JP2003041483A - Packed paste material - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a packed paste material capable of suppressing production of aggregates without causing deterioration of an odorous substance during storage. SOLUTION: This packed paste material is obtained by packing a liquid paste material comprising (a) a polymer having a structural unit derived from vinyl acetate (a-1) and a structural unit derived from at least one kind (a-2) of an unsaturated carboxylic acid and a lower alcohol ester of the unsaturated carboxylic acid, (b) a nonionic surfactant and (c) a specific perfume compound into a flexible bag-like container having <=30%; light transmission in total wavelength of 200 to 800 nm.

Description

Description: BACKGROUND OF THE INVENTION 1. Field of the Invention
Containers filled in flexible bag-like packaging containers such as tic containers
It relates to the paste in the container. [0002] Conventional glue
Starch was used for the ingredients, but to make it easier to use
Various improvements have been made and are now easy to dilute in cold water,
Liquid glue has been developed as a simple and stable glue.
You. JP-A-53-70197 discloses such a paste base.
JP, JP-A-53-94688, JP-A-52-94688
No. 53089, JP-A-59-88978, etc.
A paste composition based on vinyl acetate has been proposed.
You. JP-A-5-9853 discloses vinyl acetate,
Contains unsaturated carboxylic acids and acrylamide derivatives
A size composition is disclosed. Furthermore, these paste compositions
Contains vinyl acetate and other copolymerizable monomers in aqueous solution
It is obtained by polymerizing with
The paste composition contains several hundred to several unreacted vinyl acetate monomers.
1000 ppm remaining, so strong pungent odor
Improvements such as masking have been made. The applicants have
Japanese Unexamined Patent Publication No. 2001-81669 uses a specific fragrance
Technology to suppress such irritating odors
ing. On the other hand, problems such as resource saving and plastic waste
From the title, packing in thin plastic film sachets
Replacement pastes have been proposed. The present inventors have disclosed in
No. 000-110074 discloses that glue is applied to the inner wall of a container during storage.
A liquid paste article in which the base material does not form a film.
You. However, the paste that suppresses the pungent odor is
Items packed in such refillable sachets should not be exposed to direct sunlight.
Irritating odor is reduced when stored under certain conditions
Cause the problem of significant deterioration of odor
You. In addition, agglomerates are formed during storage, making them aesthetically pleasing.
Unfortunately, these improvements are needed. [0004] The object of the present invention is therefore to reduce the smell during storage.
Into a container that does not cause coalescence and suppresses the formation of aggregates
To provide glue. SUMMARY OF THE INVENTION The present invention provides a vinyl acetate
(A-1) [hereinafter referred to as monomer (a-1)]
Structural units and unsaturated carboxylic acids and unsaturated carboxylic acids
At least one of lower alcohol esters of (a-2)
Structural units derived from [hereinafter referred to as monomer (a-2)]
Having a polymer compound (a) [hereinafter referred to as component (a)
), A nonionic surfactant (b) [hereinafter referred to as component (b)
) And at least one compound selected from the group of (c) below
Liquid containing compound (c) [hereinafter referred to as component (c)]
Light transmission of the paste composition at all wavelengths from 200 to 800 nm
Filling into flexible bag-shaped packaging containers with a rate of 30% or less
And a paste material in a container. (C): Undecyl Aldehyde, Undecylen Alde
Hyde, dodecyl aldehyde, γ-undecalact
, Allyl amyl glycolate, allyl cyclohexane
Propionate, allyl heptanoate, Amberco
A, ambroxane, amyl salicylate, benzyl
Acetate, benzyl benzoate, benzyl salicylate
G, cis-3-hexenyl salicylate, cis-di
Jasmon, Citral, Citronellol, Coumarin, Sis
Clamenaldehyde, dimethylbenzylcarbinyl ace
Tate, decenol, dihydromyrcenol, fructo
, Furtate, geraniol, edion, heliot
Lopine, hexylcinnamic aldehyde, α-iono
, Acetoxyamyltetrahydropyran, lavender
Oil, lemon oil, lilial, lime oil, li
Narole, Linalyl acetate, Lillard, Magno
, Methylionone-G, musk ketone, miracal
Dehide, nerol, tert-butylcyclohexylurea
Acetate, pt-butylcyclohexyl acetate,
Patchouli alcohol, pearl ride, phenoxano
, Phenylethyl alcohol, poarenate, rose
Absolute, rose oxide, rosemary oy
Le, sandal mysore core, tarpineol, tarpi
Nil acetate, tripral, vanillin, iranila
DETAILED DESCRIPTION OF THE INVENTION [Liquid paste composition] <Component (a)> The component (a) of the present invention comprises a monomer (a-
1) Mainly a structural unit derived from a monomer (a-2)
It is a polymer compound having a structural unit derived therefrom. monomer
As the unsaturated carboxylic acid (a-2), acrylic acid,
Methacrylic acid, crotonic acid, maleic acid, fumaric acid,
Taconic acid, aconitic acid, sorbic acid, cinnamic acid, α-
Chlorosorbic acid, citraconic acid,
Particularly preferred are acrylic acid, methacrylic acid and crotonic acid.
