JP2002521410A - Transparent hair conditioning composition containing fragile visible particles - Google Patents

Abstract

  (57) [Summary] A hair conditioning composition is disclosed, comprising: (1) fragile visible particles; (2) a silicone compound; and (3) an aqueous carrier; wherein the composition is transparent.

Description

DETAILED DESCRIPTION OF THE INVENTION

TECHNICAL FIELD The present invention relates to transparent hair conditioning compositions containing fragile visible particles.

[Background] [0002] Human hair is gradually stained due to contact with the surrounding environment and sebum secreted from the scalp. When the hair becomes dirty, the hair becomes dirty or greasy and becomes unattractive. Hair stains must be shampooed regularly.

[0003] Shampoos cleanse hair by removing excess dirt and sebum.
However, shampoos can leave hair moist, tangled and generally intractable. Once the hair dries, the hair often remains moist, rough, dull, or crumpled because the natural oils and other natural conditioning and moisturizing components of the hair are removed. . Hair also has an increased static value as it dries, and this static electricity prevents combing, resulting in what is commonly referred to as "jumping hair" or, especially, for long hair, is undesirable. It can contribute to the "split hair" phenomenon.

[0004] Various attempts have been made to alleviate these post-shampooing problems.
These attempts include leave-on products and rinse-off products.
It ranges from post-shampooing applications of hair conditioners, such as products, to hair conditioning shampoos, which attempt to both wash and condition with a single product. While some consumers prefer the ease and convenience of a shampoo that includes a conditioner, a significant percentage of consumers apply it to their hair as a separate step, usually following the shampoo. They prefer more conventional conditioner formulations. Consumers who prefer conventional conditioner formulations value the relatively higher conditioning effectiveness or convenience of varying the amount of conditioning depending on the condition of the hair or the part of the hair.

[0005] Conditioning formulations can be in the form of leave-on or rinse-off products, and can be in the form of emulsions, creams, gels, sprays and mousses. Products in the form of creams, gels and mousses are suitable because consumers can easily adjust the quantity and distribution of the product. For this reason, these products are particularly suitable for leave-on products.

[0006] Leave-on products with aesthetic benefits are preferred by consumers. Transparent or almost transparent products containing clearly visible particles are particularly preferred for aesthetics. However, while conventional leave-on products provide good conditioning and feel to the hair and hands in use, they are not entirely satisfactory in providing such aesthetic effects.

[0007] Based on the foregoing, it provides the hair with favorable aesthetic benefits, improved conditioning benefits such as smoothness, softness and reduced friction, is easy to apply to the hair, and cleans the hair and hands. There remains a desire to provide hair conditioning compositions suitable for leave-on formulations that leave a pleasant feel. None of the current technologies offer the advantages or benefits of the present invention.

SUMMARY The present invention is directed to a hair conditioning composition comprising: (1) fragile visible particles; (2) a silicone compound; and (3) an aqueous carrier, and wherein the composition is transparent. It is. These and other features, aspects and advantages of the present invention will become apparent to those skilled in the art from reading the present disclosure.

DETAILED DESCRIPTION While the specification concludes with claims particularly pointing out and distinctly claiming the invention, it is believed that the present invention will be better understood from the following description. Conceivable. All references cited are incorporated herein by reference in their entirety.
Citation of any reference is not an admission of prior art decisions regarding the claimed invention.

As used herein, “comprising” means that other steps and other ingredients which do not affect the end result can be added. This term uses the term "
And "consisting essentially of." All percentages, parts and ratios are based on the total weight of the composition of the present invention, unless otherwise specified. When such weights relate to the indicated ingredients, they are all based on the activity value and, therefore, these weights may be contained in carriers or commercially available materials Contains no by-products.

[0011] The above aspects and embodiments of the invention described herein have a number of advantages. For example, the hair conditioning compositions of the present invention: provide improved conditioning benefits to hair, such as, for example, favorable aesthetic benefits, smoothness, softness and reduced friction, are easy to apply to hair, and Leaves a clean feel on hair and hands.

Fragile Visible Particles The composition of the present invention comprises fragile visible particles. By definition, fragile visible particles are particles that are clearly detectable by the naked eye as individual particles when included in the compositions of the invention and are stable in the compositions of the invention, but are fragile in use. It is. As long as these fragile visible particles are clearly detected as individual particles by the naked eye,
It can be of any size, color or shape according to the desired characteristics of the product.
Generally, the fragile visible particles are from about 50 μm to about 3000 μm, preferably about 1 μm.
It has an average diameter of from 00 μm to about 1000 μm, more preferably from about 300 μm to about 1000 μm. Stable means that these fragile visible particles do not collapse, agglomerate or separate under normal storage conditions.
Fragile means that the fragile visible particles can be broken down with very little shear in use with the fingers of the hand.

The fragile visible particles of the present invention are at a level that provides a composition with favorable aesthetic benefits, typically up to about 10% of the composition weight, and preferably according to the desired characteristics of the product, About 0.01% to about 5% is used.

The fragile visible particles in the present invention include structural materials, and preferably encapsulated materials. Structural materials provide a specific strength to the visible particles, allowing them to retain a clearly detectable structure in the compositions of the invention under normal storage conditions, while using very little shear with the fingers of the hand during use. Can be broken or collapsed.

[0015] The structural material comprises a component selected from the group consisting of polysaccharides and their derivatives, sugars and their derivatives, oligosaccharides, monosaccharides, and mixtures thereof. Preferably, components having different water solubilities are selected from the above-mentioned groups to make up the structural material. More preferably, the structural material comprises a component selected from the group consisting of cellulose, cellulose derivatives, sugars, and mixtures thereof. More preferably, the structural material comprises a mixture of cellulose, cellulose derivatives, and sugar.

Components useful for making the structural materials include: crystalline cellulose, cellulose acetate, cellulose acetate butyrate, cellulose acetate phthalate, cellulose nitrate, ethyl cellulose, hydroxypropyl cellulose,
Hydroxypropylmethylcellulose, hydroxypropylmethylcellulose phthalate, methylcellulose, sodium carboxymethylcellulose, acacia gum (gum arabic), agar, agarose, maltodextrin, sodium alginate, calcium alginate, dextran, starch, galactose,
Glucosamine, cyclodextrin, chitin, amylose, amylopectin, glycogen, laminaran, lichenan, curdlan, inulin, levan, pectin, mannan, xylan, alginic acid, arabic acid, glucomannan, agarose, agaropectin, profilan, carrageen, Polysaccharides and sugar derivatives such as fucoidan, glucosaminoglycan, hyaluronic acid, chondroitin, peptidoglycan, lipopolysaccharide, guar gum, starch, and starch derivatives; sucrose, lactose, maltose, uronic acid, muramic acid, cellobiose, isomaltose Oligopolysaccharides such as, planteose, melezitose, gentianose, maltotriose, stachyose, glucoside and polyglucoside; glucose, fructo And monosaccharides such as mannose. Components that may further be included in the structural material include polyacrylamide, poly (alkyl cyanoacrylate), and poly (ethylene-vinyl acetate), and carboxyvinyl polymers, polyamides, poly (methyl vinyl ether-maleic anhydride), Poly (adipyl-L-lysine), polycarbonate, polyterephthalamide, polyvinyl acetate phthalate, poly (terephthaloyl-L-lysine), polyarylsulfone, poly (methyl methacrylate), poly (ε-caprolactone), polyvinylpyrrolidone, polydimethyl Siloxane, polyoxyethylene, polyester, polyglycolic acid, polybutyric acid, polyglutamic acid, polylysine, polystyrene, poly (styrene-acrylonitrile), polyimide, and poly (vinyla And synthetic polymers such as acrylic polymers and copolymers, including fats, fatty acids, fatty alcohols, milk solids, molasses, gelatin, gluten, albumin, shellac, caseinate, beeswax, carnauba wax, spermaceti, hydrogenated tallow. Other substances such as glycerol, monopalmitate, glycerol dipalmitate, hydrogenated castor oil, glycerol monostearate, glycerol distearate, glycerol tristearate, 12-hydroxystearyl alcohol, proteins, and protein derivatives;
And mixtures thereof. The components in the present invention may be described in other sections as useful components of the composition of the present invention. However,
The components in the present invention are substantially used to produce fragile visible particle structures and are not substantially dissolved in the bulk of the composition of the present invention under normal storage conditions .

The fragile visible particles in the present invention may include, contain, or be filled with an inclusion material. Such inclusion materials may be water-soluble or water-insoluble and may include the following components: vitamins, amino acids, proteins and protein derivatives, herbal extracts, pigments, dyes, antibacterial agents, chelating agents. UV absorbers, optical brighteners, silicone compounds, fragrances, generally water-soluble wetting agents, generally water-insoluble additional conditioning agents and mixtures thereof. In some embodiments, water-soluble components are preferred encapsulating materials. In another embodiment, a component selected from the group consisting of vitamins, amino acids, proteins, protein derivatives, herbal extracts and mixtures thereof is a preferred inclusion material. In yet another embodiment, a preferred inclusion material is a component selected from the group consisting of vitamin E, pantothenyl ethyl ether, panthenol, turd extract, and mixtures thereof.

The vitamins and amino acids useful as inclusion substances in the present invention include: water-soluble, such as vitamins B1, B2, B6, B12, C, pantothenic acid, pantothenyl ethyl ether, panthenol, biotin, and derivatives thereof. Water-soluble amino acids such as vitamins, asparagine, alanine, indole, glutamic acid and salts thereof; water-insoluble vitamins such as vitamins A, D, E, and derivatives thereof; and water-insoluble amino acids such as tyrosine, tryptoamine and salts thereof. No.

Pigments useful as inclusion substances in the present invention include inorganic, nitroso, monoazo,
Including diazo, carotenoid, triphenylmethane, triarylmethane, xanthene, quinoline, oxazine, azine, anthraquinone, indicoid, thione indicoid, quinacridone, phthalocyanine, plant natural pigments, including: Sexual components such as the following C.I. I. Names: acidic red 18, 26, 27, 33, 51, 52, 87, 88, 92, 94, 95, acidic yellow 1, 3, 11, 23, 36, 40, 73, edible yellow 3, edible Green 3, food blue 2,
Food red 1,6, acidic blue 5,9,74, pigment red 57-1,53 (Na), basic purple 10, solvent red 49, acidic orange 7,20,24, acidic green 1,3,5, 25, solvent green 7
, Acidic purple 9, 43; water-insoluble constituents such as the following C.I. I. Named: Pigment Red 53 (Ba), 49 (Na), 49 (Ca), 49 (Ba), 49 (Sr)
, 57, solvent red 23, 24, 43, 48, 72, 73, solvent orange 2, 7, pigment red 4
, 24, 48, 63 (Ca) 3, 64, vat red 1, vat blue 1, 6, pigment orange 1
5, 13, solvent yellow 5, 6, 33, pigment yellow 1, 12, solvent green 3, solvent purple 13, solvent blue 63, pigment blue 15, titanium dioxide, chlorophyllin copper complex, ultramarine, aluminum powder, bentonite , Calcium carbonate, barium sulfate, bismuthine, calcium sulfate, carbon black, bone char, chromate, cobalt blue, gold, iron oxide, hydrous iron oxide, ferrocyanide, magnesium carbonate, manganese phosphate, silver, and zinc oxide.

Antibacterial agents useful as encapsulating substances include those useful as cosmetic biocides and antidandruff agents, including: water-soluble components such as pyrocton olamine; Water-insoluble components such as 3,4,4'-trichlorocarbanilide (triclosan), triclocarban and zinc pyrithione.

Chelating agents useful as encapsulating materials include: 2,2′-
Dipyridylamine; 1,10-phenanthroline {o-phenanthroline}; di-
2-pyridyl ketone; 2,3-bis (2-pyridyl) pyrazine; 2,3-bis (2
-Pyridyl) -5,6-dihydropyrazine; 1,1'-carbonyldiimidazole; 2,4-bis (5,6-diphenyl-1,2,4-triazin-3-yl) pyridine; 6-tri (2-pyridyl) -1,3,5-triazine; 4,4
'-Dimethyl-2,2'-dipyridyl;2,2'-biquinoline; di-2-pyridylglyoxal {2,2'-pyridyl}; 2- (2-pyridyl) benzimidazole; 2,2'- Bipyrazine; 3- (2-pyridyl) 5,6-diphenyl-1,2,2
4-tolazine; 3- (4-phenyl-2-pyridyl) -5-phenyl-1,2,2
4-triazine; 3- (4-phenyl-2-pyridyl) -5,6-diphenyl-
1,2,4-triazine; 2,3,5,6-tetrakis- (2′-pyridyl)-
Pyrazine; 2,6-pyridinedicarboxylic acid; 2,4,5-trihydroxypyrimidine; phenyl 2-pyridylketoxime; 3-amino-5,6-dimethyl-1,
2,4-triazine; 6-hydroxy-2-phenyl-3 (2H) -pyridazinone; 2,4-pteridinediol {lumazine}; 2,2′-dipyridyl;
3-dihydroxypyridine.

The silicone compounds, humectants, additional conditioning agents, UV absorbers, optical brighteners and herbal extracts useful for the encapsulating material are the same as those exemplified elsewhere herein. It is. However, the components in the present invention are substantially retained within the fragile visible particles and are not substantially dissolved in the bulk of the composition of the present invention under normal storage conditions.

Commercially fragile visible particles that are particularly useful in the present invention are available from Induchem (Switzerland)
Trade names Unisphere and Unicerin available from
It is something like Unisphere and unicerin particles are made of microcrystalline cellulose, hydroxypropylcellulose, lactose, vitamins, pigments and proteins. In use, the Unisphere or Unicerin can be disintegrated virtually without resistance on the hand with only a very small shear by the finger and dissolves readily in the composition.

Silicone Compound The composition of the present invention contains a silicone compound. Silicone compounds useful in the present invention include volatile soluble or insoluble or non-volatile soluble or insoluble silicone conditioning agents. By solubility, it is meant that the silicone compound is miscible with the carrier of the composition to form part of the same phase. By insolubility is meant that the silicone forms a discrete phase separate from the carrier, for example, in the form of an emulsion or suspension of silicone droplets. Silicone compounds in the present invention, including emulsion polymerization,
It can be made by any suitable method known in the art. The silicone compound may further be incorporated into the composition of the present invention in the form of an emulsion, wherein the emulsion is anionic, nonionic or synthetic at the stage of synthesis by mechanical mixing or by emulsion polymerization. It is produced with or without the aid of a surfactant selected from cationic surfactants and mixtures thereof.

