JP2003040399A - Supply apparatus of liquid - Google Patents
Supply apparatus of liquidInfo
- Publication number
- JP2003040399A JP2003040399A JP2001229687A JP2001229687A JP2003040399A JP 2003040399 A JP2003040399 A JP 2003040399A JP 2001229687 A JP2001229687 A JP 2001229687A JP 2001229687 A JP2001229687 A JP 2001229687A JP 2003040399 A JP2003040399 A JP 2003040399A
- Authority
- JP
- Japan
- Prior art keywords
- liquid
- mat
- storage
- bottle
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 187
- 238000002360 preparation method Methods 0.000 claims description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 238000009792 diffusion process Methods 0.000 claims description 36
- 230000001681 protective effect Effects 0.000 claims description 18
- 238000010521 absorption reaction Methods 0.000 claims description 13
- 230000000694 effects Effects 0.000 abstract description 13
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 239000012669 liquid formulation Substances 0.000 description 19
- 239000003205 fragrance Substances 0.000 description 16
- 230000005540 biological transmission Effects 0.000 description 12
- 239000002250 absorbent Substances 0.000 description 11
- -1 polyethylene terephthalate Polymers 0.000 description 11
- 238000011010 flushing procedure Methods 0.000 description 10
- 230000002745 absorbent Effects 0.000 description 7
- 230000014759 maintenance of location Effects 0.000 description 7
- 102100040428 Chitobiosyldiphosphodolichol beta-mannosyltransferase Human genes 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000004745 nonwoven fabric Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 230000002093 peripheral effect Effects 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 230000002940 repellent Effects 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
- Devices For Dispensing Beverages (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、液体ボトル内の液
体製剤を保持マット又は吸液マットに供給し、そのマッ
トから液体製剤の有効成分を外部に供給する液体供給装
置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a liquid supply device for supplying a liquid preparation in a liquid bottle to a holding mat or a liquid-absorbing mat and supplying the active ingredient of the liquid preparation from the mat to the outside.
【0002】[0002]
【従来の技術】従来、水洗トイレの貯水タンクの蓋上面
の水受け部に配置されて使用される、所謂オンタンク式
の液体供給装置が提案されている。2. Description of the Related Art Heretofore, there has been proposed a so-called on-tank type liquid supply device which is arranged and used in a water receiving portion on an upper surface of a lid of a water storage tank of a flush toilet.
【0003】[0003]
【発明が解決しようとする課題】液体供給装置には、フ
ラッシングが繰り返されても、液体製剤を安定供給し続
けることが求められているが、この観点において従来の
製品には、更なる改善が望まれていた。また、液体供給
装置に、芳香成分を室内に揮散する機能を持たせること
が望まれている。本発明は、このような事情に鑑みてな
されたもので、その目的は、液体製剤を長期にわたって
安定供給でき、高い芳香効果を奏する液体供給装置を提
供することにある。The liquid supply device is required to continue to stably supply the liquid preparation even if the flushing is repeated. In this respect, the conventional product has a further improvement. Was wanted. Further, it is desired that the liquid supply device has a function of volatilizing the aroma component into the room. The present invention has been made in view of such circumstances, and an object thereof is to provide a liquid supply device capable of stably supplying a liquid preparation for a long period of time and exhibiting a high aroma effect.
【0004】[0004]
【課題を解決するための手段】本発明の上記目的は、下
記構成によって達成される。
(1) 液体製剤を収容した液体ボトルと、前記液体ボ
トルから流出した液体製剤を保持する保持マットとを有
し、前記保持マットの液保持率が、0.1〜0.9g/
cm3であり、かつ、0.01〜0.2g/cm2である
ことを特徴とする液体供給装置。
(2) 液体製剤を収容した液体ボトルと、前記液体ボ
トルから流出した液体製剤を吸収して保持する吸液マッ
トとを有し、前記吸液マットが、前記液体ボトルからの
液体製剤を最初に吸収保持する貯留部と、前記貯留部か
ら液体製剤が伝達される拡散部とを有し、前記拡散部に
流水が接するように構成されていることを特徴とする液
体供給装置。
(3) 前記貯留部の下面が前記拡散部に接しており、
前記貯留部の側面が保護カバーで覆われている前記
(2)に記載の液体供給装置。
(4) 液体製剤を収容した液体ボトルと、前記液体ボ
トルから流出した液体製剤を吸収して保持する吸液マッ
トとを有し、前記吸液マットの所定箇所が保護カバーで
覆われており、前記吸液マットの前記保護カバーで覆わ
れた箇所に前記液体ボトルからの液体製剤が最初に供給
されることを特徴とする液体供給装置。The above object of the present invention is achieved by the following constitution. (1) A liquid bottle containing a liquid preparation and a holding mat for holding the liquid preparation flowing out from the liquid bottle, and the liquid holding rate of the holding mat is 0.1 to 0.9 g /
A liquid supply device, wherein the liquid supply device is cm 3 and 0.01 to 0.2 g / cm 2 . (2) A liquid bottle containing a liquid preparation, and a liquid-absorbing mat that absorbs and holds the liquid preparation flowing out from the liquid bottle, and the liquid-absorbing mat first receives the liquid preparation from the liquid bottle. A liquid supply device comprising: a storage part that absorbs and holds the liquid formulation; and a diffusion part to which the liquid preparation is transferred from the storage part, and the running water is in contact with the diffusion part. (3) The lower surface of the storage section is in contact with the diffusion section,
The liquid supply apparatus according to (2), wherein the side surface of the storage section is covered with a protective cover. (4) A liquid bottle containing a liquid preparation and a liquid-absorbing mat that absorbs and holds the liquid preparation flowing out from the liquid bottle, and a predetermined portion of the liquid-absorbing mat is covered with a protective cover. A liquid supply device, wherein the liquid formulation from the liquid bottle is first supplied to a portion of the liquid absorbing mat covered with the protective cover.
