JP2003034798A - Deodorizing/washing agent and method for manufacturing the same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To render water usable as a washing/deodorizing agent by imparting it a decomposition ability. SOLUTION: This invention relates to using as the detergent and deodorant a substance that dissociates sulfate ions that are made to memorize the feeble energy emitted from feeble energy sources such as light and minerals. The above substance that dissociates the sulfate ions is added to water or a substance containing water to make the washing/deodorizing agent of the invention, or is used as the above agent without being added to water.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a deodorant / detergent and a method for producing the same.

[0002]

2. Description of the Related Art Conventionally, a surfactant has been mainly used as a cleaning agent, but the waste liquid thereof is a cause of polluting rivers. In addition, domestic drainage and industrial wastewater pollute rivers and cause a bad smell. Wastewater from food factories and the food service industry is a great source of nutrients for bacteria and produces hydrogen sulfide odor and ammonia odor. As countermeasures for these problems, there are effluent purification using microorganisms and enzymes, malodorous adsorption using zeolite and ceramics, or detergents using enzymes to reduce the amount of surfactant.

[0003]

In the conventional known technique, although a method of using a weak energy body such as minerals and charcoal is also well known, the weak energy body is directly administered to drainage or a bad odor, and a weak energy body is applied. It is no exaggeration to say that the treatment is based on the adsorption capacity of these substances rather than the utilization of the effect of. An object of the present invention is to allow water to have a decomposing ability so that it can be used as a cleaning / deodorant.

[0004]

The present invention uses, as a cleaning agent and a deodorant, a substance that dissociates sulfate ions that store weak energy emitted from a weak energy source such as light and minerals. The substance that dissociates the sulfate ion may be added to water or a substance containing water to be used as the cleaning / deodorant of the present invention, or may be used as the cleaning / deodorant without being added to water.

According to the method of the present invention, a cleaning / deodorant is obtained by storing a weak energy emitted from a weak energy source such as light or minerals in a substance which dissociates sulfate ions. The substance that dissociates the sulfate ion may be added to a substance containing water or water to store weak energy, and a method to store weak energy without adding to water. The invention of claim 3 is to add to water, and a substance which dissociates sulfate ions is added to water,
By immersing a substance that emits weak energy therein, the substance that dissociates the sulfate ions stores the weak energy. According to the invention of claim 4, which is not added to water, the substance which dissociates the sulfate ion is arranged close to the substance which emits the weak energy, and the visible light is emitted to the substance which dissociates the sulfate ion and the substance which emits the weak energy. A weak energy is stored in the substance that dissociates the sulfate ion by irradiation. The visible light is most preferably orange having an oxidative resolution, but white light may be used.

As the substance that dissociates the sulfate ion,
Although sodium sulfate and other substances that dissociate sulfate ions can be used as appropriate, sodium sulfate is preferred as the sulfate ion dissociation substance because sodium ions also have the effect of promoting oxidative decomposition. It has also been found that the combination of sulfate ion, hydrogen carbonate ion and carbonic acid improves the oxidative decomposition ability and cleaning (claim 4).
A method of mixing sodium sulfate and sodium bicarbonate, bubbling carbon dioxide gas into a solution containing sodium sulfate, adding carbonated water, or the like is preferable. As the weak energy source, tourmaline ore, granite, minerals such as barite, minerals, ceramics and bamboo charcoal made from rock,
Use Bincho charcoal. Far infrared radiation emissivity at 25 ℃ is 90
Far-infrared radiator of more than% is desirable as a weak energy source. In addition, visible light of orange to yellow of about 0.65 to 0.55 μ is also suitable as the weak energy source.

When the substance that dissociates the sulfate ion is added to water or a substance containing water, the sulfate ion is adjusted to 1 ppm or more, preferably 20 ppm or more. Since the water used may contain a substance that inhibits oxidative decomposition such as calcium ions, it is desirable to deionize and soften the water with an ion exchange membrane or the like. Water having a sulfidizing function can be obtained by storing weak energy in a substance that dissociates sulfate ions such as sodium sulfate or the like prepared as described above by irradiation or other means.

[0008]

The cleaning / deodorant of the present invention has an oxidative decomposing ability, has a function of removing stains on clothes, promotes oxidative decomposition of odors such as sulfides, and enables deodorization of odors. That is, the cleaning / deodorant of the present invention can be used in place of the surfactant, and reduces the use of the surfactant. As a result, it is possible to purify wastewater without using a special substance such as an enzyme, an adsorbent, an adsorption catalyst, or the like, or to delay consumption of the adsorbed substance. Especially for washing clothes, 0.1 to 1 g / min of inorganic salt obtained by adding 1 to 10% of sodium sulfate to sodium bicarbonate and irradiating weak energy emitted from weak energy sources such as light and minerals It was found that the amount of the surfactant used was reduced to 50% or less by adding about 1 to the soft water. Further, by adding 1 to 10% of sodium sulfate to sodium bicarbonate and adding 0.01 to 0.1% of powders of minerals such as granite, barley stone and tourmaline, soft water is added to obtain a surfactant. It has been found that the amount of use of is reduced to 50% or less. As shown in the table, the water produced by this invention was confirmed to have cleaning and deodorizing effects. In addition, the cleaning effect is better than sodium sulfate alone,
It can be seen that it improves in the presence of carbon dioxide.

