003】一方、稲の脱穀の際に生じるもみ殻は、農
業廃棄物として毎年多量に排出され、その一部が燃料と
して用いられてはいるものの、その殆どが有効利用の途
がなく、そのまま廃棄するか、或いは焼却してもみ殻灰
としてからこれを廃棄処分にしているのが現状である。
近年の資源の有効活用、リサイクル利用の気運の高まり
の中、このようなもみ殻やもみ殻灰についても有効利用
の具体的方策をたてることが強く望まれていたところで
ある。
On the other hand, the rice husks produced during threshing of rice are discharged as agricultural wastes in large amounts every year, and some of them are used as fuels, but most of them have no way to be effectively used and remain as they are. At present, it is the waste ash that is discarded or incinerated and then disposed of.
In recent years, with the growing interest in effective use of resources and recycling, it has been strongly desired to devise a concrete measure for effective use of rice husks and rice husk ash.

【0004】[0004]

【発明が解決しようとする課題】本発明者らは、もみ殻
灰にはケイ酸(SiO2 )が多く含有され、もみ殻灰の
かさ密度が0.25程度と小さいことに着目し、このよ
うなもみ殻灰は陶磁器の原料成分として利用し得て、か
つ得られる焼結体が軽量なものになるのではないかと考
えた。
The present inventors have noticed that the rice husk ash contains a large amount of silicic acid (SiO 2 ), and the rice husk ash has a low bulk density of about 0.25. We thought that such rice husk ash could be used as a raw material component for ceramics, and that the resulting sintered body would be lightweight.

【0005】この発明は、前記技術的背景に鑑みつつ上
記着想のもとになされたものであって、未利用のまま廃
棄されていたもみ殻灰を原料にして、軽量でかつ多孔質
の焼結体を製造する方法を提供することを目的とする。
The present invention has been made based on the above-mentioned idea in view of the above technical background, and is made of rice husk ash, which has been discarded as an unused material, as a raw material, and is lightweight and porous. It is an object to provide a method for producing a conjugate.

【0006】[0006]

【課題を解決するための手段】上記の目的は、もみ殻
灰、無機質骨材及びセメントを含む固形原料に水が加え
られてなる原料組成物を成形して成形体を得る工程と、
セメントの水和反応により前記成形体を硬化させる養生
工程と、前記養生を行った成形体を高温で焼成して多孔
質焼結体を得る焼結工程とを含むことを特徴とする軽量
多孔質焼結体の製造方法によって達成される。
[Means for Solving the Problems] The above object is to obtain a compact by molding a raw material composition obtained by adding water to a solid raw material containing rice husk ash, inorganic aggregate and cement,
Light-weight porous material including a curing step of curing the molded body by a hydration reaction of cement, and a sintering step of firing the cured molded body at a high temperature to obtain a porous sintered body. This is achieved by the method for producing a sintered body.

【0007】本製造方法によれば、軽量で多孔質の焼結
体を得ることができる。この焼結体の多孔質構造は、図
1の電子顕微鏡写真に示すように、外部に通ずる連続状
の多孔質構造を呈するものであり、例えば濾過材、吸着
フィルター、バイオテクノロジー分野等での担持体等と
して用いることができる。なお、前記軽量性は、もみ殻
灰を原料の1つに用いていること及び多孔質構造である
ことが大きく寄与しているものと考えられる。
According to this manufacturing method, a lightweight and porous sintered body can be obtained. The porous structure of this sintered body is, as shown in the electron micrograph of FIG. 1, a continuous porous structure that communicates with the outside, and is, for example, a filter material, an adsorption filter, or a support in the biotechnology field. It can be used as a body or the like. In addition, it is considered that the use of rice husk ash as one of the raw materials and the porous structure greatly contribute to the lightness.

【0008】また、従来の陶磁器の製造においては焼結
による収縮の程度が大きかった(例えば収縮率10〜3
0%程度)のに対し、本製造方法によれば、もみ殻灰を
原料に用いることで焼結による収縮を抑制する(例えば
収縮率2%程度)ことができ、これにより所望の形状を
正確に形成できる利点があるし、このように焼結時の収
縮が小さいので前記連続状の多孔質構造を形成できるも
のと考えられる。
Further, in the production of conventional ceramics, the degree of shrinkage due to sintering was large (for example, the shrinkage rate was 10 to 3).
On the other hand, according to the present manufacturing method, by using rice husk ash as a raw material, shrinkage due to sintering can be suppressed (for example, a shrinkage rate of about 2%), and thus a desired shape can be accurately obtained. It is considered that the continuous porous structure can be formed because the shrinkage during sintering is small as described above.

【0009】更に、本製造方法は、従来未利用のまま廃
棄されていたもみ殻灰を主原料の1つとするものである
から、資源の有効利用を図り得るし、もみ殻灰の廃棄を
回避できて環境保全にも貢献できると共に、低コストで
軽量多孔質焼結体を製造できる。
Further, in this manufacturing method, since rice husk ash, which has been conventionally discarded as unused, is used as one of the main raw materials, effective use of resources can be achieved and waste of rice husk ash can be avoided. As a result, it is possible to contribute to environmental protection and to manufacture a lightweight porous sintered body at low cost.

【0010】この発明の製造方法では、固形原料におけ
る、もみ殻灰の含有率を20〜60重量%、無機質骨材
の含有率を20〜60重量%、セメントの含有率を10
〜50重量%の範囲に設定するのが好ましい。上記特定
範囲に設定することにより、1500℃以下の温度で焼
結を行うことができるものとなる(即ち高温の焼成温度
を要しない)し、養生工程後の(焼結前の)成形体の強
度が十分に得られて成形体のハンドリング性に優れ、か
つ得られる焼結体の強度も十分に向上させることができ
る。
In the production method of the present invention, the content of rice husk ash in the solid raw material is 20 to 60% by weight, the content of inorganic aggregate is 20 to 60% by weight, and the content of cement is 10%.
It is preferably set in the range of ˜50% by weight. By setting in the above-mentioned specific range, it becomes possible to perform sintering at a temperature of 1500 ° C. or lower (that is, high firing temperature is not required), and the molded body after the curing step (before sintering) can be obtained. Sufficient strength can be obtained, the handleability of the molded body is excellent, and the strength of the obtained sintered body can be sufficiently improved.

【0011】上記原料組成物は、固形原料100重量部
に対して水が10〜50重量部混合されたものからなる
のが、好ましい。水の配合量をこのような範囲に設定す
ることにより、セメントの水和反応を十分に促進させる
ことができると共に、成形しやすいものとなる。
The above raw material composition is preferably composed of 100 parts by weight of the solid raw material and 10 to 50 parts by weight of water mixed therein. By setting the blending amount of water in such a range, the hydration reaction of the cement can be sufficiently promoted and the molding becomes easy.