The silicone compounds used in the present invention are preferably at about 25
0 to about 2,000,000 centistokes, more preferably about 10,000
It has a viscosity of from 0 to about 1,800,000 centistokes, and even more preferably from about 100,000 to about 1,500,000 centistokes. The viscosity was measured by a glass capillary viscometer using the Dow Corning Corporate Test Method CTM0004,
It can be measured as described on July 20, 1970. High molecular weight silicone compounds can be produced by emulsion polymerization. Suitable silicone fluids include polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, polyethersiloxane copolymers, and mixtures thereof. Other non-volatile silicone compounds having hair conditioning properties can also be used.

The silicone compound in the present invention is used at a weight level of the composition, preferably from about 0.1% to about 60%, more preferably from about 0.1% to about 40%.

The silicone compound in the present invention also includes a polyalkyl or polyaryl siloxane having the following formula (I):

[0028]

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Wherein R ⁹³ is alkyl or aryl and x is from about 7 to about 8,000
Is an integer up to. Z ⁸ represents a group that blocks the end of the silicone chain. The alkyl or aryl groups substituted on the siloxane chain (R ⁹³ ) or at the terminal Z ⁸ of the siloxane chain are such that the resulting silicone remains fluid at room temperature, is dispersible, and is irritating when applied to the hair. Neither toxic, nor toxic or otherwise harmful, compatible with the other components of the composition, chemically stable under normal use and storage conditions, and deposited on the hair It can have any structure as long as it is possible and the hair can be conditioned. Suitable Z ⁸ groups include hydroxy, methyl, methoxy, ethoxy, propoxy and aryloxy. The two R ⁹³ groups on a silicon atom can represent the same or different groups. Preferably, these two R ⁹³ groups represent the same group. Suitable R ⁹³ groups include methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl. Preferred silicone compounds are polydimethylsiloxane, polydiethylsiloxane and polymethylphenylsiloxane.
Polydimethylsiloxane, also known as dimethicone, is particularly preferred. Polyalkylsiloxanes that can be used include, for example, polydimethylsiloxane. These silicone compounds are available, for example, from General Electric Company, under the name Viscasil®.
And SF96 series, and from Dow Corning to Dow
Available in the Corning 200 series.

[0030] Polyalkylarylsiloxane fluids can also be used, and these include, for example, polymethylphenylsiloxane. These siloxanes are available, for example, as SF1075 methylphenyl fluid from General Electric Company or 556 Cosmetic Grade Fluid from Dow Corning.
Available as Fluid (Cosmetic Grade Fluid).

To enhance the shine properties of the hair, highly arylated silicone compounds, such as highly phenylated, having a refractive index of about 1.46 or greater, especially about 1.52 or greater Polyethyl silicone is particularly preferred. When using these high refractive index silicone compounds, they are mixed with a spreading agent, such as a surfactant or a silicone resin, to reduce surface tension and reduce the film-forming ability of this material as described below. Should be raised.

[0032] Silicone compounds that can be used include, for example, polypropylene oxide-modified polydimethylsiloxane, but ethylene oxide or a mixture of ethylene oxide and propylene oxide can also be used. The levels of ethylene oxide and polypropylene oxide must be low enough not to interfere with the dispersing properties of the silicone. These materials are also known as dimethicone copolyols.

[0033] Other silicone compounds include amino-substituted substances. Suitable alkylamino-substituted silicone compounds include those represented by the following structure (II):

[0034]

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Wherein R ⁹⁴ is H, CH ₃ or OH and p ¹ , p ² , q ¹ and q ² are based on a molecular weight whose average molecular weight is between approximately 5,000 and 10,000. Is an integer). This polymer is also known as amodimethicone.

Suitable amino-substituted silicone fluids include those represented by Formula (III):

[0037]

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Wherein G is selected from the group consisting of hydrogen, phenyl, OH, C ₁ -C ₈ alkyl, and is preferably methyl; a represents 0 or an integer from 1 to 3, and preferably B is 0 or 1, and preferably 1; p ³
The sum of + p ^{4 is} a number from 1 to 2,000, and preferably from 50 to 150, wherein p ³ is from 0 to 1,999, and preferably from 49 to 14
May indicate the number of up to 9, and p ⁴ is from 1 to 2,000, and preferably be an integer of from 1 to 10; R ⁹⁷ is wherein _{C q3} H 2q3 L (wherein,
q ³ is an integer from 2 to 8 and L is the following group:

—N (R ⁹⁶ ) CH ₂ —CH ₂ —N (R ⁹⁶ ) ₂ —N (R ⁹⁶ ) ₂ —N (R ⁹⁶ ) ₃ X′—N (R ⁹⁶ ) CH ₂ —CH ₂ —NR ⁹⁶ H ₂ X ′, wherein R ⁹⁶ is selected from the group consisting of hydrogen, phenyl, benzyl, a saturated hydrocarbon group, preferably an alkyl group containing from 1 to 20 carbon atoms, and X ′ is halogen Is a monovalent group selected from:

Particularly preferred amino-substituted silicones corresponding to formula (II) are those polymers in which R ⁹⁴ is CH ₃ and known as “trimethylsilyl amodimethicone”.

Other amino-substituted silicone polymers that can be used are represented by formula (V):

[0042]

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Wherein R ⁹⁸ represents a monovalent hydrocarbon radical having 1 to 18 carbon atoms, preferably an alkyl or alkenyl radical, for example methyl; R ⁹⁹ represents a hydrocarbon radical, preferably C ₁ -C ₁ . Represents a C ₁₈ alkylene group or a C ₁ -C ₁₈ , and more preferably a C ₁ -C ₈ alkyleneoxy group; Q ⁻ is a halide ion, preferably chloride; p ⁵ is from 2 to 20, preferably 2 From 8 to 8; p ⁶ from 20 to 200, and preferably from 20 to 50. A preferred polymer of this class is "UCAR SILICONE
) ALE56 "available from Union Carbide.

References disclosing suitable non-volatile dispersed silicone compounds include US Pat. No. 2,826,551 to Gene; Drakoff.
U.S. Pat. No. 3,964,500, issued Jun. 22, 1976; U.S. Pat. No. 4,364,837, issued to Pader; and U.S. Pat. British Patent No. 849,433. Petrarch Systems, Inc. "Silicon Compounds" distributed by (Petrarch Systems, Inc.), 1984, provides a non-limiting, extensive list of suitable silicone compounds.

Another non-volatile dispersed silicone that can be particularly useful is silicone rubber. As used herein, the term "silicone rubber" refers to 1,000 silicones at 25 ° C.
A polyorganosiloxane material having a viscosity greater than or equal to 2,000 centistokes. It is recognized that the silicone rubbers described herein may have some overlap with the silicone compounds disclosed above. This overlap is not intended as a limitation on any of these substances. Silicone rubber is disclosed in Petrarch, and U.S. Pat. No. 4,152,416 issued May 1, 1979 to Spitzer et al. And Noll, Walter, Chemistry and Technology of Technology. • Chemistry and Technology of Silicones, New York: described by others, including the Academic Press, 1968. General Electric Silicone Rubber Product Data Sheets SE30
, SE33, SE54 and SE76 also describe silicone rubber. These "silicone rubbers" will typically have a mass molecular weight of greater than about 200,000, typically between about 200,000 and about 1,000,000. Specific examples include polydimethylsiloxane, poly (dimethylsiloxane methylvinylsiloxane) copolymer, poly (dimethylsiloxanediphenylsiloxane methylvinylsiloxane) copolymer and mixtures thereof.

Also useful are highly crosslinked polymeric siloxane-based silicone resins. This crosslinking is introduced by incorporating tri- and tetra-functional silanes along with mono- or di-functional silanes or both during silicone resin production.
As is well understood in the art, the degree of crosslinking required to obtain a silicone resin will vary according to the particular silane units incorporated into the silicone resin. Generally, a silicone material that has a sufficient value of trifunctional and tetrafunctional siloxane monomer units, and therefore a sufficient value of crosslinks, to result in a dry, hard or hard film is a silicone material. Considered to be a resin. The ratio of oxygen atoms to silicon atoms is an indicator of the crosslinking value in a particular silicone material. Silicone materials having at least about 1.1 oxygen atoms per silicon atom will generally be silicone resins herein. Preferably, the ratio of oxygen: silicon atoms is at least about 1.2: 1.0. The silanes used in the production of silicone resins include monomethyl-, dimethyl-, trimethyl-, monophenyl-, diphenyl-, methylphenyl-, monovinyl and methylvinylchlorosilanes and tetrachlorosilane, with methyl-substituted silanes being the most common. Used for Preferred resins are GESS4230 and SS42 by General Electric.
67. Commercially available silicone resins will generally be supplied in dissolved form in low viscosity volatile or non-volatile silicone fluids. The silicone resins used in the present invention will be provided in dissolved form as described above and will be incorporated into the compositions of the present invention, as will be readily apparent to those skilled in the art. While not being bound by theory, it is believed that these silicone resins can enhance the deposition of other silicone compounds on the hair, and can enhance hair shine with high refractive index capacity.

Another useful silicone resin is a material provided with a silicone resin powder, such as the CTFA designation polymethylsilsequioxane, and this is Toshiba Silicone (
It is commercially available from Toshiba Silicones as Tospearl ™.

The method for producing these silicone compounds is described in Encyclopedia of Polymer Science and Engineering.
e and Engineering), Volume 15, Second Edition, pp. 204-308, Joan Willie and Sons, Inc. (John Wiley & Sons, Inc.), which can be seen during 1989.

In particular, silicone materials and silicone resins can be conveniently identified according to the abbreviated naming system well known to those skilled in the art as “MDTQ” nomenclature. In this system, the silicone is described according to the presence of the various siloxane monomer units that make up the silicone. Briefly, the symbol M denotes a monofunctional unit (CH ₃ ) ₃ SiO _0.5 ; D denotes a difunctional unit (CH ₃ ) ₂ S
indicates iO; T trifunctional unit (CH ₃₎ shows the SiO _1.5; and Q denotes the tetrafunctional unit SiO _2. Unit dashes such as M ', D', T 'and Q' indicate substituents other than methyl and must be specified in detail for each occurrence. Typical alternative substituents include groups such as vinyl, phenyl, amino, hydroxyl and the like. The molar ratios of the various units may be based on the MDTQ system based on the MDTQ system, either in relation to the subscript or the average of the symbol indicating the total number of units of each type of the silicone or as a detailed ratio in combination with the molecular weight. Complete the substance description. T, Q for D, D ', M and / or M' in silicone resin
, T ′ and / or Q ′ are indicative of a higher crosslinking value. However, as mentioned above, the overall degree of crosslinking can also be indicated by the ratio of oxygen to silicon.

Preferred silicone resins useful herein are MQ, MT, MTQ, MQ and MDT
Q resin. Thus, the preferred silicone substituent is methyl. M: Q
The ratio is about 0.5: 1.0 to about 1.5: 1.0 and the average molecular weight of the resin is about 1000 to 1000
An MQ resin of about 10,000 is particularly preferred.

Particularly suitable silicone compounds in the present invention are non-volatile silicone oils having a molecular weight of from about 200,000 to about 600,000, such as dimethicone and dimethiconol. These silicone compounds can be incorporated into the composition as a silicone oil solution; these silicone oils are volatile or non-volatile.

[0052] Commercially available silicone compounds useful in the present invention include trade name D available from Dow Corning Corporation.
Dimethicone with C345, a dimethicone gum solution with trade names SE30, SE33, SE54 and SE76 available from General Electric;
Trade name DCQ2-1403 available from Dow Corning Corporation
And dimethiconol having DCQ2-1401, and UK application 2,303,
Emulsion polymerized dimethiconol available from Toshiba Silicone as described in US Pat.

Aqueous Carrier The compositions of the present invention include an aqueous carrier, which is present as a continuous phase of the composition. The level and species of the carrier are selected according to the compatibility with other components and other desired properties of the product.

[0054] Carriers useful in the present invention include water and aqueous solutions of lower alkyl alcohols. Lower alkyl alcohols useful in the present invention are monohydric alcohols having 1 to 6 carbons, more preferably ethanol and isopropanol.

Preferably, the aqueous carrier is substantially water. Preferably, deionized water is used. Water from natural sources containing mineral cations can also be used, depending on the desired properties of the product. Generally, the compositions of the present invention contain from about 20% to about 99%, preferably from about 40% to about 98%, and more preferably from about 50% to about 98% water.

The pH of the composition of the present invention is preferably from about 4 to about 9, more preferably about 4.
5 to about 7.5. Buffers and other pH adjusting agents can be included to achieve the desired pH.

The composition of the present invention is transparent. What is meant by transparency is 1cm x 1c
That is, a black substance having a size of m square can be detected with the naked eye through a 1 cm thick composition of the present invention.

[0058] pressurized viscous adhesive composition of the present invention, anionic polymers, nonionic polymers, and mixtures thereof pressurized viscous agent selected from the group consisting of (viscosifying agent) may further comprise a. In a preferred embodiment, a thickening agent is included in the composition of the present invention to make a gel having a particular viscosity. In such preferred embodiments, the viscosifying agent is used when the composition of the composition of the present invention has a composition of from about 1,000 cps to about 100,000 cps,
Preferably, it is selected to have a viscosity of about 2,000 cps to about 50,000 cps. Viscosity in the present invention is suitably measured by Brookfield RVT at 20 ° C., 20 rpm using either spindle # 4, 5, 6, or 7, depending on the viscosity and characteristics of the composition. Can be.

[0059] The thickener in the present invention is preferably present in an amount of about 0.001 by weight of the composition.
% To about 5%, more preferably from about 0.05% to about 3%.