No. Further, the unsaturated carboxylic acid of the monomer (a-2)
Examples of alcohol esters include unsaturated carboxylic acids and charcoal.
Alcohols with prime numbers 1 to 8, especially alcohols with 1 to 4 carbon atoms
Esters with thiol are preferred. The polymer compound according to the present invention comprises a monomer
A mixture containing (a-1) and (a-2) is copolymerized.
Are preferred. In the polymer compound, the monomer (a-
1) 55 to 99.7% by mass of a structural unit derived from a monomer
The structural unit derived from (a-2) is 0.2 to 15% by mass, particularly
Preferably, it is contained at a ratio of 0.2 to 10% by mass.
When synthesizing from a monomer mixture, the monomer (a-
1), the ratio of the structural units derived from (a-2) is this ratio.
From the added monomer mixture. In the present invention, the above monomer (a-1),
Other than (a-2), α, β-unsaturated carboxylic acid amide and
And at least one unsaturated cationic monomer (hereinafter, referred to as
Monomer (a-3)].
preferable. Among the monomers (a-3), α, β-unsaturated
As the carboxylic acid amide, N, N-dialkylac
Rilamide, N, N-dialkylmethacrylamide, N
-Alkyl acrylamide, N-alkyl methacrylate
Amide, N-alkoxyalkylacrylamide, N-
Droxyalkylacrylamide, N-hydroxyal
Kill methacrylamide, N-acylalkyl acrylia
Amide, N-acylalkyl methacrylamide is preferred
And more preferably these alkyl groups, alkoxyl
Groups and acyl groups have a chain length of 1 to 18 carbon atoms.
More preferably, N, N-dimethylalkylamide, N, N
-Dimethylmethacrylamide, N, N-diethylacrylic
Amide, N, N-diethyl methacrylamide, N-P
Propyl acrylamide, N-hydroxyethyl methacryl
Luamide and diacetone isoacrylamide. Further, among the monomers (a-3), unsaturated
As the cationic monomer, JP-A-1-321981
General formulas (1) to (7) in the left column of page 1 to the right column of page 2
It is preferable to use those having the following general formula (i)
The compounds of (iv) to (iv) are preferred. [0011] (Where R ₁ Is a hydrogen atom or a methyl group,
R _Two , R _Three , R _Four May be the same or different
A hydrogen atom, an alkyl group having 1 to 4 carbon atoms or a substituted alkyl
A kill group, Y is an oxygen atom or an NH group in an amide bond, X ^- Is
Chlorine, bromine, iodine, sulfuric acid, sulfonic acid, methyl sulfate,
Monovalent anions such as acid and nitric acid, m is an integer of 1 to 10
Is shown. [0013] (Wherein R _Five Is a carbon which may have a substituent
A hydrocarbon group of the formulas 8 to 22, R ₆ , R ₇ Each have 1 carbon atom
Alkyl groups of 3 to 3, R ₈ Is a hydrogen atom or a methyl group, X ^- Is
Same as equation (i). [0015] The monomer (a-3) is used in an amount of 0.1% in the component (a).