【0012】無機質骨材としては珪石及び珪酸塩からな
る群より選ばれる1種または2種以上の骨材を用いるの
が、焼結体の強度をより向上できる点で好ましい。
As the inorganic aggregate, it is preferable to use one kind or two or more kinds of aggregates selected from the group consisting of silica stone and silicate from the viewpoint that the strength of the sintered body can be further improved.

【0013】焼結工程での焼成温度は800〜1500
℃に設定するのが好ましい。このような範囲に設定すれ
ば、焼結体の製造効率を向上できると共に、連続状の多
孔質構造を備えた焼結体を確実に製造できる。
The firing temperature in the sintering process is 800-1500.
It is preferable to set it at ℃. By setting such a range, it is possible to improve the production efficiency of the sintered body and to reliably produce the sintered body having a continuous porous structure.

【0014】また、原料組成物に、パルプ繊維、合成繊
維、ガラス繊維、炭素繊維及び鉱物繊維からなる群より
選ばれる1種または2種以上の繊維を含有せしめるもの
とし、前記もみ殻灰、無機質骨材及びセメントの総量1
00重量部に対して前記繊維の配合量を2〜5重量部に
設定するのが、好ましい。このような特定繊維を特定量
含有せしめることで、成形体の保形性を向上できるし、
養生工程後の(焼結前の)成形体の強度、更には焼結体
の強度を一層向上させることができると共に、焼結体の
寸法安定性も向上させることができる。
The raw material composition may contain one or more kinds of fibers selected from the group consisting of pulp fibers, synthetic fibers, glass fibers, carbon fibers and mineral fibers. Total amount of aggregate and cement 1
It is preferable to set the blending amount of the fibers to 2 to 5 parts by weight with respect to 00 parts by weight. By containing a specific amount of such a specific fiber, it is possible to improve the shape retention of the molded body,
The strength of the molded body (before sintering) after the curing step, and further the strength of the sintered body can be further improved, and the dimensional stability of the sintered body can also be improved.

【0015】更に、原料組成物に、水溶性繊維素類及び
水溶性ポリマーからなる群より選ばれる1種または2種
以上の粘性付与剤を含有せしめるものとし、前記もみ殻
灰、無機質骨材及びセメントの総量100重量部に対し
て前記粘性付与剤の配合量を0.5〜4重量部に設定す
るのが、好ましい。これにより原料組成物に粘性や滑性
を十分に付与でき、押出成形を行う場合においても成形
性良く成形体を得ることができ、ひいては高品質の焼結
体を製造できる。
Furthermore, the raw material composition may contain one or more kinds of a viscosity-imparting agent selected from the group consisting of water-soluble fibrin and water-soluble polymer, and the rice husk ash, inorganic aggregate and It is preferable to set the compounding amount of the viscosity imparting agent to 0.5 to 4 parts by weight based on 100 parts by weight of the total amount of cement. This makes it possible to sufficiently impart viscosity and lubricity to the raw material composition, obtain a molded product with good moldability even when extrusion molding is performed, and eventually manufacture a high quality sintered product.

【0016】また、この発明の軽量多孔質焼結体は、上
記いずれかの製造方法によって製造されたことを特徴と
するものである。
The lightweight porous sintered body of the present invention is characterized by being manufactured by any one of the above manufacturing methods.

【0017】[0017]

【発明の実施の形態】この発明の軽量多孔質焼結体の製
造方法は、もみ殻灰、無機質骨材及びセメントを含む固
形原料に水が加えられてなる原料組成物を成形して成形
体を得る工程と、セメントの水和作用により前記成形体
を硬化させる養生工程と、前記養生を行った成形体を高
温で焼成して多孔質焼結体を得る焼結工程とを含むこと
を特徴とする。
BEST MODE FOR CARRYING OUT THE INVENTION The method for producing a lightweight porous sintered body according to the present invention comprises molding a raw material composition obtained by adding water to a solid raw material containing rice husk ash, inorganic aggregate and cement. And a curing step of curing the molded body by hydration of cement, and a sintering step of firing the cured molded body at a high temperature to obtain a porous sintered body. And

【0018】本製造方法により得られた焼結体の電子顕
微鏡写真を図1に示す。この図1から明らかなように、
得られた焼結体は、外部に通ずる連続状の多孔質構造を
呈している。本製造方法は、もみ殻灰を原料の1つに用
いると共に、得られた焼結体が上記のような多孔質構造
を有するので、非常に軽量なものとなる。
An electron micrograph of the sintered body obtained by this manufacturing method is shown in FIG. As is clear from FIG. 1,
The obtained sintered body has a continuous porous structure communicating with the outside. The present manufacturing method uses rice husk ash as one of the raw materials, and the obtained sintered body has the above-mentioned porous structure, so that it is extremely lightweight.

【0019】更に、もみ殻灰を原料に用いているので、
焼結による収縮が非常に小さく、従って所望の形状を正
確に形成できる利点がある。
Furthermore, since rice husk ash is used as a raw material,
There is an advantage that shrinkage due to sintering is very small, and therefore a desired shape can be accurately formed.

【0020】加えて、従来は廃棄されていたもみ殻灰を
有効利用しているので、低コストで多孔質焼結体を製造
できるし、もみ殻灰の廃棄を回避できて環境保全にも貢
献できる。
In addition, since the rice husk ash, which has been conventionally discarded, is effectively used, a porous sintered body can be manufactured at a low cost, and the rice husk ash can be avoided, which contributes to environmental protection. it can.

【0021】この発明において、製造原料として用いる
もみ殻灰は、精米脱穀等によって得られるもみ殻を燃焼
して得られる灰であれば、どのようなものでも用いるこ
とができ、もみ殻を燃料として用いた後の灰(通常、黒
色)も含む。一般に、燃焼温度が低いと灰の色は黒く、
燃焼温度が500℃程度では灰は非晶質シリカであり、
燃焼温度が1000℃程度では結晶化が進み白色を呈
し、このようにもみ殻灰の色調や結晶の種類は、焼成の
際の雰囲気や焼成温度、焼成時間によって異なるが、こ
れらのいずれをも使用することができ、もみ殻灰の色調
や結晶の種類等は特に問わない。
In the present invention, as the rice husk ash used as a raw material for manufacturing, any ash obtained by burning rice husk obtained by milling rice can be used, and the rice husk can be used as a fuel. Includes ash (usually black) after use. Generally, when the combustion temperature is low, the ash color is black,
At a combustion temperature of about 500 ° C, the ash is amorphous silica,
When the combustion temperature is about 1000 ° C, crystallization progresses to give a white color, and the color tone of the rice husk ash and the type of crystals differ depending on the atmosphere during firing, firing temperature, and firing time. Any of these can be used. The color tone of rice husk ash and the type of crystals are not particularly limited.

【0022】もみ殻灰の組成の典型例を表1に示す。Table 1 shows typical examples of the composition of rice husk ash.

