JP2002369666A - Food additive and food composition containing the same - Google Patents

Food additive and food composition containing the same

Info

Publication number
JP2002369666A
JP2002369666A JP2001181370A JP2001181370A JP2002369666A JP 2002369666 A JP2002369666 A JP 2002369666A JP 2001181370 A JP2001181370 A JP 2001181370A JP 2001181370 A JP2001181370 A JP 2001181370A JP 2002369666 A JP2002369666 A JP 2002369666A
Authority
JP
Japan
Prior art keywords
food
food additive
inorganic particles
particles
calcium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001181370A
Other languages
Japanese (ja)
Other versions
JP4514991B2 (en
Inventor
Hidehiko Nishioka
英彦 西岡
Hiroshi Shibata
洋志 柴田
Seiya Shimizu
清也 清水
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Maruo Calcium Co Ltd
Original Assignee
Maruo Calcium Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Maruo Calcium Co Ltd filed Critical Maruo Calcium Co Ltd
Priority to JP2001181370A priority Critical patent/JP4514991B2/en
Publication of JP2002369666A publication Critical patent/JP2002369666A/en
Application granted granted Critical
Publication of JP4514991B2 publication Critical patent/JP4514991B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Dairy Products (AREA)
  • Confectionery (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Fish Paste Products (AREA)
  • Noodles (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a food additive capable of giving various food compositions such as a mineral component-reinforced instant noodle, chewing gum, biscuit, pan cake premix, processed cheese, fishery paste product without harming eat feeling. SOLUTION: The food additive consists of inorganic particles having a specific mean particle diameter of their primary particles, a cohesive property, sharpness, various viscosities, a thixotropic property, a BET specific surface area and a water-absorptivity.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、食感を損なうこと
なく食品にミネラル成分を添加することを目的とした食
品添加剤、並びに該添加剤を配合してなる食品組成物に
関する。更に詳しくは、特定の粒子径、凝集性、シャー
プネス、各種粘性、チキソ性、BET比表面積を有する
無機系粒子からなる食品添加剤、及び該食品添加剤を配
合してなる、食感を損なわずに人体に効果的にミネラル
成分を付与し得るミネラル成分強化即席麺・チューイン
グガム・ビスケット・ホットケーキプレミックス・プロ
セスチーズ・水産練り製品等の各種食品組成物に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a food additive intended to add a mineral component to food without impairing the texture, and to a food composition comprising the additive. More specifically, a specific particle size, cohesiveness, sharpness, various viscosities, thixotropic properties, a food additive composed of inorganic particles having a BET specific surface area, and a food additive comprising the food additive, without impairing the texture The present invention relates to a variety of food compositions such as instant noodles, chewing gum, biscuits, hot cake premixes, processed cheese, and fishery paste products, which can effectively impart a mineral component to the human body.

【0002】[0002]

【従来の技術】従来より、国民の健康の観点から様々な
食品に栄養成分の強化を目的として、カルシウム・カリ
ウム・マグネシウム・リンなどの各種ミネラル成分を配
合することが行われている。特にカルシウム成分の食品
への添加は、旧厚生省が国民栄養調査等を行い、国民の
カルシウム不足を指摘すると同時にカルシウムの摂取を
呼びかけている。その結果、各食品メーカーは、カルシ
ウム成分の摂取強化を目的として貝殻カルシウム・牛骨
カルシウム・重質炭酸カルシウム等の天然カルシウム
や、グルコン酸カルシウム・乳酸カルシウム・合成炭酸
カルシウム等の合成カルシウムやその他のカルシウム系
化合物を各種食品に配合している。加えてカルシウム
は、周知の様に骨の形成に重要な成分であるだけでな
く、筋肉の収縮、生体内の恒常性維持に重要な役割を果
たしていることが近年の研究で明らかになっており、既
にブームの域を超え、添加されていて当然の感があるま
でに至っている。そして、元来、ミネラル成分の中でも
カルシウム成分の多い牛乳・チーズ等の乳製品を初めと
して、即席麺等の麺類、ビスケット、ホットケーキ・チ
ューイングガム、蒲鉾等の水産練り製品等にもそれらの
ミネラル成分の添加を強化した製品が数多く上市されて
いる。
2. Description of the Related Art Conventionally, various kinds of mineral components such as calcium, potassium, magnesium, and phosphorus have been added to various foods from the viewpoint of public health in order to enhance nutritional components. In particular, regarding the addition of calcium components to foods, the former Ministry of Health and Welfare has conducted a national nutrition survey and has pointed out the lack of calcium among the people and has called for calcium intake. As a result, each food manufacturer aims to enhance the intake of calcium components by using natural calcium such as shell calcium, bovine bone, and heavy calcium carbonate, and synthetic calcium such as calcium gluconate, calcium lactate, and synthetic calcium carbonate. Calcium compounds are blended in various foods. In addition, recent studies have shown that calcium is not only an important component for bone formation, but also plays an important role in muscle contraction and maintenance of homeostasis in vivo, as is well known. Has already been added beyond the range of the boom and has a natural feeling. And from the beginning, dairy products such as milk and cheese with a high calcium content among mineral components, noodles such as instant noodles, biscuits, hot cakes, chewing gum, fish paste products such as kamaboko, etc. A number of products with enhanced additives are on the market.

【0003】上記のミネラル成分添加を目的として水溶
性、または水不溶性の無機又は有機酸形態のミネラル成
分を含む添加剤を食品に添加する方法は数多く提案され
ている。しかし、水溶性の無機又は有機酸形態のミネラ
ル成分を含む添加剤は、イオン特有の味覚を与えること
が多く、特にそれが苦みを伴うため製品である食品自体
の商品価値を損なうことが多い。更に、それらの添加剤
が原料中のタンパク質等と反応し、風味や食感に悪影響
を及ぼす場合が多いため、一定量以上の添加が困難にな
り、多量に使用できないという欠点を有しており、特に
それがカルシウム成分の場合に顕著にみられる。
[0003] There have been proposed many methods for adding additives containing a water-soluble or water-insoluble inorganic or organic acid-type mineral component to foods for the purpose of adding the above-mentioned mineral components. However, an additive containing a mineral component in the form of a water-soluble inorganic or organic acid often gives a taste unique to ions, and particularly, it is accompanied by bitterness, and often impairs the commercial value of the food product itself. Furthermore, these additives react with proteins in the raw materials and the like, and often have a bad influence on flavor and texture. Therefore, it is difficult to add a certain amount or more, and there is a disadvantage that a large amount cannot be used. This is particularly noticeable when it is a calcium component.

【0004】一方、水不溶性の無機形態のミネラル成分
を含む添加剤は無味無臭であることが多く、その点で上
述の水溶性の無機又は有機酸形態の添加剤の欠点を解消
することが可能である。しかし、水不溶性のミネラル成
分を含む無機系粒子は、例えば即席麺等の小麦粉に分散
させる際に、その比重や流動性不足が原因で小麦粉中に
偏在が生じる可能性があり、それによる食品中のミネラ
ル成分の不均一、またはバラツキが生じるため食品とし
て不適当である。更に無機系粒子の場合、食品に対する
添加量が許容量を超えると食感自体に悪影響を及ぼすこ
とも多く、また、例えば即席麺に使用した場合に、麺自
体がバラバラにちぎれる等、商品価値を失うおそれがあ
る。
On the other hand, additives containing a mineral component in a water-insoluble inorganic form are often tasteless and odorless. In this respect, it is possible to solve the above-mentioned disadvantages of the water-soluble inorganic or organic acid-type additive. It is. However, inorganic particles containing a water-insoluble mineral component, for example, when dispersed in flour such as instant noodles, may be unevenly distributed in flour due to its specific gravity or lack of fluidity, thereby resulting in food It is unsuitable as a food because of the unevenness or variation in the mineral components of Further, in the case of inorganic particles, if the amount added to the food exceeds the allowable amount, it often has a bad effect on the texture itself, and, for example, when used for instant noodles, the noodles themselves are broken apart and the commercial value is reduced. There is a risk of losing.

【0005】上記の欠点を補い、食品用途に多量のミネ
ラル成分を添加する方法として、例えば特開昭56−1177
53号公報には、炭酸カルシウムと結晶セルロースを同時
に添加し、セルロースの網目構造により炭酸カルシウム
粒子を担持させる方法が提案されている。また、特開平
9−9911号公報には、燐脂質及びタンパク分解物からな
る群から選ばれる少なくとも1種と炭酸カルシウムを混
合して添加する方法が提案されている。
As a method of compensating for the above-mentioned disadvantages and adding a large amount of mineral components to food applications, for example, Japanese Patent Application Laid-Open No.
No. 53 proposes a method in which calcium carbonate and crystalline cellulose are simultaneously added, and calcium carbonate particles are supported by the network structure of cellulose. Japanese Patent Application Laid-Open No. 9-9911 proposes a method in which at least one selected from the group consisting of phospholipids and proteolysates is mixed with calcium carbonate.

【0006】しかし、上述の結晶セルロースを添加する
方法は、カルシウム懸濁液の粘度が増大して製造時の作
業性を悪化させるだけでなく、製品である食品自体の硬
さが大きくなり、それによる食感の悪化という問題が生
じる。また、燐脂質やタンパク分解物を添加する方法
は、燐脂質に特有の臭気と苦みがあるため、風味の点で
好ましい方法と言えない。これらの方法は、いずれも液
体食品中での沈降防止を目的にしているため、風味等の
他の物性への影響を考慮していなかったことが原因であ
る。
However, the above-mentioned method of adding microcrystalline cellulose not only increases the viscosity of the calcium suspension and deteriorates the workability at the time of production, but also increases the hardness of the food product itself. This causes a problem that the texture is deteriorated. In addition, the method of adding a phospholipid or a proteolytic product is not a preferable method in terms of flavor because the phospholipid has an odor and bitterness peculiar to the phospholipid. These methods are intended to prevent sedimentation in liquid foods, and thus do not take into account the influence on other physical properties such as flavor.

【0007】他方、1953年に日清製粉より即席麺が開発
・販売され、熱湯を注ぐか、または電子レンジ等により
加熱するだけで調理が完成する即席麺は、国民食、また
は米・パンに続く第3の主食の感のある麺類を全世界に
押し広げている。この即席麺に、カルシウムを初めとす
る各種ミネラル成分を配合しようとする動きは当然であ
り、なおかつ、それらのミネラル成分の影響を受けない
食感や味覚の優れた即席麺の出現が望まれている。
On the other hand, instant noodles were developed and sold by Nisshin Flour Milling in 1953, and the instant noodles, which were cooked only by pouring boiling water or heating with a microwave oven, were used as national foods or rice and bread. The third noodles with a sense of staple food are being spread all over the world. There is no wonder that various mineral components such as calcium are blended into this instant noodle, and the appearance of instant noodles excellent in texture and taste unaffected by those mineral components is desired. I have.

【0008】麺類は、小麦粉・かんすい・食塩・水等の
比較的簡単な原料から作られるが、その味覚は非常に繊
細で多岐に渡り、国民性や性別、年齢等によって大きく
左右されるが、麺の食感に負うところが大きい。食感と
は、調理後において適度の硬さ、弾力(粘弾性)、歯ご
たえ及び滑らかさ(つるみ感)、喉ごし、湯伸び等で表
現され、これらも国民性や性別、年齢等によって大きく
左右されるが、即席麺においても同様であり、それを損
なわずにミネラル成分の添加が可能な食品添加剤が望ま
れている。
[0008] Noodles are made from relatively simple raw materials such as flour, brine, salt, water, etc., but their taste is very delicate and varied, and is greatly affected by nationality, gender, age, etc. It largely depends on the texture of the noodles. The texture is expressed by moderate hardness, elasticity (viscoelasticity), chewyness and smoothness (thickness), throat, hot water after cooking, etc., and these are also large depending on national characteristics, gender, age, etc. The same applies to instant noodles, although it depends, and a food additive capable of adding a mineral component without impairing it is desired.

【0009】即席麺へのミネラル成分の添加は従来より
検討されており、例えば特開平6−64号公報では、卵白
・カードラン・アルギン酸塩等を利用する方法が、また
特開平7−107934号公報では、麺類の品質改良剤として
乾燥卵白や小麦グルテンなどの蛋白系の改良材やローカ
ストビーンガム、キサンタンガム等の増粘多糖類等が提
案されている。また、特許第2881555 号公報では、特殊
な反応方法によって得られる多孔質炭酸カルシウムを提
案しており、BET式比表面積の大小に関わらず、空隙
率と吸油・吸水量が高い多孔質炭酸カルシウムが小麦粉
・きな粉等の粉末食品素材、ガーリック、タイム等の粉
末香辛料、食塩等の調味料、コーヒー・ココア等の粉末
状食品素材における添加剤(食品組成物)に有用として
いる。しかし、特開平6−64号公報の方法は、本来の麺
が有する食感とは異質な食感になるといった欠点が指摘
されており、また特開平7−107934号公報の方法も、食
感の問題解決において十分ではなく、更に特許第288155
5 号公報記載の方法も、粉末状食品の固結防止や流動性
改善のみに着目し、その炭酸カルシウムが食品の味覚・
食感に与える影響を考慮しておらず、即席麺等の食品の
味覚・食感に生じる違和感についての問題解消や更なる
向上については言及されていない。
The addition of mineral components to instant noodles has been studied in the past. For example, JP-A-6-64 discloses a method using egg white, curdlan, or alginate, and JP-A-7-107934. In the gazette, as a quality improving agent for noodles, protein-based improving materials such as dried egg white and wheat gluten, and thickening polysaccharides such as locust bean gum and xanthan gum are proposed. Patent No. 2881555 proposes a porous calcium carbonate obtained by a special reaction method. Regardless of the BET specific surface area, a porous calcium carbonate having a high porosity and a high oil absorption / water absorption amount can be obtained. It is useful as an additive (food composition) in powdered food materials such as flour and kinako, spices such as garlic and thyme, seasonings such as salt, and powdered food materials such as coffee and cocoa. However, it has been pointed out that the method disclosed in JP-A-6-64 has a disadvantage that the texture is different from the original texture of the noodles. Is not enough to solve the problem of
The method described in Publication No. 5 also focuses only on the prevention of caking and improvement of fluidity of powdered food, and the calcium carbonate is
No consideration is given to the effect on the texture, and no mention is made of the solution to the problem of discomfort caused by the taste and texture of foods such as instant noodles and the further improvement.