It is preferably contained in a proportion of 1 to 30% by mass,
When it is used, it becomes 0.1 to 30% by mass in all the monomers.
It is preferable to use it. The weight average molecular weight of the component (a)
Liquid chromatography using polyethylene glycol as
1000 to 200,000, especially when measured by the rough method
10,000 to 100,000 is preferred. To obtain the component (a), a polymerization initiator and
2,2'-azobis (2-amidinopropane)
Hydrogen oxide, t-butyl hydroperoxide, cumene
Hydroperoxide, methyl ethyl ketone peroxy
Side, cyclohexanone peroxide, peracetic acid, peroxy
Benzoic acid, persulfate can be used. Initiator
The range of 0.01 to 5% by mass based on the monomer (a-1)
It is preferable to use them. The temperature of the copolymerization reaction is preferably from 40 to 120 ° C.
Or 50 to 90 ° C., and the pH at the time of copolymerization is 3 to 9,
Preferably, it is performed in the range of 4 to 8. In this case, charcoal is used as a buffer.
Sodium acid, sodium bicarbonate, sodium orthophosphate
Sodium, monobasic sodium phosphate, sodium chloride, sodium sulfate
0 to 2% by mass of an inorganic salt such as thorium, preferably
It is preferable to use 0.1 to 1% by mass. The content of the component (a) of the present invention is determined by
10 to 60% by mass, particularly 30 to 55% by mass in the composition is preferred.
Good. <Component (b)> Liquid glue set according to the present invention
The product uses a nonionic surfactant as component (b) and
From the viewpoint of storage stability, Griffin's method or
319 of the Handbook of Pharmaceuticals (published by Sangyo Tosho Co., Ltd. in 1960)
If at least one of the HLBs determined by the method described on page
Preferably 15-20, more preferably 16-20, especially
Preferably 17 to 20 compounds are suitable. Specifically
Preferred compounds are those represented by the following general formula (v).
Suitable. R ₉ −T-[(R _Ten O) _a -R ₁₁ ] _b (V) [wherein, R ₉ Has 8 to 18 carbon atoms, preferably 10 to 1
6 is an alkyl group or an alkenyl group, _Ten Is the carbon number
2 or 3 alkylene groups, preferably an ethylene group
It is. R ₁₁ Is an alkyl group having 1 to 3 carbon atoms, or hydrogen
Is an atom. a is 25 to 100, preferably 30 to 8
0, more preferably 35 to 75, particularly preferably 40 to
The number 60 is shown. T is -O-, -COO-, -CON-
Or -N-, and when T is -O- or -COO-,
b is 1 and when T is -CON- or -N-, b is
1 or 2]. As specific examples of the compound of the general formula (v),
Can be mentioned. R ₉ -O- (C _Two H _Four O) _c -H [wherein, R ₉ Has the above-mentioned meaning. c is 25-100,
Preferably 30-80, more preferably 35-75, especially
Preferably a number of 40 to 60. ] R ₉ -O- (C _Two H _Four O) _d − (C _Three H ₆ O) _e -H [wherein, R ₉ Has the above-mentioned meaning. d and e are
Independently from 10 to 100, preferably from 20 to 80
D + e is 25-100, preferably 30-80, and
More preferably 35 to 75, particularly preferably 40 to 60
Is a number. Note that-(C _Two H _Four O)-and-(C _Three H ₆ O)-
It may be a random or block additive. [0024] [Wherein, R ₉ Has the above-mentioned meaning. f and
g is each independently 10 to 100, preferably 20 to 8
0 and f + g is 25 to 100, preferably 30
~ 80, more preferably 35-75, particularly preferably 4
It is a number from 0 to 60. 0-40, preferably 0-20
Is a number. R ₁₂ , R ₁₃ Are each independently a hydrogen atom or charcoal
It is an alkyl group having a prime number of 1 to 3. ]. The content of the component (b) of the present invention is determined by
0.5 to 10% by mass in the composition, further 0.5 to 5% by mass,
More preferably, the content is 0.5 to 5% by mass, particularly 0.5 to 3% by mass.