【0023】[0023]

【表1】 [Table 1]

【0024】本製造方法では、このようなもみ殻灰を原
料の1つに用いることで、軽量性を確保できると共に、
焼結時の収縮を十分に抑制し得て、連続状の多孔質構造
の形成を可能にしているものと考えられる。
In the present manufacturing method, by using such rice husk ash as one of the raw materials, it is possible to secure the lightness and
It is considered that the shrinkage during sintering can be sufficiently suppressed and the continuous porous structure can be formed.

【0025】前記固形原料中のもみ殻灰の含有率は20
〜60重量%の範囲とするのが好ましい。20重量%未
満では、養生後の成形体の耐火度が高くなって焼結する
のに著しく高温の焼成温度が必要となる上に、軽量化を
十分に図ることができなくなるし、焼結時の収縮の抑制
が不十分となって連続状の多孔質構造の形成割合が低下
するので、好ましくない。一方、60重量%を超える
と、十分な強度を確保するのが困難となって焼結体の形
状維持が難しく、例えば手で触れても表面がぼろぼろと
欠落する恐れがあるので、好ましくない。
The content rate of rice husk ash in the solid raw material is 20.
It is preferably in the range of ˜60% by weight. If it is less than 20% by weight, the fire resistance of the molded body after curing becomes high and a remarkably high firing temperature is required for sintering, and it becomes impossible to sufficiently reduce the weight. Is insufficiently controlled, and the formation rate of the continuous porous structure is reduced, which is not preferable. On the other hand, if it exceeds 60% by weight, it is difficult to secure sufficient strength and it is difficult to maintain the shape of the sintered body, and for example, the surface may be shattered even if it is touched by hand, which is not preferable.

【0026】また、無機質骨材は、焼結体における骨格
形成、即ち強度の向上のために必須の原料成分である。
この無機質骨材としては、特に限定されるものではない
が、例えば二酸化珪素を主成分とする珪石(石英等)、
川砂、山砂、海砂、或いは珪酸塩等が挙げられる。前記
珪酸塩としては、例えば粘土、長石、高炉滓(スラッ
グ)、フライアッシュ等が挙げられる。これらの中で
も、珪石や珪酸塩を用いるのが、焼結体の強度をより向
上できる点で、好ましい。特に好ましいのは無機質骨材
として珪石を用いる構成であり、焼結体の強度をより一
層向上できる利点がある。
The inorganic aggregate is an essential raw material component for forming a skeleton in the sintered body, that is, for improving the strength.
The inorganic aggregate is not particularly limited, but for example, silica stone containing silicon dioxide as a main component (quartz or the like),
Examples include river sand, mountain sand, sea sand, and silicates. Examples of the silicate include clay, feldspar, blast furnace slag, fly ash, and the like. Among these, it is preferable to use silica stone or silicate from the viewpoint that the strength of the sintered body can be further improved. Particularly preferable is a structure in which silica stone is used as the inorganic aggregate, which has an advantage that the strength of the sintered body can be further improved.

【0027】前記固形原料中の無機質骨材の含有率は2
0〜60重量%の範囲とするのが好ましい。20重量%
未満では、十分な強度を確保するのが困難となって焼結
体の形状維持が難しく、例えば手で触れても表面がぼろ
ぼろと欠落する恐れがあるので、好ましくない。一方、
60重量%を超えると、養生後の成形体の耐火度が高く
なって焼結するのに著しく高温の焼成温度が必要となる
ので好ましくない。
The content of the inorganic aggregate in the solid raw material is 2
It is preferably in the range of 0 to 60% by weight. 20% by weight
If it is less than the above range, it is difficult to secure sufficient strength, and it is difficult to maintain the shape of the sintered body. For example, the surface may be shattered even if it is touched by hand, which is not preferable. on the other hand,
If it exceeds 60% by weight, the fire resistance of the molded body after curing becomes high and a remarkably high firing temperature is required for sintering, which is not preferable.

【0028】また、製造原料として用いるセメントとし
ては、どのような種類のものでも用いることができ、例
えばポルトランドセメント、マグネシアセメント、アル
ミナセメント、混合セメント、天然セメント等を例示で
き、これらの1種を単独で用いても良いし、2種以上を
混合して用いても良い。このようなセメントを必須成分
として含有せしめることで、セメントと、もみ殻灰及び
無機質骨材との間の水和反応により、養生工程後の(焼
結前の)成形体の強度を確保することができ、該成形体
のハンドリング性が良好なものとなる。中でも、アルミ
ナセメントを用いるのが好ましい。
As the cement used as a raw material for production, any kind of cement can be used, and examples thereof include Portland cement, magnesia cement, alumina cement, mixed cement and natural cement, and one of these can be used. They may be used alone or in combination of two or more. By including such cement as an essential component, the hydration reaction between the cement and the rice husk ash and the inorganic aggregate ensures the strength of the molded body after the curing process (before sintering). And the handling property of the molded article becomes good. Among them, it is preferable to use alumina cement.

【0029】前記固形原料中のセメントの含有率は10
〜50重量%の範囲とするのが好ましい。10重量%未
満では、養生工程後の(焼結前の)成形体の強度が低下
してハンドリング性が悪くなるので、好ましくない。一
方、50重量%を超えると、養生後の成形体の耐火度が
高くなって焼結するのに著しく高温の焼成温度が必要と
なるので好ましくない。
The content of cement in the solid raw material is 10
It is preferably in the range of ˜50% by weight. If it is less than 10% by weight, the strength of the molded product after the curing step (before sintering) is lowered and the handling property is deteriorated, which is not preferable. On the other hand, if it exceeds 50% by weight, the fire resistance of the molded body after curing becomes high and a remarkably high firing temperature is required for sintering, which is not preferable.

【0030】前記原料組成物には、更に、パルプ繊維、
合成繊維、ガラス繊維、炭素繊維及び鉱物繊維からなる
群より選ばれる1種または2種以上の繊維を含有せしめ
るのが好ましく、かつ前記もみ殻灰、無機質骨材及びセ
メントの総量100重量部に対して前記繊維の配合量を
2〜5重量部に設定するのが好ましい。このような特定
繊維を特定量含有せしめることで、養生前の成形体の保
形性を向上できるし、養生工程後の(焼結前の)成形体
の強度、更には焼結体の強度や軽量性を向上できると共
に、焼結体の寸法安定性も向上できる。配合量が2重量
部未満では前記効果(強度の向上等)が殆ど得られない
し、配合量が5重量部を超えても同様に前記効果が期待
できないので、好ましくない。
The raw material composition further includes pulp fiber,
It is preferable to contain one kind or two or more kinds of fibers selected from the group consisting of synthetic fibers, glass fibers, carbon fibers and mineral fibers, and to 100 parts by weight of the total amount of the rice husk ash, the inorganic aggregate and the cement. It is preferable to set the blending amount of the fibers to 2 to 5 parts by weight. By containing a specific amount of such a specific fiber, the shape retention of the molded body before curing can be improved, and the strength of the molded body after the curing step (before sintering), and further the strength of the sintered body, It is possible to improve the lightness and also improve the dimensional stability of the sintered body. If the compounding amount is less than 2 parts by weight, the above-mentioned effects (improvement in strength, etc.) are hardly obtained, and if the compounding amount exceeds 5 parts by weight, the same effect cannot be expected.