[0060] Suitable thickeners of the invention are anionic polymers such as carboxylic acid / carboxylate copolymers. The carboxylic acid / carboxylate copolymer in the present invention is a hydrophobized cross-linked copolymer of a carboxylic acid and an alkyl carboxylate and has amphiphilic properties. These carboxylic / carboxylate copolymers include: 1) acrylic acid, methacrylic acid, maleic acid, maleic anhydride, itaconic acid, fumaric acid, crotonic acid or α-chloroacrylic acid, 2) from 1 to about 30 carbon atoms. Obtained by copolymerizing a carboxylic acid ester having an alkyl chain having the formula: and preferably 3) a crosslinking agent of the formula:

[0061]

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Wherein R ⁵² is hydrogen or an alkyl group having about 1 to about 30 carbons; Y ¹ is independently oxygen, CH ₂ O, COO, OCO,

[0063]

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Wherein R ⁵³ is hydrogen or an alkyl group having about 1 to about 30 carbons;
And Y ² are (CH ₂ ) _{m ″} , (CH ₂ CH ₂ O) _{m ″} , or (CH ₂ CH ₂ CH ₂₎
O) _{m ''} is selected from those wherein m '' is an integer from 1 to about 30; It is believed that the carboxylic acid / carboxylate copolymers of the present invention impart suitable viscosity and rheological properties to the composition and emulsify and stabilize certain conditioning agents in the composition. Further, because of the alkyl groups contained in the copolymer, the carboxylic acid / carboxylate copolymer is not believed to render the composition undesirably tacky.

A suitable carboxylic acid / carboxylate copolymer in the present invention is an acrylic acid / alkyl acrylate copolymer having the formula:

[0066]

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Wherein R ⁵¹ is independently hydrogen or alkyl having 1 to 30 carbons, wherein at least one of R ⁵¹ is hydrogen and R ⁵² is as defined above. N, n ′, m and m ′ are integers, where n + n ′ + m + m ′
Is from about 40 to about 100; n ″ is an integer from 1 to about 30; and l is that the copolymer has a molecular weight of from about 500,000 to about 3,000,000.

Commercially available carboxylic / carboxylate copolymers useful in the present invention include: F. Trade name Pemulene available from Goodrich Company
TR-1, Pemulen TR-2, Carbopol 1342, Carbopol 1382,
Acrylate / C10-3 having ATP and Carbopol ETD2020
0 alkyl acrylate crosspolymer.

[0069] Thickening agents useful in the present invention also include other anionic and nonionic polymers. In the present invention, a vinyl polymer such as CTF
Crosslinked acrylic acid polymers having the A name Carbomer, cellulose derivatives and modified cellulose polymers such as methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose, nitrocellulose, sodium cellulose sulfate, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder, Polyvinyl pyrrolidone, polyvinyl alcohol, guar gum, hydroxypropyl guar gum, xanthan gum, gum arabic, tragacanth, galactan, carob gum, guar gum, karaya gum, carrageenan, pectin, agar, quince seed (Cydonia oblonga Mill), starch (rice, corn, potato, wheat) ), Algal colloid (algal extract),
Microbiological polymers such as dextran, succinoglucan, prelan, starch-based polymers such as carboxymethyl starch, methylhydroxypropyl starch, alginic acid-based polymers such as sodium alginate, propylene glycol alginate esters, acrylate polymers such as sodium polyacrylate, Useful are polyethyl acrylate, polyacrylamide, polyethylene imine, and inorganic water-soluble substances such as bentonite, aluminum magnesium silicate, laponite, hectonite and silicic anhydride.

[0070] Polyalkylene glycols having a molecular weight of greater than about 1000 are useful in the present invention. The following general formula:

[0071]

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Those having the formula wherein R ⁹⁵ is selected from the group consisting of H, methyl and mixtures thereof are useful. When R ⁹⁵ is H, these materials are polymers of ethylene oxide, also known as polyethylene oxide, polyoxyethylene and polyethylene glycol. When R ⁹⁵ is methyl, these materials are polymers of propylene oxide, also known as polypropylene oxide, polyoxypropylene and polypropylene glycol. It is also understood that when R ⁹⁵ is methyl, various regioisomers of the resulting polymer may exist. In the above structure, x3 is from about 1500 to about 25,000, preferably from about 2500 to about 20,000, and more preferably from about 3500 to about 15
It has an average value of up to 10,000. Other useful polymers include polypropylene glycol and mixed polyethylene-polypropylene glycol or polyoxyethylene-polyoxypropylene copolymer polymers. Polyethylene glycol polymers useful in the present invention is R ⁹⁵ is H and x3 is about 2,0
PEG-2M having an average value of 00 (PEG-2M is also known as Polyox WSR® N-10 available from Union Carbide and also as PEG-2,000. and have); R ⁹⁵ is H and x3
Has an average value of about 5,000 (PEG-5M is also available as Polyox WSR® N-35 and Polyox WSR® N-80, both available from Union Carbide). PEG-7M, also known as PEG-5,000 and polyethylene glycol 300,000); ^R95 is H and x3 has an average value of about 7,000 (PEG-7M is also a union・ Polyox WSR (registered trademark) N- available from carbide
Also known as 750); R ⁹⁵ is H and PEG-9M x3 has an average value of about 9,000 (PEG-9M is also possible Polyox WSR available from Union Carbide (TM) N-3333);
And PEG-1 wherein R ⁹⁵ is H and x3 has an average value of about 14,000.
4M (PEG-14M is also known as Polyox WSR® N-3000 available from Union Carbide).

Commercially available viscosifiers that are very useful in the present invention include all B.I. F. Trade names available from Goodrich Company, Carbopol 934, Carbopol 9
Acrysol, available from Rohm and Haas, a carbomer with Carbopol 40, Carbopol 950, Carbopol 980, and Carbopol 981 (ACRY
Acrylate / steareth-20 methyl methacrylate copolymer with SOL) 22, trade name AMERCELL polymer HM available from Amarcol
Nonoxynyl hydroxyethylcellulose with -1500, methylcellulose with brand name BENECEL, all supplied by Herculus, hydroxyethylcellulose with brand name natrosol, hydroxypropylcellulose with brand name KLUSEL, Cetyl hydroxyethylcellulose with the trade name POLYSURF 67, all supplied by AMERCOL, trade name CARBOWAX PEG, Polyox W
ASR and ethylene oxide and / or propylene oxide based polymers with turmeric liquid (UCON FLUIDS).

A neutralizing agent may be included to neutralize the anionic polymer in the present invention.
Examples of such neutralizing agents include sodium hydroxide, potassium hydroxide, ammonium hydroxide, monoethanolamine, diethanolamine, triethanolamine, diisopropanolamine, aminomethylpropanol, tromethamine.
mine), tetrahydroxypropylethylenediamine and mixtures thereof.

Humectants The compositions of the present invention may further include a humectant. The humectant in the present invention is selected from the group consisting of polyhydric alcohols, water-soluble alkoxylated nonionic polymers and mixtures thereof. The humectant in the present invention is used at the weight level of the composition, preferably from about 0.1% to about 20%, more preferably from about 0.5% to about 5%.

Polyhydric alcohols useful in the present invention include glycerin, sorbitol, propylene glycol, butylene glycol, hexylene glycol, ethoxylated glucose, 1,2-hexanediol, hexanetriol, dipropylene glycol, erythritol, trehalose, Glycerin, xylitol, maltitol, maltose, glucose, fructose, chondroitin sulfate sodium, sodium hyaluronate, sodium adenosine phosphate, sodium lactate,
Includes pyrrolidone carbonate, glucosamine, cyclodextrin and mixtures thereof.

[0077] Water-soluble alkoxylated nonionic polymers useful in the present invention include about 100
Polyethylene glycol and polypropylene glycol having a molecular weight of up to 0, such as the CTFA designations PEG-200, PEG-400, PEG-600, P
Includes those having EG-1000 and mixtures thereof.

Commercially available humectants in the present invention include: STAR and SUPEROL, trade names available from The Procter & Gamble Company; Kuroda Universal Eltidi. (CRODEROL) G available from (Croda Universal Ltd.)
A7000, a PRESERIN series available from Unichema, and glycerin available from NF (NOF) and having the same trade name as the chemical name; Lexol (LEXO) available from Inolex
L) PG-865 / 855, USP 1,2-Available from BASF (BASF)
Propylene glycol with propylene glycol; trade name LIPONIC series available from Lipo, SORBO available from ICI, ALEX, A-625 and A-641 and UNISWEET 70, available from UPI; sorbitol with Unisuit CONC; dipropylene glycol with the same trade name available from Basff; Solvay GmbH
Diglycerol with the trade name DIGLYCEROL available from Kyowa and Eizai; xylitol with the same trade name available from Kyowa and Eizai; MALBIT trade name available from Hayashibara Maltitol with the same trade name available from Freeman and Bioiberica and Atomergic
Chondroitin sodium sulfate with the trade name ATOMERGIC SODIUM CHONDROITIN SULFATE available from Chemetals; Actimoist, trade name available from Active Organics Sodium Hyaluronate with AVIAN SODIUM HYALURONATE Series available from Intergen), HYALURONIC ACID Na available from Ichimaru Pharcos; Asahikasei ), Sodium adenosine phosphate with the same trade name available from Kyowa and Daiichi Seiyaku; Merck
Sodium lactate having the same trade name available from Wako, Showa Kako; trade names CAVITRON, Rhone-Poulenc available from American Maize RHODOCAP series available from Tomen and cyclodextrin with DEXPEARL available from Tomen; and CARBOWAX series available under the trade name Union Carbide. Polyethylene glycol having the same.

[0079] The composition of the optical brightener present invention may further comprise an optical brightener (optical brightener). Optical brighteners are compounds that absorb ultraviolet light and emit its energy again in the form of visible light. In particular, optical brighteners useful in the present invention have an absorption, preferably a major absorption peak, at a wavelength between about 1 nm and about 420 nm and emit at a wavelength between about 360 nm and about 830 nm, preferably Has a major emission peak; wherein the major absorption peak has a shorter wavelength than the major emission peak. More preferably, the optical brighteners useful in the present invention have a major absorption peak at a wavelength between about 200 nm and about 420 nm, and a major emission peak at a wavelength between about 400 nm and about 780 nm. ing. The optical brightener may or may not have a minor absorption peak in the visible range between about 360 nm and about 830 nm. Optical brighteners can be described in the art and other industries under other names, such as fluorescent bleaches, fluorescent brighteners and fluorescent dyes.

When applied to hair via a suitable vehicle, the optical brighteners of the present invention provide benefits to the hair in three areas. First, the optical brighteners of the present invention change hair color by emitting light in the visible range. Second, the optical brighteners of the present invention enhance hair shine by emitting light in the visible range. Third, the optical brightener of the present invention protects hair from ultraviolet light by absorbing ultraviolet light.

Optical brighteners are generally based on structures of aromatic and heteroaromatic systems that provide these unique characteristics. Optical brighteners useful in the present invention can be water-soluble and water-insoluble, and can be classified according to their basic structure, as described below. Preferred optical brighteners in the present invention include polystyryl stilbene, triazine stilbene, hydroxycoumarin, aminocoumarin, triazole, pyrazoline, oxazole, pyrene, porphyrin and imidazole.

The optical brighteners useful in the present invention are used at a weight level of the composition, preferably from about 0.001% to about 10%.

Polystyrylstilbene Polystyrylstilbene is a class of compounds having two or more of the following basic structures:

[0084]

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The polystyrylstilbenes useful in the present invention include those of formulas (1), (2) and (3)
Including those with:

[0086]

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(Wherein R ¹⁰¹ is H, OH, SO ₃ M, COOM, OSO ₃ M, OPO (OH)
OM (wherein, M is H, Na, K, Ca, Mg, ammonium, mono-, - di -, tri - or tetra -C ₁ -C ₃₀ - alkyl ammonium, mono-, - di - or tri -C ₁ ~ C ₃₀ - hydroxyalkyl ammonium or C ₁ -C ₃₀ - di with a mixture of hydroxyalkyl group - - alkyl and C ₁ -C ₃₀ or tri -
Substituted ammonium); or SO ₂ N (C ₁ -C ₃₀ -alkyl) ₂
, O- (C ₁ ~C ₃₀ - alkyl), CN, Cl, COO ( C 1 ~C 30 - alkyl)
, CON (C ₁ ~C ₃₀ - alkyl) ₂ or ^{_{O (CH 2) 3 N +}} (CH 3) 2 X - ( wherein, X ^- is chloride, bromide, iodide, formate, acetate, propionate, glycolate, Lactate, acrylate, methanephosphonate, phosphite, dimethyl or diethylphosphite anion); C
N or alkyl of 1 to 30 carbons, wherein R ¹⁰² and R ¹⁰³ are independently H,
SO ₃ M wherein M is as defined above; and x is 0 or 1, wherein the compound has a trans or cis coplanar orientation; preferably Is x, R ¹⁰¹ is SO ₃ Na, and R ¹⁰² and R ¹⁰³ are H, wherein the compound has a trans-coplanar orientation.
;

[0088]

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Wherein R ¹⁰⁴ and R ¹⁰⁵ are independently CN, COO (C ₁ -C ₃₀ -alkyl), CONHC ₁ -C ₄ -alkyl or CON (C ₁ -C ₄ -alkyl) ₂ And
The compound then has a trans-coplanar or cis-coplanar orientation;
Preferably R ¹⁰⁴ and R ¹⁰⁵ are 2-cyano, wherein the compound has a trans-coplanar orientation);

[0090]

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Wherein each R ¹⁰⁶ is independently H or alkyl of 1 to 30 carbons; and wherein the compound is in a trans or cis coplanar orientation, preferably in a trans coplanar orientation Orientation).

[0092] Suitable polystyrylstilbenes include Ciba Specialty Chemicals (Ci
Tinopal CBS- available from Ba Specialty Chemicals)
Disodium-1,4'-bis (2-sulfostyryl) bisphenyl with X (CI Fluorescent Brightener 351), available from Basff under the trade name Ultraphor RN , 4-bis (2-cyanostyryl) benzene (CI fluorescent brightener 199).

