JP2003136341A - Electrode wire for wire discharge work - Google Patents

Electrode wire for wire discharge work

Info

Publication number
JP2003136341A
JP2003136341A JP2001339763A JP2001339763A JP2003136341A JP 2003136341 A JP2003136341 A JP 2003136341A JP 2001339763 A JP2001339763 A JP 2001339763A JP 2001339763 A JP2001339763 A JP 2001339763A JP 2003136341 A JP2003136341 A JP 2003136341A
Authority
JP
Japan
Prior art keywords
layer
zinc
wire
copper
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001339763A
Other languages
Japanese (ja)
Inventor
Isao Izui
功夫 伊豆井
Shigemi Hasegawa
茂巳 長谷川
Masakazu Yoshimoto
雅一 吉本
Yoichiro Kimoto
洋一郎 木本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oki Electric Cable Co Ltd
Original Assignee
Oki Electric Cable Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oki Electric Cable Co Ltd filed Critical Oki Electric Cable Co Ltd
Priority to JP2001339763A priority Critical patent/JP2003136341A/en
Publication of JP2003136341A publication Critical patent/JP2003136341A/en
Pending legal-status Critical Current

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  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide an electrode wire for wire discharge work capable of achieving high speed compared to conventional wires for suppressing processing cost low. SOLUTION: Copper alloy or copper-coated steel wire is used as a center core material 2, a high zinc density copper - zinc alloy layer 3 with 45-65 wt.% zinc density is formed in 10-20% thickness of finished outer diameter, and a surface layer on its outer circumference is ground. A zinc plating layer 4 is further provided with 0.5-3% thickness of total finished outer diameter to provide this electrode wire 1 for wire discharge work. After the high zinc density alloy layer is formed, a rough part in the surface layer is shaved by a shaving die or the like only for a part where adhesion of electroplating is kept, so that a void layer 5' as in conventional devices is eliminated. Peeling of plating is thus eliminated, and the high zinc density layer which affects processing speed can be left to the utmost. High speed processing can thus be achieved.