【0031】更に、前記原料組成物に、水溶性繊維素類
及び水溶性ポリマーからなる群より選ばれる1種または
2種以上の粘性付与剤を含有せしめるものとし、前記も
み殻灰、無機質骨材及びセメントの総量100重量部に
対して前記粘性付与剤の配合量を0.5〜4重量部に設
定する場合には、成形性を顕著に向上できる利点があ
る。即ち、成形を押出成形で行う場合等には原料組成物
に粘性や滑性が不足していると成形が困難になって良好
な成形体が得られがたいのであるが、このような場合で
あっても、前記特定の粘性付与剤を特定量含有せしめる
ことで、成形性良く成形体を得ることができ、ひいては
高品質の焼結体を製造できる。また、前記粘性付与剤
は、焼成時に燃えて揮散してしまうので、より多孔度の
大きい焼結体を製造することができ、ひいては得られる
焼結体のかさ密度をより小さく設計できるし、焼結体の
吸水率もより大きいものとなる。配合量が0.5重量部
未満では前記効果(成形性向上)が殆ど得られないし、
配合量が4重量部を超えても同様に前記効果が期待でき
ないので、好ましくない。
Further, the raw material composition may contain one or more kinds of viscosity-imparting agents selected from the group consisting of water-soluble fibrins and water-soluble polymers, the rice husk ash and the inorganic aggregate. And, when the compounding amount of the viscosity imparting agent is set to 0.5 to 4 parts by weight with respect to the total amount of 100 parts by weight of cement, there is an advantage that the formability can be remarkably improved. That is, when the molding is carried out by extrusion molding, if the raw material composition lacks viscosity and lubricity, molding becomes difficult and it is difficult to obtain a good molded body. Even if there is a specific amount of the specific viscosity-imparting agent, a molded product can be obtained with good moldability, and a high quality sintered product can be manufactured. Further, since the viscosity-imparting agent burns and volatilizes during firing, it is possible to produce a sintered body having a higher porosity, and further, it is possible to design the bulk density of the obtained sintered body to be smaller and to burn it. The water absorption rate of the aggregate is also higher. If the blending amount is less than 0.5 parts by weight, the above effect (improvement in moldability) is hardly obtained, and
Even if the blending amount exceeds 4 parts by weight, the above effect cannot be expected in the same manner, which is not preferable.

【0032】前記水溶性繊維素類としては、特に限定さ
れるものではないが、例えばカルボキシメチルセルロー
ス、ヒドロキシエチルセルロース、微小パルプ等を例示
できる。また、前記水溶性ポリマーとしては、特に限定
されるものではないが、例えばポリビニルアルコール、
ポリ酢酸ビニルのケン化物等を例示できる。
The water-soluble fibrin is not particularly limited, and examples thereof include carboxymethyl cellulose, hydroxyethyl cellulose, micropulp and the like. Further, the water-soluble polymer is not particularly limited, for example, polyvinyl alcohol,
Examples thereof include saponified products of polyvinyl acetate.

【0033】前記原料組成物中における水の配合量は、
前記固形原料(もみ殻灰、無機質骨材、セメント等)1
00重量部に対して10〜50重量部に設定するのが好
ましい。10重量部未満では十分な成形体が得られない
ばかりでなく、セメントの水和反応の進行が遅くなるの
で、好ましくない。また50重量部を超えると余剰水が
多くなって養生前の成形体の保形性が低下するので、好
ましくない。
The amount of water blended in the raw material composition is
Solid materials (rice husk ash, inorganic aggregate, cement, etc.) 1
It is preferably set to 10 to 50 parts by weight with respect to 00 parts by weight. If it is less than 10 parts by weight, not only a sufficient molded article cannot be obtained, but also the progress of the hydration reaction of cement is delayed, which is not preferable. On the other hand, if it exceeds 50 parts by weight, excess water increases and the shape retention of the molded product before curing is deteriorated, which is not preferable.

【0034】なお、前記原料組成物を成形する際の成形
法として押出成形法を採用する場合には、原料組成物中
における水の配合量は、前記固形原料100重量部に対
して30〜50重量部に設定するのが特に好ましい。
When the extrusion molding method is adopted as the molding method for molding the raw material composition, the amount of water in the raw material composition is 30 to 50 with respect to 100 parts by weight of the solid raw material. It is particularly preferable to set it in parts by weight.

【0035】前記原料組成物を作成するに際しては、各
材料成分の配合順序は特に限定されない。例えば、水を
最後に配合せしめるようにしても良いし、途中段階で配
合せしめるようにしても良い。
When preparing the raw material composition, the order of mixing the respective material components is not particularly limited. For example, water may be added last, or may be added in the middle.

【0036】また、前記原料組成物には、必要に応じ
て、この発明の効果を阻害しない範囲で、その他の添加
剤等を配合せしめることもできる。
If necessary, the raw material composition may be blended with other additives and the like within a range that does not impair the effects of the present invention.

【0037】前記原料組成物を成形する際の成形法は、
特に限定されず、例えば型枠成形、加圧成形、押出成形
等を例示できる。中でも、高品質の多孔質焼結体を生産
性良く製造できる点で、加圧成形又は押出成形で成形す
るのが好ましい。
The molding method for molding the raw material composition is as follows:
It is not particularly limited, and examples thereof include mold molding, pressure molding, extrusion molding and the like. Above all, it is preferable to mold by pressure molding or extrusion molding because a high-quality porous sintered body can be manufactured with high productivity.

【0038】また、養生工程での養生法についても特に
限定されず、例えば自然養生、水中養生、蒸気養生、オ
ートクレーブ養生等を例示できる。このような養生工程
を経てセメントの水和反応を進行させて凝結、硬化させ
ることによってハンドリングに必要な強度を確保する。
The curing method in the curing step is not particularly limited, and examples thereof include natural curing, underwater curing, steam curing and autoclave curing. The strength required for handling is secured by advancing the hydration reaction of the cement through such a curing step, setting and hardening.

【0039】また、焼結工程における焼成温度は、高温
であれば特に限定されないものの、800〜1500℃
の範囲とするのが好ましい。800℃未満では焼結を完
了させるのに時間を要して焼結体の製造効率が低下する
ので好ましくない。一方、1500℃を超えると原料が
溶融して多孔質構造が得られなくなるので好ましくな
い。中でも、焼成温度は1000〜1300℃の範囲に
設定するのがより好ましく、この焼成温度で1〜2時間
保持するのが最も良い。
The firing temperature in the sintering step is not particularly limited as long as it is high, but it is 800 to 1500 ° C.
The range is preferably If the temperature is lower than 800 ° C., it takes time to complete the sintering and the production efficiency of the sintered body decreases, which is not preferable. On the other hand, if the temperature exceeds 1500 ° C, the raw material is melted and a porous structure cannot be obtained, which is not preferable. Above all, it is more preferable to set the firing temperature in the range of 1000 to 1300 ° C., and it is best to maintain the firing temperature for 1 to 2 hours.