[0093] triazine stilbene triazine stilbene are a class of compounds which have both triazine structure and a stilbene structure in the same molecule. Triazine stilbenes useful in the present invention include those having formula (4):

[0094]

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Wherein R ¹⁰⁷ and R ¹⁰⁸ are independently phenylamino, mono- or disulfonated phenylamino, morpholino, N (CH ₂ CH ₂ OH) ₂ , N (CH ₃ ) (C
_{H 2 CH 2 OH), NH} 2, N (C 1 ~C 4 - _{alkyl) 2, OCH 3, Cl,} NH-
(CH ₂ ) _1-4 SO ₃ H or NH— (CH ₂ ) _1-4 OH; An ⁻ is a carboxylate, sulfate, sulfonate or phosphate anion, and M is as defined above. Wherein the compound has a trans or cis coplanar orientation; preferably, R ¹⁰⁷ is 2,5-disulfophenylamino and each R ¹⁰⁸ is morpholino; or R ¹⁰⁷ is 2,5
-Disulfophenylamino and each R ¹⁰⁸ is N (C ₂ H ₅ ) ₂ ; or each R ¹⁰⁷ is 3-sulfophenyl and each R ¹⁰⁸ is NH (CH ₂ CH ₂ OH)
Or N (CH ₂ CH ₂ OH) ₂ ; or each R ¹⁰⁷ is 4-sulfophenyl, and each R ¹⁰⁸ is N (CH ₂ CH ₂ OH) ₂ ; and in each case, The sulfo group is SO ₃ M, where M is sodium; wherein the compound has a trans-coplanar orientation.

Suitable triazine stilbenes include 4,4′-bis-[(4-anilino-6-bis (2-hydroxyethyl) amino having the trade name Tinopal UNPA-GX available from Ciba Specialty Chemicals. -1,3,5-triazine-2
-Yl) amino] stilbene-2,2'-disulfonic acid, 4,4'-bis-[(4-anilino-6-morpholine-1) having the trade name Tinopal AMS-GX available from Ciba Specialty Chemicals. , 3,5-Triazin-2-yl)
Amino] stilbene-2,2'-disodium sulfonate, 4,4 'with the trade name Tinopal 5BM-GX available from Ciba Specialty Chemicals
-Bis-[(4-anilino-6- (2-hydroxyethyl) methylamino-1,
3,5-triazin-2-yl) amino] stilbene-2,2'-disodium sulfonate; 4 ', 4-bis-[(4,6-dianilino-1,3,5-triazin-2-yl) Amino] stilbene-2,2′-disodium sulfonate,
4,4'-bis-[(4-anilino-6-methylamino-1,3,5-triazin-2-yl) amino] stilbene-2,2'-disodium sulfonate,
, 4'-Bis-[(4-anilino-6-ethylamino-1,3,5-triazin-2-yl) amino] stilbene-2,2'-disodium sulfonate and 4
, 4'-bis- (4-phenyl-1,2,3-triazol-2-yl) stilbene-2,2'-disulfonic acid.

[0097] hydroxycoumarin hydroxycoumarin is the class of compounds with a and at least one hydroxy moiety of the following coumarin basic structure:

[0098]

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Hydroxycoumarins useful in the present invention include those having formula (5):

[0100]

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Wherein R ²⁰¹ is H, OH, Cl, CH ₃ , CH ₂ COOH, CH ₂ SO ₃ H, CH ₂ OSO ₃ H or CH ₂ OPO (OH) OH, and R ²⁰² is H, phenyl , COO
—C ₁ -C ₃₀ -alkyl, glucose or formula (6):

[0102]

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And R is²⁰³Is OH or OC₁~ C₃₀-Alkyl and R ²⁰⁴ Is OH or OC₁~ C₃₀Alkyl, glycoside or the following formula (7):

[0104]

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Wherein R ²⁰⁵ and R ²⁰⁶ are independently phenylamino, mono- or disulfonated phenylamino, morpholino, N (CH ₂ CH ₂ OH) ₂ , N (CH ₃ ) (C
_{H 2 CH 2 OH), NH} 2, N (C 1 ~C 30 - _{alkyl) 2, OCH 3, Cl,} NH-
(CH ₂ ) _1-4 SO ₃ H or NH— (CH ₂ ) _1-4 OH).

Suitable hydroxycoumarins include 6,7-dihydroxycoumarin available from Wako Chemicals, 4-methyl-7-hydroxycoumarin available from Wako Chemicals, 4-methyl-7-hydroxycoumarin available from Wako Chemicals. Methyl-6
7-dihydroxycoumarin, esculin available from Wako Chemicals and umbelliferone (4-hydroxycoumarin) available from Wako Chemicals.

[0107] Amino coumarin amino coumarin has a coumarin basic structure and a class of compounds having at least one amino moiety of.

[0108] Aminocoumarins useful in the present invention include those having formula (8):

[0109]

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Where R²⁰⁷Is H, Cl, CH_Three, CH_TwoCOOH, CH_TwoSO_ThreeH, CH_TwoOSO _Three H or CH_TwoOPO (OH) OH and R²⁰⁸Is H, phenyl or COOC₁~
C₃₀Alkyl and R²⁰⁹And R²¹⁰Is independently H, NH_Two, N (C₁ ~ C₃₀Alkyl)_Two, NHC₁~ C₃₀Alkyl or NHCOC₁~ C₃₀With alkyl
is there.

Suitable aminocoumarins include the trade name Calcofluor (Calc, available from Basff)
ofluor) -methyl-7,7'-diethylaminocoumarin with -RWP, 4-methyl-7,7 'with the trade name Calcofluor-LD available from Basff
-Includes dimethylaminocoumarin.

Triazoles Triazoles are a class of compounds having the following basic structure.

[0113]

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The triazoles useful in the present invention include those having formulas (9) to (12) and (15) to (20):

[0115]

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Wherein R ³⁰¹ and R ³⁰² are independently H, C ₁ -C ₃₀ alkyl, phenyl or monosulfonated phenyl; An ⁻ and M are as defined above,
The compound then has a trans-coplanar or cis-coplanar orientation;
Preferably, R ³⁰¹ is phenyl, R ³⁰² is H, and M is sodium; wherein the compound has a trans-coplanar orientation;

[0117]

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Wherein R ³⁰³ is H or Cl; R ³⁰⁴ is SO ₃ M, SO ₂ N (C ₁ -C ₃₀ -alkyl) ₂ , SO ₂ O-phenyl or CN; R ³⁰⁵ is H , SO ₃ M, COOM
, OSO ₃ M or OPO (OH) OM; and M is as defined above, wherein the compound has a trans or cis coplanar orientation; preferably, R ³⁰³ and R ³⁰⁵ is H and R ³⁰⁴ is SO ₃ M, where M is Na; wherein the compound has a trans-coplanar orientation;

[0119]

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In the formula, R ³⁰⁶ and R ³¹² each independently represent H, a sulfonic acid group or a salt, ester or amide thereof, a carboxylic acid group or a salt thereof, an ester or amide, a cyano group, a halogen atom, an unsubstituted Or a substituted alkylsulfonyl, arylsulfonyl, alkyl, alkoxy, aralkyl, aryl, aryloxy, aralkoxy or cycloalkyl group, a non-alkyl group containing 2 to 3 nitrogen atoms or 1 oxygen atom and 1 or 2 nitrogen atoms. Represents a substituted or substituted 5-membered heterocyclic ring, or together with R ³⁰⁷ and R ³¹³ , methylenedioxy, ethylenedioxy, methyleneoxymethyleneoxy, trimethylene, tetramethylene, propenylene, butenylene or butadienylene R ³⁰⁷ and R ³¹³ are each independently H, sulf Acid group or a salt, ester or amide with a carboxylic acid group or a salt, ester or amide, cyano group, halogen atom, or an unsubstituted or substituted alkyl or alkoxy group, or these and R ³⁰⁶ and R ³¹² Represents a methylenedioxy, ethylenedioxy, methyleneoxymethyleneoxy, trimethylene, tetramethylene, propenylene, butenylene or butadienylene group, and R ³⁰⁸ and R ³¹⁴ each independently represent H, a halogen atom or an unsubstituted group. R ³⁰⁹ and R ³¹¹ each independently represent H, a halogen atom, a cyano group, a sulfonic acid group or a salt, ester or amide thereof, or a carboxylic acid group or a salt, ester or amide thereof. And R ³¹⁰ are independently H, halogen, cyano An alkyl group, preferably hydroxy, alkoxy of 1 to 30 carbon atoms, cyano,
Halogen, carboxy, sulfonic acid groups, can be substituted by carbalkoxy, phenyl or phenoxy having 1 to 30 carbon atoms in the alkoxy moiety; alkoxy groups are hydroxy, alkoxy of 1 to 30 carbon atoms, cyano , Halogen, carboxy, carboxy, phenyl or phenoxy having from 1 to 30 carbon atoms in the alkoxy moiety can be substituted; Carbalkoxy, sulfo having 30 carbon atoms, or 1 to 30 each
May be substituted with alkyl or alkoxy at carbon atoms; the compound having a trans-coplanar or cis-coplanar orientation; the number of possible cycloalkyl groups is preferably from 1 to 30 Cyclohexyl and cyclopentyl groups which can be substituted with alkyl of carbon atoms; possible 5-membered heterocyclic rings are v-triazole, oxazole or 1,3,4-oxadiazole groups, and Is an alkyl group of 1 to 4 carbon atoms as a substituent, halogen, phenyl, carboxy, carbalkoxy, cyano, benzyl having 1 to 30 carbon atoms in the alkoxy moiety, alkoxy of 1 to 30 carbon atoms, It may contain phenoxy or sulfo, but the above triazole and oxazole groups Two adjacent substituents taken together can form a substituted or unsubstituted fused benzene nucleus; that time the compound has a trans-coplanar orientation;

[0121]

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Wherein Q ¹ represents ^one of the ring systems (13) or (14):

[0123]

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In the above formula, R ³¹⁷ is H, alkyl having ₁ to ₃₀ carbon atoms, cyclohexyl, phenylalkyl having C _{1 to} C ₃₀ carbon atoms in the alkyl moiety, phenyl, 1 to 30 carbon atoms or an alkoxy or Cl with a, or an alkylene having R ^{31 8} 3 to 30 carbon atoms together, whether R ³¹⁸ represents an H or alkyl having 1 to 30 carbon atoms, Alternatively, together with R ³¹⁷ , it represents alkylene having 3 to 30 carbon atoms, R ³¹⁹ represents H or methyl, R ³²⁰ is H, alkyl having 1 to 30 carbon atoms, phenyl, 1 to 30 3
Represents alkoxy or Cl having 0 carbon atoms, or together with R ³²¹ represents a fused benzene ring, and R ³²¹ represents H or Cl, or together with R ³²⁰ represents a fused benzene ring. R ³¹⁵ represents H, alkyl having 1 to 30 carbon atoms, alkoxy or Cl having 1 to 30 carbon atoms, R ³¹⁶
Represents H or Cl, Q ² represents H, Cl, alkyl or phenyl having 1 to 30 carbon atoms, and Q ³ represents H or Cl, wherein the compound is in trans coplanar orientation or cis. Have a coplanar orientation, preferably a trans coplanar orientation;

[0125]

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Wherein R ³²² represents H, Cl, methyl, phenyl, benzyl, cyclohexyl or methoxy, R ³²³ represents H or methyl, and Z represents O or S; Has a planar or cis coplanar orientation, preferably a trans coplanar orientation;

[0127]

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Wherein R ³²⁴ is H, Cl, alkyl having 1 to 30 carbon atoms, 1 to 30
Phenylalkyl having carbon atoms, or an alkoxy having a phenyl or 1 to 30 carbon atoms, or R ³²⁴ represents a fusion benzene group together with R ^325, R ³²⁵ represents H or methyl Or R ³²⁵ together with R ³²⁴ represents a fused benzene group, R ³²⁶ is H, alkyl having 1-30 carbon atoms, alkoxy having 1-30 carbon atoms, Cl, 1- Represents carbalkoxy having 30 carbon atoms or alkylsulfonyl having 1 to 30 carbon atoms, and R ³²⁷ represents H, Cl, methyl or methoxy; wherein the compound is in trans coplanar orientation or cis coplanar It has an orientation, preferably a trans-coplanar orientation.

Suitable triazoles include 2- (4-styryl-3-sulfophenyl) -2 with the trade name Tinopal RBS available from Ciba Specialty Chemicals.
H-naphtho [1,2-d] triazole (CI fluorescent brightener 46) is included.

[0130] pyrazoline pyrazoline is a class of compounds having the following basic structure.

[0131]

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The pyrazolines useful in the present invention include those having formulas (21) to (23):

[0133]

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Wherein R ⁴⁰¹ is H, Cl or N (C ₁ -C ₃₀ -alkyl) ₂ , and R ⁴⁰² is H,
_{Cl, SO 3 M, SO 2} NH 2, SO 2 NH- (C 1 ~C 30 alkyl), COO-C ₁ ~C ₃₀ alkyl, SO ₂ C ₁ ~C _{30 alkyl, SO 2 NH (CH 2)} 1 _-4 N ⁺ (CH ₃
) ₃ or SO ₂ (CH ₂ ) _1-4 N ⁺ H (C ₁ -C ₃₀ -alkyl) ₂ An ⁻ and R ⁴⁰³
And R ⁴⁰⁴ are the same or different and are each H, C ₁ -C ₃₀ alkyl or phenyl, and R ⁴⁰⁵ is H or Cl; and An ⁻ and M are as defined above. Preferably, R ⁴⁰¹ is Cl, R ⁴⁰² is SO ₂ CH ₂ CH ₂ N ⁺ H (C ₁ -C ₄ -alkyl) ₂ An ⁻ , wherein An ⁻ is a phosphite, And R ⁴⁰³ , R ⁴⁰⁴ and R ⁴⁰⁵ are each H; and equations (22) and (23) are shown below.

[0135]

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Suitable pyrazolines include 1- (4-amidosulfonylphenyl) -3- with the trade name Blankophor DCB available from Bayer.
(4-chlorophenyl) -2-pyrazolin (CI fluorescent brightener 121); 1-
[4- (2-Sulfoethylsulfonyl) phenyl] -3- (4-chlorophenyl) -2-pyrazolin, 1- [4- (2-sulfoethylsulfonyl) phenyl]-
3- (3,4-dichloro-6-methylphenyl) -2-pyrazolin, 1- <4-
{N- [3- (N, N, N-trimethylammonio) propyl] amidosulfonyl} phenyl> -3- (4-chlorophenyl) -2-pyrazolinmethylsulfate and 1- <4- {2- [ 1-methyl-2- (N, N-dimethylamino) ethoxy] ethylsulfonyl {phenyl> -3- (4-chlorophenyl) -2-pyrazolinmethyl sulfate.

Oxazoles Oxazoles are a class of compounds having the following basic structure.