【0010】[0010]

【発明が解決しようとする課題】本発明は、かかる実状
に鑑み、即席麺やチューイングガム・ビスケット・ホッ
トケーキ等の菓子類、プロセスチーズ等の乳製品、蒲鉾
等の水産水練り製品において、カルシウム、カリウム、
マグネシウム等の各種ミネラル成分が高分散性を有し、
同時に該成分の効果的な人体への吸収を促し、なおかつ
食感・味覚に悪影響を与えない食品添加剤、及びこれを
含有してなる食品組成物を提供する。
SUMMARY OF THE INVENTION In view of the above circumstances, the present invention relates to calcium and potassium in confectionery products such as instant noodles, chewing gum, biscuits, and hot cakes, dairy products such as process cheese, and fishery products such as kamaboko. ,
Various mineral components such as magnesium have high dispersibility,
At the same time, the present invention provides a food additive that promotes effective absorption of the component into the human body and does not adversely affect the texture and taste, and a food composition containing the same.

【0011】[0011]

【課題を解決するための手段】本発明者らは上記課題を
解決するべく鋭意検討の結果、特定の一次粒子の平均粒
径、凝集性、シャープネス、各種粘性、チキソ性、BE
T比表面積、吸水性を有する無機系粒子からなる食品添
加剤が、食感を損なわずに効果的にミネラル成分を食品
に付与し得ることを見出し本発明に到達した。
Means for Solving the Problems The present inventors have conducted intensive studies in order to solve the above-mentioned problems, and as a result, have found that the average particle size of specific primary particles, cohesiveness, sharpness, various viscosities, thixotropy, BE
The present inventors have found that a food additive composed of inorganic particles having a T specific surface area and water absorbability can effectively impart a mineral component to food without impairing the texture.

【0012】すなわち、本発明の第1は、下記の式
(a)〜(g)を満足する無機系粒子からなることを特
徴とする食品添加剤を内容とする(請求項1)。 (a)0.01≦dx≦10(μm ) (b)1 ≦α≦200 但し α=d50/dx (c)0≦β≦7 但し β=(d90−d10)/d50 (d)40≦CA ≦65(重量%) (e)20≦Vis ≦140 (Pa・ sec.) (f)1≦Ti ≦10 (g)0.1 ≦Sw≦50(m2 /g) (h) 0.1 ≦Wg≦2(g/g) 但し、 dx :電子顕微鏡写真により測定した、粒子を構成す
る一次粒子の平均粒子径(μm )。 α :凝集指数。 d50 :マイクロトラックFRAレーザー式粒度分布計
により測定した粒子の50%平均粒子径(μm )。 β :シャープネス。 d90 :マイクロトラックFRAレーザー式粒度分布計
により測定した粒子のふるい通過側累計90%粒子径(μ
m )。 d10 :マイクロトラックFRAレーザー式粒度分布計
により測定した粒子のふるい通過側累計10%粒子径(μ
m )。 CA :無機系粒子の懸濁液の粘度が、60rpm/min.の条件
で200Pa ・ s に達するときの固形分濃度(重量%) Vis :無機系粒子の固形分濃度45%、60rpm/min.の条
件で測定したときの懸濁液の粘度(Pa・ sec.:20℃) Ti :下記式(i)で表される無機系粒子の固形分濃
度45%の懸濁液のチキソ性 (i) Ti=VisA/Vis 但し、 VisA:無機系粒子の固形分濃度45%、6rpm/min.の条件
で測定したときの懸濁液の粘度(Pa・ sec.:20℃) Sw :窒素吸着法によるBET比表面積(m2 /g) Wg :無機系粒子1g当たりの吸水量(g/g)
That is, a first aspect of the present invention is directed to a food additive comprising inorganic particles satisfying the following formulas (a) to (g) (claim 1). (A) 0.01 ≦ dx ≦ 10 (μm) (b) 1 ≦ α ≦ 200 where α = d 50 / dx (c ) 0 ≦ β ≦ 7 where β = (d 90 -d 10) / d 50 (d) 40 ≦ CA ≦ 65 (% by weight) (e) 20 ≦ Vis ≦ 140 (Pa · sec.) (F) 1 ≦ Ti ≦ 10 (g) 0.1 ≦ Sw ≦ 50 (m 2 / g) (h) 0.1 ≦ Wg ≦ 2 (g / g), where dx is an average particle diameter (μm) of primary particles constituting the particles, as measured by an electron micrograph. α: Aggregation index. d 50 : 50% average particle diameter (μm) of particles measured by a Microtrac FRA laser type particle size distribution analyzer. β: sharpness. d 90 : Cumulative 90% particle diameter (μ) of particles passing through the sieve measured by a Microtrac FRA laser type particle size distribution analyzer
m). d 10 : Total 10% particle diameter (μ) of particles passing through the sieve measured by a Microtrac FRA laser particle size distribution analyzer
m). CA: solid content concentration (weight%) when the viscosity of the suspension of inorganic particles reaches 200 Pa · s under the condition of 60 rpm / min. Vis: solid content concentration of inorganic particles 45%, 60 rpm / min. Viscosity of suspension (Pa · sec .: 20 ° C.) when measured under the following conditions: Ti: thixotropic property of a suspension having a solid concentration of 45% of inorganic particles represented by the following formula (i) (i ) Ti = VisA / Vis, where VisA is the viscosity of the suspension measured at 6 rpm / min. At a solid concentration of 45% of inorganic particles (Pa · sec .: 20 ° C.) Sw: Nitrogen adsorption method BET specific surface area (m 2 / g) according to the formula: Wg: Water absorption (g / g) per 1 g of inorganic particles

【0013】好ましい態様として、請求項1記載の無機
系粒子がカルシウム系化合物であることを特徴とする食
品添加剤である。(請求項2)
In a preferred embodiment, the food additive is characterized in that the inorganic particles according to claim 1 are calcium compounds. (Claim 2)

【0014】好ましい態様として、請求項1又は2記載
の無機系粒子が、乳化安定剤、縮合燐酸およびその塩よ
りなる群から選択された少なくとも1種で表面処理され
ていることを特徴とする食品添加剤である。(請求項
3)
In a preferred embodiment, the inorganic particles according to claim 1 or 2 are surface-treated with at least one selected from the group consisting of an emulsion stabilizer, condensed phosphoric acid and a salt thereof. It is an additive. (Claim 3)

【0015】本発明の第2は、請求項1〜3のいずれか
1項に記載の食品添加剤を食品に配合してなる食品組成
物を内容とする。(請求項4)
A second aspect of the present invention is directed to a food composition comprising the food additive according to any one of claims 1 to 3 incorporated into a food. (Claim 4)

【0016】好ましい態様として、請求項4に記載の食
品が、麺類又は即席麺であることを特徴とする食品組成
物である。(請求項5)
In a preferred embodiment, the food according to the fourth aspect is a food composition characterized by being noodles or instant noodles. (Claim 5)

【0017】好ましい態様として、請求項4に記載の食
品が、チューインガムであることを特徴とする食品組成
物である。(請求項6)
In a preferred embodiment, the food according to claim 4 is a food composition characterized by being chewing gum. (Claim 6)

【0018】好ましい態様として、請求項4に記載の食
品が、ビスケットであることを特徴とする食品組成物で
ある。(請求項7)
[0018] In a preferred embodiment, the food according to claim 4 is a food composition characterized by being a biscuit. (Claim 7)

【0019】好ましい態様として、請求項4に記載の食
品が、ホットケーキプレミックスであることを特徴とす
る食品組成物である。(請求項8)
In a preferred embodiment, the food according to the fourth aspect is a food composition characterized by being a hot cake premix. (Claim 8)

【0020】好ましい態様として、請求項4に記載の食
品が、プロセスチーズであることを特徴とする食品組成
物である。(請求項9)
[0020] In a preferred embodiment, the food according to claim 4 is a processed cheese, which is a food composition. (Claim 9)

【0021】好ましい態様として、請求項4に記載の食
品が、水産練り製品であることを特徴とする食品組成物
である。(請求項10)
In a preferred embodiment, the food according to the fourth aspect is a food composition characterized by being a fishery paste product. (Claim 10)

【0022】[0022]

【発明実施の形態】本発明の第1の特徴は、粒度ならび
に粒度分布を厳しく制限した無機系粒子からなる食品添
加剤にある。即ち、本発明の食品添加剤の電子顕微鏡写
真により測定した粒子を構成する一次粒子の平均粒子径
dx(μm)は、0.01≦dx≦10であり、好ましくは0.
1 ≦dx≦5、より好ましくは0.2 ≦dx≦2である。
dxが10μmを越えると、例えばカップラーメン等の即
席麺に規定量の無機粒子を配合した場合、無機粒子の体
内での溶解に時間を要し、体内への速やかな吸収を妨げ
る為、ミネラル補強の点で好ましくなく、また、それら
が5〜6個凝集するだけで数十μmの大きさとなり、食
感にざらつき感を与えるため好ましくない。一方、dx
が0.01μm未満の場合、粒子自体の凝集が緻密になり、
堅密な凝集粒子を構成するため、無機粒子の体内での溶
解に時間を要し、体内への速やかな吸収を妨げる等、本
来の目的であるミネラル補強の点で好ましくなく、更
に、表面積が増えることにより吸水性や吸油性が大きく
なりすぎる問題が生じ好ましくない。なお、本発明の一
次粒子が針状・柱状ないし不定形の場合は、1個の一次
粒子の最長径と最短径の積の平方根をdxとする。
DETAILED DESCRIPTION OF THE INVENTION The first feature of the present invention resides in a food additive comprising inorganic particles whose particle size and particle size distribution are severely restricted. That is, the average particle diameter dx (μm) of the primary particles constituting the particles of the food additive of the present invention measured by an electron micrograph is 0.01 ≦ dx ≦ 10, preferably 0.1.
1 ≦ dx ≦ 5, more preferably 0.2 ≦ dx ≦ 2.
If dx exceeds 10 μm, for example, when a prescribed amount of inorganic particles are added to instant noodles such as cup ramen, it takes time for the inorganic particles to dissolve in the body and hinders rapid absorption into the body, so mineral reinforcement is required. In addition, it is not preferable because only 5 to 6 of them are aggregated to have a size of several tens of μm, which gives a rough texture to the texture. On the other hand, dx
Is less than 0.01 μm, the aggregation of the particles themselves becomes dense,
In order to form dense aggregated particles, it takes time for the inorganic particles to dissolve in the body, hinders rapid absorption into the body, and is not preferable in terms of the original purpose of reinforcing minerals. When the amount increases, there is a problem that water absorbency and oil absorbency become too large, which is not preferable. In the case where the primary particles of the present invention are acicular, columnar or irregular, the square root of the product of the longest diameter and the shortest diameter of one primary particle is dx.

【0023】吸水性や吸油性が原因で生じる問題とは、
例えば小麦粉を使用する食品の場合、小麦粉と水の反応
で生成するグルテンによって形成されるが、本発明の食
品添加剤の吸水性が大きくなりすぎると、グルテンの生
成に使用される水分が少なくなり、所望のグルテン量が
得られず、設計した食感・味覚通りの食品が得られなく
なる。また、吸油量が大きくなりすぎると、例えばホッ
トケーキプレミックスに使用する乳化剤等や、チューン
グガム等に使用するショ糖や酢酸ビニル等を取り込んで
しまい、設計通りの味覚や食感を得られないだけでな
く、重要な要素である食品の形状・色彩にも悪影響を与
えるため好ましくない。
The problems caused by water absorption and oil absorption are as follows.
For example, in the case of food using wheat flour, it is formed by gluten generated by the reaction of flour and water.If the water absorbency of the food additive of the present invention becomes too large, the water used for gluten production decreases. As a result, the desired amount of gluten cannot be obtained, and the food having the designed texture and taste cannot be obtained. Also, if the oil absorption is too large, for example, an emulsifier or the like used in a hot cake premix, or sucrose or vinyl acetate used in a chewing gum or the like is taken in, and the taste and texture as designed cannot be obtained. Not only that, it also has an adverse effect on the shape and color of the food, which is an important factor, which is not preferable.

【0024】本発明の食品添加剤の凝集性を表す指数で
あるαは1 ≦α≦200 であり、好ましくは5≦α≦150
、より好ましくは10≦α≦100 である。αが200 を超
える場合、凝集体粒子の表面積が増えることにより吸水
性・吸油性が増加するため好ましくない。またαが1未
満の場合、本発明の食品添加剤が無機系粒子であるた
め、有機物である食品中に充分に混合・分散せず、食品
から浮き出る等の問題を生じ、味覚・食感を低下させる
だけでなく商品価値自体を失わせるため好ましくない。
更にミネラル分補強の点からも体内に速やかな吸収を妨
げる等の問題が生じるため好ましくない。
Α, which is an index indicating the cohesiveness of the food additive of the present invention, is 1 ≦ α ≦ 200, preferably 5 ≦ α ≦ 150.
And more preferably 10 ≦ α ≦ 100. If α exceeds 200, the surface area of the aggregated particles increases, so that the water absorption and oil absorption increase, which is not preferable. When α is less than 1, since the food additive of the present invention is inorganic particles, it does not mix and disperse sufficiently in foods that are organic substances, causing problems such as floating out of the foods, resulting in poor taste and texture. This is not preferable because it not only lowers the price but also loses the commercial value itself.
Further, from the point of mineral reinforcement, problems such as impeding rapid absorption into the body occur, which is not preferable.