【0040】なお、前記焼成温度に到達するまでの昇温
速度は5〜10℃/分に設定するのが好ましい。また、
一般に陶磁器原料を焼成して陶磁器を製造する時には、
焼成温度から常温にまで降温する際の降温速度は、その
際のひび割れ、クラック発生を防止するために、極力遅
くする必要があるが、本発明の焼結体では焼結時の収縮
率が非常に小さいので、例えば5〜10℃/分程度の速
い降温速度で降温してもひび割れ等が発生しない。従っ
て、焼成後の降温速度を大きく設定することもできるの
で、生産効率良く軽量多孔質焼結体を製造できる利点も
ある。
The rate of temperature increase until the firing temperature is reached is preferably set to 5 to 10 ° C./min. Also,
Generally, when firing ceramic raw materials to manufacture ceramics,
The temperature lowering rate at the time of lowering the temperature from the firing temperature to room temperature needs to be as slow as possible in order to prevent cracking and cracking at that time, but in the sintered body of the present invention, the shrinkage rate during sintering is extremely high. Since it is very small, cracks and the like do not occur even when the temperature is lowered at a high temperature lowering rate of, for example, 5 to 10 ° C./min. Therefore, the temperature lowering rate after firing can be set to a large value, and there is also an advantage that a lightweight porous sintered body can be manufactured with high production efficiency.

【0041】この発明の製造法で得られた軽量多孔質焼
結体は、断熱材、遮音材、調湿性建材、土木材、濾過
材、吸着フィルター、バイオテクノロジー分野等での担
持体等として用いることができる。また、該軽量多孔質
焼結体に酵素や触媒等を担持して水質浄化材等として用
いることもできる。なお、この発明の製造法で得られた
軽量多孔質焼結体の用途は、前記例示の用途に特に限定
されるものではない。
The lightweight porous sintered body obtained by the production method of the present invention is used as a heat insulating material, a sound insulating material, a humidity control building material, earth and wood, a filter material, an adsorption filter, a carrier in the biotechnology field and the like. be able to. Further, the lightweight porous sintered body may be loaded with an enzyme, a catalyst or the like and used as a water purification material or the like. The application of the lightweight porous sintered body obtained by the production method of the present invention is not particularly limited to the above-mentioned applications.

【0042】[0042]

【実施例】次に、この発明の具体的実施例について説明
するが、この発明はこれら実施例に示す製造方法に特に
限定されるものではない。
EXAMPLES Next, specific examples of the present invention will be described, but the present invention is not particularly limited to the manufacturing methods shown in these examples.

【0043】<実施例1>もみ殻灰(平均粒径350μ
m、黒色)40重量部、珪石(平均粒径4.63μm)
40重量部、アルミナセメント(平均粒径14.5μ
m)20重量部、水15重量部を十分に混合して均一な
原料組成物を得た。なお、ここで用いたもみ殻灰、珪
石、アルミナセメントは、それぞれ表1に示す組成から
なる。
<Example 1> Rice husk ash (average particle size: 350 μm)
m, black) 40 parts by weight, silica stone (average particle size 4.63 μm)
40 parts by weight, alumina cement (average particle size 14.5μ
m) 20 parts by weight and 15 parts by weight of water were sufficiently mixed to obtain a uniform raw material composition. The rice husk ash, silica stone, and alumina cement used here had the compositions shown in Table 1, respectively.

【0044】次に、この原料組成物を金型に入れ、20
0kg/cm2 の圧力で加圧成形することによって、成
形体を得た。この成形体を、25℃、湿度90%の養生
槽中で24時間保持して水和反応により硬化させた(養
生工程)。次いで、50℃において24時間乾燥させた
後、成形体を大気中において1300℃の焼成温度で1
時間焼成して焼結体を得た。なお、1300℃に到達す
るまでの昇温速度は10℃/分とし、この後の降温速度
は10℃/分とした。
Next, this raw material composition was placed in a mold and the
A molded body was obtained by pressure molding at a pressure of 0 kg / cm 2 . The molded body was kept in a curing tank at 25 ° C. and a humidity of 90% for 24 hours to be cured by a hydration reaction (curing step). Then, after drying at 50 ° C. for 24 hours, the molded body is exposed to 1300 ° C. for 1 hour in the air.
It was fired for a time to obtain a sintered body. The rate of temperature increase until reaching 1300 ° C. was 10 ° C./minute, and the rate of temperature decrease thereafter was 10 ° C./minute.

【0045】<実施例2、3>原料組成物の組成比を表
2に示すような割合に設定した以外は、実施例1と同様
にして焼結体を得た。
<Examples 2 and 3> A sintered body was obtained in the same manner as in Example 1 except that the composition ratios of the raw material compositions were set as shown in Table 2.

【0046】<実施例4>珪石40重量部に代えて高炉
滓40重量部を原料組成物に含有せしめるものとした以
外は、実施例1と同様にして焼結体を得た。
<Example 4> A sintered body was obtained in the same manner as in Example 1 except that 40 parts by weight of silica stone was added to the raw material composition in an amount of 40 parts by weight.

【0047】<実施例5>もみ殻灰(平均粒径350μ
m、黒色)40重量部、珪石(平均粒径4.63μm)
40重量部、アルミナセメント(平均粒径14.5μ
m)20重量部、パルプ繊維2重量部、カルボキシメチ
ルセルロース(信越化学製、商品名「メトロース90S
H15000」)2.5重量部、水50重量部を十分に
混合して均一な原料組成物を得、該原料組成物を混練し
て押出圧力20〜21kg/cm2 で押出成形して成形
体を得た。この成形体を、25℃、湿度90%の養生槽
中で24時間保持して水和反応により硬化させた(養生
工程)。次いで、50℃において24時間乾燥させた
後、成形体を大気中において1300℃の焼成温度で1
時間焼成して焼結体を得た。なお、1300℃に到達す
るまでの昇温速度は10℃/分とし、この後の降温速度
は10℃/分とした。
Example 5 Rice husk ash (average particle size 350 μ
m, black) 40 parts by weight, silica stone (average particle size 4.63 μm)
40 parts by weight, alumina cement (average particle size 14.5μ
m) 20 parts by weight, pulp fibers 2 parts by weight, carboxymethyl cellulose (manufactured by Shin-Etsu Chemical, trade name "Metrose 90S"
H15000 ") 2.5 parts by weight and 50 parts by weight of water are sufficiently mixed to obtain a uniform raw material composition, and the raw material composition is kneaded and extrusion molded at an extrusion pressure of 20 to 21 kg / cm 2 to obtain a molded article. Got The molded body was kept in a curing tank at 25 ° C. and a humidity of 90% for 24 hours to be cured by a hydration reaction (curing step). Then, after drying at 50 ° C. for 24 hours, the molded body is exposed to 1300 ° C. for 1 hour in the air.
It was fired for a time to obtain a sintered body. The rate of temperature increase until reaching 1300 ° C. was 10 ° C./minute, and the rate of temperature decrease thereafter was 10 ° C./minute.