[0138]

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Oxazoles useful in the present invention include those of formulas (24), (25), (26) and (27)
Including those with:

[0140]

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In the formula, R⁵⁰¹And R⁵⁰²Is independently H, Cl, C₁~ C₃₀Alkyl or SO_Two -C₁~ C₃₀Alkyl, wherein the compound is trans coplanar or
Having a coplanar orientation;⁵⁰¹Is 4-CH_ThreeAnd R ⁵⁰² Is 2-CH_ThreeWherein the compound has a trans-coplanar orientation
;

[0142]

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Wherein R ⁵⁰³ is independently H, C (CH ₃ ) ₃ , C (CH ₃ ) ₂ -phenyl, C ₁ -C ₃₀ alkyl or COO-C ₁ -C ₃₀ alkyl, preferably H and Q ⁴ is —CH ＝ CH—;

[0144]

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Preferably,

[0146]

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Or one group R ^{503 in} each ring is 2-methyl and the other R ⁵⁰³ is H, and Q ⁴ is —CH ＝ CH—; One group R ⁵⁰³ is 2-C (CH ₃ ) ₃ and the other R ⁵⁰³ is H, wherein the compound has a trans or cis coplanar orientation, preferably a trans coplanar orientation. There;

[0148]

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Wherein R ⁵⁰⁴ is CN, Cl, COO-C ₁ -C ₃₀ alkyl or phenyl;
R ⁵⁰⁵ and R ⁵⁰⁶ are the atoms necessary to form a fused benzene ring or R ⁵⁰⁶ and R ⁵⁰⁸ are independently H or C ₁ -C ₃₀ alkyl; and R ⁵⁰⁷ is H, C ₁ -C ₃ is 0 alkyl or phenyl; that time the compound has a trans-coplanar orientation or cis coplanar orientation; preferably, R ⁵⁰⁴ is a 4-phenyl group, and R ⁵⁰⁵ to R ⁵⁰⁸ Are each H; wherein the compound has a trans-coplanar orientation; and

[0150]

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Wherein R ⁵⁰⁹ is H, Cl, alkyl having 1 to 30 carbon atoms, cyclohexyl, phenylalkyl having 1 to 30 carbon atoms in the alkyl moiety, phenyl or 1 to 30 carbon atoms And R ⁵¹⁰ is H or 1 to
Denotes alkyl having 30 carbon atoms and Q ⁵ is a group;

[0152]

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Wherein R ⁵¹¹ is H, alkyl having 1 to 30 carbon atoms, alkoxy having 1 to 30 carbon atoms, Cl, carbalkoxy having 1 to 30 carbon atoms, unsubstituted sulfamoyl, Or sulfamoyl mono- or di-substituted by alkyl or hydroxyalkyl having 1 to 30 carbon atoms, or alkylsulfonyl having 1 to 30 carbon atoms); Has a trans coplanar orientation or a cis coplanar orientation, preferably a trans coplanar orientation.

Suitable oxazoles include 4,4′-bis (5-methylbenzoxazole-
2-yl) stilbene and 2- (4-methoxycarbonylstyryl) benzoxazole.

Pyrenes Pyrenes useful in the present invention include those having formulas (28) and (29):

[0156]

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Wherein each R ⁶⁰¹ is independently C ₁ -C ₃₀ alkoxy; preferably methoxy; and

[0158]

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Wherein each R ⁶⁰² is independently H, OH or SO ₃ M, wherein M is as defined above, sulfonated phenylamino or anilino.

Suitable pyrenes include 2,4- having the trade name Fluolite XMF
Dimethoxy-6- (1′-pyrenyl) -1,3,5-triazine (CI fluorescent brightener 179), 8-hydroxy-1,3,6-pyrenetrisulfonic acid (Pharmaceutical and cosmetic green 8) No.) and 3-hydroxy-5,8,10-trisulfanylpyrene.

Porphyrins Porphyrins useful in the present invention include those having formulas (30), (31) and (32):

[0162]

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Wherein R ⁷⁰¹ is CH ₃ or CHO, R ⁷⁰² is H or COOC ₁ -C ₃₀ alkyl, and R ⁷⁰³ is H or an alkyl group having 1 to 30 carbons;
And

[0164]

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Wherein each R ⁷⁰⁴ is independently H, SO ₃ M, COOM, OSO ₃ M or OPO
(OH) OM where M is as defined above, halide or alkyl of 1 to 30 carbons; and Q ⁶ is Cu, Mg, Fe, Cr, C
o or a mixture thereof having a positive charge.

Suitable porphyrins include porphyrins available from Wako Chemicals and copper (II) phthalocyanines available from Wako Chemicals.

Imidazoles Imidazoles are a class of compounds having the following basic structure.

[0168]

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[0169] Imidazoles useful in the present invention include those of formula (33):

[0170]

Embedded image Wherein X ^- is as defined above.

Suitable imidazoles include C.I. I. One having the trade name of Fluorescent Brightener 352 or Uvtex available from Ciba Specialty Chemicals
AT is included.

Additional Conditioning Agents The compositions of the present invention may comprise an amphoteric conditioning polymer, a high melting point compound, a cationic surfactant, a high molecular weight ester oil, a cationic polymer, an additional oily compound, and mixtures thereof. It may further include additional conditioning agents selected. The additional conditioning agent is selected according to its compatibility with other components and the desired characteristics of the product. For example, components of cationic nature will be included in an amount that does not cause separation taking into account components of anionic and / or ampholytic nature. Additional conditioning agents in the present invention are used at the weight level of the composition, preferably from about 0.01% to about 10%.

Amphoteric Conditioning Polymers Amphoteric conditioning polymers useful in the present invention are compatible with carboxylic acid / carboxylate copolymers, and these polymers provide conditioning benefits to hair. Some amphoteric conditioning polymers in the present invention can have hair retention or hair fixation properties,
Such hair retention or hair fixation properties are not a requirement of the amphoteric conditioning polymer in the present invention. Amphoteric conditioning polymers useful in the present invention are those containing at least one cationic monomer and at least one anionic monomer; said cationic monomer being a quaternary ammonium, preferably a dialkyldiallylammonium chloride or a carboxamidoalkyltrialkylammonium. And the anionic monomer is a carboxylic acid. The amphoteric conditioning polymer in the present invention can include a nonionic monomer such as acrylamine, methacrylate or ethacrylate. Further, the amphoteric conditioning polymers useful in the present invention do not contain betainized monomers.

In the present invention, the CTFA designation Polyquaternium (Polyquaternium) 22,
Polymers having polyquaternium 39 and polyquaternium 47 are useful. Such polymers include, for example, copolymers of dimethyldiallylammonium chloride and acrylic acid, terpolymers of dimethyldiallylammonium chloride and acrylamide, and terpolymers of acrylic acid, methacrylamidopropyltrimethylammonium chloride and methyl acrylate, for example, A terpolymer of the formula: wherein the ratio of n ⁶ : n ⁷ : n ⁸ is 45:
45:10.

[0175]

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Highly preferred commercially available amphoteric conditioning polymers according to the present invention include MERQUAT® 280, polyquaternium 22 with a mercoat 295, Mercoat PLUS3330, Mercoat PLU.
Polyquaternium 39 having S3331, and trade name Marcoat 2001,
Included is Polyquaternium 47 with Marcoat 2001N, all of which are available from Calgon Corporation.

In the present invention, a vinyl monomer having at least one carboxyl group, for example, acrylic acid, methacrylic acid, maleic acid, itaconic acid, fumaric acid, crotonic acid or alpha-chloroacrylic acid, and at least one basic acid Also useful are basic monomers which are substituted vinyl compounds containing a nitrogen atom, such as dialkylaminoalkyl methacrylates and acrylates and polymers obtained from the copolymerization of dialkylaminoalkyl methacrylamides and acrylamides.

In the present invention: i) at least one monomer selected from acrylamide or methacrylamide in which an alkyl group is substituted on the nitrogen, ii) containing one or more reactive carboxyl groups At least one acid comonomer, and iii) an ester of acrylic acid and methacrylic acid having at least one basic comonomer, such as a primary, secondary and tertiary amine substituent and a quaternary ammonium substituent. Also useful are polymers containing units derived from the quaternization of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate.

Most particularly preferred N-substituted acrylamides or methacrylamides are the groups in which the alkyl group contains from 2 to 12 carbon atoms, in particular N-ethylacrylamide, N-tert-butylacrylamide, N-tert-octylacrylamide , N-octylacrylamide, N-decylacrylamide and N-dodecylacrylamide, and also the corresponding methacrylamide. The above acid comonomers are more particularly acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid and fumaric acid, and also the alkyl part of maleic acid or fumaric acid has 1 to 4 carbon atoms. It is selected from alkyl monoesters.

Preferred basic comonomers are aminoethyl, butylaminoethyl, N, N′-
Dimethylaminoethyl and N-tert-butylaminoethyl methacrylate.

Commercially available amphoteric conditioning polymers in the present invention include AMPHOMER, Amphomer SH701, Amphomer 28-4910, trade names supplied by National Starch & Chemical. An octyl acrylamine / acrylate / butylaminoethyl mesoacrylate copolymer having Amphomer LV71 and Amphomer LV47 is included.

High Melting Compounds The high melting compounds useful in the present invention are selected from the group consisting of fatty alcohols, fatty acids, fatty alcohol derivatives, fatty acid derivatives, hydrocarbons, steroids and mixtures thereof, and have a melting point of at least about 25 ° C. Have. One skilled in the art will appreciate that the compounds disclosed in this section of the specification may potentially fall into more than one category, for example, certain fatty alcohol derivatives may be classified as fatty acid derivatives. are doing. However, the classification given is not intended to be a limitation on that particular compound, but is for convenience of classification and nomenclature. Further, one skilled in the art will recognize that certain compounds having certain requisite carbon atoms, depending on the number and position of
It is understood that it may have a melting point below. Such low melting compounds are not intended to be included in this section. Examples of the above high melting point compounds are International Cosmetic Ingredient Dictionary (Inte
rnational Cosmetic Ingredient Dictionary), 5th edition, 1993 and CTF
A Cosmetic Ingredient Handbook
Handbook), Second Edition, found during, but not limited to, 1992.

It is believed that these high melting compounds cover the hair surface and reduce friction, thereby providing the hair with a smooth feel and easy combing.

The fatty alcohols useful in the present invention are those having about 14 to about 30 carbon atoms, preferably about 16 to about 22 carbon atoms. These fatty alcohols can be straight or branched chain alcohols and can be saturated or unsaturated. Examples of fatty alcohols include, but are not limited to, cetyl alcohol, stearyl alcohol, behenyl alcohol, and mixtures thereof.

Fatty acids useful in the present invention contain from about 10 to about 30 carbon atoms, preferably about 1 to about 30 carbon atoms.
Those having from 2 to about 22 carbon atoms, and more preferably from about 16 to about 22 carbon atoms. These fatty acids can be straight or branched chain acids, and can be saturated or unsaturated. Also included are diacids, triacids and other polyacids that meet the requirements of the invention. In the present invention, salts of these fatty acids are also included. Examples of fatty acids include, but are not limited to, lauric acid, palmitic acid, stearic acid, behenic acid, sebacic acid and mixtures thereof.

Fatty alcohol derivatives and fatty acid derivatives useful in the present invention include alkyl ethers of fatty alcohols, alkoxylated fatty alcohols, alkyl ethers of alkoxylated fatty alcohols, esters of fatty alcohols, and compounds having an esterifiable hydroxy group. Includes fatty acid esters, hydroxy-substituted fatty acids, and mixtures thereof. Examples of fatty alcohol derivatives and fatty acid derivatives are substances such as methyl stearyl ether; compounds of the ceteth series, for example from ceteth-1 to ceteth-45, which are ethylene glycol ethers of cetyl alcohol, the designations according to the above numbers being: Indicates the number of ethylene glycol moieties present; compounds of the steareth series, such as steareth-1, the ethylene glycol ether of steareth alcohol, from 1 to 10, wherein the designation by number above indicates the number of ethylene glycol moieties present Ceteareth alcohols, ie, Ceteareth 1 to Ceteareth-10, which are ethylene glycol ethers of fatty alcohol mixtures containing mainly cetyl and stearyl alcohol, the designations by the above numbers being used to refer to ethylene glycol Indicates the number of calls moiety; ceteth just described, steareth and C ₁ -C ₃₀ alkyl ethers of ceteareth compounds; behenyl polyoxyethylene ethers; ethyl stearate, cetyl stearate, cetyl palmitate, stearyl stearate, myristyl Myristate, polyoxyethylene cetyl ether stearate, polyoxyethylene stearyl ether stearate, polyoxyethylene lauryl ether stearate, ethylene glycol monostearate, polyoxyethylene monostearate, polyoxyethylene distearate, propylene glycol mono Stearate, propylene glycol distearate, trimethylolpropane distearate, sorbitan stearate, polyglyceryl stearate , Glyceryl monostearate, glyceryl distearate, but are glyceryl tristearate, and mixtures thereof, without limitation.

[0187] Hydrocarbons useful in the present invention include compounds having at least about 20 carbons. Steroids useful in the present invention include compounds such as cholesterol. High purity single compound high melting point compounds are preferred. Highly preferred is a single compound of pure fatty alcohols selected from the group of pure cetyl alcohol, stearyl alcohol and behenyl alcohol. By "pure" herein is meant that the compound has a purity of at least about 90%, preferably at least about 95%. These high purity single compounds provide good rinsing potential from the hair when the consumer rinses the composition.

Commercially available high melting compounds useful in the present invention include: Shin Nippon Rika (Sh
cetyl alcohol, stearyl alcohol, and behenyl alcohol having the KONOL series (trade name) available from Nihon Rika (Osaka, Japan) and the NAA series available from NF (NOF) (Tokyo, Japan); Wako (Japan Pure Behenyl Alcohol with the tradename 1-DOCOSANOL available from Osaka, Japan; NEO-FAT, Witco available from Akzo (Chicago, Ill., USA). Corp. (Witco Corp.
) (HYSTRENE) available from Dublin, Ohio, USA; and various fatty acids with DERMA available from Vevy, Genoa, Italy; and products available from Nikko Cholesterol with the name NIKKOL AGUASOME LA is included.

