JP2003055604A - Light-screening titanic acid chelate agent, oil-resistant and solvent-resistant plastic container, and other sundry goods - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a glass coating capable of making it easier for stains to be removed from glass surfaces and also capable of cutting off UV rays, and a container for the coating, highly oil-resistant and solvent-resistant, light in weight and low in price. SOLUTION: A coating composition, wherein a spiropyran dye solution is mixed with one or more solutions selected from the group consisting of glycolic chelates of titanic acid, silicic acid, zirconic acid, and stannic acid, is applied to and dried on glass, car bodies, hulls, railway vehicles, or buildings for the formation of metallic chelate coatings. To obtain an oil-resistant and solvent- resistant sprayer container for such a coating, a gel liquid, wherein a mixture of a sodium tungstate or sodium molybdate surfactant, aluminum oxide, calcium hydroxide, magnesium oxide, or silica rock powder is mixed with a sodium silicate or sodium aluminate water solution, is applied to the internal walls of the sprayer tank, and the tank is rotated while it is dried in blown air for the formation of a multilayer coating.

Description

DETAILED DESCRIPTION OF THE INVENTION [Industrial application] Glass windows have started in ordinary houses and have become very large.
Type buildings, automobiles, ships, trains, greenhouses and high-speed
Wide side wall of motorway, airplane and other uses
However, in urban areas, dirt is particularly noticeable due to dust and
Have to be cleaned. Useless cleaning costs for that
This can be reduced once a year to maintain cleanliness.
If you can hold it, you will have more
Can be effective. And if the glass window is UV cut, purple
Long-term storage of articles without sunburn due to outside lines
Quality is maintained sufficiently. In addition to the glass window,
Painted on vehicle bodies, airplane fuselage and train surfaces
If a V-cut titanate chelate is applied,
Prevent aging caused by aging and improve paint life, and improve the quality of automobile bodies and trains
Body paint no longer requires the use of wax
You. And the thing which painted this on the poster paper surface is
It has the effect of not blurring the image, and is used for television, radio and other electric
If you wipe the dust that adheres to the instrument lightly, the first light
It can maintain a lot of transparency. Also, this UV cut
Titanic acid, silicon acid, zirconic acid, stannic acid, gray
The plastic container that holds the coal chelate is an organic solvent
Contains, so the solvent evaporates from the container and there is no storage
Only porcelain or metal containers were durable and storable
To a gelling solution of sodium silicate or sodium aluminate.
Sodium ungstenate or sodium molybdate
Cium, alumina oxide, aluminum powder foam, silica stone
Powder, diatomaceous earth powder, surfactant, boric acid, borosilicate, fluorinated silica
Mix the salt, sulfur, water, etc. and masticate the mucus with plastic.
Apply to the inside of the bottle and dry it while rotating.
And apply a double container or plastic sol
By putting the above organic solvent into a cured triple container,
Oil and organic solvents
The use of plastics containers with enhanced
It is possible to make a lightweight container with high light resistance and
It is also used for tile walls and building materials other than
Utilizing the fire resistance of composite veneer and acid rain
Used for concrete processing to prevent condensation and condensation.
UV-cut titanate is also used in textile processing
Aging solution prevents aging and cleans buildings
And turn plastic into artificial leather
It can do things, and its use is wide. 2. Description of the Related Art To form a titanate film on a window glass
Is a solution prepared by dissolving titanium tetrachloride in water
Sprayed with pertitanic acid solution
Window glass with dried titanate film attached
However, one is that when the film thickness is thick, a yellow reflective film is formed, sometimes
White titanium film is formed and light transmittance is getting worse
Was. And to make a UV cut on the window glass surface,
Compression glue on one side of plastic film mixed with cut
Has been applied in advance. And
For liquid type, UV cut dye is pre-added to the plastic sol.
The mixture is used as a coating liquid and bottled.
Affix the former UV cut film to the window glass
Is difficult to attach to unskilled people, causing a lot of loss
Was. In addition, the liquid type like the latter has four corners of the window glass.
The surface was stained and the finishing was difficult. UV cut
Generally dissolves UV cutting agent in plastic sol
It was common sense to apply
The film thickness is not constant and uniform unless you are a person with a high level of skill
Painting was difficult. And on the painted surface of the car body
It is common to apply wax oil to protect the painted surface.
When you drive both in the city and outdoors, dust appears.