Description

【発明の詳細な説明】 【0001】 【発明が属する技術分野】本発明は、ワイヤ放電加工機
に使用する電極線に関するもので、特に、加工コストを
低く抑える為に切削物を削り取る加工速度を速くし、従
来のワイヤよりも高速化をはかることが可能なワイヤ放
電加工用電極線1に関する。 【0002】 【従来の技術】現在、ワイヤ放電加工用電極線において
は、高速加工を目的とした様々な電極線が市場に出回っ
ており、より高速化を狙った電極線構造として亜鉛濃度
のより高い銅亜鉛合金層を電極線表面に形成した複合構
造の電極線が主流となってきている。このような従来の
複合構造電極線を製造する過程で、高温雰囲気中にて銅
合金と亜鉛を相互拡散する際、図2に示すように、電極
線表層に空洞の集合体からなるボイド層5′が多々発生
して表面が荒れてしまう。最外層に亜鉛等をコーティン
グするケースではこの表層の荒れがめっきの密着性を著
しく低下させてしまう為、めっきの前処理として電解酸
洗いによる表層研磨を行い、めっきの密着性を向上させ
ていた。 【0003】 【発明が解決しようとする課題】しかしながら、銅ー亜
鉛合金の表層に亜鉛めっき層を形成し、酸化雰囲気中に
て熱処理による相互拡散を行って亜鉛濃度45〜65%の高
亜鉛濃度の合金層を生成する場合、銅中の亜鉛の拡散速
度と亜鉛中の銅の拡散速度に大きな差がある為、銅亜鉛
合金と亜鉛めっき層の境界面から密に相互拡散が始ま
り、最終的に表層に空洞部が出来てしまうので滑らかな
表面状態を得ることが出来ない。この高亜鉛濃度合金層
を有した電極線に、更に亜鉛めっき層を形成するには、
表面を滑らかにする必要があり、その手法として酸洗い
によって表層を削り取る手法があるが、脱亜鉛により表
層の亜鉛濃度が低下してしまい、ワイヤ放電加工速度向
上の妨げになってしまうという欠点があった。又、具体
的に述べると、亜鉛濃度20〜40wt%の銅亜鉛合金
の表層に、電気めっきにて亜鉛をコーティングしたワイ
ヤを400〜900℃の高温雰囲気中に滞在させ、相互
拡散により高亜鉛合金層を形成する。中心心材の亜鉛濃
度により異なるが、亜鉛濃度20%の銅ー亜鉛合金の場
合、十数μm程の厚さで表層に空洞の集合体からなるボ
イド層5′が発生して表面が荒れてしまう。この状態で
電気めっきにて亜鉛をコーティングすると空洞部にめっ
きがされず、高亜鉛合金層と亜鉛めっき層の境界面に空
洞集合体からなるボイド層5′が出来てしまう。この状
態で、ワイヤ放電加工用電極線の製品外径である0.1
〜0.3mmに伸線を行うと表層の亜鉛が膨れ上がった
り、めっきが剥がれたりしてしまうという欠点もあっ
た。又、亜鉛めっきの仕上がり状態を良好にするたの手
法として電解酸洗いによる表面研磨を行うと、脱亜鉛現
象により亜鉛濃度が激減した層が形成され、加工速度の
低下の要因となってしまうという欠点があった。 【0004】 【課題を解決する為の手段】本発明は、これらの問題を
解決する為に、鋭意検討した結果、銅合金又は銅被鋼線
を中心心材2とし、この中心心材2の表面に亜鉛濃度4
5〜65wt%の高亜鉛の銅ー亜鉛合金層3を前記仕上
がり外径の10〜20%の厚さで形成し、その外周の表
層を研磨して削り取り、更にその外周に亜鉛めっき層4
をトータル仕上がり外径の0.5〜3%の厚さで設けた
ワイヤ放電加工用電極線1であり、高亜鉛合金層形成後
に表層の荒れた部位をシェービングダイス等にて電気め
っきの密着性が保たれる部分のみを削り取ることによ
り、加工速度に影響を及ぼす高亜鉛濃度層を最大限に残
すことが出来る。 【0005】 【発明の実施の形態】以下、本発明放電加工用電極線1
の実施形態について説明を行う。図1は、本発明のワイ
ヤ放電加工用電極線1の断面図であり、銅合金として
は、代表的な銅亜鉛合金を使用した場合を例に取り説明
する。亜鉛濃度20〜40%の銅亜鉛合金又は銅被鋼線
を中心心材2とし、この中心心材2の表面に亜鉛濃度4
5〜65wt%の高亜鉛の銅ー亜鉛合金層3を前記仕上
がり外径の10〜20%の厚さで形成し、その外周の表
層を研磨して削り取り、更にその外周に亜鉛めっき層4
をトータル仕上がり外径の0.5〜3%の厚さで設けた
ワイヤ放電加工用電極線1である。ここで、銅被鋼線と
は、鋼線、合金鋼線及び鉄の外周に銅を被覆したものを
いう。この放電加工用電極線1は、外径0.9mmの中心
心材となる銅亜鉛合金の表層に電気亜鉛めっきにて亜鉛
を20〜30μmの厚さでめっきし、400〜900℃
の高温雰囲気中に滞在させ、相互拡散により高亜鉛合金
層を形成する。その際、発生した十数μm程度の表層の
空洞の集合体をシェービングダイス等によって削り取
り、最外層に電気亜鉛めっきを施したものである。高亜
鉛合金層形成後に表層の荒れた部位をシェービングダイ
ス等にて電気めっきの密着性が保たれる部分のみを削り
取ることにより、加工速度に影響を及ぼす高亜鉛濃度層
を最大限に残した構造にしたものである。研磨して削り
取る方法としては、代表的なシェービングダイスを使用
したが、これに限るものではない。 【実施例】本発明の放電加工用電極線1を実際の放電加
工機に使用して評価した結果を下記に示す。本実施例で
使用する電極線は、図1に示す電極線の中心心材に亜鉛
濃度20%の銅亜鉛合金を使用した電極線でシェービン
グを施したもの、及び比較用の電極線として電解酸洗を
施した電極線の2種類とする。ワイヤ径0.30mm、ワーク
材SKD-11、ワーク厚60mm、放電加工機SX-10を用いて荒
加工最大条件を基に、下記の表1に示す通りワイヤ断線
が発生するまで加工条件を上げていき、各ワイヤの最大
加工速度を比較した。 【0006】 【表1】 【0007】次に、その結果を下記の表2に示すが、上
記電解酸洗を施した電極線の最大加工速度を1としたと
きの比率で加工速度を表現する。下記の表2は、本発明
の電極線と従来の製造方法で作成した従来の電極線及び
比較用の電極線について、切削物を削り取る加工速度の
評価を行った結果を示す。 【0008】 【表2】 【0009】上記表2の評価結果から以下の結果が得ら
れる。 1.シェービングダイス等によって前処理することによ
り加工速度が向上する。 2.シェービングダイス等によって前処理することによ
り断線耐力を向上することが出来る。 【0010】今迄、銅合金としては、銅ー亜鉛合金を代
表例に取り説明してきたが、これに限らず、銅ー錫、銅
ーマグネシウム、銅ー銀、銅ークロム合金等でも構わ
ず、本発明の範囲内であることはいうまでもない。 【0011】 【発明の効果】以上説明したように本発明によれば、相
互拡散により高亜鉛合金層を形成した際、発生した十数
μm程度の表層の空洞の集合体からなるボイド層5′を
シェービングダイス等によって削り取り、最外層に密着
強度の高い電気亜鉛めっきを容易に施せるよう前処理す
ることにより、従来のボイド層5′が除かれた構造とな
るので、めっきの剥離の発生がなくなり、加工速度に影
響を及ぼす高亜鉛濃度層を最大限に残すことが出来るの
で、高速化をはかることが可能となるという優れた効果
を発揮することが出来るので、その工業的価値は極めて
大きい。
Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an electrode wire used in a wire electric discharge machine, and more particularly to a machining speed for shaving a cut object in order to keep machining costs low. The present invention relates to an electrode wire 1 for wire electric discharge machining, which can be made faster and faster than a conventional wire. 2. Description of the Related Art At present, various types of electrode wires for wire electric discharge machining are on the market for the purpose of high-speed machining. Electrode wires having a composite structure in which a high copper-zinc alloy layer is formed on the electrode wire surface have become mainstream. When copper alloy and zinc are interdiffused in a high temperature atmosphere in the process of manufacturing such a conventional composite structure electrode wire, as shown in FIG. 2, a void layer 5 composed of an aggregate of cavities is formed on the surface of the electrode wire. 'Are generated frequently and the surface becomes rough. In the case where the outermost layer is coated with zinc or the like, since the roughness of the surface layer significantly reduces the adhesion of the plating, the surface is polished by electrolytic pickling as a pretreatment for plating to improve the adhesion of the plating. . However, a zinc plating layer is formed on a surface layer of a copper-zinc alloy, and interdiffusion is performed by heat treatment in an oxidizing atmosphere to obtain a high zinc concentration of 45 to 65%. When an alloy layer is formed, there is a large difference between the diffusion rate of zinc in copper and the diffusion rate of copper in zinc, so that interdiffusion starts densely from the interface between the copper-zinc alloy and the zinc plating layer, In addition, since a cavity is formed in the surface layer, a smooth surface state cannot be obtained. To further form a galvanized layer on the electrode wire having the high zinc concentration alloy layer,
It is necessary to smooth the surface, and there is a method of shaving the surface layer by pickling as a method, but there is a disadvantage that zinc concentration in the surface layer is reduced by dezincification, which hinders the improvement of wire electric discharge machining speed. there were. More specifically, a wire coated with zinc by electroplating on a surface layer of a copper-zinc alloy having a zinc concentration of 20 to 40 wt% is allowed to stay in a high-temperature atmosphere of 400 to 900 ° C. Form a layer. Although it depends on the zinc concentration of the central core material, in the case of a copper-zinc alloy having a zinc concentration of 20%, a void layer 5 'consisting of a collection of cavities is generated in the surface layer with a thickness of about several tens of micrometers, and the surface becomes rough. . If zinc is coated by electroplating in this state, the cavity is not plated, and a void layer 5 'composed of a hollow aggregate is formed at the interface between the high zinc alloy layer and the zinc plating layer. In this state, the product outer diameter of the electrode wire for wire electric discharge machining is 0.1.
There is also a drawback that when the wire is drawn to 0.3 mm, the zinc in the surface layer swells and the plating peels off. In addition, if the surface is polished by electrolytic pickling as a technique for improving the finished state of zinc plating, a layer in which the zinc concentration is drastically reduced due to the dezincing phenomenon is formed, which causes a reduction in the processing speed. There were drawbacks. According to the present invention, as a result of diligent studies to solve these problems, a copper alloy or a copper-coated steel wire is used as the center core material 2 and the surface of the center core material 2 Zinc concentration 4
A copper-zinc alloy layer 3 of high zinc of 5 to 65 wt% is formed with a thickness of 10 to 20% of the finished outer diameter, and the outer peripheral surface layer is polished and shaved off.
Is an electrode wire 1 for wire electric discharge machining provided with a thickness of 0.5 to 3% of the total finished outer diameter. After forming the high zinc alloy layer, the rough portion of the surface layer is subjected to electroplating adhesion with a shaving die or the like. By shaving off only the portion where is maintained, the high zinc concentration layer which affects the processing speed can be left as much as possible. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, an electrode wire 1 for electric discharge machining according to the present invention will be described.
The embodiment will be described. FIG. 1 is a cross-sectional view of an electrode wire 1 for wire electric discharge machining according to the present invention, and a description will be given taking a case where a typical copper-zinc alloy is used as a copper alloy as an example. A copper-zinc alloy or a copper-coated steel wire having a zinc concentration of 20 to 40% is used as the center core 2, and the surface of the center core 2 has a zinc concentration of 4%.
A copper-zinc alloy layer 3 of high zinc of 5 to 65 wt% is formed with a thickness of 10 to 20% of the finished outer diameter, and the outer peripheral surface layer is polished and shaved off.
Is an electrode wire 1 for wire electric discharge machining provided with a thickness of 0.5 to 3% of the total finished outer diameter. Here, the copper-coated steel wire refers to a steel wire, an alloy steel wire, and an iron whose outer periphery is coated with copper. This electrode wire 1 for electric discharge machining is formed by plating zinc on a surface layer of a copper-zinc alloy serving as a central core material having an outer diameter of 0.9 mm by electro-galvanization to a thickness of 20 to 30 μm, and at 400 to 900 ° C.
And a high zinc alloy layer is formed by mutual diffusion. At this time, the aggregate of the cavities in the surface layer having a thickness of about several tens of μm was scraped off by a shaving die or the like, and the outermost layer was subjected to electrogalvanization. A structure that leaves a high zinc concentration layer that affects the processing speed by shaving off the rough part of the surface layer after shaping with a shaving die etc. only the part where the electroplating adhesion is maintained. It was made. As a method of polishing and shaving, a typical shaving die was used, but the method is not limited to this. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The results of evaluation using the electrode wire for electric discharge machining 1 of the present invention in an actual electric discharge machine are shown below. The electrode wire used in this embodiment was obtained by shaving the center wire of the electrode wire shown in FIG. 1 with an electrode wire using a copper-zinc alloy having a zinc concentration of 20%, and an electrolytic pickling as a comparative electrode wire. And two types of electrode wires. Using a wire diameter of 0.30 mm, workpiece material SKD-11, workpiece thickness 60 mm, and the maximum conditions for rough machining using an electric discharge machine SX-10, raise the machining conditions until wire breakage occurs as shown in Table 1 below. The maximum processing speed of each wire was compared. [Table 1] Next, the results are shown in Table 2 below, wherein the processing speed is expressed as a ratio when the maximum processing speed of the electrode wire subjected to the electrolytic pickling is set to 1. Table 2 below shows the results of the evaluation of the processing speed for shaving a cut object with respect to the electrode wire of the present invention, the conventional electrode wire prepared by the conventional manufacturing method, and the comparative electrode wire. [Table 2] The following results are obtained from the evaluation results in Table 2 above. 1. Processing speed is improved by pre-processing with a shaving die or the like. 2. The pre-treatment with a shaving die or the like can improve the disconnection resistance. Until now, a copper-zinc alloy has been described as a typical example of a copper alloy, but the present invention is not limited to this, and copper-tin, copper-magnesium, copper-silver, copper-chromium alloy, etc. may be used. It goes without saying that it is within the scope of the present invention. As described above, according to the present invention, when a high zinc alloy layer is formed by interdiffusion, a void layer 5 'formed of an aggregate of surface cavities of about tens of μm is generated. Is scraped off with a shaving die or the like, and the outermost layer is subjected to a pretreatment so that electrogalvanizing with high adhesion strength can be easily applied, so that the conventional void layer 5 'is removed. Since the high zinc concentration layer which affects the processing speed can be left as much as possible, it is possible to achieve an excellent effect that the speed can be increased, so that its industrial value is extremely large.