【0005】本発明者らは、保持マット(吸液マット)
の液保持性(吸液性)に着目した。保持マットの液保持
性が低ければ、液体ボトルから流出した液体製剤が迅速
に保持マットの全域に広がる(拡散速度が速い)ため、
短い時間間隔でフラッシングが繰り返されるときにも、
液体製剤を流水中に供給できる。しかし、保持マットの
液保持性が低いことは、保持マットに芳香成分等の有効
成分が保持されにくいことを意味し、このような保持マ
ットでは高い芳香効果を奏することができない。一方、
保持マットの液保持性が高ければ、液体製剤を迅速に吸
液マットの全域に広げることができない。上記(1)の
構成のように、保持マットの液保持率を適切な範囲に設
定することで、液体製剤を迅速に保持マットの全域に広
げることができ、かつ、高い芳香効果を奏することがで
きた。保持マットは、液体製剤を吸液して保持するもの
(吸液マット)でもよいし、表面に液を保持するための
多数の溝等が設けられたもの(溝付マット)でもよい
し、液を保持するための微孔が設けられたもの(多孔マ
ット)でもよい。繊維マットやパルプマットでもよい。
上記(2)の構成によれば、フラッシング時に拡散部に
流水が接して拡散部に保持された液体製剤が洗い流され
ても、貯留部に液体製剤が保持されているので、その貯
留部に保持された液体製剤により高い芳香効果が得られ
る。そして、液体製剤を洗い流された拡散部に、貯留部
からすみやかに液体製剤が供給されて、次のフラッシン
グまでには拡散部に液体製剤が十分保持される。貯留部
と拡散部とは、別体に形成されてもよいし、一体に形成
されてもよい。上記(3)の構成によれば、貯留部に流
水が直接当たるのを、保護カバーによって確実に防止で
き、液体製剤の安定供給と高い芳香効果とを奏すること
ができる。上記(4)の構成によれば、吸液マットの保
護カバーで覆われた箇所が、あたかも貯留部のように機
能するので、少ない部品点数で、液体製剤の安定供給と
高い芳香効果とを奏することができる。The present inventors have developed a holding mat (liquid absorbing mat).
Attention was paid to the liquid retention property (liquid absorption property) of. If the retention mat has low liquid retention, the liquid formulation that has flowed out of the liquid bottle spreads quickly throughout the retention mat (the diffusion speed is high),
Even when flushing is repeated at short time intervals,
Liquid formulations can be supplied in running water. However, the low liquid-retaining property of the holding mat means that it is difficult for the holding mat to hold an effective component such as an aroma component, and such a holding mat cannot exhibit a high aroma effect. on the other hand,
If the holding mat has a high liquid holding property, the liquid preparation cannot be quickly spread over the entire area of the liquid absorbing mat. By setting the liquid retention rate of the holding mat within an appropriate range as in the configuration of (1) above, the liquid preparation can be rapidly spread over the entire area of the holding mat, and a high aroma effect can be achieved. did it. The holding mat may be one that absorbs and holds the liquid formulation (liquid absorbing mat), one that is provided with a number of grooves for holding the liquid on the surface (grooved mat), or liquid It may be provided with micropores for holding (perforated mat). It may be a fiber mat or a pulp mat.
According to the configuration of (2) above, even if the liquid formulation held in the diffusing section is washed away by contacting running water with the diffusing section during flushing, the liquid formulation is held in the storing section, and thus is retained in the storing section. The liquid formulation provided has a high aroma effect. Then, the liquid formulation is quickly supplied from the storage section to the diffusion section where the liquid formulation has been washed away, and the liquid formulation is sufficiently retained in the diffusion section until the next flushing. The storage part and the diffusion part may be formed separately or integrally. According to the configuration of (3) above, it is possible to reliably prevent the running water from directly hitting the storage portion by the protective cover, and to achieve a stable supply of the liquid preparation and a high aroma effect. According to the above configuration (4), since the portion of the liquid-absorbent mat covered with the protective cover functions as if it were a storage portion, a stable supply of the liquid preparation and a high aroma effect can be achieved with a small number of parts. be able to.