It adhered to the surface and the glossy surface was lost, forcing the car to be washed. So
Here, the aqueous solution of titanic acid must be further applied to the surface of the wax.
Was carried out, but white spots were formed and spots were conspicuous
There was a visible defect. And many plastic containers
When stored with an organic solvent, it is poorly durable and deforms
Or dissolves, or a transparent object turns white,
There were drawbacks such as leakage of the medium. And receive the sunlight
Then, there was a drawback that it was easy to age. [Problem to be solved by the present invention]
Transparent glass for cars, trains, window glasses for planes and ships,
Eyeglass glass, binocular glass, measuring glass, plastic
When forming a titanate film on a transparent plate, a white film is formed
The thickness of the transparent titanate film, which did not easily disappear,
When it becomes thick, it emits light, and when it is projected on glass, it is reflected.
The light makes it difficult to confirm the position of the other party. And
UV cut is 50-60% for thin titanate film
Therefore, in order to raise this to 90% or more, it is for UV cut
UV cut dye on transparent plastic film as
And a film pre-filled with pigments was pasted with pressure glue
Because it takes time and effort, the pasting often fails.
A solution by the method is desired and its UV
Durability to put cut titanate chelate liquid, oil resistance, resistance
Solvent and corrosion resistant plastic containers need to be improved.
Was. [MEANS FOR SOLVING THE PROBLEMS] Alcohol is added to titanium tetrachloride.
And titanic acid alcohol
Make a chelating solution of glycol glycol titanate and apply this
Injection of Lucari's ammonia gas or sodium percarbonate
-Make a titanate chelate solution with powder added as a neutralizing agent.
You. Separately spiropyran, for example, 1,3,3-trimethyl
Indolino-6-nitrobenzospiropyran in acetone
Or MEK and mixed with the titanate chelate solution
Make a mixed solution and spray it on the surface of the washed glass
Or, apply and dry, then polish with a piece of cloth. UV light
The mirror surface of the rearview mirror is formed
, A clear image is obtained. And this
Apply it to the body of the car and wipe it dry with a piece of cloth.
A titanate film is formed. This can be used for automobile window glass
Apply to machine window glass, train window glass and building window glass
When it does, dust becomes hard to adhere, and it takes one year
Secure a glass surface or a shiny painted surface that shines near
It becomes possible. And, if necessary,
If you apply twice later, you can keep the UV cut constant
I can do it. UV-cut titanic acid, silicon acid, zircon
Plastic containers that spray nitric acid and stannic acid chelates
Solvent resistant and oil resistant, to make it resistant to deformation and discoloration
To sodium silicate or sodium aluminate to tungstic acid
Soda, sodium molybdate, sodium sulfate, boric acid, borosilicate
Acid, fluosilicate and lime aluminum powder, magnesium oxide
Viscous liquid containing silica, powdered silica, slaked lime, and surfactant.
Apply to the inside of the styks container and dry to form a film
Developed and used multi-layer plastic containers to further prevent aging
A container coated with paint was used. This is a plus
Fire resistance of plastic molded products as well as Chicks
Discoloration due to water resistance, oil resistance, solvent resistance, deformability and corrosion resistance
To help improve flammable plastic building materials and plywood
To improve the aging resistance of applied plastics
Prevent by applying UV-cut titanate chelate liquid
Improves durability and protects concrete from acid rain
It can also be used to improve condensation prevention. [Function] First, titanic acid, zirconic acid and silicon
Make an alcohol chelate solution of acid and stannic acid. Next, Spiropi
Make a run solution, mix both and UV-cut titanic acid
Make a chelating solution. The molecular structure of the titanate chelate is
It is as follows. The spiropyran acetone side is on the left side. This is Nikko
If you hit it, it will change to the right. That is, it cleaves and changes to purple. And partly titanic acid
Rycol chelate titanium oxygen and spiropyran
Join lightly. 10 g of solution B was added thereto and mixed by stirring.
After that, this is the UV-cut titanic acid glycol chelate
Spray as a liquid onto glass or building surfaces to dry. Iron piece
Melts light reflected from the titanate chelate film
And increase the UV cut. This titanate chelate solution
Zirconate chelate, silicon acid chelate and stannate
Similarly, in the case of the rate liquid, the mixing of the spiropyran liquid
UV cutting becomes possible. 1,3 of this spiropyran
3-trimethylindolino-6'-nitrobenzospiro
Pyran retains its original structure in the dark and is colorless but solid
When irradiated with ultraviolet light in the dissolved state (organic solvent),
Ring opens and changes to merocyanine dye structure (B)
It becomes color. 7'-nitro is orange against this purple color
Color, 6'8'-dipromo is blue, 5'-nitro8'-
Toxi is green and 6'-nitro-8'-promolo is dark green.
