JP2003063014A - Method for manufacturing nozzle plate for ink jet printer - Google Patents

Method for manufacturing nozzle plate for ink jet printer

Info

Publication number
JP2003063014A
JP2003063014A JP2001254183A JP2001254183A JP2003063014A JP 2003063014 A JP2003063014 A JP 2003063014A JP 2001254183 A JP2001254183 A JP 2001254183A JP 2001254183 A JP2001254183 A JP 2001254183A JP 2003063014 A JP2003063014 A JP 2003063014A
Authority
JP
Japan
Prior art keywords
ink
nozzle
nozzle plate
jet printer
ink jet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001254183A
Other languages
Japanese (ja)
Other versions
JP4374811B2 (en
Inventor
Yoshinari Suzuki
能成 鈴木
Makoto Kurosawa
誠 黒沢
Osamu Machida
治 町田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koki Holdings Co Ltd
Original Assignee
Hitachi Koki Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Koki Co Ltd filed Critical Hitachi Koki Co Ltd
Priority to JP2001254183A priority Critical patent/JP4374811B2/en
Publication of JP2003063014A publication Critical patent/JP2003063014A/en
Application granted granted Critical
Publication of JP4374811B2 publication Critical patent/JP4374811B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Particle Formation And Scattering Control In Inkjet Printers (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a nozzle plate which generates no ejection bending, nor ejection failure. SOLUTION: After an ink-repellent film is formed over the entire nozzle plate, a masking treatment by a photosensitive resin is applied up to a prescribed depth of a nozzle surface and the inside of the nozzle and an ink-affinity treatment is applied to the channel by plasma radiation.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、インクジェットプ
リンタ用ノズルプレートの製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a nozzle plate for an ink jet printer.

【0002】[0002]

【従来の技術】従来技術のインクジェットヘッドにおい
ては、ノズルよりインク滴を吐出させる際、インクの溢
れ出しやインクミストが付着する等ノズル表面の濡れや
汚れが発生し、それらに吐出するインク滴が影響を受け
飛翔方向曲がりや、最悪の場合不吐出ノズルが発生し、
印刷品質が低下するという問題を抱えている。
2. Description of the Related Art In a conventional ink jet head, when ink droplets are ejected from a nozzle, wetting or dirt of the nozzle surface occurs such as ink overflow or ink mist adhering to the ink droplets ejected. It is affected by bending in the flight direction, and in the worst case, a non-ejection nozzle occurs,
There is a problem that print quality is degraded.

【0003】ノズルプレートは、ガラス、金属、樹脂等
の材料で構成されており、それらの部材に撥インク処理
を施し、ノズルプレート表面の濡れを防止することが一
般的である。代表例として特開平9-267478号公報に記載
されている、ノズル表面に撥インク膜を形成し、撥イン
ク膜の表面に撥インク膜の親インク化を防ぐためゴム状
の弾性体を貼付し、活性ガス雰囲気へさらして流路を親
インク化する方法などが提案されている。
The nozzle plate is made of a material such as glass, metal or resin, and it is common to apply an ink repellent treatment to these members to prevent the nozzle plate surface from getting wet. As a typical example, in JP-A-9-267478, an ink repellent film is formed on the nozzle surface, and a rubber-like elastic body is attached to the surface of the ink repellent film to prevent the ink repellent film from becoming ink-philic. , A method of exposing a flow path to an ink by exposing it to an active gas atmosphere has been proposed.

【0004】しかし上記方法では、ノズルプレート表面
にのみ撥インク処理が施されるため、インクメニスカス
がほぼノズルプレート表面に形成される。撥インク処理
が施されていない状態と比較すればノズルプレート表面
の濡れは改善されるが、ノズルプレート表面にメニスカ
スが形成されていることで、紙紛や異物が付着しやすく
汚れやすい。
However, in the above method, since the ink repellent treatment is applied only to the nozzle plate surface, the ink meniscus is formed almost on the nozzle plate surface. Although the wetting of the nozzle plate surface is improved as compared with the state in which the ink repellent treatment is not applied, the formation of the meniscus on the nozzle plate surface makes it easier for paper dust or foreign matter to adhere and stain easily.