【0025】本発明の食品添加剤を構成する無機粒子の
凝集体の粒度分布のシャープネスを表す指数であるβは
0≦β≦7であり、好ましくは0≦β≦5、より好まし
くは0≦β≦3である。βが7を超える場合、粒度分布
幅がブロードになり、粗大な凝集粒子又は微細な凝集粒
子、もしくはその両方が多量に存在するため、例えば即
席麺等の食品に配合した際に、製品である麺の食感に対
する悪影響や、小麦粉等との練り合わせ時に必要以上の
粘性増加等を生じるので好ましくない。なお、βが負の
値を示すことはあり得ない。
The index β representing the sharpness of the particle size distribution of the aggregates of the inorganic particles constituting the food additive of the present invention is 0 ≦ β ≦ 7, preferably 0 ≦ β ≦ 5, more preferably 0 ≦ β ≦ 5. β ≦ 3. When β exceeds 7, the particle size distribution width becomes broad, and coarse agglomerate particles or fine agglomerated particles, or both are present in a large amount. For example, when blended in food such as instant noodles, it is a product. It is not preferable because it adversely affects the texture of the noodles and increases the viscosity more than necessary when kneading with noodles. Note that β cannot be a negative value.

【0026】本発明の食品添加剤の懸濁液の粘度が、60
rpm/min.の条件で200Pa ・ s に達するときの固形分濃度
CA(重量%)は、40≦CA ≦65であり、好ましくは45≦
CA≦60であり、より好ましくは50≦CA ≦55である。
CA が65重量%を超える場合、食品中に充分に混合・分
散せず、食品から浮き出る等の問題を生じ、味覚・食感
を低下させるだけでなく商品価値自体を失わせるため好
ましくない。一方、CA が40重量%未満の場合、吸水性
が大きく、小麦粉と水から生成されるグルテン量が不足
することになり、得られた麺の食感がパサパサする等の
問題が生じる為に好ましくない。更に、必要量のミネラ
ル分を添加すると、粘性が上がりすぎて麺の生成が不可
能になる場合もあり、麺生成の為にミネラル分を減らす
必要が生ずるなど好ましくない。なお、粘度の測定はB
型粘度計を用いて行った。
The viscosity of the suspension of the food additive of the present invention is 60
The solid content concentration CA (% by weight) when reaching 200 Pa · s under the condition of rpm / min. is 40 ≦ CA ≦ 65, preferably 45 ≦
CA ≦ 60, more preferably 50 ≦ CA ≦ 55.
If CA exceeds 65% by weight, it is not preferable because it does not mix and disperse sufficiently in the food, causing problems such as emergence from the food, not only lowering the taste and texture but also losing the commercial value itself. On the other hand, when the content of CA is less than 40% by weight, the water absorption is large, the amount of gluten produced from flour and water becomes insufficient, and the resulting noodles have problems such as a textured texture. Absent. Furthermore, if the required amount of mineral is added, the viscosity may be too high to produce noodles in some cases, and it is not preferable because it is necessary to reduce the mineral content for producing noodles. The measurement of the viscosity was performed using B
This was performed using a mold viscometer.

【0027】本発明の食品添加剤の固形分濃度45%、60
rpm/min.の条件で測定したときの懸濁液の粘度Vis (Pa
・ sec.:20℃)は20≦Vis ≦140 であり、好ましくは30
≦Vis ≦100 であり、より好ましくは40≦Vis ≦60であ
る。Vis が140Pa ・ sec.を超えると、乾粉の吸水性が大
きく、小麦粉と水から生成されるグルテン量が不足する
ことになり、例えば即席麺の場合、得られた麺の食感が
パサパサする等の問題が生じるため好ましくなく、ま
た、食品の製造時に粘度上昇が起こし、作業性を低下さ
せるため好ましくない。一方、Vis が20Pa・ sec.未満の
場合、食品中に充分に混合・分散せず、食品から浮き出
る等の問題を生じ、味覚・食感を低下させるだけでなく
商品価値自体を失わせるため好ましくない。
The food additive of the present invention has a solid content of 45%,
Viscosity of suspension (Vis (Pa) measured at rpm / min.
(Sec .: 20 ° C.) is 20 ≦ Vis ≦ 140, preferably 30
≦ Vis ≦ 100, more preferably 40 ≦ Vis ≦ 60. When the Vis exceeds 140 Pa · sec., The water absorption of the dried powder is large, and the amount of gluten generated from flour and water becomes insufficient. For example, in the case of instant noodles, the texture of the obtained noodles becomes dry. This is not preferred because of the problem described above, and the viscosity is increased during the production of food, which lowers the workability. On the other hand, if the Vis is less than 20 Pa · sec., It does not mix and disperse sufficiently in the food, causing problems such as floating out of the food, not only reducing the taste / texture but also losing the commercial value itself. Absent.

【0028】本発明の食品添加剤の固形分濃度45%の懸
濁液のチキソ性Tiは1≦Ti≦10であり、好ましくは
1.7 ≦Ti≦5.0 、より好ましくは2.1 ≦Ti≦2.5 で
ある。Tiが10を超えると、例えば、製品である即席麺
作成時における小麦粉等との練り合わせ時に著しい粘性
増加が生じたり、麺の食感に悪影響や与えるため好まし
くない。これは、粒度分布幅がブロードになり、粗大な
凝集粒子又は微細な凝集粒子、もしくはその両方が多量
に存在するためと考えられる。なお、Tiが1未満の値
を示すことは、我々の研究においてはあり得なかった。
The thixotropic Ti of the suspension of the food additive of the present invention having a solid concentration of 45% is 1 ≦ Ti ≦ 10, preferably
1.7 ≦ Ti ≦ 5.0, more preferably 2.1 ≦ Ti ≦ 2.5. If the Ti exceeds 10, for example, a remarkable increase in viscosity occurs during kneading with flour or the like at the time of producing instant noodles, which is a product, and the texture of the noodles is unfavorably affected. This is presumably because the particle size distribution width becomes broad, and a large amount of coarse aggregated particles or fine aggregated particles, or both, are present. It should be noted that it was impossible in our study that Ti has a value of less than 1.

【0029】本発明の食品添加剤のBET比表面積Sw
(m2/g)は、0.1 ≦Sw≦50であり、好ましくは1≦
Sw≦20、より好ましくは5≦Sw≦10である。Swが
50m2/gを超える場合、乾粉の吸水性・吸油性が大き
く、食感・味覚だけでなく、食品自体の商品価値を失わ
しめ、更に製造時に粘度上昇を起こし、作業性を低下さ
せるため好ましくない。一方、Swが0.1 m2/g未満の
場合、食品中に充分に混合・分散せず、食品から浮き出
る等の問題を生じ、味覚・食感を低下させるだけでなく
商品価値自体を失わせるため好ましくない。
The BET specific surface area Sw of the food additive of the present invention
(M 2 / g) is 0.1 ≦ Sw ≦ 50, preferably 1 ≦ Sw
Sw ≦ 20, more preferably 5 ≦ Sw ≦ 10. Sw is
If it exceeds 50 m 2 / g, the water absorption and oil absorption of the dry powder are large, not only the texture and taste, but also the commercial value of the food itself is lost, and the viscosity increases during production, which is preferable because the workability is reduced. Absent. On the other hand, if Sw is less than 0.1 m 2 / g, it will not mix and disperse sufficiently in the food, causing problems such as floating out of the food, not only reducing the taste and texture but also losing the commercial value itself. Not preferred.

【0030】本発明の食品添加剤の1g当たりの吸水量
Wg(g/ g)は、0.1 ≦Wg≦2であり、好ましくは
0.2 ≦Wg≦1.5 、より好ましくは0.5 ≦Wg≦1.0 で
ある。Wgが2g/ gを超える場合、乾粉の吸水性が大
きく、小麦粉と水から生成されるグルテン量が不足する
ことになり、得られた麺の食感がパサパサする等の問題
や、製品である麺製造時に粘度上昇が作業性を低下させ
る可能性が生じるため好ましくない。一方、Wgが0.1
g/ g未満の場合、食品中に充分に混合・分散せず、食
品から浮き出る等の問題を生じ、味覚・食感を低下させ
るだけでなく商品価値自体を失わせるため好ましくな
い。
The water absorption Wg (g / g) per gram of the food additive of the present invention is 0.1 ≦ Wg ≦ 2, and is preferably
0.2 ≦ Wg ≦ 1.5, more preferably 0.5 ≦ Wg ≦ 1.0. When Wg exceeds 2 g / g, the water absorption of the dry powder is large, the amount of gluten generated from flour and water is insufficient, and the obtained noodles have a problem of texture and the like, and the product is a product. An increase in viscosity during the production of noodles is not preferred because the possibility of lowering the workability is generated. On the other hand, Wg is 0.1
If it is less than g / g, it is not preferable because it does not mix and disperse sufficiently in the food, causes problems such as floating out of the food, and not only lowers the taste and texture but also loses the commercial value itself.

【0031】なお、本発明における吸水量は下記の方法
で測定した。底面に細孔を多数有する容積20mlの円筒形
容器の底面に濾紙を置き、本発明の食品添加剤を5g投
入した後、1000gのピストンで該充填炭酸カルシウムに
圧密する。ピストンを除去後、圧密された本発明の食品
添加剤を充填したままで該容器を常温・常圧下で、水に
10分間浸し、その後、濾紙上で5分間放置した後に、容
器側面・底部の水を拭き取り、水に浸す前後の重量差を
本発明の食品添加剤の投入量(5g)で除算した値を吸
水量とした。
The amount of water absorption in the present invention was measured by the following method. A filter paper is placed on the bottom surface of a cylindrical container having a large number of pores on the bottom surface and having a capacity of 20 ml. After 5 g of the food additive of the present invention is charged, the mixture is compacted with the filled calcium carbonate with a 1000 g piston. After removing the piston, the container is filled with water at normal temperature and normal pressure while the compacted food additive of the present invention is filled.
After soaking for 10 minutes and then leaving on filter paper for 5 minutes, the water on the side and bottom of the container is wiped off, and the difference between the weight before and after soaking in water divided by the input amount (5 g) of the food additive of the present invention is taken as the water absorption. Amount.

【0032】本発明の食品添加剤を構成する無機系粒子
は、厚生省が昭和63年にリスト化した食品添加剤におい
て、食品の栄養価を補充するものとしたミネラル成分が
好適で、例えばグルコン酸亜鉛・硫酸亜鉛である亜鉛
類、塩化カルシウム、塩化第二鉄、クエン酸カルシウ
ム、クエン酸第一鉄ナトリウム、クエン酸鉄、クエン酸
鉄アンモニウム、グリセリン酸カルシウム、グルコン酸
カルシウム、グルコン酸第一鉄、水酸化カルシウム、炭
酸カルシウム、グルコン酸銅・硫酸銅である銅塩類、乳
酸カルシウム、乳酸鉄、ピロ燐酸二水素カルシウム、ピ
ロ燐酸第一鉄、ピロ燐酸第二鉄、硫酸カルシウム、硫酸
第一鉄(結晶・乾燥)、燐酸三カルシウム、燐酸一水素
カルシウム、燐酸二水素カルシウムが挙げられる。既述
の様に、国民のカルシウム成分の摂取量は不足している
ことから、その添加が重要とされており、塩化カルシウ
ム、クエン酸カルシウム、グリセリン酸カルシウム、グ
ルコン酸カルシウム、水酸化カルシウム、炭酸カルシウ
ム、乳酸カルシウム、乳酸鉄、ピロ燐酸二水素カルシウ
ム、硫酸カルシウム、燐酸三カルシウム、燐酸一水素カ
ルシウム、燐酸二水素カルシウムのカルシウム系無機物
の添加が好ましく、中でも本発明の特徴を有する無機系
粒子を調製時のコスト、作業性等の点で炭酸カルシウ
ム、燐酸三カルシウム、燐酸一水素カルシウム、燐酸二
水素カルシウムが最も好ましい。これらは、単独で又は
必要に応じ2種以上組み合わせて用いられる。
As the inorganic particles constituting the food additive of the present invention, mineral additives which supplement the nutritional value of food in the food additives listed by the Ministry of Health and Welfare in 1988 are suitable, for example, gluconic acid. Zinc and zinc sulfate, calcium chloride, ferric chloride, calcium citrate, sodium ferrous citrate, iron citrate, ammonium iron citrate, calcium glycerate, calcium gluconate, ferrous gluconate, Calcium hydroxide, calcium carbonate, copper salts of copper gluconate and copper sulfate, calcium lactate, iron lactate, calcium dihydrogen pyrophosphate, ferrous pyrophosphate, ferric pyrophosphate, calcium sulfate, ferrous sulfate ( (Crystal / dry), tricalcium phosphate, calcium monohydrogen phosphate, calcium dihydrogen phosphate. As mentioned above, the intake of the calcium component of the people is insufficient, and its addition is considered important. Calcium chloride, calcium citrate, calcium glycerate, calcium gluconate, calcium hydroxide, calcium carbonate It is preferable to add calcium-based inorganic substances such as calcium lactate, iron lactate, calcium dihydrogen pyrophosphate, calcium sulfate, tricalcium phosphate, calcium monohydrogen phosphate, and calcium dihydrogen phosphate, and particularly to prepare inorganic particles having the characteristics of the present invention. Calcium carbonate, tricalcium phosphate, calcium monohydrogen phosphate, and calcium dihydrogen phosphate are most preferable in terms of cost, workability, and the like. These may be used alone or in combination of two or more as necessary.

【0033】上述のカルシウム系無機粒子は、化学反応
によって得られる合成品であっても、焼成牛骨カルシウ
ム・未焼成牛骨カルシウム・未焼成魚骨カルシウム・未
焼成甲殻カルシウム・未焼成卵殻カルシウム等を粉砕・
分級して得られる天然カルシウムの何れでも良いが、本
発明の物性を調整時におけるコスト、製造時の作業性、
製造量の安定性等の点で合成品が好ましく用いられる。
The above-mentioned calcium-based inorganic particles may be a synthetic product obtained by a chemical reaction, such as calcined bovine bone calcium, unbaked bovine bone calcium, unbaked fish bone calcium, unbaked crust calcium, unbaked egg shell calcium, etc. Crushing
Any of natural calcium obtained by classification may be used, but the cost at the time of adjusting the physical properties of the present invention, workability at the time of production,
Synthetic products are preferably used in view of the stability of the production amount and the like.