Become This spiropyran is exposed to ultraviolet light and sunlight
When exposed to visible light, accelerates the decolorization reaction
You. [Fig.18] shows the absorption spectrum in (A) ⇔ (B).
Shows the change in KEK solution of cyanoethyl cellulose
Although dissolved in liquid and coated, the absorption spectrum of (B) is
The color shown in (B) and its life as shown in FIG.
In terms of molecular structure, 6'-nitro is purple
7'-nitro is orange, 6 ', 8 dipromo is blue and 5'-
Nitro-8'-methoxy is green, 6'-nitro-8'-butyl
Lomo changes to dark green. Spiropyran in the side chain
The effect is that images generated by light can be kept for a long time.
Fruit, and when used as a crosslinking component,
Effect occurs. Organizing to show photochromism
As compounds, thioinchigo and pian by photoisomerization
By the same photoion cleavage reaction as spiropyrans
O-nitrobenzyl derivative or trans cis isomerization
The combination of hydrogen transfer results in a discolorable discoloration.
The mercury salt of dithizone is solid and exhibits photochromism,
Diphenylthiom studied at American Cyanaside
Ocarbazone H ₈ Salt discolored by light as shown in the following structure
Then, the deep yellow darkens. Mix this with plastic
The combined lens has been put into practical use as a sunglass lens.
You. The spiropyran solution also contains methylene briu and other diazo
Mix and color the dye dissolved in alcoholic water
If you use them, you can also cut by color. or,
Titanium emits electrons when sunlight hits the surface of the titanate film
Which, in the presence of spiropyran,
Activated by sunlight and cleaved to become oxygen (-)
When the color of N becomes (+), electrons are exchanged,
Its surface changes to (+). Also, SnCl ₄ The chloride
Spray 10% of thymon on glass surface
When heating at 0 ° C to make a semiconductor film, a spiro
When spraying pyran solution, expose the semiconductor film to sunlight
A semiconductor film with a (-) surface on the surface is formed.
This opens up new applications electrically. Now, U on glass
Spiropyran is applied as a V-cut
Plastic ssol is used, but sun-sensitive active
Because the refractive index is different from glass when forming a film
In particular, it is difficult to form a transparent film.
Almost no transparency when used in combination with a tannic acid chelate
It was difficult to get. Apply this titanate chelate liquid
To apply a transparent film, and apply cyanoethyl cellulose
And ethyl cellulose, butyral resin, vinyl acetate
Resin with organic solvents acetone, ethyl acetate and MEK
Apply the spiropyran dye solution to the dissolved solution
And white opaque film, not suitable for automotive window glass
It was correct. And cellulose ether resin is
The resulting adhesion is still worse. And for workability
The UV cut film and the titanate film twice
Is not efficient in terms of workability.
What can be completed by spraying the membrane at once
Was needed. Embodiments of the present invention will now be described with reference to the drawings.
The invention will be described in detail as follows. [Fig.1] is one
A commonly known polypropylene or raw polyethylene injector
Shows a side view of the albumin to prevent evaporation of the organic solvent.
Water or arginic acid water, borane liquid complex acid vinyl liquid or poly
The ester liquid was blown into the container (1) of the injector.
Apply on the inside and dry. Next, sodium silicate
Glass fiber powder or calcium carbonate in sodium luminate water,
Mix magnesium oxide and aluminum oxide diatomaceous earth powder
Add sodium gustinate or sodium molybdate
Of sodium silicate or sodium aluminate solution
Pour into the inner surface of the vessel and let dry while rotating. Soshi
And apply it twice, apply it to a uniform thickness, and dry it.
You. For mass production, make paper or glass fiber containers,
On the surface, sodium silicate water and sodium borate, tungsten
Acid soda, sodium molyptate, glass powder, oxidation
Mix magnesium, alumina oxide and calcium carbonate
And apply it to the aqueous solution mixed with surfactant glycol.
Dry, apply this repeatedly and dry.