【0006】液体ボトルの材質、形状は特に限定され
ず、液体製剤を安定に収容できるものであればよく、そ
の材質として、ポリエステル、ポリエチレンテレフタレ
ート(PET)、ポリプロピレン等を例示できる。液体
ボトルは、液体ボトルに設けられた開口を塞ぐ中栓と、
一端が液体ボトル内に位置するとともに他端が中栓を貫
通して液体ボトル外の吸液マットに接する液体伝達部材
とを備えた構成とすることができる。液体伝達部材とし
ては、ポリプロピレン、ポリアセタール、ナイロン等の
プラスチックからなるものや、ステンレススチール等の
金属からなるものを例示できる。また、繊維集合体から
なる液体伝達部材として、ポリエチレン、ポリプロピレ
ン、ポリエステル、ポリエチレンテレフタレート、人
絹、綿、羊毛等からなるものを例示できる。更に、多孔
質体からなる液体伝達部材として、プラスチックの焼結
成形体、不織布、スポンジ体、金属焼結体、素焼(陶
器、セラミク、レンガ)等からなるものを例示できる。
吸液マットの材質としては、パルプ、レーヨン、ポリエ
ステル、ポリエチレン、ポリプロピレン、PP不織布等
を例示できる。液体製剤としては、例えば、界面活性剤
及び増粘剤、香料、溶剤(水、アルコール、ポリエチレ
ングリコール、ジプロピレングリコール、3−メトキシ
−3−メチルブタノール(商品名ソルフィット クラレ
(株)製)、濃グリセリン)、着色剤等を含むものを採
用でき、更に洗浄、防汚、漂白、撥水、撥油、芳香、消
臭、除菌、防黴、殺菌、忌避、防虫、殺虫等の成分を配
合することができる。上記界面活性剤としては、代表的
にはアニオン系界面活性剤、ノニオン系界面活性剤の少
なくとも一方を挙げることができるが、実施可能なかぎ
りそれらに限定されない。The material and shape of the liquid bottle are not particularly limited as long as it can stably store the liquid preparation, and examples of the material include polyester, polyethylene terephthalate (PET), polypropylene and the like. The liquid bottle has an inner stopper that closes the opening provided in the liquid bottle,
A liquid transmission member having one end located in the liquid bottle and the other end penetrating the inner plug and contacting the liquid absorbing mat outside the liquid bottle can be provided. Examples of the liquid transmission member include those made of plastics such as polypropylene, polyacetal and nylon, and those made of metal such as stainless steel. Examples of the liquid transmission member made of a fiber assembly include those made of polyethylene, polypropylene, polyester, polyethylene terephthalate, human silk, cotton, wool and the like. Further, examples of the liquid transmission member made of a porous body include a sintered body of plastic, a nonwoven fabric, a sponge body, a sintered metal body, unglazed (ceramic, ceramic, brick) and the like.
Examples of the material of the liquid absorbing mat include pulp, rayon, polyester, polyethylene, polypropylene and PP non-woven fabric. As the liquid preparation, for example, a surfactant and a thickener, a fragrance, a solvent (water, alcohol, polyethylene glycol, dipropylene glycol, 3-methoxy-3-methylbutanol (trade name, manufactured by Solfit Kuraray Co., Ltd.), Concentrated glycerin), colorants, etc. can be adopted, and further components such as washing, antifouling, bleaching, water repellent, oil repellent, fragrance, deodorant, disinfectant, mildew, sterilization, repellent, insect repellent, insecticidal It can be blended. Typical examples of the above-mentioned surfactant include at least one of an anionic surfactant and a nonionic surfactant, but the surfactant is not limited thereto as long as it is practicable.
【0007】[0007]
【発明の実施の形態】以下、本発明の実施形態を図面に
基づいて詳しく説明する。図1に示す第1実施形態の液
体供給装置10は、水洗トイレ用貯水タンクの上面
(蓋)に形成された凹状の水受け部91に設置されて使
用される。水受け部91には、貯水タンク内に連通した
注水孔92が設けられている。BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of the present invention will be described below in detail with reference to the drawings. The liquid supply apparatus 10 of the first embodiment shown in FIG. 1 is used by being installed in a concave water receiving portion 91 formed on the upper surface (lid) of the flush toilet water storage tank. The water receiving portion 91 is provided with a water injection hole 92 that communicates with the inside of the water storage tank.
【0008】液体供給装置10は、香料を含む液体製剤
Lを収容した液体ボトル11と、液体ボトル11から流
出した液体製剤Lを吸収して保持する吸液マット14と
を備えている。本実施形態では、有底円筒状の収納部1
5の底壁上に、吸液マット14が設置されている。吸液
マット14は、収納部15の底壁に対応した形状(ここ
では円板状)に形成されるとともにその底壁上に敷かれ
た拡散マット14bと、拡散マット14b上の所定箇所
(ここでは中央部)に敷かれた貯留マット14aとの二
層からなる場合のものを備えている。液体ボトル11
は、収納部15にセットした状態における下部が、上部
より小径の円筒状になっている。液体ボトル11の最下
部には開口が設けられている。その開口は、プラスチッ
クやゴム等の弾性体からなる中栓12によって塞がれて
いる。The liquid supply device 10 comprises a liquid bottle 11 containing a liquid preparation L containing a fragrance, and a liquid absorption mat 14 for absorbing and holding the liquid preparation L flowing out from the liquid bottle 11. In this embodiment, the bottomed cylindrical storage unit 1
The liquid absorbing mat 14 is installed on the bottom wall of No. 5. The liquid-absorbent mat 14 is formed in a shape (here, a disk shape) corresponding to the bottom wall of the storage section 15 and is spread on the bottom wall of the storage mat 15 and at a predetermined position on the diffusion mat 14b (here. Then, it is provided with a two-layered storage mat 14a laid in the central part). Liquid bottle 11
Has a cylindrical shape having a diameter smaller than that of the upper portion when the lower portion is set in the storage portion 15. An opening is provided at the bottom of the liquid bottle 11. The opening is closed by an inner plug 12 made of an elastic material such as plastic or rubber.
【0009】収納部15の周壁の下部には、周方向に間
隔をあけて複数の通水口16が設けられている。収納部
15の底壁にも、通水口(図示せず)が設けられてお
り、その通水口を塞ぐか適度に開口された拡散マット1
4bが敷かれ、更に拡散マット14bの上面に貯留マッ
ト14aが敷かれている。貯留マット14a上に中栓1
2が配置されている。ここでは貯留マット14aが、拡
散マット14bより小さく、かつ、中栓12と同等に又
は中栓12より大きく形成されている。貯留マット14
aは、液体ボトル11の最下部の開口内に嵌め込まれて
いてもよい。A plurality of water passages 16 are provided in the lower portion of the peripheral wall of the storage portion 15 at intervals in the circumferential direction. The bottom wall of the storage portion 15 is also provided with a water passage (not shown), and the diffusion mat 1 with which the water passage is closed or opened appropriately.