【0034】また、上述の燐酸カルシウム系粒子は、例
えば国際公開番号WO97/03119、WO98/29490等に記載の方
法で製造することが出来る。例えば、基体としての炭酸
カルシウムの水懸濁液とリン酸の希釈水溶液をCa/P
の原子比率が33.3以下となる割合で水中で下記の混
合条件で混合反応させた後、更に下記の熟成条件で熟成
してリン酸カルシウム系化合物の水スラリーを得、脱水
を行うか又は脱水せずに700℃以下の乾燥雰囲気下で
乾燥後、解砕仕上げを行うことにより製造することがで
きる。 混合条件 炭酸カルシウムの水懸濁液固形分濃度 1〜15重量% 燐酸の希釈水溶液濃度 1〜50重量% 混合攪拌羽根の周速 0.5〜50m/秒 混合時間 0.1〜150時間 混合系水懸濁液温度 0〜80℃ 混合系の水懸濁液pH 5〜9 熟成条件 熟成系のCa濃度 0.4〜5重量% 熟成時間 0.1〜100時間 熟成系水懸濁液温度 20〜80℃ 熟成系水懸濁液pH 6〜9 攪拌羽根の周速 0.5〜50m/秒 なお、水懸濁液の状態から乾粉を得る工程において、必
要に応じて脱水・希釈を繰り返して燐酸カルシウム系粒
子の洗浄を行い、系内に溶存する不純物を除去すること
も可能である。
The above-mentioned calcium phosphate-based particles can be produced, for example, by the methods described in International Publication Nos. WO97 / 03119, WO98 / 29490 and the like. For example, an aqueous suspension of calcium carbonate as a substrate and a diluted aqueous solution of phosphoric acid are mixed with Ca / P
After the mixture is reacted in water at a ratio such that the atomic ratio of is 33.3 or less under water under the following mixing conditions, the mixture is further aged under the following aging conditions to obtain a calcium phosphate-based compound water slurry, which is dehydrated or dehydrated. Instead, it can be manufactured by performing a crushing finish after drying in a drying atmosphere of 700 ° C. or less. Mixing conditions Solid concentration of aqueous suspension of calcium carbonate 1 to 15% by weight Concentration of diluted aqueous solution of phosphoric acid 1 to 50% by weight Peripheral speed of mixing and stirring blade 0.5 to 50 m / sec Mixing time 0.1 to 150 hours Mixing system Water suspension temperature 0 to 80 ° C Water suspension pH of mixed system 5 to 9 Aging condition Ca concentration of aging system 0.4 to 5% by weight Aging time 0.1 to 100 hours Aging water suspension temperature 20 -80 ° C Aged water suspension pH 6-9 Peripheral speed of stirring blade 0.5-50 m / sec In the step of obtaining dry powder from the state of the water suspension, dehydration / dilution is repeated as necessary. The calcium phosphate-based particles can be washed to remove impurities dissolved in the system.

【0035】また本発明の食品添加剤は、上述の無機系
粒子を表面処理剤により処理してもよい。かかる表面処
理剤としては、例えば、(ポリ)グリセリン脂肪酸エス
テル、有機酸モノグリセリド、ショ糖脂肪酸エステル、
レシチン、大豆多糖類、カルボキシルメチルセルロー
ス、加工澱粉、グアーガム、ローストビーンガム、キサ
ンタンガム、ペクチン、カラギーナン、ガティガム、カ
ードラン、タマリンドシードガム、カラヤガム、タラガ
ム、ジェランガム、トラガントガム、アラビアガム、ア
ラビーノガラクタン等の乳化安定剤や、燐酸一ピロ燐
酸、燐酸二ピロ燐酸、燐酸三ピロ燐酸、トリポリ燐酸、
テトラポリ燐酸、ペンタポリ燐酸、トリメタ燐酸、ヘキ
サメタ燐酸等の縮合燐酸、およびそれらの縮合燐酸のナ
トリウム・カリウム・アンモニウム等のアルカリ金属塩
等からなる縮合燐酸塩が例示される。これらの中でも、
酵素分解タイプの等のレシチン類、パルミチン酸やステ
アリン酸等のポリグリセリン脂肪酸エステル、HLBが
8以上のショ糖脂肪酸エステル、ガディガム、トラガン
トガムが、例えば麺類に添加された場合に食感を長時間
維持する点で好ましく、また、ピロ燐酸以上の長鎖長の
縮合燐酸塩が、例えば麺類に添加された場合に弾力性と
のどごしといった食感に与える効果の点で好ましく、な
かでもメタ燐酸ソーダが入手のしやすさ、コスト、食感
への影響、無機系粒子の表面処理時のハンドリングのし
やすさの点で最も好ましい。
In the food additive of the present invention, the above-mentioned inorganic particles may be treated with a surface treating agent. Such surface treating agents include, for example, (poly) glycerin fatty acid esters, organic acid monoglycerides, sucrose fatty acid esters,
Emulsification of lecithin, soy polysaccharide, carboxymethyl cellulose, modified starch, guar gum, roast bean gum, xanthan gum, pectin, carrageenan, gati gum, curdlan, tamarind seed gum, karaya gum, tara gum, gellan gum, tragacanth gum, arabic gum, arabino galactan, etc. Stabilizers, monopyrophosphate, dipyrophosphate, tripyrophosphate, tripolyphosphate,
Examples thereof include condensed phosphoric acids such as tetrapolyphosphoric acid, pentapolyphosphoric acid, trimetaphosphoric acid, and hexametaphosphoric acid, and condensed phosphates composed of alkali metal salts such as sodium, potassium and ammonium of these condensed phosphoric acids. Among these,
Lecithins such as enzymatic degradation type, polyglycerin fatty acid esters such as palmitic acid and stearic acid, sucrose fatty acid esters having an HLB of 8 or more, gaddy gum, tragacanth gum, for example, maintain the texture for a long time when added to noodles In addition, a condensed phosphate having a long chain length equal to or longer than pyrophosphoric acid is preferable in terms of the effect on the texture such as elasticity and throat when added to noodles, and among them, sodium metaphosphate is available. It is most preferable in terms of ease of use, cost, influence on texture, and ease of handling during surface treatment of inorganic particles.

【0036】上記表面処理剤の無機系粒子への添加量
は、本発明の食品添加剤の効能を損なわない範囲で添加
することが好ましく、その添加量は0.01重量%以上10重
量%以下であり、好ましくは0.05重量%以上5重量%以
下、より好ましくは0.1 重量%以上2重量%以下であ
る。
The amount of the surface treatment agent to be added to the inorganic particles is preferably within a range that does not impair the efficacy of the food additive of the present invention, and the addition amount is from 0.01% by weight to 10% by weight. It is preferably 0.05% by weight or more and 5% by weight or less, more preferably 0.1% by weight or more and 2% by weight or less.

【0037】本発明の第2は、本発明で得られた食品添
加剤を配合してなる食品組成物に関する。本発明の食品
添加剤が配合される食品は、本発明の食品添加剤を配合
することが可能な食品であれば特に制限なく、例えば、
うどん・そば・焼きそば・ラーメン等の麺類や即席麺
類、白色パン・クリームパン等の菓子パン・ドーナツ等
の揚げパン・ホットケーキ等のパン類、はるさめ、まん
じゅう、煎餅、ビスケット加工品、スナック菓子、キャ
ンデー・キャラメル等のドロップ類、インスタントココ
ア・インスタントコーヒー、チューイングガム、マーガ
リン、ジャム、もめん・絹ごし等の豆腐類、油揚げ、植
物性タンパク、コンニャク、蒲鉾・はんぺん等の水産練
り製品類、ハム・ソーセージ、餃子の皮、乳飲料・ヨー
グルト・チーズ等の乳製品、アイスクリーム、炭酸・コ
ーヒー飲料、豆乳、みそ、キムチ・漬け物類、マヨネー
ズ、カレールウ、コンビーフ缶詰、昆布佃煮、煮豆、納
豆、ふりかけ、塩、エビフライ・フライポテト等の冷凍
製品が挙げられる。なかでも、うどん・そば・ラーメン
・素麺・焼きそば等の即席麺、チューイングガム・ビス
ケット・ホットケーキ等の菓子類、チーズなどの乳製
品、蒲鉾等の水産練り製品に配合された場合に、それら
の食品中での分散性や、食感の違和感、ミネラル成分の
吸収性において、より有効にその効能を発揮する。
The second aspect of the present invention relates to a food composition containing the food additive obtained in the present invention. The food in which the food additive of the present invention is blended is not particularly limited as long as the food can be blended with the food additive of the present invention, for example,
Noodles such as udon, buckwheat, yakisoba, ramen and instant noodles, baked goods such as white bread and cream bread, doughnuts and other fried bread, hot cakes and other breads, harusame, buns, crackers, biscuit products, snacks, candy, Drops such as caramel, instant cocoa / instant coffee, chewing gum, tofu such as margarine, jam, rice noodles / silk, oil fried, vegetable protein, konjac, fish paste products such as kamaboko / hanpon, ham / sausage, dumpling skin Dairy products such as milk drinks, yogurt and cheese, ice cream, carbonated and coffee drinks, soy milk, miso, kimchi and pickles, mayonnaise, curry roux, canned corned beef, kelp tsukudani, boiled beans, natto, sprinkle, salt, shrimp fries And frozen products such as potatoes. Above all, instant noodles such as udon, soba, ramen, light noodles, yakisoba, sweets such as chewing gum, biscuits, hot cakes, dairy products such as cheese, and fish paste products such as kamaboko are used in such foods. The effect is more effectively exhibited in dispersibility, texture discomfort, and absorption of mineral components.

【0038】まず、本発明の食品添加剤を配合した食品
組成物の好ましい態様である即席麺について説明する。
即席麺は袋めんとスナック(カップ)麺に大別され、更
に袋麺は即席中華麺・即席和風麺・即席欧風麺に分類さ
れ、スナック麺は中華スタイルと和風スタイルに分類さ
れる。上記の各種麺は、更にアルファー化油揚げ麺・ア
ルファー化非油揚げ麺・非アルファー化油揚げ麺に細分
化され、各々にラーメン・タンメン・ワンタンメン・焼
きそば・そば・うどん等が分類される。本発明の食品添
加剤を配合した食品組成物は、何れの製品においてもそ
の効能を発揮するが、中でも袋麺の即席中華麺用途、な
らびにスナック麺の中華スタイルに特に好適である。
First, an instant noodle, which is a preferred embodiment of a food composition containing the food additive of the present invention, will be described.
Instant noodles are broadly divided into bag noodles and snack (cup) noodles. Bag noodles are further classified into instant Chinese noodles, instant Japanese noodles and instant European noodles, and snack noodles are classified into Chinese style and Japanese style. The above-mentioned various noodles are further subdivided into pregelatinized oil fried noodles, pregelatinized non-fried noodles, and non-pregelatinized fried noodles, and each is classified into ramen, tanmen, wontanmen, yakisoba, soba, udon and the like. The food composition containing the food additive of the present invention exerts its effect in any product, but is particularly suitable for use in instant Chinese noodles for sack noodles and Chinese style for snack noodles.

【0039】本発明の食品組成物である即席麺は、通常
の即席麺作成と同様、小麦粉もしくは小麦粉とそば粉、
澱粉等に、かんすい、ペクチン・アルギン酸・澱粉類・
寒天・ゼラチン・卵白等の増粘多糖類、本発明の食品添
加剤を溶かした捏ね水で練り合わせ、麺帯を形成後に圧
延して切り出し麺線を作成し、得られた麺を蒸した後に
エキスパウダーやアミノ酸等の調味料を溶かした液で味
付けし、酸化防止剤が添加された油で揚げて乾燥し、調
味料とかやくを添付して容器詰めをして作成される。な
お、必要により捏ね水に麺捏込用油脂の分散を目的とし
て各種乳化剤や、麺質調整を目的としてソルビトール
を、着色を目的としてカロチン色素を、本発明の食品添
加剤の効能を妨げない範囲で加えてもよい。
Instant noodles, which are food compositions of the present invention, can be prepared from wheat flour or flour and buckwheat,
To starch, etc., cinnamon, pectin, alginic acid, starch,
Thickening polysaccharides such as agar, gelatin, egg white, etc., are kneaded with kneading water in which the food additive of the present invention is dissolved, rolled out after forming a noodle belt, cut out noodle strings, steamed the obtained noodles, and then extracted. It is made by seasoning with a solution in which a seasoning such as powder or amino acid is dissolved, fried in oil to which an antioxidant has been added, dried, and packed in a container with the seasoning and syrup attached. In addition, various emulsifiers for the purpose of dispersing the fat and oil for kneading noodles in kneading water, sorbitol for the purpose of adjusting the quality of noodles, carotene pigments for the purpose of coloring, a range that does not hinder the efficacy of the food additive of the present invention. May be added.

【0040】即席麺に配合される本発明の食品添加剤の
配合量は、得られる食品(この場合は即席麺の麺線)に
対して0.05〜30重量%が好ましく、0.1 〜25重量%が更
に好ましく、0.3 〜20重量%が最も好ましい。配合量が
0.05重量%未満であると所望のミネラル配合効果が得ら
れず、30重量%を超えると食感に悪影響を与えるだけで
なく、即席麺を湯戻しした際に、麺がプツプツと切れる
現象が生じ、商品価値を損なうので好ましくない。
The amount of the food additive of the present invention blended in the instant noodles is preferably 0.05 to 30% by weight, and more preferably 0.1 to 25% by weight, based on the obtained food (in this case, instant noodle noodle strings). More preferably, it is most preferably 0.3 to 20% by weight. The amount
If it is less than 0.05% by weight, the desired mineral compounding effect cannot be obtained, and if it exceeds 30% by weight, not only does it adversely affect the texture, but also when the instant noodles are returned to hot water, the noodles are cut off. However, it is not preferable because it impairs the commercial value.