/ M in a plastic container
First, make a multi-layer container. [FIG. 2] is an injector container (1).
Fig. 1 shows a longitudinal sectional view of the soybean soybean soup inside the injector container (1).
Surface activity of white matter, albumin protein and sodium acrylate
Sodium silicate on the film (1 ') coated with aqueous solution containing a surfactant
A film (1 ") coated with a mixed water solution is applied in multiple layers and cured
Make membrane (A). The UV cut spiropyran inside
When adding a solvent solution in which oils have been dissolved, use the same oil-resistant
The container of the nature is obtained. And the plastic container alone
As described above, the organic solvent is prevented from permeating and disappearing. [Figure
3] is a side view of the upper cap (B) to which the injector is attached.
And two capillaries (3) in the center of the cap (2).
(3 ') is fitted, and a control valve (4) is fitted at the lower end.
UV inside the oil-resistant film (A) joined inside the lounge space (5)
The cutting liquid (6) is introduced, and the cap (2) is filled.
Screw it into the liquid port (7) of the container (1)
When pushing down the vertical lid (8) containing (8),
Press UV cut liquid (6) in oil resistant film (A) of container (1)
Spray from the nozzle (8 ') protruding from the side of the lid (8)
Confuse. This control valve (4) is made of a fluorinated resin or an oil-resistant film valve.
Standing. This valve uses conventional polyethylene or polyp
Unlike ropylene resin valves, there is almost no breakage. Also, fluorine
The same effect can be obtained by attaching a resin valve. [Fig.4]
Shows a side view of a liquid titanate chelate liquid container
Inside the box (2a), a square container (1
Swipe a) and place it on a square container (1a) in a polypropylene bag.
The neck of the bag (3a) is joined to the side of the bag,
Screw the top lid (4a) onto the top of the pipe (3a) and seal it.
You. Put this in the cardboard box (2a) on the entrance tube (3a).
Make a perforation with a protruding part, and place a hole in the upper part of the entrance pipe (3a).
Bonding (5a) board, perforating corrugated cardboard with top lid
(6a) Closely fixed to (6'a). This bag (1a)
The oil-resistant film (A) is joined to the inner wall of the bag (1a) to form an oil-resistant film.
Let it do. Put the organic solvent in a plastic container
If present, the container will be partially eroded, deformed and transparent
And disappeared. To prevent this, organic solvent resistant coatings
The membrane must be applied to the surface of the plastic container beforehand.
You. And many solvent resistant paints are hydrophilic,
Water-based paints have a problem in adhesion to plastic.
For this purpose, borane liquid is generally used for surface treatment.
Had been. This borane solution is a polyacrylic acid chromium complex
Or silicone chelating solution is used, but plastic
It is durable only with this liquid such as borane to apply it to the container
Not only does it have no
In the ester resin, the solvent gradually penetrates, causing resin dissolution.
Many disadvantages. The present invention relates to a plastic container
Soy milk or amino acid or soluble protein solution
Insoluble protein is plastic when immersed in a plastic container
Form a protein film on the surface and, with time, the formed protein
The film develops into a thick film. Also, beforehand,
If the surface is eroded by contact with hydrogen chloride or another strong acid, the surface
Uneven surface is formed on the surface.
And the hydrophilic resin is easily bonded. General Polyamide
The cellophane paper is pressed against the resin film.
With lophan paper inside, add a sodium silicate mixed solution
Extremely oil resistant when applied to cellophane paper
Is formed. Also, use of fluorine resin is acceptable.
No. In order to process this, UV must be added to the paper or container in advance.
The cutting liquid (7a) is introduced and sealed. This switch
An example of the composition of the tank chelate solution is as follows. Chita
Acid UV cut chelate liquid, propylene titanate gray
Make a call chelate solution and use it as solution A. This chelate is
Titanium tetrachloride, silicon tetrachloride, zirconium tetrachloride
Or tin tetrachloride solution dropped into propylene glycol solution
Stirring to remove titanium, silicon, zirconium and tin.
Hydrochloric acid by-produced is ammonia or sodium percarbonate.