【0005】このような問題に対して、インクが吐出す
るノズル表面及びある所定の範囲でノズル内面に撥イン
ク膜を形成することで、インクがノズル表面に溢れ出す
ことを防止し、ノズル内のメニスカス形成位置を安定さ
せインクの飛翔方向の曲がりを防止することが可能であ
る。
To solve such a problem, by forming an ink repellent film on the nozzle surface from which ink is ejected and on the inner surface of the nozzle in a predetermined range, the ink is prevented from overflowing to the nozzle surface, and the inside of the nozzle is prevented. It is possible to stabilize the meniscus formation position and prevent the ink from bending in the flight direction.

【0006】[0006]

【発明が解決しようとする課題】本発明の課題は、イン
クジェットプリンタ用ノズルプレートにおいて、ノズル
プレート表面のインクによる汚れを防止し、インク直進
飛行性向上及びノズル内のインクの挙動を安定化し、高
印字品質の印字ができるノズルプレートを提供すること
にある。また、本発明においては、簡便なノズルプレー
トを製造する方法を提供することを課題とする。
DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention An object of the present invention is to prevent ink stains on the surface of a nozzle plate in an ink jet printer nozzle plate, improve straight flight performance of ink, and stabilize the behavior of ink in the nozzle. An object of the present invention is to provide a nozzle plate capable of printing with print quality. Another object of the present invention is to provide a simple method for manufacturing a nozzle plate.

【0007】[0007]

【課題を解決するための手段】本発明は、このような課
題を達成するためインクを吐出するノズル表面及びノズ
ル内部が所定の深さまで撥インク処理され、それ以外の
インク流路が親インク処理されたインクジェットプリン
タ用ノズルプレートの製造方法において、ノズルプレー
ト全面に撥インク処理した後、ノズル表面及びノズル内
部の所定の深さまで感光性樹脂によりマスク処理を施
し、プラズマ照射により流路の親インク処理を行う。
According to the present invention, in order to achieve the above object, the nozzle surface for ejecting ink and the inside of the nozzle are subjected to an ink repellent treatment to a predetermined depth, and the other ink flow paths are treated with an ink-philic treatment. In the method for manufacturing a nozzle plate for an inkjet printer described above, after ink-repellent treatment is applied to the entire surface of the nozzle plate, mask treatment is performed with a photosensitive resin to a predetermined depth on the nozzle surface and inside the nozzle, and plasma-irradiated ink-treatment of the flow path is performed. I do.

【0008】[0008]

【発明の実施の形態】以下、本発明を説明するが、本発
明はこれによって限定されるものではない。 (実施例1)図1は、本発明の一例となるインクジェッ
トプリンタ用ノズルプレートの製造方法について説明し
たものである。
BEST MODE FOR CARRYING OUT THE INVENTION The present invention is described below, but the present invention is not limited thereto. (Embodiment 1) FIG. 1 illustrates a method for manufacturing a nozzle plate for an inkjet printer, which is an example of the present invention.

【0009】図1の(a)において、ノズルプレート1
はステンレスで形成され、ノズル部は、プレスによって
裏面に開いた漏斗状に形成される。本例では、プレート
厚80μm、インク吐出側穴径40μm、インク供給側穴
径80μm、材質SUS304のものを用いた。
In FIG. 1A, the nozzle plate 1
Is made of stainless steel, and the nozzle portion is formed in a funnel shape opened on the back surface by pressing. In this example, a plate having a thickness of 80 μm, an ink discharge side hole diameter of 40 μm, an ink supply side hole diameter of 80 μm, and a material of SUS304 was used.

【0010】なお、本例では、ノズルプレート1の材質
をステンレスとしたが、その他の金属、セラミック、シ
リコン、ガラス、プラスチック樹脂などで形成しても問
題はない。また、ノズル部も電鋳、機械加工、ドライエ
ッチングなどの方法を用いても何ら問題はない。
Although the nozzle plate 1 is made of stainless steel in this example, it may be formed of other metal, ceramic, silicon, glass, plastic resin, or the like. Further, there is no problem even if the nozzle portion is formed by using a method such as electroforming, machining, dry etching or the like.

【0011】次に、(b)でノズルプレート1の全面に
撥インク膜2を形成する。例としてフッ素系高分子を用
いて撥インク膜を形成した。また、ノズルプレート1の
全面に撥インク膜2を形成するとしたが、ノズルプレー
ト表面とノズル内部に撥インク膜が形成されていればノ
ズルプレート裏面に撥インク膜の形成が無くとも何ら問
題はない。
Next, in (b), the ink repellent film 2 is formed on the entire surface of the nozzle plate 1. As an example, an ink repellent film was formed using a fluorine-based polymer. Although the ink repellent film 2 is formed on the entire surface of the nozzle plate 1, there is no problem even if the ink repellent film is not formed on the back surface of the nozzle plate as long as the ink repellent film is formed on the nozzle plate surface and inside the nozzle. .