【0041】次に、本発明の食品添加剤を配合した食品
の好ましい態様であるチューイングガムについて説明す
る。チューイングガムは、アカテツ科・キョウチクトウ
科等の樹木から採取したジェルトン・ソルバ・チクル等
の植物性樹脂、酢酸ビニル樹脂等の熱軟化性樹脂、植物
性ワックス等のワックス、本発明の食品添加剤をニーダ
ー等で加熱・溶融・混練して得られたガムベースに、糖
類、香料、グリセリン等の軟化剤、その他をミキサーで
錬成・混合してチューイングガム生地が得られる。な
お、得られたチューイングガム生地を、更にエキストル
ーダー等で錬成押出しつつ圧延ロールで所定の厚さに伸
ばし、クーリングトンネルで所望の硬さを付与後に切断
ロールで切断し、恒温・恒湿での一定期間熟成後に包装
したものが、所謂、板ガムである。なお、切断の際に必
要に応じて粘着防止を目的として粉糖またはマンニトー
ルを散布しても良い。
Next, a chewing gum, which is a preferred embodiment of a food containing the food additive of the present invention, will be described. Chewing gum is kneaded with a vegetable resin such as gelton, solva, and tickle collected from a tree such as Acetaceae / Apocynaceae, a thermosoftening resin such as a vinyl acetate resin, a wax such as a vegetable wax, and a food additive of the present invention. A chewing gum material is obtained by kneading and mixing a softening agent such as saccharides, flavoring agents, glycerin and the like with a mixer to a gum base obtained by heating, melting and kneading with a mixer. The obtained chewing gum material was further stretched to a predetermined thickness by a rolling roll while being extruded through an extruder or the like, and after being provided with a desired hardness in a cooling tunnel, cut with a cutting roll, and then cut at a constant temperature and humidity. What is packaged after a period of aging is the so-called plate gum. In addition, at the time of cutting, powdered sugar or mannitol may be sprayed as needed for the purpose of preventing adhesion.

【0042】チューイングガムのガムベースに配合され
る本発明の食品添加剤の配合量は、ガムベースに対して
1〜40重量%が好ましく、5〜30重量%が更に好まし
く、8〜20重量%が最も好ましい。配合量が1重量%未
満であると所望のミネラル配合効果が得られず、40重量
%を超えるとチューイングガムの噛み具合にざらつく等
の悪影響を与え、商品価値を損なうので好ましくない。
The amount of the food additive of the present invention to be added to the gum base of the chewing gum is preferably 1 to 40% by weight, more preferably 5 to 30% by weight, and most preferably 8 to 20% by weight based on the gum base. . If the blending amount is less than 1% by weight, the desired mineral blending effect cannot be obtained, and if it exceeds 40% by weight, the chewing gum has an adverse effect such as roughening of the chewing gum, which undesirably impairs commercial value.

【0043】次に、本発明の食品添加剤を配合した食品
組成物の好ましい態様であるビスケットについて説明す
る。ビスケットは、小麦粉、砂糖、ショートニング、全
粉乳、食塩、膨張剤、香料、本発明で得られた食品添加
剤等に水を加えてミキサーで混合し、ハードビスケット
は、上記の混合体をロールで圧延して一定の厚みのシー
ト状とした後に、スタンピングマシンで型抜き・成形す
ると同時に針穴をあけ、オーブンで焼き上げて作成す
る。ソフトビスケットは、上記の混合体をロープ状とし
て切ったり、型(モールド)を使用して成形後に焼き上
げて作成する。なお、ビスケットに使用するクリーム等
は、例えばクリームの場合、砂糖、脱脂粉乳、ショート
ニング、レシチン、香料をよく混合し、滑らかに仕上げ
て得られるが、このクリームに乳化剤や本発明の食品添
加剤を配合してもよい。
Next, a biscuit, which is a preferred embodiment of a food composition containing the food additive of the present invention, will be described. Biscuit is mixed with flour, sugar, shortening, whole milk powder, salt, leavening agent, flavor, food additive obtained in the present invention, etc. with water and mixed with a mixer, and hard biscuit is rolled with the above mixture. After being rolled into a sheet of a certain thickness, the sheet is punched and formed by a stamping machine, and at the same time, a needle hole is formed, and the sheet is baked in an oven. The soft biscuit is formed by cutting the above mixture into a rope shape or baking after molding using a mold. In addition, creams and the like used for biscuits are, for example, in the case of creams, sugar, skim milk powder, shortening, lecithin, and fragrance are mixed well, and a smooth finish is obtained.Emulsifiers and food additives of the present invention are added to this cream. You may mix.

【0044】ビスケットに配合される本発明の食品添加
剤の配合量は、得られる食品に対して0.1 〜20重量%が
好ましく、2〜10重量%が更に好ましく、3〜7重量%
が最も好ましい。配合量が0.1 重量%未満であると所望
のミネラル配合効果が得られず、20重量%を超えるとビ
スケットのさくさくとした噛み具合に悪影響を与えるだ
けでなく、ビスケット自体の成形性に乏しく型くずれを
起こしやすい等、商品価値を損なうので好ましくない。
The amount of the food additive of the present invention to be added to the biscuit is preferably 0.1 to 20% by weight, more preferably 2 to 10% by weight, and more preferably 3 to 7% by weight based on the obtained food.
Is most preferred. If the compounding amount is less than 0.1% by weight, the desired mineral compounding effect cannot be obtained. If the compounding amount exceeds 20% by weight, not only does the crispy bite of the biscuit adversely affect, but also the biscuit itself has poor moldability and loses shape. It is not preferable because it impairs the commercial value, such as easy occurrence.

【0045】次に、本発明の食品添加剤を配合した食品
組成物の好ましい態様であるホットケーキプレミックス
について説明する。ホットケーキプレミックスは、小麦
粉、澱粉、砂糖、ブドウ糖、油脂、粉乳、膨張剤、食
塩、香料、本発明で得られた食品添加剤等を撹拌・混合
し、計量後に梱包して得られる。なお、上述のホットケ
ーキプレミックスに、本発明の食品添加剤の効能に影響
を及ぼさない範囲で、風味や外観の向上を目的としてビ
タミンB2 等を加えてもよい。
Next, a hot cake premix, which is a preferred embodiment of the food composition containing the food additive of the present invention, will be described. The hot cake premix is obtained by stirring and mixing flour, starch, sugar, glucose, oil and fat, milk powder, leavening agent, salt, flavor, the food additive obtained in the present invention, etc., weighing, and packing. It should be noted that vitamin B 2 or the like may be added to the above-mentioned hot cake premix for the purpose of improving flavor and appearance as long as the effect of the food additive of the present invention is not affected.

【0046】ホットケーキプレミックスに配合される本
発明の食品添加剤の配合量は、得られる食品に対して0.
01〜10重量%が好ましく、0.05〜5重量%が更に好まし
く、0.1 〜3重量%が最も好ましい。配合量が0.01重量
%未満であると所望のミネラル配合効果が得られず、10
重量%を超えるとホットケーキの食感に悪影響を与える
だけでなく、苦み等の味覚にも悪影響を与えるため好ま
しくない。
The amount of the food additive of the present invention to be added to the hot cake premix is 0.1% based on the obtained food.
It is preferably from 0.01 to 10% by weight, more preferably from 0.05 to 5% by weight, most preferably from 0.1 to 3% by weight. If the blending amount is less than 0.01% by weight, the desired mineral blending effect cannot be obtained,
Exceeding the weight percent not only adversely affects the texture of the hot cake, but also adversely affects the taste such as bitterness, which is not preferable.

【0047】次に、本発明の食品添加剤を配合した食品
組成物の好ましい態様であるプロセスチーズについて説
明する。プロセスチーズは、ナチュラルチーズの表面に
ある外皮を除去した後に、アミノ酸等の調味料、カロチ
ン等の色素、ソルビン酸カリウム等の保存料、香料、本
発明で得られた食品添加剤等を加えて加熱溶融し、クエ
ン酸ナトリウム等の乳化剤を加えて乳化し、充填・冷却
後に梱包して得られる。
Next, a process cheese, which is a preferred embodiment of the food composition containing the food additive of the present invention, will be described. Process cheese, after removing the outer skin on the surface of natural cheese, adding seasonings such as amino acids, pigments such as carotene, preservatives such as potassium sorbate, flavors, food additives obtained in the present invention, etc. It is obtained by heating and melting, emulsifying by adding an emulsifier such as sodium citrate, filling, cooling and packing.

【0048】プロセスチーズに配合される本発明の食品
添加剤の配合量は、得られる食品に対して0.01〜20重量
%が好ましく、0.1 〜10重量%が更に好ましく、0.5 〜
5重量%が最も好ましい。配合量が0.01重量%未満であ
ると所望のミネラル配合効果が得られず、20重量%を超
えるとプロセスチーズ中で偏在が生じてチーズ表面の外
観を損なう上に、食感にも悪影響を与えるので好ましく
ない。
The amount of the food additive of the present invention to be incorporated into the processed cheese is preferably 0.01 to 20% by weight, more preferably 0.1 to 10% by weight, and more preferably 0.5 to 10% by weight based on the obtained food.
5% by weight is most preferred. If the compounding amount is less than 0.01% by weight, the desired mineral compounding effect cannot be obtained, and if it exceeds 20% by weight, uneven distribution occurs in the processed cheese, which impairs the appearance of the cheese surface and adversely affects the texture. It is not preferable.

【0049】次に、本発明の食品添加剤を配合した食品
組成物の好ましい態様である水産練り製品の板付き蒸し
蒲鉾について説明する。板付き蒸し蒲鉾は、生鮮魚から
その魚肉をとり、水晒し、脱水を行った後に食塩、砂
糖、調味料、本発明で得られた食品添加剤等を加えて練
り合わせ、蒸気で加熱・殺菌して得られる。なお、通
常、蒲鉾の原料となる生鮮魚は白身魚が中心であるが、
最近では鰯・鯖・鯵等の赤身魚も使用されているが、本
発明の食品添加剤は、それらに使用しても白身魚の場合
と同様に良好に使用される。また、表面を着色する目的
で着色料や、夏期の保存性向上を目的としてソルビン酸
・ソルビン酸カリウム等の保存料の使用も可能である
が、その添加量は本発明の食品添加剤の効能に影響を及
ぼさない範囲の量で留めることが好ましい。
Next, a preferred embodiment of a food composition containing the food additive of the present invention is a steamed kamaboko with a plate of a fishery paste product. Steamed kamaboko with plate is obtained by taking the fish meat from fresh fish, exposing it to water, dehydrating, kneading with salt, sugar, seasoning, the food additive obtained in the present invention, heating and sterilizing with steam. Obtained. In addition, usually, the fresh fish used as the raw material for kamaboko is mainly white fish,
Recently, red fish such as sardine, mackerel, and horse mackerel have been used, but the food additive of the present invention can be used as well as white fish even when used in them. It is also possible to use a coloring agent for the purpose of coloring the surface or a preservative such as sorbic acid / potassium sorbate for the purpose of improving the preservability in summer, but the amount of the additive is determined by the effect of the food additive of the present invention. It is preferable to keep the amount within a range that does not affect the above.

【0050】蒲鉾に配合される本発明の食品添加剤の配
合量は、得られる食品に対して0.01〜5重量%が好まし
く、0.05〜3重量%が更に好ましく、0.1 〜2重量%が
最も好ましい。配合量が0.01重量%未満であると所望の
ミネラル配合効果が得られず、5重量%を超えると蒲鉾
の食感に悪影響を与えるので好ましくない。
The amount of the food additive of the present invention to be added to the kamaboko is preferably 0.01 to 5% by weight, more preferably 0.05 to 3% by weight, and most preferably 0.1 to 2% by weight based on the obtained food. . If the blending amount is less than 0.01% by weight, the desired mineral blending effect cannot be obtained, and if it exceeds 5% by weight, the texture of kamaboko is adversely affected, which is not preferable.

【0051】[0051]

【実施例】以下に本発明の実施例及び比較例により更に
詳細に説明するが、本発明はこれらになんら限定される
ものではない。本発明の食品添加剤ならびに該添加剤を
配合した食品組成物の実施例、比較例を以下に示す。
The present invention will be described in more detail with reference to the following Examples and Comparative Examples, but the present invention is not limited thereto. Examples and comparative examples of the food additive of the present invention and the food composition containing the additive are shown below.

【0052】<原料となる炭酸カルシウムの調製>実施
例及び比較例にシード粒子として使用する炭酸カルシウ
ム懸濁液の調製方法を以下に示す。 炭酸カルシウム懸濁液A1:比重1.060 、液温15℃に調
整した石灰乳10,000リットルに、炭酸ガス濃度16重量%
の炉ガスを25m3/min の流速で導通して炭酸化反応を行
い、炭酸カルシウムの水懸濁液A1を得た。 炭酸カルシウム懸濁液A2:比重1.110 、液温35℃に調
整した石灰乳10,000リットルに、炭酸ガス濃度16重量%
の炉ガスを25m3/min の流速で導通して炭酸化反応を行
い、炭酸カルシウムの水懸濁液A2を得た。 炭酸カルシウム懸濁液A3:丸尾カルシウム株式会社製
重質炭酸カルシウム「カルテックス5」
<Preparation of Calcium Carbonate as Raw Material> A method for preparing a calcium carbonate suspension used as seed particles in Examples and Comparative Examples will be described below. Calcium carbonate suspension A1: A specific gravity of 1.060, a liquid temperature adjusted to 15 ° C., 10,000 liters of lime milk, a carbon dioxide gas concentration of 16% by weight
Was passed through at a flow rate of 25 m 3 / min to carry out a carbonation reaction to obtain an aqueous suspension A1 of calcium carbonate. Calcium carbonate suspension A2: A specific gravity of 1.110, a lime milk adjusted to a liquid temperature of 35 ° C., 10,000 liters, and a carbon dioxide gas concentration of 16% by weight
Was passed through at a flow rate of 25 m 3 / min to carry out a carbonation reaction to obtain an aqueous suspension A2 of calcium carbonate. Calcium carbonate suspension A3: Heavy calcium carbonate "Caltex 5" manufactured by Maruo Calcium Co., Ltd.