Good. <Component (c)> Liquid glue set according to the present invention
The product is composed of undecyl aldehyde, c) as component (c).
Ndecylene aldehyde, dodecyl aldehyde, γ-
Undecalactone, allyl amyl glycolate, allyl
Cyclohexane propionate, allyl heptanoe
, Amber core, ambroxane, amyl salicile
G, benzyl acetate, benzyl benzoate, ben
Jil salicylate, cis-3-hexenyl salicylate
G, cis-jasmon, citral, citronello
, Coumarin, cyclamenaldehyde, dimethylbenzy
Lucarvinyl acetate, decenol, dihydromyrce
Knoll, fructon, furtate, geraniol, edible
, Heliotropin, hexylcinnamic alde
Hyd, α-ionone, acetoxyamyltetrahydropi
Orchid, lavender oil, lemon oil, lilial,
Lime oil, linalool, linalyl acetate, lira
, Magnole, Methylionone-G, Musket
, Mirac aldehyde, nerol, tert-butyl
Cyclohexyl acetate, pt-butylcyclohexyl
Sil acetate, patchouli alcohol, pearl ride,
Phenoxanol, phenylethyl alcohol, poare
Nate, rose absolute, rose oxide, b
Zumary oil, sandal mysore core, tarpine
Oar, terpinyl acetate, tripral, vanili
Selected from oil, ylang-ylang oil and α-damascon
One or more perfume ingredients. Special among these
Amber core, amyl salicylate, benzyl acetate
Tate, geraniol, edion, α-ionone, la
Bender oil, lilial, linalool, liral,
Methylionone-G, ot-butylcyclohexylurea
Acetate, pearlride, phenylethyl alcohol,
Ylang-ylang oil is preferred. In the present invention, the scent other than the component (c) is used.
You may contain the ingredient (c '). Such fragrance ingredients
"The Chemistry of Fragrances" (Ryoichi Akahoshi, edited by The Chemical Society of Japan)
Industrial Chemistry Series Published on September 16, 1983)
Perfumery Chemistry and Product Knowledge ”(Genji Indo, March 1996)
Published on March 6), “Known and used technology collections (fragrances) published by the JPO
You can use those described in Part 1
You. However, the component (c ′) does not impair the effects of the present invention.
It is important to use (c) component / [(c)
Component + (c ') Component] is 0.3 to 1 by mass ratio, preferably
Is preferably from 0.5 to 1, particularly preferably from 0.7 to 1.
You. The content of the component (c) of the present invention is determined by
0.01-1% by mass in the product, 0.01-0.5 quality
%, Particularly preferably 0.05 to 0.5% by mass. <Other components> Liquid paste according to the present invention
The composition is silicone based on storage stability and texture of clothing.
Containing the compound (hereinafter referred to as the component (d))
preferable. (D) Component is dimethyl polysiloxa
Amino-modified silicone, alkyl-modified silicone
Reether-modified silicone, alcohol-modified silicone
And among them, particularly, a molecular weight of 100
0-200,000 dimethylpolysiloxane is good
You. The component (d) is contained in the liquid paste composition in an amount of 0.01 to 0.5.
% By mass, preferably 0.05 to 0.4% by mass.
Is preferred. The liquid paste composition according to the present invention includes a composition
In order to further improve the separation stability of
Soluble polymers can be included. Such poly
Polyvinyl alcohol, polyvinylpyrroli
Don, modified starch and water-soluble cellulose derivatives
Can be. Further, the average degree of polymerization is 500 to 5000, preferably
Or 500 to 3000 is preferable. The degree of polymerization is
Polyethylene by gel permeation chromatography
Glycol can be determined as a standard. Nonio
The amount of the water-soluble polymer is preferably used in the liquid paste composition.
0.1 to 10% by mass, more preferably 1 to 4% by mass
%. In the liquid paste composition according to the present invention,
(A) The component is adsorbed on the fiber, and the tension is efficiently given.
It is preferable to use further cationic polymers for the purpose.
No. Such cationic polymers are cationic
Cellulose, cationic starch, the above monomer (a-3)
And cationic vinyl polymers from other than
You. The cationic polymer is added to 100 parts by mass of the component (a).
So that the ratio is 0.1 to 15 parts by mass.
Is preferred. In addition, the liquid paste composition according to the present invention
If necessary, commonly used polymer emulsions
Additives for ethylene such as ethylene glycol and propylene
Freeze stabilizers such as glycol, ethanol, or
Is dibutyl phthalate, dibutyl adipate,
Butyl adipate, dioctyl adipate, triaceti
Plasticizers, etc., disinfectants, preservatives, fluorescent dyes, face
And the like can be appropriately added. The liquid paste composition according to the present invention has a balance of water.
Yes, 20-90% by mass in the composition, and 50-70 mass%
% Is preferably contained. [Packaging container] The paste in a container of the present invention
The liquid paste composition containing the essential components was
Light transmittance at all wavelengths of 0 nm is 30% or less, preferably
20% or less, more preferably 10% or less, particularly preferably
Is less than 5% plastic or paper flexibility
In a bag-shaped packaging container. Here, the light transmittance is smaller than that of the container having the final shape.
At least for the container of the composition.
Using a spectrophotometer (UV-2500PC, manufactured by Shimadzu)
Measured. The flexible bag-shaped packaging container is made of plastic
It is preferably made of lum or paper. Where "flexibility"
Means that the bag is not rigid, i.e. semi-rigid
Or it refers to the state of being flexible,
Shape packaging container "means the ability to shield from the outside, the dimensional stability of the bag,
With sufficient strength, etc., the shape of the bag-shaped packaging container is partially
Means a container that can be easily deformed. In addition, bag-like packaging containers
This indicates that the film is made of a film having an appropriate texture.
The packaging container is 5-1000 μm, preferably 5-500 μm
m, more preferably a plate having a thickness of 50 to 500 μm.
It is preferred to be made of a plastic film. As a plastic material, a linear low-density polye
Tylene, low density polyethylene, undrawn polypropylene,
Stretched nylon, stretched polypropylene and polyethylene
Use at least one selected from phthalate
Is preferred. The plastic packaging container of the present invention
It consists of a plastic film with a multilayer laminated structure
Is preferred. For example, a linear low-density poly
It is preferable to use ethylene, the outermost layer is mechanical
Strong plastic, preferably stretched nylon,
It is preferred to use stretched polypropylene. Each of these
The thickness of the layer is preferably from 5 to 300 μm. Furthermore these
The plastic container has a barrier layer, pinhole-resistant layer,
It is also possible to provide a tear induction layer or the like. In order to reduce the light transmittance to 30% or less,
Forming a plastic container from a multi-layer film,
An aluminum foil, an aluminum deposition film or a colored layer is sandwiched between the layers.
The method is preferred. The colored layer is, for example, gray gravure in
Ki and white gravure ink, black ink, silver in
It can be produced by applying a key or the like. The plus used in the bag-shaped packaging container of the present invention
The tic film can be easily manufactured by a known method. Special
A laminated film is preferable, and the method for producing the
Rye lamination method, T-die method, co-extrusion lamination
Method, inflation method, tandem lamination method, etc.
I can do it. The form of the packaging container is not limited,
For example, around the plastic film of the desired size
Heat-sealed containers (bags) of desired capacity
It is preferred to use The paste in a container of the present invention can be easily used by a user.
Packaged in a bag (container) large enough to be handled and used by hand
Have been. EXAMPLES <Preparation of size base> (1) Preparation of size base A A cationized starch [corn
Starch and 3- (N, N, N-trimethylammonium
Chloride) -1,2-propylene oxide
obtain. Degree of cation substitution = 0.08, 50 ° C of 5% aqueous solution
Is 70 mPa · s], 8.9 parts by mass,
And 100 parts by mass of ion-exchanged water are uniformly dissolved at 90 ° C.