Cationic Surfactants Among the useful thione surfactants useful in the present invention are those corresponding to the general formula (I):

[0190]

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Wherein at least one of R ⁷¹ , R ⁷² , R ⁷³ and R ⁷⁴ is an aliphatic group of from 8 to 30 carbon atoms, or an aromatic, alkoxy having up to about 22 carbon atoms. , A polyoxyalkylene, an alkylamide, a hydroxyalkyl, an aryl or an alkylaryl group, wherein R ⁷¹ , R ⁷² , R ⁷³ and R ⁷⁴ independently represent a fatty acid of from 1 to about 22 carbon atoms. X or an aromatic, alkoxy, polyoxyalkylene, alkylamide, hydroxyalkyl, aryl or alkylaryl group having up to about 22 carbon atoms;
Is a salt-forming anion, such as one selected from halogen (eg, chloride, bromide), acetate, citrate, lactate, glycolate, phosphate, nitrate, sulfonate, sulfate, alkyl sulfate and alkyl sulfonate groups. The aliphatic group, in addition to carbon and hydrogen atoms,
It may contain ether linkages and other groups such as amino groups. Longer chain aliphatic groups, such as groups of about 12 or more carbons, can be saturated or unsaturated. R ⁷¹ , R ⁷² , R ⁷³ and R ⁷⁴ are independently:
Preferred when selected from C ₁ to about C ₂₂ alkyl. Examples of cationic surfactants useful in the present invention include materials having the following CTFA designations: Quaternium-8, Quaternium-14, Quaternium-18, Quaternium-18 mesosulfate, Quaternium-24, and mixtures thereof. However, it is not limited to these.

Among the cationic surfactants of the general formula (I), those containing at least one alkyl chain having at least 16 carbon atoms in the molecule are preferred. Examples of such preferred cationic surfactants include: for example, INCROQUAT TMC-80 from Croda or Sanyo Kas.
ei) behenyltrimethylammonium chloride available from ECONOL TM22; e.g., cetyltrimethylammonium chloride available from Nikko Chemicals under the trade name CA-2350; hydrogenated tallowalkyltrimethylammonium chloride, dialkyl (14-18) ) Dimethyl ammonium chloride, ditallow alkyl dimethyl ammonium chloride, dihydrogenated tallow alkyl dimethyl ammonium chloride, distearyl dimethyl ammonium chloride, dicetyl dimethyl ammonium chloride, di (behenyl / arachidyl)
Dimethyl ammonium chloride, dibehenyl dimethyl ammonium chloride, stearyl dimethyl behenyl ammonium chloride, stearyl propylene glycol phosphate dimethyl ammonium chloride, stearoyl amide propyl dimethyl benzyl ammonium chloride, stearoyl amido propyl dimethyl (myristyl acetate) ammonium chloride, and N- (stearoyl colamino) (Formylmethyl) pyridinium chloride.

At least one of the substituents contains one or more aromatic, ether, ester, amide or amino moieties which are present as substituents or as bonds in the backbone, and At least one of the R ^{71 to} R ⁷⁴ groups is an alkoxy (preferably C _{1 to} C ₃ alkoxy), a polyoxyalkylene (preferably a C ₁
-C ₃ polyoxyalkylene), alkylamido, hydroxyalkyl, and alkyl esters and cationic surfactants are hydrophilically substituted containing one or more hydrophilic moieties selected from combinations thereof preferred . Preferably, the hydrophilically substituted cationic conditioning surfactant contains from 2 to about 10 nonionic hydrophilic moieties located within the ranges set forth above. Preferred hydrophilically substituted cationic surfactants include compounds of the following formula (II)
) To (VIII) are included:

[0194]

Embedded image

Wherein n ¹ is from 8 to about 28, m ¹ + m ² is from 2 to about 40,
Z ¹ is a short chain alkyl, preferably C ₁ -C ₃ alkyl, or more preferably methyl _{(CH 2 CH 2 O) m3} H, this time m ¹ + m ² + m ³ is up to 60, And X is a salt-forming anion as defined above;

[0196]

Embedded image

Wherein n ² is 1 to 5, and one or more of R ⁷⁵ , R ⁷⁶ and R ⁷⁷ is independently C ₁ -C ₃₀ alkyl, and the remainder is CH ₂ CH ₂ OH and R ⁷⁸
, R ⁷⁹ and R ⁸⁰ are independently C ₁ -C ₃₀ alkyl;
And the remainder is CH ₂ CH ₂ OH, and X is a salt-forming anion as described above;

[0198]

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Wherein, for formulas (IV) and (V), independently Z ² is alkyl, preferably C ₁ -C ₃ alkyl, more preferably methyl, and Z ³ is a short chain hydroxy Alkyl, preferably hydroxymethyl or hydroxyethyl,
n ³ and n ⁴ are independently an integer from 2 to 4 (inclusive), preferably from 2 to 3 (inclusive), and more preferably 2, and R ⁸¹ and R ⁸² are independently to, substituted or unsubstituted hydrocarbyl, C ₁₂ -C ₂₀ alkyl or alkenyl,
And X is a salt-forming anion as defined above;

[0200]

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Wherein R ⁸³ is hydrocarbyl, preferably C ₁ -C ₃ alkyl, more preferably methyl, and Z ⁴ and Z ⁵ are independently short chain hydrocarbyl, preferably C ₂
-C ₄ alkyl or alkenyl, more preferably ethyl, m ⁴ is from 2 to about 4
0, preferably from about 7 to about 30, and X is a salt-forming anion as defined above;

(VII) wherein R ⁸⁴ and R ⁸⁵ are independently C ₁ -C ₃ alkyl, preferably methyl, and Z ⁶ is C ₁₂ -C ₂₂ hydrocarbyl, alkylcarboxy or alkylamide. And A is a protein, preferably collagen, keratin, milk protein, silk, soy protein, wheat protein or a hydrolyzed form thereof; and X is a salt-forming anion as defined above;

[0203]

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Wherein n ⁵ is 2 or 3, R ⁸⁶ and R ⁸⁷ are independently C ₁ -C ₃ hydrocarbyl, preferably methyl, and X is as defined above. It is a salt-forming anion. Examples of hydrophilically substituted cationic surfactants useful in the present invention include the following CTFA names: Quaternium-16, Quaternium-26,
Quaternium-27, Quaternium-30, Quaternium-33, Quaternium-43, Quaternium-52, Quaternium-53, Quaternium-56, Quaternium-60, Quaternium-61, Quaternium-6
2, Quaternium-70, Quaternium-71, Quaternium-72, Quaternium-75, Quaternium-76 hydrolyzed collagen, Quaternium-77, Quaternium-78, Quaternium-79 hydrolyzed collagen,
Quaternium-79 hydrolyzed keratin, quaternium-79 hydrolyzed milk protein, quaternium-79 hydrolyzed silk, quaternium-79 hydrolyzed soy protein and quaternium-79 hydrolyzed wheat protein, quaternium-80, quaternium-81, quaternium-82, Quaternium-
83, quaternium-84, and mixtures thereof, including but not limited to.

Highly preferred hydrophilically substituted cationic surfactants include dialkylamidoethyl hydroxyethylmonium salts, dialkylamidoethyldimonium salts, dialkiloylethylhydroxyethylmonium salts, dialkiloylethidimonium salts Salts and mixtures thereof; these include, for example, the following trade names: Witco Chemical's Varisoft 110, Varisoft 222, Variquat K1215 and Varicoat 638, Mac Intyre (McIntyre) MacPro KLP, MacPro WLW, MacPro MLP, MacPro NSP, MacPro NLW, MacPro WWP, MacPro NLP, MacPro SLP, Akzo's ETHOQUAD 18 /
25, ethquad 0 / 12PG, ethquad C / 25, ethquad S / 2
5 and ETHODUOQUAD, Henkel's DEHYQUAT and ICI Americas' Atlas (AT)
LAS) G265.

Amines are suitable as cationic surfactants. Primary, secondary and tertiary fatty amines are useful. Tertiary amidoamines having alkyl groups of from about 12 to about 22 carbons are particularly useful. Representative tertiary amidoamines include: stearamidopropyldimethylamine, stearamidopropyldiethylamine, stearamidoethyldiethylamine, stearamidoethyldimethylamine, palmitamidopropyldimethylamine, palmitamidopropyldiethylamine, palmitamidoethyldiethylamine , Palmitamidoethyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethylamine, behenamidoethyldimethylamine, arachidoamidopropyldimethylamine, arachidoamidopropyldiethylamine, arachidoamidoethyldiethylamine, arachidoamidoethyldimethyl Amines and diethylaminoethyl stearamide. Dimethyl stearamine, dimethyl soiamine, soiamine, myristylamine, tridecylamine, ethylstearylamine, N-tallowpropanediamine, ethoxylated (using 5 moles of ethylene oxide) stearylamine, dihydroxyethylstearylamine and arachidylbehenylamine Is also useful. Amines useful in the present invention are nactigal (
Nachtigal) et al., US Pat. No. 4,275,055.

These amines may also be acids, such as 1-glutamic acid, lactic acid, hydrochloric acid, malic acid,
It can be used in combination with succinic acid, acetic acid, fumaric acid, tartaric acid, citric acid, 1-glutamic acid hydrochloride, maleic acid and mixtures thereof, more preferably 1-glutamic acid, lactic acid and citric acid. The amine in the present invention is preferably about 1
: 0.3 to about 1: 2, more preferably about 1: 0.4 to about 1: 1 amine to acid molar ratio, partially neutralized with any of the above acids.

High Molecular Weight Ester Oils High molecular weight ester oils are useful in the present invention. High molecular weight ester oils useful in the present invention are water-insoluble and have at least about 500, preferably at least about 8
It has a molecular weight of 00 and is in liquid form at 25 ° C. Useful high molecular weight ester oils in the present invention include pentaerythritol ester oils, trimethylol ester oils, poly alpha-olefin oils, citrate ester oils, glyceryl ester oils and mixtures thereof. As used herein, the term “water-insoluble” means that the compound is not substantially soluble in water at 25 ° C .; When mixed with water at concentrations greater than wt%, the compound temporarily disperses to form an unstable colloid in water, which then rapidly separates from the water into two phases.

The high molecular weight ester oils of the present invention provide conditioning benefits such as moisture, smooth feel and ease of handling when the hair dries, but do not leave the hair with an oily feel. It is generally believed that water-insoluble oils can deposit on the hair. While not being bound by theory, it is believed that high molecular weight ester oils, due to their bulkiness, cover the hair surface, and consequently, high molecular weight ester oils reduce hair friction and give hair smoothness and ease of handling . Although high molecular weight ester oils have some hydrophilic groups, they provide a moist feeling, but since this is a liquid, it is not believed to leave an oily feel on the hair. The high molecular weight ester oil is chemically stable under normal use and storage conditions.

[0210] Pentaerythritol ester oils useful in the present invention are those having the following formula:

[0211]

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Wherein R ¹ , R ² , R ³ and R ⁴ are independently branched, straight chain, saturated or unsaturated alkyl, aryl and alkylaryl having from 1 to about 30 carbons Group. Preferably, R ¹ , R ² , R ³ and R ⁴ are independently a branched, straight chain, saturated or unsaturated alkyl group having about 8 to about 22 carbons. More preferably, R ¹ , R ² , R ³ and R ⁴ are defined such that the molecular weight of the compound is from about 800 to about 1200.

[0213] Trimethylol ester oils useful in the present invention are those having the following formula:

[0214]

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In the formula, R¹¹Is an alkyl group having 1 to about 30 carbons and R ¹² , R¹³And R¹⁴Is independently a branched chain having from 1 to about 30 carbons,
Chains, saturated or unsaturated alkyl, aryl and alkylaryl groups. Preferred
Or R¹¹Is ethyl and R¹², R¹³And R¹⁴Independently from 8 to about
A branched, straight-chain, saturated or unsaturated alkyl group having up to 22 carbons. Change
Preferably, R¹¹, R¹², R¹³And R¹⁴Is that the molecular weight of the above compound is about 800
Up to about 1200.

[0216] The polyalphaolefin oil useful in the present invention has the formula: and from about 1 to about 35,
Have a viscosity of up to 000 cst, a molecular weight of about 200 to about 60,000 and a polydispersity of only about 3;

[0219]

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Wherein R ³¹ is alkyl having about 4 to 14 carbons, preferably 4 to 10 carbons. Polyalphaolefin oils having a molecular weight of at least about 800 are useful in the present invention. It is believed that such high molecular weight poly-α-olefin oils provide a long-lasting moist feeling to the hair. Polyalphaolefin oils having a molecular weight of less than about 800 are useful in the present invention. Such low molecular weight poly alpha olefin oils are believed to provide a smooth, light, clean feel to the hair.

Citrate ester oils useful in the present invention have at least about 5
It has a molecular weight of 00:

[0220]

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Wherein R ²¹ is OH or CH ₃ COO and R ²² , R ²³ and R ²⁴ are independently branched, linear, saturated having from 1 to about 30 carbons. Or unsaturated alkyl, aryl and alkylaryl groups. Preferably, R ²¹ is OH and R ²² , R ²³ and R ²⁴ are independently branched, straight-chain, saturated or unsaturated alkyl, having 8 to about 22 carbons, aryl and It is an alkylaryl group. More preferably, R ²¹ , R ²² , R ²³ and R ²⁴ are defined such that the molecular weight of the compound is at least about 800.

The glyceryl ester oil useful in the present invention has a molecular weight of at least about 500 and has the following formula:

[0223]

Embedded image

Wherein R ⁴¹ , R ⁴² and R ⁴³ are independently branched, straight-chain, saturated or unsaturated alkyl, aryl and alkylaryl groups having from 1 to about 30 carbons . Preferably, R ⁴¹ , R ⁴² and R ⁴³ are independently branched, straight chain, saturated or unsaturated alkyl, aryl and alkylaryl groups having from 8 to about 22 carbons. More preferably, R ⁴¹ , R ⁴² and R ⁴³ are defined such that the molecular weight of the compound is at least about 800.

Particularly useful pentaerythritol ester oils and trimethylol ester oils in the present invention include pentaerythritol tetraisostearate, pentaerythritol tetraoleate, trimethylolpropane triisostearate, trimethylolpropane trioleate and mixtures thereof. Is included. Such compounds are available under the trade names KAKPTI, KAKTI and Kokyo Alcohol (Koky Alcohol).
o Alcohol) and from Nippon Rika under the trade name PTO, ENUJERUBUTP3SO.