【0053】実施例1 炭酸カルシウム懸濁液A1をシード粒子の懸濁液として
選択し、15℃に調整した160 リットルのシード粒子の懸
濁液に、比重1.060 、液温15℃の石灰乳960 リットルの
滴下と炭酸ガス濃度16重量%の炉ガスの導通を、仕事量
0.3 kJの撹拌の下で、系内のpH11〜12、液温45℃以
下に維持しながら、36時間かけて滴下反応を行い炭酸カ
ルシウムの水懸濁液を得た。得られた炭酸カルシウムの
懸濁液に炭酸ガスを導通して系内をpH8以下にした後
に、メタ燐酸ソーダを懸濁液中の炭酸カルシウムに対し
て0.2 重量%添加して表面処理を行い、該懸濁液をフィ
ルタープレスで脱水・洗浄後、得られたプレスケーキを
パドルドライヤーで乾燥し、乾式粉砕機で解砕して無機
系粒子からなる食品添加剤を得た。具体的な製造方法
と、得られた食品添加剤の各種物性を表1に示す。
Example 1 A suspension of calcium carbonate suspension A1 was selected as a suspension of seed particles, and a suspension of 160 liters of seed particles adjusted to 15 ° C. was added with 960 of lime milk having a specific gravity of 1.060 and a liquid temperature of 15 ° C. Liter drop and conduction of furnace gas with carbon dioxide concentration of 16% by weight
While maintaining the system pH at 11 to 12 and the liquid temperature at 45 ° C. or lower under agitation of 0.3 kJ, a drop reaction was carried out over 36 hours to obtain an aqueous suspension of calcium carbonate. After passing carbon dioxide gas through the obtained suspension of calcium carbonate to adjust the pH of the system to 8 or less, sodium metaphosphate was added at 0.2% by weight to the calcium carbonate in the suspension to perform a surface treatment. After dehydrating and washing the suspension with a filter press, the obtained press cake was dried with a paddle drier and crushed with a dry grinder to obtain a food additive composed of inorganic particles. Table 1 shows specific production methods and various physical properties of the obtained food additive.

【0054】実施例2〜13 比較例1〜5 炭酸カルシウム懸濁液ANをシード粒子の懸濁液として
選択し、T1℃に調整したL1リットルのシード粒子の
懸濁液に、比重ρ、液温T2℃の石灰乳L2リットルの
滴下と炭酸ガス濃度Cg重量%の炉ガスの導通を、仕事
量EkJの撹拌の下で、系内のpHα、液温T3℃以下
に維持しながら、θ時間かけて滴下反応を行い炭酸カル
シウムの水懸濁液を得た。得られた炭酸カルシウムの懸
濁液に炭酸ガスを導通して系内をpH8以下にした後
に、乳化安定剤または縮合燐酸およびその塩Zを懸濁液
中の炭酸カルシウムに対してX重量%添加して表面処理
を行い、該懸濁液をフィルタープレスで脱水・洗浄後、
得られたプレスケーキをパドルドライヤーで乾燥し、乾
式粉砕機で解砕して無機系粒子からなる食品添加剤を得
た。具体的な製造方法と、得られた食品添加剤の各種物
性を表1,2に示す。
Examples 2 to 13 Comparative Examples 1 to 5 A calcium carbonate suspension AN was selected as a seed particle suspension, and a specific gravity ρ and a liquid were added to an L1 liter seed particle suspension adjusted to T1 ° C. The addition of 2 liters of lime milk L at a temperature of T2 ° C. and the conduction of furnace gas having a carbon dioxide gas concentration of Cg wt. Then, a dropping reaction was performed to obtain an aqueous suspension of calcium carbonate. After passing carbon dioxide gas through the obtained suspension of calcium carbonate to adjust the pH of the system to 8 or less, an emulsion stabilizer or condensed phosphoric acid and its salt Z are added in an amount of X% by weight to the calcium carbonate in the suspension. After the surface treatment, the suspension is dehydrated and washed with a filter press,
The obtained press cake was dried with a paddle dryer and crushed with a dry pulverizer to obtain a food additive composed of inorganic particles. Tables 1 and 2 show specific production methods and various physical properties of the obtained food additive.

【0055】実施例14 国際公開番号WO97/03119 号及びWO98/29490 号記載の
方法に従い、炭酸カルシウム懸濁液A2とリン酸の希釈
水溶液を下記の処方・方法で混合・反応・熟成等を行
い、脱水・水洗後、700 ℃以下の乾燥雰囲気下で乾燥
し、解砕仕上げを行い、燐酸カルシウム粒子からなる食
品添加剤を得た。得られた食品添加剤の物性を表2に示
す。
Example 14 According to the method described in International Publication Nos. WO97 / 03119 and WO98 / 29490, a calcium carbonate suspension A2 and a diluted aqueous solution of phosphoric acid were mixed, reacted, and aged by the following formulation and method. After being dehydrated and washed with water, it was dried in a dry atmosphere at a temperature of 700 ° C. or less, and was crushed to obtain a food additive composed of calcium phosphate particles. Table 2 shows the physical properties of the obtained food additive.

【0056】<燐酸カルシウム懸濁液の作成>平均径0.
1 μmの炭酸カルシウムの水懸濁液(固形分10重量%)2
40kgに、濃度10重量%の燐酸溶液180kg を、撹拌速度7
m/sec.、温度55℃、pH6〜7に維持しつつ、180 分で
滴下して反応を行い、その後、pH7〜8に維持し1000
時間熟成して燐酸カルシウムの懸濁液を得た。得られた
懸濁液の固形分濃度を5重量%に調整し、該懸濁液に前
述の炭酸カルシウム懸濁液を70kg、濃度20%の燐酸第一
アンモニウム35kgを、撹拌速度6.5m/sec. 、温度70℃、
pH6〜9に維持しつつ、90分で滴下して燐酸カルシウ
ム粒子上に、更に燐酸カルシウムを担持させ、その後、
pH6〜9に維持し1000時間熟成して燐酸カルシウムの
懸濁液を得た。
<Preparation of Calcium Phosphate Suspension>
1 μm aqueous calcium carbonate suspension (solid content 10% by weight) 2
To 40 kg, 180 kg of a 10% by weight phosphoric acid solution was added at a stirring speed of 7
The reaction was carried out by dropping in 180 minutes while maintaining the m / sec.
After aging for a time, a suspension of calcium phosphate was obtained. The solid content concentration of the obtained suspension was adjusted to 5% by weight, and 70 kg of the above-described calcium carbonate suspension and 35 kg of 20% concentration of ammonium phosphate monobasic were added to the suspension, and the stirring speed was 6.5 m / sec. , Temperature 70 ℃,
While maintaining the pH at 6 to 9, the calcium phosphate particles are further dropped on the calcium phosphate particles for 90 minutes to further support the calcium phosphate.
The mixture was maintained at pH 6 to 9 and aged for 1000 hours to obtain a suspension of calcium phosphate.

【0057】比較例6 丸尾カルシウム株式会社製 重質炭酸カルシウム「カル
テックス5」を食品添加剤として使用した。該食品添加
剤の物性を表2に示す。
Comparative Example 6 Heavy calcium carbonate "Caltex 5" manufactured by Maruo Calcium Co., Ltd. was used as a food additive. Table 2 shows the physical properties of the food additive.

【0058】[0058]

【表1】 [Table 1]

【0059】[0059]

【表2】 [Table 2]

【0060】実施例15〜28 比較例7〜12 下記の各種即席麺原料を下記の配合割合で混合して麺生
地を作成した。得られた麺生地にロール圧延機で延伸を
行い麺帯厚1.08mmの麺帯を作成し、#20の切り刃を通し
て麺線を得た。得られた麺線を所定時間蒸し、油で揚げ
てミネラル成分強化即席麺を得た。得られたミネラル成
分強化板ガムの評価を以下の方法で行った。なお食感の
評価は、本発明の食品添加剤を含まない即席麺を本発明
の即席麺と同様に作成し、比較対象とした。
Examples 15 to 28 Comparative Examples 7 to 12 The following various instant noodle materials were mixed in the following proportions to prepare noodle dough. The obtained noodle dough was stretched by a roll mill to form a noodle belt having a noodle belt thickness of 1.08 mm, and a noodle string was obtained through a # 20 cutting blade. The obtained noodle strings were steamed for a predetermined time and fried in oil to obtain instant noodles reinforced with mineral components. The obtained mineral component-reinforced board gum was evaluated by the following method. The evaluation of the texture was made by comparing instant noodles containing no food additive of the present invention in the same manner as the instant noodles of the present invention, and used as a comparison object.

【0061】 <即席麺原料ならびに配合割合> 小麦粉 800 g 馬鈴薯澱粉 200 g かん水 1.5 g 食塩 20 g 水 330 g 食品添加剤(実施例1〜14、比較例1〜6) 7 g<Instant noodle raw materials and mixing ratio> Flour 800 g Potato starch 200 g Brackish water 1.5 g Salt 20 g Water 330 g Food additives (Examples 1 to 14, Comparative Examples 1 to 6) 7 g

【0062】<即席麺中での分散性>得られた即席麺の
任意の10箇所より正確に1gを量り取り、各々の即席麺
中に含まれるミネラル成分(本実施例・比較例の場合は
カルシウム)を原子吸光光度計で測定しそのバラツキを
評価した。結果を表3に示す。
<Dispersibility in Instant Noodles> 1 g is weighed accurately from any 10 places of the obtained instant noodles, and the mineral components contained in each instant noodle (in the case of this example and comparative example, (Calcium) was measured with an atomic absorption spectrophotometer, and the variation was evaluated. Table 3 shows the results.

【0063】<食感の評価>本発明の食品である即席麺
を湯戻した後、男女各々10名で官能試験を行い、食感に
関して下記の基準で判定した。結果を表3に示す。 A:ミネラル成分無添加品との違いが全く分からない。
(20 名全員が違いを訴えなかった。) B:ミネラル成分無添加品と殆ど同等である。 (20 名中1名が違いを訴えた。) C:ミネラル成分無添加品と微妙に異なる。(20 名中2
〜4名が違いを訴えた。) D:ミネラル成分無添加品と違いが明らかである。(20
名中10〜14名が違いを訴えた。) E:麺が切れやすい上にざらつきやすく、ミネラル成分
無添加品と食感が明らかに異なる。(20 名中15名以上が
違いを訴えた。)
<Evaluation of texture> After the instant noodles as foods of the present invention were reconstituted in hot water, a sensory test was conducted by 10 men and women, and the texture was determined according to the following criteria. Table 3 shows the results. A: No difference from a mineral component-free product was found.
(All 20 people did not complain of the difference.) B: Almost the same as the product without mineral components. (One out of 20 complained of the difference.) C: Slightly different from the mineral-free product. (2 out of 20 people
~ 4 complained of the difference. D: The difference from the product without the mineral component is apparent. (20
10-14 of them complained of the difference. E) Noodles are easy to cut and rough, and the texture is clearly different from that of the mineral-free product. (More than 15 out of 20 complained.)

【0064】[0064]

【表3】 [Table 3]

【0065】実施例29〜42 比較例13〜18 下記の各種チューイングガムのガムベース原料を、下記
の配合割合でニーダー等を用いて加熱・溶融・混練して
ガムベースを得、得られたガムベースに糖類、香料、グ
リセリン等の軟化剤、本発明の食品添加剤をミキサーで
錬成・混合してチューイングガム生地を得た。得られた
チューイングガム生地を、更にエキストルーダー等で錬
成押出しつつ圧延ロールで所定の厚さに伸ばし、クーリ
ングトンネルで所望の硬さを付与後に切断ロールで切断
し、恒温・恒湿の条件で一定期間熟成後して板ガムを得
た。得られたミネラル成分強化板ガム(スペアミントガ
ム)の評価を以下の方法で行った。なお食感の評価は、
本発明の食品添加剤を含まない板ガムを本発明の板ガム
と同様に作成し、比較対象とした。
Examples 29 to 42 Comparative Examples 13 to 18 The following gum base materials for chewing gum were heated, melted and kneaded using a kneader or the like at the following proportions to obtain a gum base. A chewing gum material was obtained by kneading and mixing a flavoring agent, a softener such as glycerin, and the food additive of the present invention with a mixer. The obtained chewing gum material is further stretched to a predetermined thickness by a rolling roll while being extruded by an extruder or the like, and given a desired hardness in a cooling tunnel, cut by a cutting roll, and then cut for a certain period of time under constant temperature and humidity conditions. After aging, a plate gum was obtained. The obtained mineral component-reinforced board gum (spearmint gum) was evaluated by the following method. The evaluation of texture is
A plate gum containing no food additive of the present invention was prepared in the same manner as the plate gum of the present invention, and was used as a comparative object.

【0066】 <ガムベースの原料ならびに配合割合> 弾性体(ポリイソブチレン樹脂) 200g 酢酸ビニル樹脂 300g ワックス分(パラフィンワックス) 320g 乳化剤(脂肪酸モノグリセライド) 30g 食品添加剤(実施例1〜14、比較例1〜6) 150g <板ガムの原料ならびに配合割合> 上記ガムベース 24g グラニュー糖 58g ブドウ糖 7g シロップ 14g グリセリン 1.5g スペアミント香料 0.5g<Raw materials and mixing ratio of gum base> Elastic body (polyisobutylene resin) 200 g Vinyl acetate resin 300 g Wax content (paraffin wax) 320 g Emulsifier (fatty acid monoglyceride) 30 g Food additive (Examples 1 to 14, Comparative Examples 1 to 14) 6) 150g <Raw material and mixing ratio of board gum> The above gum base 24g Granulated sugar 58g Glucose 7g Syrup 14g Glycerin 1.5g Spearmint flavor 0.5g

【0067】<板ガム中での分散性>得られた板ガムか
ら任意の10箇所より正確に0.1 gを量り取り、各々の板
ガム中に含まれるミネラル成分(本実施例・比較例の場
合はカルシウム)を原子吸光光度計で測定し、そのバラ
ツキを評価した。結果を表4に示す。
<Dispersibility in board gum> From the obtained board gum, 0.1 g was weighed accurately from any 10 places, and the mineral components contained in each board gum (in the case of this example and comparative example) Was measured with an atomic absorption spectrophotometer, and the variation was evaluated. Table 4 shows the results.

【0068】<食感の評価>本発明の食品である板ガム
を男女各々10名で官能試験を行い、食感に関して下記の
基準で判定した。結果を表4に示す。 A:ミネラル成分無添加品との違いが全く分からない。
(20 名全員が違いを訴えなかった。) B:ミネラル成分無添加品と殆ど同等である。(20 名中
1名が違いを訴えた。) C:ミネラル成分無添加品と微妙に異なる。(20 名中2
〜4名が違いを訴えた。) D:ミネラル成分無添加品と違いが明らかである。(20
名中10〜14名が違いを訴えた。) E:ガムが割れやすい上にざらつきやすく、ミネラル成
分無添加品と食感が明らかに異なる。(20 名中15名以上
が違いを訴えた。)
<Evaluation of Texture> A sensory test was performed on the board gum as a food of the present invention by 10 men and women, and the texture was evaluated according to the following criteria. Table 4 shows the results. A: No difference from a mineral component-free product was found.
(All 20 people did not complain of the difference.) B: Almost the same as the product without mineral components. (One out of 20 complained of the difference.) C: Slightly different from the mineral-free product. (2 out of 20 people
~ 4 complained of the difference. D: The difference from the product without the mineral component is apparent. (20
10-14 of them complained of the difference. E) The gum is easily cracked and rough, and the texture is clearly different from that of the mineral-free product. (More than 15 out of 20 complained.)

【0069】[0069]

【表4】 [Table 4]

【0070】実施例43〜56 比較例19〜24 下記の配合割合の各種ビスケット原料を水と共にミキサ
ーで混合し、該混合体をロールで圧延して一定の厚みの
シート状とした後に、スタンピングマシンで型抜き・成
形すると同時に針穴をあけ、オーブンで約200 ℃で6分
間焼き上げてミネラル成分強化ハードビスケットを得
た。得られたミネラル成分強化ハードビスケットの評価
を以下の方法で行った。なお食感の評価は、本発明の食
品添加剤を含まないハードビスケットを本発明の板ガム
と同様に作成し、比較対象とした。
Examples 43 to 56 Comparative Examples 19 to 24 Various biscuit raw materials having the following compounding ratios were mixed with water by a mixer, and the mixture was rolled into rolls to form a sheet having a certain thickness. At the same time, a needle hole was punched out and baked in an oven at about 200 ° C. for 6 minutes to obtain a mineral component-reinforced hard biscuit. The obtained mineral component-reinforced hard biscuit was evaluated by the following method. For evaluation of texture, a hard biscuit containing no food additive of the present invention was prepared in the same manner as the plate gum of the present invention, and was used as a comparative object.

【0071】 <ビスケット原料ならびに配合割合> 中力小麦粉 62g 砂糖 15g ショートニング 10g 全粉乳 1.2g 食塩 0.5g 膨張剤(重炭酸ソーダ+重炭酸アンモニウム) 0.5g 香料 0.05g 亜硫酸塩 0.07g 水 11g 食品添加剤(実施例1〜14、比較例1〜6) 4g<Biscuit Raw Materials and Mixing Ratio> Neutral flour 62 g Sugar 15 g Shortening 10 g Whole milk powder 1.2 g Salt 0.5 g Swelling agent (sodium bicarbonate + ammonium bicarbonate) 0.5 g Fragrance 0.05 g Sulfite 0.07 g Water 11 g Food additive (implementation Examples 1 to 14, Comparative Examples 1 to 6) 4 g

【0072】<ハードビスケット中での分散性>得られ
たハードビスケットの任意の10箇所から正確に0.1 gを
量り取り、各々のハードビスケット中に含まれるミネラ
ル成分(本実施例・比較例の場合はカルシウム)を原子
吸光光度計で測定し、そのバラツキを評価した。結果を
表5に示す。
<Dispersibility in Hard Biscuit> 0.1 g was weighed accurately from any 10 places of the obtained hard biscuit, and the mineral components contained in each hard biscuit (in the case of this example and comparative example) Was measured with an atomic absorption spectrophotometer, and the variation was evaluated. Table 5 shows the results.

【0073】<食感の評価>本発明の食品であるハード
ビスケットを男女各々10名で官能試験を行い、食感に関
して下記の基準で判定した。結果を表5に示す。 A:ミネラル成分無添加品との違いが全く分からない。
(20 名全員が違いを訴えなかった。) B:ミネラル成分無添加品と殆ど同等である。(20 名中
1名が違いを訴えた。) C:ミネラル成分無添加品と微妙に異なる。(20 名中2
〜4名が違いを訴えた。) D:ミネラル成分無添加品と違いが明らかである。(20
名中10〜14名が違いを訴えた。) E:ハードビスケットが壊れやすい上にざらつきやす
く、ミネラル成分無添加品と食感が明らかに異なる。(2
0 名中15名以上が違いを訴えた。)
<Evaluation of Texture> A sensory test was conducted on the hard biscuit as the food of the present invention by 10 men and women, and the texture was evaluated according to the following criteria. Table 5 shows the results. A: No difference from a mineral component-free product was found.
(All 20 people did not complain of the difference.) B: Almost the same as the product without mineral components. (One out of 20 complained of the difference.) C: Slightly different from the mineral-free product. (2 out of 20 people
~ 4 complained of the difference. D: The difference from the product without the mineral component is apparent. (20
10-14 of them complained of the difference. E) Hard biscuit is easily broken and rough, and its texture is clearly different from that of a mineral-free product. (2
More than 15 out of 0 complained of the difference. )

【0074】[0074]

【表5】 [Table 5]

【0075】実施例57〜70 比較例25〜30 下記の配合割合のホットケーキプレミックス原料を撹拌
・混合してミネラル成分強化ホットケーキプレミックス
を得た。得られたミネラル成分強化ホットケーキプレミ
ックス200 gを、全卵100 gと牛乳30mlにとき、それを
焼き上げてホットケーキを作成し、本発明の食品である
ホットケーキプレミックスの評価を以下の方法で行っ
た。なお食感の評価は、本発明の食品添加剤を含まない
ホットケーキプレミックスを、本発明のホットケーキプ
レミックスと同様に作成し、ホットケーキを作成し比較
対象とした。
Examples 57 to 70 Comparative Examples 25 to 30 Hot cake premix raw materials having the following mixing ratios were stirred and mixed to obtain a mineral component-enriched hot cake premix. When 200 g of the obtained mineral-enriched hot cake premix is turned into 100 g of whole egg and 30 ml of milk, it is baked to prepare a hot cake, and the hot cake premix which is a food of the present invention is evaluated in the following manner. I went in. For evaluation of texture, a hot cake premix containing no food additive of the present invention was prepared in the same manner as the hot cake premix of the present invention, and a hot cake was prepared for comparison.

【0076】 <ホットケーキプレミックス原料ならびに配合割合> 小麦粉(薄力粉) 400g 砂糖 400g ベーキングパウダー 1g 乳化剤(理研ビタミン製エマルジーMH) 3g 乳化油剤(理研ビタミン製フレンジーF) 5g 粉末油剤(理研ビタミン製エマファットPA-80) 10g 食品添加剤(実施例1〜14,比較例1〜6) 3g<Hot cake premix raw material and mixing ratio> Flour (soft flour) 400 g Sugar 400 g Baking powder 1 g Emulsifier (RIKEN Vitamin Emulgy MH) 3 g Emulsifying oil (RIKEN Vitamin Frenzy F) 5 g Powder oil (RIKEN Vitamin Emafat) PA-80) 10 g Food additive (Examples 1 to 14, Comparative Examples 1 to 6) 3 g

【0077】<ホットケーキ中での分散性>得られたホ
ットケーキの任意の10箇所から正確に10gを量り取り、
各々のホットケーキ中に含まれるミネラル成分(本実施
例・比較例の場合はカルシウム)を原子吸光光度計で測
定し、そのバラツキを測定した。結果を表6に示す。
<Dispersibility in Hot Cake> 10 g of the obtained hot cake was weighed accurately from any 10 places,
Mineral components (calcium in the case of this example and comparative example) contained in each hot cake were measured with an atomic absorption spectrophotometer, and the variation was measured. Table 6 shows the results.

【0078】<食感の評価>本発明のホットケーキプレ
ミックスから作成したホットケーキを男女各々10名で官
能試験を行い、食感に関して下記の基準で判定した。結
果を表6に示す。 A:ミネラル成分無添加品との違いが全く分からない。
(20 名全員が違いを訴えなかった。) B:ミネラル成分無添加品と殆ど同等である。(20 名中
1名が違いを訴えた。) C:ミネラル成分無添加品と微妙に異なる。(20 名中2
〜4名が違いを訴えた。) D:ミネラル成分無添加品と違いが明らかである。(20
名中10〜14名が違いを訴えた。) E:ざらつき感があり、ミネラル成分無添加品と食感が
明らかに異なる。(20 名中15名以上が違いを訴えた。)
<Evaluation of texture> A hot cake prepared from the hot cake premix of the present invention was subjected to a sensory test by 10 men and women, and the texture was evaluated according to the following criteria. Table 6 shows the results. A: No difference from a mineral component-free product was found.
(All 20 people did not complain of the difference.) B: Almost the same as the product without mineral components. (One out of 20 complained of the difference.) C: Slightly different from the mineral-free product. (2 out of 20 people
~ 4 complained of the difference. D: The difference from the product without the mineral component is apparent. (20
10-14 of them complained of the difference. E: There is a rough feeling, and the texture is clearly different from that of the product without mineral components. (More than 15 out of 20 complained.)

【0079】[0079]

【表6】 [Table 6]

【0080】実施例71〜84 比較例31〜36 チェーダーチーズ・ゴーダーチーズ等のナチュラルチー
ズの表面にある外皮を除去した後に、下記の配合割合か
らなるプロセスチーズ原料と共にケトル乳化釜に入れ、
撹拌120rpm、85℃で加熱乳化し、得られた乳化物をカー
トンに充填・冷却してミネラル成分強化プロセスチーズ
を得た。得られたミネラル成分強化プロセスチーズの評
価を以下の方法で行った。なお食感の評価として、本発
明の食品添加剤を含まないプロセスチーズを本発明のプ
ロセスチーズと同様に作成し比較対象とした。
Examples 71 to 84 Comparative Examples 31 to 36 After removing the rind on the surface of natural cheese such as Cheddar cheese or Gorder cheese, the mixture was placed in a kettle emulsification kettle together with a processed cheese raw material having the following compounding ratio.
The emulsion was heated and emulsified at 85 ° C. with stirring at 120 rpm, and the obtained emulsion was filled in a carton and cooled to obtain a processed cheese with enhanced mineral components. The obtained mineral component-enhanced processed cheese was evaluated by the following method. In order to evaluate the texture, a processed cheese containing no food additive of the present invention was prepared in the same manner as the processed cheese of the present invention and used as a comparative object.

【0081】 <プロセスチーズ原料ならびに配合割合> ナチュラルチーズ(ゴーダーチーズ65%・チェーダーチーズ35%) 1000g 溶融塩(ポリ燐酸塩) 10g 重曹 6g 食品添加剤(実施例1〜14、比較例1〜6) 12g<Process Cheese Raw Materials and Mixing Ratio> Natural cheese (65% godder cheese / 35% cheddar cheese) 1000 g molten salt (polyphosphate) 10 g baking soda 6 g Food additives (Examples 1 to 14, Comparative Examples 1 to 6) ) 12g

【0082】<プロセスチーズ中での分散性>得られた
プロセスチーズの任意の10箇所より正確に1gを量り取
り、各々のプロセスチーズ中に含まれるミネラル成分
(本実施例・比較例の場合はカルシウム)を原子吸光光
度計で測定し、そのバラツキを評価した。結果を表7に
示す。
<Dispersibility in Processed Cheese> 1 g was weighed accurately from any 10 places of the obtained processed cheese, and the mineral components contained in each processed cheese (in the case of the present embodiment and comparative example, (Calcium) was measured with an atomic absorption spectrophotometer, and the variation was evaluated. Table 7 shows the results.

【0083】<食感の評価>本発明のプロセスチーズを
男女各々10名で官能試験を行い、食感に関して下記の基
準で判定した。結果を表7に示す。 A:ミネラル成分無添加品との違いが全く分からない。
(20 名全員が違いを訴えなかった。) B:ミネラル成分無添加品と殆ど同等である。(20 名中
1名が違いを訴えた。) C:ミネラル成分無添加品と微妙に異なる。(20 名中2
〜4名が違いを訴えた。) D:ミネラル成分無添加品と違いが明らかである。(20
名中10〜14名が違いを訴えた。) E:ざらつき感があり、ミネラル成分無添加品と食感が
明らかに異なる。(20 名中15名以上が違いを訴えた。)
<Evaluation of Texture> The processed cheese of the present invention was subjected to a sensory test by 10 men and women, and the texture was evaluated according to the following criteria. Table 7 shows the results. A: No difference from a mineral component-free product was found.
(All 20 people did not complain of the difference.) B: Almost the same as the product without mineral components. (One out of 20 complained of the difference.) C: Slightly different from the mineral-free product. (2 out of 20 people
~ 4 complained of the difference. D: The difference from the product without the mineral component is apparent. (20
10-14 of them complained of the difference. E: There is a rough feeling, and the texture is clearly different from that of the product without mineral components. (More than 15 out of 20 complained.)

【0084】[0084]

【表7】 [Table 7]

【0085】実施例85〜98 比較例37〜42 白身魚の生鮮魚から魚肉をとり、水晒し・脱水を行った
後に、下記の板付き蒸し蒲鉾原料を加えて練り合わせ、
蒸気で加熱・殺菌してミネラル成分強化板付き蒸し蒲鉾
を得た。得られたミネラル成分強化板付き蒸し蒲鉾の評
価を以下の方法で行った。なお食感の評価として、本発
明の食品添加剤を含まない板付き蒸し蒲鉾を本発明のプ
ロセスチーズと同様に作成し比較対象とした。
Examples 85 to 98 Comparative Examples 37 to 42 Fish meat was taken from fresh white fish, exposed to water and dehydrated, and the following steamed kamaboko raw material with a plate was added and kneaded.
It was heated and sterilized with steam to obtain a steamed kamaboko with a mineral component reinforcing plate. The obtained steamed kamaboko with a mineral component strengthening plate was evaluated by the following method. In order to evaluate the texture, a steamed kamaboko with a plate containing no food additive of the present invention was prepared in the same manner as the processed cheese of the present invention, and was used as a comparative object.