【0012】マスクは、スピンコーターを用い、感光性
樹脂3(例えば東京応化(株)製ネガ型フォトレジスト
OMR83)を基板4(例えばシリコンウェハ)にコー
トし、ポストベークしたものを使用した。なお、本例で
は、ネガ型フォトレジストをコートする基板をシリコン
ウェハとしたが、金属、セラミック、ガラス、プラスチ
ック樹脂など平行度が高く表面が平滑で且つ高硬度な部
材であれば何ら問題ない。
As the mask, a substrate was coated with a photosensitive resin 3 (for example, a negative photoresist OMR83 manufactured by Tokyo Ohka Kogyo Co., Ltd.) on a substrate 4 (for example, a silicon wafer) using a spin coater and post-baked. In this example, the substrate coated with the negative photoresist is a silicon wafer, but there is no problem as long as it is a member having a high degree of parallelism, a smooth surface and a high hardness, such as metal, ceramic, glass or plastic resin.

【0013】続いて、ノズルプレート1と基板4上にス
ピンコートした感光性樹脂3を温度90℃、圧力3kg/c
m2、時間3分間の条件でプレスし、(c)のようにノズ
ル内へ入り込ませ、インク供給側から紫外線を12mW/c
m2照射しプラズマに十分耐えうるマスクを形成した。
Then, the photosensitive resin 3 spin-coated on the nozzle plate 1 and the substrate 4 is heated at a temperature of 90 ° C. and a pressure of 3 kg / c.
Press under the condition of m 2 for 3 minutes, let it enter the nozzle as shown in (c), and apply ultraviolet rays of 12 mW / c from the ink supply side.
A mask capable of sufficiently withstanding the plasma was formed by irradiation with m 2 .

【0014】更に、ベルジャー方式プラズマ発生装置を
用い酸素プラズマ雰囲気中にさらし、(d)のようにマ
スクされた以外の撥インク膜を除去する。本例では、真
空度0.1Torr(酸素導入後0.5Torr)高周波電源出力300W
処理時間3分の条件で行った。本例ではプラズマとなる
ガスに酸素を用いたが、窒素、アルゴン等でも撥インク
膜が除去可能なガスであれば何ら問題はない。
Further, the ink repellent film other than the masked layer as shown in (d) is removed by exposing it to an oxygen plasma atmosphere using a bell jar type plasma generator. In this example, the degree of vacuum is 0.1 Torr (0.5 Torr after oxygen is introduced) High frequency power output 300W
The processing time was 3 minutes. In this example, oxygen is used as the gas that becomes plasma, but there is no problem as long as it is a gas that can remove the ink repellent film, such as nitrogen or argon.

【0015】その後、マスクを除去し(e)のノズルプ
レートを得た。本例では、100℃に加熱したOMR8
3用剥離液502A中に(d)で得られたノズルプレー
ト一式を浸漬し超音波洗浄機で15分間処理を行った。
After that, the mask was removed to obtain a nozzle plate (e). In this example, OMR8 heated to 100 ° C
The set of nozzle plates obtained in (d) was immersed in the stripping solution 502A for 3 and treated with an ultrasonic cleaner for 15 minutes.

【0016】上記方法で得られたノズルプレート表面の
純水に対する接触角は115〜120°、流路となる裏
面の純水に対する接触角は5〜10°となり、ノズルプ
レート表面は十分な撥インク性を有し、裏面の流路は十
分な親インク性を有していた。また、非接触式3次元測
定機を用いノズルの流路側からインクを充填しメニスカ
スの位置を測定し、ノズルプレート表面から2±0.5
μm入り込んで形成したことを確認した。 (実施例2)図2は、実施例1でスピンコートしたネガ
型フォトレジストOMR83に代えて、ドライフィルム
レジストを用いた本発明の他の例となるインクジェット
用ノズルプレートの製造方法について説明したものであ
る。
The contact angle of pure water on the surface of the nozzle plate obtained by the above method is 115 to 120 °, and the contact angle of pure water on the rear surface to be the flow path is 5 to 10 °, and the surface of the nozzle plate is sufficiently ink repellent. And the flow path on the back surface had sufficient ink affinity. In addition, using a non-contact type three-dimensional measuring machine, ink is filled from the flow path side of the nozzle and the position of the meniscus is measured.
It was confirmed that the film was formed by entering μm. (Embodiment 2) FIG. 2 illustrates a method for manufacturing an inkjet nozzle plate, which is another example of the present invention, using a dry film resist in place of the negative photoresist OMR83 spin-coated in Embodiment 1. Is.