Neutralize with a mortar or the like to adjust PH to 3-5, and add 1 mole of titanium
Mix and stir 3 to 4 moles of propylene glycol to react
Let me know. This is stored as solution A, and spiropyran
Dissolve 10g in MEK solution or 500g of acetone
Solution B. [Example 1] 100 g of solution A of a glycolic acid titanate chelate solution 10 g of solution B of a spiropyran acetone solution are mixed and stirred well to produce a yellow solution. This is UV
Window glass and automobile body as titanium dioxide liquid
As soon as it is applied to the rearview mirror or the
Come and wipe it with a piece of paper, cloth or sponge
Make a glossy surface. If the UV cut is insufficient, the next UV
Cut solution was sprayed further or dye was dissolved in MEK
Apply a mixture of UV cut solution and dry it
You. To dissolve the steel pieces and dissolve the ferrous salt in the solution.
Make a melted green-blue liquid. Next, oil-resistant organic solvent-resistant coating
The fee is as follows. [Example 4] Baume 20 sodium silicate water sol 100 g Calcium hydroxide 1 g Magnesium oxide 1 g White refined diatomaceous earth powder 5 g Sodium tungstate or sodium molybdate 5 g Water 10 g Surfactant 0.1 g [Example 5] Baume 20 silica Soda water sol 100 g Slaked lime 20 g Aluminum powder 1 g Diazo foaming agent 3 g Gelated silica powder 1 g Sodium tungstate 12 g Sodium borate 3 g Sodium fluorosilicate 0.1 g Water 10 g Surfactant 0.1 g [Example 6] Sodium silicate or aluminate Soda 100g Aluminum oxide powder 5g Slaked lime 5g Gelled silica powder 5g Water 10g Sodium tungstate 3g [Example 7] Paper heat resistant paint paste Sodium silicate water or sodium aluminate 100g Sodium tungstate water or sodium molybdate 5g Water 50 g surfactant 0.1 g [Example 8] sodium metasilicate 100 g sodium tungstate or sodium molybdate 5 g boric acid 1 g polymerization degree 500 polyvinyl alcohol 2 g water 1000 cc [example 9] vinyl acetate resin 20 g acetone or ethyl acetate 1000 cc spiropyran powder 10 g Azo dye alcohol solution 10 cc 5% titanate alcohol chelate solution 100 cc [Example 10] Butyral resin 10 g Acetone 1000 cc Spiropyran powder 10 g Azo dye 0.8 g Vanish pigment sol 1 g Titanate alcohol chelate solution 100 cc [Example 11] Polyester resin 20 g Acetone 1000 cc Schner 200 cc Spiropyran powder 10 g Vanish pigment 5 g Titanate alcohol chelate 100 cc First, a mixer [Example 4] ] [Example 5] Add [Example 6] and stir
Stir with a machine and plastic sheet with a coating roll
And dried, and the plastic of [Example 9] to [Example 11]
Apply and dry the sol. For molded bottles and containers
Is dried while rotating the pickled dough to form a hard film.
UV-cut titanate chelate of [Example 9] to [Example 11]
And dry it. [Example 6] to [Example 7] are foaming properties
Silicate sol, foamed by heating and emitted at room temperature
A foamed multi-cellular cured film is formed. [Example 8] is liquid
No viscosity with paint. Window glass, especially for large buildings
UV-cut paint and glico-titanate chelate liquid
First, a 5% glycolic acid titanate chelate solution was added
Dilute twice and apply to window glass or wall, wash immediately with water
Wash off excess liquid and dry. Next, apply UV cut liquid
And let it dry. Car window glass, car body surface and battery
UV cut containing [Example 3] and [Example 4]
Spray with the combined use of glico-titanate and sponge
Wipe dry with a piece of cloth while keeping dry
And polish it to a glossy surface. Cloth when cloudy
If you wipe it empty, the gloss will be reproduced. This bag contains 20 l
Acetone, thinner, acetate, MEK,
Solvent such as cyclohexanone and store in 20l of this in bag
PET does not evaporate at times and does not corrode plastic bags
As shown in FIG. 4, the bottle is also a PET bottle.
When making the inner wall of the sodium silicate mixture on the surface,
The organic solvent remains in the bottle without evaporating. This PET
Waste PET bottles can be washed with hot water to dissolve
Recycling becomes possible. [Figure 5] shows a side view of the car
And front glass (1d), rear window glass (2d), and
The window glass (3d) (3'd) of the door and the vehicle body (5
d) and rear mirror (5'd) with UV cut chita
After applying the glycolic acid chelate solution, dry the cloth
When wiping the coated surface, keep the glossy UV cut surface
The film that has been held is formed, and when it gets dirty, it can be cleared with an empty wipe
Is done. [Fig. 6] shows a side view of the architectural building,
(1e) window glass (2e) and concrete tiles
UV coating titanic acid clean when applied to wall surface (3e)
A film is formed. Wipe windows and walls of high-rise buildings
Because it is difficult, wash with water after coating
Sometimes finish. [FIG. 7] shows the television set (1
F) shows an oblique front view, and the image screen (2F) shows UV
After applying the cut titanate chelate solution, wipe dry with a piece of cloth.