【0086】 <板付き蒸し蒲鉾原料ならびに配合割合> 白身魚(たちうおの生鮮魚)の魚肉 1000g 食塩 25g グルタミン酸ナトリウム 15g みりん 10g 酒(料理用) 40g 卵白 100g 馬鈴薯澱粉 70g 氷水 500g 食品添加剤(実施例1〜14、比較例1〜6) 23g<Steamed Kamaboko raw material with plate and mixing ratio> White meat (fresh fish) 1000g Salt 25g Sodium glutamate 15g Mirin 10g Sake (for cooking) 40g Egg white 100g Potato starch 70g Ice water 500g Food additive (implementation) Examples 1 to 14, Comparative Examples 1 to 6) 23 g

【0087】<板付き蒸し蒲鉾中での分散性>得られた
板付き蒸し蒲鉾の任意の10箇所より正確に1gを量り取
り、各々の蒲鉾中に含まれるミネラル成分(本実施例・
比較例の場合はカルシウム)を原子吸光光度計で測定
し、そのバラツキを測定した。結果を表8に示す。
<Dispersibility in steamed kamaboko with plate> 1 g was accurately weighed from any 10 places of the obtained steamed kamaboko with a plate, and the mineral component contained in each kamaboko (this embodiment,
In the case of the comparative example, calcium) was measured with an atomic absorption spectrophotometer, and the variation was measured. Table 8 shows the results.

【0088】<食感の評価>本発明の板付き蒸し蒲鉾を
男女各々10名で官能試験を行い、食感に関して下記の基
準で判定した。結果を表7に示す。 A:ミネラル成分無添加品との違いが全く分からない。
(20 名全員が違いを訴えなかった。) B:ミネラル成分無添加品と殆ど同等である。(20 名中
1名が違いを訴えた。) C:ミネラル成分無添加品と微妙に異なる。(20 名中2
〜4名が違いを訴えた。) D:ミネラル成分無添加品と違いが明らかである。(20
名中10〜14名が違いを訴えた。) E:ざらつき感があり、ミネラル成分無添加品と食感が
明らかに異なる。(20 名中15名以上が違いを訴えた。)
<Evaluation of texture> The steamed kamaboko with a plate of the present invention was subjected to a sensory test by 10 men and women, and the texture was determined according to the following criteria. Table 7 shows the results. A: No difference from a mineral component-free product was found.
(All 20 people did not complain of the difference.) B: Almost the same as the product without mineral components. (One out of 20 complained of the difference.) C: Slightly different from the mineral-free product. (2 out of 20 people
~ 4 complained of the difference. D: The difference from the product without the mineral component is apparent. (20
10-14 of them complained of the difference. E: There is a rough feeling, and the texture is clearly different from that of the product without mineral components. (More than 15 out of 20 complained.)

【0089】[0089]

【表8】 [Table 8]

【0090】[0090]

【発明の効果】叙上のとおり、本発明の食品添加剤は、
食感を損なうことなく、ミネラル成分強化即席麺・チュ
ーイングガム・ビスケット・ホットケーキプレミックス
・プロセスチーズ・水産練り製品等の各種食品組成物を
提供することができる。
As described above, the food additive of the present invention comprises:
Various food compositions such as instant noodles, chewing gum, biscuits, hot cake premixes, processed cheese, and fishery paste products can be provided without impairing the texture.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) A23G 3/30 A23G 3/30 4B046 A23L 1/16 A23L 1/16 A 1/325 101 1/325 101C (72)発明者 清水 清也 兵庫県明石市魚住町西岡1455番地 丸尾カ ルシウム株式会社内 Fターム(参考) 4B001 AC46 AC99 EC05 4B014 GB11 GB13 GK06 GL01 4B018 LE03 MD04 ME05 4B032 DB21 DB35 DK01 4B034 LC04 LK01 4B046 LA01 LB06 LC06 LG03 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI theme coat ゛ (Reference) A23G 3/30 A23G 3/30 4B046 A23L 1/16 A23L 1/16 A 1/325 101 1/325 101C ( 72) Inventor Kiyomizu Shimizu 1455 Nishioka, Uozumi-cho, Akashi-shi, Hyogo F-term (reference) 4C001 AC46 AC99 EC05 4B014 GB11 GB13 GK06 GL01 4B018 LE03 MD04 ME05 4B032 DB21 DB35 DK01 4B034 LC04 LK01 406046 LA LC06 LG03

Claims (10)

【特許請求の範囲】[Claims] 【請求項1】 下記の式(a)〜(h)を満足する無機
系粒子からなることを特徴とする食品添加剤。 (a)0.01≦dx≦10(μm ) (b)1 ≦α≦200 但し α=d50/dx (c)0≦β≦7 但し β=(d90−d10)/d50 (d)40≦CA ≦65(重量%) (e)20≦Vis ≦140 (Pa・ sec.) (f)1≦Ti ≦10 (g)0.1 ≦Sw≦50(m2 /g) (h) 0.1 ≦Wg≦2(g/g) 但し、 dx :電子顕微鏡写真により測定した、粒子を構成す
る一次粒子の平均粒子径(μm )。 α :凝集指数。 d50 :マイクロトラックFRAレーザー式粒度分布計
により測定した粒子の50%平均粒子径(μm )。 β :シャープネス。 d90 :マイクロトラックFRAレーザー式粒度分布計
により測定した粒子のふるい通過側累計90%粒子径(μ
m )。 d10 :マイクロトラックFRAレーザー式粒度分布計
により測定した粒子のふるい通過側累計10%粒子径(μ
m )。 CA :無機系粒子の懸濁液の粘度が、60rpm/min.の条
件で200Pa ・ s に達するときの固形分濃度(重量%) Vis :無機系粒子の固形分濃度45%、60rpm/min.の条
件で測定したときの懸濁液の粘度(Pa・ sec.:20℃) Ti :下記式(i)で表される無機系粒子の固形分濃
度45%の懸濁液のチキソ性 (i) Ti=VisA/Vis 但し、 VisA:無機系粒子の固形分濃度45%、6rpm/min.の条件
で測定したときの懸濁液の粘度(Pa・ sec.:20℃) Sw :窒素吸着法によるBET比表面積(m2 /g) Wg :無機系粒子1g当たりの吸水量(g/g)
1. A food additive comprising inorganic particles satisfying the following formulas (a) to (h). (A) 0.01 ≦ dx ≦ 10 (μm) (b) 1 ≦ α ≦ 200 where α = d 50 / dx (c ) 0 ≦ β ≦ 7 where β = (d 90 -d 10) / d 50 (d) 40 ≦ CA ≦ 65 (% by weight) (e) 20 ≦ Vis ≦ 140 (Pa · sec.) (F) 1 ≦ Ti ≦ 10 (g) 0.1 ≦ Sw ≦ 50 (m 2 / g) (h) 0.1 ≦ Wg ≦ 2 (g / g), where dx is an average particle diameter (μm) of primary particles constituting the particles, as measured by an electron micrograph. α: Aggregation index. d 50 : 50% average particle diameter (μm) of particles measured by a Microtrac FRA laser type particle size distribution analyzer. β: sharpness. d 90 : Cumulative 90% particle diameter (μ) of particles passing through the sieve measured by a Microtrac FRA laser type particle size distribution analyzer
m). d 10 : Total 10% particle diameter (μ) of particles passing through the sieve measured by a Microtrac FRA laser particle size distribution analyzer
m). CA: solid content concentration (weight%) when the viscosity of the suspension of inorganic particles reaches 200 Pa · s under the condition of 60 rpm / min. Vis: solid content concentration of inorganic particles 45%, 60 rpm / min. Viscosity of suspension (Pa · sec .: 20 ° C.) when measured under the following conditions: Ti: thixotropic property of a suspension having a solid concentration of 45% of inorganic particles represented by the following formula (i) (i ) Ti = VisA / Vis, where VisA is the viscosity of the suspension measured at 6 rpm / min. At a solid concentration of 45% of inorganic particles (Pa · sec .: 20 ° C.) Sw: Nitrogen adsorption method BET specific surface area (m 2 / g) according to the formula: Wg: Water absorption (g / g) per 1 g of inorganic particles
【請求項2】 無機系粒子がカルシウム系化合物である
ことを特徴とする請求項1記載の食品添加剤。
2. The food additive according to claim 1, wherein the inorganic particles are calcium compounds.
【請求項3】 無機系粒子が、乳化安定剤、縮合燐酸お
よびその塩よりなる群から選択された少なくとも1種で
表面処理されていることを特徴とする請求項1又は2記
載の食品添加剤。
3. The food additive according to claim 1, wherein the inorganic particles are surface-treated with at least one selected from the group consisting of an emulsion stabilizer, condensed phosphoric acid and a salt thereof. .
【請求項4】 請求項1〜3のいずれか1項に記載の食
品添加剤を食品に配合してなることを特徴とする食品組
成物。
4. A food composition comprising the food additive according to claim 1 in a food.
【請求項5】 食品が麺又は即席麺であることを特徴と
する請求項4記載の食品組成物。
5. The food composition according to claim 4, wherein the food is noodle or instant noodle.
【請求項6】 食品がチューイングガムであることを特
徴とする請求項4記載の食品組成物。
6. The food composition according to claim 4, wherein the food is a chewing gum.
【請求項7】 食品がビスケットであることを特徴とす
る請求項4記載の食品組成物。
7. The food composition according to claim 4, wherein the food is a biscuit.
【請求項8】食品がホットケーキプレミックスであるこ
とを特徴とする請求項4記載の食品組成物。
8. The food composition according to claim 4, wherein the food is a hot cake premix.
【請求項9】食品がプロセスチーズであることを特徴と
する請求項4記載の食品組成物。
9. The food composition according to claim 4, wherein the food is processed cheese.
【請求項10】 食品が水産練り製品であることを特徴
とする請求項4記載の食品組成物。
10. The food composition according to claim 4, wherein the food is a fishery paste product.
JP2001181370A 2001-06-15 2001-06-15 Calcium food additive for instant noodles and instant noodles containing the same Expired - Fee Related JP4514991B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001181370A JP4514991B2 (en) 2001-06-15 2001-06-15 Calcium food additive for instant noodles and instant noodles containing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001181370A JP4514991B2 (en) 2001-06-15 2001-06-15 Calcium food additive for instant noodles and instant noodles containing the same

Publications (2)

Publication Number Publication Date
JP2002369666A true JP2002369666A (en) 2002-12-24
JP4514991B2 JP4514991B2 (en) 2010-07-28

Family

ID=19021653

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001181370A Expired - Fee Related JP4514991B2 (en) 2001-06-15 2001-06-15 Calcium food additive for instant noodles and instant noodles containing the same

Country Status (1)

Country Link
JP (1) JP4514991B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2021166531A (en) * 2016-01-26 2021-10-21 タイ ユニオン グループ パブリック カンパニー リミテッド Calcium-fortified seafood product
JP2022067605A (en) * 2020-10-20 2022-05-06 株式会社ピアンタ Material for confectionery, gum, and method for producing the gum

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2021166531A (en) * 2016-01-26 2021-10-21 タイ ユニオン グループ パブリック カンパニー リミテッド Calcium-fortified seafood product
JP7406524B2 (en) 2016-01-26 2023-12-27 タイ ユニオン グループ パブリック カンパニー リミテッド Calcium-fortified seafood products
JP2022067605A (en) * 2020-10-20 2022-05-06 株式会社ピアンタ Material for confectionery, gum, and method for producing the gum

Also Published As

Publication number Publication date
JP4514991B2 (en) 2010-07-28

Similar Documents

Publication Publication Date Title
JP6163427B2 (en) Powdered brown algae and their use
US8197878B2 (en) Method for producing a low sodium salt composition
TWI546019B (en) Method for improving salty taste of food or beverage and salty taste improving agent
WO2017061628A1 (en) Food-improving agent
JP3522115B2 (en) Food composition containing a plurality of dispersible cellulose composites
CN111770690B (en) Method for producing instant noodles
JP2002369666A (en) Food additive and food composition containing the same
US20110020522A1 (en) Process for producing granular low-calorie food material and raw material for producing the same
JPH10327823A (en) Production of roux
EP2647298A1 (en) Agent for imparting viscosity to liquid batter
WO2008001588A1 (en) Boiled egg yolk-like food
JP2002186458A (en) Food additive composition and food composition containing the same
JP6132329B2 (en) Chinese noodle manufacturing method
JP2003219837A (en) Food additive and food composition containing the same
WO2021065930A1 (en) Composition
JP2979258B2 (en) Processed foods and food ingredients containing micronized cellulose
JP2002186468A (en) Mix for flour-baked food and flour-baked food
JP5872231B2 (en) Rice flour-containing boiled noodles and method for producing the same
JP5120858B2 (en) Quality improvement agent for fish paste products and / or fish surimi
JP2002176934A (en) Granular food and method for producing the same
JP2682661B2 (en) Method for improving the quality of flour products
JP2022156190A (en) Food raw material, production method thereof, and flavor improvement method
WO2024058258A1 (en) Production method for lumpy bread
JP6529785B2 (en) Processed wheat flour containing melinjo powder, method for producing processed wheat flour and composition for processed wheat flour
JP2021058162A (en) Method for producing baked japanese and western confectioneries using bubble-bearing composition containing kale powder

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20040426

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20050823

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20050830

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20051028

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20061219

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20070216

A911 Transfer of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20070412

A912 Removal of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A912

Effective date: 20070511

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100318

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20100512

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

Ref document number: 4514991

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130521

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140521

Year of fee payment: 4

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

RD02 Notification of acceptance of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: R3D02

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees