JP2003109573A - Separator with rib for lead storage battery - Google Patents
Separator with rib for lead storage batteryInfo
- Publication number
- JP2003109573A JP2003109573A JP2001304648A JP2001304648A JP2003109573A JP 2003109573 A JP2003109573 A JP 2003109573A JP 2001304648 A JP2001304648 A JP 2001304648A JP 2001304648 A JP2001304648 A JP 2001304648A JP 2003109573 A JP2003109573 A JP 2003109573A
- Authority
- JP
- Japan
- Prior art keywords
- rib
- separator
- mini
- storage battery
- lead storage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Cell Separators (AREA)
- Secondary Cells (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、鉛蓄電池用セパレ
ータに関し、更に詳しくは、肉薄シートのベース面に、
電極板に当接させるように所定の間隔を存して多数条の
主リブを設けた鉛蓄電池用リブ付きセパレータに関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a lead storage battery separator, and more specifically, to a base surface of a thin sheet,
The present invention relates to a ribbed separator for a lead storage battery in which a large number of main ribs are provided at a predetermined interval so as to come into contact with an electrode plate.
【０００２】[0002]
【従来の技術】従来の鉛蓄電池用リブ付きセパレータと
しては、柔軟な合成樹脂製薄肉シートのベース面に、電
極板に当接させるように所定の間隔を存して多数条の主
リブを設けるようにしたものが使用されている。2. Description of the Related Art As a conventional ribbed separator for a lead storage battery, a large number of main ribs are provided on a base surface of a flexible thin sheet made of synthetic resin so as to be in contact with an electrode plate at predetermined intervals. Is used.
【０００３】[0003]
【発明が解決しようとする課題】上記、従来のリブ付き
セパレータを極板群に組み込み、鉛蓄電池に構成した場
合、その使用中において、充放電による陽極板の膨張、
収縮などに伴う変形や、セパレータの特にリブのない平
坦な肉薄ベース部の湾曲などにより、該セパレータの該
肉薄シートのベース部は陽極面と接触し、その極板の活
物質である酸化鉛により酸化されて、酸化劣化を起こ
し、ついには孔があき、その結果、極板間の短絡や電池
寿命の短縮をもたらすという不都合を有していた。これ
を防止するため、該リブの高さを著しく高くすることが
考えられるが、極板面との間隔が大きくなり、電気抵抗
の増大をもたらすという不都合を有するものである。ま
た、リブ付きセパレータとは別に、セパレータの酸化劣
化を防止するため、平坦な肉薄セパレータ面にガラスマ
ットを重合してなるガラスマット付きセパレータも提案
されているが、該ガラスマットは、リブ付きセパレータ
に比べ製造コストの増大をもたらしてしまうものであ
る。また、ガラス繊維にバインダを混在しているため、
極板群に組み込んだ場合、電気抵抗の増大、電池の放電
特性の劣化をもたらすという不都合もある。そこで、こ
のような従来の技術に鑑み、本出願人は、先に、平成３
年実用新案登録願第７８６８０号において、肉薄シート
ベース面に間隔を存して多数条の主リブを設けたリブ付
きセパレータの隣接する主リブ間に該主リブよりも高さ
の低いミニリブを少なくとも１条設けることにより、電
池使用時に陽極板やセパレータの変形が生じても、該ミ
ニリブに陽極板面が当接されることにより該セパレータ
のベース部が直接陽極板面と接触することを防止できる
ようにしたリブ付きセパレータを提案した。しかしなが
ら、このセパレータでは、ミニリブの断面形状が台形状
となっており、上面が完全なフラットで、上面から側壁
面へかけての面が角張った面に形成されている。このた
め、充放電による陽極板の膨張、収縮等に伴う変形や、
セパレータの特にリブのない平坦な肉薄ベース部の湾曲
等により、ミニリブに陽極板面が接触すると、該ミニリ
ブの角張った面によって陽極板表面の活物質が掻き取ら
れて脱落し易くなる問題がある。When the conventional ribbed separator is incorporated into an electrode plate group to constitute a lead storage battery, expansion of the anode plate due to charge and discharge during use thereof,
Deformation due to shrinkage, etc., due to the curvature of the flat thin base portion of the separator without any ribs, the base portion of the thin sheet of the separator comes into contact with the anode surface, and lead oxide is the active material of the electrode plate. There is a disadvantage that it is oxidized to cause oxidative deterioration, and finally holes are formed, resulting in a short circuit between the electrode plates and a shortened battery life. In order to prevent this, it is conceivable to make the height of the rib extremely high, but this has a disadvantage that the distance between the rib and the electrode plate surface becomes large and the electric resistance increases. In addition to the ribbed separator, in order to prevent oxidative deterioration of the separator, a glass matted separator obtained by polymerizing a glass mat on a flat thin separator surface has been proposed. This leads to an increase in manufacturing cost. Also, since the binder is mixed in the glass fiber,
When incorporated in the electrode plate group, there are disadvantages that the electrical resistance increases and the discharge characteristics of the battery deteriorate. Then, in view of such a conventional technique, the present applicant has previously
In the utility model registration application No. 78680, at least a mini-rib having a height lower than that of the main ribs is provided at least between adjacent main ribs of a ribbed separator provided with a large number of main ribs at intervals on the thin sheet base surface. By providing one strip, even if the anode plate or the separator is deformed during use of the battery, it is possible to prevent the base portion of the separator from directly contacting the anode plate surface by contacting the anode plate surface with the mini-rib. A ribbed separator was proposed. However, in this separator, the cross-sectional shape of the mini-rib is trapezoidal, the upper surface is completely flat, and the surface from the upper surface to the side wall surface is formed into an angular surface. Therefore, deformation due to expansion and contraction of the anode plate due to charge and discharge,
When the anode plate surface comes into contact with the mini-ribs due to the curvature of the flat thin base portion having no ribs, the active material on the surface of the anode plate is easily scraped off by the angular surface of the mini-ribs, which makes it easy to fall off. .
【０００４】[0004]
【課題を解決するための手段】本発明者等は、かかる要
望に応えるべく、鋭意検討の結果、隣接する主リブ間
に、前記リブよりも高さの低いミニリブを設けると共
に、前記ミニリブ上面の少なくとも長辺に沿ってアール
を設けることにより、電気抵抗の増大をもたらすことな
く、放電特性の劣化なしに、肉薄シートのベース部の酸
化劣化を防止し得る鉛蓄電池用リブ付きセパレータを構
成できることを知見した。本発明の鉛蓄電池用リブ付き
セパレータは、かかる知見に基づきなされたもので、請
求項１記載の通り、肉薄シートのベース面に、所定の間
隔を存して多数条の主リブを設けた鉛蓄電池用リブ付き
セパレータにおいて、隣接する主リブ間に、前記リブよ
りも高さの低いミニリブを設けると共に、前記ミニリブ
上面の少なくとも長辺に沿ってアールを設けたことを特
徴とする。また、請求項２記載の鉛蓄電池用リブ付きセ
パレータは、請求項１記載の鉛蓄電池用リブ付きセパレ
ータにおいて、前記ミニリブの短辺にもアールを設けた
ことを特徴とする。また、請求項３記載の鉛蓄電池用リ
ブ付きセパレータは、請求項１または２記載の鉛蓄電池
用リブ付きセパレータにおいて、前記アールの曲率半径
を０．０２〜０．２ｍｍの範囲に形成したことを特徴と
する。また、請求項４記載の鉛蓄電池用リブ付きセパレ
ータは、請求項１乃至３の何れかに記載の鉛蓄電池用リ
ブ付きセパレータにおいて、前記ミニリブの高さを主リ
ブの１０〜５０％の高さに形成したことを特徴とする。
また、請求項５記載の鉛蓄電池用リブ付きセパレータ
は、請求項１乃至４の何れかに記載の鉛蓄電池用リブ付
きセパレータにおいて、前記ミニリブを隣接する主リブ
間の中央部近傍のみに設けたことを特徴とする。また、
請求項６記載の鉛蓄電池用リブ付きセパレータは、請求
項１乃至５の何れかに記載の鉛蓄電池用リブ付きセパレ
ータにおいて、前記主リブのピッチ間距離が５．０ｍｍ
以上であることを特徴とする。Means for Solving the Problems The inventors of the present invention have made earnest studies in order to meet such a demand. As a result, a mini-rib having a height lower than that of the rib is provided between the adjacent main ribs, and at the same time, the upper surface of the mini-rib is reduced. By providing the radius along at least the long side, it is possible to configure a ribbed separator for a lead storage battery that can prevent the oxidation deterioration of the base portion of the thin sheet without causing an increase in electric resistance and without deterioration of discharge characteristics. I found out. The ribbed separator for a lead-acid battery of the present invention is made on the basis of such findings, and as described in claim 1, a lead having a large number of main ribs provided at predetermined intervals on the base surface of the thin sheet. In the ribbed separator for a storage battery, a mini-rib having a height lower than that of the rib is provided between adjacent main ribs, and a rounded shape is provided at least along a long side of the upper surface of the mini-rib. The ribbed separator for a lead storage battery according to claim 2 is characterized in that, in the ribbed separator for a lead storage battery according to claim 1, a radius is also provided on the short side of the mini-rib. The lead-acid battery ribbed separator according to claim 3 is the lead-acid battery ribbed separator according to claim 1 or 2, wherein the radius of curvature of the radius is formed in a range of 0.02 to 0.2 mm. Characterize. The lead-acid battery ribbed separator according to claim 4 is the lead-acid battery ribbed separator according to any one of claims 1 to 3, wherein the height of the mini rib is 10 to 50% of the main rib. It is characterized in that it is formed.
A ribbed separator for a lead storage battery according to claim 5 is the ribbed separator for a lead storage battery according to any one of claims 1 to 4, wherein the mini-rib is provided only near a central portion between adjacent main ribs. It is characterized by Also,
The ribbed separator for a lead storage battery according to claim 6 is the ribbed separator for a lead storage battery according to any one of claims 1 to 5, wherein a pitch distance between the main ribs is 5.0 mm.
The above is characterized.
【０００５】[0005]
【発明の実施の形態】図１は、本発明鉛蓄電池用リブ付
きセパレータの一実施の形態の平面図、図２はその拡大
断面図を示すもので、図中１０で示される本発明鉛蓄電
池用リブ付きセパレータは、ポリエチレン樹脂シート等
からなる肉薄シート１のベース面２に、電極板２０に当
接させるように所定の間隔を存して多数条の主リブ３を
設けると共に、これら隣接する主リブ３，３間に、前記
リブ３よりも高さの低いミニリブ４を設けると共に、前
記ミニリブ４の上面の長辺に沿ってアール４ａを設ける
ようにてある。図示のものでは、主リブ３，３間の中心
線Ｌに沿って１本のミニリブ４のみを設けるようにした
ものである。このミニリブ４の高さは主リブ３の高さの
１／５に形成してある。1 is a plan view of an embodiment of a ribbed separator for a lead-acid battery of the present invention, and FIG. 2 is an enlarged cross-sectional view of the same. The lead-acid battery of the present invention is shown at 10 in the drawing. The rib-equipped separator is provided with a large number of main ribs 3 at predetermined intervals on the base surface 2 of a thin sheet 1 made of a polyethylene resin sheet or the like so as to be in contact with the electrode plate 20 and adjacent to each other. Between the main ribs 3 and 3, a mini rib 4 having a height lower than that of the rib 3 is provided, and a radius 4a is provided along the long side of the upper surface of the mini rib 4. In the illustrated example, only one mini rib 4 is provided along the center line L between the main ribs 3 and 3. The height of the mini rib 4 is formed to be 1/5 of the height of the main rib 3.
【０００６】かくして、上記、ミニリブ付きセパレータ
を極板群に組み込み、鉛蓄電池に構成した場合、その使
用中において、充放電による極板の膨張、収縮などに伴
う変形や、セパレータの肉薄ベース部の湾曲が生じて
も、前記セパレータの主リブ間の中央近傍に設けられた
ミニリブによって、薄肉シートのベース部が極板面と接
触するのが防止され、前記シートの酸化劣化は未然に防
止され、その結果、内部短絡の防止、電池寿命の増大が
図られる。特に、前記ミニリブの上面の長辺に沿ってア
ールを設けてあるため、極板がミニリブに当接した際
に、極板の活物質がミニリブの上面のエッジによって脱
落されるのを防止でき、電池寿命を長寿命化させること
ができる。Thus, when the above-mentioned mini-ribbed separator is incorporated into the electrode plate group to form a lead storage battery, the electrode plate is deformed due to expansion and contraction due to charging and discharging during use, and the separator has a thin base portion. Even if bending occurs, the mini-rib provided near the center between the main ribs of the separator prevents the base portion of the thin sheet from coming into contact with the electrode plate surface, and oxidation deterioration of the sheet is prevented in advance. As a result, an internal short circuit is prevented and the battery life is extended. In particular, since the radius is provided along the long side of the upper surface of the mini-rib, when the electrode plate contacts the mini-rib, it is possible to prevent the active material of the electrode plate from falling off by the edge of the upper surface of the mini-rib, The battery life can be extended.
【０００７】前記ミニリブ４は、図中Ｒで示した、隣接
する主リブ３，３のピッチ間距離に対して中央から左右
１０％の範囲内に設けることが好ましく、１本に限ら
ず、２本など、複数本設けることもできる。It is preferable that the mini-ribs 4 be provided within a range of 10% from the center to the distance between the pitches of the adjacent main ribs 3 and 3 shown by R in the figure, and the number is not limited to one, but 2 It is also possible to provide a plurality of books such as books.
【０００８】また、図示のミニリブ４は、主リブ３の高
さの１／５の高さに形成したが、１／２以下の高さにす
れば、電気抵抗の増大をもたらすことなく、前記薄肉シ
ートのベース部が極板面と接触するのを防止することが
できる。また、このような薄肉シートのベース部の極板
面との接触を防止するためには、最低でも１／１０程度
の高さを有するように形成することが好ましく、従っ
て、ミニリブの高さは、主リブの高さに対して１／２〜
１／１０の範囲にするのが好ましい。Although the mini-rib 4 shown in the figure is formed to have a height of ⅕ of the height of the main rib 3, if the height is ½ or less, the electric resistance is not increased, and It is possible to prevent the base portion of the thin sheet from coming into contact with the electrode plate surface. Further, in order to prevent the contact of the base portion of such a thin sheet with the electrode plate surface, it is preferable to form the thin sheet so as to have a height of at least about 1/10. , 1/2 to the height of the main rib
It is preferably in the range of 1/10.
【０００９】また、前記ミニリブは直線状に形成した
が、図３に示すように、破断線状に形成してもよいし、
或いは、図４に示すように、破断したものを、更に、傾
斜配置するように形成してもよい。これらの場合も、少
なくともミニリブの上面の少なくとも長辺に沿ってアー
ルを形成すればよい。勿論、短辺にもアールを設けるこ
とが、より好ましい。Further, although the mini-ribs are formed in a linear shape, they may be formed in a broken line shape as shown in FIG.
Alternatively, as shown in FIG. 4, the broken pieces may be further formed so as to be arranged in an inclined manner. Also in these cases, it is sufficient to form the radius R at least along the long side of the upper surface of the mini-rib. Of course, it is more preferable to provide the radius on the short side.
【００１０】[0010]
【実施例】次に、本発明鉛蓄電池用リブ付きセパレータ
の具体的実施例を、比較例と比較して説明する。
（実施例１）本実施例の鉛蓄電池用リブ付きセパレータ
は、高密度ポリエチレン樹脂粉末と、無機粉体として平
均粒径５μｍのシリカ粉末と、鉱物オイルとしてパラフ
ィン系オイルとをヘンシェルミキサで混合し、得られた
混合物を２軸押出機で押出し、成形ロールで加圧成形
し、トリクロロエチレン中に浸漬して鉱物オイルを除去
し、セパレータの鉱物オイル含有量が１３質量％となる
ようにした。そして、厚さ０．２５ｍｍのベース部上
に、上辺０．４ｍｍ、底辺０．８ｍｍ、高さ１．００ｍ
ｍ、断面積０．６０ｍｍ2の断面形状を有する主リブを
１０ｍｍ間隔で連設するようにして形成した。また、前
記主リブ間のほぼ中央に、上辺０．２ｍｍ、底辺０．４
ｍｍ、高さ０．３０ｍｍ、断面積０．０９ｍｍ2（主リ
ブの断面積比０．１５）の断面形状を有する直線状のミ
ニリブを１本形成した。そして、このミニリブの上辺の
長辺に沿って、曲率半径０．１ｍｍのアールを形成し
た。EXAMPLE Next, a specific example of the ribbed separator for a lead storage battery of the present invention will be described in comparison with a comparative example. Example 1 A ribbed separator for a lead-acid battery of this example was prepared by mixing a high-density polyethylene resin powder, silica powder having an average particle diameter of 5 μm as an inorganic powder, and paraffin oil as a mineral oil with a Henschel mixer. The obtained mixture was extruded with a twin-screw extruder, pressure-molded with a molding roll, and immersed in trichlorethylene to remove mineral oil, so that the mineral oil content of the separator was 13% by mass. Then, on the base portion having a thickness of 0.25 mm, the top side is 0.4 mm, the bottom side is 0.8 mm, and the height is 1.00 m.
Main ribs having a cross-sectional shape of m and a cross-sectional area of 0.60 mm 2 were formed so as to be continuously arranged at intervals of 10 mm. In addition, the upper side is 0.2 mm and the bottom side is 0.4 mm in the middle of the main ribs.
mm, a height of 0.30 mm, and a cross-sectional area of 0.09 mm 2 (a cross-sectional area ratio of the main ribs was 0.15). Then, a radius having a radius of curvature of 0.1 mm was formed along the long side of the upper side of the mini-rib.
【００１１】（比較例１）従来品
主リブ間にミニリブを設けなかったこと以外は実施例１
と同様にして、鉛蓄電池用リブ付きセパレータを作製し
た。(Comparative Example 1) Example 1 except that mini ribs were not provided between the main ribs of the conventional product.
In the same manner as in, a ribbed separator for a lead storage battery was produced.
【００１２】（比較例２）ミニリブにアールを設けなか
ったこと以外は実施例１と同様にして、鉛蓄電池用リブ
付きセパレータを作製した。(Comparative Example 2) A ribbed separator for a lead storage battery was prepared in the same manner as in Example 1 except that the mini-rib was not provided with a radius.
【００１３】次に、得られた実施例並びに各比較例の鉛
蓄電池用リブ付きセパレータにつき、下記に示す耐酸化
時間試験を行い、セパレータの寿命評価を行うと共に、
電池の始動性に影響する電気抵抗試験を行った。その結
果を下記表１に示す。
［耐酸化時間］試験容器に試料（セパレータ７０ｍｍ
角）を１０ｋＰａの圧力がかかるようセットし、比重
１．３００（２０℃）の電解液を１０００ｍｌ注入し、
電界液温度を４５±２℃の状態で２．５Ａの調整をし
た。耐酸化時間は、端子電圧が２．６Ｖ以下または電圧
差が０．２Ｖ以上となった時間で表示するようにした。
［電気抵抗］ＪＩＳ Ｃ２３１３に準拠した方法により
測定した。Next, with respect to the ribbed separators for lead acid batteries of the obtained Examples and Comparative Examples, the following oxidation resistance time test was conducted to evaluate the life of the separators and
An electric resistance test that affects the startability of the battery was performed. The results are shown in Table 1 below. [Oxidation resistance time] Test sample (separator 70 mm
Corner) is set so that a pressure of 10 kPa is applied, and 1000 ml of an electrolytic solution having a specific gravity of 1.300 (20 ° C.) is injected,
The electrolytic solution temperature was adjusted to 2.5 A while the temperature was 45 ± 2 ° C. The oxidation resistance time was displayed as the time when the terminal voltage was 2.6 V or less or the voltage difference was 0.2 V or more. [Electrical resistance] The electric resistance was measured by a method according to JIS C2313.
【００１４】[0014]
【表１】 [Table 1]
【００１５】表１に示すように、実施例の鉛蓄電池用リ
ブ付きセパレータは、電気抵抗は従来品と同等で、耐酸
化時間は２５％の向上が認められた。また、比較例１
（従来品）の鉛蓄電池用リブ付きセパレータは、実施例
１の鉛蓄電池用リブ付きセパレータに比べ、電気抵抗は
同等であったが、耐酸化時間では２５％も劣るものであ
った。また、比較例２の鉛蓄電池用リブ付きセパレータ
は、実施例と同等に電気抵抗の上昇もなく、耐酸化時間
の向上が認められたが、活物質の脱落が認められ、実施
例に比べ、電池の長寿命化を達成することができなかっ
た。As shown in Table 1, the ribbed separators for lead-acid batteries of Examples had the same electrical resistance as conventional products, and the oxidation resistance time was improved by 25%. Comparative Example 1
The ribbed separator for a lead storage battery (conventional product) had an electric resistance equivalent to that of the ribbed separator for a lead storage battery of Example 1, but was inferior in oxidation resistance time by 25%. Further, the ribbed separator for a lead storage battery of Comparative Example 2 did not show an increase in electrical resistance and an improvement in oxidation resistance time was observed as in the case of Example, but the active material was observed to fall off, and It has not been possible to achieve a long battery life.
【００１６】[0016]
【発明の効果】以上説明したように、本発明のリブ付き
セパレータを鉛蓄電池に使用した場合、主リブ間に配置
したミニリブにアールを設けることにより、極板とセパ
レータの薄肉シートベースとの接触を防止でき、また、
電気抵抗を小さく維持できるばかりでなく、ミニリブと
極板の当接時における活物質の脱落を防止でき、セパレ
ータ寿命の長寿命化をもたらす効果を有する。As described above, when the ribbed separator of the present invention is used in a lead-acid battery, the mini-ribs arranged between the main ribs are provided with a radius so that the electrode plate and the thin sheet base of the separator are brought into contact with each other. Can be prevented
Not only can the electric resistance be kept small, but the active material can be prevented from falling off when the mini-rib and the electrode plate are brought into contact with each other, which has the effect of extending the life of the separator.
【図面の簡単な説明】[Brief description of drawings]
【図１】 本発明鉛蓄電池用リブ付きセパレータの一実
施の形態の平面図FIG. 1 is a plan view of an embodiment of a ribbed separator for a lead storage battery according to the present invention.
【図２】 同拡大断面図FIG. 2 is an enlarged sectional view of the same.
【図３】 本発明鉛蓄電池用リブ付きセパレータの実施
の形態の一変形例を示す平面図FIG. 3 is a plan view showing a modified example of the embodiment of the ribbed separator for a lead storage battery according to the present invention.
【図４】 本発明鉛蓄電池用リブ付きセパレータの実施
の形態の他変形例を示す平面図FIG. 4 is a plan view showing another modified example of the embodiment of the ribbed separator for a lead storage battery according to the present invention.
１ 肉薄シート ２ ベース面 ３ 主リブ ４ ミニリブ ４ａアール １０ 鉛蓄電池用リブ付きセパレータ ２０ 極板 Ｈｓ 主リブの高さ Ｈｍ ミニリブの高さ Ｌ 中心線 Ｒ 中央から左右１０％の範囲 1 thin sheet 2 Base surface 3 main ribs 4 mini ribs 4a are 10 Ribbon separator for lead acid batteries 20 plates Hs Main rib height Hm mini rib height L center line Range from the center R to the left and right 10%
Claims (6)
存して多数条の主リブを設けた鉛蓄電池用リブ付きセパ
レータにおいて、隣接する主リブ間に、前記リブよりも
高さの低いミニリブを設けると共に、前記ミニリブ上面
の少なくとも長辺に沿ってアールを設けたことを特徴と
する鉛蓄電池用リブ付きセパレータ。1. A lead storage battery ribbed separator having a plurality of main ribs provided at predetermined intervals on a base surface of a thin sheet, wherein a height between the main ribs adjacent to each other is lower than that of the ribs. A ribbed separator for a lead storage battery, wherein a mini-rib is provided and a rounded shape is provided along at least the long side of the upper surface of the mini-rib.
ことを特徴とする請求項１記載の鉛蓄電池用リブ付きセ
パレータ。2. The ribbed separator for a lead storage battery according to claim 1, wherein a radius is also provided on a short side of the mini-rib.
２ｍｍの範囲に形成したことを特徴とする請求項１また
は２記載の鉛蓄電池用リブ付きセパレータ。3. The radius of curvature of the radius is 0.02 to 0.
3. The ribbed separator for a lead storage battery according to claim 1, which is formed in a range of 2 mm.
０％の高さに形成したことを特徴とする請求項１乃至３
の何れかに記載の鉛蓄電池用リブ付きセパレータ。4. The height of the mini rib is 10 to 5 of the main rib.
The height is 0%, and the height is 0%.
9. A ribbed separator for a lead storage battery according to any one of 1.
部近傍のみに設けたことを特徴とする請求項１乃至４の
何れかに記載の鉛蓄電池用リブ付きセパレータ。5. The lead-acid battery rib separator according to claim 1, wherein the mini-ribs are provided only in the vicinity of a central portion between adjacent main ribs.
以上であることを特徴とする請求項１乃至５の何れかに
記載の鉛蓄電池用リブ付きセパレータ。6. The pitch between the main ribs is 5.0 mm.
It is above, The ribbed separator for lead acid batteries in any one of Claim 1 thru | or 5 characterized by the above-mentioned.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001304648A JP4812209B2 (en) | 2001-09-28 | 2001-09-28 | Rib separator for lead acid battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001304648A JP4812209B2 (en) | 2001-09-28 | 2001-09-28 | Rib separator for lead acid battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003109573A true JP2003109573A (en) | 2003-04-11 |
| JP4812209B2 JP4812209B2 (en) | 2011-11-09 |
Family
ID=19124540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001304648A Expired - Fee Related JP4812209B2 (en) | 2001-09-28 | 2001-09-28 | Rib separator for lead acid battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4812209B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003308821A (en) * | 2002-04-15 | 2003-10-31 | Nippon Muki Co Ltd | Manufacturing method for ribbed separator for lead storage battery |
| JP2007501992A (en) * | 2003-08-09 | 2007-02-01 | ダラミック，インコーポレイテッド | Separator for lead acid battery |
| JP2013211115A (en) * | 2012-03-30 | 2013-10-10 | Nippon Sheet Glass Co Ltd | Separator for liquid type lead battery, and liquid type lead battery |
| JP2015216125A (en) * | 2015-07-27 | 2015-12-03 | 日本板硝子株式会社 | Separator for liquid-type lead storage batteries, and liquid-type lead storage battery |
| US10230088B1 (en) | 2015-01-30 | 2019-03-12 | Johnson Controls Technology Company | Battery electrode assembly, separator and method of making same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62126062U (en) * | 1986-02-03 | 1987-08-10 | ||
| JPH052369U (en) * | 1991-06-26 | 1993-01-14 | 日本無機株式会社 | Rib Separator for Lead Acid Battery |
-
2001
- 2001-09-28 JP JP2001304648A patent/JP4812209B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62126062U (en) * | 1986-02-03 | 1987-08-10 | ||
| JPH052369U (en) * | 1991-06-26 | 1993-01-14 | 日本無機株式会社 | Rib Separator for Lead Acid Battery |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003308821A (en) * | 2002-04-15 | 2003-10-31 | Nippon Muki Co Ltd | Manufacturing method for ribbed separator for lead storage battery |
| JP2007501992A (en) * | 2003-08-09 | 2007-02-01 | ダラミック，インコーポレイテッド | Separator for lead acid battery |
| JP2013211115A (en) * | 2012-03-30 | 2013-10-10 | Nippon Sheet Glass Co Ltd | Separator for liquid type lead battery, and liquid type lead battery |
| US10230088B1 (en) | 2015-01-30 | 2019-03-12 | Johnson Controls Technology Company | Battery electrode assembly, separator and method of making same |
| JP2015216125A (en) * | 2015-07-27 | 2015-12-03 | 日本板硝子株式会社 | Separator for liquid-type lead storage batteries, and liquid-type lead storage battery |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4812209B2 (en) | 2011-11-09 |
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