A clear screen is obtained when it comes
It is cleaned only by wiping. [Fig. 8] shows the polyester
The front view of a corrugated sheet (1G) of plastic or polyvinyl resin
Shown on the surface and sodium tungstate
The sol mixed with the additive is applied and dried to form a film (2G).
Make and apply UV cut polybutyral resin. Mochi
Glue titanate chelate liquid is applied to the lantern in advance
And dried to form a film (3G). [Fig. 9] shows poly
AB cutting of corrugated sheet of ester resin or polyvinyl resin
FIG. FIG. 10 shows a side view of the gas tank.
The anti-aging Glyco titanate is applied to the painted surface of this surface.
Apply a surface paint mixed with Lukylate UV cut liquid
You. [Fig.11] shows a side view of the ship, and the outside of the cabin window
Glycol titanate chelate and UV
Coating liquid on the wall (P) and also on the window glass (1n)
Cloth to prevent aging and stain resistance. [Fig.12]
The front view of the il plate is shown,
Processed by hot press, the surface of which is tangled with sodium silicate
Make a sodium citrate surfactant mixed solution sol and display it.
Coating and drying the hard film (2b)
You. Next, a butyral tree is applied to the surface of the dried film (2b).
A mixture of fat and titanate chelate and UV cut
Coating and drying to form film (1b). This Thailand
The metal plate is used for the wall and the exterior. And update
To process a concrete membrane on
If you apply a paste, it will join. Such tiles are fire
If there is, make the tungstate silicate heat resistant
Acts to protect the plastic molded tile plate,
In this silicate, put aluminum powder and slaked lime
It foams and becomes sponge, resulting in heat insulation [Fig.
[3] is a handbag of plastic multi-layer coating of substitute leather
Skewed front view of a plastic handbag (3
c) Silicic acid, tungstic acid, lime, alumina powder, interface
Apply and dry sol containing activator, dye and pigment
Polybutyral resin or Polyxypolyester resin
Titanate chelate by adding solvent to fat or vinyl acetate resin
Liquid and resin containing UV cut solution are applied
Handbags that give a real leather-like feel when dried
Can be done. (4c) is a handle of the handbag. Soshi
(5c) shows a fitting to be joined to the handle (4c),
(6c) shows stop of handbag. [Fig.14]
Sodium tungstate silicate on the surface of veneer plywood (T)
Apply a soda mixture and apply butyral titanate UV
When the solution is applied, the surface is not stained and a fire wall material is made.
Nailing is also possible, and even if there is a fire, it has fire resistance to flames.
You. FIG. 15 shows an oblique front view of a multi-fiber cloth winding,
Fire aging prevention of scrolls such as cloth and wallpaper
Make a rug. [Fig.16] is a concrete block for construction.
Figure 2 shows a front elevational view of the
Add ruconium lime sol to concrete block (1 liter)
Apply to the surface, UV-cut polybutyral
The coating solution is durable to acid rain and acid resistant
It is. Polyester metal powder paint, cellulose ether
Applying a recon resin paint produces a colorful color coating
Not only does not cause concrete cracking,
Prevents dew condensation on concrete in building construction
You. [Fig.17] shows the oblique front view of the house.
And useful. [Fig.18] is a UV-cut spiropyran
This shows the characteristics of the absorption spectrum of the liquid. Thus, the present invention is self-contained.
UV cut for window glass of cars, trains, ships, airplanes, etc.
Some titanic acid, silicon acid, stannic alcohol and other
Use of paint combined with rate liquid and resistance of container containing it
Plastics with improved durability, oil resistance, solvent erosion resistance, etc.