After cooling to 60 ° C, 10 parts by mass of vinyl acetate
Vinyl alcohol (weight average molecular weight 66,000) 3 quality
Parts by weight, nonionic surfactant (polyoxyethylene lauri
Ether, ethylene oxide average addition mole number [hereinafter,
EOp) 60, HLB 18.6] 1.5 mass
And 0.5 parts by mass of trisodium phosphate,
2,2'-azobis (2-amidinopropane) hydrochloride
Add 0.4 parts by mass and 20 parts by mass of ion-exchanged water,
To initiate polymerization. 6 hours after the start of polymerization
, Vinyl acetate, acrylic acid, N, N-dimethyl
The final ratio of luamide is 95.5 / 2.5 / 2 (mass ratio)
100 parts by mass previously mixed so that
It was dropped into the reaction solution. After dropping, the temperature was raised to 80 ° C,
Stirring was continued for 1 hour. After cooling, 10 mass% carbonic acid
Adjust the pH of the emulsion to 5 using an aqueous sodium solution.
And a paste base A having a polymer weight of about 50% was obtained. (2) Preparation of size base B In preparation of size base A, a nonionic surfactant was used.
And polyoxyethylene lauryl ether (EOp8
0, HLB 19.0), except that 1.5 parts by mass was used.
Base material B prepared by the same method and having a polymer mass of about 50%
Got. (3) Preparation of Size Base C In the preparation of size base A, a nonionic surfactant was used.
And polyoxyethylene lauryl ether (EOp10
0, HLB19.3) except that 1.5 parts by mass was used.
Base material C prepared by the same method and having a polymer mass of about 50%
Got. (4) Preparation of Size Base D In the preparation of size base A, a nonionic surfactant was used.
Polyoxyethylene lauryl ether (EOp10, H
LB14.6)
To obtain a paste base D having a polymer mass of about 50%.
Was. [Container] (1) Container A 20 μm thick stretched nylon, 100 μm thick linear low
High density polyethylene, 50μm thick aluminum foil and thickness 1
5 μm stretched nylon is superimposed in this order to form a rectangular
Prepare two sets of shapes, each with a thickness of 15 μm
Layer so that the stretched nylon of
Heat seal the sides to make a sachet with a volume of 1000 ml
Was. Light transmission of this pouch at all wavelengths from 200 to 800 nm
The rate was measured to be at most 5%. This container
When used, the liquid paste composition should be a 15 μm thick
Fill between the irons and heat seal the other side of the bag
To obtain a paste in a small bag. (2) Container B: stretched nylon having a thickness of 20 μm and a linear shape having a thickness of 100 μm
Plastic sheet laminated with low density polyethylene
3μm gray gravure ink, 3μ white gravure ink
m, and a 50 μm-thick stretcher
For two sets of rectangular shapes formed by overlapping iron
So that the stretched nylon with a thickness of 50 μm is on the inside
The pouches were overlaid and made in the same manner as pouch A. This
The light transmittance of all pouches at all wavelengths from 200 to 800 nm.
As a result, the maximum was 25%. Use this container
Liquid nylon paste composition, a stretched nylon
And heat-seal the other side of the bag
A paste in a bag was obtained. (3) Container C: stretched nylon having a thickness of 20 μm and a linear low-profile having a thickness of 100 μm
High density polyethylene, 15μm thick stretched nylon
Prepare two sets of rectangular shapes superimposed on
Each stretched 15μm thick nylon is inside
Pouches are made in the same way as Pouch A
Was. Light transmission of this pouch at all wavelengths from 200 to 800 nm
The percentage was measured to be at most 75%. This container
When using, the liquid paste composition is stretched to a thickness of 15 μm.