【0048】<実施例6、7>原料組成物の組成比を表
2に示すような割合に設定した以外は、実施例5と同様
にして焼結体を得た。
<Examples 6 and 7> Sintered bodies were obtained in the same manner as in Example 5 except that the composition ratio of the raw material composition was set to the ratio shown in Table 2.

【0049】[0049]

【表2】 [Table 2]

【0050】<比較例1>もみ殻灰40重量部に代え
て、火山噴出物シラスを加熱発泡して得られるシラスバ
ルーン40重量部を原料組成物に含有せしめるものとし
た以外は、実施例1と同様にして焼結体を得た。
Comparative Example 1 Example 1 was repeated except that 40 parts by weight of shirasu balloon obtained by heating and foaming volcanic shirasu shirasu was added to the raw material composition instead of 40 parts by weight of rice husk ash. A sintered body was obtained in the same manner as in.

【0051】実施例1〜7の焼結体は、電子顕微鏡で観
察するといずれも図1に示すような連続状の多孔質構造
を呈していた。これに対し、比較例1の焼結体では、図
2に示すように連続状の多孔質構造は認められなかっ
た。
The sintered bodies of Examples 1 to 7 all exhibited a continuous porous structure as shown in FIG. 1 when observed with an electron microscope. On the other hand, in the sintered body of Comparative Example 1, no continuous porous structure was observed as shown in FIG.

【0052】上記のようにして得られた各焼結体に対し
下記測定法により評価を行った。これらの結果を表3に
示す。
The respective sintered bodies obtained as described above were evaluated by the following measuring methods. The results are shown in Table 3.

【0053】<グリーン強度及び曲げ強度測定法>成形
体のグリーン強度(養生後)及び焼結体の曲げ強度測定
は、JIS R1601の曲げ強さ試験法の3点曲げ法
に準拠して測定した。
<Measurement Method of Green Strength and Bending Strength> The green strength (after curing) of the molded body and the bending strength of the sintered body were measured in accordance with the three-point bending method of the bending strength test method of JIS R1601. .

【0054】<かさ密度測定法>焼結体の重量をその外
容積で除した値をかさ密度とした。
<Bulk Density Measuring Method> The value obtained by dividing the weight of the sintered body by its outer volume was taken as the bulk density.

【0055】<比強度測定法>焼結体の強度を焼結体の
比重で除した値を比強度とした。
<Specific Strength Measurement Method> The value obtained by dividing the strength of the sintered body by the specific gravity of the sintered body was taken as the specific strength.

【0056】<収縮率>線収縮率を採用し、下記算出式
により求めた。
<Shrinkage> The linear shrinkage was adopted and calculated by the following formula.

【0057】{(焼結前の長さ)−(焼結後の長さ)}
÷(焼結前の長さ)×100
{(Length before sintering)-(length after sintering)}
÷ (length before sintering) × 100

【0058】<吸水率測定法>焼結体を水中煮沸後冷却
し表面の水を拭き取った後の重量から、焼結体の乾燥重
量を引いて吸水量を求め、該吸水量を焼結体の乾燥重量
で除した値を吸水率とした。
<Water Absorption Rate Measuring Method> The sintered body was boiled in water, cooled and wiped to remove water from the surface, and the dry weight of the sintered body was subtracted from the weight to determine the water absorption. The value obtained by dividing by the dry weight of was taken as the water absorption rate.

【0059】[0059]

【表3】 [Table 3]

【0060】表から明らかなように、この発明の製造方
法で製造された実施例1〜7の焼結体は、いずれも軽量
で、連続状の多孔質構造を有し、かつ焼結による収縮率
が非常に小さかった。また、原料組成物への水の混合量
が多く、かつカルボキシメチルセルロースを混合せしめ
た系である実施例5〜7の焼結体は、実施例1〜4のも
のと比較して、かさ密度が小さく、吸水率が大きくなっ
ており、多孔質構造による空洞体積が実施例1〜4のも
のよりも大きいという特徴を備えている。
As is apparent from the table, the sintered bodies of Examples 1 to 7 produced by the production method of the present invention are all lightweight, have a continuous porous structure, and shrink due to sintering. The rate was very small. In addition, the sintered bodies of Examples 5 to 7 in which the amount of water mixed in the raw material composition was large and carboxymethyl cellulose was mixed, have bulk densities in comparison with those of Examples 1 to 4. It is small, has a high water absorption rate, and has a feature that the cavity volume due to the porous structure is larger than those of Examples 1 to 4.

【0061】これに対して、比較例1のシラスバルーン
系の焼結体は、軽量性が不十分であるし、連続状の多孔
質構造を有しておらず、また焼結による収縮率も大きか
った。
On the other hand, the shirasu balloon-based sintered body of Comparative Example 1 has an insufficient lightweight property, does not have a continuous porous structure, and has a shrinkage rate due to sintering. It was great.

【0062】[0062]

【発明の効果】この発明に係る焼結体の製造方法は、も
み殻灰、無機質骨材及びセメントを含む固形原料に水が
加えられてなる原料組成物を成形して成形体を得る工程
と、セメントの水和反応により前記成形体を硬化させる
養生工程と、前記養生を行った成形体を高温で焼成して
多孔質焼結体を得る焼結工程とを含むことを特徴とする
ものであるから、軽量でかつ多孔質の焼結体を製造する
ことができる。また、本製造方法では、もみ殻灰を原料
に用いているので、焼結による収縮が非常に小さく、従
って所望の形状を忠実に形成できる利点がある。更に、
従来廃棄されていたもみ殻灰を原料に用いるので、資源
の有効利用になるし、低コストで軽量多孔質焼結体を製
造できる。加えて、焼結時の収縮が非常に小さいことか
ら、焼成後の降温速度を大きくしてもひび割れ等が発生
しないので、降温速度を大きく設定して生産効率良く焼
結体を製造できる利点もある。
The method for producing a sintered body according to the present invention comprises the steps of molding a raw material composition obtained by adding water to a solid raw material containing rice husk ash, inorganic aggregate and cement to obtain a molded body. A curing step of hardening the molded body by a hydration reaction of cement, and a sintering step of firing the cured molded body at a high temperature to obtain a porous sintered body. Therefore, a lightweight and porous sintered body can be manufactured. In addition, since rice husk ash is used as a raw material in the present manufacturing method, there is an advantage that shrinkage due to sintering is extremely small and therefore a desired shape can be faithfully formed. Furthermore,
Since rice husk ash, which has been conventionally discarded, is used as a raw material, resources can be effectively used and a lightweight porous sintered body can be manufactured at low cost. In addition, since shrinkage during sintering is extremely small, cracks and the like do not occur even if the temperature lowering rate after firing is increased.Therefore, there is an advantage that a sintered body can be manufactured with high production efficiency by setting a high temperature lowering rate. is there.