Lighter and safer with the development of stick bottles and injectors
Of UV cut metal rate compound paint set products
It depends on the departure. [FIG. 19] is a solvent erosion resistant container
(A) of the present invention, (B)
And (C) are conventional. The feature of this invention is that
After forming a titanate film on the glass, apply UV cut solution
The method of applying separately was common, but it was troublesome
Therefore, the work is simplified so that the work can be completed by one coating. Soshi
Even if the container is stored in a multi-layer container,
There was no result and long term storage was obtained. In addition, plastic
With fluorinated resin film laminated on the lining
Cellophane is also used in polyamide resin
This cellophane is polyvinyl in the coated film.
Laminated acetate film is also used.
You. Also, besides this, aluminum box laminated or true
Metal film deposition on plastic film surface by empty deposition
What is done is also used, but a thin film of plastic
Oil resistance, organic solvent erosion resistance, heat resistance while increasing the strength of
In order to provide heat resistance, especially heat insulation by foamed silica,
Multi-layer formation of silica gel and sodium aluminate gel
It is widely used and inexpensive. This soda for PET resin lining
-When using a salt, no deformation occurs even if a solvent is introduced.
No. Also, azo dyes and acid dyes are used in combination with spiropyran dyes.
Then you can get more than 90% of UV and UV cut
But this is combined with the glycolic titanate chelate
This enhances the UV-cut dye film and increases the stability to 20.
% Or more, and the work is completed at once. This oil resistance, melting resistance
Application of development of multi-processing method for medium erosion and heat-resistant plastic is established
It has been expanded to construction materials and daily necessities.
It is also used to prevent condensation and acid rain,
This is an industrially useful invention. [Effects of the present invention] Oil resistance, solvent erosion resistance, deformation resistance
Use a heavy glass bottle or metal bottle as you can make a plastic container.
There is no need for And UV cut and titanium
Surface treatment of acid, silicon acid, zirconate and stannic acid films
It is easy to perform and saves time.
By preventing aging of the plastic and increasing the abrasion resistance
To expand its range of applications,
It is also used for miscellaneous goods. In addition, semiconductors
Ropyran can be applied to increase electrical efficiency
It became.

BRIEF DESCRIPTION OF THE DRAWINGS [FIG. 1] Side view of a plastic bottle of an injector [FIG. 2] Longitudinal sectional view of an injector container [FIG. 3] Side view of an upper lid cap equipped with an injector [FIG. 4] UV cut Side view of titanate chelate liquid container [Figure 5] Side view of car [Figure 6] Side view of building building [Figure 7] Slant front view of TV [Figure 8] Front view of corrugated sheet of polyester resin or polyvinyl resin 9 is a cross-sectional side view of a corrugated sheet of polyester resin or polyvinyl resin taken along line AB. FIG. 10 is a side view of a gas tank. FIG. 11 is a side view of a ship. FIG. 12 is a front view of a molded tile plate. Slant front view of handbag of plastic multi-layer coating of leather substitute [FIG. 14] Front view of multi-layer board of plywood [FIG. 15] Slant front view of multi-filament winding [FIG. 16] Slant front view of concrete block [FIG. 17] House side [18] Characteristics of the ullage of absorption spectrum [19] solvent resistance corrosion container spiropyran solution UV-cut

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI Theme coat ゛ (Reference) B65D 81/30 B65D 81/30 BD C09D 5/16 C09D 5/16 183/02 183/02 201/00 201/00 F term (reference) 3E067 AA04 AB96 BA03A BB14A BB22A CA13 CA15 CA16 EE32 3E086 AD04 BA15 BA35 BB23 BB74 CA29 4D075 CA13 CA18 CA32 CA34 CA44 CB04 CB06 DA04 DA06 DA19 DB13 DB21 DB36 DB53 DC01 DC08 DC08 DC08 EB07 EB19 EB35 EC07 EC08 EC47 4F100 AK01B AT00A BA02 BA07 CA07B CA13B CC01B GB32 JL06 4J038 DM021 NA19 PB02 PB05 PB07 PC03

Claims (1)

[Claims] Spiropyrans and dyes dissolved in an organic solvent are added to a glycol alcohol chelate solution of titanic acid, zirconic acid, stannic acid, and silicon acid to increase UV cut (ultraviolet cut), Window glass, automobile body, airplane body, train paint, electric TV and other paint appliances, highway side wall, building wall material, printed paper surface processed to remove ultraviolet rays formed by adding resin accordingly Anti-dirt paints and cream resin products, oil-resistant and solvent-resistant plastic containers and other miscellaneous goods containing this liquid.