4b, and the storage mat 14a is further laid on the upper surface of the diffusion mat 14b. Inner stopper 1 on storage mat 14a
2 are arranged. Here, the storage mat 14a is formed smaller than the diffusion mat 14b and equal to or larger than the inner plug 12. Storage mat 14
The a may be fitted in the opening at the bottom of the liquid bottle 11.
【0010】これに限定されないが、例えば、貯留マッ
ト14aとして、直径25mm、厚み3mmにカットし
た円板状のPP不織布(例えば日本バイリーン(株)製
OR125)を用いることができ、拡散マット14b
として、直径50mm、厚み2mmにカットした円板状
のポリエチレン焼結体(例えばスペイシーケミカル社製
PE70)を用いることができる。このように、貯留
マットの吸液性を、拡散マットの吸液性より高くするこ
とができる。液体ボトル11からの液量が少なく、貯留
マットに保持された液はフラッシングの水で洗い流され
ないので、すみやかに貯留マット14aから拡散マット
14bへ液が供給される。マット素材には、例えば上記
のいずれかを使用できるが、コスト面から不織布を採用
するのが有利である。Although not limited to this, for example, a disc-shaped PP non-woven fabric (for example, OR125 manufactured by Nippon Vilene Co., Ltd.) cut into a diameter of 25 mm and a thickness of 3 mm can be used as the storage mat 14a, and the diffusion mat 14b.
For example, a disc-shaped polyethylene sintered body (for example, PE70 manufactured by Spacey Chemical Co.) cut into a diameter of 50 mm and a thickness of 2 mm can be used. In this way, the liquid absorption of the storage mat can be made higher than that of the diffusion mat. Since the amount of liquid from the liquid bottle 11 is small and the liquid held in the storage mat is not washed away with the flushing water, the liquid is quickly supplied from the storage mat 14a to the diffusion mat 14b. For example, any one of the above can be used as the mat material, but it is advantageous to use a nonwoven fabric from the viewpoint of cost.
【0011】収納部15の底壁の中央部上面には、上方
へ立ち上がって、拡散マット14b、貯留マット14a
及び中栓12を貫通した、中空柱状(ここでは円筒状)
の液体伝達部材18が設けられている。液体伝達部材1
8の上端は、液体ボトル11内の液体製剤Lの液面より
突出している。液体伝達部材18の下端は、その外周面
が吸液マット14に接している。液体伝達部材18の、
中栓12を貫通する部分の外周面には、軸方向に沿った
複数の溝(図示せず)が設けられている。液体ボトル1
1中の液体製剤Lは、それら溝を伝って、吸液マット1
4に供給される。一方、収納部15の底壁の中央部下面
には、水受け部91の注水孔92に挿通されて、液体供
給装置10を水受け部91上で位置決めするための、位
置決め部材19が設けられている。On the upper surface of the central portion of the bottom wall of the storage portion 15, a diffusion mat 14b and a storage mat 14a rise upward.
And a hollow columnar shape (here, cylindrical) that penetrates the inner plug 12
The liquid transmission member 18 is provided. Liquid transmission member 1
The upper end of 8 projects from the liquid surface of the liquid preparation L in the liquid bottle 11. The outer peripheral surface of the lower end of the liquid transmission member 18 is in contact with the liquid absorbent mat 14. Of the liquid transmission member 18,
A plurality of grooves (not shown) along the axial direction are provided on the outer peripheral surface of the portion penetrating the inner plug 12. Liquid bottle 1
The liquid preparation L in 1 travels along the grooves and the liquid absorbing mat 1
4 is supplied. On the other hand, on the lower surface of the central portion of the bottom wall of the storage portion 15, there is provided a positioning member 19 which is inserted into the water injection hole 92 of the water receiving portion 91 to position the liquid supply device 10 on the water receiving portion 91. ing.
【0012】手洗い用の水が水受け部91に供給される
と、流水Wは、通水口16を通じて拡散マット14bに
触れる。拡散マット14bには、液体製剤Lが含浸され
ており、その含浸された液体製剤が、拡散マット14b
に触れた水に混合される。液体製剤を混合された水が、
収納部15の底壁の通水口を通って、注水孔92に流入
する。保持した液体製剤Lを洗い流された拡散マット1
4bには、貯留マット14aから、液体製剤Lが順次供
給される。貯留マット14aには、液体ボトル11から
液体伝達部材18を介して、液体製剤Lが順次供給され
る。When the water for washing hands is supplied to the water receiving portion 91, the running water W contacts the diffusion mat 14b through the water passage port 16. The diffusion matte 14b is impregnated with the liquid preparation L, and the impregnated liquid preparation is used as the diffusion matte 14b.
Is mixed with water that has touched. Water mixed with liquid formulation,
The water flows into the water injection hole 92 through the water passage on the bottom wall of the storage section 15. Diffusion mat 1 from which the retained liquid formulation L was washed away
The liquid formulation L is sequentially supplied to 4b from the storage mat 14a. The liquid formulation L is sequentially supplied to the storage mat 14 a from the liquid bottle 11 via the liquid transmission member 18.