【0063】固形原料における、もみ殻灰の含有率が2
0〜60重量%、無機質骨材の含有率が20〜60重量
%、セメントの含有率が10〜50重量%の範囲である
場合には、成形体のハンドリング性及び焼結体の強度を
十分に向上させることができる。
The content rate of rice husk ash in the solid raw material is 2
When the content of the inorganic aggregate is 0 to 60% by weight, the content of the inorganic aggregate is 20 to 60% by weight, and the content of the cement is 10 to 50% by weight, the handleability of the molded body and the strength of the sintered body are sufficient. Can be improved.

【0064】原料組成物が、固形原料100重量部に対
して水が10〜50重量部混合されたものからなる場合
には、セメントの水和反応を十分に促進できると共に、
養生前の成形体の保形性も向上できる。
When the raw material composition is composed of 100 parts by weight of the solid raw material and 10 to 50 parts by weight of water mixed, the hydration reaction of the cement can be sufficiently promoted, and
The shape retention of the molded product before curing can also be improved.

【0065】無機質骨材として、珪石及び珪酸塩からな
る群より選ばれる1種または2種以上の骨材を用いる場
合には焼結体の強度をより向上できる。
When one kind or two or more kinds of aggregates selected from the group consisting of silica stone and silicate are used as the inorganic aggregate, the strength of the sintered body can be further improved.

【0066】焼結工程での焼成温度が800〜1500
℃である場合には、生産性を向上できるし、連続状の多
孔質構造を十分に形成できる。
The firing temperature in the sintering process is 800 to 1500.
When the temperature is 0 ° C, the productivity can be improved and a continuous porous structure can be sufficiently formed.

【0067】原料組成物に、パルプ繊維、合成繊維、ガ
ラス繊維、炭素繊維及び鉱物繊維からなる群より選ばれ
る1種または2種以上の繊維を含有せしめるものとし、
前記もみ殻灰、無機質骨材及びセメントの総量100重
量部に対して前記繊維の配合量を2〜5重量部に設定す
る場合には、養生前の成形体の保形性を向上できるし、
養生後の成形体の強度及び焼結体の強度や軽量性を向上
させることができると共に、焼結体の寸法安定性も向上
できる。
The raw material composition should contain one or more fibers selected from the group consisting of pulp fibers, synthetic fibers, glass fibers, carbon fibers and mineral fibers,
When the compounding amount of the fibers is set to 2 to 5 parts by weight with respect to the total amount of the rice hull ash, the inorganic aggregate and the cement of 100 parts by weight, the shape retention of the molded body before curing can be improved,
The strength of the molded body after curing and the strength and lightness of the sintered body can be improved, and the dimensional stability of the sintered body can also be improved.

【0068】原料組成物に、水溶性繊維素類及び水溶性
ポリマーからなる群より選ばれる1種または2種以上の
粘性付与剤を含有せしめるものとし、前記もみ殻灰、無
機質骨材及びセメントの総量100重量部に対して前記
粘性付与剤の配合量を0.5〜4重量部に設定する場合
には、原料組成物に粘性や滑性を十分に付与できて、押
出成形を行う場合でも成形性良く成形でき、ひいてはよ
り高品質の焼結体を製造できる。更に、これら粘性付与
剤は、焼成時に燃えて揮散してしまうので、より多孔度
の大きい焼結体を製造することができ、これによりかさ
密度のより小さい、吸水率のより大きい多孔質焼結体を
得ることができる。
The raw material composition may contain one or more viscosity-imparting agents selected from the group consisting of water-soluble fibrins and water-soluble polymers, and the rice husk ash, the inorganic aggregate and the cement may be added. When the blending amount of the viscosity-imparting agent is set to 0.5 to 4 parts by weight with respect to 100 parts by weight as a total amount, it is possible to sufficiently impart viscosity and lubricity to the raw material composition and to perform extrusion molding. It can be molded with good moldability, and thus a higher quality sintered body can be manufactured. Furthermore, since these viscosity imparting agents burn and volatilize during firing, it is possible to produce a sintered body having a higher porosity, which results in a porous sintered body having a lower bulk density and a higher water absorption rate. You can get the body.

【図面の簡単な説明】[Brief description of drawings]

【図1】この発明の製造方法で得られた焼結体の電子顕
微鏡写真である。
FIG. 1 is an electron micrograph of a sintered body obtained by the manufacturing method of the present invention.

【図2】比較例のシラスバルーン系焼結体の電子顕微鏡
写真である。
FIG. 2 is an electron micrograph of a shirasu balloon-based sintered body of a comparative example.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 神尾 典 佐賀県三養基郡基山町小倉1011−23 (72)発明者 川村 弘一 京都府長岡京市うぐいす台88 (72)発明者 小山 栄一 奈良県香芝市西真美2−19−79 (72)発明者 西野 善春 奈良市南永井町甲231−16   ─────────────────────────────────────────────────── ─── Continued front page    (72) Inventor Nori Kamio             1011-23 Kokura, Kiyama-cho, Sanyo-gun, Saga Prefecture (72) Inventor Koichi Kawamura             88 Uguisudai, Nagaokakyo, Kyoto Prefecture (72) Inventor Eiichi Koyama             2-19-79 Mami Nishi, Kashiba City, Nara Prefecture (72) Inventor Yoshiharu Nishino             231-16 Ko, Minami-Nagai-cho, Nara