Particularly useful poly-α-olefin oils in the present invention include Mobil Chemical
PURESYN 6 having a number average molecular weight of about 500, available from Mobil Chemical Co., and Pressin 100 having a number average molecular weight of about 3000, and Pressin 300 having a number average molecular weight of about 6000. And polydecenes having the formula:

Particularly useful citrate ester oils in the present invention are triisocetyl citrate having the trade name Cytomol 316 available from Bernel, Peremol trade name available from Phoenix. (PELEMOL) T
Includes triisostearyl citrate with ISC, and trioctyldodecyl citrate with tradename Cytomol 320 available from Burnel.

Particularly useful glyceryl ester oils in the present invention include Taiyo Kaga
ku), a triisostearin having the trade name SUN ESPOL G-318, Kuroda Surfactants Altidi. (Croda Surf
actants Ltd.) available under the trade name CITHROL GTO, triolein, available from Vevy under the trade name EFADER
MA-F) or EFA-GLYCERIDES (trade name, available from Brooks).

Cationic Polymers Cationic polymers are useful in the present invention. As used herein, the term "polymer" will include substances made by the polymerization of one type of monomer or made of two (ie, copolymer) or more types of monomers.

Preferably, the cationic polymer is a water-soluble cationic polymer. A "water-soluble" cationic polymer means 0.1% in water (distilled or equivalent) at 25 ° C.
It is a polymer that is sufficiently soluble in water to form a substantially clear solution with the naked eye at a concentration of 100%. The preferred polymer is a concentration of 0.5%, more preferably 1%.
. It will be sufficiently soluble to form a substantially clear solution at 0% concentration.

The cationic polymers of the present invention will generally have an average molecular weight of at least about 5,000, typically at least about 10,000 and less than about 10 million. Preferably, the molecular weight is from about 100,000 to about 2,000,000
It is. Cationic polymers generally have a cationic nitrogen-containing moiety, such as a quaternary ammonium or cationic amino moiety and mixtures thereof.

Any anionic counterion to the cationic polymer can be utilized as long as the water solubility criteria are satisfied. Suitable counterions include halide (eg, Cl, Br, I, or F, preferably Cl, Br, or I) sulfate, and methyl sulfate. This list is not exclusive, so you can use others

The cationic nitrogen-containing moiety is generally present as a substituent on a fraction of the total monomer units of the cationic hair conditioning polymer. Thus, the cationic polymer can include copolymers, terpolymers, etc. of quaternary ammonium or cationic amine substituted monomer units and other non-cationic units referred to herein as spacer monomer units. Such polymers are known in the art and are available from CTFA Cosmetic Ingredient Dictionary, Third Edition, Estrin, Crosley (
Crosley) and Haynes (The Cosmetic, Toiletry, and Fragran)
ce Association, Inc., Washington, D.C. C. , 1982).

The cationic amine can be a primary, secondary or tertiary amine, depending on the particular species and pH of the composition of the present invention. Generally, secondary and tertiary amines are preferred, especially tertiary amines

The amine-substituted vinyl monomer can be polymerized in amine form, and then optionally converted to ammonium by a quaternization reaction. The amine can also be quaternized after the polymer has been formed. For example, a quaternary amine functionality is represented by the formula R ⁸⁸ X, where R ⁸⁸ is a short chain alkyl, preferably C ₁ -C ₁ .
C ₇ alkyl, more preferably a C ₁ -C ₃ alkyl, and X can be quaternized by reaction with a salt of a salt-forming anion as defined above).

Suitable cationic amino and quaternary ammonium monomers include, for example, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates,
Monoalkylaminoalkyl acrylates, vinyl compounds substituted with monoalkylaminoalkyl methacrylates, trialkylmethacryloxyalkylammonium salts, trialkylacryloxyalkylammonium salts, diallyl quaternary ammonium salts, and pyridinium, imidazolium and quaternized Vinyl quaternary ammonium monomers having a cyclic cation nitrogen-containing ring such as pyrrolidone,
For example, alkyl vinyl imidazolium, alkyl vinyl pyridinium, and alkyl vinyl pyrrolidone salts are included. The alkyl portion of these monomers is preferably a C ₁ -C ₃ alkyl group, more preferably a lower alkyl group such as a C ₁ and C ₂ alkyl group. Suitable amine-substituted vinyl monomers for use in the present invention include dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, dialkylaminoalkyl acrylamides, and dialkylaminoalkyl methacrylamides, where the alkyl group is preferably C ₁
-C ₇ hydrocarbyl, more preferably a C ₁ -C ₃ alkyl.

The cationic polymer may comprise a mixture of monomer units derived from amine- and / or quaternary ammonium-substituted monomers and / or compatible spacer monomers.

Suitable cationic hair conditioning polymers include, for example, copolymers of 1-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazolium salt (eg, chloride salt) (Cosmetic, Toiletry, and Fragrance Association, That is, it is referred to in the industry as "Polyquaternium-16" by "CTFA"), for example, Basff Wyandotte Corp. (BASF Wyandotte Corp.
) (Parsippany, NJ, USA) under the trade name LUVIQUAT (eg, Rubiquat FC370); a copolymer of 1-vinyl-2-pyrrolidone and dimethylaminoethyl methacrylate (C
TFA has designated it as polyquaternium-11 in this field of industry),
For example, the trade name of GAFQUAT from Gaf Corporation (Wayne, NJ, USA) (eg, GAFQUAT 7)
55N) commercially available, for example, dimethyldiallylammonium chloride homopolymer and acrylamide and dimethyldiallylammonium chloride, referred to in the art (CTFA) as polyquaternium 6 and polyquaternium 7, respectively. Cationic diallyl quaternary ammonium containing polymers, including copolymers of the following: and as described in US Patent 4,009,256.
Includes mineral acid salts of aminoalkyl esters of homo- and copolymers of unsaturated carboxylic acids having from 3 to 5 carbon atoms.

Other cationic polymers that can be used include polysaccharide polymers, such as cationic cellulose derivatives and cationic starch derivatives.

The cationic polysaccharide polymer materials suitably used in the present invention include those of the following formula:

[0241]

Embedded image

Wherein Z ⁷ is an anhydroglucose residue, such as a starch or cellulose anhydroglucose residue, R ⁸⁹ is an alkyleneoxyalkylene, polyoxyalkylene or hydroxyalkylene group or a combination thereof; ⁹⁰ , R ⁹¹ and R ⁹² are independently an alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl group, wherein each group contains up to about 18 carbon atoms and Total number of carbon atoms in the cation moiety (
That is, the sum of the carbon atoms of R ⁹⁰ , R ⁹¹ and R ⁹² ) is preferably about 20 or less, and X is as described above.

[0243] Cationic cellulose is manufactured by Amercol Corp. (Amerchol Corp.) (Edison, NJ, USA) from Polymer JR® and LR
A series of polymers, available as a salt of hydroxyethylcellulose reacted with a trimethylammonium-substituted epoxide, and which is designated Polyquaternium 10 in the field of industry (CTFA). Another type of cationic cellulose includes a polymeric quaternary ammonium salt of hydroxyethyl cellulose reacted with a lauryl dimethyl ammonium substituted epoxide, which is referred to as polyquaternium 24 in the field of industry (CTFA). I have. These materials are available from Amercol Corp. (Edison, NJ, USA) under the trade name Polymer LM-200®.

Other cationic polymers that can be used include cationic guar gum derivatives such as Celanese Corp. Guar hydroxypropyltrimonium chloride, commercially available in Jaguar R series from (Celanese Corp.). Other materials include quaternary nitrogen-containing cellulose ethers as described in US Pat. No. 3,962,418 and copolymers of etherified cellulose and starch as described in US Pat. No. 3,958,581. included.

Particularly useful cationic polymers in the present invention include polyquaternium-7, polyquaternium-10, polyquaternium-24, and mixtures thereof.

Additional Oil Compounds Additional oil compounds useful in the present invention include fatty alcohols and their derivatives, fatty acids and their derivatives, and hydrocarbons. Additional oily compounds useful in the present invention can be volatile or non-volatile and have a melting point below about 25 ° C. Without being bound by theory, these additional oily compounds can penetrate the hair and modify the hydroxy bonds of the hair, and thereby provide the hair with smoothness and flexibility. The additional oily compounds in this section should be distinguished from the high melting point compounds described above. Examples of these additional oily compounds are found in the International Cosmetic Ingredient Dictionary, 5th Edition, 1993, and the CTFA Cosmetic Ingredient Handbook, 2nd Edition, 1992, It is not limited to these.

The fatty alcohols useful in the present invention contain from about 10 to about 30 carbon atoms, preferably from about 12 to about 22 carbon atoms, and more preferably about 16 carbon atoms.
And up to about 22 carbon atoms. These fatty alcohols can be straight or branched chain alcohols and can be saturated or unsaturated alcohols, preferably unsaturated alcohols. Examples of these compounds include oleyl alcohol, palmitoleic alcohol, isostearyl alcohol, isocetyl alcohol, undecanol, octyldodecanol, octyldecanol, octyl alcohol, caprylic alcohol, decyl alcohol, and lauryl alcohol. It is not limited to.

[0248] Fatty acids useful in the present invention include from about 10 to about 30 carbon atoms, preferably from about 12 to about 22 carbon atoms, and more preferably from about 16 to about 22 carbon atoms. Are included. These fatty acids can be straight or branched chain acids, and can be saturated or unsaturated. Suitable fatty acids include, for example, oleic acid, linoleic acid, isostearic acid, linolenic acid, ethyl linolenic acid, ethyl linolenic acid, arachidonic acid and ricinoleic acid.

As used herein, fatty acid derivatives and fatty alcohol derivatives include, for example, esters of fatty alcohols, alkoxylated fatty alcohols, alkyl ethers of fatty alcohols, alkyl ethers of alkoxylated fatty alcohols, and bulky ester oils such as pentaerythritol esters It is defined to include oils, trimethylol ester oils, citrate ester oils, glyceryl ester oils and mixtures thereof. Examples of fatty acid derivatives and fatty alcohol derivatives include, for example, methyl linoleate, ethyl linoleate, isopropyl linoleate, isodecyl oleate, isopropyl oleate, ethyl oleate, octyl dodecyl oleate,
Oleyl oleate, decyl oleate, butyl oleate, methyl oleate, octyl dodecyl stearate, octyl dodecyl isostearate, octyl dodecyl isopalmitate, octyl isoperargonate, octyl pelargonate, hexyl isostearate, isopropyl isostearate Rates include, but are not limited to, isodecyl isononanoate, isopropyl stearate, ethyl stearate, methyl stearate, and oleth-2. Bulk ester oils such as pentaerythritol ester oil, trimethylol ester oil, citrate ester oil, and glyceryl ester oil useful in the present invention are about 800
Less than about 500, preferably less than about 500.

Hydrocarbons useful in the present invention include straight chain, cyclic and molecular chain hydrocarbons which can be either saturated or unsaturated, as long as they have a melting point of at most about 25 ° C. It is. These hydrocarbons have from about 12 to about 40 carbon atoms,
It preferably has about 12 to about 30 carbon atoms, and preferably about 12 to about 22 carbon atoms. The present invention also includes polymer hydrocarbons of alkenyl monomers, for example, polymers of C _2-6 alkenyl monomers.
These polymers can be linear or branched polymers. These linear polymers are typically relatively short in length and have a total number of carbon atoms as described above. The branched polymer can have a substantially longer chain length. The number average molecular weight of such materials can vary widely, but will typically be up to about 500, preferably from about 200 to about 400, and more preferably from about 300 to about 350. Various grades of mineral oils are also useful in the present invention. Mineral oil is a liquid mixture of hydrocarbons obtained from petroleum. Particular examples of suitable hydrocarbon materials include paraffinic oil, mineral oil, dodecane, isododecane, hexadecane, isohexadecane, eicosene, isoeicosene, tridecane, tetradecane, polybutene, polyisobutene and mixtures thereof. For use in the present invention, preference is given to mineral oils, polyalphaolefin oils, for example hydrocarbons selected from the group consisting of isododecane, isohexadecane, polybutene, polyisobutene, and mixtures thereof.

The commercially available fatty alcohols and derivatives thereof useful in the present invention include: UNJECOL 90BHR available from Shin Nippon Rika
Oleyl alcohol having the trade name SCHERCEMOL series available from Scher, and hexyl isostearate having the trade name HIS available from Kokyu Alcohol And isopropyl isostearate with ZPIS. Useful and commercially available bulky ester oils in the present invention include: trimethylolpropanetri with the trade name MOBIL ESTER P43 from Mobil Chemical Co. Caprylate / tricha plates are included. Commercially available hydrocarbons useful in the present invention include PERMETHYL 99A, available from Presperse (South Plainfield, NJ, USA);
Isododecane, isohexadecane and isoeicosene having permethyl 101A and permethyl 1082, a copolymer of isobutene and normal butene having the trade name INDOPOL H-100 available from Amoco Chemicals (Chicago, Ill., USA); Exxon C, a mineral oil with the trade name Benol available from Witco
Chemical Co.) (Houston, Tex., USA) with the isoparaffin (ISOPAR) trade name. (Houston Texas, USA.)

Additional Components The compositions of the present invention may include additional components, which may be selected by one skilled in the art according to the desired characteristics of the final product, and the compositions of the present invention. Is suitable to make it more cosmetically or cosmetically acceptable,
Alternatively, it is suitable for providing additional use benefits to the composition of the present invention. Additional components include, for example, UV absorbers, herbal extracts, and other additional components.

UV Absorbers The compositions of the present invention may contain UV (ultraviolet) absorbers. UV absorbers are particularly useful for the substantially transparent compositions of the present invention. UV absorber in the present invention,
It is used at a weight level of the composition, preferably from about 0.01% to about 10%.

The UV absorbers useful in the present invention can be water-soluble or water-insoluble, and include p-aminobenzoic acid, its salts and derivatives (ethyl, isobutyl, glyceryl esters; p-dimethylaminobenzoic) Acid); anthranilate (ie, methyl o-aminobenzoate, menthyl, phenyl, benzyl, phenylethyl, linalyl, terpinyl and cyclohexenyl ester); salicylate (amyl, phenyl, benzyl, menthyl, glyceryl and dipropylene glycol ester) ); Cinnamic acid derivatives (menthyl and benzyl esters, -phenylcinnamonitrile); butylcinnamoylpyruvate; trihydroxycinnamic acid derivatives (esculetin, methylesculetin, daphnetin and glucoside, esculin and Dibenzalacetone and benzalacetophenone; naphthol sulfonate (sodium salt of 2-naphthol-3,6-disulfonic acid and 2-naphthol-6,8-disulfonic acid); dihydroxy-naphthoic acid and salts thereof; o -And p-hydroxybiphenyl disulfonates; quinine salts (bisulfate, sulfate, chloride, oleate and tannate); quinoline derivatives (8-hydroxyquinoline salt, 2-phenylquinoline); hydroxy- or methoxy-substituted benzophenones; Tannic acid and its derivatives (for example, hexaethyl ether); (butyl carbyl) (6-propylpiperonyl) ether; hydroquinone; benzophenone (oxybenzene, slisobenzone, dioxybenzone, Benzoresorcinol, 2,2 ', 4,4'-tetrahydroxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, octabenzone); 4-isopropyldibenzoylmethane; butylmethoxydibenzoylmethane; ethacrylene And 4-isopropyl-di-benzoylmethane. Among these, 2-ethylhexyl p-methoxycinnamic acid, 4,4'-t-butylmethoxydibenzoylmethane, 2-hydroxy-
4-methoxybenzophenone, octyldimethyl p-aminobenzoic acid, digalloyl trioleate, 2,2-dihydroxy-4-methoxybenzophenone, ethyl 4- [bis (hydroxypropyl)] aminobenzoate, 2-ethylhexyl 2-cyano-3 , 3-Diphenyl acrylate, 2-ethylhexyl salicylate, glyceryl p-aminobenzoate, 3,3,5-trimethylcyclohexyl salicylate, methyl anthranilate, p-dimethyl-aminobenzoic acid or aminobenzoate, 2-ethylhexyl p-Dimethylamino-benzoate, 2-phenylbenzimidazole-5-sulfonic acid, 2- (p-dimethylaminophenyl) -5-sulfonic benzoxazonic acid and mixtures thereof. Preferred sunscreen agents useful in the compositions of the present invention are 2-ethylhexyl p-methoxycinnamic acid, butylmethoxydibenzoylmethane, 2-hydroxy-4-methoxybenzophenone, octyldimethyl p-aminobenzoic acid and mixtures thereof. is there.

Herbal Extract The composition of the present invention may further contain an herbal extract. Herbal extracts useful in the present invention include those that are water-soluble and those that are insoluble in water. Useful herbal extracts in the present invention include: Tsurukudami extract, Pterodactyl extract, Yellowfin bark extract, Chinese smelt extract, white dead nettle
Extract, licorice root extract, herbal button extract, soapwort extract, loofah extract, china peel extract, vine saxifrage extract, Sophora angustifolia extract, candock extract Stuff, chamomile extract, primrose extract, rose extract, pheasant extract, lemon extract, sicon extract, aloe extract, iris root extract, eucalyptus extract, horsetail extract,
Sage extract, thyme extract, tea extract, amanori extract, cucumber extract,
Clove extract, raspberry extract, melissa extract, melissa extract, carrot extract, horse chestnut extract, peach extract, peach leaf extract, mulberry extract, cornflower extract, hamamelis Extract, placenta extract, thymus extract, silk extract, algae extract, hollyhock extract, osseous extract, apple extract, apricot kernel extract, ragweed extract, sagebrush extract, talus extract, and horse mackerel Extract, perilla extract, birch bark extract, daisy bark extract, tea tree extract, burdock root extract, waremokou extract, Nagakada extract, Stephania cepharantha (Stephania cepharantha)
) Extracts, daisies extract, chrysanthemum flower extract, Satsuma Mandarin peel extract, cnidium extract, coix seed extract, cane extract, fillet leaf extract, hawthorn extract, pine primrose Oil, Gambir extract, Ganoderma extract, Gardenia extract, Gentian root extract, Geranium extract, Ginkgo extract, Grape leaf extract, Hawthorn extract, Prunus japonicus extract, Honeysuckle extract, Honeysuckle flower Extract, Heel
en) extract, hop extract, horsetail extract, hydrangea extract, hypericum extract, isodonis extract, isola ivy extract, arachis extract,
Japanese coptis extract, juniper extract, jujube extract, japonicus extract, lavender extract, lettuce extract, licorice extract, linden extract, murasaki extract, loquat extract, loofah extract, Malloti extract, mallow extract, calendula extract, moutan
) Bark extract, mistletoe extract, mukurossi extract, mugwort extract, mulberry root extract, nettle extract, nutmeg extract, orange extract, parsley extract, hydrolyzed conchiorin protein, button Root extract, peppermint extract, philodendron extract, pine cone extract, platicodone (
platycodon extract, mamadokoro extract, rehmannia extract, rice bran extract, rhubarb extract, rosehip extract, rosemary extract, royal jelly extract, safflower extract, saffron crocus extract, elderberry extract Thing, saponaria (saponaria) extract, Sasa albo marginata (Sasa albo mar
ginata) extract, Saxifraga extract, Scutellaria root extract, Cortinelas (Co
rtinellus) shiitake extract, purple extract, sophora extract, bay extract, shobu root extract, assembly extract, thyme extract, linden extract, tomato extract, turmeric extract, uncaria (uncaria) ) Extracts, Capsicum extract, Logwood extract, Grape extract, White lily extract, Wild rose extract, Wildflower extract, Mansac extract, Yarrow extract, Yeast extract, Yucca extract Stuff, salamander extract and mixtures thereof.

[0256] Commercially available herbal extracts useful in the present invention include those that are soluble in water and are available from the Institute of Occupational Medicine.
of Occupational Medicine, CAPM, China National Light Industry and Maruzen, as well as those listed above available from Maruzen Contains herbal extracts.

Other Additional Components A wide variety of other additional components can be formulated in the compositions of the present invention.
These include: Other conditioning agents, such as hydrolyzed collagen with the trade name Peptein 2000 available from Hormel, vitamins with the trade name Emix-d available from Eisai E, panthenol available from Roche, panthenyl ethyl ether available from Roche, hydrolyzed keratin, proteins, plant extracts and nutrients; hair fixing polymers such as amphoteric fixing polymers, cationic fixing Preservatives such as benzyl alcohol, methyl paraben, propyl paraben and imidazolidinyl urea; pH regulators such as citric acid, sodium citrate; Succinic acid Acids, sodium hydroxide, sodium carbonate; generally, salts such as potassium acetate and sodium chloride; coloring agents, such as food, pharmaceutical and cosmetic or pharmaceutical and cosmetic dyes; hair oxidizing (bleaching) agents, such as hydrogen peroxide Hair reducing agents, such as thioglycolate; fragrances; and sequestering agents, such as disodium ethylenediaminetetraacetate; ultraviolet and infrared screens and absorbers such as octyl salicylate, perborate and persulfate salts;
Antidandruff agents such as zinc pyrithione; and mixtures thereof.

EXAMPLES The following examples further describe and illustrate embodiments within the scope of the present invention. These examples are provided for illustrative purposes only, and many modifications of the present invention are possible without departing from the spirit and scope of the present invention and should be construed as limiting the invention. is not. Components are identified by chemical or CTFA name, or otherwise defined below.

[0259]

[Table 1]

[0260]

[Table 2]

Compound Definition 1 Visible Particle 1: Unspheres available from Induchem
AGE-527 2 Visible Particles 2: Unispheres YE-501 available from Induchem 3 Visible Particles 3: Uniserin C-304 available from Induchem Visible Particles 4: Unispheres UEA available from Induchem -509 5 Vitamin E: Emix-d available from Eisai. 6 Acrylic acid / alkyl acrylate copolymer 1: B.F. PEMULEN TR-17 acrylic acid / alkyl acrylate copolymer 2, available from BF Goodrich 2: BF. PEMULEN TR-28 carbomer 1 available from Goodrich 1: B.F. Carbopol available from Goodrich (Ca
rbopol) 981 9 carbomer 2: BF. Carbopol Ultrez 1010 acrylate / steareth-20 methacrylate copolymer available from Goodrich: Acrysol 22 available from Rohm and Haas

11 Bentonite: Bentonite available from Southern Clay 12 Aluminum magnesium silicate: Gelwhite MAS-L 13 available from Southern Clay 13 Cetyl hydroxyethylcellulose: Polysurf available from Aqualon ( Polysurf) 67 14 Hydroxyethylcellulose: Amarcol polymer HM-1500 commercially available from Amarcol 15 Monoxinylhydroxyethylcellulose: Amarchol polymer HM-1500 16 commercially available from Amarcol Triethanolamine: from Nippon Shokubai Available Triethanolamine 17 Dimethicone and Dimethiconol: DC Available from Dow Corning
Q2-1403 18 Cyclomethicone / Dimethiconol: D available from Dow Corning
CQ2-140119 Cyclomethicone / Dimethicone: G available from Shin-Etsu
um / cyclomethicone blend 20 Cyclomethicone: DC345 available from Dow Corning

21 Panthenol: Panthenol available from Roche 22 Alkyl silicone emulsion: Alkyl grafted copolymer silicone emulsion DC2-2845 available from Dow Corning 23 Polyquaternium-39: Available from Calgon Merquat Plus 3330 24 polyquaternium-47: Merquat available from Calgon (Merqua
t) 2001 25 Polyquaternium-22: Mercoat available from Calgon 280 26 Polyquaternium-24: Polymer LM available from Amarcol
200 27 PEG-2M: Polyox (available from Amerchol)
Polyox) PEG2M 28 polyethylene glycol 200: Union Carbide
Carbowax PEG 200 29 Hexylene glycol available from Mitsui Toatsu 30 Behenyl trimethyl ammonium chloride: INCROQUAT TMC- available from Croda 80

31 Pentaerythritol tetraoleate: Shinnihon Rika
Pentaerythritol tetraoleate 32 Aloe extract available from Ichimaru Farcos Aloe extract Vera 33 obtained from Ichimaru Farcos 33 Turdkudami Extract: Occupational M
edicine), an extract of turkudukami obtained from CAPM 34 Ginseng: Occupational Medicine, Ginseng available from CAPM 35 Benzophenone-4: Uvnus available from BASF (BASF)
l) MS-4036 octylmethoxycinnamic acid: Parasol MCX 37 2,4-dimethoxy-6- (1'pyrenyl) -1,3,5-triazine available from Roche:
2,4-Dimethoxy-6- (1 ′) available from Ciba Geigy
Pyrenyl) -1,3,5-triazine 38 porphyrin: porphyrin available from Wako Chemicals

Preparation methods Polymeric substances such as, for example, thickeners, amphoteric conditioning polymers, if present, are dispersed in water at room temperature, mixed with vigorous stirring, and then heated to about 50 ° C. I do. The resulting mixture is cooled to less than 40 ° C. and then a neutralizing agent is added to the mixture. If necessary to disperse the polymeric material, a tri-blender can be used.

After neutralization, the remaining components are added to the above mixture. If a cationic surfactant is included in the formulation, a premix is prepared by dissolving the cationic surfactant in hot water at a temperature above 70 ° C. with stirring, and then cooling to below 40 ° C. The premix obtained is added to the above mixture.

Examples 1 to 12 are hair conditioning compositions of the present invention that are particularly useful in leave-on formulations. These embodiments have many advantages. For example, they are clear and clearly indicate fragile visible particles. In addition, they provide improved conditioning benefits to the hair, such as smoothness, softness and reduced friction, are easy to apply to the hair, and leave a clean feel on the hair and hands.

The examples and embodiments described herein are for illustrative purposes only, and in view of these, various modifications or alterations may be made without departing from the spirit and scope of the invention. It is understood that this will be suggested to those skilled in the art.

──────────────────────────────────────────────────続 き Continuation of front page (81) Designated country EP (AT, BE, CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE ), OA (BF, BJ, CF, CG, CI, CM, GA, GN, GW, ML, MR, NE, SN, TD, TG), AP (GH, GM, KE, LS, MW, SD, SZ, UG, ZW), EA (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM), AL, AM, AT, AU, AZ, BA, BB, BG, BR, BY, CA, CH, CN, CU, CZ, DE, DK, EE, ES, FI, GB, GE, GH, GM, HR, HU, ID, IL, IS, JP, KE, KG, KP , KR, KZ, LC, LK, LR, LS, LT, LU, LV, MD, MG, MK, MN, MW, MX, NO, NZ, PL, PT, RO, RU, SD, SE, SG, SI, SK, SL, TJ, TM, TR, TT, UA, UG, US, UZ, VN, YU, ZW. Inventor Cox, Bruce Russell F-term 4C083 AA112 AB382 AB442 AC112 AC122 AC172 AC212 AC342 AC392 AC482 AC532 AC542 AC642 AC692 AC852 AD042 AD092 AD132 AD152 AD162 AD172 AD282 AD662 CC33 DD01 DD23 DD27 EE06 EE28

Claims (10)

[Claims] 1. A hair conditioning composition comprising (1) fragile visible particles; (2) a silicone compound; and (3) an aqueous carrier, the composition being transparent. 2. The hair conditioning composition according to claim 1, wherein the fragile visible particles comprise a structural material selected from the group consisting of cellulose, cellulose derivatives, sugars, and mixtures thereof. 3. The hair conditioning composition according to claim 1, wherein the fragile visible particles include an inclusion substance, and the inclusion substance contains a water-soluble component. 4. The hair conditioning composition according to claim 1, wherein the fragile visible particles comprise an inclusion substance selected from the group consisting of vitamins, amino acids, proteins, protein derivatives, herbal extracts, and mixtures thereof. . 5. The hair conditioning composition according to claim 4, wherein the contained substance is selected from the group consisting of vitamin E, pantothenyl ethyl ether, panthenol, turd kudami extract, and a mixture thereof. 6. The hair conditioning composition according to claim 1, further comprising a thickener. 7. The hair conditioning composition according to claim 1, further comprising a wetting agent. 8. The hair conditioning composition according to claim 1, further comprising an optical brightener. 9. The hair conditioning composition according to claim 1, further comprising an additional conditioning agent. 10. The following: (1) about 0.01 to about 5% by weight of fragile visible particles; (2) about 0.1 to about 60% by weight of a silicone compound; A hair conditioning composition comprising from about 0.1% to about 10% by weight of a thickening agent; (4) about 0.1 to about 20% by weight of a wetting agent; and (5) an aqueous carrier.