【0013】以上のような構成の液体供給装置10によ
れば、フラッシング時に拡散マット14bに流水Wが接
して拡散マット14bに保持された液体製剤Lが洗い流
されても、貯留マット14aに液体製剤Lが保持されて
いるので、その貯留マット14aに保持された液体製剤
Lにより高い芳香効果が得られる。そして、液体製剤L
を洗い流された拡散マット14bに、貯留マット14a
から液体製剤Lが供給されて、次のフラッシングまでに
は拡散マット14bに液体製剤Lが十分保持される。According to the liquid supply apparatus 10 having the above-described structure, even if the liquid preparation L held on the diffusion mat 14b is washed away by contacting the running water W with the diffusion mat 14b during flushing, the liquid preparation is stored in the storage mat 14a. Since L is held, the liquid formulation L held in the storage mat 14a can obtain a high aroma effect. And liquid formulation L
The storage mat 14a is attached to the diffusion mat 14b that has been washed away.
The liquid preparation L is supplied from, and the liquid preparation L is sufficiently held on the diffusion mat 14b by the next flushing.
【0014】図2に、第2実施形態である液体供給装置
20の要部を示す。なお、以下に説明する実施形態にお
いて、既に説明した部材等と同様な構成・作用を有する
部材等については、図中に同一符号又は相当符号を付す
ことにより説明を簡略化或いは省略する。液体供給装置
20は、液体ボトル11と、中栓12と、液体伝達部材
18と、吸液マット14とを備えている。吸液マット1
4は、拡散マット14bと、拡散マット14bの上に敷
かれた貯留マット14aとからなる。液体伝達部材18
の一端は、拡散マット14b、貯留マット14a及び中
栓12を貫通している。液体供給装置20は、第1実施
形態と同様な収納部を備えてもよい。FIG. 2 shows a main part of the liquid supply apparatus 20 according to the second embodiment. In the embodiments described below, members having the same configurations and functions as those already described are given the same or corresponding symbols in the drawings to simplify or omit the description. The liquid supply device 20 includes a liquid bottle 11, an inner plug 12, a liquid transmission member 18, and a liquid absorbing mat 14. Liquid absorption mat 1
Reference numeral 4 includes a diffusion mat 14b and a storage mat 14a laid on the diffusion mat 14b. Liquid transfer member 18
Has one end penetrating the diffusion mat 14b, the storage mat 14a and the inner plug 12. The liquid supply device 20 may include a storage unit similar to that of the first embodiment.
【0015】液体供給装置20は、更に、貯留マット1
4aの側面を外側から覆う保護カバー21を有してい
る。すなわち貯留マット14aは、側面が保護カバー2
1で覆われており、下面が拡散マット14bの上面に接
している。保護カバー21は、ここでは円筒状に形成さ
れている。The liquid supply device 20 further includes a storage mat 1
It has a protective cover 21 that covers the side surface of 4a from the outside. That is, the side surface of the storage mat 14a is the protective cover 2
1 and the lower surface is in contact with the upper surface of the diffusion mat 14b. The protective cover 21 is formed in a cylindrical shape here.
【0016】以上のような構成の液体供給装置20によ
れば、流水が、拡散マット14b上を流れて貯留マット
14aに直接当たるのを、保護カバー21によって確実
に防止できる。したがって、貯留マット14aにより、
液体製剤の安定供給と高い芳香効果とを奏することがで
きる。According to the liquid supply apparatus 20 having the above-described structure, the protective cover 21 can reliably prevent the flowing water from flowing on the diffusion mat 14b and directly hitting the storage mat 14a. Therefore, by the storage mat 14a,
A stable supply of the liquid preparation and a high aroma effect can be achieved.
【0017】図3に、第3実施形態である液体供給装置
30の要部を示す。液体供給装置30は、液体ボトル1
1と、中栓12と、液体伝達部材18と、保護カバー2
1と、吸液マット34とを備えている。液体供給装置3
0は、第1実施形態と同様な収納部を備えてもよい。本
実施形態における吸液マット34は、一枚のマットであ
り、二枚のマットを重ねた構成になっていない。吸液マ
ット34上面と中栓12下面との間隔は、2mm以下と
することができる。液体伝達部材18の一端は、吸液マ
ット34及び中栓12を貫通している。FIG. 3 shows a main part of the liquid supply apparatus 30 according to the third embodiment. The liquid supply device 30 is a liquid bottle 1.
1, inner plug 12, liquid transmission member 18, and protective cover 2
1 and a liquid absorbing mat 34. Liquid supply device 3
0 may include a storage unit similar to that of the first embodiment. The liquid-absorbent mat 34 in the present embodiment is a single mat and is not configured to have two mats stacked. The distance between the upper surface of the liquid absorbing mat 34 and the lower surface of the inner plug 12 can be set to 2 mm or less. One end of the liquid transmission member 18 penetrates the liquid absorption mat 34 and the inner plug 12.
【0018】本実施形態では、吸液マット34の、保護
カバー21で覆われた部分(以下「貯留部」という。こ
こでは中央部)が、貯留マット的な機能を果たし、保護
カバー21で覆われた部分の外側の部分(以下「拡散
部」という)が、拡散マット的な機能を果たす。すなわ
ち、液体ボトル11から浸出した液体製剤は、先ず吸液
マット34の貯留部に供給される。この貯留部に供給さ
れた液体製剤が、拡散部へと伝わる。フラッシング時に
流水が拡散部に当たると、拡散部に保持された液体製剤
は洗い流される。しかしこの時、貯留部には流水が当た
らないため、貯留部に保持された液体製剤は洗い流され
ない。In the present embodiment, the portion of the liquid absorbent mat 34 covered with the protective cover 21 (hereinafter referred to as "reservoir portion", here, the central portion) functions as a reservoir mat and is covered with the protective cover 21. A portion outside the broken portion (hereinafter referred to as “diffusion portion”) functions as a diffusion mat. That is, the liquid preparation leached from the liquid bottle 11 is first supplied to the storage part of the liquid absorbent mat 34. The liquid formulation supplied to this storage section is transmitted to the diffusion section. When the running water hits the diffusing section during flushing, the liquid formulation held in the diffusing section is washed away. However, at this time, since the reservoir is not hit with running water, the liquid preparation held in the reservoir is not washed away.
【0019】以上のような構成の液体供給装置30によ
れば、少ない部品点数で、液体製剤の安定供給と高い芳
香効果とを奏することができる。According to the liquid supply apparatus 30 having the above-mentioned structure, it is possible to achieve a stable supply of the liquid preparation and a high aroma effect with a small number of parts.
【0020】[第1〜第3実施形態の試験]上記第1〜
第3実施形態の液体供給装置を、水洗トイレ用貯水タン
クの水受け部に設置し、トイレ内の芳香強度の経時変化
を確認した。なお、トイレ室内容積は2m3、トイレ室
内温度は10℃、フラッシング間隔は1回/30分、水
受け部への流水量は1リットル/1回とし、液体製剤と
しては以下の組成のものを用いた。
液体製剤 香料:レモン系香料 10重量部
界面活性剤:ポリオキシエチレン硬化ヒマシ油 20重量部
増粘剤:カルボキシメチルセルロース 適量
(粘度 1900mPa/sに調整)
残り:水[Tests of First to Third Embodiments]
The liquid supply device according to the third embodiment was installed in the water receiving portion of the water storage tank for flush toilets, and changes with time of the fragrance intensity in the toilets were confirmed. The volume of the toilet room is 2 m 3 , the temperature of the toilet room is 10 ° C, the flushing interval is 1/30 minutes, and the amount of water flowing to the water receiving part is 1 liter / once. Using. Liquid preparation Fragrance: Lemon-based fragrance 10 parts by weight Surfactant: Polyoxyethylene hydrogenated castor oil 20 parts by weight Thickener: Carboxymethyl cellulose Suitable amount (viscosity adjusted to 1900 mPa / s) Remaining: water
【0021】試験の結果、第1実施形態によれば、長期
にわたってトイレ内における強い芳香強度を維持するこ
とができた。また、第2実施形態によれば、長期にわた
ってトイレ内における高い芳香強度を維持することがで
きた。第3実施形態によれば、若干芳香強度は弱かった
が、長期にわたって実用に耐えうるレベルの芳香効果を
奏することができた。As a result of the test, according to the first embodiment, it was possible to maintain a strong aroma intensity in the toilet for a long period of time. Moreover, according to 2nd Embodiment, the high fragrance intensity | strength in the toilet was able to be maintained over a long period of time. According to the third embodiment, the fragrance intensity was slightly weak, but the fragrance effect of a level that could be practically used for a long period of time could be obtained.
【0022】比較のため、マット及び保護カバーを有し
ない形態(上記第3実施形態から保護カバーを取り除い
た形態)について、同様な試験を行ったところ、芳香強
度が弱く、実用に耐えうるレベルの芳香効果を奏するこ
とができなかった。For comparison, a similar test was carried out on a form having no mat and no protective cover (a form in which the protective cover is removed from the third embodiment), and as a result, the fragrance strength was weak and the practicable level was obtained. The scent effect could not be achieved.
【0023】次に、本発明の第4実施形態について説明
する。第4実施形態である液体供給装置は、吸液マット
の吸液率(保持量)を所定範囲内にしたものである。そ
の他の構成は、例えば、第3実施形態と同様とすること
ができる。本実施形態では、吸液マットの吸液率(保持
量)を、0.1〜0.9g/cm 3、かつ、0.01〜
0.2g/cm2とする。すなわち、吸液マットの体積
1cm3(1cc)あたり0.1〜0.9gの液体を吸
液(保持)でき、表面積1cm2あたり0.01〜0.
2gの液体を吸液(保持)できるるようにする。Next, a fourth embodiment of the present invention will be described.
To do. The liquid supply device according to the fourth embodiment is a liquid absorbing mat.
The liquid absorption rate (holding amount) of is within a predetermined range. So
Other configurations are the same as those in the third embodiment, for example.
You can In the present embodiment, the liquid absorption rate (retention
Amount), 0.1 to 0.9 g / cm 3And 0.01 to
0.2 g / cm2And That is, the volume of the absorbent mat
1 cm3Suction 0.1 to 0.9g of liquid per (1cc)
Liquid (holding) possible, surface area 1 cm2Per 0.01 to 0.
It should be able to absorb (hold) 2 g of liquid.
【0024】例えば、市販の室内用芳香器に使用されて
いる吸液マット(吸液率(保持量)0.9g/cm3か
つ0.45g/cm2、マット厚み5mm)を、液体供
給装置に用いると、拡散速度が遅く、かつ、フラッシン
グ時に水を多く吸収するので芳香強度が十分でなくな
る。しかし、同じ材質の吸液マットを、マット厚み2m
m、吸液率0.18g/cm2にして使用すると、拡散
性及び芳香強度が著しく改善される。なお、吸液マット
の吸液率(保持量)を、0.26〜0.79g/cm3
とし、0.03〜0.12g/cm2とすることがより
好ましい。For example, a liquid-absorbing mat used in a commercially available indoor aroma machine (liquid absorption rate (holding amount) 0.9 g / cm 3 and 0.45 g / cm 2 , mat thickness 5 mm) is supplied to a liquid supply device. When used for, the diffusion rate is slow, and a large amount of water is absorbed during flushing, so that the fragrance strength becomes insufficient. However, a liquid-absorbent mat made of the same material, with a mat thickness of 2 m
m, when used in the liquid absorption rate 0.18 g / cm 2, diffusivity and fragrance strength are significantly improved. In addition, the liquid absorption rate (holding amount) of the liquid absorbing mat is 0.26 to 0.79 g / cm 3.