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】 もみ殻灰、無機質骨材及びセメントを含
む固形原料に水が加えられてなる原料組成物を成形して
成形体を得る工程と、 セメントの水和反応により前記成形体を硬化させる養生
工程と、 前記養生を行った成形体を高温で焼成して多孔質焼結体
を得る焼結工程とを含むことを特徴とする軽量多孔質焼
結体の製造方法。
1. A step of molding a raw material composition obtained by adding water to a solid raw material containing rice husk ash, an inorganic aggregate and cement to obtain a molded body, and hardening the molded body by a hydration reaction of cement. A method of manufacturing a lightweight porous sintered body, comprising: a curing step of: and a sintering step of firing the cured molded body at a high temperature to obtain a porous sintered body.
【請求項2】 前記固形原料における、もみ殻灰の含有
率が20〜60重量%、無機質骨材の含有率が20〜6
0重量%、セメントの含有率が10〜50重量%の範囲
である請求項1に記載の軽量多孔質焼結体の製造方法。
2. The content of rice husk ash in the solid raw material is 20 to 60% by weight, and the content of inorganic aggregate is 20 to 6%.
The method for producing a lightweight porous sintered body according to claim 1, wherein the content of 0% by weight and the content of cement are in the range of 10 to 50% by weight.
【請求項3】 前記原料組成物が、前記固形原料100
重量部に対して水が10〜50重量部混合されたものか
らなる請求項1または2に記載の軽量多孔質焼結体の製
造方法。
3. The solid raw material 100 is the raw material composition.
The method for producing a lightweight porous sintered body according to claim 1 or 2, comprising 10 to 50 parts by weight of water mixed with parts by weight.
【請求項4】 前記無機質骨材として、珪石及び珪酸塩
からなる群より選ばれる1種または2種以上の骨材を用
いる請求項1〜3のいずれか1項に記載の軽量多孔質焼
結体の製造方法。
4. The lightweight porous sintered body according to claim 1, wherein one or more kinds of aggregates selected from the group consisting of silica stones and silicates are used as the inorganic aggregates. Body manufacturing method.
【請求項5】 前記焼結工程での焼成温度が800〜1
500℃である請求項1〜4のいずれか1項に記載の軽
量多孔質焼結体の製造方法。
5. The firing temperature in the sintering step is 800-1.
It is 500 degreeC, The manufacturing method of the lightweight porous sintered compact of any one of Claims 1-4.
【請求項6】 前記原料組成物に、パルプ繊維、合成繊
維、ガラス繊維、炭素繊維及び鉱物繊維からなる群より
選ばれる1種または2種以上の繊維を含有せしめるもの
とし、前記もみ殻灰、無機質骨材及びセメントの総量1
00重量部に対して前記繊維の配合量を2〜5重量部に
設定する請求項1〜5のいずれか1項に記載の軽量多孔
質焼結体の製造方法。
6. The raw material composition contains one kind or two or more kinds of fibers selected from the group consisting of pulp fibers, synthetic fibers, glass fibers, carbon fibers and mineral fibers, and the rice husk ash, Total amount of inorganic aggregate and cement 1
The method for producing a lightweight porous sintered body according to any one of claims 1 to 5, wherein the blending amount of the fibers is set to 2 to 5 parts by weight with respect to 00 parts by weight.
【請求項7】 前記原料組成物に、水溶性繊維素類及び
水溶性ポリマーからなる群より選ばれる1種または2種
以上の粘性付与剤を含有せしめるものとし、前記もみ殻
灰、無機質骨材及びセメントの総量100重量部に対し
て前記粘性付与剤の配合量を0.5〜4重量部に設定す
る請求項1〜6のいずれか1項に記載の軽量多孔質焼結
体の製造方法。
7. The rice husk ash, the inorganic aggregate, wherein the raw material composition contains one or more viscosity-imparting agents selected from the group consisting of water-soluble fibrins and water-soluble polymers. 7. The method for producing a lightweight porous sintered body according to any one of claims 1 to 6, wherein the compounding amount of the viscosity imparting agent is set to 0.5 to 4 parts by weight with respect to 100 parts by weight of the total amount of cement. .
【請求項8】 請求項1〜7のいずれか1項に記載の製
造方法によって製造された軽量多孔質焼結体。
8. A lightweight porous sintered body produced by the production method according to claim 1.
JP2001361039A 2001-11-27 2001-11-27 Method for producing lightweight porous sintered body Expired - Fee Related JP3816376B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001361039A JP3816376B2 (en) 2001-11-27 2001-11-27 Method for producing lightweight porous sintered body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001361039A JP3816376B2 (en) 2001-11-27 2001-11-27 Method for producing lightweight porous sintered body

Publications (2)

Publication Number Publication Date
JP2003165783A true JP2003165783A (en) 2003-06-10
JP3816376B2 JP3816376B2 (en) 2006-08-30

Family

ID=19171761

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001361039A Expired - Fee Related JP3816376B2 (en) 2001-11-27 2001-11-27 Method for producing lightweight porous sintered body

Country Status (1)

Country Link
JP (1) JP3816376B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006281042A (en) * 2005-03-31 2006-10-19 Suminoe Textile Co Ltd Continuous porous molded body immobilizing microbe and method for discoloring dye using this
JP2009298612A (en) * 2008-06-11 2009-12-24 Maruni Toryo Kk Ceramic material and its manufacturing method
CN116396095A (en) * 2023-04-10 2023-07-07 湖南工业大学 Light heat-insulating brick and preparation method thereof
CN116396095B (en) * 2023-04-10 2024-04-26 湖南工业大学 Light heat-insulating brick and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006281042A (en) * 2005-03-31 2006-10-19 Suminoe Textile Co Ltd Continuous porous molded body immobilizing microbe and method for discoloring dye using this
JP2009298612A (en) * 2008-06-11 2009-12-24 Maruni Toryo Kk Ceramic material and its manufacturing method
CN116396095A (en) * 2023-04-10 2023-07-07 湖南工业大学 Light heat-insulating brick and preparation method thereof
CN116396095B (en) * 2023-04-10 2024-04-26 湖南工业大学 Light heat-insulating brick and preparation method thereof

Also Published As

Publication number Publication date
JP3816376B2 (en) 2006-08-30

Similar Documents

Publication Publication Date Title
JPH0543666B2 (en)
JP4540656B2 (en) Composition for porous ceramics, porous ceramics using the same, and method for producing the same
US4663104A (en) Method for producing high-strength inorganic cement articles
JP2007145704A (en) Porous ceramic and method for manufacturing the same
JP2003165783A (en) Lightweight porous sintered compact and method for producing the same
JP4488404B2 (en) Porous sintered pavement material and manufacturing method thereof
JP2756934B2 (en) Sinter from coal ash as raw material and method for producing the same
JP4129695B2 (en) Method for producing porous water-absorbing ceramics
JP2007284292A (en) Method of manufacturing porous lightweight construction material
JP2007261901A (en) Ceramic formed by using waste as main material, and its manufacturing method
JP4152771B2 (en) Lightweight porous body, method for producing the same, carrier and water purification material
JP4967111B2 (en) Alumina-based porous ceramics and method for producing the same
JP4445324B2 (en) Lightweight porous body and method for producing the same
JP2003020265A (en) Method for producing multicolored brick
JP4064319B2 (en) Method for manufacturing vegetation planting base material
JP3109382B2 (en) Manufacturing method of permeable pavement material
JP2007246335A (en) Kaolin for forming lightweight strengthening earthenware, and lightweight strengthening earthenware
JPH0259479A (en) Method for lightening fly-ash formed material
JP2959402B2 (en) High strength porcelain
JP2006151730A (en) Light-weight inorganic plate and its manufacturing method
JPH0460952B2 (en)
JP2004161556A (en) Foamed glass and method of manufacturing the same
JPH0664982A (en) Production of ceramic form
CN1524827A (en) Method for manufacturing light weight ceramics
JPH09286658A (en) Production of ceramic spherical hollow body and manufacture of ceramic panel using ceramic spherical hollow body as constituent material

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20051011

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20060214

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060411

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20060411

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20060530

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20060607

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

RD02 Notification of acceptance of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: R3D02

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090616

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100616

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110616

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120616

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130616

Year of fee payment: 7

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees