JP2003104845A - Hair cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a hair cosmetic which has a new excellent dryness- preventing effect, is non-sticky, can prevent stickiness caused by the secretion of sebum, the collapse of a styling agent with time, and can retain a dry feeling. SOLUTION: This hair cosmetic contains the following components (A) and (B). (A) A guanidine derivative having a surface-activating ability or its salt. (B) An organic modified clay mineral.

Description

DETAILED DESCRIPTION OF THE INVENTION [0001] TECHNICAL FIELD The present invention relates to a hair shampoo,
Hair rinse, hair conditioner, hair treatment
G, styling agent, hair pack, hair spray, hair growth
For hair cosmetics used as a preparation, hair tonic, etc.
For more details, suppresses unprecedented roughness on hair
Has an effect and gives a dry feeling without stickiness
Can further secrete sebum, collapse of styling agents, etc.
Reduces the stickiness that occurs over time, giving a smooth feeling
The present invention relates to a hair cosmetic that can be continued. [0002] 2. Description of the Related Art In recent years, women's hair has been
As the consciousness rises, daily hair washing, styling,
Physical damage, hair dye, bleach, par
It is susceptible to chemical damage due to treatments.
The defects of damaged hair include the length of the hair after drying.
And deterioration of smoothness, combing, etc.
You. Hairline to improve the above hair defects
Hair, hair conditioner, hair treatment, hair
Mousse, hair cream, hair spray, styling
Hair cosmetics such as foam are used. Conventionally, such hair cosmetics are, for example,
Guanidine derivatives and their salts with surface-active ability
Containing a combination with a secondary alcohol as a main component
JP-A-5-194150) or the above guanidine
Derivatives and their salts and liquid oils, cationic polymers,
Various combinations such as glycerin fatty acid esters
(Japanese Patent Application Laid-Open No. 4-49220,
JP-A-4-54112, JP-A-2001-17212
No. 9). In addition, organically modified clay minerals and water-soluble polymers
Hair cosmetic containing the compound and a high molecular weight silicone
JP-A-5-246824), cationic thickener and organic
Hair cosmetics containing modified clay minerals (JP-A-10-26)
No. 5344) has been proposed. [0004] However, conventional hair cosmetics do not
Has the effect of suppressing dusty and non-sticky
Can give a feeling of smoothness, secretion of sebum, styling
Prevents stickiness that occurs over time due to collapse of the ring agent, etc.
However, it was insufficient in maintaining a smooth feeling. [0005] SUMMARY OF THE INVENTION The present invention
Overcome the drawbacks of conventional hair cosmetics and have excellent dryness
It has the effect of suppressing and has a smooth feeling without stickiness
Can be given, furthermore sebum secretion, styling
Reduces the stickiness that occurs over time due to
The aim is to provide hair cosmetics that can maintain a feeling
You. [0006] Means for Solving the Problems The present inventors have solved the above problems.
As a result of intensive studies to solve the problem, (A)
Derivative or salt thereof and (B) organic modification
Hair cosmetics containing clay minerals provide excellent suppression of dryness
Has an effect that gives
In addition to sebum secretion and styling
Suppresses the stickiness that occurs over time due to
They have found that they can be sustained, and have completed the present invention. That is, the present invention provides the following component (A):
(B) A hair cosmetic comprising the component
I will provide a. (A) Guanidine derivative or salt thereof having surface activity (B) Organic modified clay mineral [0008] BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in more detail.
I will tell. The hair cosmetic of the present invention, as described above,
(A) Guanidine derivative or salt thereof having surface activity
And (B) the combined use of an organically modified clay mineral
Has an unprecedented effect of suppressing roughness and is solid
It can give a dry feeling without sticking, and furthermore sebum
Should occur over time due to lactation, collapse of styling agents, etc.
It can reduce rattling and maintain a dry feel. [0009] Here, the component (A) of the hair cosmetic of the present invention.
Guanidine derivative or salt thereof having surface active ability
Examples thereof include those represented by the following general formula (1).
I can do it. [0010] Embedded image [Wherein, R¹Is linear or branched having 1 to 22 carbon atoms
Alkyl group, alkenyl group, or alkyl ether group
And m is 0 or 1. A is CHR⁶(CH_Two)_n
[However, R⁶Is a hydrogen atom or COOR⁷(R⁷Is hydrogen field
, A branch optionally substituted by a hydrogen group having 1 to 6 carbon atoms
Or linear alkyl or alkenyl groups)
And n is an integer from 0 to 9. ], R^Two, R^ThreeIs water
May be substituted with a hydrogen atom or a hydroxyl group having 1 to 12 carbon atoms.