【0017】図2の(g)撥インク処理工程までは、実
施例1(b)と同様に行った。
The procedure up to the ink repellent treatment step (g) in FIG. 2 was performed in the same manner as in Example 1 (b).

【0018】マスクは、感光性樹脂フィルム5、一例と
してDupont社製ドライフィルムレジストFX130を1
10℃、4kg/cm2の条件でラミネートし(h)のように
ノズル内へ入り込ませ、該ドライフィルムレジストに3
20〜400nmの長波長紫外線を照射し、プラズマに十
分耐えうるマスクを形成した。
The mask is a photosensitive resin film 5, for example, a dry film resist FX130 manufactured by Dupont Co., Ltd.
Laminate it under the conditions of 10 ° C and 4 kg / cm 2 and let it enter the nozzle as shown in (h), and apply 3 to the dry film resist.
Irradiation with long wavelength ultraviolet rays of 20 to 400 nm was performed to form a mask sufficiently resistant to plasma.

【0019】それを(i)の工程にて、実施例1同様、
酸素プラズマ処理を行った。
In the step (i), as in Example 1,
Oxygen plasma treatment was performed.

【0020】その後、マスクを除去し、(j)に示すノ
ズルプレートを得た。本例では、50℃に加熱した濃度
5%の水酸化ナトリウム水溶液中に(i)で得られたノ
ズルプレート一式を浸漬し超音波洗浄機で15分間処理
を行った。
After that, the mask was removed to obtain a nozzle plate shown in (j). In this example, the set of nozzle plates obtained in (i) was immersed in an aqueous solution of sodium hydroxide having a concentration of 5% and heated at 50 ° C., and treated with an ultrasonic cleaner for 15 minutes.

【0021】上記方法で得られたノズルプレート表面の
純水に対する接触角は115〜120°、流路となる裏
面の純水に対する接触角は5〜10°となり、ノズルプ
レート表面は十分な撥インク性を有し、裏面の流路は十
分な親インク性を有していた。また、非接触式3次元測
定機を用いノズルの流路側からインクを充填しメニスカ
スの位置を測定し、ノズルプレート表面から5±0.5
μm入り込んで形成したことを確認した。
The contact angle of pure water on the surface of the nozzle plate obtained by the above method is 115 to 120 °, and the contact angle of pure water on the back surface to be the flow path is 5 to 10 °, and the surface of the nozzle plate is sufficiently ink repellent. And the flow path on the back surface had sufficient ink affinity. In addition, using a non-contact type three-dimensional measuring machine, ink is filled from the flow path side of the nozzle and the position of the meniscus is measured, and it is 5 ± 0.5 from the nozzle plate surface.
It was confirmed that the film was formed by entering μm.

【0022】表1は、本発明の実施例1、2で得られた
ノズルプレートをピエゾ駆動方式のオンデマンド型イン
クジェットプリントヘッドに装着して、インク吐出側穴
径が40μmのノズル100個から20kHzの駆動周
波数で30分連続吐出を行った時に発生した不吐出や曲
がりなどの吐出不良の発生回数を従来方法の処理なし品
と比較したものである。
Table 1 shows that the nozzle plates obtained in Examples 1 and 2 of the present invention were mounted on a piezo drive type on-demand type ink jet print head, and 20 kHz from 100 nozzles having an ink discharge side hole diameter of 40 μm. This is a comparison of the number of occurrences of ejection failure such as non-ejection and bending that occurred when continuous ejection was performed for 30 minutes at the driving frequency of the conventional method with no treatment.

【0023】[0023]

【表1】 [Table 1]

【0024】この結果より、本発明の撥インク膜形成を
施したノズルプレートは、不吐出や曲がりなどの吐出不
良が発生し難くいことが分かった。
From these results, it was found that the nozzle plate provided with the ink repellent film of the present invention is less likely to cause ejection failure such as non-ejection or bending.

【0025】この様に感光性樹脂は、被覆時に適度にノ
ズル内に入り込み確実に入り込み量を制御可能であり、
その後、紫外線照射によって硬化しプラズマに耐え得る
マスク材となりバラツキの少ない安定した境界を得るこ
とが出来る。
As described above, the photosensitive resin can appropriately enter into the nozzle at the time of coating and reliably control the entering amount.
After that, it becomes a mask material that is hardened by ultraviolet irradiation and can withstand plasma, and stable boundaries with less variation can be obtained.