Fill between nylon and heat seal the other side of the bag
Then, a paste in a small bag was obtained. (4) Container D: stretched nylon having a thickness of 20 μm and a linear shape having a thickness of 100 μm
Plastic sheet laminated with low density polyethylene
Gray gravure ink 1μm, white gravure ink 1μ
m in order, and then a stretched nylon
Two sets of rectangular shapes with overlapping
And stretched so that stretched nylon with a thickness of 50 μm is on the inside.
A pouch was prepared in the same manner as in pouch A. this
Measures light transmittance of pouches at all wavelengths from 200 to 800 nm
As a result, the maximum was 35%. Use this container
In the case, the liquid paste composition is a stretched nylon having a thickness of 50 μm.
Fill in between, heat seal the other side of the bag and pouch
A paste containing the paste was obtained. [Preparation and evaluation of paste in container]
The glue base thus formed and the components shown in Table 1 (perfume is also shown in Table 2)
The liquid paste composition having the composition shown in Table 1 using
Got. Fill them into containers as described above,
After shaking twice, 30 days outdoors in sunlight
For a while. After that, open the container and evaluate the odor of the contents.
And the state of agglomerate formation is determined according to the following criteria, and storage stability
The sex was evaluated. <Odor evaluation> Keep in a 100 mL screw tube.
Preparing 50 mL of each liquid paste composition before or after storage,
The plate was covered and left at 20 ° C. for 1 hour. After that, the trained
The odor was evaluated according to the following criteria by 10 Nellers, and the average score was
I asked. If the average score is 3 or more, ○;
Δ, less than 2.5 was indicated as x. 4: No smell derived from vinyl acetate is recognized. 3: Smell from vinyl acetate but not noticeable
It is. 2: It smells from vinyl acetate and is quite anxious. 1: Smell derived from vinyl acetate is strong. <Agglomerate formation status> In a 100 mL beaker
Charge 10 g of each liquid paste composition before or after storage,
After adding 90 g of ion-exchanged water to the mixture,
Stirring was performed with a tick stirrer. After stirring, the glue
100 parts of a pre-measured mass of the diluent composition
The wire mesh after filtration is washed with ion-exchanged water.
After that, put it in a 105 ° C electric thermostat and dry it for 30 minutes.
Was. Measure the mass of the wire mesh after drying, and agglutinate from the following formula.
The amount (%) was determined. ## EQU1 ## [Table 1] (Note) ・ Silicone: KM-97 manufactured by Shin-Etsu Chemical Co., Ltd.

Claims (1)

Claims 1. A structural unit derived from vinyl acetate (a-1) and a structural unit derived from at least one of unsaturated carboxylic acids and lower alcohol esters of unsaturated carboxylic acids (a-2). A liquid paste composition containing the polymer compound (a), the nonionic surfactant (b), and one or more compounds (c) selected from the following group (c) is prepared by adding 200 to 80
A paste material in a container filled in a flexible bag-like packaging container having a light transmittance of 30% or less at all wavelengths of 0 nm. (C): undecyl aldehyde, undecylene aldehyde, dodecyl aldehyde, γ-undecalactone, allyl amyl glycolate, allyl cyclohexane propionate, allyl heptanoate, amber core, ambroxane, amyl salicylate, benzyl acetate, benzyl benzoate Benzyl salicylate, cis-3-hexenyl salicylate, cis-jasmon, citral, citronellol, coumarin, cyclamenaldehyde, dimethylbenzylcarbinyl acetate, decenol, dihydromyrcenol, fructon, furtate, geraniol, edion, heliotropin, hexylsine Namic aldehyde, α-ionone, acetoxyamyltetrahydropyran, lavender oil, lemon oil, Lilyal, lime oil, linalool, linalyl acetate, lillal, magnole, methylionone-G, musk ketone, milac aldehyde, nerol, ot-butylcyclohexyl acetate, pt-butylcyclohexyl acetate,
Patchouli alcohol, pearlide, phenoxanol, phenylethyl alcohol, poarenate, rose absolute, rose oxide, rosemary oil, sandal mysole core, terpineol, terpinyl acetate, tripral, vanillin, ylang ylang oil and α-damascon