【図面の簡単な説明】 【図1】本発明のワイヤ放電加工用電極線1の断面図で
ある。 【図2】従来のワイヤ放電加工用電極線1′の断面図で
ある。 【符号の説明】 1 本発明のワイヤ放電加工用電極線 2 中心心材(銅合金又は銅被鋼線) 3 高亜鉛の銅ー亜鉛合金層(亜鉛濃度45〜65
%の銅ー亜鉛合金) 4 亜鉛めっき層 1′ 従来のワイヤ放電加工用電極線 2′ 中心心材(銅合金) 3′ 高亜鉛の銅ー亜鉛合金層 4′ 亜鉛めっき層 5′ 空洞の集合体からなるボイド層
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a sectional view of an electrode wire 1 for wire electric discharge machining of the present invention. FIG. 2 is a sectional view of a conventional wire electrode for wire electric discharge machining 1 '. DESCRIPTION OF SYMBOLS 1 Electrode wire for wire electric discharge machining of the present invention 2 Center core material (copper alloy or copper-coated steel wire) 3 High zinc copper-zinc alloy layer (zinc concentration 45 to 65)
% Copper-zinc alloy) 4 galvanized layer 1 'conventional electrode wire for wire electric discharge machining 2' center core material (copper alloy) 3 'high-zinc copper-zinc alloy layer 4' galvanized layer 5 'aggregate of cavities Void layer consisting of

フロントページの続き (72)発明者 吉本 雅一 神奈川県川崎市中原区下小田中2丁目12番 8号 沖電線株式会社内 (72)発明者 木本 洋一郎 神奈川県川崎市中原区下小田中2丁目12番 8号 沖電線株式会社内 Fターム(参考) 3C059 AA01 AB05 DA06 DB03 DC02 4K024 AA01 AA05 AB02 BA09 BB09 BC03 DA10 DB01 DB07 GA01Continuation of front page    (72) Inventor Masakazu Yoshimoto             2-12 Shimoodanaka, Nakahara-ku, Kawasaki City, Kanagawa Prefecture             No. 8 Oki Electric Wire Co., Ltd. (72) Inventor Yoichiro Kimoto             2-12 Shimoodanaka, Nakahara-ku, Kawasaki City, Kanagawa Prefecture             No. 8 Oki Electric Wire Co., Ltd. F term (reference) 3C059 AA01 AB05 DA06 DB03 DC02                 4K024 AA01 AA05 AB02 BA09 BB09                       BC03 DA10 DB01 DB07 GA01

Claims (1)

【特許請求の範囲】 【請求項1】銅合金又は銅被鋼線を中心心材2とし、こ
の中心心材2の表面に亜鉛濃度45〜65wt%の高亜
鉛の銅ー亜鉛合金層3を前記仕上がり外径の10〜20
%の厚さで形成し、その外周の表層を研磨して削り取
り、更にその外周に亜鉛めっき層4をトータル仕上がり
外径の0.5〜3%の厚さで設けたことを特徴とするワ
イヤ放電加工用電極線1。
Claims: 1. A copper alloy or a copper-coated steel wire is used as a core material 2 and a high-zinc copper-zinc alloy layer 3 having a zinc concentration of 45 to 65 wt% is formed on the surface of the core material 2. Outer diameter 10-20
%, And the outer peripheral surface layer is polished and shaved off, and the outer periphery is further provided with a galvanized layer 4 having a thickness of 0.5 to 3% of the total finished outer diameter. Electrode wire 1 for electric discharge machining.
JP2001339763A 2001-11-05 2001-11-05 Electrode wire for wire discharge work Pending JP2003136341A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001339763A JP2003136341A (en) 2001-11-05 2001-11-05 Electrode wire for wire discharge work

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001339763A JP2003136341A (en) 2001-11-05 2001-11-05 Electrode wire for wire discharge work

Publications (1)

Publication Number Publication Date
JP2003136341A true JP2003136341A (en) 2003-05-14

Family

ID=19154064

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001339763A Pending JP2003136341A (en) 2001-11-05 2001-11-05 Electrode wire for wire discharge work

Country Status (1)

Country Link
JP (1) JP2003136341A (en)

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