【0026】[0026]

【発明の効果】本発明によれば、インクを吐出するノズ
ル表面及びノズル内部の所定の深さまで撥インク膜を感
光性樹脂によって保護し、それ以外のインク流路部をプ
ラズマによって親インク処理することにより、ノズルプ
レート表面はインクで汚れることなく、吐出するインク
は直進飛行性に優れノズル内のインクの挙動が安定し、
信頼性が高く高印字品質の印字ができるノズルプレート
を形成することができる。
According to the present invention, the ink repellent film is protected by the photosensitive resin up to a predetermined depth inside the nozzle for ejecting ink and the inside of the nozzle, and the other ink flow passages are treated with ink by plasma. As a result, the surface of the nozzle plate is not contaminated with ink, the ejected ink has excellent straight flight performance, and the behavior of the ink in the nozzle is stable,
It is possible to form a nozzle plate having high reliability and capable of printing with high printing quality.

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明の一例となるノズルプレートの製造工
程を示す図。
FIG. 1 is a diagram showing a manufacturing process of a nozzle plate as an example of the present invention.

【図2】 本発明の他の例となるノズルプレートの製造
工程を示す図。
FIG. 2 is a diagram showing a manufacturing process of a nozzle plate which is another example of the present invention.

【符号の説明】[Explanation of symbols]

1はオリフィスプレート、2は撥インク膜、3は感光性
樹脂、4は基板、5は感光性樹脂フィルムである。
1 is an orifice plate, 2 is an ink repellent film, 3 is a photosensitive resin, 4 is a substrate, and 5 is a photosensitive resin film.

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 2C057 AF43 AP13 AP43 AP57 AP59 AP60 AQ06    ─────────────────────────────────────────────────── ─── Continued front page    F-term (reference) 2C057 AF43 AP13 AP43 AP57 AP59                       AP60 AQ06

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】インクを吐出するノズル表面及びノズル内
部が所定の深さまで撥インク処理され、それ以外のイン
ク流路が親インク処理されたインクジェットプリンタ用
ノズルプレートの製造方法において、 ノズルプレート全面に撥インク処理した後、ノズル表面
及びノズル内部の所定の深さまで感光性樹脂によりマス
ク処理を施し、プラズマ照射により流路の親インク処理
を行うことを特徴とするインクジェットプリンタ用ノズ
ルプレートの製造方法。
1. A method for manufacturing a nozzle plate for an inkjet printer, wherein the nozzle surface for ejecting ink and the inside of the nozzle are subjected to an ink repellent treatment to a predetermined depth, and the other ink flow paths are treated to be ink-philic. A method for manufacturing a nozzle plate for an inkjet printer, comprising performing a mask treatment with a photosensitive resin up to a predetermined depth on the nozzle surface and inside the nozzle after the ink repellent treatment, and performing an ink-affinity treatment of the flow path by plasma irradiation.
【請求項2】前記感光性樹脂の厚さが100μm以下で
あることを特徴とする請求項1記載のインクジェットプ
リンタ用ノズルプレートの製造方法。
2. The method of manufacturing a nozzle plate for an ink jet printer according to claim 1, wherein the thickness of the photosensitive resin is 100 μm or less.
【請求項3】請求項1または2記載の製造方法で得られ
たインクジェットプリンタ用ノズルプレートを用いたこ
とを特徴とするインクジェットプリンタ用ヘッド。
3. A head for an ink jet printer, characterized by using a nozzle plate for an ink jet printer obtained by the manufacturing method according to claim 1.
【請求項4】請求項3記載のインクジェットプリンタ用
ヘッドを搭載したインクジェットプリンタ。
4. An ink jet printer equipped with the ink jet printer head according to claim 3.
JP2001254183A 2001-08-24 2001-08-24 Method for manufacturing nozzle plate for inkjet printer Expired - Lifetime JP4374811B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001254183A JP4374811B2 (en) 2001-08-24 2001-08-24 Method for manufacturing nozzle plate for inkjet printer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001254183A JP4374811B2 (en) 2001-08-24 2001-08-24 Method for manufacturing nozzle plate for inkjet printer

Publications (2)

Publication Number Publication Date
JP2003063014A true JP2003063014A (en) 2003-03-05
JP4374811B2 JP4374811B2 (en) 2009-12-02