[0009]

EXAMPLES The table shows the results of the following experiments.
Using 1 L of water obtained by the method shown in the following Examples and Comparative Examples, a 10 cm square gauze with stain and odor was stirred at a water temperature of 25 ° C. for 60 minutes to conduct a washing test. In addition, the obtained water was subjected to wave measurement in the items of jejunal mucosa and intestinal indigenous bacteria. The jejunal eardrum is an index of water penetration and absorption,
Intestinal bacteria are indicators of oxidative degradation. Number is +10
If it is above, it is shown that those effects are remarkable. (Examples 1 to 5) To 1 L of non-ionized water obtained by treating tap water with an anion exchange membrane and a cation exchange membrane, sodium sulfate 1 to 80 mg (ion concentration 0.6 ppm to 50 ppm) was added, and Brazilian tourmaline ore 20 g Was immersed for 3 hours. (Comparative Example 1) Tap water was treated with an anion exchange membrane and a cation exchange membrane to obtain non-ionized water. (Comparative Examples 2 to 6) 1 to 80 mg of sodium sulfate was added to 1 L of non-ionized water obtained by treating tap water with an anion exchange membrane and a cation exchange membrane. Comparative Example 7 20 g of Brazilian tourmaline ore was immersed in 1 L of non-ionized water obtained by treating tap water with an anion exchange membrane and a cation exchange membrane for 3 hours. (Examples 6 to 10) Sodium sulfate was spread on a tourmaline plate and left for 1 hour to 3 days. 40 mg (ion concentration 25 ppm) of the sodium sulfate was added to 1 L of non-ionized water treated with tap water and anion exchange membrane. (Example 11) Sodium sulfate is spread on a tourmaline board,
For one hour, a white light bulb was used as a light source, and visible light transmitted through an orange transparent film was irradiated. 40 mg of the sodium sulfate was added to 1 L of non-ionized water obtained by treating tap water with an anion exchange membrane and a cation exchange membrane (ion concentration: 25 p
pm) was added. (Example 12) Tap water was treated with an anion exchange membrane and a cation exchange membrane.
g (ion concentration 25 ppm) was added, and 20 g of Brazilian tourmaline ore was immersed in carbon dioxide gas and bubbling for 3 hours. (Examples 13 to 15) Sodium sulfate 1 to 10 in baking soda.
% Of the inorganic salt was spread on a tourmaline plate, and for one hour, a white light bulb was used as a light source and a visible light source transmitted through an orange transparent film was irradiated. 1 L of non-ionized water obtained by treating the inorganic salt with tap water using an anion exchange membrane and a cation exchange membrane
0.3 g (ion concentration 2 to 20 ppm) was added. Experiment 1 Gauze experiment with stain with ketchup 2 Gauze experiment with stain soaked with coffee 3 Gauze with smell of hydrogen sulfide The stain and smell of each gauze were confirmed.

[Table 1]

Table 2 shows the results of the following experiments. 50 mg of the inorganic salt obtained by the method shown in the following Examples and Comparative Examples was added to 1 L of non-ionized water treated with anion / cation exchange membrane, and the obtained water was added to the jejunal mucosa
Wave measurement was performed on the item of intestinal indigenous bacteria. Comparing Examples 16 to 19 with Comparative Examples 8 to 11, the effect of the weak energy treatment is remarkable. Further, the effect of sulfate ion can be understood by comparing the example with Comparative example 12 containing no sulfate ion. (Example 16) Spreading sodium sulfate on a tourmaline board,
It was left for 24 hours. (Example 17) Spreading potassium sulfate on a tourmaline board, 2
It was left for 4 hours. (Example 18) An inorganic salt prepared by adding 5% (by weight) of sodium sulfate to sodium bicarbonate was spread on a tourmaline plate and left for 24 hours. (Example 19) 5% sodium sulfate to sodium carbonate
(Weight) The added inorganic salt was spread on a tourmaline plate and left for 24 hours. (Comparative Example 8) Sodium sulfate not treated with weak energy. (Comparative Example 9) Potassium sulfate untreated with weak energy. (Comparative Example 10) 5% (by weight) of sodium sulfate was added to sodium bicarbonate. Weak energy untreated. (Comparative Example 11) 5% sodium sulfate in sodium carbonate
(Weight) Added inorganic salt. Weak energy untreated. (Comparative Example 12) Sodium chloride is spread on a tourmaline plate,
It was left for 24 hours.

[Table 2]

Claims (5)

[Claims] 1. A deodorizing / cleaning agent comprising a substance capable of dissociating sulfate ions in which weak energy is stored. 2. A method for producing a deodorant / detergent, which comprises storing weak energy in a substance that dissociates sulfate ions. 3. A substance which dissociates sulfate ions is added to water, and a substance which emits weak energy is immersed in the water to store weak energy in the substance which dissociates sulfate ions. , Deodorant / cleaning agent manufacturing method 4. The method for producing a deodorizing / detergent according to claim 3, wherein hydrogen carbonate ion or carbonic acid is added to water. 5. A substance which dissociates sulfate ions is disposed in the vicinity of a substance which emits weak energy, and the substance which dissociates sulfate ions and the substance which emits weak energy are irradiated with visible light to thereby remove the sulfate ions. Characterized by storing weak energy in a substance that dissociates,
Deodorant / cleaning agent manufacturing method