And more preferably 0.03 to 0.12 g / cm 2 .
【0025】[第4実施形態の試験]表1に示すような
7種類の吸液マットを用意した。各吸液マットは、直径
50mmの円板状にカットした。各吸液マットの吸液率
(保持量)は、各吸液マットに十分に水を含ませ、その
重量変化から求めた。次に、少量の界面活性剤を含んだ
水道水を、各吸液マットに十分に含ませた。その後、下
記試験液を、できるだけ液が広がらないように、マット
の中心に、シリンジを用いて200mg滴下した。
試験液 香料:レモン系香料 10重量部
界面活性剤:ポリオキシエチレン硬化ヒマシ油 20重量部
増粘剤:カルボキシメチルセルロース 適量
(粘度 2000mPa/sに調整)
残り:水[Test of Fourth Embodiment] Seven kinds of liquid absorbing mats as shown in Table 1 were prepared. Each liquid absorbing mat was cut into a disk shape having a diameter of 50 mm. The liquid absorption rate (retention amount) of each liquid absorbing mat was obtained from the weight change of each liquid absorbing mat, which was made to sufficiently contain water. Next, tap water containing a small amount of a surfactant was sufficiently included in each absorbent mat. Then, 200 mg of the following test solution was dropped on the center of the mat using a syringe so that the solution did not spread as much as possible. Test liquid Fragrance: Lemon-based fragrance 10 parts by weight Surfactant: Polyoxyethylene hydrogenated castor oil 20 parts by weight Thickener: Carboxymethyl cellulose Appropriate amount (viscosity adjusted to 2000 mPa / s) Remaining: water
【0026】[0026]
【表1】 [Table 1]
【0027】各吸液マットを、直径100mmのプラス
チックシャーレ上に置き、室内の温度を20℃にコント
ロールしたボックス(幅1000mm、奥行き2000
mm、高さ1900mm)に、それらシャーレを置い
た。そして、30分後に、10名の試験員によって芳香
強度を評価した。評価は、5点:強い、4点:やや強
い、3点:普通、2点:やや弱い、1点:弱い、という
5段階で行った。評価結果を、表1の「芳香強度」の欄
に示す。すべての吸液マットが、十分な芳香強度のレベ
ルである3点を上回った。Each liquid absorbing mat was placed on a plastic petri dish having a diameter of 100 mm, and a box in which the temperature inside the room was controlled at 20 ° C. (width 1000 mm, depth 2000)
mm, height 1900 mm), the petri dishes were placed. Then, 30 minutes later, the aroma intensity was evaluated by 10 testers. The evaluation was carried out on a scale of 5: 5 points: strong, 4 points: slightly strong, 3 points: normal, 2 points: slightly weak, 1 point: weak. The evaluation results are shown in the column of "fragrance strength" in Table 1. All the absorbent mats were above the level of sufficient fragrance intensity of 3 points.
【0028】比較のため、表2に示すような2種類の吸
液マットを用意し、同様な試験を行った。すると、表2
の「芳香強度」の欄に示すように、これらでは芳香強度
が弱く、実用レベルに達しなかった。For comparison, two kinds of absorbent mats as shown in Table 2 were prepared and the same test was conducted. Then, Table 2
As shown in the column of "Aroma intensity" in Table 1, these compounds had weak aroma intensity and did not reach the practical level.
【0029】[0029]
【表2】 [Table 2]
【0030】なお、本発明は、前述した実施形態に限定
されるものではなく、適宜な変形、改良等が可能であ
る。例えば、上記実施形態を組み合わせた構成にするこ
ともできる。例えば、貯留マットを液体ボトルの開口内
に嵌め込むことで、液体ボトルの開口付近の箇所を保護
カバーとして機能させることもできる。本発明は、トイ
レボウル内に吊り下げられるタイプの液体供給装置にも
適用できる。The present invention is not limited to the above-described embodiment, but can be appropriately modified and improved. For example, a configuration in which the above-described embodiments are combined can be adopted. For example, by fitting the storage mat into the opening of the liquid bottle, a portion near the opening of the liquid bottle can function as a protective cover. The present invention can also be applied to a liquid supply device of the type that is suspended in a toilet bowl.
【0031】[0031]
【発明の効果】以上説明したように、本発明によれば、
液体製剤を長期にわたって安定供給でき、高い芳香効果
を奏する液体供給装置を提供できる。As described above, according to the present invention,
It is possible to provide a liquid supply device capable of stably supplying a liquid preparation for a long period of time and exhibiting a high aroma effect.
【図1】本発明の第1実施形態を示す概略斜視図であ
る。FIG. 1 is a schematic perspective view showing a first embodiment of the present invention.
【図2】本発明の第2実施形態を示す要部斜視図であ
る。FIG. 2 is a main part perspective view showing a second embodiment of the present invention.
【図3】本発明の第3実施形態を示す要部斜視図であ
る。FIG. 3 is a perspective view of an essential part showing a third embodiment of the present invention.
10,20,30 液体供給装置 11 液体ボトル 12 栓 14,34 吸液マット 14a 貯留マット 14b 拡散マット 10, 20, 30 Liquid supply device 11 liquid bottles 12 stoppers 14,34 Liquid absorption mat 14a Storage mat 14b diffusion mat
───────────────────────────────────────────────────── フロントページの続き (72)発明者 松井 敏也 兵庫県赤穂市塩屋2124−4 (72)発明者 新井 康子 兵庫県赤穂市坂越3150 Fターム(参考) 2D038 BA12 3E082 AA01 BB10 DD20 ─────────────────────────────────────────────────── ─── Continued front page (72) Inventor Toshiya Matsui 2124-4 Shioya, Ako City, Hyogo Prefecture (72) Inventor Yasuko Arai 3150 Sakakoshi, Ako City, Hyogo Prefecture F-term (reference) 2D038 BA12 3E082 AA01 BB10 DD20
Claims (4)
液体ボトルから流出した液体製剤を保持する保持マット
とを有し、前記保持マットの液保持率が、0.1〜0.
9g/cm3であり、かつ、0.01〜0.2g/cm2
であることを特徴とする液体供給装置。1. A liquid bottle containing a liquid preparation, and a holding mat for holding the liquid preparation flowing out of the liquid bottle, wherein the holding mat has a liquid holding ratio of 0.1 to 0.
9 g / cm 3 and 0.01 to 0.2 g / cm 2
Is a liquid supply device.
液体ボトルから流出した液体製剤を吸収して保持する吸
液マットとを有し、前記吸液マットが、前記液体ボトル
からの液体製剤を最初に吸収保持する貯留部と、前記貯
留部から液体製剤が伝達される拡散部とを有し、前記拡
散部に流水が接するように構成されていることを特徴と
する液体供給装置。2. A liquid bottle containing a liquid preparation, and a liquid-absorbing mat that absorbs and holds the liquid preparation flowing out from the liquid bottle, wherein the liquid-absorbing mat stores the liquid preparation from the liquid bottle. A liquid supply device comprising: a storage part that first absorbs and holds the liquid preparation; and a diffusion part to which the liquid preparation is transferred from the storage part, and the running water is in contact with the diffusion part.
おり、前記貯留部の側面が保護カバーで覆われている請
求項2に記載の液体供給装置。3. The liquid supply apparatus according to claim 2, wherein a lower surface of the storage section is in contact with the diffusion section, and a side surface of the storage section is covered with a protective cover.
液体ボトルから流出した液体製剤を吸収して保持する吸
液マットとを有し、前記吸液マットの所定箇所が保護カ
バーで覆われており、前記吸液マットの前記保護カバー
で覆われた箇所に前記液体ボトルからの液体製剤が最初
に供給されることを特徴とする液体供給装置。4. A liquid bottle containing a liquid preparation, and a liquid-absorbing mat that absorbs and holds the liquid preparation flowing out from the liquid bottle, and a predetermined portion of the liquid-absorbing mat is covered with a protective cover. The liquid supply device is characterized in that the liquid preparation from the liquid bottle is first supplied to a portion of the liquid absorption mat covered with the protective cover.
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JP2001229687A JP4535649B2 (en) | 2001-07-30 | 2001-07-30 | Liquid supply device |
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JP2001229687A JP4535649B2 (en) | 2001-07-30 | 2001-07-30 | Liquid supply device |
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JP2003040399A true JP2003040399A (en) | 2003-02-13 |
JP4535649B2 JP4535649B2 (en) | 2010-09-01 |
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JP2001229687A Expired - Fee Related JP4535649B2 (en) | 2001-07-30 | 2001-07-30 | Liquid supply device |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013028960A (en) * | 2011-07-28 | 2013-02-07 | Yoshino Kogyosho Co Ltd | Liquid medicine extractor |
JP6360651B1 (en) * | 2018-03-31 | 2018-07-18 | 村上 豊 | Impregnated body for drug supply device and drug supply device using the same |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02121034U (en) * | 1989-03-16 | 1990-10-01 | ||
JP2000314169A (en) * | 1999-04-19 | 2000-11-14 | Sara Lee De Nv | Cleaning/freshening apparatus intended to be hung from rim of toilet stool |
JP2002146879A (en) * | 2000-11-10 | 2002-05-22 | T Hasegawa Co Ltd | On-tank type chemical feeding device |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02229333A (en) * | 1989-03-01 | 1990-09-12 | Kao Corp | Liquid fragrant cleaner device for on-tank type flush toilet |
-
2001
- 2001-07-30 JP JP2001229687A patent/JP4535649B2/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02121034U (en) * | 1989-03-16 | 1990-10-01 | ||
JP2000314169A (en) * | 1999-04-19 | 2000-11-14 | Sara Lee De Nv | Cleaning/freshening apparatus intended to be hung from rim of toilet stool |
JP2002146879A (en) * | 2000-11-10 | 2002-05-22 | T Hasegawa Co Ltd | On-tank type chemical feeding device |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013028960A (en) * | 2011-07-28 | 2013-02-07 | Yoshino Kogyosho Co Ltd | Liquid medicine extractor |
JP6360651B1 (en) * | 2018-03-31 | 2018-07-18 | 村上 豊 | Impregnated body for drug supply device and drug supply device using the same |
JP2019183384A (en) * | 2018-03-31 | 2019-10-24 | 村上 豊 | Impregnation body for chemical supply tool and chemical supply tool using the same |
Also Published As
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JP4535649B2 (en) | 2010-09-01 |
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