Family

ID=19082377

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JP2006175604A (en) * 2004-12-20 2006-07-06 Seiko Epson Corp Film formation method, liquid feeding head and liquid feeder
US7232206B2 (en) 2003-05-09 2007-06-19 Ricoh Printing Systems, Ltd. Ink-jet head, ink-jet printer using the same, and process for producing ink-jet head
JP2007261070A (en) * 2006-03-28 2007-10-11 Seiko Epson Corp Manufacturing method of nozzle forming substrate and nozzle forming substrate
EP1997636A1 (en) 2007-05-31 2008-12-03 Mimaki Engineering Co., Ltd. Nozzle plate for inkjet head, method for manufacturing the same, and treatment liquid for inkjet head
EP2129526A1 (en) * 2007-03-12 2009-12-09 Silverbrook Research Pty. Ltd Metal film protection during printhead fabrication with minimum number of mems processing steps
US7641943B2 (en) 2004-12-24 2010-01-05 Seiko Epson Corporation Coating method, liquid supplying head and liquid supplying apparatus
US8012363B2 (en) 2007-11-29 2011-09-06 Silverbrook Research Pty Ltd Metal film protection during printhead fabrication with minimum number of MEMS processing steps
JP2011183646A (en) * 2010-03-08 2011-09-22 Fujifilm Corp Method for manufacturing inkjet head, and inkjet head
CN103085481A (en) * 2011-11-08 2013-05-08 富士胶片株式会社 Method Of Manufacturing Liquid Droplet Ejection Head
KR101912606B1 (en) * 2016-10-18 2018-10-29 세메스 주식회사 Nozzle Plate for Processing Droplet Formation and Coating Method of Nozzle Plate for Processing Droplet Formation

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US7232206B2 (en) 2003-05-09 2007-06-19 Ricoh Printing Systems, Ltd. Ink-jet head, ink-jet printer using the same, and process for producing ink-jet head
JP4595527B2 (en) * 2004-12-20 2010-12-08 セイコーエプソン株式会社 Film forming method, liquid supply head, and liquid supply apparatus
JP2006175604A (en) * 2004-12-20 2006-07-06 Seiko Epson Corp Film formation method, liquid feeding head and liquid feeder
US7641943B2 (en) 2004-12-24 2010-01-05 Seiko Epson Corporation Coating method, liquid supplying head and liquid supplying apparatus
JP2007261070A (en) * 2006-03-28 2007-10-11 Seiko Epson Corp Manufacturing method of nozzle forming substrate and nozzle forming substrate
EP2129526A1 (en) * 2007-03-12 2009-12-09 Silverbrook Research Pty. Ltd Metal film protection during printhead fabrication with minimum number of mems processing steps
EP2129526A4 (en) * 2007-03-12 2010-04-28 Silverbrook Res Pty Ltd Metal film protection during printhead fabrication with minimum number of mems processing steps
US8550596B2 (en) 2007-05-31 2013-10-08 Mimaki Engineering Co., Ltd. Nozzle plate for inkjet head, method for manufacturing the same, and treatment liquid for inkjet head
EP1997636A1 (en) 2007-05-31 2008-12-03 Mimaki Engineering Co., Ltd. Nozzle plate for inkjet head, method for manufacturing the same, and treatment liquid for inkjet head
US8012363B2 (en) 2007-11-29 2011-09-06 Silverbrook Research Pty Ltd Metal film protection during printhead fabrication with minimum number of MEMS processing steps
US8491803B2 (en) 2007-11-29 2013-07-23 Zamtec Ltd Method of hydrophobizing and patterning frontside surface of integrated circuit
JP2011183646A (en) * 2010-03-08 2011-09-22 Fujifilm Corp Method for manufacturing inkjet head, and inkjet head
CN103085481A (en) * 2011-11-08 2013-05-08 富士胶片株式会社 Method Of Manufacturing Liquid Droplet Ejection Head
JP2013099880A (en) * 2011-11-08 2013-05-23 Fujifilm Corp Method of manufacturing liquid droplet ejection head
US9090064B2 (en) 2011-11-08 2015-07-28 Fujifilm Corporation Method of manufacturing liquid droplet ejection head
CN103085481B (en) * 2011-11-08 2016-06-08 富士胶片株式会社 The manufacture method of droplet jetting head
KR101912606B1 (en) * 2016-10-18 2018-10-29 세메스 주식회사 Nozzle Plate for Processing Droplet Formation and Coating Method of Nozzle Plate for Processing Droplet Formation

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