Branched or linear alkyl or alkenyl groups
And R^Four, R^FiveIs a hydrogen atom, a hydroxyl group having 1 to 6 carbon atoms
Optionally substituted branched or straight-chain alkyl
X is an inorganic acid or an organic acid.
You. ] Here, the substituent R in the above formula (1)¹Is
C 1-22, preferably 11-21, more preferably
Is a branched or linear alkyl group of 11 to 17,
Alkenyl group or alkyl ether group, such as acid
C which may have an intervening elemental atom₁₁H_{twenty three}-, C₁₂H_{twenty five}-, C₁₃
H₂₇-, C₁₄H₂₉-, C₁₅H₃₁-, C₁₆H₃₃-, C₁₇H
₃₅−, (C₈H₁₇)_TwoCH-, 4-C_TwoH_FiveC₁₅H₃₀-Etc.
Are preferred. R^Two, R^ThreeIs a hydrogen atom or a group having 1 to 12 carbon atoms.
Branched or straight-chain alkyl or alkenyl group
Of these, a hydrogen atom is more preferred. R^Four, R^FiveRepresents a hydrogen atom, a group having 1 to 6 carbon atoms.
A branched or straight-chain alkyl or alkenyl group;
Of these, a hydrogen atom is more preferred. A is CHR⁶(CH_Two)_nWhere n is
0-9, preferably an integer of 1-5, (CH_Two)_nWhen
Is preferably a linear alkylene group such as methyl
Len group, ethylene group, propylene group, butylene group, pen
Examples include a tylene group and a hexylene group. Also, R⁶
Is a hydrogen atom or COOR⁷And R⁷Is a hydrogen atom,
Substituted by a hydroxyl group having 1 to 6, preferably 1 to 3 carbon atoms
A branched or straight-chain alkyl group or
Kenyl group, for example, COOH, COOC_TwoH_Fiveetc
No. Note that m is 0 or 1. The surfactant (A) of the present invention
Guanidine derivatives or salts thereof having functional properties
In addition, those represented by the following general formula (2) are also preferably used.
be able to. [0016] Embedded image (However, in the above formula, R⁸Is a linear or C2-C6
Is a branched alkylene group in which some of the hydrogen atoms are
It may be substituted with a alkyl group. R⁹Has 12 or more carbon atoms
24 branched or straight-chain alkyl groups or alke
Represents a nyl group. X is an inorganic acid or an organic acid. ) The above guanidine derivative is usually used in the form of a salt.
Be blended. That is, the general formula (1) and the general formula
X in (2) is an inorganic compound such as hydrochloric acid, sulfuric acid, phosphoric acid, and nitric acid
Acid or glycolic acid, acetic acid, tartaric acid, propionic acid,
Lactic acid, citric acid, salicylic acid, succinic acid, malic acid, butyric
Acid, p-toluenesulfonic acid, higher fatty acid, L or DL
-Pyrrolidone carboxylic acid, acidic amino acid, pyroglutami
Can be used as organic acids such as
When using an inorganic acid salt from the viewpoint of the solubility of
Or phosphates, glycolates when used as organic acid salts,
Acetate or L- or DL-pyrrolidone carboxylate
Is desirable. In order to make these salts,
The guanidine derivative may be neutralized with the above acid. The component (A) has such a surfactant activity.
More specific as guanidine derivatives and their salts
Include, for example, hexadecylguanidine, octadecyl
Alkyls such as anidine and 2-octyldodecylguanidine
Alkyleneguas such as luguanidine and oleylguanidine
Niidine, 2-guanidinoethyl lauroamide, 4-gua
Nidinobutyl lauroamide, 3-guanidinopropyl
Kutanoylamide, 2-guanidinoethyl stearoyl
Amide, 6-guanidinohexyl myristoyl amide, etc.
Alkylamidoguanidine, 4-guanidinobutyryl
Alkylene amide guanines such as lenoylamido guanidine
Gin, N-coconut fatty acid acyl-L-arginine ethyl
, N-coconut fatty acyl-L-arginine stearyl
, N- [3-alkyl (12,14) oxy-2-hi
Droxypropyl] -L-arginine hydrochloride, N-lauro
Il-L-argininepropyl, N-2-ethylhexa
Arginine derivatives such as Noyl-L-arginine methyl,
1,8-diguanidinooctane, 1,18-diguanidine
Diguanidine derivatives such as noolein and salts thereof
Is mentioned. The guanidine derivative of the component (A) or a salt thereof
May be used alone or in combination of two or more.
The amount is not particularly limited, but hair
0.01 to 20% of the whole material (% by mass, the same applies hereinafter),
Or 0.1-10%, more preferably 0.1-3%
Is preferred. If the amount is too small, the present invention
The effect may not be enough. On the other hand, too much is economic
Not only disadvantageous but also rather sticky and heavy finish
It tends to be bitter. [0020] The component (B) of the hair cosmetic of the present invention has
Modified clay minerals are water-swellable clay minerals that are quaternary ammonium.
Salt-type cationic surfactant and / or nonionic interface
Those obtained by treatment with an activator are preferred. Swelling above
Wet clay mineral is a colloidal hydrous silica having a three-layer structure.
A type of aluminum acid, specifically montmorillonii
And saponite and hectorite
Montmorillonite group (commercially available Vegum, Kunipia,
Laponite and Wenger. ) And sodium salt
Lithic mica, sodium or lithium teniolite
Synthetic mica known under the name
P Industries Ltd. ). The above quaternary ammonium salt type cationic interface
The activator is represented by the following general formula (3). (However
And in the following formula, R₁Has 10 to 22 carbon atoms, especially 16 to 2 carbon atoms.
2, an alkyl group or a benzyl group, R_TwoIs a methyl group or charcoal
An alkyl group having a prime number of 10 to 22, especially 16 to 22, R_ThreeWhen
R_FourIs an alkyl group having 1 to 3 carbon atoms or hydroxyalkyl
X represents a halogen atom or a methyl sulfate residue.
Represent. ) [0022] Embedded image The above quaternary ammonium salt type cationic interface
As the activator, more specifically, for example, dodecyltri
Methylammonium chloride, myristyltrimethyla
Ammonium chloride, cetyltrimethylammonium chloride
Chloride, stearyltrimethylammonium chloride,
Aralkyltrimethylammonium chloride, behenylt
Limethyl ammonium chloride, myristyl dimethyl ester
Tillammonium chloride, cetyl dimethylethylan
Monium chloride, stearyl dimethyl ethyl ammonium
Um chloride, aralkyl dimethyl ethyl ammonium chloride
Loride, behenyldimethylethylammonium chloride
De, myristyl diethylmethylammonium chloride,
Cetyl diethyl methyl ammonium chloride, steari
Diethylmethylammonium chloride, araquildie
Tyl methyl ammonium chloride, behenyl diethyl
Thilammonium chloride, benzyldimethyl myristi
Luammonium chloride, benzyldimethylcetyluan
Monium chloride, benzyl dimethyl stearyl ammonium
Numium chloride, benzyl dimethyl behenyl ammonium
Muchloride, benzylmethylethylcetyl ammonium
Chloride, benzyl methyl ethyl stearyl ammonium
Muchloride, dibehenyldihydroxyethylammonium
Muchloride and the corresponding bromides, and also dipalmichi
Rupropylethylammonium methyl sulfate
No. In practicing the present invention,
One or more types are arbitrarily selected. The above-mentioned non-ionic surfactant has an HLB
Values are in the range of 2 to 16, with 3 to 12 being more preferred.
Suitable. For example, 2-30 polyoxyethylene
Addition of POE (hereinafter abbreviated as POE (2-30)). }, Oleil
Ether POE (2-35) stearyl ether, PO
E (2-20) lauryl ether, POE (1-20)
Alkyl phenyl ether, POE (6-18) beheni
, POE (5-25) 2-decylpentadeci
Ruether, POE (3-30) 2-decyltetradeci
Ruether, POE (8-16) 2-octyldecyl
Ether type activators such as ether, and POE (4-60)
Hardened castor oil, POE (3-14) fatty acid monoester
, POE (6-30) fatty acid diester, POE (5
-20) Ester type activity such as sorbitan fatty acid ester
Agent, further POE (2-30) glyceryl monoisostea
Rate, POE (10-60) glyceryl triisoste
Allate, POE (7-50) hydrogenated castor oil monoisos
Tearate, POE (12-60) hydrogenated castor oil Torii
Etile of ether ester type activator such as sostearate
Oxide-added surfactant and decaglyceryl tet
Laolate, hexaglyceryl triisostearate,
Tetraglyceryl diisostearate, diglyceryl di
Polyglycerin fatty acid esters such as isostearate,
Glyceryl monostearate, glyceryl monoisoste
Glycerin fats such as allate and glyceryl monooleate
Polyhydric alcohol fatty acid ester type surfactants such as acid esters
And the like. Among them, decaglycerylte
Traolate, hexaglyceryl triisostearate
Triglyceride such as tetraglyceryl diisostearate
Serine or higher polyglycerin fatty acid ester, POE
(2-12) Oleyl ether, POE (3-12)
Tearyl ether, POE (2-10) lauryl ethere
, POE (2-10) nonylphenyl ether, PO
E (6 to 15) behenyl ether, POE (5 to 20)
2-decylpentadecyl ether, POE (5-17)
2-decyltetradecyl ether, POE (8-16)
POE addition ether type such as 2-octyldecyl ether
Activator and POE (10-20) hydrogenated castor oil, PO
E (5-14) oleic acid monoester, POE (6 ~
20) Oleic acid diester, POE (5-10) sol
POE addition ester type activity such as bitan oleate
Agent, POE (3 to 15) glyceryl monoisostearee
, POE (10-40) glyceryl triisostea
POE addition ether ester type activators such as
Tylene oxide-added nonionic surfactants are particularly preferred.
Good. In practicing the present invention, these nonionic
One or two or more surfactants are arbitrarily selected.
Used. The HLB value of the nonionic activator is:
It is calculated by the following Kawakami equation. [0025] (Equation 1) (Where M_wIs the molecular weight of the hydrophilic group, M_oIs
Each represents the molecular weight of the lipophilic base. ) The organically modified clay mineral used in the present invention is, for example,
Low boiling point such as water, acetone or lower alcohol
Water swellable clay mineral and quaternary ammonium salt type
A thione surfactant and / or a nonionic surfactant
By dispersing and stirring, and then removing the low boiling point solvent.
(Commercially available products are Esven E, Esven W, D
Sven XL, Esven N-400;
Manufactured by Clayton AF, Clayton SO; Southern Crepe
There is a product made by Rodact. ). The organically modified clay mineral used in the present invention is
Grade ammonium salt type cationic surfactant and / or non-a
Water swells due to penetration of on-active surfactant between layers
Since the layer spacing of the clayey mineral is widened, X-ray
Quaternary ammonium
Salt type cationic surfactant and / or nonionic surfactant
The presence or absence of the adsorption of the agent can be confirmed. In preparing the organically modified clay mineral of the present invention,
Mixing ratio of quaternary ammonium salt type cationic surfactant
Is 20 parts by mass with respect to 100 parts by mass of the water-swellable clay mineral.
To 120 parts by mass, more preferably 30 to 10 parts by mass.
0 parts by mass. Quaternary ammonium salt type cationic interface
If the compounding ratio of the activator is too small, it will have a sufficient effect.
Machine modified clay minerals may not be obtained.
Too much quaternary ammonium salt type cationic
In cases where surfactants are mixed in and reduce the stability of the formulation
There is a case. Further, the organically modified clay mineral of the present invention is prepared.
The mixing ratio of the nonionic surfactant at the time of
5 to 120 parts by mass is preferable for 100 parts by mass of the earth mineral.
And more preferably 15 to 100 parts by mass. Non-a
Sufficient effect if the proportion of on-surfactant is too small
May not be obtained, and vice versa
If the blending ratio is too high, excess nonionic surfactant
In some cases, it may be mixed to lower the stability of the preparation. [0031] The component (B) of the hair cosmetic composition of the present invention has
Modified clay minerals can be used alone or in combination of two or more.
May be used in combination, and the amount thereof is not particularly limited.
However, 0.01-20% of the total hair cosmetics, preferably
0.05 to 10%, more preferably 0.05 to 5%
Is preferred. If the amount is too small, the effect of the present invention will be obtained.
May not be enough. On the other hand, if it is too large,
Not only good, but also rather sticky and heavy finish
It tends to be. [0032] The hair cosmetic composition of the present invention comprises
In addition, as long as the effects of the present invention are not impaired, ordinary hair makeup
Ingredients, especially compounding agents used in emulsified compositions, such as
Activators, oils, alcohols, humectants, thickeners, preservatives
Agents, antioxidants, chelating agents, pH adjusters, fragrances, colors
Element, UV absorber / scatterer, vitamins, amino acids, water
And the like. Optional components
It is not limited. The present invention provides a hair shampoo, a hair rinse,
Conditioners, treatments, styling agents,
It can be used in hair compositions such as hair restorer and hair restorer.
Also, prepare according to the usual method for each dosage form, and
The dose can be used in the usual way. [0034] According to the present invention, an unprecedented and excellent
Has the effect of suppressing roughness and has no stickiness
Can give a feeling of sebum, secretion of sebum, and styling
Reduces the stickiness that occurs over time due to disintegration of the agent, etc.
It is possible to obtain a hair cosmetic which can maintain a smooth feeling. [0035] The present invention will now be described based on examples and comparative examples.
The present invention will be described more specifically by the following examples.
It is not limited. It should be noted that Examples and Comparative Examples
The composition of the cosmetic to be used is indicated by mass%. Examples 1 to 8 and Comparative Examples 1 to 7
The indicated hair rinse was produced. First, the sample preparation method and
And evaluation methods. (1) Preparation of sample Prepare oil phase by heating and dissolving oil components at 40-80 ° C
I do. Heat and dissolve other aqueous components in water at 25-80 ° C
Adjust the aqueous phase. Add the oil phase to the aqueous phase, stir with an azihomomixer,
Form an O / W emulsion. Stir with a paddle mixer, slowly cool to room temperature,
You. (2) Evaluation method About 30 women in their 20s and 30s (length of hair: show
G-semi-long-long), actual use evaluation was performed. Evaluation
The items are dry, dry and smooth.
Sensation, dryness after 24 hours of drying, comprehensive evaluation
Performed according to the following ratings. (Score) ◎; 25 or more out of 30 respondents Good: 15 to 24 out of 30 respondents △: 5 to 14 out of 30 respondents ×: Less than 5 out of 30 respondents [0040] [Table 1][0041] * 1; Esven E manufactured by Toyojun Yoko * 2: Esven W manufactured by Toyojun Yokosha * 3: Esven N-400 manufactured by TOYOJUN YOKO * 4: Clayton AF manufactured by Southern Clay Products * 5: Clayton SO manufactured by Southern Clay Products * 6: Kunipia F manufactured by Kunimine Industries * 7: Kunipia G manufactured by Kunimine Industries * 8: Wenger FW manufactured by TOYOJUN YOKO * 9: Smecton SA manufactured by Kunimine Industries Example 9 Hair condition having the following composition
The knives were manufactured according to a conventional method. 4-guanidinobutyl lauroamide acetic acid 0.5% Dimethyl distearyl ammonium bentonite * 10 0.3% Dimethyl silicone 1 million cst 1.0% Dimethyl silicone 100,000 cst 1.0% Dimethyl silicone 50cst 1.0% Glycine 1.0% Cetanol 0.5% Behenyl alcohol 1.8% Oleyl alcohol 0.3% Oleic acid 0.2% Isostearic acid 0.2% Piroctone olamine 0.3% Trimethylglycine 0.2% Arginine 0.3% Cysteine 0.3% Glyceryl monostearate 0.1% Sorbitan monolaurate 0.1% Methyl paraoxybenzoate 0.2% Propyl parahydroxybenzoate 0.05% Benzoic acid 0.1% Triisopropanolamine 0.1% Glycolic acid qs Acetic acid Sodium hydroxide appropriate amount Perfume B 0.6%Purified water balance   100.0% in total * 10 Esven W manufactured by Toyojun Yokosha (hereinafter the same) Properties pH 6.5 Particle size 0.5-5 μm Viscosity 4500cp / 25 ° C Example 10 Hair reed having the following composition
Were prepared according to a standard method. N-coconut fatty acid acyl-L-arginine ethyl 0.5% Dimethyl distearyl ammonium bentonite * 11 0.2% Dimethyl silicone 10 million cst 0.5% Dimethyl silicone 100,000 cst 1.0% Dimethyl silicone 30cst 1.5% Cetanol 4.0% Amino-modified silicone * 12 0.3% Behenyl alcohol 3.0% Stearyl alcohol 2.0% Isostearic acid 0.2% Glycerin 3.0% Propylene glycol 5.0% Glyceryl monostearate 0.1% Sorbitan monolaurate 0.1% Glycerin monolaurate 0.1% Methyl paraoxybenzoate 0.2% Propyl parahydroxybenzoate 0.05% Glycolic acid qs Acetic acid Sodium hydroxide appropriate amount Perfume C 0.5%Purified water balance   100.0% in total * 11 Clayton AF manufactured by Southern Clay Products (hereinafter the same) * 12 KF867S manufactured by Shin-Etsu Chemical Properties pH 6.4 Viscosity 130p / 25 ° C Particle size 1-5 μm Example 11 Hair essence having the following composition
Was produced according to a conventional method. 4-guanidinobutyl lauroamide acetic acid 0.1% 4-guanidinobutyl palmiteramide acetic acid 0.2% 4-guanidinobutyl myristamidoacetic acid 0.2% Dimethyl distearyl ammonium bentonite * 13 0.5% Polyoxyethylene-modified dimethylpolysiloxane * 14 2.0% Cetanol 0.5% Behenyl alcohol 0.2% Stearyl alcohol 0.7% Isostearic acid 0.2% Oleyl oleate 0.2% Glycine 0.8% Trimethylglycine 0.2% Arginine 0.3% Cysteine 0.3% Glyceryl monostearate 0.1% Sorbitan monolaurate 0.1% Polyoxyethylene (40) hardened castor oil 1.0% Methyl paraoxybenzoate 0.1% Propyl paraoxybenzoate 0.02% Benzoic acid 0.1% Acetic acid Sodium hydroxide appropriate amount Perfume D 0.3%Purified water balance   100.0% in total * 13 Clayton SO manufactured by Southern Clay Products * 14 Toray Dow Corning SH3775M Properties pH 5.8 Particle size 0.01-0.1 μm Viscosity 6500cp / 25 ° C Appearance Transparent gel Example 12 Hair conditioner having the following composition
Was prepared according to a conventional method. 4-guanidinobutyl lauroamide acetic acid 0.15% 4-guanidinobutyl palmiteramide acetic acid 0.2% 4-guanidinobutyl myristamidoacetic acid 0.2% Dimethyl distearyl ammonium bentonite * 10 0.1% Dimethyl silicone 1 million cst 1.0% Dimethyl silicone 100,000 cst 1.0% Dimethyl silicone 30cst 1.0% Stearyl alcohol 1.0% Cetanol 1.0% Behenyl alcohol 1.0% Polyoxyethylene (POE6) oleyl ether 0.1% Glyceryl monostearate 0.1% Sorbitan monolaurate 0.1% Methyl paraoxybenzoate 0.2% Propyl parahydroxybenzoate 0.05% Propylene glycol 8.0% Triisopropanolamine 0.1% Hydroxyethyl cellulose 0.5% Highly polymerized polyethylene glycol * 15 0.1% Glycolic acid qs Acetic acid Sodium hydroxide appropriate amount Perfume A 0.6%Purified water balance   100.0% in total * 15 Union Carbide POLYOX WSR N-60KCG Properties pH 6.5 Particle size 0.5 to 10 μm Viscosity 4500cp / 25 ° C Example 13 A hair gel having the following composition was
Manufactured according to the method. 4-guanidinobutyl palmiteramide acetic acid 0.2% 4-guanidinobutyl myristamidoacetic acid 0.2% Dimethyl distearyl ammonium bentonite * 10 0.5% Hexaglyceryl monoisostearate 5.0% Carboxyvinyl polymer 0.5% Quince seed gum 0.3% Methylsiloxane / polyoxyethylene copolymer 2.0% N-methacryloyloxyethyl N, N-dimethylaminoethyl-α-N-methyl Lecarboxybetaine / alkyl methacrylate copolymer 2.0% Polyoxyethylene hydrogenated castor oil 0.3% Dihydroxybenzophenone 0.1% Methyl paraben 0.1% Triethanolamine 0.5% Perfume B 0.2% Ethanol 5.0%Purified water balance   100.0% in total Properties pH 6.0 Viscosity 50p / 25 ° C Particle size 1-5 μm Example 14 A hair wax having the following composition was used.
It was manufactured according to the usual method. 4-guanidinobutyl lauroamide acetic acid 0.1% 4-guanidinobutyl palmiteramide acetic acid 0.2% 4-guanidinobutyl myristamidoacetic acid 0.2% Dimethyl distearyl ammonium bentonite * 11 0.3% Decaglyceryl diisostearate 5.0% Methylsiloxane / polyoxyethylene copolymer 2.0% Vaseline 3.0% Squalane 2.0% Candelilla wax 1.0% Polyoxyethylene octyl dodecyl ether 0.3% Polyoxypropylene diglyceryl ether 4.0% Dihydroxybenzophenone 0.1% Propyl paraben 0.1% Methyl paraben 0.3% Phenoxyethanol 0.5% Tetrasodium edetate 0.05% Triethanolamine 0.5% Perfume C 0.2%Purified water balance   100.0% in total Properties pH 6.4 Viscosity 130p / 25 ° C Particle size 1-10 μm Example 15 A hair cream having the following composition was used.
It was manufactured according to the usual method. 4-guanidinobutyl lauroamide acetic acid 0.5% Dimethyl distearyl ammonium bentonite * 10 0.1% Organopolysiloxane 1.0% Hexaglyceryl tristearate 3.0% Karaya gum 0.1% Methylsiloxane / polyoxyethylene copolymer 0.5% Methyl polysiloxane (100,000 cst) 5.0% Liquid paraffin 5.0% Paraffin wax 3.0% Polyoxyethylene hydrogenated castor oil 2.0% 3-methyl-1,3-butanediol 10.0% Dihydroxybenzophenone 0.1% Propyl paraben 0.1% Methyl paraben 0.3% Phenoxyethanol 0.5% Sorbitan palm oil fatty acid 2.0% Glycerin monostearate 1.0% Propylene glycol monostearate 2.0% Triethanolamine 0.5% Perfume D 0.2%Purified water balance   100.0% in total Properties pH 6.0 Viscosity 180p / 25 ° C Particle size 1-5 μm Example 16 Hair water having the following composition
Was produced according to a conventional method. 4-guanidinobutyl palmiteramide acetic acid 0.3% 4-guanidinobutyl myristeroamide acetic acid 0.3% Dimethyl distearyl ammonium bentonite * 11 0.2% Organopolysiloxane 1.0% Polyoxyethylene modified silicone 0.5% 3-methyl-1,3-butanediol 2.0% Stearyl trimethyl ammonium chloride 0.5% Methyl polysiloxane 3.0% 0.4% of polyoxyethylene lauryl ether Lauryl dimethylamine oxide 0.2% Sodium pyrrolidonecarboxylate 1.0% Methyl paraben 0.3% Sodium citrate 0.1% Hydroxymethoxybenzophenone sulfonic acid 0.1% Fragrance A 0.1% Ethanol 20.0%Purified water balance   100.0% in total Properties pH 6.8 Particle size 0.005 to 0.05 μm Hair cosmetics prepared in Examples 9 to 16 above
Are excellent effects that suppress unprecedented roughness
Has a non-sticky feeling
Can also be caused by sebum secretion and collapse of styling agents.
To reduce stickiness that occurs over time and maintain a dry feeling
The effect was excellent. The fragrances A to D in the above examples are
The perfume compositions A to D described below were used. [0059] [Table 2] [0060] [Table 3][0061] [Table 4][0062] [Table 5][0063] [Table 6][0064] [Table 7][0065] [Table 8][0066] [Table 9][0067] [Table 10][0068] [Table 11]

   ────────────────────────────────────────────────── ─── Continuation of front page    (72) Inventor Takashi Koyama             Rio, 1-3-7, Honjo, Sumida-ku, Tokyo             Incorporated F-term (reference) 4C083 AB032 AB441 AB442 AC012                       AC022 AC062 AC072 AC122                       AC182 AC212 AC232 AC242                       AC262 AC312 AC392 AC432                       AC442 AC472 AC482 AC522                       AC542 AC582 AC642 AC692                       AC741 AC742 AC792 AC852                       AD042 AD112 AD152 AD162                       AD282 BB25 CC32 CC33                       DD23 DD27 DD41 EE28

Claims (1)

Claims: 1. A hair cosmetic comprising the following components (A) and (B): (A) a guanidine derivative or a salt thereof having surface-active ability (B) an organically modified clay mineral